Patent Grant
9631265
The present invention relates to a high-strength hot-rolled steel sheet which is excellent in uniform deformability contributing to stretchability, drawability, or the like and is excellent in local deformability contributing to bendability, stretch flangeability, burring formability, or the like, and relates to a method for producing the same. Particularly, the present invention relates to a steel sheet including a Dual Phase (DP) structure.
Priority is claimed on Japanese Patent Application No. 2011-117432, filed on May 25, 2011, and the content of which is incorporated herein by reference.
In order to suppress emission of carbon dioxide gas from a vehicle, a weight reduction of an automobile body has been attempted by utilization of a high-strength steel sheet. Moreover, from a viewpoint of ensuring safety of a passenger, the utilization of the high-strength steel sheet for the automobile body has been attempted in addition to a mild steel sheet. However, in order to further improve the weight reduction of the automobile body in future, a usable strength level of the high-strength steel sheet should be increased as compared with that of conventional one. Moreover, in order to utilize the high-strength steel sheet for suspension parts or the like of the automobile body, the local deformability contributing to the burring formability or the like should also be improved in addition to the uniform deformability.
However, in general, when the strength of steel sheet is increased, the formability (deformability) is decreased. For example, Non-Patent Document 1 discloses that uniform elongation which is important for drawing or stretching is decreased by strengthening the steel sheet.
Contrary, Non-Patent Document 2 discloses a method which secures the uniform elongation by compositing metallographic structure of the steel sheet even when the strength is the same.
In addition, Non-Patent Document 3 discloses a metallographic structure control method which improves local ductility representing the bendability, hole expansibility, or the burring formability by controlling inclusions, controlling the microstructure to single phase, and decreasing hardness difference between microstructures. In the Non-Patent Document 3, the microstructure of the steel sheet is controlled to the single phase by microstructure control, and thus, the local deformability contributing to the hole expansibility or the like is improved. However, in order to control the microstructure to the single phase, a heat treatment from an austenite single phase is a basis producing method as described in Non-Patent Document 4.
In addition, the Non-Patent Document 4 discloses a technique which satisfies both the strength and the ductility of the steel sheet by controlling a cooling after a hot-rolling in order to control the metallographic structure, specifically, in order to obtain intended morphologies of precipitates and transformation structures and to obtain an appropriate fraction of ferrite and bainite. However, all techniques as described above are the improvement methods for the local deformability which rely on the microstructure control, and are largely influenced by a microstructure formation of a base.
Also, a method, which improves material properties of the steel sheet by increasing reduction at a continuous hot-rolling in order to refine grains, is known as a related art. For example, Non-Patent Document 5 discloses a technique which improves the strength and toughness of the steel sheet by conducting a large reduction rolling in a comparatively lower temperature range within an austenite range in order to refine the grains of ferrite which is a primary phase of a product by transforming non-recrystallized austenite into the ferrite. However, in Non-Patent Document 5, a method for improving the local deformability to be solved by the present invention is not considered at all.
As described above, it is the fact that the technique, which simultaneously satisfies the high-strength and both properties of the uniform deformability and the local deformability, is not found. For example, in order to improve the local deformability of the high-strength steel sheet, it is necessary to conduct the microstructure control including the inclusions. However, since the improvement relies on the microstructure control, it is necessary to control the fraction or the morphology of the microstructure such as the precipitates, the ferrite, or the bainite, and therefore the metallographic structure of the base is limited. Since the metallographic structure of the base is restricted, it is difficult not only to improve the local deformability but also to simultaneously improve the strength and the local deformability.
An object of the present invention is to provide a hot-rolled steel sheet which has the high-strength, the excellent uniform deformability, the excellent local deformability, and small orientation dependence (anisotropy) of formability by controlling texture and by controlling the size or the morphology of the grains in addition to the metallographic structure of the base, and is to provide a method for producing the same. Herein, in the present invention, the strength mainly represents tensile strength, and the high-strength indicates the strength of 440 MPa or more in the tensile strength. In addition, in the present invention, satisfaction of the high-strength, the excellent uniform deformability, and the excellent local deformability indicates a case of simultaneously satisfying all conditions of TS 440 (unit: MPa), TS×u-EL≧7000 (unit: MPa·%), TS×λ≧30000 (unit: MPa·%), and d/RmC≧1 (no unit) by using characteristic values of the tensile strength (TS), the uniform elongation (u-EL), hole expansion ratio (λ), and d/RmC which is a ratio of thickness d to minimum radius RmC of bending to a C-direction.
In the related arts, as described above, the improvement in the local deformability contributing to the hole expansibility, the bendability, or the like has been attempted by controlling the inclusions, by refining the precipitates, by homogenizing the microstructure, by controlling the microstructure to the single phase, by decreasing the hardness difference between the microstructures, or the like. However, only by the above-described techniques, main constituent of the microstructure must be restricted. In addition, when an element largely contributing to an increase in the strength, such as representatively Nb or Ti, is added for high-strengthening, the anisotropy may be significantly increased. Accordingly, other factors for the formability must be abandoned or directions to take a blank before forming must be limited, and as a result, the application is restricted. On the other hand, the uniform deformability can be improved by dispersing hard phases such as martensite in the metallographic structure.
In order to obtain the high-strength and to improve both the uniform deformability contributing to the stretchability or the like and the local deformability contributing to the hole expansibility, the bendability, or the like, the inventors have newly focused influences of the texture of the steel sheet in addition to the control of the fraction or the morphology of the metallographic structures of the steel sheet, and have investigated and researched the operation and the effect thereof in detail. As a result, the inventors have found that, by controlling a chemical composition, the metallographic structure, and the texture represented by pole densities of each orientation of a specific crystal orientation group of the steel sheet, the high-strength is obtained, the local deformability is remarkably improved due to a balance of Lankford-values (r values) in a rolling direction, in a direction (C-direction) making an angle of 90° with the rolling direction, in a direction making an angle of 30° with the rolling direction, or in a direction making an angle of 60° with the rolling direction, and the uniform deformability is also secured due to the dispersion of the hard phases such as the martensite.
An aspect of the present invention employs the following.
(1) A hot-rolled steel sheet according to an aspect of the present invention includes, as a chemical composition, by mass %, C: 0.01% to 0.4%, Si: 0.001% to 2.5%, Mn: 0.001% to 4.0%, Al: 0.001% to 2.0%, P: limited to 0.15% or less, S: limited to 0.03% or less, N: limited to 0.01% or less, 0: limited to 0.01% or less, and a balance consisting of Fe and unavoidable impurities, wherein: an average pole density of an orientation group of {100}<011> to {223}<110>, which is a pole density represented by an arithmetic average of pole densities of each crystal orientation {100}<011>, {116}<110>, {114}<110>, {112}<110>, and {223}<110>, is 1.0 to 5.0 and a pole density of a crystal orientation {332}<113> is 1.0 to 4.0 in a thickness central portion which is a thickness range of ⅝ to ⅜ based on a surface of the steel sheet; the steel sheet includes, as a metallographic structure, plural grains, and includes, by area %, a ferrite and a bainite of 30% to 99% in total and a martensite of 1% to 70%; and when an area fraction of the martensite is defined as fM in unit of area %, an average size of the martensite is defined as dia in unit of μm, an average distance between the martensite is defined as dis in unit of μm, and a tensile strength of the steel sheet is defined as TS in unit of MPa, a following Expression 1 and a following Expression 2 are satisfied.
dia≦13 μm (Expression 1)
TS/fM×dis/dia≧500 (Expression 2)
(2) The hot-rolled steel sheet according to (1) may further includes, as the chemical composition, by mass %, at least one selected from the group consisting of Mo: 0.001% to 1.0%, Cr: 0.001% to 2.0%, Ni: 0.001% to 2.0%, Cu: 0.001% to 2.0%, B: 0.0001% to 0.005%, Nb: 0.001% to 0.2%, Ti: 0.001% to 0.2%, V: 0.001% to 1.0%, W: 0.001% to 1.0%, Ca: 0.0001% to 0.01%, Mg: 0.0001% to 0.01%, Zr: 0.0001% to 0.2%, Rare Earth Metal: 0.0001% to 0.1%, As: 0.0001% to 0.5%, Co: 0.0001% to 1.0%, Sn: 0.0001% to 0.2%, Pb: 0.0001% to 0.2%, Y: 0.0001% to 0.2%, and Hf: 0.0001% to 0.2%.
(3) In the hot-rolled steel sheet according to (1) or (2), a volume average diameter of the grains may be 5 μm to 30 μm.
(4) In the hot-rolled steel sheet according to (1) or (2), the average pole density of the orientation group of {100}<011> to {223}<110> may be 1.0 to 4.0, and the pole density of the crystal orientation {332}<113> may be 1.0 to 3.0.
(5) In the hot-rolled steel sheet according to any one of (1) to (4), when a major axis of the martensite is defined as La, and a minor axis of the martensite is defined as Lb, an area fraction of the martensite satisfying a following Expression 3 may be 50% to 100% as compared with the area fraction fM of the martensite.
La/Lb≦5.0 (Expression 3)
(6) In the hot-rolled steel sheet according to any one of (1) to (5), the steel sheet may include, as the metallographic structure, by area %, the ferrite of 30% to 99%.
(7) In the hot-rolled steel sheet according to any one of (1) to (6), the steel sheet may include, as the metallographic structure, by area %, the bainite of 5% to 80%.
(8) In the hot-rolled steel sheet according to any one of (1) to (7), the steel sheet may include a tempered martensite in the martensite.
(9) In the hot-rolled steel sheet according to any one of (1) to (8), an area fraction of coarse grain having grain size of more than 35 μm may be 0% to 10% among the grains in the metallographic structure of the steel sheet.
(10) In the hot-rolled steel sheet according to any one of (1) to (9), a hardness H of the ferrite may satisfy a following Expression 4.
H<200+30×[Si]+21×[Mn]+270×[P]+78×[Nb]1/2+108×[Ti]1/2 (Expression 4)
(11) In the hot-rolled steel sheet according to any one of (1) to (10), when a hardness of the ferrite or the bainite which is a primary phase is measured at 100 points or more, a value dividing a standard deviation of the hardness by an average of the hardness may be 0.2 or less.
(12) A method for producing a hot-rolled steel sheet according to an aspect of the present invention includes: first-hot-rolling a steel in a temperature range of 1000° C. to 1200° C. under conditions such that at least one pass whose reduction is 40% or more is included so as to control an average grain size of an austenite in the steel to 200 μm or less, wherein the steel includes, as a chemical composition, by mass %, C: 0.01% to 0.4%, Si: 0.001% to 2.5%, Mn: 0.001% to 4.0%, Al: 0.001% to 2.0%, P: limited to 0.15% or less, S: limited to 0.03% or less, N: limited to 0.01% or less, 0: limited to 0.01% or less, and a balance consisting of Fe and unavoidable impurities; second-hot-rolling the steel under conditions such that, when a temperature calculated by a following Expression 5 is defined as T1 in unit of ° C. and a ferritic transformation temperature calculated by a following Expression 6 is defined as Ar3 in unit of ° C., a large reduction pass whose reduction is 30% or more in a temperature range of T1+30° C. to T1+200° C. is included, a cumulative reduction in the temperature range of T1+30° C. to T1+200° C. is 50% or more, a cumulative reduction in a temperature range of Ar3 to lower than T1+30° C. is limited to 30% or less, and a rolling finish temperature is Ar3 or higher; first-cooling the steel under conditions such that, when a waiting time from a finish of a final pass in the large reduction pass to a cooling start is defined as t in unit of second, the waiting time t satisfies a following Expression 7, an average cooling rate is 50° C./second or faster, a cooling temperature change which is a difference between a steel temperature at the cooling start and a steel temperature at a cooling finish is 40° C. to 140° C., and the steel temperature at the cooling finish is T1+100° C. or lower; second-cooling the steel to a temperature range of 600° C. to 800° C. under an average cooling rate of 15° C./second to 300° C./second after finishing the second-hot-rolling; holding the steel in the temperature range of 600° C. to 800° C. for 1 second to 15 seconds; third-cooling the steel to a temperature range of a room temperature to 350° C. under an average cooling rate of 50° C./second to 300° C./second after finishing the holding; coiling the steel in the temperature range of the room temperature to 350° C.
T1=850+10×([C]+[N])×[Mn] (Expression 5)
here, in Expression 6, [C], [Mn], [Si] and [P] represent mass percentages of C, Mn, Si, and P respectively.
t≦2.5×t1 (Expression 7)
here, t1 is represented by a following Expression 8.
t1=0.001×((Tf−T1)×P1/100)2−0.109×((Tf−T1)×P1/100)+3.1 (Expression 8)
here, Tf represents a celsius temperature of the steel at the finish of the final pass, and P1 represents a percentage of a reduction at the final pass.
(13) In the method for producing the hot-rolled steel sheet according to (12), the steel may further includes, as the chemical composition, by mass %, at least one selected from the group consisting of Mo: 0.001% to 1.0%, Cr: 0.001% to 2.0%, Ni: 0.001% to 2.0%, Cu: 0.001% to 2.0%, B: 0.0001% to 0.005%, Nb: 0.001% to 0.2%, Ti: 0.001% to 0.2%, V: 0.001% to 1.0%, W: 0.001% to 1.0%, Ca: 0.0001% to 0.01%, Mg: 0.0001% to 0.01%, Zr: 0.0001% to 0.2%, Rare Earth Metal: 0.0001% to 0.1%, As: 0.0001% to 0.5%, Co: 0.0001% to 1.0%, Sn: 0.0001% to 0.2%, Pb: 0.0001% to 0.2%, Y: 0.0001% to 0.2%, and Hf: 0.0001% to 0.2%, wherein a temperature calculated by a following Expression 9 may be substituted for the temperature calculated by the Expression 5 as T1.
T1=850+10×([C]+[N])×[Mn]+350×[Nb]+250×[Ti]+40×[B]+10×[Cr]+100×[Mo]+100×[V] (Expression 9)
here, [C], [N], [Mn], [Nb], [Ti], [B], [Cr], [Mo], and [V] represent mass percentages of C, N, Mn, Nb, Ti, B, Cr, Mo, and V respectively.
(14) In the method for producing the hot-rolled steel sheet according to (12) or (13), the waiting time t may further satisfy a following Expression 10.
0≦t<t1 (Expression 10)
(15) In the method for producing the hot-rolled steel sheet according to (12) or (13), the waiting time t may further satisfy a following Expression 11.
t1≦t≦t1×2.5 (Expression 11)
(16) In the method for producing the hot-rolled steel sheet according to any one of (12) to (15), in the first-hot-rolling, at least two times of rollings whose reduction is 40% or more may be conducted, and the average grain size of the austenite may be controlled to 100 μm or less.
(17) In the method for producing the hot-rolled steel sheet according to any one of (12) to (16), the second-cooling may start within 3 seconds after finishing the second-hot-rolling.
(18) In the method for producing the hot-rolled steel sheet according to any one of (12) to (17), in the second-hot-rolling, a temperature rise of the steel between passes may be 18° C. or lower.
(19) In the method for producing the hot-rolled steel sheet according to any one of (12) to (18), a final pass of rollings in the temperature range of T1+30° C. to T1+200° C. may be the large reduction pass.
(20) In the method for producing the hot-rolled steel sheet according to any one of (12) to (19), in the holding, the steel may be held in a temperature range of 600° C. to 680° C. for 3 seconds to 15 seconds.
(21) In the method for producing the hot-rolled steel sheet according to any one of (12) to (20), the first-cooling may be conducted at an interval between rolling stands.
According to the above aspects of the present invention, it is possible to obtain a hot-rolled steel sheet which has the high-strength, the excellent uniform deformability, the excellent local deformability, and the small anisotropy even when the element such as Nb or Ti is added.
Hereinafter, a hot-rolled steel sheet according to an embodiment of the present invention will be described in detail. First, a pole density of a crystal orientation of the hot-rolled steel sheet will be described.
Average Pole Density D1 of Crystal Orientation: 1.0 to 5.0
Pole Density D2 of Crystal Orientation: 1.0 to 4.0
In the hot-rolled steel sheet according to the embodiment, as the pole densities of two kinds of the crystal orientations, the average pole density D1 of an orientation group of {100}<011> to {223}<110> (hereinafter, referred to as “average pole density”) and the pole density D2 of a crystal orientation {332}<113> in a thickness central portion, which is a thickness range of ⅝ to ⅜ (a range which is ⅝ to ⅜ of the thickness distant from a surface of the steel sheet along a normal direction (a depth direction) of the steel sheet), are controlled in reference to a thickness-cross-section (a normal vector thereof corresponds to the normal direction) which is parallel to a rolling direction.
In the embodiment, the average pole density D1 is an especially-important characteristic (orientation integration and development degree of texture) of the texture (crystal orientation of grains in metallographic structure). Herein, the average pole density D1 is the pole density which is represented by an arithmetic average of pole densities of each crystal orientation {100}<011>, {116}<110>, {114}<110>, {112}<110>, and {223}<110>.
A intensity ratio of electron diffraction intensity or X-ray diffraction intensity of each orientation to that of a random sample is obtained by conducting Electron Back Scattering Diffraction (EBSD) or X-ray diffraction on the above cross-section in the thickness central portion which is the thickness range of ⅝ to ⅜, and the average pole density D1 of the orientation group of {100}<011> to {223}<110> can be obtained from each intensity ratio.
When the average pole density D1 of the orientation group of {100}<011> to {223}<110> is 5.0 or less, it is satisfied that d/RmC (a parameter in which the thickness d is divided by a minimum bend radius RmC (C-direction bending)) is 1.0 or more, which is minimally-required for working suspension parts or frame parts. Particularly, the condition is a requirement in order that tensile strength TS, hole expansion ratio λ, and total elongation EL preferably satisfy TS×λ≧30000 and TS×EL≧14000 which are two conditions required for the suspension parts of the automobile body.
In addition, when the average pole density D1 is 4.0 or less, a ratio (Rm45/RmC) of a minimum bend radius Rm45 of 45°-direction bending to the minimum bend radius RmC of the C-direction bending is decreased, in which the ratio is a parameter of orientation dependence (isotropy) of formability, and the excellent local deformability which is independent of the bending direction can be secured. As described above, the average pole density D1 may be 5.0 or less, and may be preferably 4.0 or less. In a case where the further excellent hole expansibility or small critical bending properties are needed, the average pole density D1 may be more preferably less than 3.5, and may be furthermore preferably less than 3.0.
When the average pole density D1 of the orientation group of {100}<011> to {223}<110> is more than 5.0, the anisotropy of mechanical properties of the steel sheet is significantly increased. As a result, although the local deformability in only a specific direction is improved, the local deformability in a direction different from the specific direction is significantly decreased. Therefore, in the case, the steel sheet cannot satisfy d/RmC≧1.0.
On the other hand, when the average pole density D1 is less than 1.0, the local deformability may be decreased. Accordingly, preferably, the average pole density D1 may be 1.0 or more.
In addition, from the similar reasons, the pole density D2 of the crystal orientation {332}<113> in the thickness central portion which is the thickness range of ⅝ to ⅜ may be 4.0 or less. The condition is a requirement in order that the steel sheet satisfies d/RmC≧1.0, and particularly, that the tensile strength TS, the hole expansion ratio λ, and the total elongation EL preferably satisfy TS×λ≧30000 and TS×EL≧14000 which are two conditions required for the suspension parts.
Moreover, when the pole density D2 is 3.0 or less, TS×λ or d/RmC can be further improved. The pole density D2 may be preferably 2.5 or less, and may be more preferably 2.0 or less. When the pole density D2 is more than 4.0, the anisotropy of the mechanical properties of the steel sheet is significantly increased. As a result, although the local deformability in only a specific direction is improved, the local deformability in a direction different from the specific direction is significantly decreased. Therefore, in the case, the steel sheet cannot sufficiently satisfy d/RmC≧1.0.
On the other hand, when the average pole density D2 is less than 1.0, the local deformability may be decreased. Accordingly, preferably, the pole density D2 of the crystal orientation {332}<113> may be 1.0 or more.
The pole density is synonymous with an X-ray random intensity ratio. The X-ray random intensity ratio can be obtained as follows. Diffraction intensity (X-ray or electron) of a standard sample which does not have a texture to a specific orientation and diffraction intensity of a test material are measured by the X-ray diffraction method in the same conditions. The X-ray random intensity ratio is obtained by dividing the diffraction intensity of the test material by the diffraction intensity of the standard sample. The pole density can be measured by using the X-ray diffraction, the Electron Back Scattering Diffraction (EBSD), or Electron Channeling Pattern (ECP). For example, the average pole density D1 of the orientation group of {100}<011> to {223}<110> can be obtained as follows. The pole densities of each orientation {100}<110>, {116}<110>, {114}<110>, {112}<110>, and {223}<110> are obtained from a three-dimensional texture (ODF: Orientation Distribution Functions) which is calculated by a series expanding method using plural pole figures in pole figures of {110}, {100}, {211}, and {310} measured by the above methods. The average pole density D1 is obtained by calculating an arithmetic average of the pole densities.
With respect to samples which are supplied for the X-ray diffraction, the EBSD, and the ECP, the thickness of the steel sheet may be reduced to a predetermined thickness by mechanical polishing or the like, strain may be removed by chemical polishing, electrolytic polishing, or the like, the samples may be adjusted so that an appropriate surface including the thickness range of ⅝ to ⅜ is a measurement surface, and then the pole densities may be measured by the above methods. With respect to a transverse direction, it is preferable that the samples are collected in the vicinity of ¼ or ¾ position of the thickness (a position which is at ¼ of a steel sheet width distant from a side edge the steel sheet).
When the above pole densities are satisfied in many other thickness portions of the steel sheet in addition to the thickness central portion, the local deformability is further improved. However, since the texture in the thickness central portion significantly influences the anisotropy of the steel sheet, the material properties of the thickness central portion approximately represent the material properties of the entirety of the steel sheet. Accordingly, the average pole density D1 of the orientation group of {100}<011> to {223}<110> and the pole density D2 of the crystal orientation {332}<113> in the thickness central portion of ⅝ to ⅜ are prescribed.
Herein, {hkl}<uvw> indicates that the normal direction of the sheet surface is parallel to <hkl> and the rolling direction is parallel to <uvw> when the sample is collected by the above-described method. In addition, generally, in the orientation of the crystal, an orientation perpendicular to the sheet surface is represented by (hkl) or {hkl} and an orientation parallel to the rolling direction is represented by [uvw] or <uvw>. {hkl}<uvw> indicates collectively equivalent planes, and (hkl)[uvw] indicates each crystal plane. Specifically, since the embodiment targets a body centered cubic (bcc) structure, for example, (111), (−111), (1−11), (11−1), (−1−11), (−11−1), (1−1−1), and (−1−1−1) planes are equivalent and cannot be classified. In the case, the orientation is collectively called as {111}. Since the ODF expression is also used for orientation expressions of other crystal structures having low symmetry, generally, each orientation is represented by (hkl)[uvw] in the ODF expression. However, in the embodiment, {hkl}<uvw> and (hkl)[uvw] are synonymous.
Next, a metallographic structure of the hot-rolled steel sheet according to the embodiment will be described.
A metallographic structure of the hot-rolled steel sheet according to the embodiment is fundamentally to be a Dual Phase (DP) structure which includes plural grains, includes ferrite and/or bainite as a primary phase, and includes martensite as a secondary phase. The strength and the uniform deformability can be increased by dispersing the martensite which is the secondary phase and the hard phase to the ferrite or the bainite which is the primary phase and has the excellent deformability. The improvement in the uniform deformability is derived from an increase in work hardening rate by finely dispersing the martensite which is the hard phase in the metallographic structure. Moreover, herein, the ferrite or the bainite includes polygonal ferrite and bainitic ferrite.
The hot-rolled steel sheet according to the embodiment includes residual austenite, pearlite, cementite, plural inclusions, or the like as the microstructure in addition to the ferrite, the bainite, and the martensite. It is preferable that the microstructures other than the ferrite, the bainite, and the martensite are limited to, by area %, 0% to 10%. Moreover, when the austenite is retained in the microstructure, secondary work embrittlement or delayed fracture properties deteriorates. Accordingly, except for the residual austenite of approximately 5% in area fraction which unavoidably exists, it is preferable that the residual austenite is not substantially included.
Area fraction of Ferrite and Bainite which are Primary Phase: 30% to less than 99%
The ferrite and the bainite which are the primary phase are comparatively soft, and have the excellent deformability. When the area fraction of the ferrite and the bainite is 30% or more in total, both properties of the uniform deformability and the local deformability of the hot-rolled steel sheet according to the embodiment are satisfied. More preferably, the ferrite and the bainite may be, by area %, 50% or more in total. On the other hand, when the area fraction of the ferrite and the bainite is 99% or more in total, the strength and the uniform deformability of the steel sheet are decreased.
Preferably, the area fraction of the ferrite which is the primary phase may be 30% to 99%. By controlling the area fraction of the ferrite which is comparatively excellent in the deformability to 30% to 99%, it is possible to preferably increase the ductility (deformability) in a balance between the strength and the ductility (deformability) of the steel sheet. Particularly, the ferrite contributes to the improvement in the uniform deformability.
Alternatively, the area fraction of the bainite which is the primary phase may be 5% to 80%. By controlling the area fraction of the bainite which is comparatively excellent in the strength to 5% to 80%, it is possible to preferably increase the strength in a balance between the strength and the ductility (deformability) of the steel sheet. By increasing the area fraction of the bainite which is harder phase than the ferrite, the strength of the steel sheet is improved. In addition, the bainite, which has small hardness difference from the martensite as compared with the ferrite, suppresses initiation of voids at an interface between the soft phase and the hard phase, and improves the hole expansibility.
Area fraction fM of Martensite: 1% to 70%
By dispersing the martensite, which is the secondary phase and is the hard phase, in the metallographic structure, it is possible to improve the strength and the uniform deformability. When the area fraction of the martensite is less than 1%, the dispersion of the hard phase is insufficient, the work hardening rate is decreased, and the uniform deformability is decreased. Preferably, the area fraction of the martensite may be 3% or more. On the other hand, when the area fraction of the martensite is more than 70%, the area fraction of the hard phase is excessive, and the deformability of the steel sheet is significantly decreased. In accordance with the balance between the strength and the deformability, the area fraction of the martensite may be 50% or less. Preferably, the area fraction of the martensite may be 30% or less. More preferably, the area fraction of the martensite may be 20% or less.
Average Grain Size dia of Martensite: 13 μm or less
When the average size of the martensite is more than 13 μm, the uniform deformability of the steel sheet may be decreased, and the local deformability may be decreased. It is considered that the uniform elongation is decreased due to the fact that contribution to the work hardening is decreased when the average size of the martensite is coarse, and that the local deformability is decreased due to the fact that the voids easily initiates in the vicinity of the coarse martensite. Preferably, the average size of the martensite may be less than 10 μm. More preferably, the average size of the martensite may be 7 μm or less.
Relationship of TS/fM×dis/dia: 500 or more
Moreover, as a result of the investigation in detail by the inventors, it is found that, when the tensile strength is defined as TS (tensile strength) in unit of MPa, the area fraction of the martensite is defined as fM (fraction of Martensite) in unit of %, an average distance between the martensite grains is defined as dis (distance) in unit of μm, and the average grain size of the martensite is defined as dia (diameter) in unit of μm, the uniform deformability of the steel sheet is improved in a case that a relationship among the TS, the fM, the dis, and the dia satisfies a following Expression 1.
TS/fM×dis/dia≧500 (Expression 1)
When the relationship of TS/fM×dis/dia is less than 500, the uniform deformability of the steel sheet may be significantly decreased. A physical meaning of the Expression 1 has not been clear. However, it is considered that the work hardening more effectively occurs as the average distance dis between the martensite grains is decreased and as the average grain size dia of the martensite is increased. Moreover, the relationship of TS/fM×dis/dia does not have particularly an upper limit. However, from an industrial standpoint, since the relationship of TS/fM×dis/dia barely exceeds 10000, the upper limit may be 10000 or less.
Fraction of Martensite having 5.0 or less in Ratio of Major Axis to Minor Axis: 50% or more
In addition, when a major axis of a martensite grain is defined as La in unit of μm and a minor axis of a martensite grain is defined as Lb in unit of μm, the local deformability may be preferably improved in a case that an area fraction of the martensite grain satisfying a following Expression 2 is 50% to 100% as compared with the area fraction fM of the martensite.
La/Lb≦5.0 (Expression 2)
The detail reasons why the effect is obtained has not been clear. However, it is considered that the local deformability is improved due to the fact that the shape of the martensite varies from an acicular shape to a spherical shape and that excessive stress concentration to the ferrite or the bainite near the martensite is relieved. Preferably, the area fraction of the martensite grain having La/Lb of 3.0 or less may be 50% or more as compared with the fM. More preferably, the area fraction of the martensite grain having La/Lb of 2.0 or less may be 50% or more as compared with the fM. Moreover, when the fraction of equiaxial martensite is less than 50% as compared with the fM, the local deformability may deteriorate. Moreover, a lower limit of the Expression 2 may be 1.0.
Moreover, all or part of the martensite may be a tempered martensite. When the martensite is the tempered martensite, although the strength of the steel sheet is decreased, the hole expansibility of the steel sheet is improved by a decrease in the hardness difference between the primary phase and the secondary phase. In accordance with the balance between the required strength and the required deformability, the area fraction of the tempered martensite may be controlled as compared with the area fraction fM of the martensite.
The metallographic structure such as the ferrite, the bainite, or the martensite as described above can be observed by a Field Emission Scanning Electron Microscope (FE-SEM) in a thickness range of ⅛ to ⅜ (a thickness range in which ¼ position of the thickness is the center). The above characteristic values can be determined from micrographs which are obtained by the observation. In addition, the characteristic values can be also determined by the EBSD as described below. For the observation of the FE-SEM, samples are collected so that an observed section is the thickness-cross-section (the normal vector thereof corresponds to the normal direction) which is parallel to the rolling direction of the steel sheet, and the observed section is polished and initial-etched. Moreover, in the thickness direction, the metallographic structure (constituent) of the steel sheet may be significantly different between the vicinity of the surface of the steel sheet and the vicinity of the center of the steel sheet because of decarburization and Mn segregation. Accordingly, in the embodiment, the metallographic structure based on ¼ position of the thickness is observed.
Volume Average Diameter of Grains: 5 μm to 30 μm
Moreover, in order to further improve the deformability, size of the grains in the metallographic structure, particularly, the volume average diameter may be refined. Moreover, fatigue properties (fatigue limit ratio) required for an automobile steel sheet or the like are also improved by refining the volume average diameter. Since the number of coarse grains significantly influences the deformability as compared with the number of fine grains, the deformability significantly correlates with the volume average diameter calculated by the weighted average of the volume as compared with a number average diameter. Accordingly, in order to obtain the above effects, the volume average diameter may be 5 μm to 30 μm, may be more preferably 5 μm to 20 μm, and may be furthermore preferably 5 μm to 10 μm.
Moreover, it is considered that, when the volume average diameter is decreased, local strain concentration occurred in micro-order is suppressed, the strain can be dispersed during local deformation, and the elongation, particularly, the uniform elongation is improved. In addition, when the volume average diameter is decreased, a grain boundary which acts as a barrier of dislocation motion may be appropriately controlled, the grain boundary may affect repetitive plastic deformation (fatigue phenomenon) derived from the dislocation motion, and thus, the fatigue properties may be improved.
Moreover, as described below, the diameter of each grain (grain unit) can be determined. The pearlite is identified through a metallographic observation by an optical microscope. In addition, the grain units of the ferrite, the austenite, the bainite, and the martensite are identified by the EBSD. If crystal structure of an area measured by the EBSD is a face centered cubic structure (fcc structure), the area is regarded as the austenite. Moreover, if crystal structure of an area measured by the EBSD is the body centered cubic structure (bcc structure), the area is regarded as the any one of the ferrite, the bainite, and the martensite. The ferrite, the bainite, and the martensite can be identified by using a Kernel Average Misorientation (KAM) method which is added in an Electron Back Scatter Diffraction Pattern-Orientation Image Microscopy (EBSP-OIM, Registered Trademark). In the KAM method, with respect to a first approximation (total 7 pixels) using a regular hexagonal pixel (central pixel) in measurement data and 6 pixels adjacent to the central pixel, a second approximation (total 19 pixels) using 12 pixels further outside the above 6 pixels, or a third approximation (total 37 pixels) using 18 pixels further outside the above 12 pixels, an misorientation between each pixel is averaged, the obtained average is regarded as the value of the central pixel, and the above operation is performed on all pixels. The calculation by the KAM method is performed so as not to exceed the grain boundary, and a map representing intragranular crystal rotation can be obtained. The map shows strain distribution based on the intragranular local crystal rotation.
In the embodiment, the misorientation between adjacent pixels is calculated by using the third approximation in the EBSP-OIM (registered trademark). For example, the above-described orientation measurement is conducted by a measurement step of 0.5 μm or less at a magnification of 1500-fold, a position in which the misorientation between the adjacent measurement points is more than 15° is regarded as a grain border (the grain border is not always a general grain boundary), the circle equivalent diameter is calculated, and thus, the grain sizes of the ferrite, the bainite, the martensite, and the austenite are obtained. When the pearlite is included in the metallographic structure, the grain size of the pearlite can be calculated by applying an image processing method such as binarization processing or an intercept method to the micrograph obtained by the optical microscope.
In the grain (grain unit) defined as described above, when a circle equivalent radius (a half value of the circle equivalent diameter) is defined as r, the volume of each grain is obtained by 4×π×r3/3, and the volume average diameter can be obtained by the weighted average of the volume. In addition, an area fraction of coarse grains described below can be obtained by dividing area of the coarse grains obtained using the method by measured area. Moreover, except for the volume average diameter, the circle equivalent diameter or the grain size obtained by the binarization processing, the intercept method, or the like is used, for example, as the average grain size dia of the martensite.
The average distance dis between the martensite grains may be determined by using the border between the martensite grain and the grain other than the martensite obtained by the EBSD method (however, FE-SEM in which the EBSD can be conducted) in addition to the FE-SEM observation method.
Area fraction of Coarse Grains having Grain Size of more than 35 μm: 0% to 10%
In addition, in order to further improve the local deformability, with respect to all constituents of the metallographic structure, the area fraction (the area fraction of the coarse grains) which is occupied by grains (coarse grains) having the grain size of more than 35 μm occupy per unit area may be limited to be 0% to 10%. When the grains having a large size are increased, the tensile strength may be decreased, and the local deformability may be also decreased. Accordingly, it is preferable to refine the grains. Moreover, since the local deformability is improved by straining all grains uniformly and equivalently, the local strain of the grains may be suppressed by limiting the fraction of the coarse grains.
Standard Deviation of Average Distance dis between Martensite Grains: 5 μm or less
Moreover, in order to further improve the local deformability such as the bendability, the stretch flangeability, the burring formability, or the hole expansibility, it is preferable that the martensite which is the hard phase is dispersed in the metallographic structure. Therefore, it is preferable that the standard deviation of the average distance dis between the martensite grains is 0 μm to 5 μm. In the case, the average distance dis and the standard deviation thereof may be obtained by measuring the distance between the martensite grains at 100 points or more.
Hardness H of Ferrite: it is preferable to satisfy a following Expression 3
The ferrite which is the primary phase and the soft phase contributes to the improvement in the deformability of the steel sheet. Accordingly, it is preferable that the average hardness H of the ferrite satisfies the following Expression 3. When a ferrite which is harder than the following Expression 3 is contained, the improvement effects of the deformability of the steel sheet may not be obtained. Moreover, the average hardness H of the ferrite is obtained by measuring the hardness of the ferrite at 100 points or more under a load of 1 mN in a nano-indenter.
H<200+30×[Si]+21×[Mn]+270×[P]+78×[Nb]1/2+108×[Ti]1/2 (Expression 3)
Here, [Si], [Mn], [P], [Nb], and [Ti] represent mass percentages of Si, Mn, P, Nb, and Ti respectively.
Standard Deviation/Average of Hardness of Ferrite or Bainite: 0.2 or less
As a result of investigation which is focused on the homogeneity of the ferrite or bainite which is the primary phase by the inventors, it is found that, when the homogeneity of the primary phase is high in the microstructure, the balance between the uniform deformability and the local deformability may be preferably improved. Specifically, when a value, in which the standard deviation of the hardness of the ferrite is divided by the average of the hardness of the ferrite, is 0.2 or less, the effects may be preferably obtained. Moreover, when a value, in which the standard deviation of the hardness of the bainite is divided by the average of the hardness of the bainite, is 0.2 or less, the effects may be preferably obtained. The homogeneity can be obtained by measuring the hardness of the ferrite or the bainite which is the primary phase at 100 points or more under the load of 1 mN in the nano-indenter and by using the obtained average and the obtained standard deviation. Specifically, the homogeneity increases with a decrease in the value of the standard deviation of the hardness/the average of the hardness, and the effects may be obtained when the value is 0.2 or less. In the nano-indenter (for example, UMIS-2000 manufactured by CHEW corporation), by using a smaller indenter than the grain size, the hardness of a single grain which does not include the grain boundary can be measured.
Next, a chemical composition of the hot-rolled steel sheet according to the embodiment will be described.
Hereinafter, description will be given of the base elements of the hot rolled steel sheet according to the embodiment and of the limitation range and reasons for the limitation. Moreover, the % in the description represents mass %.
C: 0.01% to 0.4%
C (carbon) is an element which increases the strength of the steel sheet, and is an essential element to obtain the area fraction of the martensite. A lower limit of C content is to be 0.01% in order to obtain the martensite of 1% or more, by area %. On the other hand, when the C content is more than 0.40%, the deformability of the steel sheet is decreased, and weldability of the steel sheet also deteriorates. Preferably, the C content may be 0.30% or less.
Si: 0.001% to 2.5%
Si (silicon) is a deoxidizing element of the steel and is an element which is effective in an increase in the mechanical strength of the steel sheet. Moreover, Si is an element which stabilizes the ferrite during the temperature control after the hot-rolling and suppresses cementite precipitation during the bainitic transformation. However, when Si content is more than 2.5%, the deformability of the steel sheet is decreased, and surface dents tend to be made on the steel sheet. On the other hand, when the Si content is less than 0.001%, it is difficult to obtain the effects.
Mn: 0.001% to 4.0%
Mn (manganese) is an element which is effective in an increase in the mechanical strength of the steel sheet. However, when Mn content is more than 4.0%, the deformability of the steel sheet is decreased. Preferably, the Mn content may be 3.5% or less. More preferably, the Mn content may be 3.0% or less. On the other hand, when the Mn content is less than 0.001%, it is difficult to obtain the effects. In addition, Mn is also an element which suppresses cracks during the hot-rolling by fixing S (sulfur) in the steel. When elements such as Ti which suppresses occurrence of cracks due to S during the hot-rolling are not sufficiently added except for Mn, it is preferable that the Mn content and the S content satisfy Mn/S≧20 by mass %.
Al: 0.001% to 2.0%
Al (aluminum) is a deoxidizing element of the steel. Moreover, Al is an element which stabilizes the ferrite during the temperature control after the hot-rolling and suppresses the cementite precipitation during the bainitic transformation. In order to obtain the effects, Al content is to be 0.001% or more. However, when the Al content is more than 2.0%, the weldability deteriorates. In addition, although it is difficult to quantitatively show the effects, Al is an element which significantly increases a temperature Ar3 at which transformation starts from γ (austenite) to α (ferrite) at the cooling of the steel. Accordingly, Ar3 of the steel may be controlled by the Al content.
The hot-rolled steel sheet according to the embodiment includes unavoidable impurities in addition to the above described base elements. Here, the unavoidable impurities indicate elements such as P, S, N, O, Cd, Zn, or Sb which are unavoidably mixed from auxiliary raw materials such as scrap or from production processes. In the elements, P, S, N, and O are limited to the following in order to preferably obtain the effects. It is preferable that the unavoidable impurities other than P, S, N, and O are individually limited to 0.02% or less. Moreover, even when the impurities of 0.02% or less are included, the effects are not affected. The limitation range of the impurities includes 0%, however, it is industrially difficult to be stably 0%. Here, the described % is mass %.
P: 0.15% or less
P (phosphorus) is an impurity, and an element which contributes to crack during the hot-rolling or the cold-rolling when the content in the steel is excessive. In addition, P is an element which deteriorates the ductility or the weldability of the steel sheet. Accordingly, the P content is limited to 0.15% or less. Preferably, the P content may be limited to 0.05% or less. Moreover, since P acts as a solid solution strengthening element and is unavoidably included in the steel, it is not particularly necessary to prescribe a lower limit of the P content. The lower limit of the P content may be 0%. Moreover, considering current general refining (includes secondary refining), the lower limit of the P content may be 0.0005%.
S: 0.03% or Less
S (sulfur) is an impurity, and an element which deteriorates the deformability of the steel sheet by forming MnS stretched by the hot-rolling when the content in the steel is excessive. Accordingly, the S content is limited to 0.03% or less. Moreover, since S is unavoidably included in the steel, it is not particularly necessary to prescribe a lower limit of the S content. The lower limit of the S content may be 0%. Moreover, considering the current general refining (includes the secondary refining), the lower limit of the S content may be 0.0005%.
N: 0.01% or less
N (nitrogen) is an impurity, and an element which deteriorates the deformability of the steel sheet. Accordingly, the N content is limited to 0.01% or less. Moreover, since N is unavoidably included in the steel, it is not particularly necessary to prescribe a lower limit of the N content. The lower limit of the N content may be 0%. Moreover, considering the current general refining (includes the secondary refining), the lower limit of the N content may be 0.0005%.
O: 0.01% or less
O (oxygen) is an impurity, and an element which deteriorates the deformability of the steel sheet. Accordingly, the O content is limited to 0.01% or less. Moreover, since O is unavoidably included in the steel, it is not particularly necessary to prescribe a lower limit of the O content. The lower limit of the O content may be 0%. Moreover, considering the current general refining (includes the secondary refining), the lower limit of the O content may be 0.0005%.
The above chemical elements are base components (base elements) of the steel in the embodiment, and the chemical composition, in which the base elements are controlled (included or limited) and the balance consists of Fe and unavoidable impurities, is a base composition of the embodiment. However, in addition to the base elements (instead of a part of Fe which is the balance), in the embodiment, the following chemical elements (optional elements) may be additionally included in the steel as necessary. Moreover, even when the optional elements are unavoidably included in the steel (for example, amount less than a lower limit of each optional element), the effects in the embodiment are not decreased.
Specifically, the hot-rolled steel sheet according to the embodiment may further include, as a optional element, at least one selected from a group consisting of Mo, Cr, Ni, Cu, B, Nb, Ti, V, W, Ca, Mg, Zr, REM, As, Co, Sn, Pb, Y, and Hf in addition to the base elements and the impurity elements. Hereinafter, numerical limitation ranges and the limitation reasons of the optional elements will be described. Here, the described % is mass %.
Ti: 0.001% to 0.2%
Nb: 0.001% to 0.2%
B: 0.001% to 0.005%
Ti (titanium), Nb (niobium), and B (boron) are the optional elements which form fine carbon-nitrides by fixing the carbon and the nitrogen in the steel, and which have the effects such as precipitation strengthening, microstructure control, or grain refinement strengthening for the steel. Accordingly, as necessary, at least one of Ti, Nb, and B may be added to the steel. In order to obtain the effects, preferably, Ti content may be 0.001% or more, Nb content may be 0.001% or more, and B content may be 0.0001% or more. However, when the optional elements are excessively added to the steel, the effects may be saturated, the control of the crystal orientation may be difficult because of suppression of recrystallization after the hot-rolling, and the workability (deformability) of the steel sheet may deteriorate. Accordingly, preferably, the Ti content may be 0.2% or less, the Nb content may be 0.2% or less, and the B content may be 0.005% or less. Moreover, even when the optional elements having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. Moreover, since it is not necessary to add the optional elements to the steel intentionally in order to reduce costs of alloy, lower limits of amounts of the optional elements may be 0%.
Mg: 0.0001% to 0.01%
REM: 0.0001% to 0.1%
Ca: 0.0001% to 0.01%
Ma (magnesium), REM (Rare Earth Metal), and Ca (calcium) are the optional elements which are important to control inclusions to be harmless shapes and to improve the local deformability of the steel sheet. Accordingly, as necessary, at least one of Mg, REM, and Ca may be added to the steel. In order to obtain the effects, preferably, Mg content may be 0.0001% or more, REM content may be 0.0001% or more, and Ca content may be 0.0001% or more. On the other hand, when the optional elements are excessively added to the steel, inclusions having stretched shapes may be formed, and the deformability of the steel sheet may be decreased. Accordingly, preferably, the Mg content may be 0.01% or less, the REM content may be 0.1% or less, and the Ca content may be 0.01% or less. Moreover, even when the optional elements having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. Moreover, since it is not necessary to add the optional elements to the steel intentionally in order to reduce costs of alloy, lower limits of amounts of the optional elements may be 0%.
In addition, here, the REM represents collectively a total of 16 elements which are 15 elements from lanthanum with atomic number 57 to lutetium with atomic number 71 in addition to scandium with atomic number 21. In general, REM is supplied in the state of misch metal which is a mixture of the elements, and is added to the steel.
Mo: 0.001% to 1.0%
Cr: 0.001% to 2.0%
Ni: 0.001% to 2.0%
W: 0.001% to 1.0%
Zr: 0.0001% to 0.2%.
As: 0.0001% to 0.5%
Mo (molybdenum), Cr (chromium), Ni (nickel), W (tungsten), Zr (zirconium), and As (arsenic) are the optional elements which increase the mechanical strength of the steel sheet. Accordingly, as necessary, at least one of Mo, Cr, Ni, W, Zr, and As may be added to the steel. In order to obtain the effects, preferably, Mo content may be 0.001% or more, Cr content may be 0.001% or more, Ni content may be 0.001% or more, W content may be 0.001% or more, Zr content may be 0.0001% or more, and As content may be 0.0001% or more. However, when the optional elements are excessively added to the steel, the deformability of the steel sheet may be decreased. Accordingly, preferably, the Mo content may be 1.0% or less, the Cr content may be 2.0% or less, the Ni content may be 2.0% or less, the W content may be 1.0% or less, the Zr content may be 0.2% or less, and the As content may be 0.5% or less. Moreover, even when the optional elements having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. Moreover, since it is not necessary to add the optional elements to the steel intentionally in order to reduce costs of alloy, lower limits of amounts of the optional elements may be 0%.
V: 0.001% 1.0%
Cu: 0.001% to 2.0%
V (vanadium) and Cu (copper) are the optional elements which is similar to Nb, Ti, or the like and which have the effect of the precipitation strengthening. In addition, a decrease in the local deformability due to addition of V and Cu is small as compared with that of addition of Nb, Ti, or the like. Accordingly, in order to obtain the high-strength and to further increase the local deformability such as the hole expansibility or the bendability, V and Cu are more effective optional elements than Nb, Ti, or the like. Therefore, as necessary, at least one of V and Cu may be added to the steel. In order to obtain the effects, preferably, V content may be 0.001% or more and Cu content may be 0.001% or more. However, the optional elements are excessively added to the steel, the deformability of the steel sheet may be decreased. Accordingly, preferably, the V content may be 1.0% or less and the Cu content may be 2.0% or less. Moreover, even when the optional elements having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. In addition, since it is not necessary to add the optional elements to the steel intentionally in order to reduce costs of alloy, lower limits of amounts of the optional elements may be 0%.
Co: 0.0001% to 1.0%
Although it is difficult to quantitatively show the effects, Co (cobalt) is the optional element which significantly increases the temperature Ar3 at which the transformation starts from γ (austenite) to α (ferrite) at the cooling of the steel. Accordingly, Ar3 of the steel may be controlled by the Co content. In addition, Co is the optional element which improves the strength of the steel sheet. In order to obtain the effect, preferably, the Co content may be 0.0001% or more. However, when Co is excessively added to the steel, the weldability of the steel sheet may deteriorate, and the deformability of the steel sheet may be decreased. Accordingly, preferably, the Co content may be 1.0% or less. Moreover, even when the optional element having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. In addition, since it is not necessary to add the optional element to the steel intentionally in order to reduce costs of alloy, a lower limit of an amount of the optional element may be 0%.
Sn: 0.0001% to 0.2%
Pb: 0.0001% to 0.2%
Sn (tin) and Pb (lead) are the optional elements which are effective in an improvement of coating wettability and coating adhesion. Accordingly, as necessary, at least one of Sn and Pb may be added to the steel. In order to obtain the effects, preferably, Sn content may be 0.0001% or more and Pb content may be 0.0001% or more. However, when the optional elements are excessively added to the steel, the cracks may occur during the hot working due to high-temperature embrittlement, and surface dents tend to be made on the steel sheet. Accordingly, preferably, the Sn content may be 0.2% or less and the Pb content may be 0.2% or less. Moreover, even when the optional elements having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. In addition, since it is not necessary to add the optional elements to the steel intentionally in order to reduce costs of alloy, lower limits of amounts of the optional elements may be 0%.
Y: 0.0001% to 0.2%
Hf: 0.0001% to 0.2%
Y (yttrium) and Hf (hafnium) are the optional elements which are effective in an improvement of corrosion resistance of the steel sheet. Accordingly, as necessary, at least one of Y and Hf may be added to the steel. In order to obtain the effect, preferably, Y content may be 0.0001% or more and Hf content may be 0.0001% or more. However, when the optional elements are excessively added to the steel, the local deformability such as the hole expansibility may be decreased. Accordingly, preferably, the Y content may be 0.20% or less and the Hf content may be 0.20% or less. Moreover, Y has the effect which forms oxides in the steel and which adsorbs hydrogen in the steel. Accordingly, diffusible hydrogen in the steel is decreased, and an improvement in hydrogen embrittlement resistance properties in the steel sheet can be expected. The effect can be also obtained within the above-described range of the Y content. Moreover, even when the optional elements having the amount less than the lower limit are included in the steel, the effects in the embodiment are not decreased. In addition, since it is not necessary to add the optional elements to the steel intentionally in order to reduce costs of alloy, lower limits of amounts of the optional elements may be 0%.
As described above, the hot-rolled steel sheet according to the embodiment has the chemical composition which includes the above-described base elements and the balance consisting of Fe and unavoidable impurities, or has the chemical composition which includes the above-described base elements, at least one selected from the group consisting of the above-described optional elements, and the balance consisting of Fe and unavoidable impurities.
Moreover, surface treatment may be conducted on the hot-rolled steel sheet according to the embodiment. For example, the surface treatment such as electro coating, hot dip coating, evaporation coating, alloying treatment after coating, organic film formation, film laminating, organic salt and inorganic salt treatment, or non-chrome treatment (non-chromate treatment) may be applied, and thus, the hot-rolled steel sheet may include various kinds of the film (film or coating). For example, a galvanized layer or a galvanized layer may be arranged on the surface of the hot-rolled steel sheet. Even if the hot-rolled steel sheet includes the above-described coating, the steel sheet can obtain the high-strength and can sufficiently secure the uniform deformability and the local deformability.
Moreover, in the embodiment, a thickness of the hot-rolled steel sheet is not particularly limited. However, for example, the thickness may be 1.5 mm to 10 mm, and may be 2.0 mm to 10 mm. Moreover, the strength of the hot-rolled steel sheet is not particularly limited, and for example, the tensile strength may be 440 MPa to 1500 MPa.
The hot-rolled steel sheet according to the embodiment can be applied to general use for the high-strength steel sheet, and has the excellent uniform deformability and the remarkably improved local deformability such as the bending workability or the hole expansibility of the high-strength steel sheet.
In addition, since the directions in which the bending for the hot-rolled steel sheet is conducted differ in the parts which are bent, the direction is not particularly limited. In the hot-rolled steel sheet according to the embodiment, the similar properties can be obtained in any bending direction, and the hot-rolled steel sheet can be subjected to the composite forming including working modes such as bending, stretching, or drawing.
Next, a method for producing the hot-rolled steel sheet according to an embodiment of the present invention will be described. In order to produce the hot-rolled steel sheet which has the high-strength, the excellent uniform deformability, and the excellent local deformability, it is important to control the chemical composition of the steel, the metallographic structure, and the texture which is represented by the pole densities of each orientation of a specific crystal orientation group. The details will be described below.
The production process prior to the hot-rolling is not particularly limited. For example, the steel (molten steel) may be obtained by conducting a smelting and a refining using a blast furnace, an electric furnace, a converter, or the like, and subsequently, by conducting various kinds of secondary refining, in order to melt the steel satisfying the chemical composition. Thereafter, in order to obtain a steel piece or a slab from the steel, for example, the steel can be cast by a casting process such as a continuous casting process, an ingot making process, or a thin slab casting process in general. In the case of the continuous casting, the steel may be subjected to the hot-rolling after the steel is cooled once to a lower temperature (for example, room temperature) and is reheated, or the steel (cast slab) may be continuously subjected to the hot-rolling just after the steel is cast. In addition, scrap may be used for a raw material of the steel (molten steel).
In order to obtain the high-strength steel sheet which has the high-strength, the excellent uniform deformability, and the excellent local deformability, the following conditions may be satisfied. Moreover, hereinafter, the “steel” and the “steel sheet” are synonymous.
First-Hot-Rolling Process
In the first-hot-rolling process, using the molten and cast steel piece, a rolling pass whose reduction is 40% or more is conducted at least once in a temperature range of 1000° C. to 1200° C. (preferably, 1150° C. or lower). By conducting the first-hot-rolling under the conditions, the average grain size of the austenite of the steel sheet after the first-hot-rolling process is controlled to 200 μm or less, which contributes to the improvement in the uniform deformability and the local deformability of the finally obtained hot-rolled steel sheet.
The austenite grains are refined with an increase in the reduction and an increase in the frequency of the rolling. For example, in the first-hot-rolling process, by conducting at least two times (two passes) of the rolling whose reduction is 40% or more per one pass, the average grain size of the austenite may be preferably controlled to 100 μm or less. In addition, in the first-hot-rolling, by limiting the reduction to 70% or less per one pass, or by limiting the frequency of the rolling (the number of times of passes) to 10 times or less, a temperature fall of the steel sheet or excessive formation of scales may can be decreased. Accordingly, in the rough rolling, the reduction per one pass may be 70% or less, and the frequency of the rolling (the number of times of passes) may be 10 times or less.
As described above, by refining the austenite grains after the first-hot-rolling process, it is preferable that the austenite grains can be further refined by the post processes, and the ferrite, the bainite, and the martensite transformed from the austenite at the post processes may be finely and uniformly dispersed. As a result, the anisotropy and the local deformability of the steel sheet are improved due to the fact that the texture is controlled, and the uniform deformability and the local deformability (particularly, uniform deformability) of the steel sheet are improved due to the fact that the metallographic structure is refined. Moreover, it seems that the grain boundary of the austenite refined by the first-hot-rolling process acts as one of recrystallization nuclei during a second-hot-rolling process which is the post process.
In order to inspect the average grain size of the austenite after the first-hot-rolling process, it is preferable that the steel sheet after the first-hot-rolling process is rapidly cooled at a cooling rate as fast as possible. For example, the steel sheet is cooled under the average cooling rate of 10° C./second or faster. Subsequently, the cross-section of the sheet piece which is taken from the steel sheet obtained by the cooling is etched in order to make the austenite grain boundary visible, and the austenite grain boundary in the microstructure is observed by an optical microscope. At the time, visual fields of 20 or more are observed at a magnification of 50-fold or more, the grain size of the austenite is measured by the image analysis or the intercept method, and the average grain size of the austenite is obtained by averaging the austenite grain sizes measured at each of the visual fields.
After the first-hot-rolling process, sheet bars may be joined, and the second-hot-rolling process which is the post process may be continuously conducted. At the time, the sheet bars may be joined after a rough bar is temporarily coiled in a coil shape, stored in a cover having a heater as necessary, and recoiled again.
Second-Hot-Rolling Process
In the second-hot-rolling process, when a temperature calculated by a following Expression 4 is defined as T1 in unit of ° C., the steel sheet after the first-hot-rolling process is subjected to a rolling under conditions such that, a large reduction pass whose reduction is 30% or more in a temperature range of T1+30° C. to T1+200° C. is included, a cumulative reduction in the temperature range of T1+30° C. to T1+200° C. is 50% or more, a cumulative reduction in a temperature range of Ar3° C. to lower than T1+30° C. is limited to 30% or less, and a rolling finish temperature is Ar3° C. or higher.
As one of the conditions in order to control the average pole density D1 of the orientation group of {100}<011> to {223}<110> and the pole density D2 of the crystal orientation {332}<113> in the thickness central portion which is the thickness range of ⅝ to ⅜ to the above-described ranges, in the second-hot-rolling process, the rolling is controlled based on the temperature T1 (unit: ° C.) which is determined by the following Expression 4 using the chemical composition (unit: mass %) of the steel.
T1=850+10×([C]+[N])×[Mn]+350×[Nb]+250×[Ti]+40×[B]+10×[Cr]+100×[Mo]+100×[V] (Expression 4)
In Expression 4, [C], [N], [Mn], [Nb], [Ti], [B], [Cr], [Mo], and [V] represent mass percentages of C, N, Mn, Nb, Ti, B, Cr, Mo, and V respectively.
The amount of the chemical element, which is included in Expression 4 but is not included in the steel, is regarded as 0% for the calculation. Accordingly, in the case of the chemical composition in which the steel includes only the base elements, a following Expression 5 may be used instead of the Expression 4.
T1=850+10×([C]+[N])×[Mn] (Expression 5)
In addition, in the chemical composition in which the steel includes the optional elements, the temperature calculated by Expression 4 may be used for T1 (unit: ° C.), instead of the temperature calculated by Expression 5.
In the second-hot-rolling process, on the basis of the temperature T1 (unit: ° C.) obtained by the Expression 4 or 5, the large reduction is included in the temperature range of T1+30° C. to T1+200° C. (preferably, in a temperature range of T1+50° C. to T1+100° C.), and the reduction is limited to a small range (includes 0%) in the temperature range of Ar3° C. to lower than T1+30° C. By conducting the second-hot-rolling process in addition to the first-hot-rolling process, the uniform deformability and the local deformability of the steel sheet is preferably improved. Particularly, by including the large reduction in the temperature range of T1+30° C. to T1+200° C. and by limiting the reduction in the temperature range of Ar3° C. to lower than T1+30° C., the average pole density D1 of the orientation group of {100}<011> to {223}<110> and the pole density D2 of the crystal orientation {332}<113> in the thickness central portion which is the thickness range of ⅝ to ⅜ are sufficiently controlled, and as a result, the anisotropy and the local deformability of the steel sheet are remarkably improved.
The temperature T1 itself is empirically obtained. It is empirically found by the inventors through experiments that the temperature range in which the recrystallization in the austenite range of each steels is promoted can be determined based on the temperature T1. In order to obtain the excellent uniform deformability and the excellent local deformability, it is important to accumulate a large amount of the strain by the rolling and to obtain the fine recrystallized grains. Accordingly, the rolling having plural passes is conducted in the temperature range of T1+30° C. to T1+200° C., and the cumulative reduction is to be 50% or more. Moreover, in order to further promote the recrystallization by the strain accumulation, it is preferable that the cumulative reduction is 70% or more. Moreover, by limiting an upper limit of the cumulative reduction, a rolling temperature can be sufficiently held, and a rolling load can be further suppressed. Accordingly, the cumulative reduction may be 90% or less.
When the rolling having the plural passes is conducted in the temperature range of T1+30° C. to T1+200° C., the strain is accumulated by the rolling, and the recrystallization of the austenite is occurred at an interval between the rolling passes by a driving force derived from the accumulated strain. Specifically, by conducting the rolling having the plural passes in the temperature range of T1+30° C. to T1+200° C., the recrystallization is repeatedly occurred every pass. Accordingly, it is possible to obtain the recrystallized austenite structure which is uniform, fine, and equiaxial. In the temperature range, dynamic recrystallization is not occurred during the rolling, the strain is accumulated in the crystal, and static recrystallization is occurred at the interval between the rolling passes by the driving force derived from the accumulated strain. In general, in dynamic-recrystallized structure, the strain which introduced during the working is accumulated in the crystal thereof, and a recrystallized area and a non-crystallized area are locally mixed. Accordingly, the texture is comparatively developed, and thus, the anisotropy appears. Moreover, the metallographic structures may be a duplex grain structure. In the method for producing the hot-rolled steel sheet according to the embodiment, the austenite is recrystallized by the static recrystallization. Accordingly, it is possible to obtain the recrystallized austenite structure which is uniform, fine, and equiaxial, and in which the development of the texture is suppressed.
In order to increase the homogeneity, and to preferably increase the uniform deformability and the local deformability of the steel sheet, the second-hot-rolling is controlled so as to include at least one large reduction pass whose reduction per one pass is 30% or more in the temperature range of T1+30° C. to T1+200° C. In the second-hot-rolling, in the temperature range of T1+30° C. to T1+200° C., the rolling whose reduction per one pass is 30% or more is conducted at least once. Particularly, considering a cooling process as described below, the reduction of a final pass in the temperature range may be preferably 25% or more, and may be more preferably 30% or more. Specifically, it is preferable that the final pass in the temperature range is the large reduction pass (the rolling pass with the reduction of 30% or more). In a case that the further excellent deformability is required in the steel sheet, it is further preferable that all reduction of first half passes are less than 30% and the reductions of the final two passes are individually 30% or more. In order to more preferably increase the homogeneity of the steel sheet, a large reduction pass whose reduction per one pass is 40% or more may be conducted. Moreover, in order to obtain a more excellent shape of the steel sheet, a large reduction pass whose reduction per one pass is 70% or less may be conducted.
Moreover, in the rolling in the temperature range of T1+30° C. to T1+200° C., by suppressing a temperature rise of the steel sheet between passes of the rolling to 18° C. or lower, it is possible to preferably obtain the recrystallized austenite which is more uniform.
In order to suppress the development of the texture and to keep the equiaxial recrystallized structure, after the rolling in the temperature range of T1+30° C. to T1+200° C., an amount of working in the temperature range of Ar3° C. to lower than T1+30° C. (preferably, T1 to lower than T1+30° C.) is suppressed as small as possible. Accordingly, the cumulative reduction in the temperature range of Ar3° C. to lower than T1+30° C. is limited to 30% or less. In the temperature range, it is preferable that the cumulative reduction is 10% or more in order to obtain the excellent shape of the steel sheet, and it is preferable that the cumulative reduction is 10% or less in order to further improve the anisotropy and the local deformability. In the case, the cumulative reduction may be more preferably 0%. Specifically, in the temperature range of Ar3° C. to lower than T1+30° C., the rolling may not be conducted, and the cumulative reduction is to be 30% or less even when the rolling is conducted.
When the cumulative reduction in the temperature range of Ar3° C. to lower than T1+30° C. is large, the shape of the austenite grain recrystallized in the temperature range of T1+30° C. to T1+200° C. is not to be equiaxial due to the fact that the grain is stretched by the rolling, and the texture is developed again due to the fact that the strain is accumulated by the rolling. Specifically, as the production conditions according to the embodiment, the rolling is controlled at both of the temperature range of T1+30° C. to T1+200° C. and the temperature range of Ar3° C. to lower than T1+30° C. in the second-hot-rolling process. As a result, the austenite is recrystallized so as to be uniform, fine, and equiaxial, the texture, the metallographic structure, and the anisotropy of the steel sheet are controlled, and therefore, the uniform deformability and the local deformability can be improved. In addition, the austenite is recrystallized so as to be uniform, fine, and equiaxial, and therefore, the ratio of major axis to minor axis of the martensite, the average size of the martensite, the average distance between the martensite, and the like of the finally obtained hot-rolled steel sheet can be controlled.
In the second-hot-rolling process, when the rolling is conducted in the temperature range lower than Ar3° C. or the cumulative reduction in the temperature range of Ar3° C. to lower than T1+30° C. is excessive large, the texture of the austenite is developed. As a result, the finally obtained hot-rolled steel sheet does not satisfy at least one of the condition in which the average pole density D1 of the orientation group of {100}<011> to {223}<110> is 1.0 to 5.0 and the condition in which the pole density D2 of the crystal orientation {332}<113> is 1.0 to 4.0 in the thickness central portion. On the other hand, in the second-hot-rolling process, when the rolling is conducted in the temperature range higher than T1+200° C. or the cumulative reduction in the temperature range of T1+30° C. to T1+200° C. is excessive small, the recrystallization is not uniformly and finely occurred, coarse grains or mixed grains may be included in the metallographic structure, and the metallographic structure may be the duplex grain structure. Accordingly, the area fraction or the volume average diameter of the grains which is more than 35 μm is increased.
Moreover, when the second-hot-rolling is finished at a temperature lower than Ar3 (unit: ° C.), the steel is rolled in a temperature range of the rolling finish temperature to lower than Ar3 (unit: ° C.) which is a range where two phases of the austenite and the ferrite exist (two-phase temperature range). Accordingly, the texture of the steel sheet is developed, and the anisotropy and the local deformability of the steel sheet significantly deteriorate. Here, when the rolling finish temperature of the second-hot-rolling is T1 or more, the anisotropy may be further decreased by decreasing an amount of the strain in the temperature range lower than T1, and as a result, the local deformability may be further increased. Therefore, the rolling finish temperature of the second-hot-rolling may be T1 or more.
Here, the reduction can be obtained by measurements or calculations from a rolling force, a thickness, or the like. Moreover, the rolling temperature (for example, the above each temperature range) can be obtained by measurements using a thermometer between stands, by calculations using a simulation in consideration of deformation heating, line speed, the reduction, or the like, or by both (measurements and calculations). Moreover, the above reduction per one pass is a percentage of a reduced thickness per one pass (a difference between an inlet thickness before passing a rolling stand and an outlet thickness after passing the rolling stand) to the inlet thickness before passing the rolling stand. The cumulative reduction is a percentage of a cumulatively reduced thickness (a difference between an inlet thickness before a first pass in the rolling in each temperature range and an outlet thickness after a final pass in the rolling in each temperature range) to the reference which is the inlet thickness before the first pass in the rolling in each temperature range. Ar3, which is a ferritic transformation temperature from the austenite during the cooling, is obtained by a following Expression 6 in unit of ° C. Moreover, although it is difficult to quantitatively show the effects as described above, Al and Co also influence Ar3.
Ar3=879.4−516.1×[C]−65.7×[Mn]+38.0×[Si]+274.7×[P] (Expression 6)
In the Expression 6, [C], [Mn], [Si] and [P] represent mass percentages of C, Mn, Si and P respectively.
First-Cooling Process
In the first-cooling process, after a final pass among the large reduction passes whose reduction per one pass is 30% or more in the temperature range of T1+30° C. to T1+200° C. is finished, when a waiting time from the finish of the final pass to a start of the cooling is defined as t in unit of second, the steel sheet is subjected to the cooling so that the waiting time t satisfies a following Expression 7. Here, t1 in the Expression 7 can be obtained from a following Expression 8. In the Expression 8, Tf represents a temperature (unit: ° C.) of the steel sheet at the finish of the final pass among the large reduction passes, and P1 represents a reduction (unit: %) at the final pass among the large reduction passes.
T≦2.5×t1 (Expression 7)
t1=0.001×((Tf−T1)×P1/100)2−0.109×(Tf−T1)×P1/100)+3.1 (Expression 8)
The first-cooling after the final large reduction pass significantly influences the grain size of the finally obtained hot-rolled steel sheet. Moreover, by the first-cooling, the austenite can be controlled to be a metallographic structure in which the grains are equiaxial and the coarse grains rarely are included (namely, uniform sizes). Accordingly, the finally obtained hot-rolled steel sheet has the metallographic structure in which the grains are equiaxial and the coarse grains rarely are included (namely, uniform sizes), and the ratio of the major axis to the minor axis of the martensite, the average size of the martensite, the average distance between the martensite, and the like may be preferably controlled.
The right side value (2.5×t1) of the Expression 7 represents a time at which the recrystallization of the austenite is substantially finished. When the waiting time t is more than the right side value (2.5×t1) of the Expression 7, the recrystallized grains are significantly grown, and the grain size is increased. Accordingly, the strength, the uniform deformability, the local deformability, the fatigue properties, or the like of the steel sheet are decreased. Therefore, the waiting time t is to be 2.5×t1 seconds or less. In a case where runnability (for example, shape straightening or controllability of a second-cooling) is considered, the first-cooling may be conducted between rolling stands. Moreover, a lower limit of the waiting time t is to be 0 seconds or more.
Moreover, when the waiting time t is limited to 0 second to shorter than t1 seconds so that 0≦t<t1 is satisfied, it may be possible to significantly suppress the grain growth. In the case, the volume average diameter of the finally obtained hot-rolled steel sheet may be controlled to 30 μm or less. As a result, even if the recrystallization of the austenite does not sufficiently progress, the properties of the steel sheet, particularly, the uniform deformability, the fatigue properties, or the like may be preferably improved.
Moreover, when the waiting time t is limited to t1 seconds to 2.5×t1 seconds so that t1≦t≦2.5×t1 is satisfied, it may be possible to suppress the development of the texture. In the case, although the volume average diameter may be increased because the waiting time t is prolonged as compared with the case where the waiting time t is shorter than t1 seconds, the crystal orientation may be randomized because the recrystallization of the austenite sufficiently progresses. As a result, the anisotropy, the local deformability, and the like of the steel sheet may be preferably improved.
Moreover, the above-described first-cooling may be conducted at an interval between the rolling stands in the temperature range of T1+30° C. to T1+200° C., or may be conducted after a final rolling stand in the temperature range. Specifically, as long as the waiting time t satisfies the condition, a rolling whose reduction per one pass is 30% or less may be further conducted in the temperature range of T1+30° C. to T1+200° C. and between the finish of the final pass among the large reduction passes and the start of the first-cooling. Moreover, after the first-cooling is conducted, as long as the reduction per one pass is 30% or less, the rolling may be further conducted in the temperature range of T1+30° C. to T1+200° C. Similarly, after the first-cooling is conducted, as long as the cumulative reduction is 30% or less, the rolling may be further conducted in the temperature range of Ar3° C. to T1+30° C. (or Ar3° C. to Tf° C.). As described above, as long as the waiting time t after the large reduction pass satisfies the condition, in order to control the metallographic structure of the finally obtained hot-rolled steel sheet, the above-described first-cooling may be conducted either at the interval between the rolling stands or after the rolling stand.
In the first-cooling, it is preferable that a cooling temperature change which is a difference between a steel sheet temperature (steel temperature) at the cooling start and a steel sheet temperature (steel temperature) at the cooling finish is 40° C. to 140° C. When the cooling temperature change is 40° C. or higher, the growth of the recrystallized austenite grains may be further suppressed. When the cooling temperature change is 140° C. or lower, the recrystallization may more sufficiently progress, and the pole density may be preferably improved. Moreover, by limiting the cooling temperature change to 140° C. or lower, in addition to the comparatively easy control of the temperature of the steel sheet, variant selection (variant limitation) may be more effectively controlled, and the development of the recrystallized texture may be preferably controlled. Accordingly, in the case, the isotropy may be further increased, and the orientation dependence of the formability may be further decreased. When the cooling temperature change is higher than 140° C., the progress of the recrystallization may be insufficient, the intended texture may not be obtained, the ferrite may not be easily obtained, and the hardness of the obtained ferrite is increased. Accordingly, the uniform deformability and the local deformability of the steel sheet may be decreased.
Moreover, it is preferable that the steel sheet temperature T2 at the first-cooling finish is T1+100° C. or lower. When the steel sheet temperature T2 at the first-cooling finish is T1+100° C. or lower, more sufficient cooling effects are obtained. By the cooling effects, the grain growth may be suppressed, and the growth of the austenite grains may be further suppressed.
Moreover, it is preferable that an average cooling rate in the first-cooling is 50° C./second or faster. When the average cooling rate in the first-cooling is 50° C./second or faster, the growth of the recrystallized austenite grains may be further suppressed. On the other hand, it is not particularly necessary to prescribe an upper limit of the average cooling rate. However, from a viewpoint of the sheet shape, the average cooling rate may be 200° C./second or slower.
Second-Cooling Process
In the second-cooling process, the steel sheet after the second-hot-rolling and after the first-cooling process may be preferably cooled to a temperature range of 600° C. to 800° C. under an average cooling rate of 15° C./second to 300° C./second. When a temperature (unit: ° C.) of the steel sheet becomes Ar3 or lower by cooling the steel sheet during the second-cooling process, the martensite starts to be transformed to the ferrite. When the average cooling rate is 15° C./second or faster, grain coarsening of the austenite may be preferably suppressed. It is not particularly necessary to prescribe an upper limit of the average cooling rate. However, from a viewpoint of the sheet shape, the average cooling rate may be 300° C./second or slower. In addition, it is preferable to start the second-cooling within 3 seconds after finishing the second-hot-rolling or after the first-cooling process. When the second-cooling start exceeds 3 seconds, coarsening of the austenite may occur.
Holding Process
In the holding process, the steel sheet after the second-cooling process is held in the temperature range of 600° C. to 800° C. for 1 second to 15 seconds. By holding in the temperature range, the transformation from the austenite to the ferrite progresses, and therefore, the area fraction of the ferrite can be increased. It is preferable that the steel is held in a temperature range of 600° C. to 680° C. By conducting the ferritic transformation in the above comparatively lower temperature range, the ferrite structure may be controlled to be fine and uniform. Accordingly, the bainite and the martensite which are formed in the post process may be controlled to be fine and uniform in the metallographic structure. In addition, in order to accelerate the ferritic transformation, a holding time is to be 1 second or longer. However, when the holding time is longer than 15 seconds, the ferrite grains may be coarsened, and the cementite may precipitate. In a case where the steel is held in the comparatively lower temperature range of 600° C. to 680° C., it is preferable that the holding time is 3 seconds to 15 seconds.
Third-Cooling Process
In the third-cooling process, the steel sheet after the holding process is cooled to a temperature range of a room temperature to 350° C. under an average cooling rate of 50° C./second to 300° C./second. During the third-cooling process, the austenite which is not transformed to the ferrite even after the holding process is transformed to the bainite and the martensite. When the third-cooling process is stopped at a temperature higher than 350° C., the bainitic transformation excessively progresses due to the excessive high temperature, and the martensite of 1% or more in unit of area % cannot be finally obtained. Moreover, it is not particularly necessary to prescribe a lower limit of the cooling stop temperature of the third-cooling process. However, in a case where water cooling is conducted, the lower limit may be the room temperature. In addition, when the average cooling rate is slower than 50° C./second, the pearlitic transformation may occur during the cooling. Moreover, it is not particularly necessary to prescribe an upper limit of the average cooling rate in the third-cooling process. However, from an industrial standpoint, the upper limit may be 300° C./second. By decreasing the average cooling rate within the above-described range of the average cooling rate, the area fraction of the bainite may be increased. On the other hand, by increasing the average cooling rate within the above-described range of the average cooling rate, the area fraction of the martensite may be increased. In addition, the grain sizes of the bainite and the martensite are also refined.
In accordance with properties required for the hot-rolled steel sheet, the area fractions of the ferrite and the bainite which are the primary phase may be controlled, and the area fraction of the martensite which is the second phase may be controlled. As described above, the ferrite can be mainly controlled in the holding process, and the bainite and the martensite can be mainly controlled in the third-cooling process. In addition, the grain sizes or the morphologies of the ferrite and the bainite which are the primary phase and of the martensite which is the secondary phase significantly depend on the grain size or the morphology of the austenite which is the microstructure before the transformation. Moreover, the grain sizes or the morphologies also depend on the holding process and the third-cooling process. Accordingly, for example, the value of TS/fM×dis/dia, which is the relationship of the area fraction fM of the martensite, the average size dia of the martensite, the average distance dis between the martensite, and the tensile strength TS of the steel sheet, may be satisfied by multiply controlling the above-described production processes.
Coiling Process
In the coiling process, the steel sheet after the third-cooling starts to be coiled at a temperature of the room temperature to 350° C. which is the cooling stop temperature of the third-cooling, and the steel sheet is air-cooled. As described above, the hot-rolled steel sheet according to the embodiment can be produced.
Moreover, as necessary, the obtained hot-rolled steel sheet may be subjected to a skin pass rolling. By the skin pass rolling, it may be possible to suppress a stretcher strain which is formed during working of the steel sheet, or to straighten the shape of the steel sheet.
Moreover, the obtained hot-rolled steel sheet may be subjected to a surface treatment. For example, the surface treatment such as the electro coating, the hot dip coating, the evaporation coating, the alloying treatment after the coating, the organic film formation, the film laminating, the organic salt and inorganic salt treatment, or the non-chromate treatment may be applied to the obtained hot-rolled steel sheet. For example, a galvanized layer or a galvanized layer may be arranged on the surface of the hot-rolled steel sheet. Even if the surface treatment is conducted, the uniform deformability and the local deformability are sufficiently maintained.
Moreover, as necessary, a tempering treatment or an ageing treatment may be conducted as a reheating treatment. By the treatment, Nb, Ti, Zr, V, W, Mo, or the like which is solid-soluted in the steel may be precipitated as carbides, and the martensite may be softened as the tempered martensite. As a result, the hardness difference between the ferrite and the bainite which are the primary phase and the martensite which is the secondary phase is decreased, and the local deformability such as the hole expansibility or the bendability is improved. The effects of the reheating treatment may be also obtained by heating for the hot dip coating, the alloying treatment, or the like.
Hereinafter, the technical features of the aspect of the present invention will be described in detail with reference to the following examples. However, the condition in the examples is an example condition employed to confirm the operability and the effects of the present invention, and therefore, the present invention is not limited to the example condition. The present invention can employ various conditions as long as the conditions do not depart from the scope of the present invention and can achieve the object of the present invention.
Steels S1 to S98 including chemical compositions (the balance consists of Fe and unavoidable impurities) shown in Tables 1 to 6 were examined, and the results are described. After the steels were melt and cast, or after the steels were cooled once to the room temperature, the steels were reheated to the temperature range of 900° C. to 1300° C. Thereafter, the hot-rolling and the temperature control (cooling, holding, or the like) were conducted under production conditions shown in Tables 7 to 14, and hot-rolled steel sheets having the thicknesses of 2 to 5 mm were obtained.
In Tables 15 to 22, the characteristics such as the metallographic structure, the texture, or the mechanical properties are shown. Moreover, in Tables, the average pole density of the orientation group of {100}<011> to {223}<110> is shown as D1 and the pole density of the crystal orientation {332}<113> is shown as D2. In addition, the area fractions of the ferrite, the bainite, the martensite, the pearlite, and the residual austenite are shown as F, B, fM, P, and γ respectively. Moreover, the average size of the martensite is shown as dia, and the average distance between the martensite is shown as dis. Moreover, in Tables, the standard deviation ratio of hardness represents a value dividing the standard deviation of the hardness by the average of the hardness with respect to the phase having higher area fraction among the ferrite and the bainite.
As a parameter of the local deformability, the hole expansion ratio λ and the critical bend radius (d/RmC) by 90° V-shape bending of the final product were used. The bending test was conducted to C-direction bending. Moreover, the tensile test (measurement of TS, u-EL and EL), the bending test, and the hole expansion test were respectively conducted based on JIS Z 2241, JIS Z 2248 (V block 90° bending test) and Japan Iron and Steel Federation Standard JFS T1001. Moreover, by using the above-described EBSD, the pole densities were measured by a measurement step of 0.5 in the thickness central portion which was the range of ⅝ to ⅜ of the thickness-cross-section (the normal vector thereof corresponded to the normal direction) which was parallel to the rolling direction at ¼ position of the transverse direction. Moreover, the r values (Lankford-values) of each direction were measured based on JIS Z 2254 (2008) (ISO 10113 (2006)). Moreover, the underlined value in the Tables indicates out of the range of the present invention, and the blank column indicates that no alloying element was intentionally added.
Production Nos. P1, P2, P7, P10, P11, P13, P14, P16 to P19, P21, P23 to P27, P29 to P31, P33, P34, P36 to P41, P48 to P77, and P141 to P180 are the examples which satisfy the conditions of the present invention. In the examples, since all conditions of TS 440 (unit: MPa), TS×u−EL≧7000 (unit: MPa·%), TS×λ≧30000 (unit: MPa·%), and d/RmC≧1 (no unit) were simultaneously satisfied, it can be said that the hot-rolled steel sheets have the high-strength, the excellent uniform deformability, and the excellent local deformability.
On the other hand, P3 to P6, P8, P9, P12, P15, P20, P22, P28, P32, P35, P42 to P47, and P78 to P140 are the comparative examples which do not satisfy the conditions of the present invention. In the comparative examples, at least one condition of TS 440 (unit: MPa), TS×u−EL≧7000 (unit: MPa·%), TS×λ≧30000 (unit: MPa·%), and d/RmC≧1 (no unit) was not satisfied.
In regard to the examples and the comparative examples, the relationship between D1 and d/RmC is shown in
[Table 1]
[Table 2]
[Table 3]
[Table 4]
[Table 5]
[Table 6]
[Table 7]
[Table 8]
[Table 9]
[Table 10]
[Table 11]
[Table 12]
[Table 13]
[Table 14]
[Table 15]
[Table 16]
[Table 17]
[Table 18]
[Table 19]
[Table 20]
[Table 21]
[Table 22]
According to the above aspects of the present invention, it is possible to obtain the hot-rolled steel sheet which simultaneously has the high-strength, the excellent uniform deformability, and the excellent local deformability. Accordingly, the present invention has significant industrial applicability.
0.260
1.500
0.120
5.000
3.000
0.040
5.000
0.008
0.401
2.510
4.010
0.1500
2.500
0.0110
2.010
0.151
0.031
0.0110
0.0110
1.010
2.010
2.010
2.010
0.0051
0.201
0.201
1.010
1.010
0.0110
0.0110
0.2010
0.1010
0.5010
1.0100
0.2010
0.2010
0.2010
0.2010
0.0009
0.00009
0.0009
0.0009
0.0009
0.0009
0.00009
0.00009
0.00009
0.00009
0.00009
0.00009
0.00009
0.00009
0.00009
0.00009
45
0
250
45
0
300
0
350
45
35
0
2.00
160
0
250
45
0
35
760
35
145
954
0
250
45
35
760
2.50
35
145
954
830
820
600
600
50.0
500
500
500
500
10
829
805
0.5
16.0
20
355
355
10
829
805
0.5
16.0
20
355
355
5.3
4.3
29.0
71.0
5.9
4.9
0.0
100.0
0.0
6.9
5.1
5.6
4.6
5.3
4.3
5.8
4.8
5.8
4.8
5.2
4.8
6.8
5.1
7.1
5.8
15.0
20.0
15.0
15.0
14.0
16.0
15.5
13.5
13.3
100.0
0.0
100.0
0.0
5.8
4.8
5.8
4.8
5.8
4.8
5.8
4.8
5.8
4.8
5.8
4.8
23.5
71.0
23.5
71.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0
5.8
4.8
100.0
0.0
100.0
0.0
5.1
4.1
5.1
4.1
5.1
4.1
5.1
4.1
5.1
4.1
5.1
4.1
23.5
71.0
23.5
71.0
5.1
4.1
100.0
0.0
100.0
0.0
99.8
0.2
5.8
4.8
5.8
4.8
5.8
4.8
15.5
15.5
15.5
15.5
15.5
15.5
15.5
15.5
15.5
165
151
175
134
182
345
232
386
| Number | Date | Country | Kind |
|---|---|---|---|
| 2011-117432 | May 2011 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2012/063273 | 5/24/2012 | WO | 00 | 1/8/2014 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2012/161248 | 11/29/2012 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20030196735 | Sugiura et al. | Oct 2003 | A1 |
| 20040244877 | Yokoi et al. | Dec 2004 | A1 |
| 20070089814 | Sugiura et al. | Apr 2007 | A1 |
| 20080202639 | Tomida et al. | Aug 2008 | A1 |
| 20110036465 | Kawasaki et al. | Feb 2011 | A1 |
| 20130192724 | Tanaka et al. | Aug 2013 | A1 |
| 20140000765 | Nozaki et al. | Jan 2014 | A1 |
| Number | Date | Country |
|---|---|---|
| 1462317 | Dec 2003 | CN |
| 1599802 | Mar 2005 | CN |
| 101535519 | Sep 2009 | CN |
| 103476960 | Dec 2013 | CN |
| 1 201 780 | May 2002 | EP |
| 1 327 695 | Jul 2003 | EP |
| 1 362 930 | Nov 2003 | EP |
| 2 088 218 | Aug 2009 | EP |
| 2 264 206 | Dec 2010 | EP |
| 61-217529 | Sep 1986 | JP |
| 05-059429 | Mar 1993 | JP |
| 2001-089811 | Apr 2001 | JP |
| 2002-97545 | Apr 2002 | JP |
| 2002-115025 | Apr 2002 | JP |
| 2003-113440 | Apr 2003 | JP |
| 2003-293083 | Oct 2003 | JP |
| 2004-35905 | Feb 2004 | JP |
| 2004-250743 | Sep 2004 | JP |
| 2004-250744 | Sep 2004 | JP |
| 2005-256020 | Sep 2005 | JP |
| 2005-314798 | Nov 2005 | JP |
| 2006-22349 | Jan 2006 | JP |
| 2007-146275 | Jun 2007 | JP |
| 2007-162078 | Jun 2007 | JP |
| 2007-291514 | Nov 2007 | JP |
| 2008-274395 | Nov 2008 | JP |
| 2009-13478 | Jan 2009 | JP |
| 2009-30159 | Feb 2009 | JP |
| 2009-114523 | May 2009 | JP |
| 2009-132981 | Jun 2009 | JP |
| 2009-263718 | Nov 2009 | JP |
| 2010-53387 | Mar 2010 | JP |
| 2010-59452 | Mar 2010 | JP |
| 10-0754035 | Sep 2007 | KR |
| 10-2010-0101691 | Sep 2010 | KR |
| 2294386 | Feb 2007 | RU |
| 2 312 163 | Dec 2007 | RU |
| 2323983 | May 2008 | RU |
| 2 403 291 | Nov 2010 | RU |
| 200938640 | Sep 2009 | TW |
| 201114921 | May 2011 | TW |
| WO 2009099251 | Aug 2009 | WO |
| WO 2011148490 | Dec 2011 | WO |
| WO 2012014926 | Feb 2012 | WO |
| Entry |
|---|
| Chinese Office Action and Search Report, dated Jan. 13, 2015, for Chinese Application No. 201280024587.9 with an English translation. |
| Chinese Office Action and Search Report, dated Jan. 16, 2015, for Chinese Application No. 201280024780.2 with an English translation. |
| Russian Notice of Allowance, dated Jan. 19, 2015, for Russian Application No. 2013151804/02 with an English translation. |
| Korean Notice of Allowance dated Mar. 25, 2016, issued in Korean Patent Application No. 10-2013-7030692. |
| Russian Notice of Allowance, dated Apr. 22, 2015, for Russian Application No. 2013151463, including an English translation. |
| International Search Report issued in PCT/JP2012/063261 mailed Aug. 21, 2012. |
| International Search Report issued in PCT/JP2012/063273 mailed Aug. 21, 2012. |
| Katoh, H. et al. “Development of New High-Strength Hot-Rolled Steel Sheets,” Steel-manufacturing studies (Seitetsu Kenkyu), 1984, vol. 312, pp. 41-50. |
| Kishida, K. “High Strength Steel Sheets for Light Weight Vehicle,” Nippon Steel Corporation Technical Report, 1999, No. 371, pp. 13-17. |
| Matsumura, O. et al. “Enhancement of Elongation by Retained Austenite in Intercritical Annealed 0.4C-1.5Si-0.8Mn Steel,” Transactions ISIJ, 1987, vol. 27, pp. 570-579. |
| NFG Catalog, Nakayama Steel Works, Ltd. Web. Sep. 5, 2012. <http://www.nakayama-steel.co.jp/menu/product/nfg.html>. |
| Office Action issued in Japanese Patent Application No. 2011-032465 mailed Aug. 27, 2013. |
| Sugimoto, K. et al. “Stretch-flangeability of a High-strength TRIP Type Bainitic Sheet Steel,” ISIJ International, 2000, vol. 40, No. 9, pp. 920-926. |
| Takahashi, M. et al. “High Strength Hot-rolled Steel Sheets for Automobiles,” Nippon Steel Corporation Technical Report, 2003, No. 378, pp. 7-11. |
| Taiwanese Office Action dated Jan. 17, 2014 for Taiwanese Application No. 101118534 with English translation. |
| Extended European Search Report, issued Nov. 26, 2014, for European Application No. 12789266.9. |
| European Search Report dated Nov. 7, 2014, issued in European Patent Application No. 12762991.3. |
| Extended European Search Report, dated Nov. 5, 2014, for European Application No. 12763971.4. |
| International Search Report dated Jun. 26, 2012 in PCT/JP2012/058160 (Form PCT/ISA/210). |
| Japanese Notice of Allowance issued in Japanese Patent Application No. 2011-035776 dated Apr. 1, 2014. |
| Korean Notice of Allowance, dated Apr. 14, 2015, issued in Korean Patent Application No. 10-2013-7024766. |
| PCT/ISA/210—International Search Report mailed on Jun. 26, 2012, issued in PCT/JP2012/058199. |
| Taiwanese Office Action issued in Taiwanese Patent Application No. 101110980 dated Jan. 14, 2014. |
| U.S. Office Action dated Apr. 7, 2016, issued in related U.S. Appl. No. 14/007,583. |
| Notice of Allowance dated Sep. 12, 2016 issued in U.S. Appl. No. 14/007,583. |
| Number | Date | Country | |
|---|---|---|---|
| 20140110022 A1 | Apr 2014 | US |
