Patent Application
20180119240
The disclosure relates to a hot rolled steel sheet having high strength such as a tensile strength (TS) of 780 MPa or more, excellent stretch flangeability and blanking workability, and excellent manufacturing stability and suitable for structural-use steel material such as material for parts of transport machinery including vehicles and construction steel material. The disclosure also relates to a method of manufacturing the hot rolled steel sheet.
To reduce CO2 emissions for global environment protection, an ever-present important issue for the automotive industry is to improve automotive fuel efficiency by lightening automotive bodies while maintaining the strength of automotive bodies. An effective way of lightening automotive bodies while maintaining their strength is to strengthen steel sheets as material for automotive parts to thus reduce the thickness of steel sheets. For example, automotive suspension parts in which thick steel sheets tend to be used are expected to be lightened considerably by reducing the thickness of steel sheets through strengthening.
Typically, automotive suspension parts such as lower control arms are formed by burring, and so require steel sheets to have excellent stretch flangeability. Much research and development have been conducted for hot rolled steel sheets having both strength and workability, and various techniques have been proposed. For example, it is known that high tensile strength and excellent stretch flangeability can both be achieved by making the metallic microstructure a substantially ferrite single-phase microstructure and precipitating fine carbides in the grains of the ferrite phase.
As such a technique, JP 2012-26034 A (PTL 1) discloses a hot rolled steel sheet whose strength is improved while maintaining stretch flangeability, by making the steel sheet microstructure a ferrite single-phase microstructure having excellent workability with low dislocation density and dispersing and precipitating fine carbides in the ferrite to achieve strengthening by precipitation.
Burring is typically performed using a steel sheet blanked in a predetermined shape. In actual mass production of parts, the part blanking clearance usually varies due to a temperature increase or wear of the tool caused by continuous pressing. In the case where the clearance varies, defects such as cracking or chipping may occur in the punched end surface. This has raised demand for a steel sheet that maintains excellent blanking workability regardless of the variations of the blanking conditions.
As such a steel sheet, for example, JP 2014-205888 A (PTL 2) discloses a high strength hot rolled steel sheet whose mass-production blanking workability is improved by setting the volume fraction of bainite phase to more than 92%, setting the average spacing of bainite laths to 0.60 or less, and setting the number ratio of Fe-based carbides precipitated in the grains to all Fe-based carbides to 10% or more.
PTL 1: JP 2012-26034 A
PTL 2: JP 2014-205888 A
The steel sheet described in PTL 1 has both high strength and excellent stretch flangeability. However, since the steel sheet microstructure is a substantially ferrite single-phase microstructure, there is hardly any inclusion that serves as a void origin when blanking the steel sheet. Accordingly, in the steel sheet described in PTL 1, the punched end surface may become rough when conditions such as clearance and a blank holder vary.
The steel sheet described in PTL 2 has excellent blanking workability, by controlling the hot rolling conditions so that the steel sheet microstructure is mainly composed of predetermined bainite. Such a bainite microstructure, however, tends to vary in mechanical properties such as tensile strength due to variations in coiling temperature. It is often not easy to keep uniform steel sheet temperature throughout the length and width of the coil during cooling after hot rolling. The steel sheet described in PTL 2 may thus vary greatly in mechanical properties, leading to lower manufacturing stability.
It could be helpful to provide a hot rolled steel sheet having high strength such as a tensile strength (TS) of 780 MPa or more, excellent stretch flangeability and blanking workability, and excellent manufacturing stability, together with an advantageous method of manufacturing the hot rolled steel sheet.
We carefully examined a method that can strengthen a steel sheet while maintaining workability and especially stretch flangeability, provide excellent blanking workability, and reduce variations in mechanical properties caused by variations in manufacturing conditions.
To improve the stretch flangeability of a steel sheet, it is effective to uniformize the strength in the metallic microstructure, as mentioned above. Available techniques include a strengthening technique of forming a ferrite single-phase microstructure to achieve solid solution strengthening or strengthening by precipitation and a strengthening technique of forming a bainite single-phase microstructure to achieve microstructure strengthening. However, in the steel sheet having the ferrite single-phase microstructure, there is hardly any inclusion that serves as a void origin when blanking the steel sheet, so that the punched end surface may become rough when conditions such as clearance and a blank holder vary.
The steel sheet having the bainite single-phase microstructure has excellent stretch flangeability. The steel sheet having the bainite single-phase microstructure also has excellent blanking workability, because many Fe-based carbides are present in the bainite microstructure and serve as a void origin during blanking. However, since the bainite microstructure varies greatly in mechanical properties such as strength depending on the transformation temperature, there is a possibility that the mechanical properties of the steel sheet vary greatly due to variations in hot rolling conditions such as coiling temperature.
We then considered reducing the influence of the variations of the hot rolling conditions by tempering a microstructure mainly composed of bainite or bainite and martensite.
Tempering a bainite or martensite microstructure typically enables a significant reduction of the variations of the mechanical properties caused by the variations of the hot rolling conditions, but also leads to a significant decrease in steel sheet strength. Besides, since Fe-based carbide morphology in tempered bainite or tempered martensite phase varies depending on the annealing conditions, the steel sheet may not be able to have excellent blanking workability depending on the annealing conditions.
In view of this, we carefully examined a technique of preventing such a decrease in steel sheet strength and achieving excellent stretch flangeability and blanking workability when tempering the microstructure mainly composed of bainite or bainite and martensite.
We consequently discovered that dispersing and precipitating MC-type carbides such as TiC inside and at the boundaries of laths inhibits the coarsening of laths during annealing and the disappearance of laths resulting from recovery, so that high steel sheet strength can be maintained even after annealing. We also discovered that excellent blanking workability is achieved by ensuring that Fe-based carbides with an aspect ratio of 5 or less make up at least a predetermined proportion in Fe-based carbides precipitated inside and at the boundaries of laths.
Upon further examination, we discovered that the aforementioned steel sheet microstructure can be stably obtained particularly by adding 0.03% or more Ti and appropriately adjusting heat hysteresis in the annealing.
MC-type carbides are carbides, such as TiC, NbC, VC, and (Ti, Mo)C, with an atom ratio between an M element (for example, Ti, Nb, V, or Mo) and C of approximately 1:1. The M element need not be of one type, and a complex carbide containing a plurality of metal elements is applicable. A N-containing carbonitride or complex carbonitride is applicable, too.
Upon further examination, we also discovered that, by appropriately controlling heat hysteresis when cooling the steel sheet from the maximum heating temperature to the room temperature in the annealing, the formation of the balance other than tempered martensite phase and tempered bainite phase, especially the formation of martensite phase, coarse pearlite phase, and retained austenite phase, is suppressed, as a result of which excellent stretch flangeability can be achieved in addition to high strength and excellent blanking workability.
The disclosure is based on these discoveries and further studies.
We thus provide:
1. A hot rolled steel sheet comprising: a composition containing (consisting of), in mass%, C: 0.03% or more and 0.20% or less, Si: 0.4% or less, Mn: 0.5% or more and 2.0% or less, P: 0.03% or less, S: 0.03% or less, Al: 0.1% or less, N: 0.01% or less, and Ti: 0.03% or more and 0.15% or less, with a balance being Fe and incidental impurities; a microstructure in which a total area ratio of a tempered bainite phase and a tempered martensite phase is 70% or more, a total area ratio of a coarse pearlite phase, a martensite phase, and a retained austenite phase is 10% or less, the tempered bainite phase and the tempered martensite phase have laths with an average width of 1.0 μm or less as a substructure, a proportion of Fe-based carbides with an aspect ratio of 5 or less in Fe-based carbides precipitated inside and at boundaries of the laths is 80% or more, and MC-type carbides with an average particle size of 20 nm or less are dispersed and precipitated inside and at the boundaries of the laths; and an average dislocation density of 1.0×1014 m−2 or more and 5.0×1015 m−2 or less.
2. The hot rolled steel sheet according to 1., wherein the composition further contains, in mass %, one or more of V: 0.01% or more and 0.3% or less, Nb: 0.01% or more and 0.1% or less, and Mo: 0.01% or more and 0.3% or less.
3. The hot rolled steel sheet according to 1. or 2., wherein the composition further contains, in mass%, B: 0.0002% or more and 0.010% or less.
4. The hot rolled steel sheet according to any one of 1. to 3., wherein the composition further contains, in mass%, one or more of REM, Zr, As, Cu, Ni, Sn, Pb, Ta, W, Cr, Sb, Mg, Ca, Co, Se, Zn, and Cs: 1.0% or less in total.
5. The hot rolled steel sheet according to any one of 1. to 4., comprising a coated or plated layer on a surface thereof.
6. A method of manufacturing a hot rolled steel sheet, comprising: hot rolling a steel raw material having the composition according to any one of claims 1 to 4, whereby the steel raw material is heated to an austenite single phase region and subjected to rough rolling and finish rolling to obtain a steel sheet, and the steel sheet is cooled and coiled after the finish rolling; pickling the steel sheet after the hot rolling; and then continuous annealing the steel sheet, wherein in the hot rolling, a finisher delivery temperature is 850° C. or more and 1000° C. or less, an average cooling rate to 500° C. after the finish rolling is 30° C./s or more, and a coiling temperature is 500° C. or less, and in the continuous annealing, a maximum heating temperature of the steel sheet is 700° C. or more and (A3 point+A1 point)/2 or less, a time during which a temperature of the steel sheet is 600° C. or more and 700° C. or less in heating the steel sheet to the maximum heating temperature is 20 s or more and 1000 s or less, a time during which the temperature of the steel sheet is more than 700° C. is 200 s or less, an average cooling rate to 530° C. when cooling the steel sheet from the maximum heating temperature is 8° C./s or more and 25° C./s or less, and a time of holding the steel sheet in a temperature range of 470° C. or more and 530° C. or less after the cooling stops is 10 s or more.
7. The method of manufacturing a hot rolled steel sheet according to 6., further comprising performing a coating or plating treatment on the steel sheet, after the continuous annealing.
It is possible to obtain a hot rolled steel sheet that has high strength such as a tensile strength (TS) of 780 MPa or more and excellent stretch flangeability and blanking workability and whose variations in mechanical properties caused by variations in manufacturing conditions are reduced, which is suitable for structural-use steel material such as material for parts of transport machinery including vehicles and construction steel material. This widens the range of uses of hot rolled steel sheets, and has an industrially significant advantageous effect.
In the accompanying drawings:
Detailed description is given below.
The chemical composition of a hot rolled steel sheet according to the disclosure is described first. The unit of the content of each element in the chemical composition is “mass %”, which is simply expressed as “%” below unless otherwise noted.
C: 0.03% or more and 0.20% or less
C improves the strength of the steel, and promotes the formation of bainite and martensite during hot rolling. The C content therefore needs to be 0.03% or more. If the C content is more than 0.20%, equivalent carbon content is excessively high, which causes a decrease in weldability of the steel sheet. The C content is therefore 0.03% or more and 0.20% or less. The C content is preferably 0.04% or more. The C content is preferably 0.18% or less. The C content is more preferably more than 0.05%. The C content is more preferably 0.15% or less.
Si: 0.4% or less
Typically, Si is actively used in a high strength steel sheet as an effective element that improves the steel sheet strength without decreasing ductility (elongation). If the Si content is more than 0.4%, however, Si forms oxides on the steel sheet surface during heat treatment, and degrades coating adhesion property. The Si content is therefore 0.4% or less. The Si content is preferably 0.3% or less. The Si content is more preferably 0.2% or less. The Si content may be reduced to an impurity level, and may be 0%.
Mn: 0.5% or more and 2.0% or less
Mn is an element that dissolves and contributes to higher strength of the steel. Mn also promotes the formation of bainite and martensite during hot rolling, by improving quench hardenability. To achieve such effects, the Mn content needs to be 0.5% or more. If the Mn content is more than 2.0%, austenite becomes excessively stable, causing the microstructure of the steel sheet to excessively contain martensite and retained austenite. This decreases stretch flangeability. The Mn content is therefore 0.5% or more and 2.0% or less. The Mn content is preferably 0.8% or more. The Mn content is preferably 1.8% or less. The Mn content is more preferably 1.0% or more. The Mn content is more preferably 1.7% or less.
P: 0.03% or less
P is a harmful element that segregates to grain boundaries to decrease elongation, induce cracking during working, and degrade anti-crash property. The P content is therefore 0.03% or less. Excessive dephosphorization, however, leads to longer refining time and higher cost, and so the P content is preferably 0.002% or more.
S: 0.03% or less
S exists as MnS or TiS in the steel, and facilitates the formation of voids when blanking the hot rolled steel sheet. S also serves as a void origin during working, and causes a decrease in stretch flangeability. The S content is therefore desirably as low as possible, and is 0.03% or less. The S content is preferably 0.01% or less. Excessive desulfurization, however, leads to longer refining time and higher cost, and so the S content is preferably 0.0002% or more.
Al: 0.1% or less
Al is an element that acts as a deoxidizing material. To achieve such effects, the Al content is desirably 0.01% or more. If the Al content is more than 0.1%, Al remains in the steel sheet as Al oxide. Such Al oxide tends to coagulate and be coarsened, causing a decrease in stretch flangeability. The Al content is therefore 0.1% or less.
N: 0.01% or less
N exists as coarse TiN in the steel, and facilitates the formation of coarse voids when blanking the hot rolled steel sheet. N also serves as an origin of coarse voids during working, and causes a decrease in stretch flangeability. The N content is therefore desirably as low as possible, and is 0.01% or less. The N content is preferably 0.006% or less. Excessive denitrification, however, leads to longer refining time and higher cost, and so the N content is preferably 0.0005% or more.
Ti: 0.03% or more and 0.15% or less
Ti is a necessary element to form MC-type carbides to thus inhibit lath coarsening in the annealing and strengthen the steel sheet. MC-type carbides also enhance the steel sheet strength by strengthening by precipitation. If the Ti content is less than 0.03%, such effects are insufficient, and lath coarsening and lower precipitation amount cause a decrease in steel sheet strength, making it difficult to achieve desired steel sheet strength (tensile strength of 780 MPa or more). If the Ti content is more than 0.15%, central segregation is noticeable, causing a decrease in blanking workability. The Ti content is therefore 0.03% or more and 0.15% or less. The Ti content is preferably 0.04% or more. The Ti content is preferably 0.14% or less. The Ti content is further preferably 0.05% or more. The Ti content is further preferably 0.13% or less.
While the basic components have been described above, the hot rolled steel sheet may optionally contain one or more of V: 0.01% or more and 0.3% or less, Nb: 0.01% or more and 0.1% or less, and Mo: 0.01% or more and 0.3% or less, for higher strength.
V: 0.01% or more and 0.3% or less
V forms MC-type carbides and contributes to higher strength of the steel sheet by lath coarsening inhibition in the annealing and strengthening by precipitation, as with Ti. To achieve such effects, the V content needs to be 0.01% or more. If the V content is more than 0.3%, central segregation is noticeable, causing a decrease in blanking workability. Accordingly, the V content is preferably 0.01% or more. The V content is preferably 0.3% or less. The V content is more preferably 0.01% or more. The V content is more preferably 0.2% or less. The V content is further preferably 0.01% or more. The V content is further preferably 0.15% or less. V may form MC-type carbides by itself, or form complex carbides with Ti, Nb, and Mo. Such carbide composition does not affect the advantageous effects of the disclosure at all.
Nb: 0.01% or more and 0.1% or less
Nb forms MC-type carbides and contributes to higher strength of the steel sheet by lath coarsening inhibition in the annealing and strengthening by precipitation, as with Ti. To achieve such effects, the Nb content needs to be 0.01% or more. If Nb is excessively added to be more than 0.1% in content, Nb does not dissolve in the heating furnace during hot rolling. The effects thus saturate, and the alloy cost increases. Accordingly, the Nb content is preferably 0.01% or more. The Nb content is preferably 0.1% or less. The Nb content is more preferably 0.01% or more. The Nb content is more preferably 0.08% or less. The Nb content is further preferably 0.01% or more. The Nb content is further preferably 0.06% or less. Nb may form MC-type carbides by itself, or form complex carbides with Ti, V, and Mo. Such carbide composition does not affect the advantageous effects of the disclosure at all.
Mo: 0.01% or more and 0.3% or less
Mo, when added in combination with Ti, forms MC-type complex carbides and contributes to higher strength of the steel sheet by lath coarsening inhibition in the annealing and strengthening by precipitation, as with Ti. To achieve such effects, the Mo content needs to be 0.01% or more. If the Mo content is more than 0.3%, central segregation is noticeable, causing a decrease in blanking workability. Accordingly, the Mo content is preferably 0.01% or more. The Mo content is preferably 0.3% or less. Mo may form complex carbides with Nb and V. Such carbide composition does not affect the advantageous effects of the disclosure at all.
The hot rolled steel sheet may optionally contain B: 0.0002% or more and 0.010% or less, for improved quench hardenability during hot rolling.
B: 0.0002% or more and 0.010% or less
B is an element that segregates to austenite grain boundaries and inhibits the formation and growth of ferrite to improve quench hardenability and promote the formation of bainite and martensite. To achieve such effects, the B content is preferably 0.0002% or more. If the B content is more than 0.010%, hard iron boride forms and causes a decrease in stretch flangeability. Accordingly, in the case of adding B, the B content is preferably 0.0002% or more and 0.010% or less. The B content is more preferably 0.0002% or more. The B content is more preferably 0.0050% or less. The B content is further preferably 0.0004% or more. The B content is further preferably 0.0030% or less.
In addition to the composition described above, the hot rolled steel sheet may contain one or more of REM, Zr, As, Cu, Ni, Sn, Pb, Ta, W, Cr, Sb, Mg, Ca, Co, Se, Zn, and Cs so that their total content is 1.0% or less.
The components other than those described above are Fe and incidental impurities.
The reasons for limiting the microstructure in the hot rolled steel sheet are given below.
Total area ratio of tempered bainite phase and tempered martensite phase: 70% or more
The hot rolled steel sheet has a microstructure mainly composed of tempered bainite and tempered martensite having both high strength and excellent blanking workability. If the total area ratio of tempered bainite phase and tempered martensite phase is less than 70%, the hot rolled steel sheet cannot have desired high strength and blanking workability. Here, the ratio of each of tempered bainite phase and tempered martensite is not individually defined because tempered bainite and tempered martensite after annealing are microstructures not distinguishable from each other. This is a major factor that can reduce variations in mechanical properties after annealing in the case where the manufacturing conditions during hot rolling vary. The total area ratio of tempered bainite phase and tempered martensite phase is therefore 70% or more. The total area ratio of tempered bainite phase and tempered martensite phase is preferably 75% or more. The total area ratio of tempered bainite phase and tempered martensite phase is more preferably 80% or more. The total area ratio of tempered bainite phase and tempered martensite phase may be 100%.
Total area ratio of coarse pearlite phase, martensite phase, and retained austenite phase: 10% or less.
As mentioned above, the microstructure of the hot rolled steel sheet is mainly composed of tempered bainite and tempered martensite, with the balance other than tempered bainite and tempered martensite being, for example, Fe-based carbides, coarse pearlite, fine pearlite, degenerate pearlite, bainite, martensite, and retained austenite. Of these, particularly in the case where coarse pearlite, martensite, and retained austenite are present in the metallic microstructure, stretch flangeability decreases noticeably. The total area ratio of coarse pearlite phase, martensite phase, and retained austenite phase is therefore 10% or less. The total area ratio of coarse pearlite phase, martensite phase, and retained austenite phase is preferably 8% or less. The total area ratio of coarse pearlite phase, martensite phase, and retained austenite phase is more preferably 5% or less. The total area ratio of coarse pearlite phase, martensite phase, and retained austenite phase may be 0%.
Here, coarse pearlite has a lamellar spacing of 0.2 μm or more, fine pearlite has a lamellar spacing of less than 0.2 μm, and degenerate pearlite is a phase in which pearlite lamellar is not clearly observable. The lamellar spacing can be measured by microstructure observation using a scanning electron microscope.
The balance other than tempered bainite phase, tempered martensite phase, coarse pearlite phase, martensite phase, and retained austenite phase is, for example, ferrite phase, degenerate pearlite phase, and fine pearlite phase. A total area ratio of such balance of 30% or less is allowable.
Average width of laths which tempered bainite phase and tempered martensite phase have as substructure: 1.0 μm or less
For strengthening by tempered bainite phase and tempered martensite phase, it is important that tempered bainite phase and tempered martensite phase have fine laths with an average width of 1.0 μm or less as their substructure.
Proportion of Fe-based carbides with an aspect ratio of 5 or less in Fe-based carbides precipitated inside and at the boundaries of laths: 80% or more
Fe-based carbides precipitated inside and at the boundaries of laths as illustrated in
Fe-based carbides are θ carbide (cementite), ϵ carbide, and the like. An alloying element may be dissolved in the carbides. The aspect ratio is the ratio of the major axis length and minor axis length of Fe-based carbides precipitated inside and at the boundaries of laths.
Average particle size of MC-type carbides dispersed and precipitated inside and at the boundaries of laths: 20 nm or less
MC-type carbides finely dispersed and precipitated inside and at the boundaries of laths as illustrated in
It is also important that the hot rolled steel sheet has an average dislocation density in the following range.
Average dislocation density: 1.0×1014 m−2 or more and 5.0×1015 m−2 or less
The variations of the hot rolled steel sheet caused by the variations of the hot rolling conditions are reduced by tempering the steel sheet having bainite and martensite microstructure. If the average dislocation density of the steel sheet after annealing is more than 5.0×1015m−2, the tempering of the steel sheet is insufficient and the influence of the variations of the hot rolling conditions cannot be reduced sufficiently. In the case where tempering is sufficient, the average dislocation density is typically 1.0×1014 m−2 or more. The average dislocation density is therefore 1.0×1014 m−2 or more and 5.0×1015 m−2 or less. The average dislocation density is preferably 1.0×1014 m−2 or more. The average dislocation density is preferably 2.0×1015 m−2 or less.
A method of manufacturing the hot rolled steel sheet according to the disclosure is described below.
The method of manufacturing the hot rolled steel sheet includes: hot rolling a steel raw material having the chemical composition described above, whereby the steel raw material is heated to an austenite single phase region, subjected to rough rolling and finish rolling to obtain a steel sheet, and the steel sheet is cooled and coiled after the finish rolling; pickling the steel sheet after the hot rolling; and then continuous annealing the steel sheet, wherein in the hot rolling, a finisher delivery temperature is 850° C. or more and 1000° C. or less, an average cooling rate to 500° C. after the finish rolling is 30° C./s or more, and a coiling temperature is 500° C. or less, and in the continuous annealing, a maximum heating temperature of the steel sheet is 700° C. or more and (A3 point+A1 point)/2 or less, a time during which a temperature of the steel sheet is 600° C. or more and 700° C. or less in heating the steel sheet to the maximum heating temperature is 20 s or more and 1000 s or less, a time during which the temperature of the steel sheet is more than 700° C. is 200 s or less, an average cooling rate to 530° C. when cooling the steel sheet from the maximum heating temperature is 8° C./s or more and 25° C./s or less, and a time of holding the steel sheet in a temperature range of 470° C. or more and 530° C. or less after the cooling stops is 10 s or more. The method may further include performing a coating or plating treatment on the steel sheet, after the continuous annealing.
The method of obtaining the steel raw material by steelmaking is not limited, and any known steelmaking process such as a converter steelmaking process or an electric furnace steelmaking process may be used. After steelmaking, continuous casting is preferably performed to yield a slab (steel raw material) in terms of productivity and the like. The slab may be yielded by a known casting method such as ingot casting and blooming, thin slab continuous casting, or the like.
The obtained steel raw material is subjected to hot rolling, in which the steel raw material is subjected to rough rolling and finish rolling. Before the rough rolling, the steel raw material is heated in the austenite single phase region. If the steel raw material before the rough rolling is not heated in the austenite single phase region, the remelting of Ti carbide and the like present in the steel raw material does not progress, and fine MC-type carbides do not precipitate during the annealing after the hot rolling. Accordingly, the steel raw material is heated to the austenite single phase region, preferably to 1150° C. or more, before the rough rolling. No upper limit is placed on the heating temperature, yet an excessively high heating temperature leads to a considerable decrease in yield rate due to the oxidation of the slab surface, and so the heating temperature is typically 1350° C. or less. In the case where the temperature of the cast steel raw material (slab) is in the austenite single phase region when hot rolling the steel raw material, the steel raw material may be subjected to hot direct rolling without being heated or after being heated for a short time.
The reasons for limiting the manufacturing conditions in the hot rolling are given below.
Finisher delivery temperature: 850° C. or more and 1000° C. or less
If the finisher delivery temperature is low, ferrite transformation is promoted during the cooling after the rolling, causing a decrease in the bainite and martensite ratio of the hot rolled steel sheet after the hot rolling. This makes it impossible to obtain a predetermined tempered bainite and tempered martensite ratio after the annealing. Accordingly, the finisher delivery temperature needs to be 850° C. or more. The finisher delivery temperature is preferably 880° C. or more. If the finisher delivery temperature is more than 1000° C., the surface characteristics of the steel sheet degrade. The finisher delivery temperature is therefore 1000° C. or less. The finisher delivery temperature is preferably 970° C. or less. Each of the temperatures such as the finisher delivery temperature and the coiling temperature mentioned here is the temperature of the steel sheet surface.
Cooling rate to 500° C. after finish rolling: 30° C./s or more
When cooling the steel sheet after the finish rolling, if the cooling rate is insufficient, ferrite cannot be suppressed adequately, causing a decrease in the bainite and martensite ratio of the hot rolled steel sheet after the hot rolling. This makes it impossible to obtain a predetermined tempered bainite and tempered martensite ratio after the annealing. Accordingly, the cooling rate to 500° C. after the finish rolling needs to be 30° C./s or more. The cooling rate is preferably 50° C./s or more. No upper limit is placed on the cooling rate, yet the upper limit is typically about 300° C./s.
Coiling temperature: 500° C. or less
Appropriately adjusting the coiling temperature is important in controlling the steel sheet microstructure after the hot rolling. If the coiling temperature is more than 500° C., the lath width of bainite increases. This makes it impossible to obtain a predetermined lath width of tempered bainite after the annealing. No lower limit is placed on the coiling temperature, yet an excessively low coiling temperature merely leads to higher cooling cost, and so the coiling temperature is preferably 0° C. or more. The coiling temperature is more preferably 200° C. or more.
After the hot rolling, the hot rolled steel sheet is subjected to pickling and then to continuous annealing. The reasons for limiting the manufacturing conditions in the continuous annealing are given below.
Maximum heating temperature of steel sheet: 700° C. or more and (A3 point+A1 point)/2 or less
Appropriately adjusting the maximum heating temperature of the steel sheet in the continuous annealing is important in sufficiently reducing the influence of the variations of the manufacturing conditions in the hot rolling caused by the annealing and achieving desired high strength. If the maximum heating temperature of the steel sheet is less than 700° C., the dislocation density in bainite and martensite is difficult to be controlled within an appropriate range, and so the influence of the variations of the manufacturing conditions in the hot rolling cannot be reduced sufficiently. Besides, if the heating temperature of the steel sheet is less than 700° C., the aspect ratio of Fe-based carbides inside and between laths tends to be high, which makes it difficult to set the proportion of Fe-based carbides with an aspect ratio of 5 or less to be in a desired range. If the maximum heating temperature of the steel sheet is more than (A3 point+A1 point)/2, MC-type carbides coarsen noticeably, as a result of which lath coarsening in bainite and martensite cannot be inhibited adequately. Moreover, austenitizing is promoted, causing a decrease in the bainite and martensite ratio. This makes it impossible to obtain a desired tempered bainite and tempered martensite ratio. The maximum heating temperature of the steel sheet in the continuous annealing is therefore 700° C. or more and (A3 point+A1 point)/2 or less.
The maximum heating temperature is preferably 700° C. or more. The maximum heating temperature is preferably {(A3 point+A1 point)/2}−10° C. or less.
The A1 point and the A3 point can be calculated according to the following expressions.
A
1 point=751−26.6×[% C]+17.6×[% Si]−11.6×[% Mn]+22.5×[% Mo]+233×[% Nb]−39.7×[% V]−57×[% Ti]−895×[% B]−169×[% Al]
A
3 point=937−476.5×[% C]+56×[% Si]−19.7×[% Mn]+38.1×[% Mo]+124.8×[% V]+136.3×[% Ti]−19×[% Nb]+3315×[% B]
where [% X] denotes the content of an X element in steel (mass %).
Time during which the steel sheet temperature is 600° C. or more and 700° C. or less in heating the steel sheet to the maximum heating temperature: 20 s or more and 1000 s or less
In heating the steel sheet to the maximum heating temperature, it is important to appropriately control heat hysteresis in imparting desired high strength and excellent blanking workability to the steel sheet. The pinning effect of MC-type carbides is used to inhibit lath coarsening, as mentioned above. To achieve the pinning effect, MC-type carbides need to be sufficiently dispersed in bainite and martensite before lath coarsening starts. According to our study, the precipitation of MC-type carbides begins to occur noticeably at 600° C. or more. Meanwhile, lath coarsening and disappearance are noticeable at more than 700° C. Hence, lath coarsening and disappearance can be inhibited by holding the steel sheet temperature in the temperature range of 600° C. or more and 700° C. or less for a predetermined time so that MC-type carbides precipitate sufficiently. For sufficient precipitation of MC-type carbides, the holding time in this temperature range needs to be 20 s or more. If the holding time in the temperature range is insufficient, lath coarsening starts before MC-type carbides precipitate sufficiently, so that the pinning effect is insufficient and the laths coarsen. The holding time is preferably 35 s or more. The holding time is more preferably 50 s or more.
If the holding time of the steel sheet temperature in the temperature range of 600° C. or more and 700° C. or less is more than 1000 s, Fe-based carbides precipitated inside and between laths dissolve again and move to prior austenite grain boundaries, packet grain boundaries, block grain boundaries, and the like. Thus, Fe-based carbides inside and between laths that effectively contribute to improved blanking workability no longer exist. Accordingly, to obtain a steel sheet having excellent blanking workability, the holding time of the steel sheet temperature in the temperature range of 600° C. or more and 700° C. or less needs to be 1000 s or less. The holding time is preferably 800 s or less. The holding time is more preferably 500 s or less. The steel sheet temperature mentioned here is the temperature of the steel sheet surface.
Time during which the steel sheet temperature is more than 700° C.:
200 s or less
When the steel sheet temperature is in the temperature range of more than 700° C., lath coarsening is noticeable. The pinning effect of MC-type carbides finely dispersed and precipitated is used to prevent the movement of lath boundaries and inhibit lath coarsening, as mentioned above. The steel sheet strength is maintained in this way. If the holding time in this temperature range is excessively long, however, lath coarsening cannot be inhibited. Accordingly, the holding time of the steel sheet temperature in the temperature range of more than 700° C. is 200 s or less, in terms of preventing lath coarsening. The holding time is preferably 180 s or less. The holding time is more preferably 150 s or less. If the time during which the steel sheet temperature is more than 700° C. is less than 10 s, the ductility of the steel sheet decreases to some extent, and so the holding time is preferably 10 s or more.
Average cooling rate to 530° C. when cooling the steel sheet from the maximum heating temperature: 8° C./s or more and 25° C./s or less
When cooling the steel sheet after heating it to the maximum heating temperature in the continuous annealing, it is important to appropriately control the cooling rate in achieving excellent stretch flangeability.
Particularly in the case where the average cooling rate to 530° C. is less than 8° C./s, pearlite transformation cannot be suppressed during the cooling, as a result of which coarse pearlite forms in a predetermined amount or more. This decreases stretch flangeability. If the average cooling rate is excessively high, holding the steel sheet in the temperature range of 470° C. or more and 530° C. or less for a predetermined time as mentioned below is difficult. The average cooling rate to 530° C. when cooling the steel sheet from the maximum heating temperature is therefore 25° C./s or less.
Holding time in the temperature range of 470° C. or more and 530° C. or less: 10 s or more
In the continuous annealing, it is important to hold the steel sheet in the temperature range of 470° C. or more and 530° C. or less for a predetermined time after the aforementioned controlled cooling, in achieving excellent stretch flangeability. If the holding temperature after the cooling stops is more than 530° C., coarse pearlite forms, causing a decrease in stretch flangeability. If the holding temperature after the cooling stops is less than 470° C., the transformation from austenite to bainite delays. As a result, C concentrates in the non-transformed austenite region to stabilize austenite, hampering the completion of the transformation. In the subsequent cooling, non-transformed austenite transforms to martensite or remains in the steel sheet microstructure as retained austenite, so that stretch flangeability decreases. In the case where the steel sheet is held in the temperature range of 470° C. or more and 530° C. or less for 10 s or more, the transformation of most austenite to bainite completes, with it being possible to reduce the proportion of martensite which forms during the subsequent cooling to a predetermined range. Accordingly, the holding time in the temperature range of 470° C. or more and 530° C. or less after the controlled cooling stops is 10 s or more. The holding time is preferably 20 s or more. The holding time is more preferably 30 s or more. No upper limit is placed on the holding time, yet the holding time is typically 300 s or less.
Holding the steel sheet in the temperature range of 470° C. or more and 530° C. or less completes the control of the steel sheet microstructure. The subsequent cooling conditions are not limited, and the steel sheet may be cooled to room temperature by any cooling method.
Even in the case of reheating the steel sheet to 700° C. or less after holding the steel sheet in the temperature range of 470° C. or more and 530° C. or less, desired steel sheet microstructure can still be obtained as long as the total holding time in the temperature range of 600° C. or more and 700° C. or less is 1000 s or less.
For example, after holding the steel sheet in the temperature range of 470° C. or more and 530° C. or less, the steel sheet may be immersed in a zinc pot to yield a hot-dip galvanized steel sheet. The steel sheet may then be further heated to yield a galvannealed steel sheet. The hot dip coating is not limited to zinc, and may be a coating of aluminum, an aluminum alloy, or the like.
After the continuous annealing, the steel sheet may be subjected to temper rolling either continuously in the annealing line or using another line according to a conventional method.
The hot rolled steel sheet manufactured as described above may be electrogalvanized or hot-dip galvanized. The hot rolled steel sheet according to the disclosure is suitable not only as a steel sheet for automotive suspension parts but also for press forming typically performed at ordinary temperature, and has excellent heat resistance. Hence, the hot rolled steel sheet manufactured as described above is also suitable as a blank sheet for a warm forming process of heating a steel sheet to 400° C. to 700° C. before pressing and then immediately press forming the steel sheet.
Molten steels having the compositions listed in Table 1 were each obtained by steelmaking and subjected to continuous casting by a typically known technique, to yield a slab (steel raw material) with a thickness of 300 mm. The slab was heated to the temperature in Table 2, rough rolled, and finish rolled at the finisher delivery temperature in Table 2. After completing the finish rolling, the steel sheet was cooled at the average cooling rate in Table 2, and coiled at the coiling temperature in Table 2, to obtain a hot rolled steel sheet with a sheet thickness of 3.2 mm. The hot rolled steel sheet was then pickled by a typically known technique, and annealed in a continuous annealing line under the conditions in Table 2. Some of the steel sheets were subjected to hot-dip galvanizing treatment and optionally further subjected to alloying treatment in the continuous annealing line, thus yielding hot-dip galvanized steel sheets and galvannealed steel sheets.
A test piece was collected from each obtained hot rolled steel sheet, and subjected to microstructure observation, average dislocation density measurement, a tensile test, a hole expansion test, a blanking test, and manufacturing stability evaluation. The evaluation results are listed in Table 3. The test methods are as follows.
(i) Microstructure Observation
A test piece was collected from each obtained hot rolled steel sheet, and polished in a cross-section (L cross-section) parallel to the rolling direction of the test piece and etched by nital. A micrograph taken with a scanning electron microscope (1000, 3000, 5000 magnifications) was used to determine the total area ratio of tempered bainite phase and tempered martensite phase, the area ratio of coarse pearlite phase, the total area ratio of martensite phase and retained austenite phase (MA), and the area ratio of phase other than these, through the use of an image analyzer. It is difficult to distinguish martensite phase and retained austenite phase from each other with a scanning electron micrograph. In this example, however, the total area ratio of coarse pearlite phase, martensite phase, and retained austenite phase is important, and accordingly the total area ratio of martensite phase and retained austenite phase (MA) was determined without distinguishing martensite phase and retained austenite phase from each other.
Moreover, a thin film made from each hot rolled steel sheet was observed using a transmission electron microscope (TEM), to measure the lath width in tempered bainite and tempered martensite and determine the proportion of Fe-based carbides with an aspect ratio of 5 or less in Fe-based carbides precipitated inside and at the boundaries of laths and the average particle size of MC-type carbides precipitated inside and at the boundaries of laths.
The lath width in tempered bainite and tempered martensite was measured as follows. In a transmission electron micrograph of 120 mm×80 mm in size taken for 10 observation fields at 30000 magnifications, five straight lines orthogonal to the major axes of three or more consecutively aligned laths were drawn at intervals of 10 mm, the length of each line segment where the corresponding straight line intersects with the lath boundaries was measured, and the average length of the line segments was set as the average lath width.
The proportion of Fe-based carbides with an aspect ratio of 5 or less in Fe-based carbides precipitated inside and at the boundaries of laths was determined as follows. In a micrograph taken at 165000 magnifications, the major axis length and the minor axis length were measured for at least 100 particles of Fe-based carbides precipitated inside and at the boundaries of laths for 5 observation fields in total, to calculate the aspect ratio. The proportion of Fe-based carbides with an aspect ratio of 5 or less was thus determined. The average particle size of MC-type carbides was determined as follows. In a micrograph taken at 300000 magnifications, the diameter was measured for at least 100 particles of MC-type carbides such as TiC for 5 observation fields in total, and an arithmetic average (average particle size ddef) was calculated. The lower limit of the measured particle size was 2 nm.
(ii) Average Dislocation Density Measurement
A test piece was collected from each obtained hot rolled steel sheet, and the dislocation density of a ¼ portion in sheet thickness was measured. Assuming that the dislocation density of a ¼ portion in sheet thickness represents the average dislocation density of the steel sheet, the measurement was set as average dislocation density. The collected test piece was subjected to mechanical grinding and also polishing with oxalic acid for 0.1 mm, to adjust the sample so that the ¼ portion in sheet thickness was exposed to the surface. Polishing with oxalic acid was intended to remove the layer worked by grinding.
For the sample adjusted in this way, the strain of the steel sheet was measured by an X-ray diffractometer. With an X-ray diffractometer, the diffraction intensity of (110) plane, (211) plane, and (220) plane of α-iron in the ¼ portion in sheet thickness was measured using CoKα rays. The half-value breadth of the peak value of the reflection intensity of each crystal plane was calculated from the obtained measurement chart, and the local strain ϵ′ applied to the steel sheet was determined according to the following Expressions (1) and (2).
βcosθ/λ=0.9/D+2ϵ′sinθ/λ (1)
where β is the half-value breadth of the peak value (the value corrected according to Expression (2) was used), θ is the diffraction angle, λ is the wavelength of CoKα rays (0.1790 nm), D is the crystallite size (dislocation cell, crystal grain size), and ϵ′ is the local strain.
β2=βm2−B02 (2)
where βm is the half-value breadth of the peak of the sample subjected to dislocation density measurement, and β0 is the half-value breadth of the peak of a strain-free sample.
Here, βcosθ/λ was plotted against sinθ/λ, and ϵ′ and D were calculated from the slope and the intercept. From the obtained local strain ϵ′, the dislocation density ρ was determined according to the following Expression (3).
ρ=14.4ϵ′2/b2 (3)
where b is the Burgers vector (0.248 nm).
(iii) Tensile Test
A JIS No. 5 tensile test piece (JIS Z 2001) was collected from each obtained hot rolled steel sheet so that the direction (C direction) orthogonal to the rolling direction was the tensile direction, and subjected to a tensile test in conformity with JIS Z 2241 to measure yield strength (YS), tensile strength (TS), and elongation (El).
(iv) Hole Expansion Test
A test piece (size: 100 mm×100 mm) was collected from each obtained hot rolled steel sheet, and blanked with a hole of 10 mmφ in initial diameter d0 (clearance: 12.5% of the test piece sheet thickness). A hole expansion test was conducted using the test piece. In detail, a conical punch with a vertex angle of 60° was inserted into the hole of 10 mmφ in initial diameter d0 from the punch side at the time of blanking, to expand the hole. The diameter d (mm) of the hole when a crack ran through the steel sheet (test piece) was measured, and the hole expansion ratio λ (%) was calculated according to the following expression.
Hole expansion ratio λ (%)={(d−d0)/d0}×100.
The stretch flangeability was evaluated as favorable in the case where tensile strength (TS)×{hole expansion ratio (X)}0.5 was 6200·MPa %0.5 or more.
(v) Blanking Test
A test piece (size: 30 mm×30 mm) was collected from each obtained hot rolled steel sheet, and blanked with a hole of 10 mmφ in diameter d0 (clearance: 20%, 30% of the test piece sheet thickness). After the blanking, the fracture state of the punched end surface was observed by a microscope (50 magnifications) on the whole circumference of the punch hole, to observe whether or not any crack, chip, or brittle fracture occurred. The blanking workability was evaluated as “pass” if there was no crack, chip, or brittle fracture, and “fail” otherwise.
As can be seen from Table 3, in all Examples, a hot rolled steel sheet having high strength such as a tensile strength (TS) of 780 MPa or more and excellent stretch flangeability and blanking workability was obtained.
To evaluate the variations of the mechanical properties of each steel sheet, 100 JIS No. 5 tensile test pieces (JIS Z 2001) were optionally collected from the whole length and whole width of the hot rolled steel sheets of Examples so that the orthogonal direction (C direction) was the tensile direction. A tensile test was conducted in conformity with JIS Z 2241 to measure the tensile strength (TS), and their standard deviation σ was calculated. In all Examples, the standard deviation of the tensile strength (TS) was 10 MPa or less.
Thus, in all Examples, the mechanical properties of the steel sheet such as tensile strength (TS) had little variations, exhibiting excellent manufacturing stability.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2015-075329 | Apr 2015 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2016/001834 | 3/30/2016 | WO | 00 |
