Patent Application
20200182519
The present invention relates generally to a heat distribution and cooling device with an integrated chemical heat pump.
Heat sorption pumps are used in various heating systems today and will increase primarily due to cost reasons because of its ability to reduce energy consumption. Additionally, but not least this will have a positive environmental impact since reduction of energy consumption most often means reduced CO2 emissions.
In order for sorption heat-pumps to be profitable, they need to be simple, robust, highly efficient, affordable and easy to integrate with energy storage. In addition, such sorption heat pumps must also be easily integrated into the relevant heating and cooling appliances already on the market today.
In PCT/SE2008/000676 there is disclosed a combination of a sorption heat pump with integrated energy storage. For such a sorption heat pump or any other sorption heat-pump to operate energy- and cost-effectively in an appliance and/or in a cooling or heating system, it requires a device consisting of a multitude of valves, heat exchangers, hydraulic piping, pumps and a controller.
Chemical heat pumps are also disclosed in U.S. Ser. No. 09/868,326, U.S. Ser. No. 12/812,090, U.S. Ser. No. 12/302,868, U.S. Ser. No. 13/319,485, U.S. Ser. No. 13/319,496, and U.S. Ser. No. 13/319,502.
To meet the need these pumps have to be reliable and solid with few moving parts.
Many sorption machines work according to a batch process which means that they work intermittently. These sorption machines usually consist of two main components: a reactor and a part that acts as a condenser or evaporator depending on the phase of the process. In these types of machines there are two well defined phases: charging and discharging. During the charging phase, the reactor takes in heat at high temperature and the condenser releases heat at lower temperatures. During the discharging phase, the reactor releases heat at low relatively temperatures and the evaporator absorbs heat at much lower temperatures (i.e. cooling).
The two phases are strongly based on heat exchange with the environment. Additionally, since the absorption machine works intermittently, the reactor needs heat in one phase and in the following phase it releases heat. The same occurs with the condenser/evaporator but conversely.
In order to supply or release heat at different temperatures, the sorption machine often uses a complex system of valves, pumps and pipes that act as an auxiliary system for the sorption machine. Thus, the sorption machine becomes more complex by having moving parts resulting in higher electricity consumption and a greater risk of leakage in addition to higher costs and a more complicated manufacturing process.
WO2015/053764 and WO2015/053767 both disclose a water heater with a sorption based reactor integrated into a water tank. The reactor is operated between an adsorption cycle and a desorption cycle. There is disclosed a space in contact with a heat source. A medium evaporates from that space.
Although the technology according to the prior art is working, there is still room for an improvement. Problems to be solved in the prior art include how to feed a suitable amount of medium to the space from which the medium evaporates. Since that space is often located at a low level in the device the medium cannot be allowed to flow freely into the space. Further the feed rate of medium must be suitable with regard to the evaporation rate. Another problem to be solved is that pumps should be avoided if possible or at least the number of pumps should be minimized to obtain a device which consumes less energy, is less expensive to manufacture and less prone to break down.
Thus there is a need to provide a machine with fewer moving parts, and with an improved feeding of heat transferring medium to the heated space where the medium evaporates.
It is an object of the present invention to obviate at least some of the disadvantages in the prior art and to provide an improved heat transferring device with an integrated chemical heat pump which also has the ability of cooling.
In a first aspect there is provided a heat transferring device comprising:
a first space 22 in thermal contact with a heat source,
a second space 34 in fluid contact with a third space 33 over at least one heat transferring member 13,
at least one first conduit 1 giving a fluid contact between the first space 22 and the second space 34,
a heat exchanger 26,
a reservoir 30,
a pump 28,
at least one second conduit 2 giving a fluid contact between the reservoir 30 and the pump 28 and between the pump 28 and the heat exchanger 26,
at least one active substance 27 in thermal contact with the outer surface of the at least one heat transferring member 13, the at least one heat transferring member 13 being inside a fourth space 31
a volatile liquid inside the fourth space 31 wherein the volatile liquid is adapted to be absorbed by the active substance 27 at a first temperature and be desorbed by the active substance 27 at a second higher temperature,
at least one third conduit 3 giving a fluid contact between the third space 33 and the reservoir 30,
at least one fourth conduit 4 giving a fluid contact between the heat exchanger 26 and the second space 34,
at least one fifth conduit 5 giving a fluid contact between the reservoir 30 and the first space 22, wherein the fifth conduit (5) is at least one capillary tube.
Further aspects and embodiments are defined in the appended claims.
The invention is highly suitable for all applications where heat is to be transferred from a small volume to a large area. It is also suitable where the same large area needs to be cooled.
One advantage is that the feeding of heat transferring medium to the space where it evaporates is solved in a passive way which both gives a suitable flow resistance and at the same time an appropriate feed of medium.
Thus an advantage is that the number of moving parts is minimized which gives lower costs for use, manufacture, maintenance etc.
The invention is very versatile and can be utilized in many different applications where it is desired to transfer heat from one point to a large area. It can also be used for cooling purposes. The large area is represented by the heat exchanger 26.
The invention is suitably used for heating and cooling of offices, residential buildings, industries, private homes and so on. For instance heating during the night can be followed by cooling during the day. In industry cooling followed by heating or vice versa can benefit from this technology in various industrial processes.
Further the invention can be applied to a large variety of areas, including but not limited to water heaters, domestic water heaters, furnaces, gas driven heat pumps, vehicle heating and/or cooling including cars, trucks, on road and off road, heating and/or cooling of ships as well as combined heating and cooling power production.
The invention is described, by way of example, with reference to the accompanying drawings, in which:
Before the invention is disclosed and described in detail, it is to be understood that this invention is not limited to particular compounds, configurations, method steps, substrates, and materials disclosed herein as such compounds, configurations, method steps, substrates, and materials may vary somewhat. It is also to be understood that the terminology employed herein is used for the purpose of describing particular embodiments only and is not intended to be limiting since the scope of the present invention is limited only by the appended claims and equivalents thereof.
It must be noted that, as used in this specification and the appended claims, the singular forms “a”, “an” and “the” include plural referents unless the context clearly dictates otherwise.
If nothing else is defined, any terms and scientific terminology used herein are intended to have the meanings commonly understood by those of skill in the art to which this invention pertains.
The term conduit as used throughout the description and the claims denotes a pipe or a tube through which a fluid is conveyed. In one embodiment conduit denotes a pipe or a tube between two spaces so that there is fluid contact between the spaces. In an alternative embodiment the two spaces are positioned at least partially adjacent to each other and the conduit is an opening giving a fluid contact between the spaces. Such an opening between two adjacent spaces is also considered to be encompassed by the term conduit.
Unless nothing else is clearly indicated the term lower refers to the direction in relation to the gravitational force when the device is placed in a position intended for operation.
In a first aspect there is provided a heat transferring device comprising:
a first space 22 in thermal contact with a heat source,
a second space 34 in fluid contact with a third space 33 over at least one heat transferring member 13,
at least one first conduit 1 giving a fluid contact between the first space 22 and the second space 34,
a heat exchanger 26,
a reservoir 30,
a pump 28,
at least one second conduit 2 giving a fluid contact between the reservoir 30 and the pump 28 and between the pump 28 and the heat exchanger 26,
at least one active substance 27 in thermal contact with the outer surface of the at least one heat transferring member 13, the at least one heat transferring member 13 being inside a fourth space 31
a volatile liquid inside the fourth space 31 wherein the volatile liquid is adapted to be absorbed by the active substance 27 at a first temperature and be desorbed by the active substance 27 at a second higher temperature,
at least one third conduit 3 giving a fluid contact between the third space 33 and the reservoir 30,
at least one fourth conduit 4 giving a fluid contact between the heat exchanger 26 and the second space 34,
at least one fifth conduit 5 giving a fluid contact between the reservoir 30 and the first space 22, wherein the fifth conduit (5) is at least one capillary tube
It is conceived that several loops are formed of spaces and conduits in which the heat transferring medium can flow. One loop is formed by the following: the second space 34, the heat transferring member 13, the third space 33, the third conduit 3, the reservoir 30, second conduit 2 including the pump 28, the heat exchanger 26, and the fourth conduit 4 leading back to the second space 34. Another loop is formed by the following: the first space 22, the first conduit 1, the second space 34, the heat transferring member 13, the third space 33, the third conduit 3, the reservoir 30, and the fifth conduit 5 leading back to the first space 22.
It is intended that the heat transferring medium will circulate depending on the operation mode of the device. Below the charging and discharging modes are described in greater detail. The heat transferring medium that is evaporated from the first space 22 is replaced by heat transferring medium from the reservoir 30 through the fifth conduit 5.
In one embodiment the heat source 22 is at least one selected from the group consisting of a gas burner, an electrical heater, an oil burner, a wood burner, a coal burner, a nuclear powered heat source, a solar powered heat source, a wave powered heat source, and a wind powered heat source. Surplus heat from any source can be used, for instance from a combustion engine. Any heat source that can provide heat as long as the heat source is able to provide enough heat to evaporate the heat transferring medium.
In one embodiment the at least one heat transferring member 13 is shaped as a plate. The heat transferring members 13 between the spaces 34 and 33 provides a fluid contact between the spaces. In order to transfer heat to and from the active substance on the outside of the heat transferring members they are suitably made with a large surface area and thin so that heat can efficiently be transferred between the heat transferring medium inside and the active substance on the outside.
In one embodiment the third conduit comprises at least one valve. This allows the flow rate to be adjusted. In an alternative embodiment the capacity of the pump 28 is instead adapted to a suitable flow rate. It is preferred that the pump 28 runs at its optimum rate and that the flow is unrestricted. Then the flow rate is adapted by selecting a suitable pump with the desired capacity. This will minimize the energy consumption.
In one embodiment the fourth conduit 4 ends in the uppermost third of the second space 34. In an alternative embodiment the fourth conduit 4 ends in the uppermost fourth part of the second space 34. It is conceived that the space 34 is divided into three or four parts of equal volume. In one embodiment the fourth conduit 4 ends in the top of the second space 34. The fourth conduit advantageously ends towards the upper part of the space 34 so that the fluid inside the system (i.e. space 34) does not take an undesired shortcut during circulation.
In one embodiment the fourth space 31 is in fluid connection with a condenser/evaporator through a conduit for the volatile liquid. The fourth space 31 together with the condenser/evaporator and the connection between then serves as a chemical heat pump. In one embodiment the conduit for the volatile liquid has a valve so that it is possible to keep the volatile liquid from reaching the active substance after a charging phase. When discharging is desired, the valve is opened. The condenser/evaporator then forms a part of the chemical heat pump. If cooling is desired the condenser/evaporator can be utilized for cooling during the discharging phase. Thus a system distributing a cooling medium in thermal contact with the condenser/evaporator is envisaged.
The active substance is not necessarily a salt. The active substance can be any material, compound and/or entity capable of absorbing a volatile liquid at a first temperature and desorbing the volatile liquid at a second higher temperature.
In one embodiment the active substance is at least one selected from the group consisting of CaO, CaOH, LiCl, LiBr, LiI, MgCl2, MgBr2, MgI2, CaCl2, CaBr2, CaI2, SrI2, KOH, NaOH, ZnCl2, ZnBr2, ZnI2, AlCl3, AlBr3 and AlI3. In an alternative embodiment the active substance is at least one selected from the group consisting of CaOH, LiCl, LiBr, LiI, MgCl2, MgBr2, MgI2, CaCl2, CaBr2, CaI2, SrI2, KOH, NaOH, ZnCl2, ZnBr2, ZnI2, AlCl3, AlBr3 and AlI3.
In one embodiment the volatile liquid is at least one selected from the group consisting of water, and ammonia.
In one embodiment the heat transferring medium is at least one selected from water, a C1-C7 alcohol, and ammonia. The skilled person realizes that any suitable heat transferring medium can be utilized.
The active substance on the outside of the heat transferring elements 13 are parts of a chemical heat pump together with a volatile liquid. The active substance can be a salt and the volatile liquid can be water. The chemical heat pump works batch-wise in two phases. That means it has a charging phase and a discharging phase.
Now the operation and function of the device is described in greater detail. The first phase of absorption cycle is the desorption i.e. the charging. This is depicted in
The discharging phase is depicted in
It is conceived that the heat exchanger 26 can be placed anywhere in the loop of circulating heat transferring medium which is created when the pump 28 is on. The same applies for the pump 28 and the tank 30. Thus the relative position of the tank 30, pump 28 and heat exchanger 26 could be varied.
The operation principle of the chemical heat pump part of the device is described in greater detail: The first phase of the heat pump is the charge phase. It involves drying the active substance, i.e. desorption. In this phase, volatile liquid desorbs as a gas, from the active substance on the surface of the heat transferring elements 13, and is then subsequently condensed in the combined condenser/evaporator which it reaches through the conduit for the volatile liquid. The condensation that now takes place in the condenser/evaporator can be used as useful energy for heating purposes. In the discharging phase the volatile liquid is allowed to reach the dried active substance so that heat is released. A valve between the condenser/evaporator and the fourth space 31 can be used to control when the volatile liquid can flow back to the active substance on the heat transferring elements 13 from the condenser/evaporator.
The volatile liquid is adapted to be absorbed by the active substance at a first temperature and the volatile liquid is adapted to be desorbed by the active substance at a second higher temperature, whereby the active substance at the first temperature has a solid phase, from which the active substance during uptake of the volatile liquid and its gas phase immediately transforms partially into liquid phase and/or a solution and whereby the active substance at the second higher temperature has a liquid phase and/or a solution phase, from which the active substance during desorption of the volatile liquid, in particular the gas phase of the volatile liquid, in particular the gas phase of the volatile liquid, immediately transforms partially into solid phase.
In one embodiment the heat source 22 is a gas burner. Other heat sources are also encompassed. In one embodiment the heat source is an electric heater. In another embodiment the heat source is fuelled with oil. In yet another embodiment the heat source is burning wood and/or coal. In an alternative embodiment the heat source is a combination of different sources such as a combination of at least two selected from the group consisting of gas, oil, electricity, wood, coal and other organic materials. A heat source that is an organic material means that it burns that organic material using oxygen from the surrounding air. Another alternative is solar powered heating. Further waste heat from an engine, an industrial process or another sources can also be utilized.
In one embodiment the at least one heat transferring member 13 is shaped as a disc. Alternative shapes are also encompassed. An advantage of a flat and/or disc shaped body 13 is that it is easy to cover with a matrix, which in turn is able to hold the active substance 27, i.e. the active substance in the chemical heat pump. A flat body gives a large surface to cover with matrix and active substance 27.
In one embodiment the active substance 27 is at least one selected from the group consisting of LiCl, LiBr, LiI, MgCl2, MgBr2, MgI2, CaCl2, CaBr2, CaI2, SrI2, KOH, NaOH, ZnCl2, ZnBr2, ZnI2, AlCl3, AlBr3 and AlI3. In an alternative embodiment the active substance 27 is at least one selected from the group consisting of MgCl2, MgBr2, LiCl, CaCl2, CaBr2, ZnCl2 and NaOH.
In one embodiment the heat transferring element(s) 13 are covered with a matrix. In one embodiment the heat transferring element(s) 13 are covered with a matrix adapted to holding the active substance both in solid state and in solution with the volatile liquid. The matrix is adapted to holding the active substance in all states using for instance capillary force. The function of the matrix is to maintain the solution of the active substance at the location thereof and thereby increase the heat conduction between the heat transferring body 13 and the active substance when the active substance is changing from its liquid (i.e. solution in volatile liquid) to its solid state in the charging process and from its solid to its liquid state during the discharging process. Thereby the fact that the solution often has a higher heat conducting capability than the solid substance can be exploited. The matrix is formed from a substance that is inert to the process in the heat pump and may generally have an ability of binding the solution phase of the active substance to itself and at same time allow the active substance to interact with the volatile medium.
In one embodiment the heat transferring element(s) 13 are in thermal contact with particles comprising an inner part and an outer coating, said inner part comprises at least one selected from the group consisting of a salt and CaO and said outer coating comprises hydrophobic nanoparticles, wherein the particle has an average size from 1 to 1000 μm.
In one embodiment the fifth conduit 5 comprises from 1 to 5 capillary tubes. In one embodiment the fifth conduit 5 is at least one capillary tube with an inner diameter in the interval from 0.01 to 3 mm. The inner diameter of the capillary tube determines the capillary force exerted on fluid in the tube. If the tube is too large the capillary force will be negligible and if the tube is too small the flow rate will be too low. Thus in one embodiment the fifth conduit comprises several tubes each with a different diameter. In an alternative embodiment the fifth conduit comprises several tubes each with the same diameter. For the case where the conduit is a passage between two adjacent spaces the fifth conduit is constructed so that a non-negligible capillary force occurs in the passage.
For the fifth conduit the number of capillary tubes and the inner diameter of the tubes should be selected to obtain a suitable flow resistance so that only a suitable amount of heat transferring medium flows down in the first space 22. Further the number of capillary tubes and the inner diameter of the tubes should be selected to obtain a suitable flow rate with regard to the intended evaporation in the first space 22.
The flow resistance of the fifth conduit is illustrated in
The fifth conduit 5 should be constructed with the intended flow rate during evaporation in mind. The flow through the fifth conduit should correspond at least roughly to the evaporation rate during heating by the heat source. During heating mode the heat transferring medium flows from the tank 30 through the fifth conduit 5 into the first space 22 where it is evaporated by heat from the heat source. In one embodiment the flow rate through the fifth conduit 5 equals the evaporation rate from the first space 22. This is indicated in
In one embodiment at least one of the capillary tubes has a circular cross section. Other shapes of the cross section is also conceivable.
In one embodiment the volatile liquid comprises water. In one embodiment the volatile liquid is water.
In one embodiment the heat transferring medium comprises water. In one embodiment the heat transferring medium is water. In one embodiment the heat transferring medium consists of water.
In one embodiment a further reservoir 29 is arranged between the evaporator 26 and the pump 28. An advantage of using the additional reservoir 29 is that liquid can be pumped into the reservoir 29 and subsequently slowly flow into the space 34.
Other features and uses of the invention and their associated advantages will be evident to a person skilled in the art upon reading the description and the examples.
It is to be understood that this invention is not limited to the particular embodiments shown here. The embodiments are provided for illustrative purposes and are not intended to limit the scope of the invention since the scope of the present invention is limited only by the appended claims and equivalents thereof.
| Number | Date | Country | Kind |
|---|---|---|---|
| 16171915.8 | May 2016 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2017/061690 | 5/16/2017 | WO | 00 |
| Number | Date | Country | |
|---|---|---|---|
| 62409905 | Oct 2016 | US |
