Patent Grant
11105612
The present disclosure relates to characterizing stress in transparent chemically strengthened substrates, and in particular relates to hybrid systems and methods for characterizing stress chemically strengthened transparent substrates.
Transparent substrates that have undergone a chemical strengthening process exhibit increased resistance to scratching and breaking. Such substrates extremely useful for a variety of display applications ranging from television screens to computer screens to mobile hand-held device screens to watches. An example chemical strengthening process is an ion-exchange (IOX) process, whereby ions in a near-surface region of a glass-based substrate are exchanged for external ions, e.g., from a salt bath.
Manufacturing transparent chemically strengthened (CS) substrates requires characterizing their stress characteristics to ensure the CS substrates have the desired levels of chemical strengthening suitable for the given application. The characterization typically requires measuring a stress profile of the CS substrate from the surface to the center, along with related stress parameters, such as the surface compressive stress, the knee stress, the spike depth of layer, the total depth of layer, the depth of compression and the central tension. Other stress-related parameters include the variation in the birefringence with depth into the CS substrate.
There are two main methods used to characterize stress of a transparent CS substrate. The first utilizes evanescent prism coupling spectroscopy (EPCS). The EPCS method using a coupling prism to couple light into guided modes supported by a near-surface waveguide (NSWG) formed in the substrate, e.g., by an IOX process. A coupling prism is also used to couple light out of the NSWG to form a guided mode spectrum. The guide mode spectrum includes a transverse electric (TE) mode spectrum with TE mode lines and a transverse magnetic (TM) spectrum with TM mode lines. The TE and TM modes lines are analyzed to extract stress-related characteristics, including a stress profile. The EPCS method is particularly useful for characterizing stress in the near-surface region of the CS substrate (e.g., surface compressive stress and spike depth of layer) but is not useful for characterizing a central tension (CT) and depth of compression (DOC) that reside deeper within the substrate.
The second main method utilizes light-scattering polarimetry (LSP). In LSP, the CS substrate is irradiated with input laser light at a relatively shallow angle through a coupling prism. The laser light polarization is varied continuously between different polarization states using an optical compensator. The scattered light is detected by an image sensor. Stress in the CS substrate causes optical retardation along the light path, with the amount of stress being proportional to the derivative of the optical retardation. The amount of optical retardation can be determined from the detected scattered light intensity distribution, which varies due to the constructive and destructive interference for the different effective path lengths of the detected light. The LSP method is useful for measuring certain stress-related properties, such as the central tension (CT) and depth of compression (DOC) but is not useful for measuring near-surface stress-related properties.
Presently, to fully characterize the stress profile of a CS substrate from the surface to the center, the CS substrate is first measured using a EPCS measurement system and is them moved to a LSP measurement system and the two measurement stitched together. This is time consuming and introduces the risk of breakage by having to handle the CS substrate when moving the CS substrate between the two measurement systems.
It would therefore be more advantageous to have a single measurement system capable of performing both EPCS and LSP measurements.
The hybrid measurement systems and methods disclosed herein enable a full stress characterization of a transparent CS substrate, including the surface stress S(0), the near-surface compressive stress profile S(x) including the knee stress Sk=S(xk), the depth of layer DOL, the central tension CT, and the depth of compression DOC. The full stress characterization is obtained by combining the stress calculations using both EPCS and LSP measurements.
An embodiment of the disclosure is directed to a system for characterizing stress in a CS substrate having a top surface and a near-surface waveguide. The system comprises: an EPCS sub-system comprising a EPCS light source system and a EPCS detector system in optical communication through an EPCS coupling prism having a EPCS coupling surface; a LSP sub-system comprising a LSP light source system, an optical compensator and a LSP detector system in optical communication with the optical compensator through an LSP coupling prism having a LSP coupling surface; a coupling prism assembly comprising a prism support frame configured to operably support the EPCS and LSP coupling prisms so that the EPCS and LSP coupling surfaces resides substantially in a common plane; and a support plenum having a surface and a measurement aperture, the support plenum configured to support the CS substrate at a measurement plane at the measurement aperture, and to operably support the coupling prism assembly at the measurement aperture so that the EPCS and LSP coupling surfaces reside substantially at the measurement plane.
Another embodiment of the disclosure is directed to a method of measuring first and second stress characteristics of a CS substrate having a surface and a near-surface waveguide, comprising: operably disposing the surface of the CS substrate relative to a coupling prism assembly at a measurement location, the coupling prism assembly comprising an EPCS coupling prism and a LSP coupling prism to respectively define adjacent EPCS and LSP coupling interfaces; performing a EPCS measurement of the CS substrate using the EPCS coupling interface to obtain the first stress characteristics and performing a LSP measurement of the CS substrate using the LSP coupling interface to obtain the second stress characteristics without removing either the coupling prism assembly or the CS substrate from the measurement location; and combining the first and second stress characteristics to establish a full stress characterization of the CS substrate.
In a 1st embodiment, a system for characterizing stress in a chemically strengthened (CS) substrate having a top surface and a near-surface waveguide, comprises: an evanescent prism coupling spectroscopy (EPCS) sub-system comprising a EPCS light source system and a EPCS detector system in optical communication through an EPCS coupling prism having a EPCS coupling surface;
a scattered light polarimetry (LSP) sub-system comprising a LSP light source system, an optical compensator and a LSP detector system in optical communication with the optical compensator through an LSP coupling prism having a LSP coupling surface; and
a coupling prism assembly comprising a prism support frame configured to operably support the EPCS and LSP coupling prisms so that the EPCS and LSP coupling surfaces resides substantially in a common plane; and
a support plenum having a surface and a measurement aperture, the support plenum configured to support the CS substrate at a measurement plane at the measurement aperture, and to operably support the coupling prism assembly at the measurement aperture so that the EPCS and LSP coupling surfaces reside substantially at the measurement plane.
In a 2nd embodiment, for the 1st embodiment, the CS substrate is transparent and comprises either a glass material, a glass-ceramic material or a crystalline material.
In a 3rd embodiment, for any of the 1st through 2nd embodiments, the near-surface waveguide of the CS substrate is defined by at least one ion-exchanged (IOX) region.
In a 4th embodiment, for any of the 1st through 3rd embodiments, the near-surface waveguide of the CS substrate is defined by a near-surface spike region and a deep region.
In a 5th embodiment, for any of the 1st through 4th embodiments, the prism support frame comprises a molded unitary structure.
In a 6th embodiment, for any of the 1st through 5th embodiments, the EPCS and LSP coupling prisms are constituted by first and second sections of a common coupling prism.
In a 7th embodiment, for any of the 1st through 5th embodiments, the prism support frame is adjustable to move at least one of the EPCS and LSP coupling prisms.
In a 8th embodiment, for any of the 1st through 5th embodiments, the prism support frame comprises an isolation member that at least one of:
i) fluidly isolates the EPCS and LSP coupling prisms from each other; and
ii) optically isolates the EPCS and LSP coupling prisms from each other.
In a 9th embodiment, any of the 1st through 8th embodiments further comprises:
the CS substrate operably supported on or adjacent the surface of the support plenum so that the top surface of the CS substrate interfaces with the EPCS and LSP coupling surfaces of the EPCS and LSP coupling prisms to define respective EPCS and LSP coupling interfaces, and wherein the EPCS and LSP coupling interfaces share a common index-matching fluid;
wherein the CS substrate includes a near-surface spike region with a surface refractive index ns and a deep region immediately adjacent the spike region and opposite the top surface of the CS substrate, and wherein the index-matching fluid has a refractive index nf and wherein Δn=nf−ns is in the range from 0.02 to 0.06; and
wherein λ is a measurement wavelength, n(z) is a refractive index profile of the near-surface spike region, and wherein the near-surface spike region of the CS substrate has a normalized slope Sn=|(λ/n)dn(z)/dz|<0.0005.
In a 10th embodiment, for any of the 1st through 9th embodiments, nkneeTM, nkneeTE are the TM and TE refractive indices of the near-surface spike region, wherein nf=noil, wherein ncritTM, ncritTE are a TM critical refractive index and a TE critical refractive index respectively, and wherein the index-matching fluid refractive index noil is selected to satisfy at least one of the following conditions:
max(nkneeTM,nkneeTE)−0.0005≤noil≤max(nkneeTM,nkneeTE)+0.001
max(nkneeTM,nkneeTM)−0.0005≤noil≤max(nkneeTM,nkneeTE+0.0005
min(ncritTM,ncritTE)−0.001≤noil≤max(ncritTM,ncritTE)
min(ncritTM,ncritTE)−0.001≤noil≤min(ncritTM,ncritTE)+0.0005
min(ncritTM,ncritTE)−0.0005≤noil≤min(ncritTM,ncritTE)+0.0005
min(ncritTM,ncritTE)−0.0002≤noil
noil≤min(ncritTM,ncritTE)+0.0002
min(ncritTM,ncritTE)−0.01≤noil≤max(ncritTM,ncritTE)+0.01.
In a 11th embodiment, for any of the 1st through 10th embodiments, the CS substrate is operably supported by a movable substrate holder configured to move along the surface of the support plenum.
In a 12th embodiment, the system of any of the 1st through 11th embodiments further comprises a pressure-vacuum (PV) system comprising a PV source and an array of PV bars pneumatically coupled to the PV source and disposed within the measurement aperture proximate the measurement plane and to the coupling prism assembly to pneumatically engage the CS substrate when the CS substrate is supported by the surface of the support plenum.
In a 13th embodiment, for any of the 1st through 12th embodiments, the EPCS detector system is configured to capture a mode spectrum of the near-surface waveguide based on light from the light source coupled into and out of the near-surface waveguide by the EPCS coupling prism as reflected light, and wherein the EPCS detector system comprises a focusing lens operably arranged in an optical path relative to a digital detector, wherein the mode spectrum has a contrast and wherein the focusing lens has at least one of an adjustable position and an adjustable focal length to adjust the contrast of the mode spectrum.
In a 14th embodiment, for the 13th embodiment, the focusing lens is one of multiple focusing lenses of different focal lengths supported by a support member that can be moved to insert a select one of the focusing lenses into the optical path.
In a 15th embodiment, for any of the 1st through 14th embodiments, the CS substrate is operably supported by a movable substrate holder configured to move along the surface of the support plenum.
In a 16th embodiment, for any of the 1st through 15th embodiments, the LSP light source system comprises a movable light diffuser.
In a 17th embodiment, a method of measuring first and second stress characteristics of a chemically strengthened (CS) substrate having a surface and a near-surface waveguide, comprises:
operably disposing the surface of the CS substrate relative to a coupling prism assembly at a measurement location, the coupling prism assembly comprising an evanescent prism coupling spectroscopy (EPCS) coupling prism and a light-scattering polarimetry (LSP) coupling prism to respectively define adjacent EPCS and LSP coupling interfaces;
performing a EPCS measurement of the CS substrate using the EPCS coupling interface to obtain the first stress characteristics and performing a LSP measurement of the CS substrate using the LSP coupling interface to obtain the second stress characteristics without removing either the coupling prism assembly or the CS substrate from the measurement location; and
combining the first and second stress characteristics to define a full stress characterization of the CS substrate, wherein the first stress characteristics are selected from the group of first stress characteristics comprising: a surface compressive stress S(0), a total depth of layer DOLT, a spike depth of layer DOLsp, a knee stress CSk and a birefringence B and the second stress characteristic comprises at least one of a depth of compression DOC and a central tension CT.
In a 18th embodiment, for the 17th embodiment, performing the LSP measurement comprises:
forming an LSP image on a digital detector to define a raw digital LSP image;
performing a Gaussian-blurring of the raw digital LSP image to form a Gaussian-blurred LSP image;
performing an Otsu thresholding process on the Gaussian-blurred image to define a threshold image; and
using the threshold image to calculate an optical retardation versus depth into the CS substrate to obtain the second stress characteristics.
In a 19th embodiment, for the 17th embodiment, performing the LSP measurement comprises:
forming an LSP image on a digital detector to define a raw digital LSP image;
performing a Gaussian-blurring of the raw digital LSP image to form a Gaussian-blurred LSP image;
performing a binarizing method on the Gaussian-blurred LSP image to define an image contour; and
using the image contour to calculate an optical retardation versus depth into the CS substrate to obtain the second stress characteristics.
In a 20th embodiment, for the 17th embodiment, performing the LSP measurement comprises:
forming an LSP image on a digital detector;
processing the LSP image to form an optical retardation (OR) versus depth (D) curve comprising OR data points;
employing a combination of linear and quadratic functions to obtain a fitted curve to the OR data points.
In a 21th embodiment, for any of the 17th through 20th embodiments, one of the first stress characteristics comprises a measured knee stress CSK, and further comprising:
performing an independent measurement of the knee stress CSK(ind);
defining a calibration factor Kcal=CSk/CSk(ind); and
applying the calibration factor Kcal to at least one of the first stress characteristics.
In a 22nd embodiment, for the 17th embodiment, performing the LSP measurement comprises:
forming an LSP image on a digital detector;
processing the LSP image to form an optical retardation (OR) versus depth (D) curve comprising OR data points that include first and second bend points; and carrying at least one of the following acts:
In a 23rd embodiment, for the 17th embodiment, the method further comprises: forming an LSP image on a digital detector;
processing the LSP image to form an optical retardation (OR) versus depth (D) curve comprising OR data points that define first and second bend points and first and second end regions; and performing at least one of:
In a 24th embodiment, for any of the 17th through 23rd embodiments, the EPCS and LSP coupling interfaces comprise different index-matching fluids and fluidly isolating the different index-matching fluids.
In a 25th embodiment, for any of the 17th through 24th embodiments, the method further comprises optically isolating the EPCS and LSP coupling prisms.
In a 26th embodiment, for the 17th embodiment, the EPCS and LSP coupling prisms are constituted by first and second sections of a common coupling prism.
In a 27th embodiment, for any of the 17th through 26th embodiments, the LSP measurement utilizes a LSP light beam and further comprising passing the LSP light beam through a rotating diffuser disposed optically upstream of the LSP coupling interface.
In a 28th embodiment, any of the 17th through 27th embodiments further comprise:
supporting the CS substrate with a movable substrate holder;
mounting the coupling prism assembly to a support plenum at a measurement aperture of the support plenum, and wherein the support plenum has a surface; and
moving the movable substrate over the surface of the support plenum.
In a 29th embodiment, for any of the 17th through 28th embodiments, the CS substrate comprises either a glass material, a glass-ceramic material or a crystalline material.
In a 30th embodiment, for any of the 17th through 29th embodiments, the near-surface waveguide of the CS substrate is defined by at least one ion-exchanged (IOX) region.
In a 31st embodiment, for any of the 17th through 30th embodiments, the near-surface waveguide of the CS substrate is defined by a near-surface spike region and a deep region.
In a 32nd embodiment, any of the 17th through 31st embodiments further comprises applying a vacuum to the CS substrate at the measurement position to press the CS substrate against respective EPCS and LSP coupling surfaces of the EPCS and LSP coupling prisms.
In a 33rd embodiment, for any of the 17th through 32nd embodiments, the performing of the EPCS measurement comprises:
capturing a mode spectrum of the near-surface waveguide using a EPCS detector system that comprises at least one focusing lens and a digital detector, wherein the mode spectrum has a contrast and the at least one focusing lens resides in an optical path; and
adjusting at least one of a focusing lens position and a focusing lens focal length of the at least focusing lens to improve the contrast of the mode spectrum.
In a 34th embodiment, for the 33rd embodiment, the at least one focusing lens comprises multiple focusing lenses operably supported by a movable support member and having different focal lengths, and wherein said adjusting comprising moving the movable support member place a select one of the multiple focusing lenses in the optical path.
The embodiments described may be combined in any suitable combination. Additional features and advantages are set forth in the Detailed Description that follows, and in part will be apparent to those skilled in the art from the description or recognized by practicing the embodiments as described in the written description and claims hereof, as well as the appended drawings. It is to be understood that both the foregoing general description and the following Detailed Description are merely exemplary, and are intended to provide an overview or framework to understand the nature and character of the claims.
The accompanying drawings are included to provide a further understanding, and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the Detailed Description explain principles and operation of the various embodiments. As such, the disclosure will become more fully understood from the following Detailed Description, taken in conjunction with the accompanying Figures, in which:
Reference is now made in detail to various embodiments of the disclosure, examples of which are illustrated in the accompanying drawings. Whenever possible, the same or like reference numbers and symbols are used throughout the drawings to refer to the same or like parts. The drawings are not necessarily to scale, and one skilled in the art will recognize where the drawings have been simplified to illustrate the key aspects of the disclosure.
The claims as set forth below are incorporated into and constitute part of this Detailed Description.
Cartesian coordinates are shown in some of the Figures for the sake of reference and are not intended to be limiting as to direction or orientation.
In some parts of the discussion, the z coordinate is used for the depth direction into the substrate, while in other parts of the discussion a different coordinate is used.
The acronym “IOX” stands for “ion exchange” or “ion exchanged,” depending on the context of the discussion.
The acronym “CS” when used to describe a type of substrate (as in “CS substrate”) means “chemically strengthened.” The acronym CS can also mean “compressive stress,” and which meaning is being used for this acronym will be apparent by the context of the discussion.
The term “strengthened” for the CS substrates considered herein means that the original CS substrates have undergone a process to create some stress profiles that could have a variety of shapes, typically intended to make the CS substrates stronger and thus harder to break. Example strengthening processes include ion exchange, tempering, annealing and like thermal processes.
The term “transparent” as used in reference to the CS substrate means a CS substrate that has sufficient optical transmission at the give measurement wavelength (i.e., the EPCS wavelength λA or the LSP wavelength λB) to make the satisfactory measurement (i.e., an EPCS measurement or a LSP measurement) of the CS substrate that yields a sufficiently accurate measurement of the stress characteristics associated with the given measurement.
The abbreviation “ms” stands for “millisecond.”
The abbreviation “nm” stands for “nanometer.”
The term “near-surface” such as when referring to a near-surface waveguide or a near-surface spike region of the CS substrate, refers to the portion of the substrate body that resides immediately adjacent a given surface (e.g., the top or measurement surface) of the CS substrate.
In an example, a glass-based substrate is used to form the CS substrate. The term “glass-based substrate” as used herein includes any object made wholly or partly of glass, such as laminates of glass and non-glass materials, laminates of glass and crystalline materials, and glass-ceramics (including an amorphous phase and a crystalline phase). Thus, in an example, the glass-based CS substrate can consist entirely of a glass material while in another example can consist entirely of a glass-ceramic material.
The terms “image” and “line image” are used herein to describe a distribution of light (i.e., intensity distribution) of a portion of the X-shaped LSP image as formed by scattered light at digital detector (CCD camera or CMOS sensor, etc.) by the LSP sub-system, and an imaging system is not necessary to form the LSP image as considered herein.
In the discussion below, the LSP sub-system is configured to cycle between two or more polarization states (or just “polarizations” for short). In an example, there can be up to eight different polarization states per cycle that combine the linear, elliptical and circular polarizations as is known in the art. More polarizations may be used, for example up to one hundred or more.
The term “stress” as used herein can generally mean compressive stress or tensile stress. In the plots of
In an example, the “characterizing” of a CS substrate includes determining one or more stress-based properties of the CS substrate, such as a stress profile S(z), a depth of layer DOL, a surface stress S(0), a depth of compression DOC, a central tension CT, and a birefringence profile B(z). In an example, the characterizing utilizes both EPCS and LSP measurements that respectively provide first and second stress characteristics that when combined provide a “full characterization” of the stress characteristics of the CS substrate, wherein the term “full characterization” means a more complete characterization of the stress and stress-related properties than is possible with just the first stress characteristics of the EPCS measurements or just the second stress characteristics of the LSP measurements.
The acronym “OR” stands for “optical retardation” and is measured in radians (“rads”) unless otherwise stated. Plots of the optical retardation versus depth into the CS substrate are referred to below as “OR vs. D” curves or plots, where D is understood as being the depth into the CS substrate body from the top (measurement) surface.
The term “index-matching fluid” means a fluid with a refractive index substantially the same as another material to facilitate optical coupling. In an example, the index-matching fluid comprises an oil or a mixture of oils. The refractive index of the index-matching fluid is denoted by either nf or noil, i.e., these two expressions are used interchangeably below.
The CS Substrate
In some cases, the thickness TH can be in the range from 0.020 mm≤TH≤2 mm, such as 0.050 mm≤TH≤2 mm, 0.20 mm≤TH≤2 mm, 0.25 mm≤TH≤2 mm, 0.3 mm≤TH≤2 mm, or 0.3 mm≤TH≤1 mm, and any and all sub-ranges formed between these endpoints.
Example types of CS substrates 10 are glass-based and are used as protective covers for displays and/or housings for mobile devices such as smart phones, tablets, laptop computers, GPS devices, etc. Such CS substrates 10 tend to be thin and planar, such as shown in
The CS substrate 10 includes a near-surface waveguide (NSWG) 18 that resides in the body 11 proximate the top surface 12. In an example, the NSWG 18 is formed using an IOX process and is defined by at least one IOX region of varying refractive index.
The plot of
Because of the two distinct refractive-index regions R1 and R2 in the NSWG 18, certain guided modes propagate only in the uppermost spike region R1 while other guided modes travel in both regions R1 and R2, while still other guided modes travel only in the deep region R2. Other refractive index profiles n(z) include more uniform changes in the refractive index. Some of the deep guided modes can extend into the bulk region R3.
The refractive index profile n(z) of
The Hybrid EPCS-LSP System
The EPCS sub-system 100 generates an EPCS measurement signal SA representative of first stress characteristics of the CS substrate at the measurement location ML as embodied in a mode spectrum of the guided modes of the NSWG 18. The first stress characteristics can include one or more of the following: a surface compressive stress S(0), a total depth of layer DOLT, a spike depth of layer DOLsp, a knee stress CSk and a birefringence B.
The LSP sub-system 100 generates a LSP measurement signal SB representative of second stress characteristics of the CS substrate at the measurement location ML as embodied in optical retardation (OR) information as a function of depth into the CS substrate, including the deep region R2. The second stress characteristics can include one or more of the following: a stress profile, a depth of compression DOC and a central tension CT.
In an example, EPCS and LSP measurements of the first and second stress characteristics are made without moving the measurement location ML. In another example, the EPCS and LSP measurements of the first and second stress characteristics are made by translating the coupling prism assembly 40 such that the EPCS and LSP measurements are made at the same position on the substrate rather than at slightly spaced part positions at the measurement location as defined by the configuration of the coupling prism assembly.
In an example, the EPCS and LSP measurements of the first and second stress characteristics are made without removing either the coupling prism assembly 40 or the CS substrate 10 from the measurement location ML. This represents an advantage over the prior art in that both EPCS and LSP measurements can be made in a single system without having to remove or otherwise handle the CS substrate to bring it to a different measurement system.
The EPCS and LSP measurement signals SA and SB are sent to the system controller 400 for processing. The system controller 400 can comprise for example a micro-controller, computer, programmable logic controller (PLC), etc. In an example, the system controller 400 is configured with instructions embodied in a non-transitory computer-readable medium (e.g., software) to control the operation of the hybrid system 20 and perform the calculations for determining the first and second stress characteristic of the CS substrate 10 based on the EPCS and LSP measurement signals SA and SB.
In an example, the system controller 400 processes the EPCS and LSP measurement signals SA and SB to define a stress profile and related stress characteristics from the top surface 12 of the CS substrate 10 down to at least the bottom of the deep region R2. In other words, the system controller combines the first and second stress characteristics obtained from EPCS sub-system 100 and the LSP sub-system 200 to generate a more complete or “full” stress profile of the CS substrate than is possible with just one of the measurement sub-systems.
The coupling prism assembly 40 includes a EPCS coupling prism 42A and a LSP coupling prism 42B operably supported by a prism support structure 46. The coupling prism assembly 40 is operably disposed on or proximate the top surface 12 of the CS substrate 10. In examples discussed below, the EPCS coupling prism 42A and the LSP coupling prism 42B can be separate coupling prisms or different sections of a single (common) coupling prism.
With continuing reference to
The EPCS sub-system 100 includes a EPCS light source system 110 and a EPCS detector system 140 optically coupled via the EPCS coupling prism 42A. The LSP sub-system 200 includes a LSP light source system 210, an optical compensator 230 and a LSP detector system 240 optically coupled to the optical compensator via the LSP coupling prism 42B. The detector systems 140 and 240 are operably connected to the system controller 400. Examples of the EPCS sub-system 100 is described in U.S. Pat. No. 9,534,981 and in U.S. Pat. No. 9,696,207, which are incorporated by reference herein. Examples of the LSP sub-system 100 are described in U.S. Pat. No. 4,655,589, and in U.S. Provisional Patent Application Ser. No. 62/753,388, which are incorporated by reference herein.
The EPCS Sub-System
With reference to
The EPCS light source system 110 also includes along the first optical axis A1: an optional polarizer 118, a light diffuser 122 that resides downstream of the EPCS light source 112, and a focusing lens 120 that resides downstream of the light diffuser. In an example, the light source comprises a light-emitting diode (LED), and further in an example the LED operates at an EPCS measurement wavelength λA of 365 nm. The EPCS detector system 140 resides along a second axis A2 and includes in order along the second axis: a focusing lens 142, a band-pass filter 144 centered on the wavelength λA, an attenuator 146, a TM-TE polarizer 148 (which has TM and TE sections, not shown) and a digital detector (e.g., a digital camera, image sensor, CCD array, etc.) 150 that has TM and TE sections (not shown) as defined by the TM-TE polarizer 148.
The EPCS light beam 116 from the EPCS light source 112 is diffused by the light diffuser 120 and is focused by the focusing lens 120 to form a focused EPCS light beam 116F. The focused EPCS light beam 116F is incident upon the EPCS coupling prism 42A at an input surface 43A. This couples the EPCS focused light beam into the NSWG 18 at a first (EPCS) coupling interface INT1 defined by the top surface 12 of the CS substrate and a bottom or “coupling” surface 45A of the EPCS coupling prism 42A. The first coupling interface INT1 can include an index-matching fluid 5A, as discussed in greater detail below.
A reflected EPCS light beam 116R is formed from the focused EPCS light beam 116F at the first EPCS coupling interface INT1 and exits the output surface 44A of the EPCS coupling prism 42A to travel along a second axis A2. The first and second axes A1 and A2 residing in a common plane (e.g., x-z plane of
The band-pass filter 144 assures that only the reflected EPCS light beam 116R makes it through to the digital detector 150. The attenuator 146 assures that the detected reflected EPSC light beam 116R has the appropriate intensity distribution for efficient digital detection. The TM-TE polarizer 148 defines TM and TE sections for the digital detector so that TM and TE mode spectra can be captured by the digital detector 150. The TM and TE mode spectra are embodied in the first detector signal SA sent to the system controller 400 for processing. It is noted that the order of the band-pass filter 144, the attenuator 146 and the focusing lens 142 is not critical and is intentionally shown as being different between
Transition regions (“transitions”) 166TM and 166TE between the TIR section 161TM, 161TE and the non-TIR sections 162TM, 162TE define a critical angle for the optical coupling into and out of the NSWG 18 of the CS substrate 10 for TM and TE polarized light, and are referred to as the critical angle transitions. The difference in locations of the start of the critical angle transitions 166TM and 166TE is proportional to the knee stress CSk and this is proportionality is indicated by “˜CSk” in
The TM and TE mode lines 163TM and 163TE can either be bright lines or dark lines, depending on the configuration of the EPCS sub-system 100. In
The stress characteristics for the EPCS measurement are calculated based on the difference in the y positions of the TM and TE mode lines 163TM and 163TE in the mode spectrum 160. The birefringence B is the difference between the effective indices of the TM and TE polarizations, wherein the effective indices are represented by the y positions of the mode lines. The surface compressive stress S(0)=CS is computed by the y distances between the mode lines (effective indices) and the ratio B/SOC, where SOC is the stress optic coefficient. At least two TM and TE mode lines 163TM and 163TE are needed to calculate the surface stress S(0). Additional mode lines are needed to calculate the compressive stress profile S(z). The depth of layer DOLT is a measure of stress penetration or ion penetration length into the body 11 of the CS substrate 10, and in the case of an IOX process, can also be calculated by the y-locations and number of mode lines 163TM and 163TE. The TM and TE mode line locations along the y axis are thus the most basic measurement for inferring stress-related characteristics of the CS substrate 10. The calculations for determining the stress characteristics of the CS substrate 10 based on the EPCS measurements using the EPCS sub-system 100 are carried out in the system controller 400.
The LSP Sub-System
With reference now to
The LSP light source system 210 includes in order along the third axis A3: an optional neutral density filter 218 (shown in
The optical compensator 230 resides along the (folded) third axis A3 and includes a polarizer 232, which can be in the form of a polarizing beam splitter PBS. The optical compensator 230 also includes a half-wave plate 234H and a quarter-wave plate 234Q with one of the wave plates being rotatable relative to the other to change the state of polarization of the LSP light beam 216. In an example, the optical compensator 230 can comprise an electronically controlled polarization modulator, such as a liquid-crystal-based modulator or a ferroelectric liquid-crystal-based modulator or like modulator.
In an example, the optical compensator 230 is operably connected to or otherwise includes a controller (not shown) that controls the polarization switching operation performed by the optical compensator. In an example, the optical compensator 230 can comprise a single liquid crystal device. In another example, the optical compensator 230 can comprise multiple elements such as polarizers, wave plates, filters, prisms (e.g., wedge prisms), etc. In an example, the optical compensator 230 causes the LSP light beam 216 to go through a full polarization cycle (i.e., change between two or more select polarizations) in anywhere from less than 1 second to 10 seconds. In an example, the optical compensator 240 can be operably connected to and controlled by the system controller 400.
A third focusing lens 236 resides downstream of the optical compensator 230 and is used to form a focused LSP light beam 216F, which is directed to the LSP coupling prism 42B. The LSP coupling prism has respective input and output surfaces 43B and 44B and a bottom or “coupling” surface 45B. The coupling surface 45B and the top surface 12 of the CS substrate 10 defines a second (LSP) coupling interface IF2. In an example, the second coupling interface INT2 includes an index matching fluid 5B, as discussed below.
The LSP detector system 240 resides along a fourth axis A4 that is orthogonal to the third axis A3, i.e., the fourth axis A4 resides in the Y-Z plane.
In an example, the LSP detector system 240 includes a collection optical system 243 and a digital detector (e.g., a CCD camera) 246. In an example, the collection optical system 243 is telecentric and has unit magnification. The LSP detector system 240 can also include a bandpass filter 344 centered on the second wavelength λB. In the example shown in
In the operation of the LSP sub-system 200, the focused LSP light beam 216F is incident upon the input surface 43B of the LSP coupling prism 42B and travels to the coupling surface 45B and then through the index-matching fluid 5B and to the top surface 12 of the CS substrate 10 to enter the body 11 of the CS substrate. The focused LSP light beam 216F has a select polarization at any given time as defined by the optical compensator 230. The (polarized) input LSP light beam 216F is scattered by features in the body 11 of the CS substrate 10 to form a scattered LSP light beam 216S. The scattered LSP light beam 216S exits the CS substrate 10 at the top surface 12, passes back through the second coupling interface INT2 and then exits the LSP coupling prism 42B at the output surface 44B. The scattered LSP light beam 216S travels to the LSP detector system 240 and is directed to the digital detector 246 by the collection optical system 243. The scattered LSP light beam 216S forms a LSP image 248 on the digital detector 246, as shown in the close-up view of
As shown in
In an example, a given measurement of the CS substrate 10 using the LSP sub-system 200 includes making measurements for a measurement time tM of between 1 second and 10 seconds. During the measurement time tM, the polarization state of the LSP light beam 216 varies between the different polarization states, preferably making one or more cycles through the polarization states. Meantime, for each polarization state, the digital detector 246 captures the LSP image 248 during exposure times tE. In an example, the exposure times tE are about the same as the frame rate FR of the digital detector 246. An example exposure time tE=50 ms, which corresponds to a frame rate FR=20 frames per second. The exposure time tE can also be less than the frame rate.
The electronically captured LSP images 248 differ in their intensity distributions I(xL) depending on the polarization state of the input LSP light beam 216R and the stress-induced optical retardation incurred along the beam path. The difference is due to the difference in the destructive and constructive interference along the length of the scattered LSP light beam 216S as a function of depth D into the CS substrate 10 between the different polarization states. The differences between the multiple intensity distributions I(xL) for the different polarization states is used by the system controller 400 to calculate an optical retardance OR as a function of depth D into the CS substrate body 11 using relationships well known in the art. Likewise, multiple optical retardance curves OR vs the depth D (“OR vs. D plots”) are calculated using the differences in the intensity distributions I(xL). For example, for a 3 second measurement time tM with an image sensor frame rate FR of 20 frames/second, a total of 60 plots of I(xL) vs. D can be generated to compute OR vs. D and used to calculate one or more stress-related characteristics of the CS substrate 10.
While the intensity distributions I(xL) for the LSP image 248 necessarily differ between polarization states of the input light beam 112 when there is stress present in the CS substrate 10, the different OR vs. D curves (plots) as calculated from the measured intensity distributions should ideally be the same for a given CS substrate at the given measurement location for CS substrates where the stress profile is (ideally) constant.
While LSP measurement technique can generate a stress profile S(z), it does not generally produce an accurate representation of the stress profile in the near-surface region of the CS substrate 10. There are least two problematic effects that present challenges for extracting an accurate characterization of the near-surface stress profile for a CS substrate 10 using an LSP measurement from the LSP sub-system 200. One problematic effect is referred to as a “fireball” effect, which is caused by excessive light scattering at the LSP interface INT2. The excessive light scattering generates noise, which corrupts the LSP measurement data for near-surface region, which in an example is the first 60 microns to 100 micrometers below the top surface 12 of the CS substrate 10.
The other problematic effect is caused by the convolution of photons scattered from different depths into the signal corresponding to a particular depth. This convolution significantly changes the signal in the region where stress changes fast, which is usually in the near-surface compression region, most often in the first 80 microns, 100 microns, or 150 microns, but sometimes as high as 200 microns. The region of fast change is thicker for larger thicknesses of Li-based glass.
Some prior-art LSP systems attempt to decrease these convolution effects by using a very focused beam near the CS substrate surface, with beam diameter as small as 10 microns. Unfortunately, this leads to other problems—such as increased laser noise (e.g., speckle) in the same depth region of interest, making the extracted stress profiles in the near-surface region even less reliable.
Coupling Prism Assembly
The hybrid system 20 utilizes the aforementioned coupling prism assembly 40, which operably supports the EPCS coupling prism 42A and the LSP coupling prism 42B to provide the prism coupling for the EPCS sub-system 100 and the LSP sub-system 200 when making the EPCS measurement and the LSP measurement of the CS substrate 10.
In an example, the EPCS and LSP frame sections 48B and the isolation member 50 including securing tabs 52 that includes mounting holes 53 that allow for securing the cover plate 60 to the frame sections using securing members (not shown). The cover plate 60 includes a first aperture 62A sized to accommodate the coupling surface 45A of the EPCS coupling prism 42A and a second aperture 62B sized to accommodate the coupling surface 45B of the LSP coupling prism 42B.
In an example, the CS substrate 10 is operably supported by a movable substrate holder 80 that holds the CS substrate over the measurement aperture 72 so that the EPCS and LSP coupling prisms 42A and 42B can be interfaced with the top surface 12 of the CS substrate 10 to establish the first and second coupling interfaces INT1 and INT2 at or substantially at the measurement plane MP. In an example, the movable substrate holder 80 is conveyed over the upper surface 71 of the support plenum 70 using conveying elements 73 such as rollers, wheels, sliders, bearings, etc. In an example, the CS substrate 10 is supported by the movable substrate holder 80 at an interior lip 82 that supports an outer (perimeter) portion of the top surface 12 of the CS substrate. In an example, the plane of the interior lip 82 defines an example measurement plane MP. Thus,
Note that the interior lip 82 of the movable substrate holder 80 defines a stop member for limiting the vertical movement of the CS substrate 10 when a vacuum is applied to the CS substrate via the vacuum system 91.
Hybrid System Employing a Single Index-Matching Fluid
An example embodiment of the hybrid system 20 such as shown in
If the index-matching fluid is chosen based on EPCS measurement considerations, the index matching fluid has a refractive index nf that is substantially higher (e.g., by 0.1 or more) than the surface refractive index ns of CS substrate to facilitate coupling of light into the guided modes and to obtain good fringe contrast in the captured TM and TE mode spectra.
On the other hand, this level of refractive index contrast (difference) Δn between refractive indices of the index-matching fluid 5 and the surface 12 of the CS substrate 10 causes significant surface scattering at the coupling interface INT2 from beam deflection at the index mismatch associated with the micro-roughness of the surfaces. This is problematic for the accurate extraction of retardation and stress measurements at moderate depths based on receiving and processing scattered light from the CS substrate. The high degree surface scattering produces a “fireball”, e.g., a large bright spot on the image of the scattered light beam where the pixels 247 of the digital detector (CCD camera) 246 are saturated with photons. This results in the loss of a substantial amount of stress-related information. Well-polished surfaces or pristine surfaces (such as formed by fusion drawing) tend to have less scattering.
If the index-matching fluid nf is approximately matched to (e.g., being similar, slightly higher, or slightly lower than) the surface refractive index ns of the CS substrate 10 to ensure low surface scattering, the fringe contrast in the mode spectrum 160 is usually poor when there is a steep change in the refractive index near the surface, e.g., such as the spike region R1 (see
If the index-matching fluid 5 is chosen to have a refractive index nf lower than the substrate (bulk) refractive index nB of the CS substrate 10 (which also usually means lower than the surface refractive index), then the thickness of the index-matching fluid must be very small (e.g., less than 0.4 micron) to enable light coupling into the waveguide modes of the near-surface portion (spike region R1) of the NSWG 18 for the surface CS measurement. The small thickness is also required for measuring the critical angle for coupling light that travels in the deep region R2 between the surface spike region R1 and the bulk region R3. This is difficult to achieve consistently in a production environment due to issues with small particle contamination. These issues cause problems for accurately measuring the surface (compressive) stress S(0) and the “knee stress” Sk at the bottom of the surface refractive-index spike region R1 for dual IOX Li-containing glasses and glass ceramics.
It turns out a single index-matching oil 5 for both EPCS and LSP measurements can be used under select conditions wherein the spike region R1 of the CS substrate 10 has a normalized slope Sn=|(λ/n)dn(z)/dz|<0.0005, or more preferably Sn<0.0004, where λ is the measurement wavelength and n(z) is the index of refraction of the CS substrate 10 at the measurement wavelength.
In one embodiment, an index-matching fluid 5 having a refractive index nf that is higher (greater) than the surface refractive index ns of the CS substrate 10 glass by amounts Δn=nf−ns in the range from 0.02 to 0.06 is found to produce adequate measurement results for both the EPCS and LSP measurements. When Sn<0.0004, it is preferred that Δn be in the high end of the above-stated range, e.g. from 0.05 to 0.06.
In one aspect of the invention, the measurement wavelength λA for the EPCS measurement is reduced to reduce the normalized slope Sn to more readily satisfy the above-described conditions. In one example, the measurement wavelength λA of the EPCS measurement is shorter than the measurement wavelength λB of the LSP measurement by 5% or more, to help achieve a smaller normalized slope Sn. In an example, one or more light blocks (not shown) can be selectively positioned on the beam path of the EPCS sub-system 100 to preferentially block light rays propagating at larger incidence angle corresponding to higher effective indices. This enhances the contrast of the captured TM and TE fringes of the guided modes for the near-surface spike region R1 of the NSWG 18.
In another embodiment, the surface spike region R1 may have normalized slope Sn>0.0005. In an example, the index-matching fluid may be selected to have at the EPCS measurement wavelength λB a refractive index nf very close to the effective refractive index at the z location zk at the knee KN, i.e., at the bottom of the spike region R1. In this case, nf≈ncrit, where ncrit is the refractive index associated with the critical angle of the spike region, i.e., the angle below which light does not travel as a guided wave within the spike region R1
In many cases of practical interest, the difference in effective index between the TM and the TE guided wave at the location corresponding to the bottom of the surface spike region R1 is relatively small. For example, in most cases of practical interest the difference is less than 0.0006 refractive-index units (RIU), and most often it is between 0.00015 and 0.0005 RIU. In an example,
0.0001≤|ncritTM−ncritTE|≤0.0006.
In some examples, it is adequate to specify that nf≈ncrit, meaning that noil≈ncritTM and/or noil≈ncritTE. To be more specific, nf is not substantially smaller than the smaller of the TM and TE critical indices, and would also not be significantly greater than the largest of the TM and TE critical index. Thus, in an example (and to express the above mathematically):
min(ncritTM,ncritTE)−0.001≤noil≤max(ncritTE,ncritTE)+0.001
The upper limit in the equation immediately above is defined to reduce the chances of missing a fringe associated with the spike region R1 by making nf greater than the effective index of that fringe when the index-matching fluid is absent. Thus, to enable proper accounting for all modes for the purposes of accurately calculating of the depth of the surface spike region R1 (which in an example is defined by a potassium IOX process), it is preferred that nf be not significantly greater than the larger of the TM and TE critical indices nkneeTM, nkneeTE, but also ideally not significantly greater than the smaller of the two critical indices.
In one embodiment, the mode fringes in the TM and TE mode spectra associated with the spike region R1 are spaced far apart in effective index space, e.g., by more than 0.0015 RIU or preferably by more than 0.002 RIU or even more preferably by than 0.0025 RIU when there is significant effective-index difference between the effective index of the last fringe in a specific polarization state (TM or TE), and the corresponding critical index (ncritTM or ncritTE). In this embodiment, the index-matching fluid refractive index noil may be chosen closer to the higher of the two critical indices, and possibly higher than the greater one of them:
max(nkneeTM,nkneeTE)−0.0005≤noil≤max(nkneeTM,nkneeTE)+0.001
or
max(nkneeTM,nkneeTE)−0.0005≤noil≤max(nkneeTM,nkneeTE)+0.0005
These differences in effective index are easy to establish using the EPCS sub-system 100 by measuring the difference in locations of the critical angles, which corresponding to the intensity transitions 166TM and 166TE from bright total-internal reflection to dark (partial reflection) on the sensor, and/or fringe positions, and taking into account the calibration of the instrument (angle per RIU, or pixels per RIU, or spacing of points on the sensor plane per RIU).
In another embodiment having a more general application, the refractive index noil of the index-matching fluid is chosen closer to the lower of the TM and TE effective indices. This enables the capture of TM and TE fringes that may be close in effective index to the critical index, but may require relatively close proximity between the coupling surface 45A of the EPCS coupling prism 42A and the top surface 12 of the CS substrate 10 (e.g., a few wavelengths).
More specifically, in this embodiment it is preferred that
min(ncritTM,ncritTE)−0.001≤noil≤max(ncritTM,ncritTE)
or
min(ncritTM,ncritTE)−0.001≤noil≤min(ncritTM,ncritTE)+0.0005.
Furthermore, to reduce significant change in the shape of the critical-angle transition, it may be preferred that
min(ncritTM,ncritTE)−0.0005≤noil≤min(ncritTM,ncritTE)+0.0005
or even that
min(ncritTM,ncritTE)−0.0002≤noil
In some cases of practical interest, the guided mode having the lowest effective index has its effective index very close to that of the critical index, within about 0.0002 RIU. In this case, it may be ideal to also impose a stricter requirement for the index-matching fluid refractive index to be limited from above:
noil≤min(ncritTM,ncritTE)+0.0002
In cases where noil is smaller than at least one of the two critical indices, obtaining a high-contrast transition for proper measurement of the critical index ncrit may require the aforementioned close proximity between the coupling surface 45A of the EPCS coupling prism 42A and the top surface 12 of the CS substrate 10 (e.g., a few wavelengths). In an example, this close proximity is enabled by use of a vacuum system attracting the specimen toward the prism via the PV conduits 90 pneumatically connected to the PV source 92.
In another embodiment, a correction is made for a systematic error in the calculation of surface compressive stress S(0)=CS when the index-matching fluid refractive index noil is not significantly different from the effective indices of the guided optical modes that are used to calculate the surface compressive stress CS. In particular, such correction may be preferable to utilize when:
min(ncritTM,ncritTE)−0.01≤noil≤max(ncritTM,ncritTE)+0.01
In one example embodiment, the correction is prescribed by calibrating the systematic error, e.g., by comparison of the surface compressive stress CS measured using the preferred inventive dual-use index-matching fluid with the CS measured by using a more convention index matching fluid having a relatively large refractive index noil, such as an oil with noil=1.72 at λA=590 nm used for measuring a CS substrate 10 having a bulk refractive index nB in the range 1.45 to 1.55.
In a related embodiment, the systematic error may also be calibrated against the breadth of the TM and TE fringes 163TM and 163TE, as the breadth may be associated with the thickness of the index-matching fluid, and at the same time associated with the amount of systematic error in the measurement of the surface compressive stress CS. It should be noted that the systematic error would also depend on the index slope Sn of the refractive index profile of the surface spike region R1 of the CS substrate 10. This means that the systematic error can be defined for a particular type of CS substrate having a surface index slope Sn that falls within a relatively narrow range. Such a narrow range is typical for CS substrates that employ Li-based glass that has been strengthened using an IOX process.
Hybrid System Employing Two Different Index-Matching Fluids
An example embodiment of the hybrid system 20 employs two different index-matching fluids 5 (denoted 5A and 5B) for the EPCS and LSP sub-systems 100 and 200 respectively, with the two different index-matching fluids 5A and 5B having respective refractive indices nfA and nfB (or noil-A and noil-B).
Employing two different index-matching fluids 5A and 5B calls for keeping the two index-matching fluids separated so that they do not mix with each other. In one example discussed above in connection with
In another embodiment, a pressurized gas (e.g., air) is introduced into a small gap between the EPCS coupling prism 42A and the LSP coupling prism 42B to define an “air curtain” 30 (see
Hybrid System with Reduced Cross-Talk
Given the proximity of the EPCS coupling prism 42A and the LSP coupling prism 42B, cross-talk between the EPCS sub-system 100 and the LSP sub-system 200 can occur. Such cross-talk can reduce the accuracy of the stress measurement of each sub-system. The various embodiments for reducing (including eliminating) cross-talk described below can be used separately or in combination.
In one example, the EPCS detector system 140 for the EPCS sub-system 100 includes the aforementioned band pass filter 144 centered on the EPCS measurement wavelength λA. Meanwhile, the LSP detector system 240 for the LSP sub-system 200 includes a band pass filter 244 centered on the LSP measurement wavelength λB. In an example, the respective bandwidths of the band pass filters 144 and 244 are sufficiently narrow to substantially filter out the other sub-systems measurement wavelength. Since band pass filters can be made very narrow, (e.g., a few nanometers), just a small difference in the measurement wavelengths (e.g., 10 nm) would be more than sufficient to reduce or eliminate cross-talk using the band pass filters. In an example, the given band pass filter can be inserted anywhere between the corresponding coupling prism and detector system.
In another embodiment, a barrier that is optically opaque to the measurement EPCS and LSP wavelengths λA and λB is disposed between the EPCS coupling prism 42A and the LSP coupling prism 42B. In an example, the barrier takes the form of the isolation member 50 as discussed above in connection with
Coupling Prism Alignment
The hybrid system 20 provides the most accurate measurements when the EPCS and LSP coupling prisms 42A and 42B are aligned with respect to each other and with their coupling surfaces 45A and 45B residing in a common plane.
To achieve such alignment, the coupling prism assembly 40 employs the aforementioned prism support structure 46 is used. In an example of forming the prism support structure 40, the coupling surfaces 45A and 45B of the EPCS and LSP coupling prisms 42A and 42B are first ground and polished to a high degree of flatness and perpendicularity. With reference again to
With reference now to
In an example, the molded prism support structure 46 includes securing tabs 52 that include mounting holes 53 for securing the prism support structure 46 to the support plenum 70 (see also
In an example, the prism support structure 46 includes sections that are movable with respect to one another so that the EPCS and LSP prisms 42A and 42B can be moved relative to one another, e.g., axially or the z-direction as shown in
Reducing Substrate Warp
The CS substrate 10 can be large enough that it can warp to the point where making accurate EPCS and LSP stress measurements becomes problematic. In particular, a warped CS substrate 10 can make it difficult to establishing the EPCS and LSP coupling interfaces INT1 and INT2 needed for making the EPCS and LSP measurements.
With reference again to
The PV bars 90 are commercially available and can be configured for reducing warp as shown in
In some cases, it may be desirable that at least one of the EPCS and LSP coupling prisms 42A and 42B be capable of being adjusted independent of the other. In this case, the coupling prism assembly 40 can comprise two separate prism support structures 46, with one or both of them being adjustable. In one example, the EPCS coupling prism 42A is adjustable in the z-direction to optimize the contrast of the TM and TE mode fringes in the mode spectrum. This can be accomplished by using a single-axis micro-positioner operably attached to the prism support structure 46 that holds the EPCS coupling prism in a movable configuration.
Processing EPCS and LSP Measurements
Processing LSP Measurements
In an example, the system controller 400 is configured (e.g., with software) to process the LSP image 248 to extract the “second” or LSP stress characteristics obtained from the LSP sub-system 200. This includes digitally characterizing the contour of the LSP image 248 using a Gaussian blurred Otsu thresholding is performed as part of the contour detection method to facilitate the calculation of optical retardation vs. depth (OR vs. D).
The digital LSP image 248D is largely comprised of very bright pixels and pixels with little to no exposure. With reference to
With reference now to
Thus, the threshold LSP image 248T and the LSP image contour 248C are used to define a “mask” that identifies a portion or portions of the captured or Gaussian-smoothed LSP image 248B to be used for calculating the optical retardation OR as a function of depth (D) into the CS substrate 10, as explained above.
CS Substrate Thickness Extraction and Beam Angle Calculation
By looking at the edge of the CS substrate 10 along the direction of propagation of the focused LSP light beam 216F, the thickness of the CS substrate 10 as seen by the digital detector 246 of the LSP detector system 240 can be highlighted, as shown in
TH=x/{Cos(45°)
where x represents the path length in the plane of the digital detector 246.
Once the thickness TH is calculated, the propagation angle A of the focused LSP light beam 216F within the CS substrate (see
A=Arc Tan(W/TH)
where W is the horizontal distance between the center cross C of the image contour 248C and the lower right (LR) critical point of the image contour as obtained from the contour detection method described above. Once the processed area is selected, the digital detector 246 records several images 248 as a function of input polarization. The optical retardation information as a function of depth into the CS substrate is then extracted using techniques known in the art.
Lock-in Detection Method
The lock-in detection method is a signal analysis technique that has proven very adept and fast at retrieving a signal that is obscured with noise. For this method to work, the period of the signal must be known.
The measurement (detector) signal SB from the LSP sub-system 200 has a period that depends on the rate of polarization rotation by the optical compensator 230. When using a rotating half-wave plate 234H in the optical compensator 150, one full rotation corresponds to four oscillations of the polarization state of the scattered light 216S.
The derivation of the lock-in method as applied to the LSP measurement signal SB=s(t) is as follows, where t is time. Consider the LSP measurement signal s(t) to be centered around zero and having an amount of noise (“noise factor”) N. The measurement data D(t) received by the system controller 400 can be represented as:
D(t)=s(t)+N
The measurement signal s(t) can be generalized in the form
s(t)=A cos(ƒt+φ)
where φ is the phase value to be extracted and ƒ is the known frequency of the signal. This signal can be “locked” into by multiplying it with a generic test wave of an equal and negative period (and arbitrary phase) W(t)=cos (−ƒ−θ) to yield the following equations:
The first two terms of the equation for D(t)*W(t) immediately above oscillate according to the time variable t. The final term, however, is a constant that can be extracted through strong low-pass filtering of the product wave. Since the average of a wave approaches the offset value of that wave over multiple oscillations, this is achieved by averaging the product wave.
This approximation incurs a slight amount of error if the measurement signal s(t) does not have many oscillations (e.g. less than one full oscillation) or if the signal has a non-integer number of half-cycles. This error can be reduced by taking the average of the signal over only the largest amount of half-cycles in the signal. For example, if the signal has about 3.7 oscillations, then take the average of the signal up to 3.5 cycles.
Once the low-pass filtering is performed using known means, the product D(t)*W(t) is reduced to the constant term [A/2]cos(−θ+φ). Recall that φ is the desired phase value, and θ is the arbitrary phase of the test wave. Hence, if θ is incremented through a series of numbers, the constants resulting from the low-pass filtering of the product wave for each increment will oscillate according to the non-time-varying cosine function [A/2]cos(−θ+φ). This cosine wave has a wave number of −1, an amplitude of A/2, and a phase of φ. Knowing this, a cosine can be fit to these constants (e.g., using least-squares fitting), and the phase φ can be extracted. The amplitude of the signal A can also be extracted.
The lock-in method for signal extraction has proven to be much faster than a regular sine fitting.
The lock-in method removes the necessity of predicting the sine parameters for fitting. The only fitting performed is that of the cosine wave to the low-pass filtering constants, which is so constrained that it almost never produces a bad fit. If sine fitting is used, however, it has been found that it performs much more accurately when the sine wave that is fitted to the data has a constant period. If the period can be fitted along with the other parameters, the processing time takes longer and the results are often not as accurate.
Noise Reduction in the LSP Measurement
The extraction of second stress characteristics using the LSP measurements from the LSP sub-system 200 consists of two main parts—a data acquisition part and data analysis part. In the data acquisition part of the measurement, the scattered light 216S is imaged as a function of the input polarization state of the initial LSP light beam 216 from the LSP light source 212. The imaging is achieved by recording at the digital detector 246 the intensity of scattered light from features (e.g., particles, refractive index variations) within the body CS substrate 10 due to the IOX process or processes.
The recorded images 248 are processed by the system controller 400 to extract the intensity along the laser beam, which is analyzed against the input polarization to extract the amount of optical retardation between two orthogonal states of the light beam. The stress profile is reconstructed by modeling the observed retardation. As a result, the quality of LSP measured stress profile is fundamentally limited by the noise in the imaging process, which is typically dominated by laser-based noise. One example of such laser-based noise is speckle, which originates from the high degree of coherence of the LSP light source 212, and imperfections in the optical surfaces (roughness, flatness, etc.) and volume properties of the optical elements (impurities, inhomogeneity and heterogeneity of density, etc.).
During propagation of the LSP light beam 216 through the LSP sub-system 200, interactions of the light (laser) beam 216 with system imperfections result in random amplitude and phase variations within the light beam wavefront. When the LSP light beam 116 is coherently imaged by Rayleigh scattering, wavefront distortions lead to a static interference pattern in the image plane that is called a speckle pattern, which is characterized by large intensity variations with high spatial frequencies superimposed on the desired signals. Intensity deviations from the desired signals are considered as noise in an LSP measurement. To reduce the effect of laser speckle, the imaging can be averaged over independent speckle patterns by modulation of polarization, amplitude or phase in the beam wavefront.
In one embodiment, laser-based noise is reduced in the LSP sub-system 200 by passing the initial light (laser) beam 216 through a movable light diffuser 222, which in an example can comprise a holographic diffuser. This “stirs” the light beam rays within the diffusing angle depending on the local structure of the diffuser. To minimize the beam divergence caused by this “ray stirring,” the light diffuser 222 is placed in the image plane of a Keplerian telescope configuration, as shown in the example configuration of
Mitigating the divergence of the LSP light beam 216 after undergoing light diffusion provides more efficient (i.e., less aberrated) focused LSP light beam 216F at the CS substrate. Using the moving light diffuser 222, variations the laser-based noise (e.g., speckle pattern) at the digital detector 246 are produced at the rotational velocity vD of the spinning diffuser. The maximal effect of noise averaging is achieved at the vDτC>1 condition, where τc is the exposure time of the digital detector 246. This condition also eliminates a potential blinking in the imaging caused by optical transmission variations across the light diffuser 222. Implementation of diffuser-based noise reduction improves the measurement of the optical retardation. This is illustrated in
Another way to reduce noise is by moving the substrate.
Shifting the OR Plot Using the Bend Points and CS Substrate Mid-Plane
Since the location of the surface 12 of the CS substrate 10 can be difficult to determine from the LSP images 248, the stress profile can be shifted into position based on the general shape of the retardation curve (OR vs D). The OR retardation curve has two bend points where the derivative is zero. An example actual OR vs. D curve is shown in
If the stress profile is symmetric, then the two bend points BP1 and BP2 should also be symmetric around the mid-plane MP of the CS substrate (see
Shifting the OR Plot Using Curve Fitting
An alternate method of extracting the DOC for a symmetric stress profile involves analyzing the shape of the retardation profile, i.e., the OR vs. D curve. If the thickness TH of the CS substrate is known and the relative positions of the bend points BP1 and BP2 can be determined through polynomial fittings, then the depth of compression DOC of the CS substrate can be determined by expression:
DOC=[TH−(BP2−BP1)]/2
where BP1 and BP2 are the relative depth positions of the bend points.
Curve Fitting for the OR Vs. D Curve
An embodiment of the disclosure is directed to methods obtaining an excellent fit to the data of the OR vs D curve. The methods include employing a combination of linear and quadratic functions to obtain the curve fit. This method is referred to below as the LinQuad method.
One can extract the corresponding retardation and fit it to the raw data of interest to recreate the stress profile. Here, C represent the normalized modeling concentration of ions in the CS substrate. Their expressions are as follows.
where di is the depth of the linear region, dc is the depth of the curved region, C0 is a constant multiplier and t is the CS substrate thickness.
An alternate expression is given by:
Here, CT is the central tension of the stress profile, and
is a (partially arbitrary) constant of around
The true LinQuad function is defined above, w here only dc, dl, C0 are fit. However, this latest expression for σ(x) allows a fourth parameter—namely the central tension CT—to vary, which can help the function fit the data more closely.
Power-Spike Function
A power-spike function is defined as:
where CTsp is the central tension of the spike in the spike region R1, mid is half of the thickness TH, CSsp is the compressive stress of the spike, and DOLsp is the depth of layer for the spike. The parameter Leff is an effective length (depth) of the spike region R1. This function is a stitching of a power profile with two error function spikes at the ends. The CSsp and DOLsp values are specific to each glass type and are entered as a constant. The only parameters that need to be fitted are the power of the function p and the peak central tension CTp.
Removing Systematic Error to Conform with a Symmetric Stress Profile
The stress profile of the CS substrate using the LSP measurement data is obtained by differentiating the OR vs. D curve. As such, a symmetric stress profile will always correspond to an asymmetric OR vs. D curve. However, systematic error from various components in the LSP sub-system 200 can introduce a symmetric component into the OR vs. D retardation data, thereby hindering the accurate extraction of the stress profile. This effect can be mitigated by decomposing the retardation data into symmetric and anti-symmetric components, and only fitting the anti-symmetric portion (i.e., the asymmetric data points).
Given a optical retardation OR in the form of a function ƒ(x), the decomposition can be achieved as follows.
ƒ(x)=ƒs(x)+ƒα(x)
where ƒs and ƒα are the symmetric and anti-symmetric components of the retardation ƒ, and expressed by the following equations:
Adjustable Fitting Regions for Accurate CT and DOC
A single fit to the OR v. D curve may not always be adequate to accurately determine both the central tension CT and the depth of compression DOC. This is because scattering from the LSP coupling prism 42B or the coupling interface INT2 can hinder data collection close to the top surface 12 of the CS substrate 10.
In an example, the fit to the OR vs. D curve is performed using fits to separate regions of the curve respectively associate with the central tension CT and depth of compression DOC and adjust the fitting range of the OR data for accurate CT and DOC extractions.
Simultaneous EPCS and LSP Measurement Considerations
One method of achieving good precision for the measurement of the depth of compression (DOC) using the LSP sub-system 200 is to press the CS substrate 10 against a stop surface (e.g., the support plenum 70) to ensure that the top surface 12 of the CS substrate 10 is co-planar with a pre-defined surface that can be assigned a depth of z=0. This pressing can be achieved by either pushing the CS substrate 10 against the stop, or by applying a vacuum such that the ambient atmospheric pressure provides the force to push the top surface 12 of the CS substrate 10 into place at z=0 (see e.g.,
On the other hand, achieving sharp (i.e., high contrast) mode spectrum 160 using the EPCS sub-system 10 to obtain an accurate stress measurement of the near-surface region R1 of the NSWG 18 also usually requires good CS substrate flatness in the EPCS measurement area, which may be also achieved with the use of the vacuum system 91.
Due to the EPCS and LSP measurement areas being at different locations of the CS substrate, applying vacuum at the LSP measurement area can in some case deform the CS substrate at the EPCS measurement area, and result in sub-optimal, or even very poor flatness or significantly deformed surface in the EPCS measurement area. This results in an EPCS mode spectrum 160 that has poor contrast and is “out of focus”. These conditions can lead to decreased accuracy and decreased precision, as well as a failure to measure because the poor contrast can cause the system controller to fail to identify some of the target features of the mode spectrum 160 used to perform the stress calculations.
In an example embodiment, the EPCS detector system 140 of the EPCS sub-system 100 utilizes adaptive focusing to enable proper alignment of the CS substrate 10 on the support plenum 70 for the best (most precise) DOC measurement and near-surface stress measurements using the EPCS sub-system when the CS substrate is aligned for a best LSP measurement for the LSP sub-system 200.
In one embodiment illustrated in
The position of the axial movable focusing lens 142 can be monitored electronically by the system controller 400 to correct the EPCS sub-system calibration by accounting for the “optical path length” or OPL, e.g., the distance from the focusing lens 142 to the digital detector 150. In one embodiment, the accounting can be simplified as long as the OPL does not fall outside of a pre-defined acceptable range, so that the original calibration remains accurate. In another embodiment, the calibration is corrected based on the OPL, and the surface stress S(0)=CS and/or the depth of layer DOL is calculated based on the corrected calibration.
In another embodiment, the focusing lens f1 has variable effective focal length which is actively controlled by the system controller 400 to obtain a high-contrast mode spectrum 160 when the specimen is aligned to ensure most precise or accurate measurement of the depth of compression DOC for the LSP sub-system 200. The variable focal length focusing lens 142 can comprise a compound lens (similar to photographic multi-component lenses with more than one optical element), or may be otherwise comprise an adaptive lens, such as a fluid-filled lens where varying the pressure of the fluid changes the shape of the lens and thus the focal distance. When using variable focal length lens 142, shifting the position of the focusing lens 142 may not be necessary, as changing the focal length can in many cases be adequate to compensate for the deformation of the specimen shape in the EPCS measurement area as a result of aligning the specimen for best measurement in the LSP-measurement area.
In another embodiment, the variation of effective focal length of the focusing lens 142 may be enabled by an adaptive lens surface in the form of a mirror surface that may be combined with a fixed simple lens to produce a net effective focal length that can be varied over a range sufficient to produce a high-contrast mode spectrum 160 even when the CS substrate alignment is optimized for the LSP sub-system 200.
Since the deformation in the CS substrate 10 tends to not be very large, the change in refractive power for the variable focus focusing lens 142 need not be particularly large to compensate. In an example, the focal length of the focusing lens 142 can be changed by up to 15%, or in another example up to 10%.
On the other hand, when the CS substrate 10 has thickness less than 0.6 mm, it may be necessary to change the refractive power by more than 15%, and by as much as 20% or even 25%. Thus, in an example, the adaptive system for changing the focal length of the focusing lens 142 is configured to change the focal length over a focal length range that represents 25% of the average focal length, although in many cases a range of 20%, 15%, or even 10% of the average focal length may be adequate.
Similarly, since for measurements of flat CS substrates, the focusing lens 142 system is focused on infinity, when the focusing lens 142 has fixed focal length and the position of the focusing lens is axially adjusted to produce a high-contrast mode spectrum 160, the range of axial positions that are accessible by the focusing lens would ideally represent about 25% of the focal length of the lens, although in some cases 20%, 15%, or even 10% of the focal length may represent an adequate range of positions.
If the contrast of the features of interest (e.g., the TM and TE mode lines 163TM, 163TE, the TM and TE critical angle transitions 166TM, 166TE, etc.) in the mode spectrum 160 is deemed adequate, the measurement proceeds as usual. If the contrast of the features of interest is deemed inadequate, then a focusing lens 142 of a different focal length is moved into the optical path of the reflected light beam 116R and a new mode spectrum 160 is captured by the EPCS digital detector 150 and the contrast analyzed. This process repeats until a mode spectrum 160 of adequate contrast is obtained.
In an example, differences in the focal lengths of the focusing lenses 142 may be set by the total desired range of focal-length coverage and the total number of lenses on the support member. In one example, there are six focusing lenses supported by the support member, with the focusing lenses covering a range that is between 20% and 30% of the average focal length for the entire set of focusing lenses, and the spacing of focal lengths is between 3% and 7% of the average focal length.
In another example, the focal lengths are spaced unevenly, such that the spacing of each pair of neighboring focal lengths is approximately a fixed percentage of the average of the neighboring focal lengths, where that percentage is between 2% and 20%, and more preferably between 3% and 10%.
In another related embodiment, some or all of the focusing lenses 142 comprise Fresnel lenses. In another embodiment, the focusing lenses 142 need not have different focal lengths, but may be positioned on the movable support member in such a way that when the focusing lens of choice is placed in the optical path, its distance from the digital detector 150 is different than for the other focusing lenses. In this embodiment, obtaining a spectrum having adequate contrast for the features of interest is guaranteed not necessarily by having a complete set of discrete densely spaced custom-chosen focal lengths, but by a set of distances to the digital detector and/or available focal lengths. This can reduce the cost of the EPCS sub-system 100 by utilizing standard off-the-shelf focusing lenses, and positioning each focusing lens to produce a sharp image for a specific range of warp/curvature of the CS substrate 10.
In an example, the system controller 400 can be configured to select one of the focusing lenses 142 based on a measurement of the contrast of the features of interest of the captured mode spectrum 160.
In another embodiment, measurements can be made by using two or three preferred mode spectra 160 having the best contrast among all captured mode spectra, and then a preferred result may be calculated as an average of the two or three preferred mode spectra. In an example, the preferred result may be calculated as a weighted average of the two or three preferred mode spectra. In a related example, the weight for each preferred spectrum may be proportional to the contrast of a feature of interest the preferred mode spectrum.
Using an Independent Stress Measurement for Stress Measurement Calibration
The EPCS sub-system 100 can be very good at obtaining a high-contrast mode spectrum 160 for a CS substrate formed an IOX process using a Li-based glass, e.g., wherein K ions replace Li and/or Na ions from the glass in the near-surface region. This in turn allows for very good measurements of the knee stress CSk by measuring the birefringence based on the relative positions of the TM and TE critical-angle transitions 166TM and 166TE (see
On the other hand, the EPCS measurement of the knee stress CSk usually has lower relative precision than the measurement of the surface stress S(0). In particular, the standard deviation of the measurement of the knee stress CSk is usually several % of its average value, whereas the standard deviation of the surface stress S(0) is usually on the order of 1% to 2% of its average value. In addition, the value of the knee stress CSk as obtained simply as a ratio of the birefringence B of the detected critical angle and the stress-optic coefficient (SOC) differs slightly from the value of the knee stress CSk as obtained from a destructive RNF measurement of the stress profile.
When the EPCS measurement of the knee stress CSk is believed to be less accurate than it could be or should be, it can be due to a systematic error in the measurement of the birefringence of the critical angle. This systematic error can be caused by the TM and TE modes lines 163TM and 163TE being too close to the TM and TE critical angle transitions 166TM and 166TE and further by the particular shapes of the TM and TE refractive index profiles.
When making quality-control measurements, such systematic errors are mitigated by calibrating the EPCS-based measurements of the knee stress CSk measurement with corresponding independent reference stress measurement, which may be a destructive measurement on a CS substrate taken from a set of CS substrates formed using the identical process or from the same batch during the same identical process. In an example, this is accomplished by applying a calibration multiplier Kcal based on the independent measurement via the relationship:
CSk(EPCS,calibrated)=Kcal·CSk(independent).
In an example, the calibration multiplier Kcal can be used as a general calibration factor for the stress profile calculated by the EPCS sub-system 100 via the equation:
S(EPCS,calibrated)=Kcal·S(original)
where S(orig) is the originally measured (uncalibrated) stress profile S(z).
Tension Zone Stress Profile Extraction
An IOX process used to form a CS substrate 10 forms a compression zone that defines the NSWG 18. This compression zone extends into the substrate and reaches a zero value, which defines the depth of compression DOC. At the DOC, the compression zone ends and a tension zone begins.
If the stress profile in the tension zone can be accurately extracted, it can serve as a powerful tool to help extract a substantially accurate representation of the stress profile in the compression zone. This can be done by exploiting force-balancing of the stress in the entire CS substrate 10 or half of the CS substrate (i.e., so-called “half force balancing”).
In one embodiment, besides the area of the stress profile in the tension zone (which is represented by the depth integral of tensile stress from one depth of compression to the opposite-side depth of compression), a reliable value of the slope of the stress profile at a depth of reliable slope extraction is also obtained from the LSP-based measurement.
In an example, the depth of reliable slope extraction may be the depth of compression DOC. In the compressive-stress region, a surface compressive stress is determined by the EPCS method. In some cases, a portion of the compressive-stress profile is also extracted from EPCS method using prior-art techniques such as IWKB, or linear-profile, erfc-shaped profile, exponential-profile, or a LinQuad profile approximation when there are not enough guided modes for reliable IWKB extraction. The EPCS-based method then provides a target point of connection, either at the surface with a surface stress value S(0), or at a deeper connection point (for example, the knee depth zk; see
Nonetheless, this value of the knee stress CSk can provide an adequate starting point for pursuing extraction of the stress profile in the compression zone (e.g., substantially zones R1 and R2 in
In a particular example, the second connection point can be the depth of compression DOC, but it need not be. The first approximation of the stress profile S(z) is integrated. If the stress profile is asymmetric, EPCS measurements may be performed on both sides of the specimen, and first approximations of the stress profile obtained as above for each side. If the stress profile S(z) is symmetric by design and implementation, then it may be assumed that the back side of the specimen has the same stress profile in the back-side compression region as the front-side compression region.
The first approximation of the stress profile from both front-side and back-side compression zones is integrated with respect to depth over the respective compression zones, and compared to the depth integral of tension over the tension zone. If the difference is larger in absolute value than a pre-defined acceptable limit, a corrective step is performed to reduce the difference. In an example, the pre-defined acceptable limit is 5% of the tension-zone stress area, but progressively better acceptable limits include 3%, 2%, 1%, and 0.5%.
The acceptable limit may be determined based on an estimate of the degree of accuracy of extraction of the tension-zone stress profile. In one embodiment, several first approximations for the stress profile are obtained by different methods, all of which match the knee stress CSk at the first connection point, and the stress value and stress slope at the second connection point, say the depth of compress DOC. Different types of first approximations may include second, third, and 4th order polynomials, an exponential profile, an erfc-shaped profile, a Gaussian profile, and a Lorentzian profile. Then, for each of these first approximations, the difference is found between the stress area in the first-approximation compression zone, and the stress area in the tension zone extracted using LSP-based measurement. Then a linear combination of these first-approximation stress profiles is found, such that the stress area of the linear-combination stress profile equals the tension-zone stress area.
In another embodiment, the limited accuracy of the EPCS-based measurement of the knee stress CSk is taken into account by allowing a range of the knee stress CSk to be targeted around the initial EPCS-based estimate of the knee stress CSk. In a first approximation of the compressive-stress portion of the stress profile, the connection is made with the EPCS-based initial value of the knee stress CSk, using a preferred target shape function for the interpolated region of the compression zone. In an example, the preferred target shape is a second-order polynomial.
After each iteration, the stress area of the compressive-stress profile from the two combined compression zones (one on each side of the specimen) is subtracted from the stress area of the tension zone. If the difference is larger in absolute value than a target pre-defined acceptable limit, then the target value of the knee stress CSk may be changed within a pre-defined acceptable range for the knee CSk as determined in accordance with an estimated precision of the knee stress measurement available from the EPCS-based method.
In an example, an estimated knee stress precision is about 10 MPa, though in some cases it is better at 7 MPa or 5 MPa or 3 MPa. When no surface spike is present, and no guided modes are available, then the same technique may be used to connect to a target surface stress S(0) that is allowed to vary in a range determined by the precision of the surface stress measurement.
In an example, the range for acceptable values for the target surface stress S(0) or knee stress CSk may be up to 6 standard deviations wide, e.g., 3 standard deviations on either side of the measured value of surface stress or the knee stress. In one embodiment, the target surface value S(0) need not be varied iteratively, but may be determined by algebraic calculation, utilizing the measured difference in area between the first-approximation stress profile and the tension-zone stress profile and the preferred functional form chosen for the interpolated portion of the compressive-stress region.
It will be apparent to those skilled in the art that various modifications to the preferred embodiments of the disclosure as described herein can be made without departing from the spirit or scope of the disclosure as defined in the appended claims. Thus, the disclosure covers the modifications and variations provided they come within the scope of the appended claims and the equivalents thereto.
This Application claims the benefit of priority under 35 USC § 119(e) of U.S. Provisional Patent Application Ser. No. 62/822,437, filed on Mar. 22, 2019, and which is incorporated by reference herein in its entirety.
| Number | Name | Date | Kind |
|---|---|---|---|
| 356760 | Goldie | Feb 1887 | A |
| 4655589 | Cestaro et al. | Apr 1987 | A |
| 8854623 | Fontaine et al. | Oct 2014 | B2 |
| 9534981 | Roussev et al. | Jan 2017 | B2 |
| 9696207 | Roussev et al. | Jul 2017 | B2 |
| 9897574 | Andrews et al. | Feb 2018 | B2 |
| 10180416 | Roussev et al. | Jan 2019 | B2 |
| 20090119808 | Giakos | May 2009 | A1 |
| 20150116713 | Roussev | Apr 2015 | A1 |
| 20180024016 | Wang | Jan 2018 | A1 |
| 20180274997 | Shang et al. | Sep 2018 | A1 |
| 20190033144 | Andrews et al. | Jan 2019 | A1 |
| 20190219463 | Orihara | Jul 2019 | A1 |
| 20200132548 | Furnas | Apr 2020 | A1 |
| Number | Date | Country |
|---|---|---|
| 103644990 | Mar 2014 | CN |
| 203587256 | May 2014 | CN |
| 203587939 | May 2014 | CN |
| 104296903 | Jan 2015 | CN |
| 104296904 | Jan 2015 | CN |
| 104316232 | Jan 2015 | CN |
| 104330359 | Feb 2015 | CN |
| 104330360 | Feb 2015 | CN |
| 205027468 | Feb 2016 | CN |
| 205049270 | Feb 2016 | CN |
| 105424242 | Mar 2016 | CN |
| 205120285 | Mar 2016 | CN |
| 205209671 | May 2016 | CN |
| 206573478 | Oct 2017 | CN |
| 206583407 | Oct 2017 | CN |
| 206583556 | Oct 2017 | CN |
| 105203240 | Jan 2018 | CN |
| 207232491 | Apr 2018 | CN |
| 207600635 | Jul 2018 | CN |
| 2007121175 | Oct 2007 | WO |
| Entry |
|---|
| Aben et al; “On Non-Destructive Residual Stress Measurement in Glass Panels” ; Estonian Journal of Engineering, 2010, 16, 2, pp. 150156. |
| Aben et al; “Modern Photoelasticity for Residual Stress Measurement in Glass”; Glasstress Ltd., 21 Akadeemia Tee,12618 Tallinn, Estonia; 1 Page. |
| Naba et al; “Non-Destructive Stress Measurement in Double Ion-Exchanged Glass Using Optical Guided-Waves and Scattered Light”, Journal of the Ceramic Society of Japan 125 [11] 814-820 2017. |
| International Search Report and Written Opinion of the International Searching Authority; PCT/US2020/023879; dated Jul. 24, 2020; 9 Pages; European Patent Office. |
| Number | Date | Country | |
|---|---|---|---|
| 20200300615 A1 | Sep 2020 | US |
| Number | Date | Country | |
|---|---|---|---|
| 62822437 | Mar 2019 | US |
