The present invention relates to a hydro-generator plant of the type described in the preamble to the claim and which is intended for connection to distribution or transmission networks, hereinafter called power networks. The invention also relates to an electric generator for high voltage in a hydro-generator plant intended for the above-mentioned purpose. The invention further relates to a procedure for assembling such a plant and the manufacture of such a generator.
The magnetic circuits in electric generators usually comprise a laminated core, e.g. of sheet steel with a welded construction. To provide ventilation and cooling the core is often divided into stacks with radial and/or axial ventilation ducts. For larger machines the laminations are punched out in segments which are attached to the frame of the machine, the laminated core being held together by pressure fingers and pressure rings. The winding of the magnetic circuit is disposed in slots in the core, the slots generally having a cross section in the shape of a rectangle or trapezium.
In multi-phase electric generators the windings are made as either single or double layer windings. With single layer windings there is only one coil side per slot, whereas with double layer windings there are two coil sides per slot. By coil side is meant one or more conductors combined vertically or horizontally and provided with a common coil insulation, i.e. an insulation designed to withstand the rated voltage of the generator to earth.
Double-layer windings are generally made as diamond windings whereas single layer windings in the present context can be made as diamond or flat windings. Only one (possibly two) coil width exists in diamond windings whereas flat windings are made as concentric windings, i.e. with widely varying coil width. By coil width is meant the distance in arc dimension between two coil sides pertaining to the same coil.
Normally all large machines are made with double-layer winding and coils of the same size. Each coil is placed with one side in one layer and the other side in the other layer. This means that all coils cross each other in the coil end. If there are more than two layers these crossings complicate the winding work and the coil end is less satisfactory.
It is considered that coils for rotating generators can be manufactured with good results within a voltage range of 3-20 kV.
It is also generally known that connection of a synchronous machine to a power network must be via a Δ/Y-connected or step-up transformer, since the voltage of the power network is generally higher than the voltage it has hitherto been able to achieve with the electric machine. Thus this transformer and the synchronous machine constitute integrated parts of a plant. The transformer entails an extra cost and also has the drawback that the total efficiency of the system is reduced. If, therefore, it were possible to manufacture electric generators for considerably higher voltages, the step-up transformer could be eliminated.
Although the dominant known technology for supplying current from a generator to a high-voltage network, a concept which in the present application applies to the level of 20 kV and upwards, preferably higher than 36 kV, is for a transformer to be inserted between the generator and the power network, it is already known to attempt to eliminate the transformer and generate the high voltage directly out to the power network at its voltage level. Such generators are described, for instance, in U.S. Pat. Nos. 4,429,244, 4,164,672 and 3,743,867.
However, the machine designs according to the above publications do not permit optimal utilization of the electromagnetic material in the stator.
The object of the invention is thus to provide an electric generator which can be used in a hydro-generator plant for such high voltage that the above-mentioned Δ/Y-connected step-up transformer can be omitted, i.e. a plant in which the electric generators are intended for considerably high voltages than conventional machines of corresponding type, in order to be able to execute direct connection to power networks at all types of high voltage.
This object has been achieved according to the invention in that a plant of the type described in the preamble to claim 1 is given the special features defined in the characterizing part of this claim, in that a generator of the type described in the preamble to claim 34 is given the special features defined in the characterizing part of this claim, and in that a procedure of the type described in the preamble to claim 33 includes the special measures defined in the characterizing parts of respective claims.
Thanks to the solid insulation in combination with the other features defined, the network can be supplied without the use of an intermediate step-up transformer even at network voltages considerably in excess of 36 kV.
The fact that the solid insulation enables the windings to be arranged for direct connection to the high-voltage network, thus eliminating the step-up transformer, offers great advantages over known technology.
The elimination of the transformer per se entails great savings, for instance, and the absence of the transformer also results in several other simplifications and thus savings.
A plant of this type is often arranged in a rock chamber where, with conventional technology, the transformer is arranged either in direct connection with the generator in the rock chamber or above ground at a distance of several hundred meters and connected to the generator by a busbar system. Compared with the first alternative, elimination of the transformer enables the volume of the rock chamber to be greatly reduced. The fire risk entailed with an oil-insulated transformer is also eliminated therefore reducing the necessity for extensive fire-safety precautions such as special evacuation routes for personnel.
In the alternative in which the transformer is placed above ground the busbar system is more extended due to the longer distance between the generator and the transformer. Since the current in the busbars (normally with aluminium conductors) is considerable, in the order of 10-20 kA, the power losses are large. Moreover, busbar systems introduce a risk for 2- and 3-phase faults during which the currents are considerable.
With the present invention two major objectives are achieved:
The reduction in the number of electrical components achieved with the invention therefore means that the corresponding safety equipment can be omitted.
Furthermore, the rock chamber need not be blasted to allow laying of the busbar system, which entails a saving in rock chamber space of several thousand cubic meters.
The plant according to the invention also enables several connections with different voltage levels to be arranged, i.e. the invention can be used for all auxiliary power in the power station.
In all, the advantages mentioned above entail radically improved total economy for the plant. The plant cost, typically in the order of some hundred million SEK, is reduced by 30-50%. Operating economy is improved both by less need for maintenance and by an increase in the degree of efficiency by 1-1.5%. For an operating time of 8000 h/year, an output level corresponding to 150 MVA, a kWh price of SEK 0.20 and a useful service life of 30 years the gain would be approximately SEK 75-100 million per generator.
In a particularly preferred embodiment of the plant and generator respectively, the solid insulation system comprises at least two layers, each layer constituting essentially an equipotential surface, and also intermediate solid insulation therebetween, at least one of the layers having substantially the same coefficient of thermal expansion as the solid insulation.
This embodiment constitutes an expedient embodiment of the solid insulation that in an optimal manner enables the windings to be directly connected to the high-voltage network and where harmonization of the coefficients of thermal expansion eliminates the risk of defects, cracks or the like upon thermal movement in the winding.
It should be evident that the windings and the insulating layers are flexible so that they can be bent.
It should also be pointed out that the plant according to the invention can be constructed using either horizontal or vertical generators, which may be of either underground or aboveground type.
The above and other preferred embodiments of the invention are defined in the dependent claims.
The major and essential difference between known technology and the embodiment according to the invention is thus that this is achieved with a magnetic circuit included in an electric generator which is arranged to be directly connected via only breakers and isolators to a high supply voltage in the vicinity of between 20 and 800 kV, preferably higher than 36 kV. The magnetic circuit thus comprises a laminated core having at least one winding consisting of a threaded cable with one or more permanently insulated conductors having a semiconducting layer both at the conductor and outside the insulation, the outer semiconducting layer being connected to earth potential.
To solve the problems arising with direct connection of electric machines to all types of high-voltage power networks, the generator in the plant according to the invention has a number of features as mentioned above, which differ distinctly from known technology. Additional features and further embodiments are defined in the dependent claims and are discussed in the following.
Such features mentioned above and other essential characteristics of the generator and thus of the hydro-generator plant according to the invention include the following:
The use of a cable of the type described above allows the entire length of the outer sheath of the winding, as well as other parts of the plant, to be kept at earth potential. An important advantage is that the electric field is close to zero within the coil-end region outside the outer semiconducting layer. With earth potential on the outer sheath the electric field need not be controlled. This means that no field concentrations will occur either in the core, in the coil-end regions or in the transition between them.
The mixture of insulated and/or uninsulated impacted strands, or transposed strands, results in low stray losses.
The cable for high voltage used in the magnetic circuit winding is constructed of an inner core/conductor with a plurality of strands, at least two semiconducting layers, the innermost being surrounded by an insulating layer, which is in turn surrounded by an outer semiconducting layer having an outer diameter in the order of 20-200 mm and a conductor area in the order of 40-3000 mm2.
The solid insulation in a generator according to the invention also offers great advantages when constructing a hydro-generator plant. The absence of wet insulation means that the stator of the generator need not be completed at the factory but can instead be delivered in parts and assembled on site. A stator of the size under consideration here is large and heavy which has entailed transport problems with conventional designs where the roads must be reinforced and dimensioned for the vast weight. This problem is eliminated since the stator for a generator can be delivered in parts.
The invention thus also relates to the procedures as defined in claims 30 and 33, where this possibility is exploited when building a hydro-generator plant and manufacturing a generator, respectively.
The invention will be described in more detail in the following detailed description of a preferred embodiment of constructing the magnetic circuit of the electric generator in the hydro-generator plant, with reference to the accompanying drawings in which
In order to understand certain aspects of the advantages of the invention, reference is made initially to
The rotor 2 of the generator is also indicated in the schematic axial view through a sector of the stator 1 according to
The cables 6 are illustrated schematically in
A hydro-generator with a magnetic circuit of the type described above is shown in
The stator 1 of the generator 100 thus carries the stator windings 10 which are built up of the cable 6 described above. The cable 6 is unscreened and changes to a screened cable 11 at the cable splicing 9.
With a hydro-generator 100 according to the invention it is thus possible to generate extremely high electric voltages of up to approximately 800 kV. It is thus possible to electrically connect the hydro-generator 100 directly to a distribution or transmission network 110 with an intermediate step-up transformer or similar electric machine as is generally the case in conventional plants where equivalent generators are able at most to generate voltages of up of 25-30 kV.
It can also be seen from
A hydro-generator plant according to the invention is designed for operation either to generate electric voltage for the power network as described above, or as a pump plant, i.e. to be driven from the electric power network 110. The generator 100 then operates as a motor to drive the turbine 102 as a pump.
Thus, with the hydro-generator 100, no intermediate coupling of a step-up transformer is required. With the hydro-generator plant according to the present invention, therefore, several transformer and breaker units previously necessary are eliminated, which is obviously an advantage—not least from the aspects of cost and operating reliability.
Although the hydro-generator and the plant in which this generator is included have been described and illustrated in connection with an embodiment by way of example, it should be obvious to one skilled in that art that several modifications are possible without departing from the inventive concept. The generator may be earthed directly, for instance, without any impedance. The auxiliary windings can be omitted, as also other components shown. Although the invention has been exemplified with a three-phase plant, the number of phases may be more or less.
Number | Date | Country | Kind |
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9602079 | May 1996 | SE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCTSE97/00885 | 5/27/1997 | WO | 00 | 3/25/1998 |
Publishing Document | Publishing Date | Country | Kind |
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WO9745923 | 12/4/1997 | WO | A |
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336418 | Jun 1920 | DE |
372390 | Mar 1923 | DE |
386561 | Dec 1923 | DE |
387973 | Jan 1924 | DE |
406371 | Nov 1924 | DE |
425551 | Feb 1926 | DE |
426793 | Mar 1926 | DE |
432169 | Jul 1926 | DE |
433749 | Sep 1926 | DE |
435608 | Oct 1926 | DE |
435609 | Oct 1926 | DE |
436809 | Oct 1926 | DE |
441717 | Mar 1927 | DE |
443011 | Apr 1927 | DE |
460124 | May 1928 | DE |
482506 | Sep 1929 | DE |
501181 | Jul 1930 | DE |
523047 | Apr 1931 | DE |
568508 | Jan 1933 | DE |
572030 | Mar 1933 | DE |
584639 | Sep 1933 | DE |
586121 | Oct 1933 | DE |
604972 | Nov 1934 | DE |
629301 | Apr 1936 | DE |
673545 | Mar 1939 | DE |
719009 | Mar 1942 | DE |
846583 | Aug 1952 | DE |
875227 | Apr 1953 | DE |
975999 | Jan 1963 | DE |
1465719 | May 1969 | DE |
1807391 | May 1970 | DE |
2050674 | May 1971 | DE |
1638176 | Jun 1971 | DE |
2155371 | May 1973 | DE |
2400698 | Jul 1975 | DE |
2520511 | Nov 1976 | DE |
2656389 | Jun 1978 | DE |
2721905 | Nov 1978 | DE |
137164 | Aug 1979 | DE |
138840 | Nov 1979 | DE |
2824951 | Dec 1979 | DE |
2835386 | Feb 1980 | DE |
2839517 | Mar 1980 | DE |
2854520 | Jun 1980 | DE |
3009102 | Sep 1980 | DE |
2913697 | Oct 1980 | DE |
2920478 | Dec 1980 | DE |
3028777 | Mar 1981 | DE |
2939004 | Apr 1981 | DE |
3006382 | Aug 1981 | DE |
3008818 | Sep 1981 | DE |
209313 | Apr 1984 | DE |
3305225 | Aug 1984 | DE |
3309051 | Sep 1984 | DE |
3441311 | May 1986 | DE |
3543106 | Jun 1987 | DE |
2917717 | Aug 1987 | DE |
3612112 | Oct 1987 | DE |
3726346 | Feb 1989 | DE |
3728346 | Feb 1989 | DE |
PCTDE 9000279 | Nov 1990 | DE |
3925337 | Feb 1991 | DE |
4023903 | Nov 1991 | DE |
4022476 | Jan 1992 | DE |
4233558 | Mar 1994 | DE |
4402184 | Aug 1995 | DE |
4409794 | Aug 1995 | DE |
4412761 | Oct 1995 | DE |
4420322 | Dec 1995 | DE |
19620906 | Jan 1996 | DE |
4438186 | May 1996 | DE |
19020222 | Mar 1997 | DE |
19547229 | Jun 1997 | DE |
468827 | Jul 1997 | DE |
134022 | Dec 2001 | DE |
049104 | Apr 1982 | EP |
0493704 | Apr 1982 | EP |
0056580 | Jul 1982 | EP |
078908 | May 1983 | EP |
0120154 | Oct 1984 | EP |
0130124 | Jan 1985 | EP |
0142813 | May 1985 | EP |
0155405 | Sep 1985 | EP |
0102513 | Jan 1986 | EP |
0174783 | Mar 1986 | EP |
0185788 | Jul 1986 | EP |
0277358 | Aug 1986 | EP |
0234521 | Sep 1987 | EP |
0244069 | Nov 1987 | EP |
0246377 | Nov 1987 | EP |
0265868 | May 1988 | EP |
0274691 | Jul 1988 | EP |
0280759 | Sep 1988 | EP |
0282876 | Sep 1988 | EP |
0309096 | Mar 1989 | EP |
0314860 | May 1989 | EP |
0316911 | May 1989 | EP |
0317248 | May 1989 | EP |
0335430 | Oct 1989 | EP |
0342554 | Nov 1989 | EP |
0221404 | May 1990 | EP |
0375101 | Jun 1990 | EP |
0406437 | Jan 1991 | EP |
0439410 | Jul 1991 | EP |
0440865 | Aug 1991 | EP |
0469155 | Feb 1992 | EP |
0490705 | Jun 1992 | EP |
0503817 | Sep 1992 | EP |
0571155 | Nov 1993 | EP |
0620570 | Oct 1994 | EP |
0620630 | Oct 1994 | EP |
0642027 | Mar 1995 | EP |
0671632 | Sep 1995 | EP |
0676777 | Oct 1995 | EP |
0677915 | Oct 1995 | EP |
0684679 | Nov 1995 | EP |
0684682 | Nov 1995 | EP |
0695019 | Jan 1996 | EP |
0732787 | Sep 1996 | EP |
0738034 | Oct 1996 | EP |
0739087 | Oct 1996 | EP |
0740315 | Oct 1996 | EP |
0749190 | Dec 1996 | EP |
0751605 | Jan 1997 | EP |
0739087 | Mar 1997 | EP |
0749193 | Mar 1997 | EP |
0780926 | Jun 1997 | EP |
0802542 | Oct 1997 | EP |
0913912 | May 1999 | EP |
805544 | Apr 1936 | FR |
841351 | Jan 1938 | FR |
847899 | Dec 1938 | FR |
916959 | Dec 1946 | FR |
1011924 | Apr 1949 | FR |
1126975 | Mar 1955 | FR |
1238795 | Jul 1959 | FR |
2108171 | May 1972 | FR |
2251938 | Jun 1975 | FR |
2305879 | Oct 1976 | FR |
2376542 | Jul 1978 | FR |
2467502 | Apr 1981 | FR |
2481531 | Oct 1981 | FR |
2556146 | Jun 1985 | FR |
2594271 | Aug 1987 | FR |
2708157 | Jan 1995 | FR |
PCTFR 9800468 | Jun 1998 | FR |
123906 | Mar 1919 | GB |
268271 | Mar 1927 | GB |
293861 | Nov 1928 | GB |
292999 | Apr 1929 | GB |
319313 | Jul 1929 | GB |
518993 | Mar 1940 | GB |
537609 | Jun 1941 | GB |
540456 | Oct 1941 | GB |
589071 | Jun 1947 | GB |
666883 | Feb 1952 | GB |
685416 | Jan 1953 | GB |
702892 | Jan 1954 | GB |
715226 | Sep 1954 | GB |
723457 | Feb 1955 | GB |
739962 | Nov 1955 | GB |
763761 | Dec 1956 | GB |
805721 | Dec 1958 | GB |
827600 | Feb 1960 | GB |
854728 | Nov 1960 | GB |
870583 | Jun 1961 | GB |
913386 | Dec 1962 | GB |
965741 | Aug 1964 | GB |
992249 | May 1965 | GB |
1024583 | Mar 1966 | GB |
1053337 | Dec 1966 | GB |
1059123 | Feb 1967 | GB |
1103098 | Feb 1968 | GB |
1103099 | Feb 1968 | GB |
1117401 | Jun 1968 | GB |
1135242 | Dec 1968 | GB |
1147049 | Apr 1969 | GB |
1157885 | Jul 1969 | GB |
1174659 | Dec 1969 | GB |
1236082 | Jun 1971 | GB |
1268770 | Mar 1972 | GB |
1319257 | Jun 1973 | GB |
1322433 | Jul 1973 | GB |
1340983 | Dec 1973 | GB |
1341050 | Dec 1973 | GB |
1365191 | Aug 1974 | GB |
1395152 | May 1975 | GB |
1424982 | Feb 1976 | GB |
1426594 | Mar 1976 | GB |
1438610 | Jun 1976 | GB |
1445284 | Aug 1976 | GB |
1479904 | Jul 1977 | GB |
1493163 | Nov 1977 | GB |
1502938 | Mar 1978 | GB |
1525745 | Sep 1978 | GB |
2000625 | Jan 1979 | GB |
1548633 | Jul 1979 | GB |
2046142 | Nov 1979 | GB |
2022327 | Dec 1979 | GB |
2025150 | Jan 1980 | GB |
2034101 | May 1980 | GB |
1574796 | Sep 1980 | GB |
2070341 | Sep 1981 | GB |
2070470 | Sep 1981 | GB |
2071433 | Sep 1981 | GB |
2081523 | Feb 1982 | GB |
2099635 | Dec 1982 | GB |
2105925 | Mar 1983 | GB |
2106306 | Apr 1983 | GB |
2106721 | Apr 1983 | GB |
2136214 | Sep 1984 | GB |
2140195 | Nov 1984 | GB |
2150153 | Jun 1985 | GB |
2268337 | Jan 1994 | GB |
2273819 | Jun 1994 | GB |
2283133 | Apr 1995 | GB |
2289992 | Dec 1995 | GB |
2308490 | Jun 1997 | GB |
2332557 | Jun 1999 | GB |
175494 | Nov 1981 | HU |
60206121 | Mar 1959 | JP |
57043529 | Aug 1980 | JP |
57126117 | May 1982 | JP |
59076156 | Oct 1982 | JP |
59159642 | Feb 1983 | JP |
6264964 | Sep 1985 | JP |
1129737 | May 1989 | JP |
62320631 | Jun 1989 | JP |
2017474 | Jan 1990 | JP |
3245748 | Feb 1990 | JP |
4179107 | Nov 1990 | JP |
318253 | Jan 1991 | JP |
424909 | Jan 1992 | JP |
5290947 | Apr 1992 | JP |
6196343 | Dec 1992 | JP |
6233442 | Feb 1993 | JP |
6325629 | May 1993 | JP |
7057951 | Aug 1993 | JP |
7264789 | Mar 1994 | JP |
8167332 | Dec 1994 | JP |
7161270 | Jun 1995 | JP |
8264039 | Nov 1995 | JP |
9200989 | Jan 1996 | JP |
8036952 | Feb 1996 | JP |
8167360 | Jun 1996 | JP |
67199 | Mar 1972 | LU |
90308 | Sep 1937 | SE |
305899 | Nov 1968 | SE |
255156 | Feb 1969 | SE |
341428 | Dec 1971 | SE |
453236 | Jan 1982 | SE |
457792 | Jun 1987 | SE |
PCT SE 9100077 | Apr 1991 | SE |
502417 | Dec 1993 | SE |
PCTSE 9802148 | Jun 1999 | SE |
792302 | Jan 1971 | SU |
425268 | Sep 1974 | SU |
1019553 | Jan 1980 | SU |
694939 | Jan 1982 | SU |
955369 | Aug 1983 | SU |
1511810 | May 1987 | SU |
WO8202617 | Aug 1982 | WO |
WO8502302 | May 1985 | WO |
WO9011389 | Oct 1990 | WO |
WO9012409 | Oct 1990 | WO |
WO9101059 | Jan 1991 | WO |
WO9101585 | Feb 1991 | WO |
WO9107807 | Mar 1991 | WO |
WO9109442 | Jun 1991 | WO |
WO 9111841 | Aug 1991 | WO |
WO8115862 | Oct 1991 | WO |
WO 9115755 | Oct 1991 | WO |
WO9201328 | Jan 1992 | WO |
WO9203870 | Mar 1992 | WO |
WO9321681 | Oct 1993 | WO |
WO9406194 | Mar 1994 | WO |
WO9518058 | Jul 1995 | WO |
WO9522153 | Aug 1995 | WO |
WO9524049 | Sep 1995 | WO |
WO9622606 | Jul 1996 | WO |
WO9622607 | Jul 1996 | WO |
WO9630144 | Oct 1996 | WO |
WO9710640 | Mar 1997 | WO |
WO9711831 | Apr 1997 | WO |
WO9716881 | May 1997 | WO |
WO 9729494 | Aug 1997 | WO |
WO9745288 | Dec 1997 | WO |
WO9745847 | Dec 1997 | WO |
WO9745848 | Dec 1997 | WO |
WO9745906 | Dec 1997 | WO |
WO9745907 | Dec 1997 | WO |
WO9745912 | Dec 1997 | WO |
WO9745914 | Dec 1997 | WO |
WO9745915 | Dec 1997 | WO |
WO9745916 | Dec 1997 | WO |
WO9745918 | Dec 1997 | WO |
WO9745919 | Dec 1997 | WO |
WO9745920 | Dec 1997 | WO |
WO9745921 | Dec 1997 | WO |
WO9745922 | Dec 1997 | WO |
WO9745923 | Dec 1997 | WO |
WO9745924 | Dec 1997 | WO |
WO9745925 | Dec 1997 | WO |
WO9745926 | Dec 1997 | WO |
WO9745927 | Dec 1997 | WO |
WO9745928 | Dec 1997 | WO |
WO9745929 | Dec 1997 | WO |
WO9745930 | Dec 1997 | WO |
WO9745931 | Dec 1997 | WO |
WO9745932 | Dec 1997 | WO |
WO9745933 | Dec 1997 | WO |
WO9745934 | Dec 1997 | WO |
WO9745935 | Dec 1997 | WO |
WO9745936 | Dec 1997 | WO |
WO9745937 | Dec 1997 | WO |
WO9745938 | Dec 1997 | WO |
WO9745939 | Dec 1997 | WO |
WO9747067 | Dec 1997 | WO |
WO9820595 | May 1998 | WO |
WO9820596 | May 1998 | WO |
WO9820597 | May 1998 | WO |
WO 9820598 | May 1998 | WO |
WO9820600 | May 1998 | WO |
WO 9820602 | May 1998 | WO |
WO9821385 | May 1998 | WO |
WO9827634 | Jun 1998 | WO |
WO9827635 | Jun 1998 | WO |
WO9827636 | Jun 1998 | WO |
WO9829927 | Jul 1998 | WO |
WO9829928 | Jul 1998 | WO |
WO9829929 | Jul 1998 | WO |
WO9829930 | Jul 1998 | WO |
WO9829931 | Jul 1998 | WO |
WO9829932 | Jul 1998 | WO |
WO9833731 | Aug 1998 | WO |
WO9833736 | Aug 1998 | WO |
WO9833737 | Aug 1998 | WO |
WO9834238 | Aug 1998 | WO |
WO 9834239 | Aug 1998 | WO |
WO9834240 | Aug 1998 | WO |
WO9834241 | Aug 1998 | WO |
WO9834242 | Aug 1998 | WO |
WO9834243 | Aug 1998 | WO |
WO9834244 | Aug 1998 | WO |
WO9834245 | Aug 1998 | WO |
WO9834246 | Aug 1998 | WO |
WO9834247 | Aug 1998 | WO |
WO9834248 | Aug 1998 | WO |
WO9834249 | Aug 1998 | WO |
WO9834250 | Aug 1998 | WO |
WO9834309 | Aug 1998 | WO |
WO9834312 | Aug 1998 | WO |
WO9834315 | Aug 1998 | WO |
WO9834321 | Aug 1998 | WO |
WO9834322 | Aug 1998 | WO |
WO9834323 | Aug 1998 | WO |
WO9834325 | Aug 1998 | WO |
WO9834326 | Aug 1998 | WO |
WO9834327 | Aug 1998 | WO |
WO9834328 | Aug 1998 | WO |
WO9834329 | Aug 1998 | WO |
WO9834330 | Aug 1998 | WO |
WO9834331 | Aug 1998 | WO |
WO 9840627 | Sep 1998 | WO |
WO 9843336 | Oct 1998 | WO |
WO9917309 | Apr 1999 | WO |
WO9917311 | Apr 1999 | WO |
WO9917312 | Apr 1999 | WO |
WO9917313 | Apr 1999 | WO |
WO9917314 | Apr 1999 | WO |
WO9917315 | Apr 1999 | WO |
WO9917316 | Apr 1999 | WO |
WO9917422 | Apr 1999 | WO |
WO9917424 | Apr 1999 | WO |
WO9917425 | Apr 1999 | WO |
WO9917426 | Apr 1999 | WO |
WO9917427 | Apr 1999 | WO |
WO9917428 | Apr 1999 | WO |
WO9917429 | Apr 1999 | WO |
WO9917432 | Apr 1999 | WO |
WO9917433 | Apr 1999 | WO |
WO9919963 | Apr 1999 | WO |
WO9919969 | Apr 1999 | WO |
WO9919970 | Apr 1999 | WO |
WO9927546 | Jun 1999 | WO |
WO9928919 | Jun 1999 | WO |
WO9928921 | Jun 1999 | WO |
WO 9928922 | Jun 1999 | WO |
WO9928923 | Jun 1999 | WO |
WO9928924 | Jun 1999 | WO |
WO9928925 | Jun 1999 | WO |
WO9928927 | Jun 1999 | WO |
WO9928928 | Jun 1999 | WO |
WO9928929 | Jun 1999 | WO |
WO9928930 | Jun 1999 | WO |
WO9928931 | Jun 1999 | WO |
WO9928934 | Jun 1999 | WO |
WO9928994 | Jun 1999 | WO |
WO9929005 | Jun 1999 | WO |
WO9929005 | Jun 1999 | WO |
WO9929008 | Jun 1999 | WO |
WO9929011 | Jun 1999 | WO |
WO9929012 | Jun 1999 | WO |
WO9929013 | Jun 1999 | WO |
WO9929014 | Jun 1999 | WO |
WO9929015 | Jun 1999 | WO |
WO9929016 | Jun 1999 | WO |
WO9929017 | Jun 1999 | WO |
WO9929018 | Jun 1999 | WO |
WO9929019 | Jun 1999 | WO |
WO9929020 | Jun 1999 | WO |
WO9929021 | Jun 1999 | WO |
WO9929022 | Jun 1999 | WO |
WO 9929023 | Jun 1999 | WO |
WO9929024 | Jun 1999 | WO |
WO 9929025 | Jun 1999 | WO |
WO9929026 | Jun 1999 | WO |
WO9929029 | Jun 1999 | WO |
WO9929034 | Jun 1999 | WO |
WO9928926 | Sep 1999 | WO |