Patent Application
20150073196
This invention relates to a process and apparatus for the separation of a gas containing hydrocarbons. The applicants claim the benefits under Title 35, United States Code, Section 119(e) of prior U.S. Provisional Application No. 61/876,415 which was filed on Sep. 11, 2013 and No. 61/879,308 which was filed on Sep. 18, 2013. Assignees S.M.E. Products LP and Ortloff Engineers, Ltd, were parties to a joint research agreement that, was in effect before the invention of this application was made.
Natural gas is typically recovered from wells drilled into underground reservoirs. It usually has a major proportion of methane, i.e., methane comprises at least 50 mole percent of the gas. Depending on the particular underground reservoir, the natural gas also contains relatively lesser amounts of heavier hydrocarbons such as ethane, propane, butanes, pentanes and the like, as well as water, hydrogen, nitrogen, carbon dioxide, and other gases. A typical analysis of a natural gas stream to be processed in accordance with this invention would be, in approximate mole percent, 89.2% methane, 4.9% ethane and other C2 components, 2.6% propane and other C3 components, 0.4% iso-butane, 1.3% normal butane, and 0.6% pentanes plus, with the balance made up of nitrogen and carbon dioxide. Sulfur containing gases are also sometimes present.
Most natural gas is handled in gaseous form. The Most common means for transporting natural gas from the wellhead to gas processing plants and thence to the natural gas consumers is in high-pressure gas transmission pipelines. In a number of circumstances, however, it has been found necessary and/or desirable to liquefy the natural gas either for transport or for use. In remote locations, for instance, there is often no pipeline infrastructure that would allow for convenient transportation of the natural gas to market, in such cases, the much lower specific volume of liquefied natural gas (LNG) relative to natural gas in the gaseous state can greatly reduce transportation costs by allowing delivery of the LNG using cargo ships and transport trucks.
A relatively recent concept for commercializing natural gas from remote locations is to install a liquefaction plant on an offshore platform or on a ship (commonly referred to as floating LNG or FLNG) to allow moving the facility to another location when the gas reservoir is depleted. Deck space is at a premium for both of these, because each increment of deck space requires a very large quantity of supporting structure (and hull volume in the case of FLNG). As a result, great emphasis is placed on minimizing the “footprint” of each processing step in order to minimize the investment cost and thereby maximize the number of gas reservoirs in remote locations that can be economically produced.
For remote locations such as those contemplated here, recovery of the various hydrocarbons heavier than methane as separate products is generally not economically viable since there is usually no means of transporting and selling the resultant hydrocarbon product streams. Instead, to the largest extent possible, these heavier hydro-carbons are liquefied along with the methane and sold as part of the LNG product. However, some degree of heavier hydrocarbon removal is often required prior to liquefying the natural gas because there are usually limitations on the heating value of the re-vaporized gas when it is subsequently distributed from the LNG receiving terminal. In addition, hydrocarbons heavier than C5 or C6 (particularly aromatic hydrocarbons) generally must be removed upstream of the liquefaction step to avoid plugging inside the liquefaction plant caused by freezing of these heavier hydrocarbons. For these reasons, it is typical to include a processing step to remove these hydrocarbons (“heavy ends removal”) before liquefying the natural gas.
Available processes for removing these heavier hydrocarbons include those based upon cooling and refrigeration of gas, oil absorption, and refrigerated oil absorption. Additionally, cryogenic processes have become popular because of the availability of economical equipment that produces power while simultaneously expanding and extracting heat from the gas being processed. Depending upon the pressure of the gas source, the richness (ethane, ethylene, and heavier hydrocarbons content) of the gas and the desired, end products, each of these processes or a combination thereof may he employed,
The cryogenic expansion process is now generally preferred for removing heavy hydrocarbons from natural gas because it provides maximum simplicity with ease of startup, operating flexibility, good efficiency, safety, and good reliability. U.S. Pat. Nos. 3,292,380; 4,061,481; 4,140,504; 4,157,904; 4,171,964; 4,185,978; 4,251,249; 4,278,457; 4,5149,824; 4,061,039; 4,687,499; 4,689,063; 4,690,702; 4,854,955; 4,869,740; 4,889,545; 5,275,005; 5,555,748; 5,566,554: 5,568,737; 5,771,712: 5,799,507; 5,881,569; 5,890,378; 5,983,664; 6,182,469; 6,578,379; 6,712,880; 6,742,358; 6,915,662: 6,945,075; 7,010,937; 7,191,617; 7,204,100; 7,210,311; 7,219,513; 7,565,815; 8,590,340; reissue U.S. Pat. No. 33,408; and co-pending application Ser. Nos. 11/430,412: 11/839,693; 12/206,230; 12/487,078; 12/689,616; 12/717,394; 12/750,862; 12/772,472; 12/781,259; 12/868,993; 12/869,007; 12/869,139; 12/979,563; 13/048,315; 13/051,682; 13/052,348; 13/052,575; and 13/053,792 describe relevant processes (although the description of the present invention in some cases is based on different processing conditions than those described in the cited U.S. Patents and co-pending applications).
The present invention is a novel means of removing heavier hydrocarbon components from natural gas that combines what heretofore have been individual equipment items into a common housing, thereby reducing the plot space requirements, the capital cost of the plant, and (more importantly) the capital cost of the associated platform or ship. In addition, the more compact arrangement also eliminates much of the piping used to interconnect the individual equipment items in traditional plant designs, further reducing capital cost and also eliminating the associated flanged piping connections. Since piping flanges are a potential leak source for hydrocarbons (which are volatile organic compounds, VOCs, that contribute to greenhouse gases and may also be precursors to atmospheric ozone formation), eliminating these flanges reduces the potential for atmospheric emissions that may damage the environment.
For a better understanding of the present invention, reference is made to the following examples and drawings. Referring to the drawings:
In the following explanation of the above figures, tables are provided summarizing flow rates calculated for representative process conditions, in the tables appearing herein, the values for flow rates (in moles per hour) have been rounded to the nearest whole number for convenience. The total stream rates shown in the tables include all non-hydrocarbon components and hence are generally larger than the sum of the stream flow rates for the hydrocarbon components. Temperatures indicated are approximate values rounded to the nearest degree, it should also be noted that the process design calculations performed for the purpose of comparing the processes depicted in the figures are based on the assumption of no heat leak from (or to) the surroundings to (or from) the process. The quality of commercially available insulating materials makes this a very reasonable assumption and one that is typically made by those skilled in the art.
For convenience, process parameters are reported in both the traditional British units and in the units of the Système International d'Unités (SI). The molar flow rates given in the tables may be interpreted as either pound moles per hour or kilogram moles per hour. The energy consumptions reported as horsepower (HP) and/or thousand British Thermal Units per hour (MBTU/Hr) correspond to the stated molar flow rates in pound moles per hour. The energy consumptions reported as kilowatts (kW) correspond to the stated, molar flow rates in kilogram moles per hour.
The feed stream 31 is divided into two portions, streams 32 and 33. Stream 32 is cooled in heat exchanger 10 by heat exchange with cool residue gas stream 37, while stream 33 is cooled in heat exchanger 11 by heat exchange with flash expanded liquids (stream 35a). streams 32a and 33a recombine to form stream 31a, which enters separator 12 at 4° F. [−16° C.]find 980 psia [6,755 kPa(a)] where the vapor (stream 34) is separated from the condensed liquid (stream 35).
The vapor from separator 12 (stream 34) enters a work expansion machine 13 in which mechanical energy is extracted from this portion of the high pressure feed. The machine 13 expands the vapor substantially isentropically to the operating pressure (approximately 470 psia [3,238 kPa(a)]) of fractionation tower 16, with the work expansion cooling the expanded stream 34a to a temperature of approximately −59° F. [−51° C]. The typical commercially available expanders are capable of recovering on the order of 80-85% of the work theoretically available in an ideal iseniropic expansion. The work recovered is often used to drive a centrifugal compressor (such as item 14) that can be used to re-compress the heated residue gas stream, (stream 37a), for example. The partially condensed expanded stream 34a is thereafter supplied as feed to fractionation tower 16 at an upper mid-column feed point. The separator liquid (stream 35) is expanded to slightly above the operating pressure of fractionation tower 16 by expansion valve 15, then heated from −17° F. [−27° C.] to 54° F. [12° C.] in heat exchanger 11 as described earlier before stream 35b is supplied to fractionation tower 16 at a lower mid-column feed point.
Fractionation tower 16 is a conventional distillation column containing, a plurality of vertically spaced trays, one or more packed beds, or some combination of trays and packing. As is often the ease, the .fractionation tower may consist of two sections, an upper rectifying section 16a and a lower stripping section 16b. The upper rectifying section 16a contains trays and/or packing and provides the necessary contact between the vapor rising from the lower distillation or stripping section 16b and a liquid stream (reflux) to remove the heavier hydrocarbon components from the vapor. The lower, stripping section 16b also contains trays and/or packing and provides die necessary contact between the liquids failing downward and the vapors rising upward. The aripplug section 16b also includes at least one reboiler (such as the reboiler 17) which heats and vaporizes a portion of the liquids flowing down the column to provide the stripping vapors which flow up the column to strip the liquid product, stream 39, of lighter hydrocarbon components so that it contains only the heavier hydrocarbon components that were in the natural gas feed stream (stream 31), whereupon it exits the bottom of the tower at 358° F. [181° C.].
The column overhead vapor (stream 36) is withdrawn from the top of tower 16 at −6° F. [−21° C.] and is cooled to −18° F. [−28° C.] and partially condensed (stream 36a) in heat exchanger 18 using a refrigerant. The operating pressure in reflux separator 19 is maintained slightly below the operating pressure of tower 16. This provides the driving force which causes overhead vapor stream 36 to flow through reflux condenser 18 and thence into the reflux separator 19 wherein the condensed liquid (stream 38) is separated front the uncondensed vapor (stream 37). The liquid stream 38 from reflux separator 19 is pumped by reflux pump 20 to a pressure slightly above the operating pressure of tower 16, and stream 38a is then supplied as cold top column feed (reflux) to tower 16. This cold liquid reflux absorbs and condenses the heavier hydrocarbon components in the vapors rising up in rectifying section 16a of tower 16. The residue gas (vapor stream 37) passes countercurrently to the incoming feed gas in heat exchanger 10 where it is heated to 55° F. [13° C.] as it provides cooling as previously described. The residue gas is then re-compressed in two stages, compressor 14 driven by expansion machine 13 and compressor 21. driven by a supplemental power source. (In the
A summary of stream flow rates and energy consumption for the process illustrated in
In this simulation of the process, inlet gas enters the plant at 60° F. [15° C. ] and 995 psia [6,858 kPa(a)] as stream 31 and flows directly to work expansion machine 13 in which mechanical energy is extracted from the high pressure feed. The machine 13 expands the vapor substantially isentropically to the operating pressure (approximately 355 psia [2,446 kPa(a)]) of fractionation tower 16, with the work expansion cooling the expanded stream 31a to a temperature of approximately −34° F. [−37° C.] before it is supplied as feed to fractionation tower 16 at. a mid-column feed point.
Liquid product stream 39 is stripped of the lighter hydrocarbon components and exits the bottom of tower 16 at 320° F. [160° C.]. The column overhead vapor (stream 36) is withdrawn from the top of tower 16 at −8° F. [−22° C.] and is cooled to −24° F. [−31° C. ] and partially condensed (stream 36a) in heat exchange 18 using a refrigerant, and the condensed liquid stream 38 is separated from the uncondensed vapor (stream 37) in reflux separator 19. Liquid stream 38 is pumped by reflux pump 20 to a pressure slightly above the operating pressure of tower 16 and stream 38a is then supplied as cold top column feed (reflux) to tower 16. The residue gas (vapor stream 37) is re-compressed in two stages, compressor 14 driven by expansion machine 13 and compressor 21 driven by a supplemental power source. (In the
A summary of stream flow rates and energy consumption for the process illustrated in
In the process illustrated in
Separator section 116e has an internal head or other means to divide it from stripping section 116d, so that the two sections inside processing assembly 116 can operate at different pressures. The cooled stream 31a enters separator section 116c at 4° F. [−16° C.] and 980 psia [6,755 kPa(a)] where any condensed liquid (stream 35) is separated from the vapor (stream 34). Stream 35 exits separator section 116e and is expanded by expansion valve 15 to slightly above the operating pressure (470 psia [3,238 kPa(a)]) of stripping section 116d inside processing assembly 116, cooling stream 35a to −17° F. [−27° C.]. Stream 35a enters the heat exchange means in feed, cooling section 116a to supply cooling to the feed gas as described previously, heating stream 35b to 54° F. [12° C.] before it enters below a mass transfer means inside stripping section 116d of processing assembly 116.
The vapor (stream 34) from separator section 116e enters a work expansion machine 13 in which mechanical energy is extracted from this portion of the high pressure feed. The machine 13 expands the vapor substantially isentropically to the operating pressure of rectifying section 116c inside processing assembly 116, with the work expansion cooling the expanded stream 34a to −59° F. [−51° C. ]. The partially condensed expanded stream 34a is thereafter supplied as feed between an absorbing means inside rectifying section 116c and the mass transfer means inside stripping section 116d of processing assembly 116.
A heat and mass transfer means is located below the mass frontier means inside stripping section 116d. The heat and mass transfer means may be comprised of a fin and tube type heat exchanger, a plate type heat exchanger, a brazed aluminum type heat exchanger, or other type of heat transfer device, including multi-pass and/or multi-service heat exchangers. The heat and mass transfer means is configured to provide heat exchange between a heating medium flowing through one pass of the heat and mass transfer means and a distillation liquid stream flowing downward from the lower region of the mass transfer means, so that the distillation liquid stream is heated. As the distillation liquid stream is heated, a portion of it is vaporized to form shipping vapors that rise upward to the mass transfer means as the remaining liquid continues flowing downward through the heat and mass transfer means. The heat and mass transfer means provides continuous contact between the shipping vapors and the distillation liquid stream so that it also functions to provide mass transfer between the vapor and liquid phases, stripping the liquid product stream 39 of lighter hydrocarbon components. The stripping vapors produced in the heat and mass transfer means continue upward to the mass transfer means in stripping section 116d to provide partial stripping of the lighter hydrocarbon components in the liquids flowing downward from the upper part of processing assembly 116.
Another heat and mass transfer means is located inside condensing section 116b, above the absorbing means inside rectifying section 116c of processing assembly 116. This heat and mass transfer means may also be comprised of a fin and tube type heat exchanger, a plate type heat exchanger, a brazed aluminum type heat exchanger, or other type of heat transfer device, including multi-pass and/or multi-service heat exchangers. The heat and mass transfer means is configured to provide heat exchange between a refrigerant stream flowing through one pass of the heat and mass transfer means and a distillation vapor stream arising from the upper region of the absorbing means flowing upward through the other pass, so that the distillation vapor stream is cooled by the refrigerant. As the distillation vapor stream is cooled, a portion of it is condensed and falls downward while the remaining distillation vapor stream continues flowing upward through die heat and. mass transfer means. The heat and mass transfer means provides continuous contact between the condensed liquid and the distillation vapor stream so that it also functions to provide mass transfer between the vapor and liquid phases, thereby absorbing heavier hydrocarbon components from the distillation vapor stream to rectify it. The condensed liquid is collected from the bottom of the heat and mass transfer means and directed to the upper region of the absorbing means inside rectifying section 16c to provide partial rectification of the heavier hydrocarbon components in the vapors flowing upward from the lower part of processing assembly 116.
The absorbing means inside rectifying section 116c and the mass transfer means inside stripping section 116d each consist of a plurality of vertically spaced trays, one or more packed beds, or some combination of trays and packing. The trays and/or packing in rectifying section 116c and stripping section 116d provide the necessary contact between the vapors rising upward and liquid falling downward. The liquid portion of expanded stream 34a commingles with liquids falling downward from rectifying section 116c and the combined liquids continue downward into stripping section 116d, which vaporizes and strips the lighter hydrocarbon components from these liquids. The vapors arising from stripping section 116d combine with, the vapor portion of expanded stream 34a and rise upward through rectifying section 116c, to be contacted with the cold liquid failing downward to condense and absorb the heavier hydrocarbon components from these vapors.
The distillation liquid flowing downward from the hear and mass transfer means in stripping section 116d inside processing assembly 116 has been stripped of the lighter hydrocarbon components so that it contains only the heavier hydrocarbon components that were in the natural gas feed stream (stream 31) whereupon it exits the lower region of stripping section 116d as stream 39 and leaves processing assembly 116 at 356° F. [180° C. ]. The distillation vapor stream arising from condensing section 116b is heated in feed cooling section 116a as it provides cooling to stream 31 as described previously, whereupon residue gas stream 37 leaves processing assembly 116 at 55° F. [13° C. ]. The residue gas stream is then re-compressed in two stages, compressor 14 driven by expansion machine 13 and compressor 21 driven by a supplemental power source. (In this example, compressor 21 consists of two compression stages with intercooling between the stages.) After cooling in discharge cooler 22, residue gas stream 37c flows to the sales gas pipeline or to the liquefaction plant at 1603 psia [11,050 kPa(a)].
A summary of stream flow rates and energy consumption for the process illustrated in
A comparison of Tables I and III shows that, compared to the prior art, the compact processing assembly of the present invention maintains essentially the same butanes recovery and pentane+recovery using slightly less power. However, the present invention offers at least two advantages over the prior art of
The present invention also offers advantages when circumstances favor expansion of the feed gas without cooling it first, as illustrated in
In the process illustrated in
A heat and mass transfer means is located, below the mass transfer means inside stripping section 116d. The heat and mass transfer means is configured to provide heat exchange between a heating medium flowing through one pass of the heat and mass transfer means and a distillation liquid stream flowing downward horn die lower region of the mass transfer means, so that the distillation liquid stream is heated. As the distillation liquid stream is heated, a portion of it is vaporized to form stripping vapors that rise upward to the mass transfer means as the remaining liquid continues flowing downward through the heat and mass transfer means. The heat and mass transfer means provides continuous contact between the stripping vapors and the distillation liquid stream so that it also functions to provide mass transfer between the vapor and liquid phases, stripping the liquid product stream 39 of lighter hydrocarbon components. The stripping vapors produced in the heat and mass transfer means continue upward to the mass transfer means in stripping section 116d to provide partial stripping of the lighter hydrocarbon components in the liquids flowing downward from the upper part of processing assembly 116.
Another heat and mass transfer means is located inside condensing section 116b, above the absorbing means inside rectifying section 116c of processing assembly 116. The heat and mass transfer means is configured to provide heat exchange between a refrigerant stream flowing through one pass of the hear and mass transfer means and a distillation vapor stream arising irons the upper region of the absorbing means flowing upward through the other pass, so that the distillation vapor stream is cooled by the refrigerant. As the distillation vapor stream is cooled, a portion of it is condensed and falls downward while the remaining distillation vapor stream continues flowing upward through the heat and mass transfer means. The heat and mass transfer means provides continuous contact between the condensed liquid and the distillation vapor stream so that it also functions to provide mass transfer between the vapor and liquid phases, thereby absorbing heavier hydrocarbon components from the distillation vapor stream to rectify it. The condensed liquid is collected from, the bottom of the heat and mass transfer means and directed to the upper region of the absorbing means inside rectifying section 116c to provide partial rectification of the heavier hydrocarbon components in the vapors flowing upward from the lower part of processing assembly 116.
The distillation liquid flowing downward from the heat and mass transfer means in stripping section 116d inside processing assembly 116 has been shipped of the lighter hydrocarbon components so that it contains only the heavier hydrocarbon components that were in the natural gas feed stream (stream 31), whereupon it exits the lower region of stripping section 116d as stream 39 and leaves processing assembly 116 at 318° F. [159° C]. The distillation vapor stream arising from condensing section 116b is residue gas stream 37, which leaves processing assembly 116 at −25° F. [−32° C]. The residue gas stream is re-compressed in two stages, compressor 14 driven by expansion machine 13 and compressor 21 driven by a supplemental power source, (in this example, compressor 21 consists of two compression stages with intercooling between the stages.) After cooling in discharge cooler 22, residue gas stream 37d flows to the sales gas pipeline or to the liquefaction plant at 1603 psia [11,050 kPa(a)].
A summary of stream flow rates and energy consumption for the process illustrated in
A comparison of Tables II and IV shows that, compared to the prior art, the compact processing assembly of the present invention maintains essentially the same butanes recovery and pentane+recovery using slightly less power. However, the present invention offers at least two advantages over the prior art of
Some circumstances may favor eliminating feed cooling section 116a from processing assembly 116 in order to reduce the height of processing assembly 116. As shown in
In some circumstances, it may be advantageous to use an external separator vessel to separate cooled feed stream 31a, rather than including separator section 116e in processing assembly 116. As shown in
Depending on the quantity of heavier hydrocarbons in the feed gas and the feed gas pressure, the cooled feed stream 31a entering separator section 116e in
Feed gas conditions, plant size, available equipment, or other factors may indicate that elimination of work expansion machine 13, or replacement with an alternate expansion device (such as on expansion valve), is feasible. Although individual stream expansion is depicted in particular expansion devices, alternative expansion means may be employed where appropriate. For example, conditions may warrant work expansion of the separator liquid (stream 35).
In accordance with the present invention, the use of external refrigeration to supplement the cooling available to the inlet gas from the distillation vapor and separator liquid streams may be employed, particularly in the case of a rich inlet gas, in such cases, a heat and mass transfer means may be included in separator section 116e (or a collecting means in such cases when the cooled feed stream 31a contains no liquid) as shown by the dashed lines in
Depending on the type of heat transfer device selected for the heat exchange means in feed cooling section 116a and the type of heat and mass transfer device selected for the heat and mass transfer means in condensing section 116b. it may be possible to combine these in a single multi-pass and/or multi-service heat and mass transfer device. In such cases, the multi-pass and/or multi-service heat and mass transfer device will include appropriate means for distributing, segregating, end collecting streams 31/31a, streams 35a 35b. and the distillation vapor stream in order to accomplish the desired cooling and heating.
While there have been described what are believed to be preferred, embodiments of the invention, those skilled in the art will recognize that other and further modifications may be made thereto, e.g. to adapt the invention to various conditions, types of feed, or other requirements without departing from, the spirit of the present invention as defined by the following claims.
| Number | Date | Country | |
|---|---|---|---|
| 61879308 | Sep 2013 | US | |
| 61876415 | Sep 2013 | US |
