Claims
- 1. In the process of hydroformylating alphaolefins of 2 to 20 carbon atoms to form aldehydes comprising feeding of such alpha-olefin, hydrogen and carbon monoxide to a liquid homogeneous medium at a temperature between about 50.degree. C. and 145.degree. C. which medium contains (i) a solvent therein, (ii) a catalytic amount of rhodium in complex combination with carbon monoxide and triphenylphosphine, (iii) an additional amount of triphenylphosphine such that there is present at least two moles of free triphenylphosphine per mole of rhodium in said medium and (iv) products of the hydroformylation reaction; the total pressure of carbon monoxide and hydrogen is less than 450 psia with a partial pressure attributable to carbon monoxide of no greater than about 75 percent of the total pressure; all of which is sufficient to produce said aldehydes, and recovering aldehydes from said medium; wherein the improvement comprises employing higher boiling aldehyde condensation products containing hydroxyl groups as the solvent in said medium.
- 2. The process of claim 1 wherein at least a portion of said medium is removed prior to separation of said aldehydes and after removal of aldehydes from said medium, the medium is recycled to the hydroformylation reaction.
- 3. The process of claim 2 wherein the alphaolefin is propylene.
- 4. The process of claim 1 wherein there is present in the liquid medium less than about 5 percent by weight of substituted acrolein by-product.
- 5. The process of claim 3 wherein there is present in the liquid medium less than about 5 percent by weight of substituted acrolein by-product.
- 6. The process of claim 2 wherein the alphaolefin is 1-octene or 1-nonene.
- 7. The process of claim 6 wherein the alphaolefin is 1-octene.
- 8. The process of claim 2 wherein the alphaolefin is 1-octadecene.
- 9. The process of claim 1 wherein the rhodium is dissolved in a solution containing the high boiling liquid condensation product containing hydroxyl groups prior to providing it in the liquid homogeneous medium.
- 10. The process of claim 9 wherein the rhodium is first dissolved in a mixture comprising the high boiling liquid condensation product and triphenylphosphine.
Parent Case Info
This Application is a con't. of Ser. No. 556,270 filed Mar. 7, 1975, which is a con't. of Ser. No. 887,370 filed Dec. 22, 1976, both Abandoned.
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Number |
Name |
Date |
Kind |
3239566 |
Slaugh et al. |
Mar 1966 |
|
3527809 |
Pruett et al. |
Sep 1970 |
|
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Number |
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903589 |
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GBX |
1228201 |
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GBX |
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Continuations (2)
|
Number |
Date |
Country |
Parent |
556270 |
Mar 1975 |
|
Parent |
887370 |
Dec 1969 |
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