The invention describes a combustion chamber system (“steam booster”) for burning hydrogen with the aim of heating a flow of steam and/or of increasing the steam states of the hydrogen, and a method and a plant.
Frequently, a steam circuit is not internally fired, but rather the boiler in the power plant is generally fired externally with, for example, coal, nuclear waste heat or via the exhaust gas of a gas turbine which is fired with gas or oil.
Such a steam power plant is described in EP 1 375 827 A1.
The aim is to use hydrogen.
The object is achieved by a combustion chamber system and by a method and a plant as claimed.
Further advantageous measures which may be combined as desired with one another to obtain further advantages are listed in the dependent claims.
It is proposed to present a combustion chamber system having hydrogen firing, a method and a plant for this purpose.
The advantage is the combustion of pure hydrogen (H2) and preferably oxygen (O2) with water steam as a combustion product.
The aim is turbines operated without pollutants and with water or water vapor as a combustion product (CO2-free, NOx-free) or for generating process steam.
The combustion chamber system can particularly also be integrated in an existing steam power plant or in a steam gas turbine plant (GuD).
In addition, the combustion chamber system can be integrated in industrial applications with steam circuits or steam extractions, in which in particular CO2-free additional firing is required.
In the figures
The combustion chamber system 1 has, as central part, a combustion cylinder 7 with a combustion chamber 30.
The combustion chamber 30 has a baseplate 4 which is preferably directly adjoined by a flame tube 22 with the combustion chamber 30 and an outlet opening 32 at the end of the combustion chamber 30.
The flame tube 22 is preferably ceramic, particularly completely ceramic.
The length of the combustion chamber 30 or of the flame tube 22 is preferably at least three times, in particular three to five times, the length of the hydraulic diameter of the combustion chamber 30.
The cross section of the combustion chamber 30, as seen in the combustion chamber direction 31, can be circular or oval-shaped.
Preferably, in the baseplate 4 there are a plurality of lines (also see
The lines are in particular at least a first supply line 10 for the oxygen (O2), a second supply line 13 for the hydrogen (H2), and a third supply line 16 for the water vapor (H2O). There are preferably only these supply lines 10, 13, 16. However, other, fewer or more supply lines are also possible.
Water vapor is preferably supplied to the combustion chamber system 1 via a central steam line 19 which in particular is divided, particularly into the third supply line 16 for the steam for the combustion chamber 30 and preferably into a steam line 25 for the steam which flows in an intermediate space 41 around the flame tube 22 and then flows in places via steam passages 50 or steam outlets 150 (
The intermediate space 41 is preferably directly bounded by the flame tube 22 and a pressure jacket 40.
The steam passages 50 and/or steam outlets 150 are preferably distributed over the entire length of the flame tube 22 and preferably also around the circumference of the flame tube 22.
Steam flows around the flame tube 22 preferably over the entire length thereof.
The steam line 25 can be divided in particular into two steam lines 25′, 25″ for the intermediate space 41.
The intermediate space 41 is closed at the end, in particular in the region of an outlet opening 32. In particular, the intermediate space 41 is a sealed space, i.e. except for the supply lines, in particular for the steam, and the steam passages 50 and steam outlets 150. All of the steam thus flows from the supply lines preferably out of the intermediate space 41 completely into the combustion chamber 30.
The combustion chamber system 1 furthermore preferably has drainage lines 33, pressure control valves or overpressure protection 36 for it, and a steam bypass 39.
Similarly, an H2O spray 42 can preferably be present at the end of the combustion cylinder 7.
In addition, there is preferably a flushing system 3 which can flush the supply lines through; in particular, nitrogen is used here.
It is also advantageous that the flame tube 22 can be cooled during operation by the steam 28 flowing around it and/or can preferably be preheated by the water vapor in the stand-by mode.
The proposed combustion chamber system 1 preferably has a combustion chamber axis 31, as is illustrated in
The combustion chamber 7 can also be arranged horizontally with corresponding supports (optionally leaf springs 60 in
The combustion chamber 30 preferably has the same cross section transversely with respect to the combustion chamber axis 31 over the length and preferably over the entire length.
The use and the variation options of the proposed combustion chamber system 1 are universal.
The combustion chamber system 1 preferably operates in a steam atmosphere preferably of 1 bar to 140 bar, particularly 1 bar to 80 bar. The combustion chamber 30 is operated in a steam atmosphere of preferably at least 2 bar, particularly at least 6 bar.
A pressure loss of 100 mbar-3000 mbar is preferably set.
According to
The modules 46′, 46″, . . . are then preferably also ceramic.
However, a monolithic flame tube 22 made from ceramic or metal can also be used.
Use is preferably made of an oxide ceramic, particularly on the basis of aluminum oxide or aluminum oxide/spinel. Preferably, no CMC is used.
Similarly, preferably no SiC or no silicon-based ceramic is used.
The modules 46′, 46″, . . . are preferably ceramic, but may also be formed with metallic tubes, e.g., of Ni-based alloys, e.g. Inconel, with ceramic coatings, as is known from coating systems of gas turbine blades or metallic heat shield elements of gas turbines.
For the formation of the flame tube 22 of the combustion chamber system 1, the modules 46′, 46″, . . . are particularly arranged one above another and particularly coaxially with respect to one another and one above another.
The flame tube 22 or the modules 46′, 46″, . . . are particularly annular and preferably circular or oval-shaped in cross section.
A plurality of preferably rods 43, particularly threaded rods, which guide and hold together the individual modules 46′, 46″, . . . (
Similarly, other options for the mechanical assembly or mechanical holding together are conceivable.
For example, there are five modules 46′, 46″, . . . here which are held together by the rods 43 and by an upper plate 44 and the baseplate 4.
The intermediate space 41 can thus be formed around the flame tube 22 by means of the external pressure jacket 40.
In particular, the modules 46′, 46″, . . . and the baseplate 4 are held together with fastening elements 47, in particular consisting of spring elements and screws, around the rods 43 which lie against the upper plate 44. Other fastening methods and elements are possible.
Also illustrated in
A section through
The steam passages 50 are preferably distributed uniformly in the flame tube 22 or in a module 46′, 46″, . . . or particularly may also be distributed asymmetrically, depending on the heat load.
Along the length of the flame tube 22, the modules 46″, 46″, . . . or a monolithic flame tube 22 may be configured differently and variously corresponding to the technical requirements and may have more or fewer steam passages 50 or steam outlets 150 (
The outlet opening 32 is preferably realized above the upper plate 44 which firstly ensures the mutual centering of the modules 46′, 46″, . . . or of the flame tube 22 and particularly at the same time contains a shadow in order to prevent the overheating of the following components by the radiant heat of the flame tube 22.
The external pressure jacket 40 has a flange 68′ on which a cover plate 64 rests and is screwed by its flange 68″ to the flange 68′ of the external pressure jacket 40 by means of a fastening element 65, in particular a screw and nut.
The modules 46′, . . . or the flame tube 22 are/is held together or pressed together by tongue elements 67 preferably present between the cover plate 64 and upper plate 44. The cover plate 64 accordingly has an outlet opening 69 which lies opposite or extends the outlet opening 32.
The baseplate 4 (or flame tube base) (
In the case of the modular design, the combustion chamber 30 is formed in particular by stacking in particular modules 46′, 46″, . . . which, particularly by means of a tongue and groove geometry, center themselves on the contact surfaces, and provide sealing and support.
Fastening means, particularly a tongue 101 and groove 102 structure, particularly hemispherical here for example, do not obstruct a thermal expansion of the individual, in particular ceramic modules 46′, 46″, . . . , and also with the baseplate 4 during heating and cooling. This avoids thermally induced stresses.
The tongue 101 and groove 102 structure can preferably also be formed between the modules 46′, 46″, . . . and/or between a module 46′ and baseplate 4 and/or between a module 46 and upper plate 44.
The combustion chamber 30 can be varied in length as desired by the stacking of different numbers of modules 46′, 46″, . . . .
In particular, modules 46′, 46″, . . . differing in length can be used.
The combustion chamber 30 may also be varied in diameter by the modules 46′, 46″, . . . varying in diameter. A conicity with the modules 46′, 46″ is also possible.
The individual modules 46′, 46″, . . . are preferably either guided in a tube or by/on rails or prestressed by rods 43.
The prestressing is undertaken via the rods 43 and spring elements with a contact pressure suitable for ceramic. The ceramic is exclusively subjected to a compressive stress.
Each module 46′, 46″, . . . or the flame tube 22 preferably contains defined steam passages 50 which permit the mixing zone of the combustion and the surrounding steam to mix gradually in order to ensure optimum combustion of hydrogen (H2) and preferably oxygen (O2) and to set the required or desired temperatures.
The steam passages 50 are round and/or oval and/or angular and also constant or variable in cross section in their flow direction and are arranged in particular at shallow angles, particularly between 80° and <90°, in the flow direction in order to prevent application of the hot flame to the wall of the flame tube 22 and/or to introduce turbulence into the combustion media.
If required, they can also be directed in such a way that they open directly into a flame and induce vigorous mixing.
In principle, the steam passages 50 can be distributed in various sizes over the length of the modules 46 or over the length of the flame tube 22 or can be designed as steam outlets 150 on the end face 133 of a module 46. Combinations of the two principles are also possible.
The arrangement can be selected specifically for the different industrial applications, applications for generating power or using hydrogen (H2) and preferably oxygen (O2) in steam-conducted combustion processes.
Examples of the arrangement of the steam passages 50 can be gathered from
According to
By means of preferably 3D manufacturing of the baseplate 4, particularly by means of SLM, these functions can be ideally combined with one another.
The fuel is preferably mixed here only in the combustion chamber 30.
The steam preferably flows in the direction of the outlet opening 32.
Steam is also supplied to a burner 58 and/or around the burner 58.
In this variant, hydrogen (H2) and oxygen (O2) are mixed in the mixer 55 and only then supplied to the combustion chamber 30.
In this case, it is the hydrogen 111, the oxygen 112 and the steam 113 which each flow laterally into a channel 114 and are therefore mixed there.
The mixture then exits from the channel 114 in a direction 115, for example, into the combustion chamber 30 according to
A plurality of depressions 130 are preferably present starting from the upper end face 133 of the module 46.
The shape of the depressions 130 may be diverse, for example may have a narrowing, wedge-shaped profile in the plane of the base surface 134 of the depression 130.
The base surface 134 of a depression 130 is preferably flat, i.e. the combustion chamber axis 31 (or a parallel thereto) is perpendicular to the base surface 134 (
The geometry and arrangement of the steam outlets 150 may be different for each individual module 46 or identical for the modules 46′, 46″, . . . in question.
The geometry and arrangement of the steam outlets 150 may also be different in particular for an individual module 46.
Each depression 130′, 130″, 130′″, . . . has a center line 131′, 131″, 131″. The center line 131′, . . . divides the base surface 134 in half.
The center lines 131′, 131″, . . . of the depressions 130′, 130″, . . . preferably meet in the center of the module 46, i.e. at the point of the combustion chamber axis 31.
The base surface 134 here is preferably wedge-shaped (frustospherical) since the edges of the base surface 134 are radials.
Similarly, the depression 130 with its center line 131 can be configured in such a way that the center line 131 of the base surface 134 does not run through the combustion chamber axis 31, as is indicated by way of example in
The base surface 134 can preferably also be square or rectangular.
The module 46 can also in turn consist of a plurality of elements 48′, 48″, . . . . Such an element 48′, 48″, . . . of a module 46 is illustrated in
Each module 46 (
Steam outlets 150 having the same purpose as the steam passages 50 are produced only by stacking of the individual modules 46′, . . . .
The meaning of the depressions 130 becomes clear in
These steam outlets 150 can also preferably be freely selected and configured in their geometry.
Such a steam outlet 150 can also be completely produced only by the stacking of two modules 46′, 46″, . . . lying directly on one another, particularly if the end faces 133 each have a semicircular depression which, when stacked together one above another, produce a circular cross section.
Steam outlets 150 owing to the depressions 130 and steam passages 50 can also be present simultaneously (
A burner 58 is arranged on the base in the combustion chamber 30 (
This burner 58 is preferably a porous burner.
For an igniter 405, a design is possible in which the igniter 405 is introduced laterally into the combustion chamber 30 (
By means of a steam passage 50 or another feedthrough, the igniter 405 is supplied transversely with respect to the longitudinal direction above the burner 58 or is present there.
The igniter 405 can preferably be supplied to the combustion chamber such that, during operation, after ignition for the first and only time, the igniter 405 can be removed from the highly corrosive region.
The igniter 405 is at a corresponding distance 400 from the burner, as seen in the longitudinal direction of the combustion chamber 30. The ignition takes place between burner 58 and ignition device 405.
After the ignition, i.e. in the booster mode, the igniter 405 can be removed from the combustion chamber 30.
Steam is supplied to the combustion chamber system 1 from the steam of the existing plant through openings 703′, 703″. These are preferably a plurality of openings which are distributed in particular uniformly around the circumference.
The rods 43 which are also preferably distributed uniformly around the circumference are arranged schematically between the openings 703′, . . . .
The steam therefore flows here into the intermediate space 41 between the external pressure jacket 40 and flame tube 22.
The drainage openings for drainage lines 33 can also be seen.
The burner 58 around which the steam lines 25′, 25″, . . . are arranged is arranged centrally.
The profile of the modules 46 is also illustrated.
A valve for spraying the steam line is preferably also provided.
The combustion chamber system 1 is preferably connected in series with a steam tube of an existing plant and is connected in series there by means of the flange.
For the manufacturing of the ceramic segments, a three-part mold concept is provided, in which the ceramic mass is inserted at the circumference. The aim here is to manufacture the two supporting surfaces close to their final contour and to as far as possible completely avoid finishing work.
Number | Date | Country | Kind |
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21183260.5 | Jul 2021 | EP | regional |
This application is the US National Stage of International Application No. PCT/EP2022/065112 filed 2 Jun. 2022, and claims the benefit thereof, which is incorporated by reference herein in its entirety. The International Application claims the benefit of European Application No. EP21183260 filed 1 Jul. 2021.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2022/065112 | 6/2/2022 | WO |