Patent Grant
11738305
A hydrogen generation assembly is an assembly that converts one or more feedstocks into a product stream containing hydrogen gas as a majority component. The feedstocks may include a carbon-containing feedstock and, in some embodiments, also may include water. The feedstocks are delivered to a hydrogen-producing region of the hydrogen generation assembly from a feedstock delivery system, typically with the feedstocks being delivered under pressure and at elevated temperatures. The hydrogen-producing region is often associated with a temperature modulating assembly, such as a heating assembly or cooling assembly, which consumes one or more fuel streams to maintain the hydrogen-producing region within a suitable temperature range for effectively producing hydrogen gas. The hydrogen generation assembly may generate hydrogen gas via any suitable mechanism(s), such as steam reforming, autothermal reforming, pyrolysis, and/or catalytic partial oxidation.
The generated or produced hydrogen gas may, however, have impurities. That gas may be referred to as a mixed gas stream that contains hydrogen gas and other gases. Prior to using the mixed gas stream, it must be purified, such as to remove at least a portion of the other gases. The hydrogen generation assembly may therefore include a hydrogen purification device for increasing the hydrogen purity of the mixed gas stream. The hydrogen purification device may include at least one hydrogen-selective membrane to separate the mixed gas stream into a product stream and a byproduct stream. The product stream contains a greater concentration of hydrogen gas and/or a reduced concentration of one or more of the other gases from the mixed gas stream. Hydrogen purification using one or more hydrogen-selective membranes is a pressure driven separation process in which the one or more hydrogen-selective membranes are contained in a pressure vessel. The mixed gas stream contacts the mixed gas surface of the membrane(s), and the product stream is formed from at least a portion of the mixed gas stream that permeates through the membrane(s). The pressure vessel is typically sealed to prevent gases from entering or leaving the pressure vessel except through defined inlet and outlet ports or conduits.
The product stream may be used in a variety of applications. One such application is energy production, such as in electrochemical fuel cells. An electrochemical fuel cell is a device that converts fuel and an oxidant to electricity, a reaction product, and heat. For example, fuel cells may convert hydrogen and oxygen into water and electricity. In those fuel cells, the hydrogen is the fuel, the oxygen is the oxidant, and the water is a reaction product. Fuel cell stacks include a plurality of fuel cells and may be utilized with a hydrogen generation assembly to provide an energy production assembly.
Examples of hydrogen generation assemblies, hydrogen processing assemblies, and/or components of those assemblies are described in U.S. Pat. Nos. 5,861,137; 6,319,306; 6,494,937; 6,562,111; 7,063,047; 7,306,868; 7,470,293; 7,601,302; 7,632,322; 8,961,627; and U.S. Patent Application Publication Nos. 2006/0090397; 2006/0272212; 2007/0266631; 2007/0274904; 2008/0085434; 2008/0138678; 2008/0230039; and 2010/0064887. The complete disclosures of the above patents and patent application publications are hereby incorporated by reference for all purposes.
In some embodiments, feedstock delivery system 22 may additionally include any suitable structure configured to selectively deliver at least one fuel stream 28 to a burner or other heating assembly of fuel processing assembly 24. In some embodiments, feed stream 26 and fuel stream 28 may be the same stream delivered to different parts of the fuel processing assembly. The feedstock delivery system may include any suitable delivery mechanisms, such as a positive displacement or other suitable pump or mechanism for propelling fluid streams. In some embodiments, feedstock delivery system may be configured to deliver feed stream(s) 26 and/or fuel stream(s) 28 without requiring the use of pumps and/or other electrically powered fluid-delivery mechanisms. Examples of suitable feedstock delivery systems that may be used with hydrogen generation assembly 20 include the feedstock delivery systems described in U.S. Pat. Nos. 7,470,293 and 7,601,302, and U.S. Patent Application Publication No. 2006/0090397. The complete disclosures of the above patents and patent application are hereby incorporated by reference for all purposes.
Feed stream 26 may include at least one hydrogen-production fluid 30, which may include one or more fluids that may be utilized as reactants to produce product hydrogen stream 21. For example, the hydrogen-production fluid may include a carbon-containing feedstock, such as at least one hydrocarbon and/or alcohol. Examples of suitable hydrocarbons include methane, propane, natural gas, diesel, kerosene, gasoline, etc. Examples of suitable alcohols include methanol, ethanol, polyols (such as ethylene glycol and propylene glycol), etc. Additionally, hydrogen-production fluid 30 may include water, such as when the fuel processing assembly generates the product hydrogen stream via steam reforming and/or autothermal reforming. When fuel processing assembly 24 generates the product hydrogen stream via pyrolysis or catalytic partial oxidation, feed stream 26 does not contain water.
In some embodiments, feedstock delivery system 22 may be configured to deliver a hydrogen-production fluid 30 that contains a mixture of water and a carbon-containing feedstock that is miscible with water (such as methanol and/or another water-soluble alcohol). The ratio of water to carbon-containing feedstock in such a fluid stream may vary according to one or more factors, such as the particular carbon-containing feedstock being used, user preferences, design of the fuel processing assembly, mechanism(s) used by the fuel processing assembly to generate the product hydrogen stream etc. For example, the molar ratio of water to carbon may be approximately 1:1 to 3:1. Additionally, mixtures of water and methanol may be delivered at or near a 1:1 molar ratio (37 weight % water, 63 weight % methanol), while mixtures of hydrocarbons or other alcohols may be delivered at a water-to-carbon molar ratio greater than 1:1.
When fuel processing assembly 24 generates product hydrogen stream 21 via reforming, feed stream 26 may include, for example, approximately 25-75 volume % methanol or ethanol (or another suitable water-miscible carbon-containing feedstock) and approximately 25-75 volume % water. For feed streams that at least substantially include methanol and water, those streams may include approximately 50-75 volume % methanol and approximately 25-50 volume % water. Streams containing ethanol or other water-miscible alcohols may contain approximately 25-60 volume % alcohol and approximately 40-75 volume % water. An example of a feed stream for hydrogen generating assembly 20 that utilizes steam reforming or autothermal reforming contains 69 volume % methanol and 31 volume % water.
Although feedstock delivery system 22 is shown to be configured to deliver a single feed stream 26, the feedstock delivery system may be configured to deliver two or more feed streams 26. Those streams may contain the same or different feedstocks and may have different compositions, at least one common component, no common components, or the same compositions. For example, a first feed stream may include a first component, such as a carbon-containing feedstock and a second feed stream may include a second component, such as water. Additionally, although feedstock delivery system 22 may, in some embodiments, be configured to deliver a single fuel stream 28, the feedstock delivery system may be configured to deliver two or more fuel streams. The fuel streams may have different compositions, at least one common component, no common components, or the same compositions. Moreover, the feed and fuel streams may be discharged from the feedstock delivery system in different phases. For example, one of the streams may be a liquid stream while the other is a gas stream. In some embodiments, both streams may be liquid streams, while in other embodiments both streams may be gas streams. Furthermore, although hydrogen generation assembly 20 is shown to include a single feedstock delivery system 22, the hydrogen generation assembly may include two or more feedstock delivery systems 22.
Fuel processing assembly 24 may include a hydrogen-producing region 32 configured to produce an output stream 34 containing hydrogen gas via any suitable hydrogen-producing mechanism(s). The output stream may include hydrogen gas as at least a majority component and may include additional gaseous component(s). Output stream 34 may therefore be referred to as a “mixed gas stream” that contains hydrogen gas as its majority component but which includes other gases.
Hydrogen-producing region 32 may include any suitable catalyst-containing bed or region. When the hydrogen-producing mechanism is steam reforming, the hydrogen-producing region may include a suitable steam reforming catalyst 36 to facilitate production of output stream(s) 34 from feed stream(s) 26 containing a carbon-containing feedstock and water. In such an embodiment, fuel processing assembly 24 may be referred to as a “steam reformer,” hydrogen-producing region 32 may be referred to as a “reforming region,” and output stream 34 may be referred to as a “reformate stream.” The other gases that may be present in the reformate stream may include carbon monoxide, carbon dioxide, methane, steam, and/or unreacted carbon-containing feedstock.
When the hydrogen-producing mechanism is autothermal reforming, hydrogen-producing region 32 may include a suitable autothermal reforming catalyst to facilitate the production of output stream(s) 34 from feed stream(s) 26 containing water and a carbon-containing feedstock in the presence of air. Additionally, fuel processing assembly 24 may include an air delivery assembly 38 configured to deliver air stream(s) to the hydrogen-producing region.
In some embodiments, fuel processing assembly 24 may include a purification (or separation) region 40, which may include any suitable structure configured to produce at least one hydrogen-rich stream 42 from output (or mixed gas) stream 34. Hydrogen-rich stream 42 may include a greater hydrogen concentration than output stream 34 and/or a reduced concentration of one or more other gases (or impurities) that were present in that output stream. Product hydrogen stream 21 includes at least a portion of hydrogen-rich stream 42. Thus, product hydrogen stream 21 and hydrogen-rich stream 42 may be the same stream and have the same composition and flow rates. Alternatively, some of the purified hydrogen gas in hydrogen-rich stream 42 may be stored for later use, such as in a suitable hydrogen storage assembly and/or consumed by the fuel processing assembly. Purification region 40 also may be referred to as a “hydrogen purification device” or a “hydrogen processing assembly.”
In some embodiments, purification region 40 may produce at least one byproduct stream 44, which may contain no hydrogen gas or some hydrogen gas. The byproduct stream may be exhausted, sent to a burner assembly and/or other combustion source, used as a heated fluid stream, stored for later use, and/or otherwise utilized, stored, and/or disposed. Additionally, purification region 40 may emit the byproduct stream as a continuous stream responsive to the delivery of output stream 34, or may emit that stream intermittently, such as in a batch process or when the byproduct portion of the output stream is retained at least temporarily in the purification region.
Fuel processing assembly 24 may include one or more purification regions configured to produce one or more byproduct streams containing sufficient amounts of hydrogen gas to be suitable for use as a fuel stream (or a feedstock stream) for a heating assembly for the fuel processing assembly. In some embodiments, the byproduct stream may have sufficient fuel value or hydrogen content to enable a heating assembly to maintain the hydrogen-producing region at a desired operating temperature or within a selected range of temperatures. For example, the byproduct stream may include hydrogen gas, such as 10-30 volume % hydrogen gas, 15-25 volume % hydrogen gas, 20-30 volume % hydrogen gas, at least 10 or 15 volume % hydrogen gas, at least 20 volume % hydrogen gas, etc.
Purification region 40 may include any suitable structure configured to enrich (and/or increase) the concentration of at least one component of output stream 21. In most applications, hydrogen-rich stream 42 will have a greater hydrogen concentration than output stream (or mixed gas stream) 34. The hydrogen-rich stream also may have a reduced concentration of one or more non-hydrogen components that were present in output stream 34 with the hydrogen concentration of the hydrogen-rich stream being more, the same, or less than the output stream. For example, in conventional fuel cell systems, carbon monoxide may damage a fuel cell stack if it is present in even a few parts per million, while other non-hydrogen components that may be present in output stream 34, such as water, will not damage the stack even if present in much greater concentrations. Therefore, in such an application, the purification region may not increase the overall hydrogen concentration but will reduce the concentration of one or more non-hydrogen components that are harmful, or potentially harmful, to the desired application for the product hydrogen stream.
Examples of suitable devices for purification region 40 include one or more hydrogen-selective membranes 46, chemical carbon monoxide removal assemblies 48, and/or pressure swing adsorption (PSA) systems 50. Purification region 40 may include more than one type of purification device and the devices may have the same or different structures and/or operate by the same or different mechanism(s). Fuel processing assembly 24 may include at least one restrictive orifice and/or other flow restrictor downstream of the purification region(s), such as associated with one or more product hydrogen stream(s), hydrogen-rich stream(s), and/or byproduct stream(s).
Hydrogen-selective membranes 46 are permeable to hydrogen gas, but are at least substantially (if not completely) impermeable to other components of output stream 34. Membranes 46 may be formed of any hydrogen-permeable material suitable for use in the operating environment and parameters in which purification region 40 is operated. Examples of suitable materials for membranes 46 include palladium and palladium alloys, and especially thin films of such metals and metal alloys. Palladium alloys have proven particularly effective, especially palladium with 35 weight % to 45 weight % copper. A palladium-copper alloy that contains approximately 40 weight % copper has proven particularly effective, although other relative concentrations and components may be used. Three other especially effective alloys are palladium with 2 weight % to 20 weight % gold, especially palladium with 5 weight % gold; palladium with 3 weight % to 10 weight % indium plus 0 weight % to 10 weight % ruthenium, especially palladium with 6 weight % indium plus 0.5 weight % ruthenium; and palladium with 20 weight % to 30 weight % silver. When palladium and palladium alloys are used, hydrogen-selective membranes 46 may sometimes be referred to as “foils.” Typical thickness of hydrogen-permeable metal foils is less than 25 microns (micrometers), preferably less than or equal to 15 microns, and most preferably between 5 and 12 microns. The foils may be any suitable dimensions, such as 110 mm by 270 mm.
Chemical carbon monoxide removal assemblies 48 are devices that chemically react carbon monoxide and/or other undesirable components of output stream 34 to form other compositions that are not as potentially harmful. Examples of chemical carbon monoxide removal assemblies include water-gas shift reactors that are configured to produce hydrogen gas and carbon dioxide from water and carbon monoxide, partial oxidation reactors that are configured to convert carbon monoxide and oxygen (usually from air) into carbon dioxide, and methanation reactors that are configured to convert carbon monoxide and hydrogen to methane and water. Fuel processing assembly 24 may include more than one type and/or number of chemical removal assemblies 48.
Pressure swing adsorption (PSA) is a chemical process in which gaseous impurities are removed from output stream 34 based on the principle that certain gases, under the proper conditions of temperature and pressure, will be adsorbed onto an adsorbent material more strongly than other gases. Typically, the non-hydrogen impurities are adsorbed and removed from output stream 34. Adsorption of impurity gases occurs at elevated pressure. When the pressure is reduced, the impurities are desorbed from the adsorbent material, thus regenerating the adsorbent material. Typically, PSA is a cyclic process and requires at least two beds for continuous (as opposed to batch) operation. Examples of suitable adsorbent materials that may be used in adsorbent beds are activated carbon and zeolites. PSA system 50 also provides an example of a device for use in purification region 40 in which the byproducts, or removed components, are not directly exhausted from the region as a gas stream concurrently with the purification of the output stream. Instead, these byproduct components are removed when the adsorbent material is regenerated or otherwise removed from the purification region.
In
Fuel processing assembly 24 also may include a temperature modulating assembly in the form of a heating assembly 52. The heating assembly may be configured to produce at least one heated exhaust stream (or combustion stream) 54 from at least one heating fuel stream 28, typically as combusted in the presence of air. Heated exhaust stream 54 is schematically illustrated in
In some embodiments, heating assembly 52 may include a burner assembly 60 and may be referred to as a combustion-based, or combustion-driven, heating assembly. In a combustion-based heating assembly, heating assembly 52 may be configured to receive at least one fuel stream 28 and to combust the fuel stream in the presence of air to provide a hot combustion stream 54 that may be used to heat at least the hydrogen-producing region of the fuel processing assembly. Air may be delivered to the heating assembly via a variety of mechanisms. For example, an air stream 62 may be delivered to the heating assembly as a separate stream, as shown in
Combustion stream 54 may additionally, or alternatively, be used to heat other portions of the fuel processing assembly and/or fuel cell systems with which the heating assembly is used. Additionally, other configuration and types of heating assemblies 52 may be used. For example, heating assembly 52 may be an electrically powered heating assembly that is configured to heat at least hydrogen-producing region 32 of fuel processing assembly 24 by generating heat using at least one heating element, such as a resistive heating element. In those embodiments, heating assembly 52 may not receive and combust a combustible fuel stream to heat the hydrogen-producing region to a suitable hydrogen-producing temperature. Examples of heating assemblies are disclosed in U.S. Pat. No. 7,632,322, the complete disclosure of which is hereby incorporated by reference for all purposes.
Heating assembly 52 may be housed in a common shell or housing with the hydrogen-producing region and/or separation region (as further discussed below). The heating assembly may be separately positioned relative to hydrogen-producing region 32 but in thermal and/or fluid communication with that region to provide the desired heating of at least the hydrogen-producing region. Heating assembly 52 may be located partially or completely within the common shell, and/or at least a portion (or all) of the heating assembly may be located external that shell. When the heating assembly is located external the shell, the hot combustion gases from burner assembly 60 may be delivered via suitable heat transfer conduits to one or more components within the shell.
The heating assembly also may be configured to heat feedstock delivery system 22, the feedstock supply streams, hydrogen-producing region 32, purification (or separation) region 40, or any suitable combination of those systems, streams, and regions. Heating of the feedstock supply streams may include vaporizing liquid reactant streams or components of the hydrogen-production fluid used to produce hydrogen gas in the hydrogen-producing region. In that embodiment, fuel processing assembly 24 may be described as including a vaporization region 64. The heating assembly may additionally be configured to heat other components of the hydrogen generation assembly. For example, the heated exhaust stream may be configured to heat a pressure vessel and/or other canister containing the heating fuel and/or the hydrogen-production fluid that forms at least portions of feed stream 26 and fuel stream 28.
Heating assembly 52 may achieve and/or maintain in hydrogen-producing region 32 any suitable temperatures. Steam reformers typically operate at temperatures in the range of 200° C. and 900° C. However, temperatures outside this range are within the scope of this disclosure. When the carbon-containing feedstock is methanol, the steam reforming reaction will typically operate in a temperature range of approximately 200-500° C. Example subsets of that range include 350-450° C., 375-425° C., and 375-400° C. When the carbon-containing feedstock is a hydrocarbon, ethanol or another alcohol, a temperature range of approximately 400-900° C. will typically be used for the steam reforming reaction. Example subsets of that range include 750-850° C., 725-825° C., 650-750° C., 700-800° C., 700-900° C., 500-800° C., 400-600° C., and 600-800° C. Hydrogen-producing region 32 may include two or more zones, or portions, each of which may be operated at the same or at different temperatures. For example, when the hydrogen-production fluid includes a hydrocarbon, hydrogen-producing region 32 may include two different hydrogen-producing portions, or regions, with one operating at a lower temperature than the other to provide a pre-reforming region. In those embodiments, the fuel processing assembly may also be referred to as including two or more hydrogen-producing regions.
Fuel stream 28 may include any combustible liquid(s) and/or gas(es) that are suitable for being consumed by heating assembly 52 to provide the desired heat output. Some fuel streams may be gases when delivered and combusted by heating assembly 52, while others may be delivered to the heating assembly as a liquid stream. Examples of suitable heating fuels for fuel streams 28 include carbon-containing feedstocks, such as methanol, methane, ethane, ethanol, ethylene, propane, propylene, butane, etc. Additional examples include low molecular weight condensable fuels, such as liquefied petroleum gas, ammonia, lightweight amines, dimethyl ether, and low molecular weight hydrocarbons. Yet other examples include hydrogen and carbon monoxide. In embodiments of hydrogen generation assembly 20 that include a temperature modulating assembly in the form of a cooling assembly instead of a heating assembly (such as may be used when an exothermic hydrogen-generating process—e.g., partial oxidation—is utilized instead of an endothermic process such as steam reforming), the feedstock delivery system may be configured to supply a fuel or coolant stream to the assembly. Any suitable fuel or coolant fluid may be used.
Fuel processing assembly 24 may additionally include a shell or housing 66 in which at least hydrogen-producing region 32 is contained, as shown in
One or more components of fuel processing assembly 24 may either extend beyond the shell or be located external the shell. For example, purification region 40 may be located external shell 66, such as being spaced-away from the shell but in fluid communication by suitable fluid-transfer conduits. As another example, a portion of hydrogen-producing region 32 (such as portions of one or more reforming catalyst beds) may extend beyond the shell, such as indicated schematically with a dashed line representing an alternative shell configuration in
Another example of hydrogen generation assembly 20 is shown in
The feedstock delivery system may include any suitable structure configured to deliver one or more feed and/or fuel streams to one or more other components of the hydrogen-generation assembly. For example, feedstock delivery system may include a feedstock tank (or container) 84 and a pump 86. The feedstock tank may contain any suitable hydrogen-production fluid 88, such as water and a carbon-containing feedstock (e.g., a methanol/water mixture). Pump 86 may have any suitable structure configured to deliver the hydrogen-production fluid, which may be in the form of at least one liquid-containing feed stream 90 that includes water and a carbon-containing feedstock, to vaporization region 76 and/or hydrogen-producing region 78.
Vaporization region 76 may include any suitable structure configured to receive and vaporize at least a portion of a liquid-containing feed stream, such as liquid-containing feed stream 90. For example, vaporization region 76 may include a vaporizer 92 configured to at least partially transform liquid-containing feed stream 90 into one or more vapor feed streams 94. The vapor feed streams may, in some embodiments, include liquid. An example of a suitable vaporizer is a coiled tube vaporizer, such as a coiled stainless steel tube.
Hydrogen-producing region 78 may include any suitable structure configured to receive one or more feed streams, such as vapor feed stream(s) 94 from the vaporization region, to produce one or more output streams 96 containing hydrogen gas as a majority component and other gases. The hydrogen-producing region may produce the output stream via any suitable mechanism(s). For example, hydrogen-producing region 78 may generate output stream(s) 96 via a steam reforming reaction. In that example, hydrogen-producing region 78 may include a steam reforming region 97 with a reforming catalyst 98 configured to facilitate and/or promote the steam reforming reaction. When hydrogen-producing region 78 generates output stream(s) 96 via a steam reforming reaction, hydrogen generation assembly 72 may be referred to as a “steam reforming hydrogen generation assembly” and output stream 96 may be referred to as a “reformate stream.”
Heating assembly 80 may include any suitable structure configured to produce at least one heated exhaust stream 99 for heating one or more other components of the hydrogen generation assembly 72. For example, the heating assembly may heat the vaporization region to any suitable temperature(s), such as at least a minimum vaporization temperature or the temperature in which at least a portion of the liquid-containing feed stream is vaporized to form the vapor feed stream. Additionally, or alternatively, heating assembly 80 may heat the hydrogen-producing region to any suitable temperature(s), such as at least a minimum hydrogen-producing temperature or the temperature in which at least a portion of the vapor feed stream is reacted to produce hydrogen gas to form the output stream. The heating assembly may be in thermal communication with one or more components of the hydrogen generation assembly, such as the vaporization region and/or hydrogen-producing region.
The heating assembly may include a burner assembly 100, at least one air blower 102, and an igniter assembly 104, as shown in
Purification region 82 may include any suitable structure configured to produce at least one hydrogen-rich stream 112, which may include a greater hydrogen concentration than output stream 96 and/or a reduced concentration of one or more other gases (or impurities) that were present in that output stream. The purification region may produce at least one byproduct stream or fuel stream 108, which may be sent to burner assembly 100 and used as a fuel stream for that assembly, as shown in
Membrane assembly 116 may include any suitable structure configured to receive output or mixed gas stream(s) 96 that contains hydrogen gas and other gases, and to generate permeate or hydrogen-rich stream(s) 112 containing a greater concentration of hydrogen gas and/or a lower concentration of other gases than the mixed gas stream. Membrane assembly 116 may incorporate hydrogen-permeable (or hydrogen-selective) membranes that are planar or tubular, and more than one hydrogen-permeable membrane may be incorporated into membrane assembly 116. The permeate stream(s) may be used for any suitable applications, such as for one or more fuel cells. In some embodiments, the membrane assembly may generate a byproduct or fuel stream 108 that includes at least a substantial portion of the other gases. Methanation reactor assembly 118 may include any suitable structure configured to convert carbon monoxide and hydrogen to methane and water. Although purification region 82 is shown to include flow restricting orifice 111, filter assembly 114, membrane assembly 116, and methanation reactor assembly 118, the purification region may have less than all of those assemblies, and/or may alternatively, or additionally, include one or more other components configured to purify output stream 96. For example, purification region 82 may include only membrane assembly 116.
In some embodiments, hydrogen generation assembly 72 may include a shell or housing 120 which may at least partially contain one or more other components of that assembly. For example, shell 120 may at least partially contain vaporization region 76, hydrogen-producing region 78, heating assembly 80, and/or purification region 82, as shown in
Hydrogen generation assembly 72 may, in some embodiments, include a control system 126, which may include any suitable structure configured to control operation of hydrogen generation assembly 72. For example, control assembly 126 may include a control assembly 128, at least one valve 130, at least one pressure relief valve 132, and one or more temperature measurement devices 134. Control assembly 128 may detect temperatures in the hydrogen-producing region and/or purification regions via the temperature measurement device 134, which may include one or more thermocouples and/or other suitable devices. Based on the detected temperatures, the control assembly and/or an operator of the control system may adjust delivery of feed stream 90 to vaporization region 76 and/or hydrogen-producing region 78 via valve(s) 130 and pump(s) 86. Valve(s) 130 may include a solenoid valve and/or any suitable valve(s). Pressure relief valve(s) 132 may be configured to ensure that excess pressure in the system is relieved.
In some embodiments, hydrogen generation assembly 72 may include a heat exchange assembly 136, which may include one or more heat exchangers 138 configured to transfer heat from one portion of the hydrogen generation assembly to another portion. For example, heat exchange assembly 136 may transfer heat from hydrogen-rich stream 112 to feed stream 90 to raise the temperature of the feed stream prior to entering vaporization region 76, as well as to cool hydrogen-rich stream 112.
An example of a purification region 40 (or hydrogen purification device) of hydrogen generation assembly 20 of
First and second portions 154 and 156 may be coupled together using any suitable retention mechanism or structure 158. Examples of suitable retention structures include welds and/or bolts. Examples of seals that may be used to provide a fluid-tight interface between the first and second portions may include gaskets and/or welds. Additionally, or alternatively, first and second portions 154 and 156 may be secured together so that at least a predetermined amount of compression is applied to various components that define the hydrogen-separation region within the enclosure and/or other components that may be incorporated into a hydrogen generation assembly. The applied compression may ensure that various components are maintained in appropriate positions within the enclosure. Additionally, or alternatively, the compression applied to the various components that define the hydrogen-separation region and/or other components may provide fluid-tight interfaces between the various components that define the hydrogen-separation region, various other components, and/or between the components that define the hydrogen-separation region and other components.
Enclosure 148 may include a mixed gas region 160 and a permeate region 162, as shown in
Enclosure 148 also may include at least one product output port 174 through which a permeate stream 176 may be received and removed from permeate region 162. The permeate stream may contain at least one of a greater concentration of hydrogen gas and a lower concentration of other gases than the mixed gas stream. Permeate stream 176 may, in some embodiments, include at least initially a carrier, or sweep, gas component, such as may be delivered as a sweep gas stream 178 through a sweep gas port 180 that is in fluid communication with the permeate region. The enclosure also may include at least one byproduct output port 182 through which a byproduct stream 184 containing at least one of a substantial portion of other gases 172 and a reduced concentration of hydrogen gas 170 (relative to the mixed gas stream) is removed from the mixed gas region.
Hydrogen-separation region 146 may include at least one hydrogen-selective membrane 186 having a first or mixed gas surface 188, which is oriented for contact by mixed gas stream 168, and a second or permeate surface 190, which is generally opposed to surface 188. Mixed gas stream 168 may be delivered to the mixed gas region of the enclosure so that it comes into contact with the mixed gas surface of the one or more hydrogen-selective membranes. Permeate stream 176 may be formed from at least a portion of the mixed gas stream that passes through the hydrogen-separation region to permeate region 162. Byproduct stream 184 may be formed from at least a portion of the mixed gas stream that does not pass through the hydrogen-separation region. In some embodiments, byproduct stream 184 may contain a portion of the hydrogen gas present in the mixed gas stream. The hydrogen-separation region also may be configured to trap or otherwise retain at least a portion of the other gases, which may then be removed as a byproduct stream as the separation region is replaced, regenerated, or otherwise recharged.
In
The hydrogen-selective membranes may be formed of any hydrogen-permeable material suitable for use in the operating environment and parameters in which the hydrogen purification device is operated. Examples of hydrogen purification devices are disclosed in U.S. Pat. Nos. 5,997,594 and 6,537,352, the complete disclosures of which are hereby incorporated by reference for all purposes. In some embodiments, the hydrogen-selective membranes may be formed from at least one of palladium and a palladium alloy. Examples of palladium alloys include alloys of palladium with copper, silver, and/or gold. Examples of various membranes, membrane configuration, and methods for preparing membranes and membrane configurations are disclosed in U.S. Pat. Nos. 6,152,995; 6,221,117; 6,319,306; and 6,537,352, the complete disclosures of which are hereby incorporated by reference for all purposes.
In some embodiments, a plurality of spaced-apart hydrogen-selective membranes 186 may be used in a hydrogen-separation region to form at least a portion of a hydrogen-separation assembly 192. When present, the plurality of membranes may collectively define one or more membrane assemblies 194. In such embodiments, the hydrogen-separation assembly may generally extend from first portion 154 to second portion 156. Thus, the first and second portions may effectively compress the hydrogen-separation assembly. In some embodiments, enclosure 148 may additionally, or alternatively, include end plates (or end frames) coupled to opposite sides of a body portion. In such embodiments, the end plates may effectively compress the hydrogen-separation assembly (and other components that may be housed within the enclosure) between the pair of opposing end plates.
Hydrogen purification using one or more hydrogen-selective membranes is typically a pressure-driven separation process in which the mixed gas stream is delivered into contact with the mixed gas surface of the membranes at a higher pressure than the gases in the permeate region of the hydrogen-separation region. The hydrogen-separation region may, in some embodiments, be heated via any suitable mechanism to an elevated temperature when the hydrogen-separation region is utilized to separate the mixed gas stream into the permeate and byproduct streams. Examples of suitable operating temperatures for hydrogen purification using palladium and palladium alloy membranes include temperatures of at least 275° C., temperatures of at least 325° C., temperatures of at least 350° C., temperatures in the range of 275-500° C., temperatures in the range of 275-375° C., temperatures in the range of 300-450° C., temperatures in the range of 350-450° C., etc.
An example of a hydrogen purification device 144 is generally indicated at 196 in
Hydrogen purification device 196 also may include at least one foil-microscreen assembly 205, which may be disposed between and/or secured to the first and second end plates. The foil-microscreen assembly may include at least one hydrogen-selective membrane 206 and at least one microscreen structure 208, as shown in
One or more of the hydrogen-selective membranes may be metallurgically bonded to microscreen structure 208. For example, the permeate side of the hydrogen-selective membrane(s) may be metallurgically bonded to the microscreen structure. In some embodiments, one or more of hydrogen-selective membranes 206 (and/or the permeate side of those membrane(s)) may be diffusion bonded to the microscreen structure to form a solid-state diffusion bond between the membrane(s) and the microscreen structure. For example, the permeate side of the membrane(s) and the microscreen structure may be brought in contact with each other and exposed to elevated temperature and/or elevated pressure to allow the surfaces of the membrane(s) and the microscreen structure to intersperse themselves over time.
In some embodiments, the microscreen structure may be coated with a thin layer of a metal or intermediate bonding layer that aids in the diffusion bonding. For example, a thin coating of nickel, copper, silver, gold, or other metal that is amenable to solid-state diffusion bonding but does not (1) melt and enter the liquid phase at less than or equal to 700° C. and (2) form a low-melting alloy at less than or equal to 700° C. upon diffusion into the hydrogen-selective membrane(s). The thin metal layer may be applied to the microscreen structure via a suitable deposition process (e.g., electrochemical plating, vapor deposition, sputtering, etc.) of a thin coating of the intermediate bonding layer onto the surface of the microscreen structure that will be in contact with the hydrogen-selective membrane. In some embodiments, foil-microscreen assembly 205 includes only the hydrogen-selective membrane(s) and the microscreen structure(s) (with or without the above coating) and without any other frames, gaskets, components, and/or structures attached, bonded, and/or metallurgically bonded to the either or both of the hydrogen-selective membrane(s) and/or the microscreen structure(s). In other embodiments, the hydrogen-selective membrane(s) may be secured to at least one membrane frame (not shown), which may then be secured to the first and second end frames.
Microscreen structure 208 may include any suitable structure configured to support the at least one hydrogen-selective membrane. For example, the microscreen structure may include a non-porous planar sheet 213 having generally opposed surfaces 214 and 215 configured to provide support to permeate side 212, and a plurality of apertures 216 that forms a plurality of fluid passages 217 extending between the opposed surfaces which allows the permeate stream to flow through the microscreen structure, as shown in
In some embodiments, microscreen structure 208 may include one or more perforated areas (or portions) 218 that include the plurality of apertures and one or more non-perforated areas (or portions) 219 that do not include (or exclude) the plurality of apertures. Although only a few apertures 216 are illustrated in
Apertures 216 may include any suitable pattern(s), shape(s), and/or size(s). In some embodiments, the apertures may be formed with one or more patterns that maximize combined aperture area while maintaining a high enough stiffness of the microscreen structure to prevent excessive deflection under a pressure load. Apertures 216 may be circles (circular) as shown in
Apertures 216 may have any suitable orientation(s) and/or be in any suitable pattern(s). For example,
Although apertures 216 are all shown to be in the same direction or orientation in
The apertures may be any suitable size(s). For example, when the apertures are circles, the diameters may range from about 0.003 inches to about 0.020 inches. Additionally, when the apertures are ovals or ellipses, the radius of the rounded ends of the oval or ellipses may range from 0.001 inches to about 0.010 inches and the length of the oval or ellipses may be up to ten times the radius. Moreover, when the apertures are elongated circles or stadium-shaped, the width or diameter may range from 0.005 inches to 0.02 inches and the length may be from 0.05 inches to over ten times the diameter, such as 0.8 inches. An example of dimensions for the apertures in
In some examples, one or more apertures 216 may be sized to span the entire or substantially the entire width or length of the perforated area. In the example shown in
In some examples, apertures 216 may have a combination of sizes. For example, apertures 216 may be sized such that planar sheet 213 includes rows and/or columns of apertures having (1) a smaller number of apertures having one or more longer lengths and (2) a larger number of apertures having one or more shorter lengths. In some examples, the rows and/or columns with a smaller number of apertures having a longer length alternate with rows and/or columns with a larger number of apertures having a shorter length, such as in a staggered pattern. In the example shown in
The non-porous planar sheet may include any suitable materials. For example, the non-porous planar sheet may include stainless steel. The stainless steel may include 300-series stainless steel (e.g., stainless steel 303 (aluminum modified), stainless steel 304, etc.), 400-series stainless steel, 17-7 PH, 14-8 PH, and/or 15-7 PH. In some embodiments, the stainless steel may include about 0.6 weight % to about 3.0 weight % of aluminum. In some embodiments, the non-porous planar sheet may include carbon steel, copper or copper alloys, aluminum or aluminum alloys, nickel, nickel-copper alloys, and/or base metals plated with silver, nickel, and/or copper. The base metals may include carbon steel or one or more of the stainless steels discussed above.
Hydrogen-selective membrane 206 may be sized larger than the perforated area or field of the microscreen structure such that a perimeter portion 222 of the hydrogen-selective membrane contacts one or more non-perforated areas 219 of the microscreen structure when the hydrogen-selective membrane is metallurgically bonded to the microscreen structure. In some embodiments, a single hydrogen-selective membrane may be metallurgically bonded to a single microscreen structure, as shown in
When two or more hydrogen-selective membranes 206 are metallurgically bonded to the microscreen structure, the microscreen structure may include two or more discrete perforated areas 218 separated by one or more non-perforated areas 219. In some embodiments, a perforated area 218 may be sized the same as the other perforated areas 218. For example,
Microscreen structure 208 may be sized to be contained (such as entirely contained) within the open region of the permeate frame and/or supported by the membrane support structure within that open region, as shown in
Hydrogen purification device 196 also may include a plurality of plates or frames 224 disposed between and secured to the first and/or second end frames. The frames may include any suitable structure and/or may be any suitable shape(s), such as square, rectangular, or circular. For example, frames 224 may include a perimeter shell 226 and at least a first support member 228, as shown in
First support member 228 may include any suitable structure configured to support a first portion 242 of foil-microscreen assembly 205, as shown in
In some embodiments, frames 224 may include a second support member 246 and/or third support member 248, which may include any suitable structure configured to support a second portion 250 and/or a third portion 252 of foil-microscreen assembly 205, as shown in
Second support member 246 and/or third support member 248 may have any suitable orientation to first support member 228. For example, first support member 228 may extend into open region 230 from third side 238 of perimeter shell 226; second support member 246 may extend into the open region from fourth side 240 (which is opposed from the third side) of the perimeter shell; and third support member 248 may extend into the open region from the third side. Alternatively, the first, second, and/or third support members may extend into the open region from the same side, such as from the first, second, third, or fourth sides of the perimeter shell. In some embodiments, the first, second, and/or third support members may extend into the open region from the first side and/or second side (which is opposed from the first side) of the perimeter shell.
The first, second, and/or third support members may, for example, be in the form of one or more projections or fingers 258 attached to the perimeter shell and/or formed with the perimeter shell. The projections may extend from the perimeter shell in any suitable direction(s). The projections may be the full thickness of the perimeter shell or may be less than the full thickness of that shell. The projections of each frame of frames 224 may be compressed against the foil-microscreen assembly thereby locking that assembly in place. In other words, the projections of frames 224 may support the foil-microscreen assembly by being stacked extension(s) of the end frames within the first and/or second membrane support plane. In some embodiments, projection(s) 258 may include one or more receptacles or apertures (not shown) configured to receive at least one fastener (not shown) to secure frames 224 to the first and/or second end frames.
Frames 224 may include at least one feed frame 260, at least one permeate frame 262, and a plurality of gaskets or gasket frames 264, as shown in
Another example of hydrogen purification device 144 is generally indicated at 396 in
Hydrogen purification device 396 is similar in many respects to hydrogen purification device 196 but with different-shaped frames, no support members, different-sized foil-microscreen assemblies, and less gasket frames, as further described below. Components or parts of hydrogen purification device 396 correspond to components or parts of hydrogen purification device 196, and are labeled with similar reference numbers in
Hydrogen purification device 396 may include a shell or enclosure 398, which may include a first end plate or end frame 400 and a second end plate or end frame 402. The first and second end plates may be configured to be secured and/or compressed together to define a sealed pressure vessel having an interior compartment 404 in which the hydrogen-separation region is supported.
Hydrogen purification device 396 also may include at least one foil-microscreen assembly 405, which may be disposed between and/or secured to the first and second end plates. The foil-microscreen assembly may include at least one hydrogen-selective membrane 406 and at least one microscreen structure 408. One or more of the hydrogen-selective membranes may be metallurgically bonded to microscreen structure 408. For example, one or more of hydrogen-selective membranes 406 may be diffusion bonded to the microscreen structure to form a solid-state diffusion bond between the membrane(s) and the microscreen structure. Foil-microscreen assembly 405 is sized to fit the open region of the permeate frame and is thus smaller in length and width as compared or relative to foil-microscreen assembly 205.
Hydrogen purification device 396 also may include a plurality of plates or frames 424 disposed between and secured to the first and/or second end frames. Frames 424 may include a perimeter shell 426. The perimeter shell may define an open region 430. Additionally, perimeter shell 426 may include first and second opposed sides 434 and 436, and third and fourth opposed sides 438 and 440. Unlike frames 224 of hydrogen purification device 196, frames 424 do not include any support members.
Frames 424 may include at least one feed frame 460, at least one permeate frame 462, and a plurality of gaskets or gasket frames 464. Feed frame 460 may be disposed between one of the first and second end frames and at least foil-microscreen assembly 405, or between two foil-microscreen assemblies 405. The feed frame may include at least substantially similar components as feed frame 260, such as a feed frame perimeter shell, a feed frame input conduit, a feed frame output conduit, and/or a feed frame open region.
Permeate frame 462 may be positioned such that the at least one foil-microscreen assembly is disposed between one of the first and second end frames and the permeate frame or between two foil-microscreen assemblies. The permeate frame may include at least substantially similar components as permeate frame 262, such as a permeate frame perimeter shell, a permeate frame output conduit, a permeate frame open region, and/or a membrane support structure.
Frames 424 also may include gaskets or gasket frames 464. The gasket frames may include any suitable structure configured to provide fluid-tight interfaces among the other frames, such as between first and second end plates 400 and 402 and feed frames 460, and/or between feed frames 460 and foil-microscreen assemblies 405. Unlike hydrogen purification device 196, hydrogen purification device 396 does not include gasket frames 464 between the foil-microscreen assemblies and permeate frame 462. Similar to hydrogen purification device 196, the widths of the feed frame and the gasket frames are larger than the widths of the permeate frame (or the open region of the feed frame and the gasket frames is smaller than the open region of the permeate frame) such that the extra width covers the edge of the foil-microscreen assemblies to eliminate or minimize leak from the feed side to the permeate side or from the permeate side to the feed side (e.g., extra width of the feed frames and gasket frames to cover the edge of the foil-microscreen assemblies). In some embodiments, the extra width corresponds to the width of the perimeter (non-perforated) portion of the microscreen structure of the foil-microscreen assemblies.
The present disclosure, including hydrogen purification devices and components of those devices, is applicable to the fuel-processing and other industries in which hydrogen gas is purified, produced, and/or utilized.
The disclosure set forth above encompasses multiple distinct inventions with independent utility. While each of these inventions has been disclosed in its preferred form, the specific embodiments thereof as disclosed and illustrated herein are not to be considered in a limiting sense as numerous variations are possible. The subject matter of the inventions includes all novel and non-obvious combinations and subcombinations of the various elements, features, functions and/or properties disclosed herein. Similarly, where any claim recites “a” or “a first” element or the equivalent thereof, such claim should be understood to include incorporation of one or more such elements, neither requiring nor excluding two or more such elements.
Inventions embodied in various combinations and subcombinations of features, functions, elements, and/or properties may be claimed through presentation of new claims in a related application. Such new claims, whether they are directed to a different invention or directed to the same invention, whether different, broader, narrower or equal in scope to the original claims, are also regarded as included within the subject matter of the inventions of the present disclosure.
This application claims benefit of U.S. Provisional Application No. 63/071,139 filed Aug. 27, 2020 and entitled “Hydrogen Purification Devices.” This application is also a continuation-in-part of U.S. patent application Ser. No. 16/904,872, filed Jun. 18, 2020 and entitled “Hydrogen Purification Devices,” which is a divisional application of U.S. patent application Ser. No. 15/862,474, filed Jan. 4, 2018 and now issued as U.S. Pat. No. 10,717,040 and entitled “Hydrogen Purification Devices,” which is a continuation-in-part application of U.S. patent application Ser. No. 15/483,265, filed Apr. 10, 2017 and now issued as U.S. Pat. No. 10,166,506 and entitled “Hydrogen Generation Assemblies and Hydrogen Purification Devices”, which is a continuation of U.S. patent application Ser. No. 14/931,585, filed Nov. 3, 2015 and now issued as U.S. Pat. No. 9,616,389, and entitled “Hydrogen Generation Assemblies and Hydrogen Purification Devices”, which is a divisional of U.S. patent application Ser. No. 13/829,766, filed Mar. 14, 2013, and now issued at U.S. Pat. No. 9,187,324, and entitled “Hydrogen Generation Assemblies and Hydrogen Purification Devices”, which is a continuation-in-part of U.S. patent application Ser. No. 13/600,096, filed Aug. 30, 2012, and entitled “Hydrogen Generation Assemblies” now abandoned. The complete disclosures of the above applications are hereby incorporated by reference for all purposes.
| Number | Name | Date | Kind |
|---|---|---|---|
| 2196463 | Holleran | Apr 1940 | A |
| 3154920 | Nash et al. | Nov 1964 | A |
| 3608610 | Greatorex et al. | Sep 1971 | A |
| 3761382 | Hammond et al. | Sep 1973 | A |
| 3761386 | Smith | Sep 1973 | A |
| 3935636 | Mermelstein | Feb 1976 | A |
| 3984324 | Wang | Oct 1976 | A |
| 4124478 | Tsien et al. | Nov 1978 | A |
| 4319978 | Millman | Mar 1982 | A |
| 4345555 | Oshima | Aug 1982 | A |
| 4472176 | Rubin | Sep 1984 | A |
| 4692306 | Minet | Sep 1987 | A |
| 4702312 | Brown | Oct 1987 | A |
| 4887556 | Gladstone | Dec 1989 | A |
| 4896636 | Pfefferle | Jan 1990 | A |
| 5053195 | MacKay | Oct 1991 | A |
| 5139541 | Edlund | Aug 1992 | A |
| 5146881 | Pfefferle | Sep 1992 | A |
| 5164163 | Aoki et al. | Nov 1992 | A |
| 5182075 | Gotoh et al. | Jan 1993 | A |
| 5217506 | Edlund et al. | Jun 1993 | A |
| 5259870 | Edlund | Nov 1993 | A |
| 5266283 | Friesen et al. | Nov 1993 | A |
| 5393325 | Edlund | Feb 1995 | A |
| 5498278 | Edlund | Mar 1996 | A |
| 5536405 | Myrna et al. | Jul 1996 | A |
| 5580476 | Dam | Dec 1996 | A |
| 5636511 | Pfefferle | Jun 1997 | A |
| 5645626 | Edlund et al. | Jul 1997 | A |
| 5711882 | Hofmann et al. | Jan 1998 | A |
| 5782960 | Ogawa et al. | Jul 1998 | A |
| 5791308 | Carter et al. | Aug 1998 | A |
| 5861137 | Edlund | Jan 1999 | A |
| 5888273 | Buxbaum | Mar 1999 | A |
| 5904754 | Juda et al. | May 1999 | A |
| 5964089 | Murphy et al. | Oct 1999 | A |
| 5997594 | Edlund et al. | Dec 1999 | A |
| 6136222 | Friesen et al. | Oct 2000 | A |
| 6152995 | Edlund | Nov 2000 | A |
| 6168650 | Buxbaum | Jan 2001 | B1 |
| 6171574 | Juda et al. | Jan 2001 | B1 |
| 6183542 | Bossard | Feb 2001 | B1 |
| 6183543 | Buxbaum | Feb 2001 | B1 |
| 6189568 | Bergum et al. | Feb 2001 | B1 |
| 6221117 | Edlund et al. | Apr 2001 | B1 |
| 6241945 | Owen | Jun 2001 | B1 |
| 6319306 | Edlund et al. | Nov 2001 | B1 |
| 6332913 | Breitschwerdt et al. | Dec 2001 | B1 |
| 6375906 | Edlund et al. | Apr 2002 | B1 |
| 6376113 | Edlund et al. | Apr 2002 | B1 |
| 6383670 | Edlund et al. | May 2002 | B1 |
| 6419728 | Edlund | Jul 2002 | B1 |
| 6451464 | Edlund et al. | Sep 2002 | B1 |
| 6458189 | Edlund et al. | Oct 2002 | B1 |
| 6465118 | Dickman et al. | Oct 2002 | B1 |
| 6475268 | Thornton | Nov 2002 | B2 |
| 6494937 | Edlund et al. | Dec 2002 | B1 |
| 6495277 | Edlund et al. | Dec 2002 | B1 |
| 6511521 | Parchamazad | Jan 2003 | B1 |
| 6537352 | Edlund et al. | Mar 2003 | B2 |
| 6547858 | Edlund et al. | Apr 2003 | B1 |
| 6562111 | Edlund et al. | May 2003 | B2 |
| 6569227 | Edlund et al. | May 2003 | B2 |
| 6596057 | Edlund et al. | Jul 2003 | B2 |
| 6632270 | Edlund et al. | Oct 2003 | B2 |
| 6660069 | Sato et al. | Dec 2003 | B2 |
| 6667128 | Edlund | Dec 2003 | B2 |
| 6719831 | Edlund et al. | Apr 2004 | B2 |
| 6719832 | Edlund et al. | Apr 2004 | B2 |
| 6723156 | Edlund et al. | Apr 2004 | B2 |
| 6767389 | Edlund et al. | Jul 2004 | B2 |
| 6783741 | Edlund et al. | Aug 2004 | B2 |
| 6811908 | Edlund et al. | Nov 2004 | B2 |
| 6818335 | Edlund et al. | Nov 2004 | B2 |
| 6824593 | Edlund et al. | Nov 2004 | B2 |
| 6835481 | Dickman et al. | Dec 2004 | B2 |
| 6858341 | Edlund | Feb 2005 | B2 |
| 6869707 | Edlund et al. | Mar 2005 | B2 |
| 6872464 | Hubner et al. | Mar 2005 | B2 |
| 6878474 | Dickman et al. | Apr 2005 | B2 |
| 6890672 | Dickman et al. | May 2005 | B2 |
| 6896709 | Han et al. | May 2005 | B1 |
| 6953497 | Edlund et al. | Oct 2005 | B2 |
| 6979507 | Edlund et al. | Dec 2005 | B2 |
| 6979801 | Okazaki | Dec 2005 | B2 |
| 6994927 | Edlund et al. | Feb 2006 | B2 |
| 7005113 | Edlund et al. | Feb 2006 | B2 |
| 7008708 | Edlund et al. | Mar 2006 | B2 |
| 7022395 | Ackerman et al. | Apr 2006 | B2 |
| 7029515 | Krueger | Apr 2006 | B2 |
| 7033641 | Saijo et al. | Apr 2006 | B2 |
| 7052530 | Edlund et al. | May 2006 | B2 |
| 7063047 | Reinke et al. | Jun 2006 | B2 |
| 7101421 | Edlund et al. | Sep 2006 | B2 |
| 7135048 | Edlund et al. | Nov 2006 | B1 |
| 7147677 | Edlund | Dec 2006 | B2 |
| 7182917 | Krueger | Feb 2007 | B2 |
| 7195663 | Edlund et al. | Mar 2007 | B2 |
| 7201783 | Edlund | Apr 2007 | B2 |
| 7208241 | Edlund et al. | Apr 2007 | B2 |
| 7250231 | Edlund | Jul 2007 | B2 |
| 7258946 | Edlund | Aug 2007 | B2 |
| 7297183 | Edlund et al. | Nov 2007 | B2 |
| 7306868 | Arthur | Dec 2007 | B2 |
| 7341609 | DeVries | Mar 2008 | B2 |
| 7368194 | Dickman et al. | May 2008 | B2 |
| 7368195 | Edlund et al. | May 2008 | B2 |
| 7390587 | Dickman et al. | Jun 2008 | B2 |
| 7410531 | Edlund et al. | Aug 2008 | B2 |
| 7470293 | Edlund et al. | Dec 2008 | B2 |
| 7476455 | Edlund | Jan 2009 | B2 |
| 7485381 | Dickman et al. | Feb 2009 | B2 |
| 7601302 | Edlund et al. | Oct 2009 | B2 |
| 7632321 | Edlund | Dec 2009 | B2 |
| 7632322 | Edlund | Dec 2009 | B2 |
| 7659019 | Edlund | Feb 2010 | B2 |
| 7682718 | Dickman et al. | Mar 2010 | B2 |
| 7736596 | Edlund et al. | Jun 2010 | B2 |
| 7771882 | Edlund et al. | Aug 2010 | B2 |
| 7789941 | Edlund et al. | Sep 2010 | B2 |
| 7819955 | Edlund et al. | Oct 2010 | B2 |
| 7828864 | Edlund et al. | Nov 2010 | B2 |
| 7846569 | Edlund et al. | Dec 2010 | B2 |
| 7939211 | Edlund et al. | May 2011 | B2 |
| 7977000 | Edlund | Jul 2011 | B2 |
| 7981172 | Edlund et al. | Jul 2011 | B2 |
| 7985510 | Edlund et al. | Jul 2011 | B2 |
| 8021446 | Adams et al. | Sep 2011 | B2 |
| 8038748 | Edlund | Oct 2011 | B2 |
| 8057575 | Edlund et al. | Nov 2011 | B2 |
| 8133626 | Edlund et al. | Mar 2012 | B2 |
| 8226751 | Ishibe et al. | Jul 2012 | B2 |
| 8262752 | Popham | Sep 2012 | B2 |
| 8603219 | Edlund | Dec 2013 | B2 |
| 8961627 | Edlund | Feb 2015 | B2 |
| 9187324 | Edlund | Nov 2015 | B2 |
| 9616389 | Edlund | Apr 2017 | B2 |
| 9656215 | Edlund | May 2017 | B2 |
| 9914641 | Edlund et al. | May 2018 | B2 |
| 10166506 | Edlund | Jan 2019 | B2 |
| 10391458 | Edlund | Aug 2019 | B2 |
| 10702827 | Edlund | Jul 2020 | B2 |
| 20010045061 | Edlund et al. | Nov 2001 | A1 |
| 20020071976 | Edlund | Jun 2002 | A1 |
| 20020081235 | Baldwin et al. | Jun 2002 | A1 |
| 20020100518 | Kuriiwa et al. | Aug 2002 | A1 |
| 20020114984 | Edlund et al. | Aug 2002 | A1 |
| 20030015096 | Sato et al. | Jan 2003 | A1 |
| 20030033933 | Frost et al. | Feb 2003 | A1 |
| 20030087138 | Margiott et al. | May 2003 | A1 |
| 20030091876 | Rusta-Sellehy et al. | May 2003 | A1 |
| 20030167690 | Edlund et al. | Sep 2003 | A1 |
| 20030192251 | Edlund et al. | Oct 2003 | A1 |
| 20030213365 | Jantsch et al. | Nov 2003 | A1 |
| 20030223926 | Edlund et al. | Dec 2003 | A1 |
| 20030228442 | Price et al. | Dec 2003 | A1 |
| 20040003720 | Beisswenger et al. | Jan 2004 | A1 |
| 20040005720 | Cremer et al. | Jan 2004 | A1 |
| 20040065013 | DeVries | Apr 2004 | A1 |
| 20040066043 | Maiwald et al. | Apr 2004 | A1 |
| 20040067195 | Strizki et al. | Apr 2004 | A1 |
| 20040081867 | Edlund | Apr 2004 | A1 |
| 20040081868 | Edlund | Apr 2004 | A1 |
| 20040197616 | Edlund et al. | Oct 2004 | A1 |
| 20040200459 | Bennett et al. | Oct 2004 | A1 |
| 20040229090 | Davis et al. | Nov 2004 | A1 |
| 20050000802 | Hobbs | Jan 2005 | A1 |
| 20050074648 | Arthur | Apr 2005 | A1 |
| 20050129995 | Kato | Jun 2005 | A1 |
| 20050132640 | Kelly et al. | Jun 2005 | A1 |
| 20050154198 | Trotta et al. | Jul 2005 | A1 |
| 20050172554 | Basho et al. | Aug 2005 | A1 |
| 20050188616 | Bizjak et al. | Sep 2005 | A1 |
| 20050211480 | Kejha | Sep 2005 | A1 |
| 20050265915 | Tonkovich et al. | Dec 2005 | A1 |
| 20060019134 | Yagi et al. | Jan 2006 | A1 |
| 20060037244 | Clawson | Feb 2006 | A1 |
| 20060037476 | Edlund et al. | Feb 2006 | A1 |
| 20060051638 | Gross | Mar 2006 | A1 |
| 20060083956 | Ukai et al. | Apr 2006 | A1 |
| 20060090397 | Edlund et al. | May 2006 | A1 |
| 20060112636 | Chellappa et al. | Jun 2006 | A1 |
| 20060127719 | Brantley et al. | Jun 2006 | A1 |
| 20060144700 | Carson et al. | Jul 2006 | A1 |
| 20060144788 | Cath et al. | Jul 2006 | A1 |
| 20060216562 | Edlund et al. | Sep 2006 | A1 |
| 20060225350 | Spallone et al. | Oct 2006 | A1 |
| 20060233700 | Chellappa et al. | Oct 2006 | A1 |
| 20070062116 | Edlund et al. | Mar 2007 | A1 |
| 20070183968 | Healey et al. | Aug 2007 | A1 |
| 20070190380 | DeVries | Aug 2007 | A1 |
| 20070266631 | Pledger et al. | Nov 2007 | A1 |
| 20070274904 | Popham et al. | Nov 2007 | A1 |
| 20070292729 | Brantley et al. | Dec 2007 | A1 |
| 20080029389 | Dreier et al. | Feb 2008 | A1 |
| 20080041454 | Eijkelenberg et al. | Feb 2008 | A1 |
| 20080075987 | Kindler et al. | Mar 2008 | A1 |
| 20080085434 | Arthur | Apr 2008 | A1 |
| 20080115669 | Edlund et al. | May 2008 | A1 |
| 20080138677 | Edlund | Jun 2008 | A1 |
| 20080138678 | Hill | Jun 2008 | A1 |
| 20080176118 | Edlund et al. | Jul 2008 | A1 |
| 20080187797 | Edlund | Aug 2008 | A1 |
| 20080210088 | Pledger | Sep 2008 | A1 |
| 20080213638 | Brantley et al. | Sep 2008 | A1 |
| 20080222954 | Adams et al. | Sep 2008 | A1 |
| 20080230039 | Weiss et al. | Sep 2008 | A1 |
| 20090011310 | Trabold et al. | Jan 2009 | A1 |
| 20100028223 | Popham et al. | Feb 2010 | A1 |
| 20100050520 | Arnold et al. | Mar 2010 | A1 |
| 20100055518 | Chen et al. | Mar 2010 | A1 |
| 20100064887 | Edlund et al. | Mar 2010 | A1 |
| 20100068132 | Vencill et al. | Mar 2010 | A1 |
| 20100167155 | Kim et al. | Jul 2010 | A1 |
| 20100181765 | More et al. | Jul 2010 | A1 |
| 20100230079 | Byers et al. | Sep 2010 | A1 |
| 20100261074 | Edlund et al. | Oct 2010 | A1 |
| 20100263538 | DeVries | Oct 2010 | A1 |
| 20110014528 | Kani | Jan 2011 | A1 |
| 20110137537 | Leone | Jun 2011 | A1 |
| 20110180396 | Giacomini | Jul 2011 | A1 |
| 20110212375 | Taguchi et al. | Sep 2011 | A1 |
| 20110250518 | Edlund et al. | Oct 2011 | A1 |
| 20110256459 | Edlund | Oct 2011 | A1 |
| 20110256491 | Edlund et al. | Oct 2011 | A1 |
| 20120058403 | Edlund et al. | Mar 2012 | A1 |
| 20120097610 | Zheng et al. | Apr 2012 | A1 |
| 20130011301 | Edlund | Jan 2013 | A1 |
| 20130090505 | Catchpole | Apr 2013 | A1 |
| 20130255487 | Edlund et al. | Oct 2013 | A1 |
| 20140065020 | Edlund et al. | Mar 2014 | A1 |
| 20140326447 | Fermaniuk | Nov 2014 | A1 |
| 20160083251 | Edlund et al. | Mar 2016 | A1 |
| 20160130515 | Edlund | May 2016 | A1 |
| 20160325990 | Galloway | Nov 2016 | A1 |
| 20160340185 | Xiang | Nov 2016 | A1 |
| 20170043300 | Stoltenberg | Feb 2017 | A1 |
| 20170216805 | Edlund | Mar 2017 | A1 |
| 20170209828 | Edlund | Jul 2017 | A1 |
| 20180126330 | Edlund | May 2018 | A1 |
| 20180264398 | Edlund | Sep 2018 | A1 |
| 20190118132 | Edlund | Apr 2019 | A1 |
| 20190135626 | Rafati et al. | May 2019 | A1 |
| 20190336920 | Edlund | Nov 2019 | A1 |
| 20200289977 | Edlund | Sep 2020 | A1 |
| 20200289978 | Edlund | Sep 2020 | A1 |
| 20200316517 | Edlund | Oct 2020 | A1 |
| 20210162335 | Edlund | Jun 2021 | A1 |
| Number | Date | Country |
|---|---|---|
| 2467012 | Apr 2001 | CA |
| 1384043 | Dec 2002 | CN |
| 1524308 | Aug 2004 | CN |
| 1931708 | Mar 2007 | CN |
| 101214921 | Jul 2008 | CN |
| 201161926 | Dec 2008 | CN |
| 101350411 | Jan 2009 | CN |
| 101542805 | Sep 2009 | CN |
| 101837955 | Sep 2010 | CN |
| 101956634 | Jan 2011 | CN |
| 105163832 | Dec 2015 | CN |
| 107265403 | Mar 2020 | CN |
| 111542383 | Aug 2020 | CN |
| 107697885 | May 2021 | CN |
| 69120740 | Nov 1996 | DE |
| 69219084 | Jul 1997 | DE |
| 69730071 | Aug 2005 | DE |
| 60035418 | Mar 2008 | DE |
| 202007008841 | Jun 2008 | DE |
| 0570185 | Nov 1993 | EP |
| 0652042 | May 1995 | EP |
| 0718031 | Jun 1996 | EP |
| 0470822 | Jul 1996 | EP |
| 0546808 | Apr 1997 | EP |
| 0783919 | Jul 1997 | EP |
| 0957063 | Nov 1999 | EP |
| 1010942 | Feb 2003 | EP |
| 0800852 | Aug 2004 | EP |
| 1272259 | Oct 2004 | EP |
| 1516663 | Mar 2005 | EP |
| 1135822 | Apr 2005 | EP |
| 1279431 | Apr 2005 | EP |
| 1523054 | Apr 2005 | EP |
| 1557395 | Jul 2005 | EP |
| 1679111 | Jul 2006 | EP |
| 0951529 | Aug 2006 | EP |
| 1252678 | Nov 2006 | EP |
| 1189678 | Jul 2007 | EP |
| 1290747 | Feb 2009 | EP |
| 1138096 | Oct 2010 | EP |
| 2359928 | Aug 2011 | EP |
| 2969132 | Jan 2016 | EP |
| 2355418 | Apr 2001 | GB |
| 2370241 | Jun 2002 | GB |
| 63021204 | Jan 1988 | JP |
| 63039622 | Feb 1988 | JP |
| 63126539 | May 1988 | JP |
| 63252903 | Oct 1988 | JP |
| 64063019 | Mar 1989 | JP |
| H06290800 | Apr 1993 | JP |
| 3360766 | Mar 1994 | JP |
| H06127903 | May 1994 | JP |
| 10052621 | Feb 1998 | JP |
| 11265833 | Sep 1999 | JP |
| 2001010804 | Jan 2001 | JP |
| 2002346372 | Dec 2002 | JP |
| 2003081603 | Mar 2003 | JP |
| 2003511336 | Mar 2003 | JP |
| 2003277019 | Oct 2003 | JP |
| 2003282119 | Oct 2003 | JP |
| 2003290637 | Oct 2003 | JP |
| 2003530664 | Oct 2003 | JP |
| 2003334418 | Nov 2003 | JP |
| 2004071242 | Mar 2004 | JP |
| 2004525488 | Aug 2004 | JP |
| 2005067990 | Mar 2005 | JP |
| 2005154198 | Jun 2005 | JP |
| 2005520306 | Jul 2005 | JP |
| 2005296746 | Oct 2005 | JP |
| 2006012817 | Jan 2006 | JP |
| 2006019033 | Jan 2006 | JP |
| 2006040597 | Feb 2006 | JP |
| 2006503780 | Feb 2006 | JP |
| 2006137668 | Jun 2006 | JP |
| 2006523795 | Oct 2006 | JP |
| 2007095548 | Apr 2007 | JP |
| 2007099528 | Apr 2007 | JP |
| 2008518871 | Jun 2008 | JP |
| 2008171815 | Jul 2008 | JP |
| 2008528430 | Jul 2008 | JP |
| 2008536796 | Sep 2008 | JP |
| 2008253984 | Oct 2008 | JP |
| 2008285404 | Nov 2008 | JP |
| 2008308351 | Dec 2008 | JP |
| 2009173534 | Dec 2008 | JP |
| 2009000659 | Jan 2009 | JP |
| 2009509299 | Mar 2009 | JP |
| 2010010050 | Jan 2010 | JP |
| 2010013323 | Jan 2010 | JP |
| A2010111543 | May 2010 | JP |
| 2011057480 | Mar 2011 | JP |
| 2002293504 | Oct 2012 | JP |
| 2016516655 | Mar 2014 | JP |
| 2014517804 | Jul 2014 | JP |
| 2014520750 | Aug 2014 | JP |
| 2016516655 | Jun 2016 | JP |
| 6538764 | Jun 2019 | JP |
| 6975286 | Nov 2021 | JP |
| 381667 | Apr 2021 | MX |
| 563270 | Nov 2003 | TW |
| 200404739 | Apr 2004 | TW |
| 200629635 | Aug 2006 | TW |
| 200740014 | Oct 2007 | TW |
| 200804177 | Jan 2008 | TW |
| 201733903 | Oct 2017 | TW |
| 201815663 | May 2018 | TW |
| I700246 | Aug 2020 | TW |
| 202045437 | Dec 2020 | TW |
| 8806489 | Sep 1988 | WO |
| 9919456 | Apr 1999 | WO |
| 0022690 | Apr 2000 | WO |
| 0056425 | Sep 2000 | WO |
| 0108247 | Feb 2001 | WO |
| 0112311 | Feb 2001 | WO |
| 0112539 | Feb 2001 | WO |
| 0126174 | Apr 2001 | WO |
| 0150541 | Jul 2001 | WO |
| 0150542 | Jul 2001 | WO |
| 0168514 | Sep 2001 | WO |
| 0170376 | Sep 2001 | WO |
| 0173879 | Oct 2001 | WO |
| 0193362 | Dec 2001 | WO |
| 0238265 | May 2002 | WO |
| 0249128 | Jun 2002 | WO |
| 02069428 | Sep 2002 | WO |
| 03002244 | Jan 2003 | WO |
| 03026776 | Apr 2003 | WO |
| 03041188 | May 2003 | WO |
| 03077331 | Sep 2003 | WO |
| 03086964 | Oct 2003 | WO |
| 03089128 | Oct 2003 | WO |
| 03100900 | Dec 2003 | WO |
| 2004038845 | May 2004 | WO |
| 2004091005 | Oct 2004 | WO |
| 2005001955 | Jan 2005 | WO |
| 2006011619 | Jul 2005 | WO |
| 2005091785 | Oct 2005 | WO |
| 2005119824 | Dec 2005 | WO |
| 2006033773 | Mar 2006 | WO |
| 2006049918 | May 2006 | WO |
| 2006050335 | May 2006 | WO |
| 2006081402 | Aug 2006 | WO |
| 2006133003 | Dec 2006 | WO |
| 2007035467 | Mar 2007 | WO |
| 2007037856 | Apr 2007 | WO |
| 2007049130 | May 2007 | WO |
| 2008008279 | Jan 2008 | WO |
| 2008033301 | Mar 2008 | WO |
| 2008105770 | Sep 2008 | WO |
| 2009088962 | Jul 2009 | WO |
| 2010033628 | Mar 2010 | WO |
| 2010118221 | Oct 2010 | WO |
| 2011059446 | May 2011 | WO |
| 2012067612 | May 2012 | WO |
| 2012091121 | Jul 2012 | WO |
| 2014158749 | Oct 2014 | WO |
| 2019136156 | Jul 2019 | WO |
| Entry |
|---|
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 17/167,555, dated Jun. 10, 2022, 68 pages. |
| Final Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 17/167,555, dated Oct. 31, 2022, 10 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 17/348,400 dated Dec. 13, 2022, 8 pages. |
| International Search Report and Written Opinion prepared by the US Patent and Trademark Office for PCT/US2022/32503, dated Oct. 25, 2022, 17 pages. |
| Office Action prepared by the Japanese Patent Office for JP2022-3522, dated Dec. 23, 2022, 11 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/887,360, dated Sep. 22, 2020, 8 pages. |
| International Search Report and Written Opinion prepared by the US Patent and Trademark Office for PCT/US2021/047866, dated Dec. 16, 2021, 11 pages. |
| Examination Report prepared by the Taiwan Intellectual Property Office (TIPO), Taiwan Patent Application No. 110131460, dated Apr. 12, 2022, pgs, 37 pages. |
| Rejection Report prepared by the Taiwan Intellectual Property Office (TIPO), Taiwan Patent Application No. 110131460, dated Sep. 13, 2022, 9 pages. |
| Notice of Preliminary Rejection prepared by the Korean Intellectual Property Office, Korean Patent Application No. 10-2022-7033348, dated Nov. 7, 2022, 11 pages. |
| Notice of Preliminary Rejection prepared by the Korean Intellectual Property Office, Korean Patent Application No. 10-2020-7022167, dated Jan. 19, 2022, 16 pages. |
| Decision of Rejection, prepared by the China National Intellectual Property Administration (CNIPA), Chinese Patent Application No. 201980007152.5, dated Mar. 25, 2022, 22 pages. |
| Taiwan Intellectual Property Office, Decision of Rejection for Taiwanese Patent Application No. 102131014, dated Nov. 2, 2015, 20 pages. |
| Taiwan Intellectual Property Office, Examination Report for Taiwanese Patent Application No. 103108640, dated Nov. 23, 2015, 39 pages. |
| State Intellectual Property Office of the P.R.C., Office Action for Chinese Patent Application No. 201380052485.2, dated Jan. 12, 2016, 29 pages. |
| Japan Patent Office, Office Action for Japanese Patent Application No. 2015-529963, dated Jan. 18, 2016, 7 pages. |
| European Patent Office, Extended Search Report for European Patent Application No. 13832056.9, dated Mar. 18, 2016, 6 pages. |
| State Intellectual Property Office of the P.R.C., Office Action for Chinese Patent Application No. 2016062901774250, dated Jul. 4, 2016, 18 pages. |
| State Intellectual Property Office of the P.R.C., Office Action for Chinese Patent Application No. 201380052485.2, dated Jul. 20, 2016, 31 pages. |
| Japan Patent Office, Office Action for Japanese Patent Application No. 2015-135010, dated Sep. 12, 2016, 15 pages. |
| U.S. Patent and Trademark Office, Office Action for U.S. Appl. No. 14/594,997, dated Sep. 15, 2016, 85 pages. |
| Japan Patent Office, Office Action for Japanese Patent Application No. 2016-500545, dated Oct. 3, 2016, 6 pages. |
| European Patent Office, Supplementary Search Report for European Patent Application No. 14773171.5, dated Oct. 14, 2016, 7 pages. |
| State Intellectual Property Office of the P.R.C., Office Action for Chinese Patent Application No. 201380052485.2, dated Dec. 29, 2016, 15 pages. |
| European Patent Office, Extended Search Report for European Patent Application No. 14773171.5, dated Feb. 13, 2017, 13 pages. |
| European Patent Office, Communication for European Patent Application No. 14773171.5, dated Mar. 2, 2017, 1 page. |
| Edlund, David, “Methanol Fuel Cell Systems: Advancing Towards Commercialization”, Pan Stanford Publishing Pte. Ltd., Singapore, 2011, 199 pages. |
| HGS-M Series Hydrogen Generator: Powering Fuel Cells from readily available Methanol, www.hy9.com, Hopkinton, Massachusetts, USA, updated Jun. 20, 2011, 2 pages. |
| U.S. Receiving Office, International Search Report for International Application No. PCT/US12/45437, dated Nov. 19, 2012, 6 pages. |
| U.S. Receiving Office, Written Opinion for International Application No. PCT/US12/45437, dated Nov. 19, 2012, 6 pages. |
| Taiwan Intellectual Property Office, Examination Report in Taiwanese Patent Application No. 101124209, dated Dec. 19, 2013, 32 pages. |
| U.S. Receiving Office, International Preliminary Report for PCT Application No. PCT/US2012/045437, dated Jan. 7, 2014, 7 pages. |
| U.S. Receiving Office, International Search Report for PCT Application No. PCT/US13/56908, dated Jan. 24, 2014, 2 pages. |
| U.S. Receiving Office, Written Opinion for PCT Application No. PCT/US13/56908, dated Jan. 24, 2014, 12 pages. |
| U.S. Receiving Office, International Search report for PCT Application No. PCT/US2014/019837, dated Jun. 6, 2014, 2 pages. |
| Office Action prepared by the Chinese Patent Office for Chinese Patent Application No. 201480015413.5, dated Mar. 9, 2017, 17 pages. |
| Office Action prepared by the Chinese Patent Office for Chinese Patent Application No. 201510896209.5, dated Mar. 14, 2017, 6 pages. |
| Decision of Rejection prepared by the Taiwan Intellectual Property Office for Taiwanese Patent Application No. 103108640, dated Aug. 25, 2016, 25 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 14/961,529, dated Jul. 26, 2017, 79 pages. |
| Office Action prepared by the Taiwan inteilectuai Property Office for Taiwanese Patent Application No. 103108640, dated Jul. 27, 2017, 2 pages. |
| Examination Report prepared by the Indian Patent Office for Indian Patent Application No. 433/KOLNP/2015, dated Feb. 28, 2018, 7 pages. |
| Office Action prepared by the Japanese Patent Office for Japanese Patent Application No. 2017-130918, dated Feb. 26, 2018, 9 pages. |
| Office Action prepared by the Chinese Patent Office for Chinese Patent Application No. 2015108962095, dated Jan. 4, 2018, 8 pages. |
| Office Action prepared by the European Patent Office for European Patent Application No. 13832056.9, dated Dec. 19, 2017, 4 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 15/483,265, dated May 22, 2018, 56 pages. |
| Office Action prepared by the State Intellectual Property Office of PR China for CN 201710352484.X, dated Dec. 11, 2018, 14 pages. |
| Notice of Reasons for Rejection prepared by the Japanese Patent Office for JP 2017-182239, dated Nov. 12, 2018, 4 pages. |
| Decision to Reject the Amendments prepared by the Japanese Patent Office for JP 2017-130918, dated Dec. 3, 2018, 6 pages. |
| Decision of Rejection prepared by the Japanese Patent Office for JP 2017-130918, dated Dec. 3, 2018, 3 pages. |
| Office Action prepared by the European Patent Office for EP 14 773 171.5-1104, dated Jul. 20, 2018, 5 pages. |
| Office Action prepared by the European Patent Office for EP 13 832 056.9-1101, dated Aug. 21, 2018, 4 pages. |
| Office Action prepared by the Japanese Patent Office for JP 2017-130918, dated Jul. 30, 2018, 7 pages. |
| International Search Report and Written Opinion prepared by the US Patent and Trademark Office for PCT/US2019/012192, dated Mar. 8, 2019, 11 pages. |
| Office Action prepared by the European Patent Office for EP 13 832 056.9, dated Mar. 20, 2019, 5 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 15/486,755, dated Mar. 18, 2019, 77 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/287,482, dated Jun. 12, 2019, 10 pages. |
| Office Action prepared by the European Patent Office for EP 14773171.5, dated Jun. 28, 2019, 4 pages. |
| Office Action prepared by the Chinese Patent Office for CN 201710352484X, dated Jul. 18, 2019, 3 pages. |
| Hearing Notice for IN 433/KOLNP/2015, dated Jul. 30, 2019, 2 pages. |
| Office Action prepared by the China National Intellectual Property Administration for CN 201710102421, dated Sep. 16, 2019, 12 pages. |
| Election/Restriction Requirement prepared by the US Patent and Trademark Office for U.S. Appl. No. 15/862,474, dated Sep. 30, 2019, 6 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 15/985,175, dated Oct. 10, 2019, 57 pages. |
| Office Action prepared by the Taiwan Patent Office for TW 107145920, dated Nov. 5, 2019, 21 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 15/985,175, dated Jan. 29, 2020, 8 pages. |
| Office Action prepared by the Chinese Patent Office for CN201710102421, dated Apr. 16, 2020, 29 pages. |
| Examiner's Report prepared by the Canadian Patent Office for CA 2,967,340, dated May 22, 2020, 4 pages. |
| Office Action prepared by the Mexican Patent Office for MX/a/2015/012252, dated Jul. 23, 2020, 4 pages. |
| Office Action prepared by the European Patent Office for EP13832056, dated Sep. 3, 2020, 4 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/904,872, dated Sep. 22, 2020, 8 pages. |
| Office Action prepared by the Chinese Patent Office for CN201710102421, dated Oct. 20, 2020, 15 pages. |
| First Examination Report prepared by the Indian Patent Office for IN 202037032378, dated Oct. 21, 2020, 7 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/891,477, dated Nov. 6, 2020 6 pages. |
| Final Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/904,872, dated Jan. 27, 2021, 11 pages. |
| First Office Action prepared by the Japanese Patent Office for JP 2020-79526, dated Mar. 15, 2021, 6 pages. |
| Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/513,324, dated Jul. 26, 2021, 70 pages. |
| Office Action prepared by the Japanese Patent Office for JP 2020-537176, dated Aug. 30, 2021, 11 pages. |
| Extended European Search Report prepared by the European Patent Office for EP19735938.3, dated Sep. 21, 2021, 7 pages. |
| Office Action prepared by the Chinese Patent Office for CN 201980007152.5, dated Sep. 26, 2021, 26 pages. |
| Final Office Action prepared by the US Patent and Trademark Office for U.S. Appl. No. 16/513,324, dated Nov. 15, 2021, 12 pages. |
| U.S. Receiving Office, Written Opinion for PCT Application No. PCT/US2014/019837, dated Jun. 6, 2014, 8 pages. |
| Taiwan Intellectual Property Office, Examination Report for Taiwanese Patent Application No. 102131014, dated Dec. 27, 2014, 29 pages. |
| State Intellectual Property Office of the P.R.C., Office Action for Chinese Patent Application No. 201280039436.0, dated Jan. 27, 2015, 28 pages. |
| United States Patent and Trademark Office, Office Action for U.S. Appl. No. 13/600,096, dated Feb. 5, 2015, 9 pages. |
| Japan Patent Office, Office Action for Japanese Patent Application No. 2014-519267, dated Apr. 6, 2015, 13 pages. |
| Taiwan Intellectual Property Office, Office Action for Taiwanese Patent Application No. 103134184, dated Apr. 30, 2015, 17 pages. |
| U.S. Patent and Trademark Office, Office Action for U.S. Appl. No. 13/600,096, dated Jun. 1, 2015, 9 pages. |
| U.S. Patent and Trademark Office, Office Action for U.S. Appl. No. 13/829,766, dated Jun. 26, 2015, 6 pages. |
| U.S. Patent and Trademark Office, Office Action for U.S. Appl. No. 13/600,096, dated Sep. 11, 2015, 9 pages. |
| Number | Date | Country | |
|---|---|---|---|
| 20210402349 A1 | Dec 2021 | US |
| Number | Date | Country | |
|---|---|---|---|
| 63071139 | Aug 2020 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15862474 | Jan 2018 | US |
| Child | 16904872 | US | |
| Parent | 13829766 | Mar 2013 | US |
| Child | 14931585 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 14931585 | Nov 2015 | US |
| Child | 15483265 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16904872 | Jun 2020 | US |
| Child | 17412581 | US | |
| Parent | 15483265 | Apr 2017 | US |
| Child | 15862474 | US | |
| Parent | 13600096 | Aug 2012 | US |
| Child | 13829766 | US |
