Claims
- 1. A method for the recovery of one or more primary components from a gaseous feed mixture comprising said primary components and one or more secondary components, wherein said secondary components are more strongly adsorbed on an adsorbent material than said primary components, said method comprising:
- (a) passing said feed mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate intermediate product stream enriched in said primary components, wherein portions of said secondary components are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase;
- (b) withdrawing from the permeate side of said membrane a permeate comprising said secondary components;
- (c) separating said nonpermeate intermediate product stream into a high-purity product stream comprising said primary components and a reject stream comprising an additional portion of said secondary components; and
- (d) passing at least a portion of said reject stream across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of said primary components and increasing the permeation rate of said secondary components through said membrane.
- 2. The method of claim 1 wherein said intermediate product stream is separated in step (c) by passing the stream into a pressure swing adsorption system wherein remaining secondary components are selectively adsorbed, and withdrawing therefrom said high purity product comprising the primary components and said reject stream comprising an additional portion of said secondary components.
- 3. The method of claim 2 wherein said primary components comprise at least hydrogen.
- 4. The method of claim 3 wherein said secondary components comprise hydrocarbons selected from the group consisting of methane, ethane, ethylene, propane, propylene, butane, isobutane, butylene, isobutylene, and mixtures thereof.
- 5. The method of claim 4 wherein the pressure of said feed stream is between 20 and 300 psig.
- 6. The method of claim 5 wherein the pressure of said intermediate product stream is between 15 and 295 psig.
- 7. The method of claim 4 wherein the pressure of said reject stream used as said sweep gas is between 2 and 50 psig.
- 8. The method of claim 4 which further comprises reforming a methane-containing feed stream in a steam-methane reformer to produce a synthesis gas comprising hydrogen, carbon oxides, water, and unreacted methane, and combining said synthesis gas with said intermediate product stream prior to said pressure swing adsorption system.
- 9. The method of claim 8 which further comprises utilizing at least a portion of said sweep gas/permeate effluent stream as fuel in said steam-methane reformer.
- 10. The method of claim 4 which further comprises passing at least a portion of said sweep gas/permeate effluent stream into a dephlegmator, withdrawing therefrom a hydrocarbon product stream containing C.sub.3 and heavier hydrocarbons, also withdrawing therefrom an intermediate light hydrocarbon stream containing components lighter than C.sub.3, and combining said intermediate light hydrocarbon stream with said intermediate product stream prior to said pressure swing adsorption system.
- 11. A method for the production of hydrogen from a methane-containing feed gas and a gas mixture containing hydrogen and hydrocarbons, wherein said method comprises:
- (a) passing said gas mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator an intermediate product stream enriched in hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase;
- (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons;
- (c) reforming a portion of said methane-containing feed gas in a steam-methane reformer to produce a synthesis gas comprising hydrogen, carbon oxides, water, and unreacted methane, and combining said synthesis gas with said intermediate product stream;
- (d) passing the resulting combined stream of step (c) into a pressure swing adsorption system wherein hydrocarbons and carbon oxides are selectively adsorbed, and withdrawing therefrom a high purity hydrogen product and a reject stream comprising hydrocarbons and carbon oxides; and
- (e) passing the remaining portion of said methane-containing feed gas across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of hydrogen and increasing the permeation rate of hydrocarbons through said membrane.
- 12. The method of claim 11 which further comprises utilizing at least a portion of said sweep gas/permeate effluent stream as fuel in said steam-methane reformer.
- 13. The method of claim 11 which further comprises utilizing at least a portion of said sweep gas/permeate effluent stream as additional feed in said steam-methane reformer.
- 14. The method of claim 11 which further comprises utilizing at least a portion of said reject stream from said pressure swing absorption system as fuel in said steam-methane reformer.
Parent Case Info
This application is a continuation-in-part of U.S. Ser. No. 436,556 filed Nov. 14, 1989, abandoned.
US Referenced Citations (6)
Foreign Referenced Citations (4)
Number |
Date |
Country |
3315930 |
Mar 1984 |
DEX |
58-120502 |
Jul 1983 |
JPX |
62-153389 |
Jul 1987 |
JPX |
62-153390 |
Jul 1987 |
JPX |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
436566 |
Nov 1989 |
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