Claims
- 1. A process for treating an off-gas stream, containing at least hydrogen, methane and a C.sub.3+ hydrocarbon, comprising the following steps:
- (a) cooling the off-gas stream to a temperature no lower than about -40.degree. C., resulting in partial condensation of the off-gas stream, thereby dividing the off-gas stream into a condensed portion enriched in C.sub.3+ hydrocarbon and an uncondensed portion enriched in hydrogen;
- (b) passing the uncondensed portion as a feed stream to a membrane separation unit, the membrane separation unit containing a rubbery polymeric membrane having a feed side and permeate side, and being selectively permeable to methane over hydrogen, under conditions sufficient that the membrane exhibits a methane/hydrogen selectivity of at least about 2.5;
- (c) withdrawing from the permeate side a permeate stream enriched in methane and C.sub.3+ hydrocarbon compared with the uncondensed portion;
- (d) withdrawing from the feed side a hydrogen-enriched product gas;
- (e) passing the condensed portion to a hydrocarbon separation step for separation of a C.sub.3+ hydrocarbon fraction and a lighter hydrocarbon fraction from the condensed portion.
- 2. The process of claim 1, wherein the temperature is no lower than about -20.degree. C.
- 3. The process of claim 1, wherein the selectivity exhibited in step (b) is at least about 3.
- 4. The process of claim 1, wherein the selectivity exhibited in step (b) is at least about 4.
- 5. The process of claim 1, wherein the off-gas stream is subjected to a compression step prior to the cooling step.
- 6. The process of claim 1, wherein the lighter hydrocarbon fraction is recirculated to the cooling step.
- 7. The process of claim 1, wherein the hydrocarbon separation step is carried out by flashing the condensed portion.
- 8. The process of claim 1, wherein the hydrocarbon separation step is carried out by distilling the condensed portion.
- 9. The process of claim 1, wherein the permeate stream is passed to an additional treatment step for further separation of hydrogen from hydrocarbons.
- 10. The process of claim 1, wherein the hydrogen-enriched product gas is passed to an additional treatment step.
- 11. The process of claim 10, wherein the additional treatment step comprises a membrane separation step.
- 12. The process of claim 10, wherein the additional treatment step comprises pressure swing adsorption.
- 13. The process of claim 1, wherein the membrane comprises silicone rubber.
- 14. The process of claim 1, wherein the membrane comprises a polysiloxane.
- 15. A process for treating an off-gas stream, containing at least hydrogen, methane and a C.sub.3+ hydrocarbon, comprising the following steps:
- (a) cooling the off-gas stream to a temperature no lower than about -40.degree. C., resulting in partial condensation of the off-gas stream, thereby dividing the off-gas stream into a condensed portion enriched in C.sub.3+ hydrocarbon and an uncondensed portion enriched in hydrogen;
- (b) passing the uncondensed portion as a first feed stream across the first feed side of a first polymeric membrane having a first feed side and a first permeate side, and being selectively permeable to C.sub.2+ hydrocarbons over hydrogen;
- (c) withdrawing from the first permeate side a first permeate stream enriched in C.sub.3+ hydrocarbons compared with the uncondensed portion;
- (d) withdrawing from the first feed side a first residue stream enriched in hydrogen compared with the uncondensed portion;
- (e) passing the first residue stream as a second feed stream across the second feed side of a second rubbery polymeric membrane having a second feed side and a second permeate side, and being selectively permeable to methane over hydrogen, under conditions sufficient that the membrane exhibits a methane/hydrogen selectivity of at least about 2.5;
- (f) withdrawing from the second permeate side a second permeate stream enriched in methane and C.sub.3+ hydrocarbon compared with the first residue stream;
- (g) withdrawing from the second feed side a second residue stream enriched in hydrogen compared with the first residue stream;
- (h) passing the condensed portion to a hydrocarbon separation step for separation of a C.sub.3+ hydrocarbon fraction and a lighter hydrocarbon fraction from the condensed portion.
- 16. The process of claim 15, wherein the selectivity exhibited in step (e) is at least about 3.
- 17. The process of claim 15, wherein the cooling does not lower the temperature of the first feed stream below 0.degree. C.
- 18. The process of claim 15, further comprising cooling the first residue stream prior to passing the first residue stream across the second feed side.
- 19. The process of claim 15, wherein the lighter hydrocarbon fraction is recirculated to the cooling step.
- 20. The process of claim 15, wherein the first permeate stream is recirculated to the cooling step.
Parent Case Info
This application is a continuation-in-part of Ser. No. 09/083,775, filed May 22, 1998, now U.S. Pat. No. 5,980,609, issued Nov. 9, 1999, which is a continuation-in-part of Ser. No. 08/789,376, filed Jan. 24, 1997, now U.S. Pat. No. 5,785,739, issued Jul. 28, 1998 and Ser. No. 08/780,868, filed Jan. 24, 1997, now U.S. Pat. No. 5,755,855, issued May 26, 1998, all of which are incorporated herein by reference in their entirety.
Government Interests
This invention was made in part with Government support under SBIR award number DE-FG03-98ER82618 awarded by the Department of Energy. The Government has certain rights in this invention.
US Referenced Citations (38)
Non-Patent Literature Citations (7)
Entry |
H. Yamashiro et al., "Hydrogen Purification With Cellulose Acetate Membranes," presented at the Europe-Japan Congress on Membranes and Membrane Processes, Jun. 18-21, 1987. |
W.A. Bollinger et al., "Prism.TM. Separators Optimize Hydrocracker Hydrogen," presented at AIChE 1983 Summer National Meeting, Session No. 66, Aug. 29, 1983. |
H. Yamashiro et al., "Plant Uses Membrane Separation," Hydrocarbon Processing, Feb. 1985. |
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Continuation in Parts (3)
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Number |
Date |
Country |
Parent |
083775 |
May 1998 |
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Parent |
789376 |
Jan 1997 |
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Parent |
780868 |
Jan 1997 |
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