Claims
- 1. A method for reversibly storing and releasing hydrogen fuel comprising the steps of:
- providing a reaction chamber with a selectively permeable membrane;
- providing a hydrogen containing material in the reaction chamber;
- introducing a homogenous catalyst into the chamber;
- wherein the catalyst is an iridium complex of the formula:
- IrH.sub.4 {2,6C.sub.6 H.sub.3 (CH.sub.2 P(C(CH.sub.3).sub.3).sub.2).sub.2 };
- heating at least a portion of the hydrogen containing material;
- separating the material into aromatic compounds and hydrogen; and
- releasing the hydrogen through the membrane from the chamber, said hydrogen being used as a fuel.
- 2. The method of claim 1, wherein the hydrogen containing material is a hydrocarbon.
- 3. The method of claim 2, wherein the hydrocarbon containing material is a cycloalkane.
- 4. The method of claim 1, wherein heating at least a portion of the hydrogen containing material further comprises raising temperatures in the material to at least about 190.degree. C.
- 5. The method of claim 1, wherein heating the chamber for hydrogenation further comprises raising temperature in the material to at least about 150.degree. C.
- 6. The method of claim 1 further comprising establishing a hydrogen pressure in the chamber of about 10 to 50 atmospheres and combining the aromatic compounds and the hydrogen to recreate the hydrogen containing product.
- 7. A system for receiving, storing and releasing hydrogen fuel, comprising:
- a chamber with a selective membrane, said chamber having an outlet for releasing hydrogen fuel and containing hydrogenated material and a homogenous catalyst wherein the homogenous catalyst is an iridium complex of the formula:
- IrH.sub.4 {2,6C.sub.6 H.sub.3 (CH.sub.2 P(C(CH.sub.3).sub.3).sub.2).sub.2 };
- a heat source for heating the hydrogenated material to produce the hydrogen fuel; and
- an inlet for delivering pressurized hydrogen gas to the chamber to rehydrogenate said hydrogenated material.
- 8. The system of claim 7, wherein the heat source is a heat source for raising a temperature of the material to at least about 190.degree. C.
- 9. The system of claim 7, wherein heating the chamber for hydrogenation further comprises raising temperature in the material to at least about 150.degree. C.
- 10. The system of claim 7, wherein the hydrogenated material is a cycloalkane.
- 11. The system of claim 7, wherein the hydrogenated material further comprises methylcyclohexane, decalin, dicyclohexyl, cyclohexane, or a combination thereof.
- 12. A vehicular apparatus comprising:
- a body;
- a motor connected to the body for moving the body;
- a hydrogen fuel source;
- a fuel line connected to the motor and to the hydrogen fuel source, wherein the fuel source further comprises a storage tank containing hydrogenated material and a homogenous catalyst, wherein said homogenous catalyst is an iridium catalyst of the formula:
- IrH.sub.4 {2,6C.sub.6 H.sub.3 (CH.sub.2 P(C(CH.sub.3).sub.3).sub.2).sub.2 };
- and
- a heat source thermally connected for increasing the temperature in the material to at least about 150.degree. C., wherein said hydrogenated material is dehydrogenated to produce hydrogen fuel for powering said vehicular apparatus.
- 13. The apparatus of claim 12, wherein the hydrogenated material further comprises methylcyclohexane, decalin, dicyclohexyl, cyclohexane, or a combination thereof.
- 14. A method of powering a vehicle apparatus, comprising the steps of:
- providing a tank having an inlet, said tank housing a hydrogen containing material and a homogenous catalyst wherein said homogenous catalyst is an iridium catalyst of the formula:
- IrH.sub.4 {2,6C.sub.6 H.sub.3 (CH.sub.2 P(C(CH.sub.3).sub.3).sub.2).sub.2 };
- dehydrogenating the hydrogen containing material by first heating at least a portion of the hydrogen containing material to produce hydrogen;
- powering said vehicle apparatus with the hydrogen until the tank is emptied by dehydrogenating the hydrogen containing material; and
- filling the tank by second heating the tank and introducing hydrogen into the tank, to rehydrogenate the hydrogen containing material.
- 15. The method of claim 14 where in the dehydrogenating step, the first heating is carried out at a temperature of about 150.degree. C. or greater.
- 16. The method of claim 14 where in the filling step, the second heating is carried out at a temperature of about 100.degree. C. or greater, and the hydrogen is introduced into the tank to rehydrogenate the hydrogen containing material at a pressure in the range of about 10 to 50 atmospheres of hydrogen.
- 17. The method of claim 14 wherein the hydrogen containing material is a hydrocarbon.
Parent Case Info
This application is a continuation-in-part of application Ser. No. 08/807,123 filed Feb. 21, 1997 now abandoned.
US Referenced Citations (23)
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
807123 |
Feb 1997 |
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