Claims
- 1. Process for the selective hydrogenation of a poly-unsaturated organic compound containing more than one double bond in a carbon chain or ring comprising hydrogenating said compound with hydrogen in the presence of a metallic hydrogenation catalyst chosen from the group consisting of palladium, platinum, rhodium, ruthenium and nickel, at a temperature of between -20.degree. C. and 200.degree. C. and under a pressure of between 1 and 25 atm., and applying an external electric potential differing from the equilibrium potential and having a value of between 0 V and -3 V as measured against a saturated calomel electrode, to the catalyst while it is in contact with a liquid chosen, which liquid contains 0.001 to 0.1 mole per liter of an electrolyte chosen from the group consisting of quaternary ammonium salts, sodium dodecyl-6-sulphonate, sodium acetate, sodium hydroxide and sodium methanolate.
- 2. Process according to claim 1, in which the external electric potential is applied during the whole of the hydrogenation.
- 3. Process according to claim 1, in which the external electric potential is switched off after the hydrogenation reaction is started.
- 4. Process according to claim 1, in which the external potential is applied to the catalyst in a vessel separated from the hydrogenation reactor.
- 5. Process according to claim 1, in which the liquid containing an electrolyte and catalyst are brought into a reaction vessel under a hydrogen atmosphere, an external potential is applied to the catalyst and thereafter the compound to be hydrogenated is brought into the reaction vessel.
- 6. Process according to claim 1, in which the liquid containing an electrolyte, catalyst and the compound to be hydrogenated are brought into a reaction vessel under an inert atmosphere, an external potential is applied to the catalyst, and thereafter the inert atmosphere is replaced by hydrogen.
- 7. Process according to claim 4, in which liquid containing an electrolyte and the catalyst are brought into the separate vessel under an inert atmosphere, an external electric potential is applied to the catalyst, and the contents of said vessel are brought into the hydrogenation reactor already containing the compound to be hydrogenated.
- 8. Process according to claim 1 in which as the catalyst a metal supported on a carrier is used.
- 9. Process according to claim 8, in which as the metal palladium, platinum, rhodium, ruthenium and/or nickel is used.
- 10. Process according to claim 8, in which the carrier consists of a metal, carbon black, silica or an ion-exchange resin.
- 11. Process according to claim 1, in which the external potential is applied to the catalyst by stirring a suspension of the catalyst to contact the catalyst particles with an electrode to which an electric potential is applied.
- 12. Process according to claim 1, in which as the liquid an alcohol or a ketone is used.
- 13. Process according to claim 1, in which as the liquid water, methanol, ethanol, propanol, glycerol, acetone, methyl cellosolve, acetonitrile, hexane, benzene or a mixture thereof is used.
- 14. Process according to claim 1, in which the ratio by weight of the liquid to the compound to be hydrogenated is between 1:1 to 20:1.
- 15. Process according to claim 1, in which as the electrolyte a quaternary ammonium salt is used.
- 16. Process according to claim 1, in which an edible triglyceride oil is hydrogenated.
- 17. Process according to claim 1, in which as the electrolyte tetraethyl ammonium perchlorate, tetrabutyl ammonium perchlorate, tetraethyl ammonium phosphate, tetraethyl ammonium bromide, tetraethyl ammonium paratoluene sulphonate, and/or tetramethyl ammonium acetate is used.
Priority Claims (1)
Number |
Date |
Country |
Kind |
54485/76 |
Dec 1976 |
GBX |
|
Parent Case Info
This application is a continuation of co-pending application 866,147, filed Dec. 30, 1977, now abandoned.
US Referenced Citations (5)
Foreign Referenced Citations (9)
Number |
Date |
Country |
203817 |
Oct 1955 |
AUX |
189332 |
Oct 1907 |
DE2 |
1205539 |
Nov 1965 |
DEX |
786008 |
Aug 1935 |
FRX |
1025125 |
Apr 1953 |
FRX |
2169216 |
Dec 1973 |
FRX |
7300978 |
Jul 1973 |
NLX |
385273 |
Jan 1933 |
GBX |
550356 |
Jan 1943 |
GBX |
Continuations (1)
|
Number |
Date |
Country |
Parent |
866147 |
Dec 1977 |
|