Hydrolysis resistant organomodified trisiloxane surfactants

Abstract

Three types of trisiloxane surfactants having the basic formula:

Description

Claims

1. A silicone composition comprising a silicone having the formula: M1D1M2

2. The composition of claim 1 where R1 and R4 are selected from the group consisting of propyl, iso-propyl, butyl, sec-butyl, iso-butyl and tert-butyl.

3. The composition of claim 1 where R2, R3, R5, R6 and R7 are methyl.

4. The composition of claim 1 where R8 is a divalent hydrocarbon radical having three carbon atoms.

5. The composition of claim 1 where the subscript a ranges from 8 to 12.

6. The composition of claim 1 where the subscript b ranges from 0 to 3.

7. The composition of claim 1 where the subscript c is 0.

8. The composition of claim 1 where R9 is selected from the group consisting of hydrogen and methyl.

9. The composition of claim 2 where R1 and R4 are selected from the group consisting of iso-propyl and tert-butyl.

10. The composition of claim 5 where the subscript a is 11.

11. The composition of claim 8 where R9 is hydrogen.

12. The composition of claim 9 where R2, R3, R5, R6 and R7 are methyl.

13. The composition of claim 12 where R8 is a divalent hydrocarbon radical having three carbon atoms.

14. The composition of claim 13 where the subscript a is 11.

15. The composition of claim 14 where the subscripts b and c are both zero

16. The composition of claim 15 where R9 is hydrogen.

17. A silicone composition comprising a silicone having the formula: M1D1M2

18. The composition of claim 17 where R1 and R4 are selected from the group consisting of propyl, iso-propyl, butyl, sec-butyl, iso-butyl and tert-butyl.

19. The composition of claim 17 where R2, R3, R5, R6 and R7 are methyl.

20. The composition of claim 17 where R8 is a divalent hydrocarbon radical having three carbon atoms.

21. The composition of claim 17 where the subscript a ranges from 8 to 12.

22. The composition of claim 17 where the subscript b ranges from 0 to 3.

23. The composition of claim 17 where the subscript c is 0.

24. The composition of claim 17 where R9 is selected from the group consisting of hydrogen and methyl.

25. The composition of claim 18 where R1 and R4 are selected from the group consisting of iso-propyl and tert-butyl.

26. The composition of claim 21 where the subscript a is 11.

27. The composition of claim 24 where R9 is hydrogen.

28. The composition of claim 25 where R2, R3, R5, R6 and R7 are methyl.

29. The composition of claim 28 where R8 is a divalent hydrocarbon radical having three carbon atoms.

30. The composition of claim 29 where the subscript a is 11.

31. The composition of claim 30 where the subscripts b and c are both zero

32. The composition of claim 31 where R9 is hydrogen.

33. An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of claim 1.

34. An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of claim 17.

35. An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of claim 1.

36. An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of claim 17.

37. A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of claim 1.

38. A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of claim 17.

39. A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of claim 1.

40. A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of claim 17.

41. A silicone composition comprising a silicone having the formula: M3D2M4

42. The composition of claim 41 where the subscript f is 0.

43. The composition of claim 41 where the subscript e ranges from 0 to 3.

44. The composition of claim 41 where the subscript d ranges from 8 toll.

45. The composition of claim 41 where R10, R11, R12, R13, R14, R15 and R16 are methyl.

46. The composition of claim 41 where R18 is methyl.

47. The composition of claim 42 where the subscript e is 0.

48. The composition of claim 47 where the subscript d is 8.

49. The composition of claim 48 where R10, R11, R12, R13, R14, R15 and R16 are methyl.

50. The composition of claim 49 where R18 is methyl.

51. A silicone composition comprising a silicone having the formula: M3D2M4

52. The composition of claim 51 where the subscript f is 0.

53. The composition of claim 51 where the subscript e ranges from 0 to 3.

54. The composition of claim 51 where the subscript d ranges from 8 to 11.

55. The composition of claim 51 where R10, R11, R12, R13, R14, R15 and R16 are methyl.

56. The composition of claim 51 where R18 is methyl.

57. The composition of claim 52 where the subscript e is 0.

58. The composition of claim 57 where the subscript d is 8.

59. The composition of claim 58 where R10, R11, R12, R13, R14, R15 and R16 are methyl.

60. The composition of claim 59 where R18 is methyl.

61. An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of claim 41.

62. An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of claim 51.

63. An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of claim 41.

63. An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of claim 51.

65. A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of claim 41.

66. A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of claim 51.

67. A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of claim 41.

68. A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of claim 51.

69. A silicone composition comprising a silicone having the formula: M5D3M6

70. The composition of claim 69 where R27 is selected from the group consisting of hydrogen and methyl.

71. The composition of claim 69 where the subscript i is 0.

72. The composition of claim 69 where the subscript h ranges from 0 to 3.

73. The composition of claim 69 where the subscript g ranges from 8 to 11.

74. The composition of claim 69 where R25 is selected from the group of 3 and 4 carbon monovalent hydrocarbon radicals.

75. The composition of claim 69 where R26 is a 3 carbon monovalent hydrocarbon radical.

76. The composition of claim 69 where R19, R20, R21, R22, R23, and R24 are methyl.

77. The composition of claim 76 where R25 is a 4 carbon monovalent hydrocarbon radical.

78. The composition of claim 77 where R25 is a 4 carbon monovalent hydrocarbon radical.

79. The composition of claim 78 where R19, R20, R21, R22, R23, and R24 are methyl.

80. The composition of claim 79 where the subscript g is 8.

81. The composition of claim 80 where the subscript h is 0.

82. The composition of claim 81 where the subscript i is 0.

83. A silicone composition comprising a silicone having the formula: M5D3M6

84. The composition of claim 83 where R27 is selected from the group consisting of hydrogen and methyl.

85. The composition of claim 83 where the subscript i is 0.

86. The composition of claim 83 where the subscript h ranges from 0 to 3.

87. The composition of claim 83 where the subscript g ranges from 8 to 11.

88. The composition of claim 83 where R25 is selected from the group of 3 and 4 carbon monovalent hydrocarbon radicals.

89. The composition of claim 83 where R26 is a 3 carbon monovalent hydrocarbon radical.

90. The composition of claim 83 where R19, R20, R21, R22, R23, and R24 are methyl.

91. The composition of claim 90 where R25 is a 4 carbon monovalent hydrocarbon radical.

92. The composition of claim 91 where R25 is a 4 carbon monovalent hydrocarbon radical.

93. The composition of claim 92 where R19, R20, R21, R22, R23, and R24 are methyl.

94. The composition of claim 93 where the subscript g is 8.

95. The composition of claim 94 where the subscript h is 0.

96. The composition of claim 95 where the subscript i is 0.

97. An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of claim 69.

98. An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of claim 83.

99. An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of claim 69.

100. An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of claim 83.

101. A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of claim 69.

102. A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of claim 83.

103. A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of claim 69.

104. A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of claim 83.