Hydrolysis resistant polyester elastomer compositions and related articles and methods

FIELD OF INVENTION

[0002] The field of invention relates to thermoplastic polyester elastomer compositions, and in particular, to hydrolysis resistant thermoplastic polyester elastomer compositions and applications made therefrom.

BACKGROUND OF INVENTION

[0003] Increasing requirements for hydrolysis resistance of polyesters, especially those requirements proposed by the automotive industry, have made it increasingly important to be able to provide thermoplastic polyester compositions having good resistance to hydrolysis compared to currently available compositions or those described in the existing art.

[0004] Hydrolysis resistance of thermoplastic polyesters can be improved by the addition of an epoxy material. However, when incorporated at the high levels necessitated by current hydrolysis resistant requirements, an epoxy material often has the disadvantage of adversely affecting the properties of the material. Depending on the epoxy material that is used, the melt viscosity may change away from the desired viscosity to give either a higher or a lower melt viscosity. A given epoxy material may also adversely affect important physical properties, such as the low temperature impact strength of the product.

[0005] It is known that hydrolysis resistance can also be improved by the addition of carbodiimide or polycarbodiimide additives. U.S. Pat. No. 3,193,522 discloses the stabilization of polyesters with polycarbodiimide; and Example 4 of this patent discloses the stabilization of a copolyetherester elastomer with a polycarbodiimide. While the addition of polycarbodiimide does improve the hydrolytic stability, it also has some important disadvantages which may make it undesirable to use. It often increases the melt viscosity of the resin, which makes it more difficult to fill the part in an injection molding process. And, irritating odors can be generated, which is thought to be caused in part by formation of volatile isocyanates at the processing temperatures that are used to injection mold the resin.

[0006] Japanese Patent Application No. 09208816 A discloses a composition containing, inter alia, polyester resin (particularly of the ethylene terephthalate type), a compound containing at least two epoxy groups and/or an epoxy resin, and carbon black. However, this reference does not mention any boron components.

[0007] U.S. Pat. No. 5,596,049 discloses a composition containing, inter alia, linear polyester and difunctional epoxy compounds, particularly those having at least one of the epoxides on a cyclohexane ring. A potential drawback to using cyclohexane ring-based epoxides, however, is the high volatility of such epoxides that are currently available. No mention is made of copolyetherester polymers or boron components.

[0008] JP 11153226 A (Abstract) discloses adding 0.01-10 pts wt. of a thermoplastic elastomer combined with a bifunctional epoxy glycidyl ester, to 100 parts of polyester block copolymer. The polyester block copolymer contains high crystalline aromatic polymer blocks of polybutylene terephthalate and 10-80% low melting point polymer segments which mainly comprise aliphatic polyether and/or polyester groups. Recited advantages are good surface finish, long term cure and rupture prevention. In the abstract, no mention is made of improved hydrolysis resistance or the use of boron components as a component of the composition.

[0009] JP 07138355 A (Abstract) recites a thermoplastic elastomer obtained by adding to a polyester thermoplastic elastomer 0.1-3 phr of multifunctional epoxy compound, which is then extruded to cause a crosslinking reaction in the molding machine. Uses disclosed are belts, hoses, and tubes in automotive uses, sound attenuation of gears of electric and electronic parts, wire coverings, resin modifiers, and sporting goods. The disclosed advantages are excellent compression set and speedy distortion recovery. This abstract does not disclose improved hydrolysis advantages or the addition of boron components.

[0010] JP 2000159985 A (Abstract) discloses a thermoplastic polyester elastomer composition comprising 100 parts by weight of a thermoplastic polyester elastomer; and 0.05-10 parts by weight of a compound having an epoxy group. This abstract, however, does not mention improved hydrolysis properties or the use of boron components in the composition.

[0011] U.S. Pat. No. 5,298,544 discloses a non-halogen, thermoplastic flame-retarded composition comprising a thermoplastic, which may be copolyetherimide ester and/or copolyether ester; non-halogen flame retardant; and zinc borate. No mention is made of epoxy compounds or improved hydrolysis resistant properties.

[0012] JP 09194743 A (Abstract) discloses a damping composition containing thermoplastic resin; polyester elastomer containing soft segments having 6-12C aliphatic alpha, omega diol as the glycol component; and 7-40 wt % whiskers having an average fiber diameter of 0.05-3 μm. Listed as preferred whiskers are aluminum borate whiskers and magnesium borate whiskers. The abstract does not disclose the use of epoxy compounds or any advantages relating to hydrolysis resistance.

[0013] JP 62041967 B (Abstract) recites a flame-retarding resin composition comprising polyester; a very specific modified epoxy compound; inorganic flame-retarding auxiliary agent; and reinforcing agent. The inorganic flame-retarding auxiliary agent may be barium metaborate. However, this abstract does not mention copolyetherester polymers, and it does not disclose any advantages relating to hydrolysis resistance.

SUMMARY OF INVENTION

[0014] My invention includes polymer compositions comprising copolyetherester, boron component, and epoxy component. My invention also includes articles made from such compositions, preferably molded articles in which hydrolysis resistance is desired.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

[0015] Polymer compositions of my invention comprise (a) copolyetherester;

[0016] (b) boron component; and (c) epoxy component.

[0017] Copolyetherester

[0018] Compositions of my invention comprise at least one copolyetherester.

[0019] Total copolyetherester comprises preferably between about 20 and about 99.5 weight percent of the composition, more preferably between about 40 and about 99 weight percent of the composition, and even more preferably between about 60 and about 98 weight percent of the composition.

[0020] When optional polyester other than copolyetherester is part of the composition, the percentage of the total optional polyester, based on the total of the total optional polyester and total copolyetherester in the composition, is preferably about 10 to 80 weight percent, more preferably about 20 to 70 weight percent, even more preferably about 20 to 50 weight percent, and even more preferably about 25 to 50 weight percent. Of course, total copolyetherester (and total optional polyester other than copolyetherester) can comprise the balance of the composition, after the amounts of epoxy component, boron component, and any other optional components (not limited to those discussed below) are factored in.

[0021] Preferred copolyetherester(s) (also herein referred to as copolyetherester elastomers or copolyetherester polymers) are now described.

[0022] In a preferred embodiment, the copolyetherester elastomer(s) have a multiplicity of recurring long-chain ester units and short-chain ester units joined head-to-tail through ester linkages, said long-chain ester units being represented by the formula:

[0023] and said short-chain ester units being represented by the formula:

[0024] wherein

[0025] G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide)glycol having an average molecular weight of about 400-3500;

[0026] R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight less than about 300;

[0027] D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250;

[0028] wherein said copolyetherester(s) contain from about 25 to about 99 weight percent short-chain ester units.

[0029] As used herein, the term “long-chain ester units” as applied to units in a polymer chain refers to the reaction product of a long-chain glycol with a dicarboxylic acid. Suitable long-chain glycols are poly(alkylene oxide) glycols having terminal (or as nearly terminal as possible) hydroxy groups and having a molecular weight of from about 400 to about 3500, particularly from about 600 to about 2300. Preferred poly(alkylene oxide) glycols include poly(tetramethylene oxide) glycol, poly(trimethylene oxide) glycol, poly(propylene oxide) glycol, poly(ethylene oxide glycol, copolymer glycols of these alkylene oxides, and block copolymers such as ethylene oxide-capped poly(propylene oxide) glycol. Mixtures of two or more of these glycols can be used.

[0030] The term “short-chain ester units” as applied to units in a polymer chain of the copolyetheresters refers to low molecular weight compounds or polymer chain units having molecular weights less than about 550. They are made by reacting a low molecular weight diol or a mixture of diols (MW below about 250) with a dicarboxylic acid to form ester units represented by Formula (II) above.

[0031] Included among the low molecular weight diols which react to form short-chain ester units suitable for use for preparing copolyetheresters are acyclic, alicyclic and aromatic dihydroxy compounds. Preferred compounds are diols with 2-15 carbon atoms such as ethylene, propylene, isobutylene, tetramethylene, 1,4-pentamethylene, 2,2-d imethyltrimethylene, hexamethylene and decamethylene glycols, dihydroxycyclohexane, cyclohexane dimethanol, resorcinol, hydroquinone, 1,5-dihydroxynaphthalene, etc. Especially preferred diols are aliphatic diols containing 2-8 carbon atoms, most especially 1,4-butanediol. Included among the bisphenols which can be used are bis(p-hydroxy)diphenyl, bis(p-hydroxyphenyl)methane, and bis(p-hydroxyphenyl)propane. Equivalent ester-forming derivatives of diols are also useful (e.g., ethylene oxide or ethylene carbonate can be used in place of ethylene glycol or resorcinol diacetate can be used in place of resorcinol).

[0032] The term “low molecular weight diols” as used herein should be construed to include such equivalent ester-forming derivatives; provided, however, that the molecular weight requirement pertains to the diol and not to its derivatives.

[0033] Dicarboxylic acids which are reacted with the foregoing long-chain glycols and low molecular weight diols to produce the copolyetheresters are aliphatic, cycloaliphatic or aromatic dicarboxylic acids of a low molecular weight, i.e., having a molecular weight of less than about 300. The term “dicarboxylic acids” as used herein includes acid equivalents of dicarboxylic acids having two functional carboxyl groups which perform substantially like dicarboxylic acids in reaction with glycols and diols in forming copolyetherester polymers. These equivalents include esters and ester-forming derivatives, such as acid halides and anhydrides. The molecular weight requirement pertains to the acid and not to its equivalent ester or ester-forming derivative. Thus, an ester of a dicarboxylic acid having a molecular weight greater than 300 or an acid equivalent of a dicarboxylic acid having a molecular weight greater than 300 are included provided the acid has a molecular weight below about 300. The dicarboxylic acids can contain any substituent groups or combinations which do not substantially interfere with the copolyetherester polymer formation and use of the polymer in the compositions of this invention.

[0034] The term “aliphatic dicarboxylic acids”, as used herein, means carboxylic acids having two carboxyl groups each attached to a saturated carbon atom. If the carbon atom to which the carboxyl group is attached is saturated and is in a ring, the acid is cycloaliphatic. Aliphatic or cycloaliphatic acids having conjugated unsaturation often cannot be used because of homopolymerization. However, some unsaturated acids, such as maleic acid, can be used.

[0035] Aromatic dicarboxylic acids, as the term is used herein, are dicarboxylic acids having two carboxyl groups attached to a carbon atom in a carbocyclic aromatic ring structure. It is not necessary that both functional carboxyl groups be attached to the same aromatic ring and where more than one ring is present, they can be joined by aliphatic or aromatic divalent radicals or divalent radicals such as —O— or —SO2—.

[0036] Representative aliphatic and cycloaliphatic acids which can be used are sebacic acid, 1,3-cyclohexane dicarboxylic acid, 1,4-cyclohexane dicarboxylic acid, adipic acid, glutaric acid, 4-cyclohexane-1,2-dicarboxylic acid, 2-ethylsuberic acid, cyclopentanedicarboxylic acid decahydro-1,5-naphthylene dicarboxylic acid, 4,4,′-bicyclohexyl dicarboxylic acid, decahydro-2,6-naphthylene dicarboxylic acid, 4,4,′-methylenebis(cyclohexyl) carboxylic acid, 3,4-furan dicarboxylic acid. Preferred acids are cyclohexane-dicarboxylic acids and adipic acid.

[0037] Representative aromatic dicarboxylic acids include phthalic, terephthalic and isophthalic acids, bibenzoic acid, substituted dicarboxy compounds with two benzene nuclei such as bis(p-carboxyphenyl)methane, p-oxy-1,5-naphthalene dicarboxylic acid, 2,6-naphthalene dicarboxylic acid, 2,7-naphthalene dicarboxylic acid, 4,4,′-sulfonyl dibenzoic acid and C1-C12 alkyl and ring substitution derivatives thereof, such as halo, alkoxy, and aryl derivatives. Hydroxyl acids such as p-(beta-hydroxyethoxy)benzoic acid can also be used providing an aromatic dicarboxylic acid is also present.

[0038] Aromatic dicarboxylic acids are a preferred class for preparing the copolyetherester polymers useful for this invention. Among the aromatic acids, those with 8-16 carbon atoms are preferred, particularly terephthalic acid alone or with a mixture of phthalic and/or isophthalic acids.

[0039] The copolyetheresters preferably contain about 25-99 weight percent short-chain ester units corresponding to Formula (II) above, the remainder being long-chain ester units corresponding to Formula (I) above. The copolyetheresters more preferably contain about 40-95, and even more preferably about 60-90, weight percent short-chain ester units the remainder being long-chain ester units. In general, as percent short-chain ester units in the copolyetherester are increased, the polymer has a higher tensile strength and modulus, and the moisture vapour transmission rate decreases. Most preferably, at least about 70% of the groups represented by R in Formulae (I) and (II) above are 1,4-phenylene radicals and at least about 70% of the groups represented by D in Formula (II) above are 1,4-butylene radicals and the sum of the percentages of R groups which are not 1,4-phenylene radicals and D groups which are not 1,4-butylene radicals does not exceed 30%. If a second dicarboxylic acid is used to make the copolyetherester, isophthalic acid is the acid of choice and if a second low molecular weight diol is used, 1,4-butenediol or hexamethylene glycol are the diols of choice.

[0040] A blend or mixture of two or more copolyetherester elastomers can be used. The copolyetherester elastomers used in the blend need not on an individual basis come within the values disclosed hereinbefore for the elastomers. However, the blend of two or more copolyetherester elastomers must conform to the values described herein for the copolyetheresters on a weighted average basis. For example, in a mixture that contains equal amounts of two copolyetherester elastomers, one copolyetherester can contain 60 weight percent short-chain ester units and the other copolyetherester can contain 30 weight percent short-chain ester units for a weighted average of 45 weight percent short-chain ester units.

[0041] Preferably, the copolyetherester elastomers are prepared from esters or mixtures of esters of terephthalic acid and isophthalic acid, 1,4-butanediol and poly(tetramethylene ether)glycol or ethylene oxide-capped polypropylene oxide glycol, or are prepared from esters of terephthalic acid, e.g. dimethylterephthalate, 1,4-butanediol and poly(ethylene oxide)glycol. More preferably, the copolyetherester elastomers are prepared from esters of terephthalic acid, e.g. dimethylterephthalate, 1,4-butanediol and poly(tetramethylene ether)glycol.

[0042] The dicarboxylic acids or their derivatives and the polymeric glycol are preferably incorporated into the final product in the same molar proportions as are present in the reaction mixture. The amount of low molecular weight diol actually incorporated corresponds to the difference between the moles of diacid and polymeric glycol present in the reaction mixture. When mixtures of low molecular weight diols are employed, the amounts of each diol incorporated is largely a function of the amounts of the diols present, their boiling points, and relative reactivities. The total amount of glycol incorporated is still the difference between moles of diacid and polymeric glycol.

[0043] The copolyetherester elastomers described herein can be made conveniently by a conventional ester interchange reaction. A preferred procedure involves heating the ester of an aromatic acid, e.g., dimethyl ester of terephthalic acid, with the poly(alkylene oxide)glycol and a molar excess of the low molecular weight diol, 1,4-butanediol, in the presence of a catalyst at 150°-160° C., followed by distilling off methanol formed by the interchange reaction. Heating is continued until methanol evolution is complete. Depending on temperature, catalyst and glycol excess, this polymerization is complete within a few minutes to a few hours. This product results in the preparation of a low molecular weight prepolymer which can be carried to a high molecular weight copolyetherester by the procedure described below. Such prepolymers can also be prepared by a number of alternate esterification or ester interchange processes; for example, the long-chain glycol can be reacted with a high or low molecular weight short-chain ester homopolymer or copolymer in the presence of catalyst until randomization occurs. The short-chain ester homopolymer or copolymer can be prepared by ester interchange from either the dimethyl esters and low molecular weight diols as above, or from the free acids with the diol acetates. Alternatively, the short-chain ester copolymer can be prepared by direct esterification from appropriate acids, anhydrides or acid chlorides, for example, with diols or by other processes such as reaction of the acids with cyclic ethers or carbonates. Obviously the prepolymer might also be prepared by running these processes in the presence of the long-chain glycol.

[0044] The resulting prepolymer is then carried to high molecular weight by distillation of the excess of short-chain diol. This process is known as “polycondensation”. Additional ester interchange occurs during this distillation to increase the molecular weight and to randomize the arrangement of the copolyetherester units. Best results are usually obtained if this final distillation or polycondensation is run at less than 1 mm pressure and 240°-260° C. for less than 2 hours in the presence of antioxidants such as 1,6-bis-(3,5-di-tert-butyl-4-hydroxyphenol)propionamido]-hexane or 1,3,5-trimethyl-2,4,6-tris[3,5-ditertiary-butyl-4-hydroxybenzyl]benzene. Most practical polymerization techniques rely upon ester interchange to complete the polymerization reaction. In order to avoid excessive hold time at high temperatures with possible irreversible thermal degradation, it is advantageous to employ a catalyst for ester interchange reactions. While a wide variety of catalysts can be used, organic titanates such as tetrabutyl titanate used alone or in combination with magnesium or calcium acetates are preferred. Complex titanates, such as derived from alkali or alkaline earth metal alkoxides and titanate esters are also very effective. Inorganic titanates, such as lanthanum titanate, calcium acetate/antimony trioxide mixtures and lithium and magnesium alkoxides are representative of other catalysts which can be used.

[0045] Ester interchange polymerizations are generally run in the melt without added solvent, but inert solvents can be used to facilitate removal of volatile components from the mass at low temperatures. This technique is especially valuable during prepolymer preparation, for example, by direct esterification. However, certain low molecular weight diols, for example, butanediol, are conveniently removed during polymerization by azeotropic distillation. Other special polymerization techniques for example, interfacial polymerization of bisphenol with bisacylhalides and bisacylhalide capped linear diols, may be useful for preparation of specific polymers. Both batch and continuous methods can be used for any stage of copolyetherester polymer preparation. Polycondensation of prepolymer can also be accomplished in the solid phase by heating finely divided solid prepolymer in a vacuum or in a stream of inert gas to remove liberated low molecular weight diol. This method is believed to have the advantage of reducing degradation because it is used at temperatures below the softening point of the prepolymer where the degradation rate is much slower relative to the polymerization rate. The major disadvantage is the long time required to reach a given degree of polymerization.

[0046] Boron Component

[0047] Polymer compositions of my invention comprise a boron component preferably comprising boron oxide, boric acid, borate salt, or any mixtures of one or more of any of the foregoing.

[0048] The boron component comprises preferably between about 0.01 and about 5 weight percent of the composition, more preferably between about 0.05 and about 1 weight percent of the composition, and even more preferably between about 0.1 and about 0.5 weight percent of the composition.

[0049] More preferably, the boron component comprises boric acid, borate salt, or any mixtures of one or more of any of the foregoing. Even more preferably, the boron component comprises at least one borate salt.

[0050] As used herein, “borate salt” (or simply “borate”) means the salt of a boric acid. There are different boric acids, including metaboric acid (HBO2), orthoboric acid (H3BO3), tetraboric acid (H2B4O7), and pentaboric acid (HB5O9). Each of these acids can be converted to a salt by reaction with a base. Different bases can be used to make different borates. These include amino compounds which give ammonium borates, and hydrated metal oxides such as sodium hydroxide which gives sodium borates. These borates may be anhydrous, or they may be hydrated. For example, sodium tetraborate is available in the anhydrous form, and also as the pentahydrate and the decahydrate.

[0051] Preferred borate salts are alkali metal borates, with sodium, lithium, and potassium being preferred, and with sodium tetraborate being especially preferred.

[0052] Other preferred metal borates are divalent metal borates, with alkaline earth metal borates being preferred, in particular calcium and magnesium. Trivalent metal borates, such as aluminum borate, may also be used.

[0053] Epoxy Component

[0054] Polymer compositions of my invention comprise an epoxy component.

[0055] The epoxy component comprises an amount sufficient to provide preferably about 5 to 500 millequivalents (MEQ), more preferably about 10 to 300 millequivalents (MEQ), more preferably about 15 to 200 millequivalents (MEQ), and even more preferably about 20 to 150 milliequivalents (MEQ), of total epoxy function per kg of total copolyetherester (or per kg of both total copolyetherester and total other polyester if present) in the composition.

[0056] By equivalents herein is meant the number of “moles” of epoxy functional group added.

[0057] Preferably, the epoxy component comprises one or more of epoxy polymers and/or epoxy compounds.

[0058] A preferred epoxy polymer is a diphenolic epoxy condensation polymer. As used herein, “diphenolic epoxy condensation polymer” means a condensation polymer having epoxy functional groups, preferably as end groups, and a diphenol moiety within the polymer. Such diphenolic epoxy condensation polymers are well-known to one of ordinary skill in the art.

[0059] A preferred diphenolic epoxy condensation polymer is the following:

[0060] where n=1-16; and

[0061] X is —; —C(CH3)2—; —SO2—; —C(CF3)2—; —CH2—; —CO—; or —CCH3C2H5—.

[0062] n represents an average and therefore need not be a whole number; X may be the same throughout the polymer or may change throughout the polymer. Preferably, X is —C(CH3)2.

[0063] Preferred diphenolic epoxy condensation polymers include condensation polymers of epichlorohydrin with a diphenolic compound. Also preferred is a 2,2-bis(p-glycidyloxyphenyl) propane condensation product with 2,2-bis(p-hydroxyphenyl)propane and similar isomers.

[0064] Preferred commercially available diphenolic epoxy condensation polymers include the EPON® 1000 series of resins (1001 F-1009F), available from Shell Chemical Co. Particularly preferred are EPON® 1001F, EPON® 1002F, and EPON® 1009F.

[0065] A preferred epoxy compound comprises a compound comprising at least two epoxy groups per molecule of the compound, more preferably at least three epoxy groups per molecule of the compound, and more preferably at least four epoxy groups per molecule of the compound. Even more preferably, this compound comprises between two and four epoxy groups per molecule of the compound. The epoxy groups of this compound preferably comprise glycidyl ethers, and even more preferably, glycidyl ethers of phenolic compounds. This compound may be polymeric or non-polymeric, with non-polymeric being preferred. A preferred commercially available embodiment is EPON® 1031 (available from Shell Chemical Co.), which is believed to be primarily a tetraglycidyl ether of tetra (parahydroxyphenyl) ethane.

[0066] Another preferred embodiment of the epoxy component is what I shall refer to as an “epoxy system”. The epoxy system comprises (i) diphenolic epoxy condensation polymer (“first part of the epoxy system”) and (ii) at least one epoxy compound comprising at least two epoxy groups per molecule of the epoxy compound (“second part of the epoxy system”).

[0067] The first part of the epoxy system comprises the preferred diphenolic epoxy condensation polymer, as described above, of which the EPON® 1000 series of resins are preferred commercially available embodiments. The second part of the epoxy system comprises the other preferred epoxy compounds, also described above, of which EPON® 1031 is a preferred commercially available embodiment.

[0068] The epoxy compound(s) of the second part of the epoxide system is/are different from the diphenolic epoxy condensation polymers used in the first part of the epoxy system and may be polymeric or non-polymeric. Preferably, the epoxy compound is non-polymeric.

[0069] Preferably, the epoxy system comprises about 5 to 500 millequivalents (MEQ) of total epoxy function per kg of total copolyetherester (or per kg of both total copolyetherester and total other polyester if present) in the composition.

[0070] More preferably, the epoxy system comprises about 10 to 300 millequivalents (MEQ) of total epoxy function per kg of total copolyetherester (or per kg of both total copolyetherester and total other polyester if present) in the composition.

[0071] Even more preferably, the epoxy system comprises about 15 to 200 millequivalents (MEQ) of total epoxy function per kg of total copolyetherester (or per kg of both total copolyetherester and total other polyester if present) in the composition.

[0072] Even more preferably, the epoxy system comprises about 20 to 150 millequivalents (MEQ) of total epoxy function per kg of total copolyetherester (or per kg of both total copolyetherester and total other polyester if present) in the composition.

[0073] With respect to any of the above preferred ranges, the second part of the epoxy system provides preferably about 1 to about 99% of the total epoxy function, more preferably about 1 to about 80% of the total epoxy function, more preferably about 1 to about 60% of the total epoxy function, even more preferably about 10 to about 75% of the total epoxy function, and most preferably about 20 to about 50% of the total epoxy function.

[0074] Optional Component—Polyester Other Than Copolyetherester

[0075] Compositions of my invention may optionally include at least one polyester other than the copolyetherester(s).

[0076] When present, total polyester other than the copolyetherester(s) in the composition comprises preferably between about 1 and 99 weight percent of the composition, more preferably between about 10 and 50 weight percent of the composition, and even more preferably between about 20 and 40 weight percent of the composition.

[0077] Preferred polyesters include polymers which are, in general, linear saturated condensation products of glycols and dicarboxylic acids, or reactive derivatives thereof. Preferably, polyesters comprise condensation products of aromatic dicarboxylic acids having 8 to 14 carbon atoms and at least one glycol selected from the group consisting of neopentyl glycol, cyclohexane dimethanol and aliphatic glycols of the formula HO(CH2)nOH where n is an integer of 2 to 10. Up to 50 mole percent of the aromatic dicarboxylic acids can be replaced by at least one different aromatic dicarboxylic acid having from 8 to 14 carbon atoms, and/or up to 20 mole percent can be replaced by an aliphatic dicarboxylic acid having from 2 to 12 carbon atoms.

[0078] A high molecular weight polyester can be obtained preferably by solid state polymerization of a lower molecular weight polyester obtained by melt condensation.

[0079] Preferred polyesters include polyethylene terephthalate; poly(1,4-butylene) terephthalate; 1,4-cyclohexylene dimethylene terephthalate; 1,4-cyclohexylene dimethylene terephthalate/isophthalate copolymer; and other linear homopolymer esters derived from aromatic dicarboxylic acids and glycols. Preferred aromatic dicarboxylic acids include terephthalic; isophthalic; bibenzoic; naphthalane-dicarboxylic including the 1,5-,2,6-, and 2,7-naphthalenedicarboxylic acids; 4,4′diphenylenedicarboxylic acid; bis(p-carboxyphenyl) methane; ethylene-bis-p-benzoic acid; 1,4-tetramethylene bis(p-oxybenzoic) acid; ethylene bis(p-oxybenzoic) acid; and 1,3-trimethylene bis(p-oxybenzoic) acid. Preferred glycols include those selected from the group consisting of 2,2-dimethyl-1,3-propane diol; cyclohexane dimethanol; and aliphatic glycols of the general formula HO(CH2)nOH where n is an integer from 2 to 10, e.g., ethylene glycol; 1,3-trimethylene glycol; 1,4-tetramethylene glycol; 1,6-hexamethylene glycol; 1,8-octamethylene glycol; and 1,10-decamethylene glycol. Up to 20 mole percent, as indicated above, of preferably adipic, sebacic, azelaic, dodecanedioic acid or 1,4-cyclohexanedicarboxylic acid can be present.

[0080] More preferred polyesters are based on polyethylene terephthalate homopolymers, polybutylene terephthalate homopolymers, polyethylene terephthalate/polybutylene terephthalate copolymers, polyethylene terephthalate copolymers, polyethylene terephthalate/polybutylene terephthalate mixtures and/or mixtures thereof, although any other polyesters can be used as well, either alone or in any combination with any of the polyesters described herein. Even more preferred as the polyester is polybutylene terephthalate which has not been solid state polymerized.

[0081] Other Optional Components

[0082] Conventional additives may be added to the polymer compositions of my invention. For instance, a flame retardant and flame-retardant synergist may be added for the purpose of improving flame retardancy, and an antioxidant and heat stabilizer may be added for the purpose of improving heat resistance and preventing discoloration. Other additives include fillers, inert fillers, reinforcing agents, impact modifiers, viscosity modifiers, nucleating agents, colorants and dyes, lubricants, plasticizers, mold-releasing agents, and UV stabilizers.

[0083] Polymer compositions of my invention can be obtained by blending all of the component materials using any blending method. These blending components in general are preferably made homogeneous as much as possible. As a specific example, all of the component materials are mixed to homogeneity using a mixer such as a blender, kneader, Banbury mixer, roll extruder, etc. to give a resin composition. Or, part of the materials may be mixed in a mixer, and the rest of the materials may then be added and further mixed until homogeneous. Alternatively, the materials may be dry-blended in advance, and a heated extruder is then used to melt and knead until homogeneous, and then to extrude in a strand shape, followed by cutting to a desirable length to become granulates.

[0084] Polymer compositions of my invention may be used alone as molding pellets or mixed with other polymers. The pellets may be used to produce fibers, films, and coatings as well as injection molded or extruded articles, particularly for end use applications where hydrolysis resistance is desired, for example, tubing, cable jackets, molded appliance parts, and molded interior automotive parts, wire jacketing, loose buffer tubing for optical fiber cables, and molded parts used in higher humidity use environments.

[0085] Molding of the polymer compositions of my invention into articles can be carried out according to methods known to those skilled in the art. Preferred are generally utilized molding methods such as injection molding, extruding molding, pressing molding, foaming molding, blow molding, vacuum molding, injection blow molding, rotation molding, calendar molding and solution casting molding.

EXAMPLES

[0086] The following Examples 1-7 illustrate preferred embodiments of my invention. My invention is not limited to these Examples.

[0087] The materials used in the Examples were:

[0088] PBT: thermoplastic polybutylene terephthalate having a weight average molecular weight of 50,000 and an inherent viscosity of 1.07 dl/g (0.4 g/100 ml 50/50 methylene chloride/trifluoroacetic acid at 19° C.).

[0089] PEE A: segmented copolyetherester containing 38 wt % 1,4-butylene terephthalate and 11 wt % 1,4-butylene isophthalate short chain ester units, and long chain ester, units derived from the terephthalate and isophthalate esters of poly(tetramethylene ether)glycol having a number average molecular weight of about 1,000. PEE A has a Shore D hardness of 40 D.

[0090] PEE B: segmented copolyetherester containing 45 wt % 1,4-butylene terephthalate short chain ester units and long chain ester units derived from poly(tetramethylene ether)glycol having a number average molecular weight of about 1,400. PEE B has a Shore D hardness of 45 D.

[0091] PEE C: segmented copolyetherester containing 70 wt % 1,4-butylene terephthalate short chain ester units and long chain ester units derived from poly(tetramethylene ether)glycol having a number average molecular weight of about 1,000. PEE B has a Shore D hardness of 63 D.

[0092] CB: concentrate of 25% of carbon black in PEE A.

[0093] Epoxy:

[0094] Four different grades of EPON® epoxides were used. These are all different glycidyl epoxide ethers, but they differ in the chemical structure, and in the epoxide equivalent weight. The EPON® 1009F is believed to have an epoxide equivalent weight of 3050; the EPON® 1002F is believed to have an epoxide equivalent weight of 650; the EPON® 1001 F is believed to have an epoxide equivalent weight of 538; and the EPON® 1031 is believed to have an epoxide equivalent weight of 212. In general, at lower epoxide equivalent weight, there is more epoxide functionality on a weight basis. These EPON® epoxides are all available from Shell.

[0095] Borates:

[0096] Anhydrous Sodium Tetraborate (available from VWR Scientific Products, West Chester, Pa.).

[0097] Sodium Borate Decahydrate (available from US Borax Inc., Hoffman Estates, Ill.)

[0098] Sodium Borate Decahydrate “20 Mule Team Borax” (obtained from local Acme chain grocery store, Wilmington, Del.)

[0099] Potassium Tetraborate Tetrahydrate (available from Sigma, St. Louis, Mo.)

[0100] Lithium Tetraborate (available from Sigma)

[0101] Lithium Metaborate (available from Sigma)

[0102] Potassium Pentaborate (from laboratory bottle, source unknown)

[0103] Magnesium Borate (available from Bodman, Aston, Pa.)

[0104] Aluminum Borate (available from Bodman)

[0105] Calcium Tetraborate (available from Bodman)

[0106] The anhydrous sodium tetraborate was received in granular form with an average particle size of about 1 mm and was micronized in a Vortac jet mill, model E12 with a powder auger to give anhydrous sodium tetraborate with a median particle size of 6 μm, which was used for most of the Examples. The other borate compounds that were used in the Examples were received as a finer particulate, and were further ground to give a smaller particle size with a mortar and pestle.

[0107] Polymer blends were prepared by premixing the ingredients in their proper proportions in a suitable vessel such as a drum or a plastic bag. The mixture was then melt blended in a 30 mm Werner and Pfleiderer twin screw extruder with a barrel temperature of 240° C., and a polymer melt temperature of 265° C. exiting the extruder. The compounded material exiting the die was quenched in water, surface water removed by compressed air and cut into pellets. The product was thoroughly dried in a vacuum oven, and was then molded into microtensile bars on a 6 ounce (170 g) Van Dorn machine with a nozzle temperature of 250° C. and a mold temperature of 30° C.

[0108] Tensile properties including tensile strength and elongation at break were determined on injection molded microdumbbell test bars according to ASTM D412, with a test speed of 50 cm/min.

[0109] Hydrolytic stability testing was preformed by placing the molded test samples in a Barnstead Laboratory Sterilizer. The sterilizer was operated at 125° C. and 18 psi (124 KPa) water vapor pressure above atmospheric pressure. The samples were typically exposed to these conditions for time periods of up to 8 days (192 hours) or more (288 hours). After this time, the samples were removed from the autoclave, allowed to cool, and tested for tensile properties. For comparison, tensile properties were also determined on samples prior to hydrolytic stability testing.

[0110] In the Examples and tables contained therein, unless otherwise indicated, all of the amounts are given as percents by weight of each component in the final composition. Further, in the tables, “n/m” indicates that no measurement was taken for the particular entry.

Example 1

[0111] Example 1 compares the effect of using both a borate component and an epoxy component (Examples 1.1-1.9), compared to using only an epoxide component or neither component. (Comp. 1.1-1.6). Table 1A sets forth the tensile strength and elongation at break data for Examples 1.1-1.9, and Table 1 B sets forth the tensile strength and elongation at break data for Comp. 1.1-1.6.

1TABLE 1AReferenceEx. 1.1Ex. 1.2Ex. 1.3Ex. 1.4Ex. 1.5Ex. 1.6Ex. 1.7Ex. 1.8Ex. 1.9PBT252524.924.92525252525PEE B68.968.968.870.870.9635370.967.5PEE A7.915.8CB222222221.85EPON ® 1001F000000005.55EPON ® 1002F444222420Sodium Tetraborate,0.10.10.30.30.10.10.20.10.1finely groundTOTAL %100.0100.0100.0100.0100.0100.0100.0100.0100.0Original Tensile376236003652370338353717372936253058Strength psiTensile Strength after30393062311024002565256233011466n/m96 hoursTensile Strength after1611n/m21691206146212101655n/m2953192 hoursTensile Strength aftern/mn/mn/mn/mn/mn/mn/mn/m764288 hoursOriginal Elongation at507485491500504508531471369Break, %Elongation at Break446431426289327340481170n/mafter 96 hoursElongation at Breakn/m297n/mn/mn/mn/mn/m24n/mafter 144 hoursElongation at Break101n/m99141515204n/m394after 192 hoursElongation at Breakn/mn/mn/mn/mn/mn/mn/mn/m277after 288 hours

[0112]

2

TABLE 1B

Comp.
Comp.
Comp.
Comp.
Comp.
Comp.

Reference
1.1
1.2
1.3
1.4
1.5
1.6

PBT
25
25
25
25
25
23.6

PEE B
75
73
71
69
71
68.9

CB
0
2
2
2
2
1.9

EPON ® 1001F
0
0
0
0
0
5.6

EPON ® 1002F
0
0
2
4
2
0

TOTAL %
100
100
100
100
100
100

Original Tensile Strength psi
3607
3613
3717
3719
3739
3578

Tensile Strength after 96 hours
1950
2370
1833
2064
1844
n/m

Tensile Strength after 192 hours
0
0
923
1023
n/m
1934

Tensile Strength after 288 hours
n/m
n/m
n/m
n/m
n/m
0

Original Elongation at Break, %
505
480
488
507
496
519

Elongation at Break after 96
57
43
94
149
98
n/m

hours

Elongation at Break after 144
n/m
n/m
n/m
n/m
16
n/m

hours

Elongation at Break after 192
0
0
12
13
n/m
43

hours

Elongation at Break after 288
n/m
n/m
n/m
n/m
n/m
10

hours

[0113] These results show the improved hydrolytic stability performance from a combination of the boron component and the epoxy component. The elongation at break values after 96 hours exposure are considerably higher for Exs. 1.4, 1.5, 1.6, and 1.8 compared to Comp. 1.3 and 1.5 with the same amount of EPON® 1002F but no boron component. Similarly, the elongation at break values after 96 hours exposure and after 192 hours exposure are much higher for Exs. 1.1, 1.3, and 1.7 compared to Comp. 1.4 with the same level of EPON® 1002F but no boron component. Also, the elongation at break values after 192 and after 288 hours are much higher for Ex. 1.8 than for Comp. 1.6 with the same level of EPON® 1001 F but no boron component

Example 2

[0114] Example 2 contains compositions having a borate component and different types of epoxy components, as set forth in Ex. 2.1-2.7 in Table 2 below. These are effective at improving the hydrolytic stability as can be seen from the high elongation at break values after 96 hours exposure.

3TABLE 2ReferenceEx. 2.1Ex. 2.2Ex. 2.3Ex. 2.4Ex. 2.5Ex. 2.6Ex. 2.7PBT25252525252525PEE B71.269.667.962.971.5772.2370.23CB2222222EPON ® 1001F1.73.300000EPON ® 1002F0000002EPON ® 1009F00510000EPON ® 103100001.330.670.67Sodium Tetraborate, finely0.10.10.10.10.10.10.1groundTOTAL %100.0100.0100.0100.0100.0100.0100.0Original Tensile Strength psi3666368836873485345435703580Tensile Strength after 96 hours1759322315912569255519222930Tensile Strength after 192n/mn/mn/mn/m1883122310hoursOriginal Elongation at Break,479498480492482500508%Elongation at Break after 96209460129328306165421hoursElongation at Break after 1443236326137n/mn/mn/mhoursElongation at Break after 192n/mn/mn/mn/m221193hours

Example 3

[0115] Example 3 contains examples of an “epoxy system” embodiment, as forth in Ex. 3.1-3.2 in Table 3 below. Table 3 also contains Comp. 3.1.

4TABLE 3Comp.Reference3.1Ex. 3.1Ex. 3.2PBT10001PEE B093.995.9EPON ® 1001F042EPON ® 1031021Sodium Tetraborate, finely ground00.10.1TOTAL %100100.0100.0Original Tensile Strength psi369135133178Tensile Strength after 192 hours148721132253Tensile Strength after 288 hours017401420Original Elongation at Break, %886788920Elongation at Break after 192 hours81486318Elongation at Break after 288 hours058493

Example 4

[0116] Example 4 contains compositions in which the particle size of the boron component is varied, as set forth in Ex. 4.1-4.4 in Table 4 below. As shown by Table 4, inter alia, higher elongation at break values are obtained after 96 hours exposure when finely ground sodium tetraborate is used.

5TABLE 4ReferenceEx. 4.1Ex. 4.2Ex. 4.3Ex. 4.4PBT252524.925PEE B70.970.970.670.9CB2222EPON ® 1002F2222Sodium Tetraborate, finely ground0.1000Sodium Tetraborate, medium0000.1groundSodium Tetraborate, coarse ground00.10.50TOTAL %100.0100.0100.0100.0Original Tensile Strength psi3560345233433538Tensile Strength after 96 hours2522206816482328Tensile Strength after 192 hours5506n/m1263Original Elongation at Break, %457440430454Elongation at Break after 96 hours307137104123Elongation at Break after 144n/mn/m28n/mhoursElongation at Break after 192110n/m14hours

Example 5

[0117] Example 5 contains compositions in which various different boron components are employed, as set forth in Ex. 5.1-5.3.3 in Table 5A below. Table 5B below contains comparative examples (Comp. 5.1-5.3). As shown by Tables 5A and 5B, inter alia, higher elongation at break values are achieved after 96 hours exposure, especially when alkali metal borates are used as the boron component.

6TABLE 5AReferenceEx. 5.1Ex. 5.2.1Ex. 5.2.2Ex. 5.2.3Ex. 5.2.4Ex. 5.3.1Ex. 5.3.2Ex. 5.3.3PBT2525252525252525PEE B70.970.970.970.970.970.970.970.9CB22222222EPON ® 1002F22222222Sodium0.10000000Tetraborate, finelygroundLithium00.1000000TetraborateLithium000.100000MetaboratePotassium0000.10000TetraboratePotassium00000.1000PentaborateCalcium000000.100TetraborateMagnesium0000000.10BorateAluminum Borate00000000.1TOTAL %100.0100.0100.0100.0100.0100.0100.0100.0Original Tensile38203836376538563860369738163779Strength psiTensile Strength18621758162718792199208224002400after 96 hoursTensile Strength667151814530938000after 192 hoursOriginal511510506513512490494489Elongation atBreak, %Elongation at2351951451571901085170Break after 96hoursElongation at121615012000Break after 192hours

[0118]

7

TABLE 5B

Reference
Comp. 5.1
Comp. 5.2
Comp. 5.3

PBT
25
25
25

PEE B
73
73
71

CB
2
2
2

EPON ® 1002F
0
0
2

TOTAL %
100
100
100

Original Tensile Strength psi
3731
3842
3687

Tensile Strength after 96 hours
2353
1654
2452

Tensile Strength after 192 hours
0
0
0

Original Elongation at Break, %
488
504
485

Elongation at Break after 96 hours
40
39
64

Elongation at Break after 192 hours
0
0
0

Example 6

[0119] Example 6 contains examples of compositions which were direct injection molded blends of PEE C with concentrates of EPON® 1002F and sodium tetraborate in PEE A, as set forth in Ex. 6.1-6.4 in Table 6 below. These concentrates contained 79% of PEE A, 20% of EPON®) 1002F (or 13.3% of EPON® 1002F and 6.7% of EPON® 1031), and 1% of finely ground sodium tetraborate. The compositions in Table 6 give the final compositions of the molded products. Table 6 also includes Comp. 6.1.

8TABLE 6Comp.Reference6.1Ex. 6.1Ex. 6.2Ex. 6.3Ex. 6.4PEE C10095908090PEE A03.957.915.87.9EPON ® 1002F01241.33EPON ® 103100000.67Sodium Tetraborate, finely ground00.050.10.20.1TOTAL %100100.0100.0100.0100.0Original Tensile Strength psi47464534442138984362Tensile Strength after 48 hours302836403557n/m3284Tensile Strength after 96 hours9002816157327461816Tensile Strength after 192 hours00017920Original Elongation at Break, %504471486474487Elongation at Break after 48 hours363452513n/m498Elongation at Break after 96 hours920165489221Elongation at Break after 192 hours0001040

Example 7

[0120] Example 7 contains compositions containing sodium borate decahydrate, as set forth in Ex. 7.1-7.2 in Table 7 below.

9TABLE 7ReferenceEx. 7.1Ex. 7.2PBT24.924.9PEE B70.970.9CB22EPON ® 1002F22Sodium Tetraborate Decahydrate0.20.2TOTAL %100.0100.0Original Tensile Strength psi38233851Tensile Strength after 96 hours27792694Tensile Strength after 192 hours12251510Original Elongation at Break, %491505Elongation at Break after 96 hours349372Elongation at Break after 192 hours1317

[0121] While this invention has been described with respect to what is at present considered to be the preferred embodiments, it is to be understood that the invention is not limited to the disclosed embodiments. To the contrary, the invention is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims. The scope of the following claims is to be accorded the broadest interpretation so as to encompass all such modifications and equivalent formulations and functions.

Hydrolysis resistant polyester elastomer compositions and related articles and methods

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