Claims
- 1. A thickener composition comprising the reaction product of(a) a polymerization reaction product of: (1) an isocyanate starting material, (2) a polyether polyol; and (b) a linear difunctional hydrophilic endcapping material other than a polyether polyol that is reactive with isocyanate groups, and wherein said linear difunctional hydrophilic endcapping material is present in a sufficient quantity so as to provide about twice the number of equivalents as are required to theoretically react all of the isocyanate-groups.
- 2. The thickener composition of claim 1 wherein said isocyanate starting material is a diisocyanate or triisocyanate.
- 3. The thickener composition of claim 2 wherein said polyether polyol of the polymerization reaction product is a polyalkylene oxide having a number average molecular weight between about 1000 and about 20,000.
- 4. The thickener composition of claim 3 wherein said linear difunctional hydrophilic endcapping material is selected from the group consisting of C4-C20 diols, diamines, dithiols, dicarboxylic acids, diepoxies, and mixtures thereof wherein said endcapping material has isocyanate-reactive groups positioned at the end of the chain.
- 5. The thickener composition of claim 4 wherein said linear difunctional hydrophilic endcapping material is selected from the group consisting of 1,6-hexanediol, 1,10-decanediol, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane, 1,7-diaminoheptane, 1,8-diaminooctane, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, 4,4′-diaminodicyclohexylmethane, 1,4-butanedithiol, 1,5-pentanedithiol, 1,6-hexanedithiol, 1,7-heptanedithiol, 1,8-octanedithiol, 1,9-nonanedithiol, 1,10-decanedithiol, 1,4butanedicarboxylic acid, 1,5-pentanedicarboxylic acid, 1,6-hexanedicarboxylic acid, 1,7-heptanedicarboxylic acid, 1,8-octanedicarboxylic acid, 1,9-nonanedicarboxylic acid, 1,10decanedicarboxylic acid, 1,4-butanediol diglycidal ether, 1,5-pentanediol diglycidal ether, 1,6-hexanediol diglycidal ether, 1,7-heptanediol diglycidal ether, 1,8-octanediol diglycidal ether, 1,9-nonanediol diglycidal ether, 1,10-decanediol diglycidal ether, bisphenol A diepoxide, and mixtures thereof.
- 6. The thickener composition of claim 2 wherein said isocyanate starting material is selected from the group consisting of dicyclohexylmethane-4,4′-diisocyanate, isophorone diisocyanate, diphenylmethane-4,4′-diisocyanate and isocyanurate trimer of hexamethylene diisocyanate.
- 7. The thickener composition of claim 3 wherein said polyether polyol of the polymerization reaction product is selected from the group consisting of alkylene oxide adducts of an aliphatic, cycloaliphatic or aromatic polyhydroxy compound the hydroxyl-terminated prepolymers of an alkylene oxide adducts and an organic polyisocyanate, or mixtures thereof, polyalkylolalkanes and polyhydroxyalkanes.
- 8. The thickener composition of claim 7 wherein said polyether polyol of the polymerization reaction product is selected from the group consisting of polyethylene oxides and polypropylene oxides having number average molecular weights of between about 4,000 and about 20,000.
- 9. The thickener composition of claim 8 wherein said polyether polyol of the polymerization reaction product is polyethylene glycol having a number average molecular weight of between about 4,000 and about 12,000.
- 10. A thickener composition comprising a reaction product of:(a) a polymerization reaction product of: (1) an isocyanate starting material, and (2) a polyether polyol, and (3) a diol; (b) a linear difunctional hydrophilic endcapping material other than a polyether polyol that is reactive with isocyanates, and wherein said difunctional hydrophilic endcapping material is present in a sufficient quantity so as to provide about twice the number of equivalents as are required to theoretically react all of the isocyanate-groups.
- 11. The thickener composition of claim 10 wherein said isocyanate starting material is a diisocyanate or triisocyanate.
- 12. The thickener composition of claim 11 wherein said polyether polyol of the polymerization reaction product is a polyalkylene oxide having a number average molecular weight between about 1000 and about 20,000.
- 13. The thickener composition of claim 12 wherein said difunctional hydrophilic endcapping material is selected from the group consisting of C4-C20 diols, diamines, dithiols, dicarboxylic acids, diepoxies, and mixtures thereof wherein said endcapping material has isocyanate-reactive groups positioned at the end of the chain, thereof.
- 14. The thickener composition of claim 13 wherein said difunctional hydrophilic endcapping material is selected from the group consisting of 1,6-hexanediol, 1,10-decanediol, 1,4-diaminobutane, 1,5-diaminopentane, 1,6diaminohexane, 1,7-diaminoheptane, 1,8-diaminooctane, 1,9diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, 4,4′-diaminodicyclohexylmethane, 1,4-butanedithiol, 1,5-pentanedithiol, 1,6-hexanedithiol, 1,7-heptanedithiol, 1,8-octanedithiol, 1,9-nonanedithiol, 1,10-decanedithiol, 1,4-butanedicarboxylic acid, 1,5-pentanedicarboxylic acid, 1,6-hexanedicarboxylic acid, 1,7-heptanedicarboxylic acid, 1,8-octanedicarboxylic acid, 1,9-nonanedicarboxylic acid, 1,10-decanedicarboxylic acid, 1,4-butanediol diglycidal ether, 1,5-pentanediol diglycidal ether, 1,6-hexanediol diglycidal ether, 1,7-heptanediol diglycidal ether, 1,8-octanediol diglycidal ether, 1,9-nonanediol diglycidal ether, 1,10-decanediol diglycidal ether, bisphenol A diepoxide, and mixtures thereof.
- 15. The thickener composition of claim 11 wherein said isocyanate starting material is selected from the group consisting of dicyclohexylnethane-4,4′-diisocyanate, isophorone diisocyanate, diphenylmethane-4,4′diisocyanate and isocyanurate trimer of hexamethylene diisocyanate.
- 16. The thickener composition of claim 14 wherein said polyether polyol of the polymerization reaction product is selected from the group consisting of alkylene oxide adducts of an aliphatic, cycloaliphatic or aromatic polyhydroxy compound, the hydroxyl-terminated prepolymers of alkylene oxide adducts and an organic polyisocyanate, or mixtures thereof, polyalkylolalkanes and polyhydroxyalkanes.
- 17. The thickener composition of claim 16 wherein said polyether polyol of the polymerization reaction product is selected from the group consisting of polyethylene oxides and polypropylene oxides having number average molecular weights of between about 4,000 and about 20,000.
- 18. The thickener composition of claim 17 wherein said polyether polyol of the polymerization reaction product is polyethylene glycol having a number average molecular weight of between about 4,000 and about 12,000.
- 19. A thickener composition comprising the reaction product of:(a) a polymerization reaction product of: (1) an isocyanate starting material, wherein said isocyanate starting material is a diisocyanate or triisocyanate; and (2) a polyether polyol, wherein said polyether polyol is a polyalkylene oxide having a number average molecular weight between about 1000 and about 20,000; (b) a linear difunctional hydrophilic endcapping material that is reactive with isocyanate groups, and wherein said linear difunctional hydrophilic endcapping material is present in a sufficient quantity so as to provide about at least twice the number of equivalents as are required to theoretically react all of the isocyanate-groups, and wherein said linear difunctional hydrophilic endcapping material is selected from the group consisting of 1,6-hexanediol, 1,10-decanediol, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane, 1,7-diaminoheptane, 1,8-diaminooctane, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, 4,4′-diaminodicyclohexylmethane, 1,4-butanedithiol, 1,5-pentanedithiol, 1,6-hexanedithiol, 1,7-heptanedithiol, 1,8-octanedithiol, 1,9-nonanedithiol, 1,10-decanedithiol, 1,4-butanedicarboxylic acid, 1,5-pentanedicarboxylic acid, 1,6-hexanedicarboxylic acid, 1,7-heptanedicarboxylic acid, 1,8-octanedicarboxylic acid, 1,9-nonanedicarboxylic acid, 1,10-decanedicarboxylic acid, 1,4-butanediol diglycidal ether, 1,5-pentanediol diglycidal ether, 1,6-hexanediol diglycidal ether, 1,7-heptanediol diglycidal ether, 1,8-octanediol diglycidal ether, 1 ,9-nonanediol diglycidal ether, 1,10-decanediol diglycidal ether, bisphenol A diepoxide, and mixtures thereof.
- 20. A thickener composition comprising a reaction product of:(a) a polymerization reaction product of: (1) an isocyanate starting material, wherein said isocyanate starting material is a diisocyanate or triisocyanate; and (2) a polyether polyol, wherein said polyether polyol is a polyalkylene oxide having a number average molecular weight between about 1000 and about 20,000; and (3) a diol; (b) a linear difunctional hydrophilic endcapping material that is reactive with isocyanate groups, and wherein said linear difunctional hydrophilic endcapping material is present in a sufficient quantity so as to provide about at least twice the number of equivalents as are required to theoretically react all of the isocyanate-groups, and wherein said linear difunctional hydrophilic endcapping material is selected from the group consisting of 1,6-hexanediol, 1,10-decanediol, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane, 1,7-diaminoheptane, 1,8-diaminooctane, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, 4,4′-diaminodicyclohexylmethane, 1,4-butanedithiol, 1,5-pentanedithiol, 1,6-hexanedithiol, 1,7-heptanedithiol, 1,8-octanedithiol, 1, 9-nonanedithiol, 1,10-decanedithiol, 1,4-butanedicarboxylic acid, 1,5-pentanedicarboxylic acid, 1,6-hexanedicarboxylic acid, 1,7-heptanedicarboxylic acid, 1,8-octanedicarboxylic acid, 1,9-nonanedicarboxylic acid, 1,10-decanedicarboxylic acid, 1,4-butanediol diglycidal ether, 1,5-pentanediol diglycidal ether, 1,6-hexanediol diglycidal ether, 1,7-heptanediol diglycidal ether, 1,8-octanediol diglycidal ether, 1,9-nonanediol diglycidal ether, 1,10-decanediol diglycidal ether, bisphenol A diepoxide, and mixtures thereof.
Parent Case Info
This application is a continuation-in-part of application Ser. No. 08/973723 filed May 12, 1998, now abandoned which is a 317 of PCT/US96/09514 Jun. 6, 1996.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3607822 |
Nishino |
Sep 1971 |
|
3923926 |
Harada et al. |
Dec 1975 |
|
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
08/973723 |
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US |
Child |
09/538192 |
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US |