Claims
- 1. Polyisocyanates comprising at least one of i) or ii)
i) nonionically hydrophilicizing groups based on polyalkylene oxide polyethers containing at least 30% by weight ethylene oxide units. ii) ionically or potentially ionically hydrophilicizing groups which on interaction with water enter into a pH-dependent dissociation equilibrium and are therefore neutral or positively or negatively charged depending on pH, and iii) at least one structural unit of the formula (1) 6in which X is an electron-withdrawing group, R1, R2 independently of one another are a hydrogen atom, a saturated or unsaturated aliphatic or cycloaliphatic radical or an optionally substituted aromatic or araliphatic radical and each contain up to 12 carbon atoms and n is an integer from 0 to 5.
- 2. The polyisocyanates according to claim 1, wherein the electron-withdrawing group X is an ester, sulphoxide, sulphone, nitro, phosphonate, nitrile, isonitrile or carbonyl group.
- 3. A process for preparing the polyisocyanates according to claim 1, comprising reacting
A) one or more organic polyisocyanates together with B) one or more organic compounds having at least one isocyanate-reactive group which have
b1) nonionically hydrophilicizing groups based on polyalkylene oxide polyethers containing at least 30% by weight ethylene oxide units, and/or b2) ionically or potentially ionically hydrophilicizing groups which on interaction with water enter into a pH-dependent dissociation equilibrium and are therefore neutral or positively or negatively charged depending on pH, C) one or more blocking agents comprising at least one CH-acidic cyclic ketone of the general formula (2), 7in which X is an electron-withdrawing group, R1, R2 independently of one another are a hydrogen atom, a saturated or unsaturated aliphatic or cycloaliphatic radical or an optionally substituted aromatic or araliphatic radical and each contain up to 12 carbon atoms and n is an integer from 0 to 5, and D) optionally one or more (cyclo)aliphatic monoamines and/or polyamines having 1 to 4 amino groups of the molecular weight range up to 400, and optionally one or more polyhydric alcohols having 1 to 4 hydroxyl groups of the molecular weight range up to 400, optionally also amino alcohols, in the presence of E) one or more catalysts, F) optionally, auxiliaries and additives and G) optionally, solvents.
- 4. A method for producing coating materials, coatings, sizes, adhesives and mouldings comprising adding the polyisocyanate of claim 1 to a composition comprising a film-forming resin.
- 5. Aqueous solutions or dispersions of polyisocyanates according to claim 1 or 2.
- 6. Coating compositions comprising
a) one or more polyisocyanates according to claim 1, b) one or more film-forming resins, c) optionally, catalysts, d) optionally, solvents and e) optionally, auxiliaries and additives.
- 7. Coatings obtained from coating compositions according to claim 6.
- 8. Substrates coated with coatings according to claim 7.
- 9. The process of claim 3, wherein the polyisocyanates in A) are selected from the group consisting of 1,4-diisocyanatobutane, 1,5-diisocyanatopentane, 1,6-diisocyanatohexane, 2-methyl-1,5-diisocyanatopentane, 1,5-diisocyanato-2,2-dimethylpentane, 2,2,4-trimethyl-1,6-diisocyanatohexane, 2,4,4-trimethyl-1,6-diisocyanatohexane, 1,10-diisocyanatodecane, 1,3-diisocyanatocyclohexane, 1,4-diisocyanatocyclohexane, 1,3-bis-(isocyanatomethyl)cyclohexane, 1,4-bis-(isocyanatomethyl)cyclohexane, isophorone diisocyanate, 4,4′-diisocyanato-dicyclohexylmethane, triisocyanatononane, ωω′-diisocyanato-1,3-dimethyl-cyclohexane, 1-isocyanato-1-methyl-3-isocyanatomethylcyclohexane, 1-isocyanato-1-methyl-4-isocyanatomethylcyclohexane, bis-(isocyanato-methyl)norbornane, 1,5-naphthalene diisocyanate, 1,3-bis-(2-isocyanatoprop-2-yl)benzene, 1,4-bis-(2-isocyanatoprop-2-yl)benzene, 2,4-diisocyanatotoluene, 2,6-diisocyanatotoluene, 2,4′-diisocyanatodiphenylmethane, 4,4′-diisocyanatodiphenylmethane, 1,5-diisocyanatonaphthalene, 1,3-bis(isocyanatomethyl)benzene and mixtures thereof.
- 10. The process of claim 3, wherein the CH-acidic cyclic ketone of the general formula (2) is selected from the group consisting of cyclopentanone-2-carboxy-methyl ester, cyclopentanone-2-carboxyethyl ester, cyclopentanone-2-carbonitrile, cyclohexanone-2-carboxymethyl ester, cyclohexanone-2-carboxyethyl ester, and or cyclopentanone-2-carbonylmethane.
- 11. The process of claim 3, wherein the catalysts are selected from the group consisting of sodium carbonate, trisodium phosphate, 1,4-diazabicyclo[2.2.2]octane, potassium carbonate, zinc 2-ethylhexanonate, and mixtures thereof.
- 12. The coating composition according to claim 6, wherein the film-forming resins b) are selected from the group consisting of epoxy functional polyester polymers, polyurethanes, acrylic polymers, vinyl polymers, polyurethane dispersions, polyacrylate dispersions, polyurethanepolyacrylate hybrid dispersions, polyvinyl ether dispersions, polyvinyl ester dispersions, polystyrene dispersions, polyacrylonitrile dispersions, and mixtures thereof.
Priority Claims (1)
Number |
Date |
Country |
Kind |
10260298.0 |
Dec 2002 |
DE |
|
CROSS REFERENCE TO RELATED PATENT APPLICATION
[0001] The present patent application claims the right of priority under 35 U.S.C. §119 (a)-(d) of German Patent Application No.102 602 98.0, filed Dec. 20, 2002.