Claims
- 1. A cosmetic composition for combatting the greasy and unaesthetic appearance of the hair and to improve the appearance of the skin comprising a solvent selected from the group consisting of water, lower alkanol and an aqueous solution of said lower alkanol, and 0.1 to 20% by weight of an active compound selected from the group consisting of:
- (1) a compound of the formula ##STR23## wherein R.sub.1 and R.sub.2 each independently are selected from the group consisting of methyl, ethyl, isopropyl, cyclohexyl, benzyl and .beta.-hydroxyethyl, and
- R is selected from the group consisting of
- (i) linear or branched alkyl having 1-18 carbon atoms,
- (ii) alkenyl having 3-18 carbon atoms,
- (iii) alkyl having 2-3 carbon atoms and substituted by 1-2 alcohol functions,
- (iv) --(CH.sub.2).sub.m --CH(OR.sub.3).sub.2 wherein R.sub.3 is alkyl having 1-4 carbon atoms and m is 1-2,
- (v) --(CH.sub.2).sub.n R.sub.4 wherein n is 0, 1 or 2 and R.sub.4 is phenyl,
- (vi) --(CH.sub.2).sub.q R'.sub.4 wherein q is 0 or 1 and R'.sub.4 is ##STR24## wherein p is 1, 2 or 3 in which instance R.sub.5 is selected from the group consisting of F, Cl, Br, alkoxy having 1-5 carbon atoms and alkyl having 1-4 carbon atoms or wherein p is 1 in which instance R.sub.5 is selected from the group consisting of amino and dimethylamino,
- (vii) --CH.sub.2 --CH.sub.2 --NH--Y wherein Y is selected from the group consisting of hydrogen and COR.sub.9 wherein R.sub.9 is selected from the group consisting of hydrogen, alkyl having 1-18 carbon atoms and ##STR25## wherein R.sub.11 is selected from the group consisting of H, F, Cl, Br and alkoxy having 1-4 carbon atoms, and
- (viii) --(CH.sub.2).sub.s --COOH wherein s is 1-10, and
- (2) a salt of the compound in (1).
- 2. The composition of claim 1 wherein said active compound is present in the form of a salt of an acid selected from the group consisting of hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid, malic acid, citric acid, 3-hydroxy butyric acid, lactic acid, gluconic acid, isethionic acid, salicyclic acid, glutamic acid, aspartic acid, camphocarbonic acid, camphosulfonic acid, tartaric acid and nicotinic acid.
- 3. The composition of claim 1 wherein said active compound is selected from the group consisting of:
- (1) (2-hydroxy-3-octadecylthio propyl) dimethylamine hydrochloride,
- (2) (3-hexadecylthio-2-hydroxy propyl) bis (.beta.-hydroxyethyl) amine hydrochloride,
- (3) [2-hydroxy-3-(octadecene-9-ylthio)propyl] dicyclohexylamine hydrochloride,
- (4) [3-(butene-2-ylthio)-2-hydroxy propyl] diethylamine hydrochloride,
- (5) [3-(2,3-dihydroxy propylthio)-2-hydroxy propyl] diethylamine hydrochloride,
- (6) [3-(2,2-dimethoxy ethylthio)-2-hydroxy propyl] dimethylamine hydrochloride,
- (7) (3-benzylthio-2-hydroxy propyl) diisopropyl amine hydrochloride,
- (8) (3-benzylthio-2-hydroxy propyl) bis (2-hydroxy ethyl) amine hydrochloride,
- (9) (3-benzylthio-2-hydroxy propyl) diethylamine hydrochloride,
- (10) (3-decylthio-2-hydroxy propyl) methyl benzylamine hydrochloride,
- (11) (3-p-chlorobenzylthio-2-hydroxy propyl) diethylamine hydrochloride,
- (12) (3-m-fluorobenzylthio-2-hydroxy propyl) dimethylamine hydrochloride,
- (13) (3-p-bromophenylthio-2-hydroxy propyl) diethylamine hydrochloride,
- (14) [3-(2,4-dichloro benzylthio)-2-hydroxy propyl] diethylamine,
- (15) (2-hydroxy-3-p-methoxybenzylthio propyl) diisopropylamine hydrobromide,
- (16) [3-(p-butoxy benzylthio)-2-hydroxy propyl] bis (2-hydroxy ethyl) amine,
- (17) [2-hydroxy-3-(o-methylbenzylthio) propyl] diethylamine,
- (18) (2-hydroxy-3-phenylthio propyl) dicyclohexylamine,
- (19) (2-hydroxy-3-phenylthio propyl) bis (2-hydroxy ethyl) amine hydrochloride,
- (20) (3-o-aminophenylthio-2-hydroxy propyl) diethylamine,
- (21) (2-hydroxy-3-.alpha.-phenetylthio propyl) diethylamine,
- (22) [2-hydroxy-3-(2-chlorobenzamido ethylthio) propyl] diethylamine,
- (23) 5-hydroxy bis-6-(hydroxyethylamino)-3-thia hexanoic acid,
- (24) 5-hydroxy-6-(N-methylbenzylamino)-3-thia hexanoic acid,
- (25) 6-dicyclohexylamino-5-hydroxy-3-thia hexanoic acid,
- (26) 6-diethylamino-5-hydroxy-3-thia hexanoic acid,
- (27) [2-hydroxy-3-(2-tetradecanamido ethylthio) propyl] diethylamine hydrochloride, and
- (28) [2-hydroxy-3-(2-hexadecanamido ethylthio) propyl] diethylamine hydrochloride.
- 4. The composition of claim 3 wherein said active compound is 6-diethylamino-5-hydroxy-3-thia hexanoic acid.
- 5. The composition of claim 1 wherein said active compound is present in an amount of 0.5-10 percent by weight of said composition.
- 6. The composition of claim 1 wherein said carrier is selected from the group consisting of a lower alkanol and an aqueous solution of a lower alkanol, and which also includes a cosmetic film forming resin.
- 7. The composition of claim 1 which also includes a detergent selected from the group consisting of an anionic, a cationic, a nonionic and an amphoteric detergent.
- 8. The composition of claim 1 which also includes at least one reducing agent for the disulfide bonds of keratin.
- 9. The composition of claim 1 which also includes an oxidizing agent for reforming the disulfide bonds of keratin.
- 10. The composition of claim 1 which also contains a thiol and an organic disulfide, the molar ratio of said disulfide to said thiol being greater than 1.
- 11. The composition of claim 1 which also includes a bactericide or fungicide.
- 12. A process for combatting the greasy and unaesthetic appearance of the hair and to improve the appearance of the skin comprising applying to the hair and to skin so characterized an effective amount of the composition of claim 1.
Priority Claims (1)
Number |
Date |
Country |
Kind |
66207 |
Sep 1972 |
LU |
|
Parent Case Info
This is a division, of application Ser. No. 401,380 filed Sept. 27, 1973, now U.S. Pat. No. 3,968,218.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3322635 |
Erkmann et al. |
May 1967 |
|
3671643 |
Kalopissis |
Jun 1972 |
|
3821405 |
Kalopissis et al. |
Jun 1974 |
|
Divisions (1)
|
Number |
Date |
Country |
Parent |
401380 |
Sep 1973 |
|