The present invention generally relates to vehicle lighting systems, and more particularly, to vehicle lighting systems employing photoluminescent and phospholuminescent structures.
Illumination arising from the use of photoluminescent structures offers a unique and attractive viewing experience. It is therefore desired to implement such structures in automotive vehicles for various lighting applications.
According to one aspect of the present invention, a vehicle is provided that includes a panel. The panel includes a substrate defining a first surface and a second surface disposed on opposite sides thereof, a phosphorescent structure positioned on the first surface of the substrate, and a photoluminescent structure positioned on the second surface of the substrate. A light-producing assembly is positioned to illuminate the second surface of the substrate.
According to another aspect of the present invention, a vehicle is provided that includes a vehicle interior panel. The vehicle interior panel includes a substrate defining an A-surface and a B-surface disposed on opposite sides thereof. A photoluminescent structure is positioned on the B-surface of the substrate. A light-producing assembly is positioned proximate the B-surface of the substrate. The light-producing assembly is configured to emit light toward the photoluminescent structure.
According to yet another aspect of the present invention, a vehicle is provided that includes an interior panel with a substrate. The substrate includes at least one substantially translucent portion and a light-producing assembly positioned outboard of the interior panel. The light-producing assembly is configured to emit light toward an outboard surface of the substrate.
These and other aspects, objects, and features of the present invention will be understood and appreciated by those skilled in the art upon studying the following specification, claims, and appended drawings.
In the drawings:
As required, detailed embodiments of the present invention are disclosed herein. However, it is to be understood that the disclosed embodiments are merely exemplary of the invention that may be embodied in various and alternative forms. The figures are not necessarily to a detailed design and some schematics may be exaggerated or minimized to show function overview. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the present invention.
As used herein, the term “and/or,” when used in a list of two or more items, means that any one of the listed items can be employed by itself, or any combination of two or more of the listed items can be employed. For example, if a composition is described as containing components A, B, and/or C, the composition can contain A alone; B alone; C alone; A and B in combination; A and C in combination; B and C in combination; or A, B, and C in combination.
Referring now to
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Referring now to the depicted embodiment of
The panel 14 is generally disposed between the light-producing assembly 38 and the interior 46 such that the panel 14 is disposed inboard on the vehicle 10 relative to the light-producing assembly 38. In the depicted embodiment, the light-producing assembly 38 may include a printed circuit board (PCB) 54 on which a light source 58 is disposed. The light-producing assembly 38 is positioned remotely from the panel 14, which may allow light from the light-producing assembly 38 to more evenly fall on the photoluminescent structure 34.
Referring to
The light source 58 may correspond to a thin-film or printed LED assembly and includes a base member 68 as its lowermost layer. The base member 68 may include a polycarbonate, poly-methyl methacrylate (PMMA), or polyethylene terephthalate (PET) material, or any other material known in the art, on the order of 0.005 to 0.060 inches thick and is arranged over the intended vehicle 10 surface on which the light source 58 is to be received (e.g., PCB 54, an exterior panel, or the panel 14). Alternatively, as a cost saving measure, the base member 68 may directly correspond to a preexisting vehicle structure (e.g., the PCB 54, an exterior panel, or the panel 14).
The light source 58 includes a positive electrode 70 arranged over the base member 68. The positive electrode 70 includes a conductive epoxy such as, but not limited to, a silver-containing or copper-containing epoxy. The positive electrode 70 is electrically connected to at least a portion of a plurality of LED sources 72 arranged within a semiconductor ink 74 and applied over the positive electrode 70. Likewise, a negative electrode 76 is also electrically connected to at least a portion of the LED sources 72. The negative electrode 76 is arranged over the semiconductor ink 74 and includes a transparent or translucent conductive material such as, but not limited to, indium tin oxide. Additionally, each of the positive and negative electrodes 70, 76 are electrically connected to a controller 78 and a power source 80 via a corresponding bus bar 82, 84 and conductive leads 86, 88. The bus bars 82, 84 may be printed along opposite edges of the positive and negative electrodes 70, 76 and the points of connection between the bus bars 82, 84 and the conductive leads 86, 88 may be at opposite corners of each bus bar 82, 84 to promote uniform current distribution along the bus bars 82, 84. It should be appreciated that in alternate embodiments, the orientation of components within the light sources 58 may be altered without departing from the concepts of the present disclosure. For example, the negative electrode 76 may be disposed below the semiconductor ink 74 and the positive electrode 70 may be arranged over the aforementioned semiconductor ink 74. Likewise, additional components, such as the bus bars 82, 84 may also be placed in any orientation such that the light source 58 may emit inputted light 100 (
The LED sources 72 may be dispersed in a random or controlled fashion within the semiconductor ink 74 and may be configured to emit focused or non-focused light toward the photoluminescent structure 34. The LED sources 72 may correspond to micro-LEDs of gallium nitride elements on the order of about 5 to about 400 microns in size (e.g., diameter or longest dimension) and the semiconductor ink 74 may include various binders and dielectric material including, but not limited to, one or more of gallium, indium, silicon carbide, phosphorous, and/or translucent polymeric binders.
The semiconductor ink 74 can be applied through various printing processes, including ink jet and silk screen processes to selected portion(s) of the positive electrode 70. More specifically, it is envisioned that the LED sources 72 are dispersed within the semiconductor ink 74, and shaped and sized such that a substantial quantity of the LED sources 72 align with the positive and negative electrodes 70, 76 during deposition of the semiconductor ink 74. The portion of the LED sources 72 that ultimately are electrically connected to the positive and negative electrodes 70, 76 may be illuminated by a combination of the bus bars 82, 84, controller 78, power source 80, and conductive leads 86, 88. According to one embodiment, the power source 80 may correspond to a vehicular power source 80 operating at 12 to 16 VDC. Additional information regarding the construction of light-producing assemblies is disclosed in U.S. Patent Publication No. 2014/0264396 A1 to Lowenthal et al., entitled “ULTRA-THIN PRINTED LED LAYER REMOVED FROM SUBSTRATE,” filed Mar. 12, 2014, the entire disclosure of which is incorporated herein by reference.
Referring still to
The energy conversion layer 90 includes at least one photoluminescent material 96 having energy converting elements with phosphorescent or fluorescent properties. For example, the photoluminescent material 96 may include organic or inorganic fluorescent dyes including rylenes, xanthenes, porphyrins, phthalocyanines, or a combination thereof. Additionally, or alternatively, the photoluminescent material 96 may include phosphors from the group of Ce-doped garnets such as YAG:Ce. The energy conversion layer 90 may be prepared by dispersing the photoluminescent material 96 in a polymer matrix to form a homogenous mixture using a variety of methods. Such methods may include preparing the energy conversion layer 90 from a formulation in a liquid carrier medium and coating the energy conversion layer 90 to the negative electrode 76 or other desired base member 68. The photoluminescent structure 34 may be applied to the substrate 18 by painting, screen printing, flexography, spraying, slot coating, dip coating, roller coating, bar coating, and/or any other methods known in the art. Alternatively, the energy conversion layer 90 may be prepared by methods that do not use a liquid carrier medium. For example, the energy conversion layer 90 may be rendered by dispersing the photoluminescent material 96 into a solid state solution (homogenous mixture in a dry state) that may be incorporated in a polymer matrix formed by extrusion, injection seal, compression seal, calendaring, thermoforming, etc.
To protect the photoluminescent material 96 contained within the energy conversion layer 90 from photolytic and thermal degradation, the photoluminescent structure 34 may include the stability layer 92. The stability layer 92 may be configured as a separate layer optically coupled and adhered to the energy conversion layer 90 or otherwise integrated therewith. The photoluminescent structure 34 may also include the protection layer 94 optically coupled and adhered to the stability layer 92 or other layer (e.g., the energy conversion layer 90 in the absence of the stability layer 92) to protect the photoluminescent structure 34 from physical and chemical damage arising from environmental exposure. The stability layer 92 and/or the protection layer 94 may be combined with the energy conversion layer 90 through sequential coating or printing of each layer, sequential lamination or embossing, or any other suitable means. Additional information regarding the construction of photoluminescent structures is disclosed in U.S. Pat. No. 8,232,533 to Kingsley et al., entitled “PHOTOLYTICALLY AND ENVIRONMENTALLY STABLE MULTILAYER STRUCTURE FOR HIGH EFFICIENCY ELECTROMAGNETIC ENERGY CONVERSION AND SUSTAINED SECONDARY EMISSION,” filed Nov. 8, 2011, the entire disclosure of which is incorporated herein by reference.
In operation, the photoluminescent material 96 is formulated to become excited upon receiving inputted light 100 (
Positioned on the A-surface 22 of the substrate 18 is the phosphorescent structure 30. The phosphorescent structure 30 may be a multi-layered structure, similar to that of the photoluminescent structure 34. In the depicted embodiment, the phosphorescent structure 30 may include a phosphorescent layer 120, a decorative layer 98, and a viewable portion 64. It will be understood that the phosphorescent structure 30 may only include the phosphorescent layer 120 without departing from the spirit of this disclosure. The phosphorescent layer 120 may be prepared by dispersing one or more phosphorescent materials 124 in a polymer matrix to form a homogenous mixture using a variety of methods. Such methods may include preparing the phosphorescent layer 120 from a formulation in a liquid carrier medium and coating the phosphorescent layer 120 to the substrate 18 or other desired surface. Alternatively, the phosphorescent layer 120 may be prepared by methods that do not use a liquid carrier medium. For example, the phosphorescent layer 120 may be rendered by dispersing the phosphorescent material 124 into a solid state solution (homogenous mixture in a dry state) that may be incorporated in a polymer matrix formed by extrusion, injection seal, compression seal, calendaring, thermoforming, etc. The phosphorescent structure 30 may be applied to the substrate 18 by painting, screen printing, flexography, spraying, slot coating, dip coating, roller coating, bar coating, and/or any other methods known in the art. The phosphorescent structure 30 may be formed in a similar manner to that of the photoluminescent structure 34 (e.g., ink jet and/or silk screen processes).
The phosphorescent structure 30 may include one or more phosphorescent materials 124 configured to emit light once charged by ambient lighting proximate the panel 14 (e.g., lights in the vehicle 10, the sun and/or other natural or artificial sources), the outputted light 102 and/or the inputted light 100. In various embodiments, the phosphorescent materials 124 may include one or more persistent phosphor(s). The persistent phosphorescent materials 124 may be defined as being operable to carry a charge and discharge light for a period after charging. For example, persistent phosphorescent materials 124, as described herein, may have an afterglow decay time ranging from several minutes to tens of hours. The decay time may be defined as the time between the end of the excitation or charging and the moment when the light intensity of the phosphorescent material 124 drops below a minimum visibility of 0.32 mcd/m2. A visibility of 0.32 mcd/m2 is roughly 100 times the sensitivity of the dark-adapted human eye, which corresponds to a definition used by persons of ordinary skill in the art.
The persistent phosphorescent material 124, according to one embodiment, may be operable to emit light at an intensity of 0.32 mcd/m2 after a period of 10 minutes. In an exemplary embodiment, the persistent phosphorescent material 124 may be operable to emit light at an intensity of 0.32 mcd/m2 after a period of 30 minutes and, in some embodiments, for a period longer than 60 minutes.
The persistent phosphorescent materials 124 may be operable to store energy received from an activation emission (e.g., ambient light, the inputted light 100 and/or outputted light 102) or a corresponding wavelength. The stored energy may then be emitted from the persistent phosphorescent material 124 as phosphorescent light 102a for a wide range of times, some extending up to approximately 24 hours. Such materials, when utilized with the panel 14, described herein, may make it possible for the phosphorescent structure 30 to continually illuminate through a plurality of excitation sources, including, but not limited to, ambient light, the light source 58 within the light-producing assembly 38, and/or the outputted light 102 from the photoluminescent structure 34. The periodic absorption of activation emission from the excitation sources may provide for a substantially sustained charge of the persistent phosphorescent materials 124 to provide for a consistent ambient illumination. For example, the light-producing assembly 38 may be pulsed, or otherwise periodically be activated to charge the phosphorescent structure 30 such that the phosphorescent structure 30 provides a constant or changing level of emitted phosphorescent light 102a.
The persistent phosphorescent materials 124 may correspond to alkaline earth aluminates and silicates, for example doped (di)silicates, or any other compound that is capable of emitting light for a period of time once an inputted light is no longer present. Such substances may incorporate persistent phosphorescent phosphors or other doped compounds. The persistent phosphorescent materials 124 may be doped with one or more ions, which may correspond to rare earth elements, for example: Eu2+, Tb3− and/or Dy3+. According to one non-limiting exemplary embodiment, the phosphorescent structure 30 includes phosphorescent material 124 in the range of about 30% to about 55%, a liquid carrier medium in the range of about 25% to about 55%, a polymeric resin in the range of about 15% to about 35%, a stabilizing additive in the range of about 0.25% to about 20%, and performance-enhancing additives in the range of about 0% to about 5%, each based on the weight of the formulation. The phosphorescent materials 124 may have an average particle diameter of between about 1μ and about 100μ, between about 5μ and about 50μ, or between about 10μ and about 30μ. The phosphorescent materials 124 may have an excitation wavelength of between about 10 nm and about 700 nm.
According to one embodiment, the phosphorescent structure 30 is a translucent white color when unilluminated. Once the phosphorescent structure 30 receives the activation emission of a necessary wavelength, the phosphorescent structure 30 may emit the phosphorescent light 102a as blue light therefrom. The light emitted from the phosphorescent structure 30 may be of a desired brightness such that any indicia within the viewable portion 64 is perceptible, but not so bright that an onlooker could not perceive a pattern of the indicia. According to one embodiment, the blue emitting phosphorescent material 124 may be Li2ZnGeO4 and may be prepared by a high temperature solid-state reaction method. The blue afterglow may last for a duration of five to eight hours which may originate from an activation emission and d-d transitions of Mn2− ions.
According to an alternate non-limiting exemplary embodiment, 100 parts of a commercial solvent-borne polyurethane, such as Mace resin 107-268, having 50% solids polyurethane in Toluene/Isopropanol, 125 parts of a blue green long persistent phosphor, such as Performance Indicator PI-BG20, and 12.5 parts of a dye solution containing 0.1% Lumogen Yellow F083 in dioxolane may be blended to yield a low rare earth mineral phosphorescent structure 30. It will be understood that the compositions provided herein are non-limiting examples. Thus, any phosphor known in the art may be utilized for utilization as a phosphorescent structure 30 without departing from the teachings provided herein. Moreover, it is contemplated that any long persistent phosphor known in the art may also be utilized without departing from the teachings provided herein.
Additional information regarding the production of long persistence luminescent materials is disclosed in U.S. Pat. No. 8,163,201 to Agrawal et al., entitled “HIGH-INTENSITY, PERSISTENT PHOTOLUMINESCENT FORMULATIONS AND OBJECTS, AND METHODS FOR CREATING THE SAME,” issued Apr. 24, 2012, the entire disclosure of which is incorporated herein by reference. For additional information regarding long persistent phosphorescent structures, refer to U.S. Pat. No. 6,953,536 to Yen et al., entitled “LONG PERSISTENT PHOSPHORS AND PERSISTENT ENERGY TRANSFER TECHNIQUE,” issued Oct. 11, 2005; U.S. Pat. No. 6,117,362 to Yen et al., entitled “LONG-PERSISTENCE BLUE PHOSPHORS,” issued Sep. 12, 2000; and U.S. Pat. No. 8,952,341 to Kingsley et al., entitled “LOW RARE EARTH MINERAL PHOTOLUMINESCENT COMPOSITIONS AND STRUCTURES FOR GENERATING LONG-PERSISTENT LUMINESCENCE,” issued Feb. 10, 2015, all of which are incorporated herein by reference in their entirety.
With continued reference to
In some embodiments, the decorative layer 98 may be disposed between the viewable portion 64 and the phosphorescent layer 120. The decorative layer 98 may include a polymeric material or other suitable material and is configured to control or modify an appearance of the viewable portion 64. For example, the decorative layer 98 may be configured to confer a leather appearance to the viewable portion 64 when the viewable portion 64 is in an unilluminated state. In other embodiments, the decorative layer 98 may be tinted any color to complement the vehicle structure on which the phosphorescent structure 30 is to be received. For example, the decorative layer 98 may be similar in color to that of the panel 14 so that the phosphorescent structure 30 is substantially hidden when in the unilluminated state. Alternatively, the decorative layer 98 may provide indicia 50 and/or an emblem such that the decorative layer 98 and the indicia 50 may be backlit and/or otherwise illuminated by the light-producing assembly 38. In any event, the decorative layer 98 should be at least partially light transmissible such that the photoluminescent structure 34 and phosphorescent structure 30 are not prevented from illuminating the viewable portion 64 whenever an energy conversion process is underway.
The overmold material 66 is disposed around the light sources 58, photoluminescent structure 34 and/or phosphorescent structure 30. The overmold material 66 may be formed integrally with the viewable portion 64 or any layer of the light sources 58, photoluminescent structure 34 and/or phosphorescent structure 30. The overmold material 66 may protect the light-producing assembly 38, phosphorescent structure 30, and photoluminescent structure 34 from a physical and chemical damage arising from environmental exposure. The overmold material 66 may have viscoelasticity (i.e., having both viscosity and elasticity), a low Young's modulus, and/or a high failure strain compared with other materials so that the overmold material 66 may protect the light-producing assembly 38, phosphorescent structure 30 and/or photoluminescent structure 34 when contact is made thereto. For example, the overmold material 66 may protect the phosphorescent structure 30 from the repetitive contact that may occur when occupants of the vehicle 10 contact the panel 14. It should be appreciated that the viewable portion 64 and the overmold material 66 may be two separate components, or may be integrally formed as a single component.
Referring to
Referring to
With respect to the presently illustrated embodiment, the excitation of photoluminescent materials 96, 108 is mutually exclusive. That is, photoluminescent materials 96, 108 are formulated to have non-overlapping absorption spectrums and Stoke shifts that yield different emission spectrums. Also, in formulating the photoluminescent materials 96, 108, care should be taken in choosing the associated Stoke shifts such that the converted outputted light 102 emitted from one of the photoluminescent materials 96, 108, does not excite the other, unless so desired. According to one exemplary embodiment, a first portion of the LED sources 72, exemplarily shown as LED sources 72a, is configured to emit an inputted light 100 having an emission wavelength that only excites photoluminescent material 96 and results in the inputted light 100 being converted into a visible light outputted 102 of a first color (e.g., white). Likewise, a second portion of the LED sources 72, exemplarily shown as LED sources 72b, is configured to emit an inputted light 100 having an emission wavelength that only excites second photoluminescent material 108 and results in the inputted light 100 being converted into a visible outputted light 102 of a second color (e.g., red). Preferably, the first and second colors are visually distinguishable from one another. In this manner, LED sources 72a and 72b may be selectively activated using the controller 78 to cause the photoluminescent structure 34 to luminesce in a variety of colors. For example, the controller 78 may activate only LED sources 72a to exclusively excite photoluminescent material 96, resulting in the viewable portion 64 illuminating in the first color. Alternatively, the controller 78 may activate only LED sources 72b to exclusively excite the second photoluminescent material 108, resulting in the viewable portion 64 illuminating in the second color. Similarly, by choice of the photoluminescent materials 96, 108, emission from one, both, or neither of the photoluminescent materials 96, 108 may result in activation of the phosphorescent structure 30.
Alternatively still, the controller 78 may activate LED sources 72a and 72b in concert, which causes both of the photoluminescent materials 96, 108 to become excited, resulting in the viewable portion 64 illuminating in a third color, which is a color mixture of the first and second color (e.g., pinkish). The intensities of the inputted light 100 emitted from each light source 72a, 72b may also be proportionally varied to one another such that additional colors may be obtained. For energy conversion layers 90 containing more than two distinct photoluminescent materials 96, 108, a greater diversity of colors may be achieved. Contemplated colors include red, green, blue, and combinations thereof, including white, all of which may be achieved by selecting the appropriate photoluminescent materials 96, 108 and correctly manipulating their corresponding LED sources 72. The controller 78 may be configured to take into account the color of the phosphorescent light 102a when activating the light source 72a, 72b such that proper color mixing or activation of the phosphorescent structure 30 may be accomplished.
Referring to
The photoluminescent structure 34 may be applied to only a portion of the panel 14, for example, in a stripped manner. Between the photoluminescent structures 34 may be light transmissive portions 112 that allow inputted light 100 emitted from the LED sources 72 to pass therethrough at the first wavelength. The light transmissive portions 112 may be an open space, or may be a transparent or translucent material. The inputted light 100 emitted through the light transmissive portions 112 may be directed from light-producing assembly 38 towards a second photoluminescent structure or the phosphorescent structure 30. The inputted light 100 may activate the phosphorescent structure 30, pass through the phosphorescent structure 30 or both.
Referring to
According to one exemplary embodiment, a first portion of the LED sources 72, exemplarily shown as LED sources 72c is configured to emit an inputted light 100 having a wavelength that excites the photoluminescent material 96 within the photoluminescent structure 34 and results in the inputted light 100 being converted into a visible outputted light 102 of a first color (e.g., white). Likewise, a second portion of the LED sources 72, exemplarily shown as LED sources 72d, is configured to emit an inputted light 100 having a wavelength that passes through the photoluminescent structure 34 and excites additional photoluminescent structures or the photoluminescent structure 34 thereby illuminating in a second color. The first and second colors may be visually distinguishable from one another. In this manner, LED sources 72c and 72d may be selectively activated using the controller 78 to cause the panel 14 to luminesce in a variety of colors.
The viewable portion 64 of the phosphorescent structure 30 may also include optics 116 that are configured to direct inputted light 100 emitted from the LED sources 72c, 72d, the outputted light 102 emitted from the photoluminescent structure 34 and/or phosphorescent structure 30 towards pre-defined locations. For example, the inputted light 100 emitted from the LED sources 72c, 72d, the outputted light 102 from the photoluminescent structure 34 and/or phosphorescent structure 30 may be directed and/or focused towards a desired feature and/or location proximate to the panel 14 (e.g., a handle).
Referring now to
Use of the panel 14 and the light-producing assembly 38, as described herein, may offer several advantages. For example, use of the panel 14 may allow for the ambient lighting of a large area of the interior 46 of the vehicle 10, or for the highlighting of specific features of the panel 14 (e.g., handle, buttons, arm rests, door locks, aesthetic features). Additionally or alternatively, the panel 14 may be applied as a strip within the interior 46 of the vehicle 10. Another advantage that may be realized is that the panel 14 may not need to be electrically connected to the power source 80 to provide illumination. By utilizing the long persistent phosphor structure 30, lighting may be achieved without a resulting drain on a battery of the vehicle 10. Additionally, by activating the photoluminescent structure 34 by the remotely placed light-producing assembly 38, the panel 14 itself may not have an electrical connection. Further, utilizing the light-producing assembly 38 and the photoluminescent structure 34, a smaller light-producing assembly 38 may be used to the smoothing, or evening effect of the photoluminescent structure 34.
It is to be understood that variations and modifications can be made on the aforementioned structure without departing from the concepts of the present invention, and further it is to be understood that such concepts are intended to be covered by the following claims unless these claims by their language expressly state otherwise.