The present invention relates to an image forming device for processing photosensitive media, wherein the photosensitive media includes a plurality of microcapsules that encapsulate imaging material such as coloring material. The present invention further relates to an exposure member of the image forming device.
Image forming devices are known in which media having a layer of microcapsules containing a chromogenic material and a photohardenable or photosoftenable composition, and a developer, which may be in the same or a separate layer from the microcapsules, is image-wise exposed. In these devices, the microcapsules are ruptured, and an image is produced by the differential reaction of the chromogenic material and the developer. More specifically, in these image-forming devices, after exposure and rupture of the microcapsules, the ruptured microcapsules release a color-forming agent, whereupon the developer material reacts with the color-forming agent to form an image. The image formed can be viewed through a transparent support or a protective overcoat against a reflective white support as is taught in, for example, U.S. Pat. No. 5,783,353 and U.S. Publication No. 2002/0045121 A1. Typically, the microcapsules will include three sets of microcapsules sensitive respectively to red, green and blue light and containing cyan, magenta and yellow color formers, respectively, as taught in U.S. Pat. No. 4,772,541. Preferably a direct digital transmission imaging technique is employed using a modulated LED print head to expose the microcapsules.
Conventional arrangements for developing the image formed by exposure in these image-forming devices include using spring-loaded balls, micro wheels, micro rollers or rolling pins, and heat from a heat source is applied after this development step to accelerate development.
The photohardenable composition in at least one and possibly all three sets of microcapsules can be sensitized by a photo-initiator such as a cationic dye-borate complex as described in, for example, U.S. Pat. Nos. 4,772,541; 4,772,530; 4,800,149; 4,842,980; 4,865,942; 5,057,393; 5,100,755 and 5,783,353.
The above describes micro-encapsulation technology that combines micro-encapsulation with photo polymerization into a photographic coating to produce a continuous tone, digital imaging member. With regard to the media used in this technology, a substrate is coated with millions of light sensitive microcapsules, which contain either cyan, magenta or yellow image forming dyes (in leuco form). The media further comprises a monomer and the appropriate cyan, magenta or yellow photo initiator that absorb red, green or blue light respectively. Exposure to light, after the induction period is reached, induces polymerization.
When exposure is made, the photo-initiator absorbs light and initiates a polymerization reaction, converting the internal fluid (monomer) into polymer, which binds or traps leuco dye from escaping when pressure is applied.
With no exposure, microcapsules remain soft and are easily broken, permitting all of the contained dye to be expelled into a developer containing binder and developed which produces the maximum color available. With increasing exposure, an analog or continuous tone response occurs until the microcapsules are completely hardened, to thereby prevent any dye from escaping when pressure is applied.
Conventionally, as describe above, in order to develop the image, pressure is uniformly applied across the image. As a final fixing step, heat is applied to accelerate color development and to extract all un-reacted liquid from the microcapsules. This heating step also serves to assist in the development of available leuco dye for improved image stability. Generally, pressure ruptured capsules (unhardened) expel lueco dye into the developer matrix.
Approximately 100 mega Pascal or 14,500 psi normal pressure was required for capsule crushing as documented in prior art. This need for precise application of high pressure (high compressive forces) presented a limitation to the extensibility of the conventional imaging system. Small compact low cost printers typically employed micro-wheels or balls backed by springs and operate in a scanning stylus fashion by transversing the media. This allowed for low cost and relatively low spring force due to the small surface area that the ball or micro wheel (typically 2 to 3 mm diameter) contacted on the media. The disadvantage of this method was that the processing pitch required to ensure uniform development needs to be (approximately 1 mm for a 3/16″ diameter ball) which results in slow processing times for a typical print image format (4×6 inch). Ganging multiple ball stylus or micro wheels adds cost, and increases the possibility of processing failure due to debris caught under a ball surface.
Conventional high speed processing involved line processing utilizing large crushing rollers. To ensure the high pressure, (psi) required, these rollers tended to be large to minimize deflection. However, these large rollers were costly, heavy, and require high spring loading. Again, the extensibility of this method is limited as larger rollers (and spring loads) are required as media size increases.
Furthermore, the photohardenable composition in at least one and possibly all three sets of microcapsules can be sensitized by a photo-initiator as noted above such as a cationic dye-borate complex as described in, for example, U.S. Pat. Nos. 4,772,541; 4,772,530; 4,800,149; 4,842,980; 4,865,942; 5,057,393; 5,100,755 and 5,783,353. Because the cationic dye-borate anion complexes absorb at wavelengths greater than 400 nm, they are colored and the unexposed dye complex present in the microcapsules in the non-image areas can cause undesired coloration in the background area of the final print or picture. That is, the print typically exhibits an obvious overall coloration caused by the residual photo-initiator. Typically, the mixture of microcapsules is greenish and can give the background areas a greenish tint. Although exposure to room light will serve to bleach out the photo-initiator over time, the print quality immediately after processing could appear to be of poor quality.
It is also noted that recent developments in media design (or the imaging member) as described in co-pending U.S. application Ser. No. 10/687,939 have changed the prior art structure of the imaging member to the point where the aforementioned means of processing may no longer be robust. The use of a substantially non-compressible top clear polymer film layer and a rigid opaque backing layer which serves to contain the image forming layer of conventional media presented a processing position whereby balls, micro wheels or rollers could be used without processing artifacts such as scratch, banding, or dimensional or surface deformation. In addition, the non-compressibility of this prior art structure provided more tolerance to processing conditions.
The recent imaging member embodiment as described in the above-mentioned co-pending patent application, replaces the top and bottom structures of the media with highly elastic and compressible materials (gel SOC) (super over coat or top most clear gel comprising layer) and synthetic paper (polyolefin). The media as described in the above-mentioned co-pending application no longer survive these means of processing in a robust fashion where pressure is applied by a roller or ball. This is due to the fact that in the imaging member described in the co-pending application, the polyolefin paper backing that is used as fiber base substrates (cellulose fiber) present non uniform density, and the high compression forces required for processing in the conventional arrangements may make an “image” of the fiber pattern in the print, thus making the print corrupt.
Further, conventional image forming devices may include exposure systems that enable a large area exposure of microencapsulated media by utilizing a monochromatic LCD (Liquid Crystal Diode) projection system. The conventional monochromatic LCD projection system comprises a three-color (RGB) filter wheel. Prior limitations of this technology were the size of the device (large lamp due to exposure energy requirements), the additional mechanical parts for the filter wheel assembly, and the poor throughput of images due to the need of rotating and imaging the file through three filters.
U.S. Pat. No. 5,512,967 describes an LCD projection system that does not use a three color filter wheel and its related mechanical components. Although a reasonable facsimile of the image file could be generated by exposure to the LCD projector as described in this patent, the print suffered image artifacts caused by the “read out” of the grid lines inherent to the LCD's. In application as a projector, this artifact “screen door effect” is not objectionable due to the intended projected image. However, a sampling of this effect imaged on a small format print (4×6 inches) is highly objectionable, and results in a poor quality image.
It would be advantageous to provide a means of large area exposure to allow for “page printing” while minimizing or eliminating artifacts. Page printing is defined as the ability to completely and simultaneously expose the print area surface. This ability would further be enabled if the intensity of the exposing source was sufficient to permit sub-second exposure times. Furthermore, joining this means of exposure to the processing means of commonly assigned co-pending U.S. application Ser. No. 10/722,248 filed Nov. 25, 2003, would allow for a high speed rapid access means of obtaining prints.
It would be further advantageous to provide a means or method of processing that did not invoke present methods utilizing high compression forces to provide a high quality image by improving the tonal scale development and density minimum formation of the imaging member. In addition, a processing means that would use plain paper as a substrate would be highly desired. Further, it would be advantageous to provide a means of processing that is low in cost, is fully extensible, is mechanically simple and robust, and can minimize undesired coloration in the developed image.
The present invention addresses the above noted drawbacks by providing for an image forming device having an exposure member that enables simultaneous exposure of an image through a 3-color LCD device.
In an embodiment of the image forming device of the present invention, a developing roller that includes a plurality of micro-members thereon can be utilized. The micro-members provide for a compliant surface, which can be non-uniform, is self-correcting for unintentional media thickness variations within a print area, and employs shear-like forces more so than compression forces or a combination thereof for development. The use of the micro-members restricts the processing development to the image-forming layer of the media, leaving both the top-most clear gel comprising layer intact and without scratches. Further, the roller of the present invention having the micro-members does not invade the bottom-most backing layer of the media and thus avoids pattern read out of low cost supports. The roller having micro members in accordance with the present invention essentially resembles a brush and thus can be referred to as a brush roller.
The embodiment of image-forming device of the present invention that includes the brush roller is fully extensible for all printer applications and is low cost. The composition of the micro members or brushes of the brush roller of the present invention can be varied; for example, where a polymer can be used since it provides a soft contact surface, elasticity, and resiliency, however, any natural or synthetic material meeting these criteria can be employed as the micro-members or brush.
The present invention therefore relates to an image forming device that comprises an exposure member adapted to expose a photosensitive medium to form a latent image on the photosensitive medium, with the exposure member comprising a light source, a first lens provided in a light path of light from the light source, a shutter provided in the path and a media locating member adapted to locate the photosensitive medium to be exposed at a focused position along the light path relative to the light source, and the photosensitive medium comprising a plurality of microcapsules which encapsulate imaging material; and a processing member adapted to develop the latent image by contacting the photosensitive medium with a force that is sufficient to release imaging material from selected microcapsules.
The present invention further relates to an image forming method that comprises the steps of (i) exposing a photosensitive medium comprising a plurality of microcapsules that encapsulate imaging material to form a latent image; with the exposing step comprising: a) placing the photosensitive medium in front of a light exposure source having a shutter that permits controlled exposure of the media; b) placing a first lens between the light exposure source and the photosensitive medium; and c) exposing the medium by providing light from the light source along a light path that passes through the lens; and (ii) developing the latent image by contacting a surface of the medium with a processing member that is adapted to apply a force to the surface of the medium which is sufficient to release imaging material from the microcapsules.
Referring now to the drawings, wherein like reference numerals represent identical or corresponding parts throughout the several views,
Once inside image forming device 15, photosensitive media travels along media path 19, and is transported by, for example, drive rollers 21 connected to, for example, a driving mechanism such as a motor. The photosensitive media will pass by an exposure or imaging member 25 in the form of an imaging head that could include a plurality of light emitting elements (LEDs) that are effective to expose a latent image on the photosensitive media based on image information. After the latent image is formed, the photosensitive media is conveyed past a processing assembly or a development member 27. Processing assembly 27 could be a pressure applicator or pressure assembly, wherein an image such as a color image is formed based on the image information by applying pressure to microcapsules having imaging material encapsulated therein to crush the microcapsules. The pressure could be applied by way of spring-loaded balls, micro wheels, micro rollers, rolling pins, etc.
Within the context of the present invention, the imaging material comprises a coloring material (which is used to form images) or material for black and white media. After the formation of the image, the photosensitive media is conveyed past heater 29 (
As shown in
Therefore, during use of the embodiment of
The photons from the LEDs of non-imaging member 100 cause the release of radicals which accordingly causes a reduction of the photoinitiators and thus serves to bleach out the photoinitiators. This therefore eliminates the undesired coloration described above while leaving the dye image intact. Further, since non-imaging member 100 is not utilized as an image-forming device, non-imaging member 100 does not require modulation or spot shaping. An advantage of the structure of
Further, the application of heat by heater 29 could occur prior to the photobleaching step as shown in
With regard to features of the projector of the exposure member of the present invention, it is known that digital projectors use a computer chip with hundreds of thousands of miniature mirrors that can be tilted under computer control. The tilting of the mirrors changes the amount of light reflected onto the image. These mirrors can typically be tilted faster than the pixels in an LCD display, but this design can produce some unexpected effects on motion video.
These projectors will either use three separate DLP (Digital Light Projectors or Processing) chips (one for each color) and a set of prisms and mirrors to combine the three sets of pixels, or just one DLP chip and a spinning color wheel with three color filters to create the same effect. In either case, the result is that each pixel is made up of only one square, since the three colors are mixed together. This produces a less pixilated image than found on an LCD projector, but the use of a spinning wheel may sometimes create a “rainbow” effect, the result of some shimmering in the image that some viewers might see as similar to a slow CRT refresh rate. (The faster the speed of the wheel, the less of a problem this will be.)
In the present invention, lens 6002 was designed and placed in the optical path 6020 of the projector 6000 to minimize the image, thus making it suitable for typical print formats, while removing the appearance of the screen door effect discussed above. This had the additional benefit of improving the light intensity (reverse inverse square law) and allowed for sub second exposures.
A commercially available projector such as (but not limited to) PROXIMA Model C 180 can be utilized in the present invention. Such a projector can include a 4:3 native aspect ratio; a contrast ratio of 400:1; three 0.79″ polysilicon TFT LCD active matrixs; a 170 Watt UHP lamp; a 2200 ANSI lumens. This arrangement provides for both improved color rendition and short print exposure times (< 3/10ths of a second simultaneous RGB exposure resulting in a 4×6 inch print) for visible light sensitive microencapsulated media having an approximate ASA speed of 0.003.
Each of light valves 6068a, 6068b and 6068c are known light valves; wherein each light valve 6068a, 6068b, 6068c comprises an incoming polarizer 9000, a first LCD compensation filter 9002a, a LCD 9004, a second LCD compensation filter 9002b and an outgoing polarizer 9006, such that each element is located in an in-line relationship with respect to the direction of movement of light. Light valve 6068a applies modulated green light to a combining cube 6072; light valve 6068b applies modulated red light to combining cube 6072; and light valve 6068c applies modulated blue light to cube 6072. Thereafter, the modulated light from each of the light valves are combined and applied to either lens 6002 or 6008 of sliding lens mechanism 6010a, depending on the position of lens mechanism 6010a. The lens mechanism can either be a turret as shown in
As previously discussed, conventional arrangements employ spring loaded micro-wheels or ball processing (point processing) to provide a pressure or crushing force to microcapsules of microencapsulated media. The traditional approach for crushing the microcapsules by way of a crushing force applied by balls, wheels or micro-rollers may provide for processing speeds which are in some instances not as fast as desired due to the fact that the development pitch of these arrangements are small, and processing velocity is limited to reasonable by-directional travel rates. Furthermore, in the traditional ball-crushing arrangements, debris introduced into the printer can cause the ball or microwheel to drag the debris over the media to cause a scratching of the image and, thus, render the print unusable.
In order to provide for a higher throughput device, large rollers, which have a width that covers the width of the media, can be utilized. However, these large rollers tend to have a non-compliant surface and will not compensate for imperfections or undulations in the media and, thus, results in poor processing. Further, if debris is carried by the large rollers, poor processing is also achieved.
Also, as discussed above, media substrates prone to deformation under the pressure load for development (typically 100 MpA) can jam in the device or irreversibly deform thus rendering the print unusable. In addition, debris entering the processing nip between rollers can cause damage to the roller rendering the processing means unusable.
In an embodiment of the present invention, an image-forming device 150 as shown in
For processing media, roller 152a is rotated or spins about a center axis 170 in direction 172, such that micro-members 160, for example, the hooks or loop-like members, contact media 1000 with a rotational or spinning force so as to apply a shear-like force and/or a compressional force onto the top surface of media 1000. With this arrangement, the rotational force applied by micro-members 160 is essentially converted to a compressive or pressure force onto media 1000, which is sufficient to rupture the microcapsules. More specifically, micro-members 160 can be in the form of, for example, plastic loop or hook-like members that are randomly or predeterminedly provided on the outer surface of roller 152a and have random or predetermined heights and locations. The loop or hook-like members 160 provide sufficient force to rupture the capsules. Further, a random positioning in height of hook or loop-like members 160 allow for uniform development of non-uniform media thickness as the plurality of hook or loop-like members 160 impinge on the media and become self-correcting to adapt to media thickness variations.
In a further aspect of the invention, each of the separate loop or hook-like members 160 essentially form a nip-like area with backing member 152b when media 1000 passes there-between. As noted above, micro-members 160 can be plastic. However, the present invention is not limited thereto. It is noted that micro-members 160 can be made of a fiber material or synthetic material. Further, rather than hooks and loops, the outer surface of roller 152a can be a coated cloth. Essentially, outer surface of roller 152a should preferably define a compliant surface that can be non-uniform.
In a feature of the present invention, spinning roller 152a with micro-members 160 thereon is sufficient to restrict the processing development to the image forming layer of media 1000, while leaving both the top most clear gel comprising layer intact and without scratches. Further, roller 152a with micro-members 160 thereon does not invade the bottom-most backing layer of media 1000 and thus, avoids pattern readout of low-cost media supports.
In the embodiment of
Further, although roller 152a is shown as spinning in a direction opposite to the direction of movement of media 1000, the present invention is not limited thereto. Roller 152a can also spin in the direction of movement of media 1000 or tangentially to the direction of movement of media 1000.
The embodiment of
In the previous embodiments, the size of rollers 152a, 152a′ basically matched the width of the media. In a further embodiment, the roller can be a small size roller 152c as shown in
Accordingly, the above embodiments provide for an improved imaging device wherein a processing roller or member in the form of, for example, a brush roller is rotated or spun and brought into contact with the top surface of micro-encapsulated media. The roller includes micromembers such as loop or hook-like member, which come into contact with the media and convert the rotational or spinning motion into a pressure that is sufficient to rupture the microcapsules. The brush roller of the present invention achieves a Dmax (maximum density), which is improved over the Dmax of, for example, a conventional ball-like pressure-type roller.
The arrangement of the present invention is advantageous for processing media such as disclosed in co-pending application U.S. Ser. No. 10/687,939, since the plastic or resilient loop or hook-like member provide a sufficient force to rupture the capsules, while the random position and height of the loop or hook-like members allow for uniform development of non-uniform media thickness. Further, the roller is self-correcting due to a compliant surface. With the arrangement of the present invention, there is no need for a high spring force or a large roller with high hardness.
The present invention also permits the use of a low cost base media since the processing is restricted to the microcapsules and any deformation or patterning caused by density differences in the support sheet and read out in the development of the media due to the resulting differential pressures is of no consequence. Further, the roller is self-cleaning since debris cannot damage the loop or hook-like members, and the roller effectively removes the debris from the print surface during processing.
As discussed above, in a further feature of the present invention, an exposure of the latent image prior to the processing of the image involves using exposure member 25′ and placing media 1000 in front of the projector 6000, where shutter 6004 placed between the projector 6000 and the media 1000 allows controlled times of exposure. The media 1000 is maintained at a specified “in focus” relationship to the projected image source from projector 6000 by distance through the use of locating member 6006 in the form of, for example, a vacuum easel.
The latent image on the media can be developed or processed by either crushing (nominal 10,000 psi large 4″ crushing wheel) or by brush processing depending if the media exposed was plastic substrate or paper substrate respectively.
The processed media for both cases, can be heat treated at 90 C for 10 seconds to ensure complete dye yield and finally photobleached at 88Klux for 5 seconds to ensure removal of any residual photinitiators.
With the arrangement of the present invention, an effective exposure of the media is realized. Further, placement of lens 6002 or 6008 as shown in
The exposure member 25′ as shown in
Media delivery could be in light tight “daylight load” containers or feed could be employed with a cutter at the downstream side of the process.
Furthermore, this device could be customized by optical component selection to provide large format (poster, display) images. Also, the exposure speed that can be realized by the present invention permits the imaging device to be used in an operator assisted minilab or wholesale lab retail environment, as well as in a stand-alone device such as a kiosk where short exposure times are beneficial.
In a further feature of the present invention, brush processing quality could be further enhanced by utilizing two brushes 160a and 160b as shown schematically in
The invention has been described in detail with particular reference to certain preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention.
Reference is made to commonly-assigned U.S. patent application Ser. No. 10/687,939 filed Oct. 17, 2003, entitled IMAGING ELEMENT HAVING PROTECTIVE OVERCOAT LAYERS to Hwei-Ling Yau et. al.; U.S. application Ser. No. 10/722,248 filed Nov. 25, 2003, entitled AN IMAGE FORMING DEVICE HAVING A BRUSH TYPE PROCESSOR to Alphonse D. Camp et. al.; and U.S. patent application Ser. No. 10/621,785 filed Jul. 17, 2003 entitled IMAGE FORMING DEVICE HAVING A PHOTOBLEACH SYSTEM to Alphonse D. Camp, et al.