The present invention relates to an impact energy absorbing member, more particularly an energy absorbing member provided inside a vehicle structural member such as a door, a door trim, a body side panel, a roof panel, a pillar, a bumper, a seat, and instrument panel of an vehicle or the like for absorbing the impact energy from the inside such as the collision of a passenger against the inner wall of the vehicle structural member or the impact energy from the outside such as the collision with another vehicle.
The official gazette of Japanese Patent Application Laid Open (JP-A) No. 2002-187508 discloses a hollow double wall structure for the absorption of impact energies to vehicles such as automobiles. This structure is produced by blow molding of thermoplastics, forming recessed ribs from the front surface wall and the rear surface wall with the top end parts thereof bonded with each other so as to be integrated for improving the energy absorbing property. Moreover, the official gazette of Japanese Patent No. 3,313,999 discloses an energy absorbing member made of a polypropylene resin having a 5,000 kg/cm2 to 25,000 kg/cm2 flexural modulus. Furthermore, the official gazette of Japanese Patent Application Laid Open (JP-A) No. 2002-201322 discloses one made of a polypropylene resin composition including a polypropylene component and a copolymer component of a propylene and an ethylene. According to the energy absorbing member disclosed in the above-mentioned official gazette of Japanese Patent, a sufficient shock absorbing property can be obtained by forming an interlocking rib for integrally linking a plurality of recessed ribs, or the like as shown in the official gazette of Japanese Patent Application Laid Open (JP-A) No. 2002-187508. However, it has been considered important that enhanced shock absorbing property particularly at low temperature is obtained. Regarding the energy absorbing member made of a polypropylene resin having a 5,000 kg/cm2 to 25,000 kg/cm2 flexural modulus, disclosed in the official gazette of Japanese Patent No. 3,313,999, it was afterwards discovered that the stress change at the time of energy absorption at 60° C. to −15° C. is large and the energy absorbing performance is effected by the outside air temperature. That is, with the load stress at a 50% compression distortion of a polypropylene energy absorbing member provided as the reference at an ordinary temperature, the stress change ratio is 21% in the case the outside air temperature is −15° C., and the stress change ratio is −34% in the case the outside air temperature is 60° C.
Since the stress change ratio of the energy absorbing member is required to be kept within ±10% at the temperature from −15° C. to 60° C., with respect to the compression distortion at ordinary temperature, the impact absorbing member formed of a polypropylene resin having a 5,000 kg/cm2 to 25,000 kg/cm2 flexural modulus disclosed in the official gazette of Japanese Patent No. 3,313,999 can not provide the required level of performance.
One embodiment of the present invention provides a system for absorbing energy from an impact, that system comprising: an energy absorbing member comprising first and second opposing walls; at least one rib disposed between the first and second opposing walls; energy absorbing member comprising a thermoplastic, the thermoplastic comprising a polyolefin based resin and 50-75% by weight of an amorphous resin.
Another embodiment of the present invention provides such a system wherein the thermoplastic has a flexural modulus of between about approximately 9,000 kg/cm2 and about approximately 22,000 kg/cm2.
A further embodiment of the present invention provides such a system wherein the thermoplastic has a 15 to 40 kg/cm2 Izod impact value at an ordinary temperature.
Still another embodiment of the present invention provides such a system wherein the polyolefin based resin is a polypropylene resin, and the amorphous resin is at least one resin selected from the group of resins consisting of polystyrene resin, impact resistant polystyrene resin, modified polyphenylene ether resin, and mixtures thereof.
A still further embodiment of the present invention provides a system for absorbing energy from impacts, that system comprising: a blow molded energy absorbing member comprising; first and second opposing walls; at least one fused pair of first and second ribs disposed between the first and second opposing walls; the first recessed rib being integrally molded from the first wall and having a first recessed rib end; the second recessed rib is integrally molded from the second wall and having a second recessed rib end; the first and second recessed ribs being integrally fused at a welded surface disposed between the first and second recessed rib ends; the energy absorbing member comprising a thermoplastic, that thermoplastic comprising a polyolefin based resin and 50-75% by weight of an amorphous resin, and having a 15 to 40 kg/cm2 Izod impact value at about approximately normal temperature.
Even another embodiment of the present invention provides such a system wherein the polyolefin based resin is a polypropylene resin, and the amorphous resin is at least one resin selected from the group consisting of polystyrene resin, impact resistant polystyrene resin, modified polyphenylene ether resin, and mixtures thereof.
An even further embodiment of the present invention provides a system for absorbing energy from an impact, that system comprising: an energy absorbing member comprising first and second opposing walls; the energy absorbing member comprising blow molded thermoplastic; at least one rib disposed between the first and second opposing walls; and the thermoplastic comprising a first resin, having a flexural modulus of not greater than about approximately 2,000 kg/cm2, and a polyolefin based resin.
Still another embodiment of the present invention provides such a system wherein the first resin has a flexural modulus not greater than 200 kg/cm2.
A still further embodiment of the present invention provides such a system wherein the first resin is at least one resin selected from the group of resins consisting of olefin based elastomers, styrene based elastomers, super low density polyethylene, straight chain-like low density polyethylene, low density polyethylene, straight chain-like super low density polyethylene and mixtures thereof.
Even still another embodiment of the present invention provides such a system wherein the polyolefin based resin is at least one resin selected from the group consisting of a polyethylene, a polypropylene and a mixture thereof.
An even still further embodiment of the present invention provides such a system wherein the first resin comprises an olefin based elastomer and the olefin based elastomer is at least one elastomer selected from the group consisting of ethylene-propylene copolymer rubber, ethylene-butene copolymer rubber, propylene-butene copolymer rubber, hydrogenation product of butadiene-styrene copolymer rubber, and mixtures thereof.
Yet another embodiment of the present invention provides such a system wherein the first resin is added to the polyolefin based resin in a proportion of about approximately between 3 to 20 parts by weight.
A yet further embodiment of the present invention provides such a system wherein the first resin to be added to the polyolefin based resin is a thermoplastics resin having a glass transition temperature not higher than about approximately −30° C.
A yet even further embodiment of the present invention provides a system for absorbing energy from an impact, that system comprising: a blow molded hollow energy absorbing member comprising; first and second opposing walls; at least one fused pair of first and second ribs disposed between the first and second opposing walls; the first recessed rib is integrally molded from the first wall and having a first recessed rib end; the second recessed rib is integrally molded from the second wall and having a second recessed rib end; the first and second recessed ribs being integrally fused at a welded surface disposed between the first and second recessed rib ends; the blow molded hollow impact absorbing member comprising a polypropylene resin and about approximately 3 to 20 parts by weight of an olefin based elastomer, the olefin based elastomer having a flexural modulus of not greater than 200 kg/cm2 and a glass transition temperature not higher than −30° C.
The features and advantages described herein are not all-inclusive and, in particular, many additional features and advantages will be apparent to one of ordinary skill in the art in view of the drawings, specification, and claims. Moreover, it should be noted that the language used in the specification has been principally selected for readability and instructional purposes, and not to limit the scope of the inventive subject matter.
In
The energy absorbing member is herein described, for the purposes of clarity, in the context of a vehicle. The term vehicle is intended in its broadest possible meaning, and includes but is not limited to automobiles, trucks, aircraft, boats, ships, tankers, carts, etc. One skilled in the art will readily appreciate that other, non-vehicular applications such as helmets, riot gear, and protective panels would also be within the scope of the present invention.
According to one embodiment, the energy absorbing member 1 may have a configuration with the ribs provided by denting the first wall 3 toward the second wall 4 direction with the top end part bonded with the second wall 4, or by denting the second wall 4 toward the first wall 3 direction with the top end part bonded with the first wall 3 as shown in
According to an alternative embodiment, the rib may be formed by impacting, impressing, or denting or otherwise molding the rib 5 into only one of the two walls 3, 4. This would produce a single rib rather than a pair of ribs.
An energy absorbing member 1 according to one embodiment of the present invention is made of thermoplastics produced by adding 35 to 75 wt % of an amorphous resin to a polyolefin based resin, having a 9,000 kg/cm2 to 22,000 kg/cm2 flexural modulus. As the polyolefin based resin, a polypropylene resin, a polyethylene resin, an ethylene-propylene copolymer resin, or the like can be used. In one embodiment a polypropylene resin is used. As the amorphous resin, at least one resin selected from the group consisting of a polystyrene resin, an impact resistant polystyrene resin, an acrylonitrile-butadiene-styrene resin, a polyphenylene ether resin, and a mixture thereof can be used. The thermoplastics for providing the energy absorbing member 1 have a 15 to 40 kg/cm2 Izod impact value at an ordinary temperature (about approximately 20° C.).
FIGS. 9 to 11 show the result of compressing the energy absorbing member 1 formed by blow molding and measuring displacement (change of the compression distortion) with respect to the compression loaded by a tensile tester. The curves (a1), (b1), (c1) shown in the graph of
In the graph of
The curves (a2), (b2), (c2) in the graph of
As shown in the graph of
Although the case of using the modified polyphenylene ether resin as the amorphous resin is explained in the embodiment, the same effect can be obtained by using other amorphous resins such as a polystyrene resin (PS), an impact resistant polystyrene resin (HIPS), or the like. However, in the case of an impact resistant polystyrene resin, or the like being added, the Izod impact value tends to be changed significantly according to the composition ratio. Therefore, the Izod impact value should be specified in addition to the resin mixing ratio. The Izod impact value for the energy absorbing member should be 15 to 40 kg/cm2. As in the case of adding the modified polyphenylene ether resin, the temperature dependency of the energy absorbing member is improved by adding another amorphous resin.
Table 1 shows the stress change ratio (%) and the Izod impact value (kg/cm2) in the case of adding a modified polyphenylene ether resin (modified PPE) to a polypropylene resin (PP) with the mixing ratio changed. The stress change ratio is calculated with the load stress at an ordinary temperature with a 50% compression distortion of the energy absorbing member provided as the reference. The 50% compression distortion denotes the state within the energy absorbing member is deformed to the half thickness from the initial thickness by being crushed under the compression load. The results of Comparative Examples 1, 2 and Examples 1 to 3 are as follows.
An energy absorbing member was formed of only a polypropylene resin without adding a modified polyphenylene ether resin. The stress change ratio with the ordinary temperature, 50% displacement provided as the reference was 21% at −15° C., and it was −34% at 60° C. That is, the compression load is made higher at a low temperature, and the compression load is made lower at a high temperature.
An energy absorbing member was formed of a thermoplastic resin produced by adding 20 wt % of a modified polyphenylene ether resin to a polypropylene resin. In this case, the same result as in the comparative example 1 was obtained.
An impact energy absorbing member was formed of a thermoplastic resin produced by adding 35 wt % of a modified polyphenylene ether resin to a polypropylene resin. In this case, the stress change ratio was improved in particular at 60° C. by the addition of the modified polyphenylene ether so that the energy absorbing property change with respect to the temperature change is reduced.
An energy absorbing member was formed of a thermoplastic resin produced by adding 50 wt % of a modified polyphenylene ether resin to a polypropylene resin.
An energy absorbing member was formed of a thermoplastic resin produced by adding 70 wt % of a modified polyphenylene ether resin to a polypropylene resin.
According to the Examples 2, 3, the energy absorbing property change was reduced to a considerable degree by the addition of the polyphenylene ether resin so that an energy absorbing member with a diminished temperature dependency was obtained.
An energy absorbing member 1, according to one embodiment of the present invention, is made of thermoplastics with a soft polymer having a 2,000 kg/cm2 or less, particularly preferably 200 kg/cm2 or less flexural modulus added to a polyolefin based resin. Thereby, the energy absorbing property can be provided having a diminished dependence on temperature fluctuations at low temperatures, in particular at −30° C. owing to the multiplier effect of the ribs provided in the energy absorbing member and the composition of a soft resin.
The energy absorbing member 1 formed by blow molding was compressed by a tensile tester, and displacement (change of the compression distortion) was measured with respect to the compression load. The result is shown in
By adding a soft resin, a preferable energy absorbing property can be provided even at low temperature as shown in the curve (b) in the graph in
As the resin having a 2,000 kg/cm2 or less flexural modulus should be added to a polyolefin based resin, it needs to have an excellent mixing property with respect to a polyolefin based resin as the base material resin. An olefin based elastomer, a styrene based elastomer, a low density polyethylene, and a straight chain-like low density polyethylene, a super low density polyethylene, and a straight chain-like super low density polyethylene are preferable. In particular, a desired energy absorbing property can be obtained by adding 3 to 20 parts by weight of an olefin based elastomer to a polyolefin based resin as the base material resin.
As an olefin based elastomer, an ethylene-propylene copolymer rubber, an ethylene-butene copolymer rubber, a propylene-butene copolymer rubber, a hydrogenation product of a butadiene-styrene copolymer rubber, or the like can be used. As a styrene based elastomer, a styrene-butadiene block copolymer, a styrene-butadiene-styrene block copolymer, a styrene-isoprene-block copolymer, a styrene-isoprene-styrene block copolymer, and a hydrogenation product thereof can be used. These elastomers have a good mixing property with respect to a polyolefin based resin.
The energy absorbing member 1 according to one embodiment of the invention is blow molded as shown in
The energy absorbing member 1 according to one embodiment of the invention is provided inside a vehicle structural member such as a door of, a door trim, a body side panel, a roof panel, a pillar, a bumper, a seat, and an instrument panel, or the like.
The thermoplastic comprising the present invention is, in one embodiment, a thermoplastic polymer alloy, wherein the typically immiscible thermoplastic components are blended using a micro-dispersion technique or block or grafting polymerization processes. In these latter processes, the copolymers are chemically bonded or grafted, thereby combining into a unified polymer, rather than two or more polymers coexisting and retaining their independent characters. In both the microdispersion process, a fundamentally mechanical combination, and in the block or grafting polymerization processes, which are fundamentally chemical in nature, an alloy of highly amalgamated and integrated components is produced. In this way, the alloy is more uniform in the dispersion of the elastomer within the resin than would be achieved with known blending techniques. To achieve even better alloying, a compatibility accelerator (for example epoxy compound, diene rubber) may be added to the thermoplastic/elastomer mixture. To this intimate mixture of components within the alloy is attributed the beneficial characteristics exhibited by this embodiment of the present invention.
The foregoing description of the embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of this disclosure. It is intended that the scope of the invention be limited not by this detailed description, but rather by the claims appended hereto.
Number | Date | Country | Kind |
---|---|---|---|
2002-319160 | Oct 2002 | JP | national |
2002-319161 | Oct 2002 | JP | national |
2002-319162 | Oct 2002 | JP | national |
2002-319163 | Oct 2002 | JP | national |
2003-025254 | Jan 2003 | JP | national |
2003-025255 | Jan 2003 | JP | national |
2003-025256 | Jan 2003 | JP | national |
2003-025257 | Jan 2003 | JP | national |
2003-025258 | Jan 2003 | JP | national |
2003-054856 | Feb 2003 | JP | national |
2003-054857 | Feb 2003 | JP | national |
2003-054858 | Feb 2003 | JP | national |
2003-097349 | Mar 2003 | JP | national |
2003-135249 | May 2003 | JP | national |
This application is a Continuation-in-part Application which claims benefit of co-pending U.S. application Ser. No. 10/698,537, filed Oct. 31, 2003, which in turn claims the priority to Japanese Application Number 2002-319160 filed on Oct. 31, 2002, Japanese Application Number 2002-319161 filed on Oct. 31, 2002, Japanese Application Number 2002-319162 filed on Oct. 31, 2002, Japanese Application Number 2002-319163 filed on Oct. 31, 2002, Japanese Application Number 2003-025254 filed on Jan. 31, 2003, Japanese Application Number 2003-025255 filed on Jan. 31, 2003, Japanese Application Number 2003-025256 filed on Jan. 31, 2003, Japanese Application Number 2003-025257 filed on Jan. 31, 2003, Japanese Application Number 2003-025258 filed on Jan. 31, 2003, Japanese Application Number 2003-054856 filed on Feb. 28, 2003, Japanese Application Number 2003-054857 filed on Feb. 28, 2003, Japanese Application Number 2003-054858 filed on Feb. 28, 2003, Japanese Application Number 2003-097349 filed on Mar. 31, 2003, and Japanese Application Number 2003-135249 filed on May 14, 2003.
Number | Date | Country | |
---|---|---|---|
Parent | 10698537 | Oct 2003 | US |
Child | 11130616 | May 2005 | US |