Claims
- 1. An impact-resistant and stress crack resistant molding material consisting essentially of
- A. a linear, thermoplastic, amorphous nylon consisting essentially of radicals derived from terephthalic acid, isophthalic acid and hexamethylene diamine, and having a relative viscosity of from 1.40 to 1.91, measured in a 1% strength solution in concentrated sulfuric acid at 23.degree. C., and
- B. from 5 to 60% by weight, based on A, of a copolymer of
- from 50 to 79.5% by weight of ethylene, from 20-38% by weight of a primary or secondary C.sub.2 -C.sub.8 -alkyl ester of acrylic acid and
- from 0.5 to 10% by weight of a monomer possessing an acidic functional group selected from the group consisting of acrylic acid, methacrylic acid, maleic anhydride, t-butyl acrylate and t-butyl methacrylate, the percentages of the copolymer components adding up to 100%.
- 2. The molding material of claim 1, wherein B is a copolymer of ethylene, n-butylacrylate and maleic anhydride or t-butylmethacrylate.
Priority Claims (1)
| Number |
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| 3436362 |
Oct 1984 |
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Parent Case Info
This application is a division of application Ser. No. 07/039,763, filed on Apr. 17, 1987, now U.S. Pat. No. 4,818,793 which in turn is a continuation of application Ser. No. 06/782,927, filed Oct. 2, 1985 now abandoned.
Moldings produced from nylon molding materials are sensitive to stress cracking, which is initiated by, for example., inorganic solutions and organic liquids, such as lower alcohols and zinc chloride solutions. Particularly susceptible in this respect are amorphous nylons. Thus, as disclosed in European Patent Application 70,001, attempts have been made to reduce the stress corrosion cracking of amorphous nylons based on isophthalic acid and terephthalic acid by adding partially crystalline nylons, such as nylon 6. However, this modifies the properties of the original nylon. Similarly, attempts have also been made to overcome stress corrosion cracking by means of ternary nylon blends, as described in German Laid-Open Application DOS 2,651,741. An attempt was also made to apply the same principle, i.e. the addition of partially crystalline nylons, to toughened nylons based on terephthalic acid and isophthalic acid (cf. European Patent Application 73,036). However, the results obtained in this case are unsatisfactory.
It is an object of the present invention to provide toughened nylons which are based on terephthalic acid and isophthalic acid, whose mechanical properties, such as impact resistance and flexural strength, have not been adversely affected, and which furthermore are less susceptible to stress cracking, in particular those which show no tendency to stress cracking.
We have found that this object is achieved by impact-resistant nylon molding materials containing
The novel nylon molding materials are impact-resistant and possess a wide variety of excellent mechanical properties. Moreover, they are less susceptible to stress cracking and in particular show no tendency in this respect.
Nylons according to the invention (component A) are linear thermoplastic nylons composed of radicals derived from terephthalic acid and isophthalic acid and alkanediamines of 4 to 10, preferably 6 to 10, carbon atoms. In preferred nylons, the ratio of terephthalic acid radicals to isophthalic acid radicals is from 20:80 to 80:20, in particular from 30:70 to 70:30. Preferred diamines are straight-chain diamines, in particular .alpha., .omega. -diamines. Hexamethylenediamine has become particularly important. Advantageously, the thermoplastic nylons have a relative viscosity of from 1.40 to 2.50, measured in 1% strength solution in concentrated sulfuric acid at 23.degree. C.
The novel copolymers B are used in an amount of from 5 to 60, in particular from 10 to 30, % by weight, based on the nylon A.
The novel copolymers 1 should be uncrosslinked, i.e. they are advantageously not less than 90% soluble in hot solvents, such as toluene, ethyl benzene or tetrachloroethylene. They consist of
The preferred copolymers 1 have a melting range (melting point) of from 40.degree. to 100.degree. C. and a glass transition temperature below -20.degree. C., in particular below -40.degree. C. The copolymers 1 are in general high molecular weight compounds and have a melt flow index MFI 190/2.16 (DIN 53,735) of from 4 to 20. The copolymers are prepared in a conventional manner by polymerization of the components at elevated temperatures under a high ethylene pressure.
Furthermore, copolymers 2 which can be used according to the invention are those consisting of from 70 to 98, in particular from 90 to 98, % by weight of a primary or secondary C.sub.2 -C.sub.8 -alkyl ester of acrylic acid or methacrylic acid, preferably n-butyl acrylate, from 1 to 30, in particular from 1 to 20, % by weight of a monomer possessing an acidic functional group or a latent acidic functional group, for example monomers containing acidic groups, such as methacrylic acid or acrylic acid, or a monomer which possesses blocked acidic groups and forms acidic groups under the compounding conditions or polymerization conditions, e.g. maleic anhydride or tert.-butyl meth(acrylate), and from 1 to 5, advantageously from 1 to 3, % by weight of a monomer containing 2 or more olefinic double bonds in the molecule, as a crosslinking agent. For example, bifunctional monomers, such as butanediol diacrylate or dicycl-opentadienyl acrylate, are suitable.
The copolymers 2 advantageously have a glass transition temperature tg of below -10.degree. C. Elastomeric polymers of this type are known per se and are prepared by emulsion polymerization of the abovementioned monomers. The technique of emulsion polymerization is described in detail in Houben-Weyl, Meth. d. org. Chemie, Volume XII, 1 (1961), pages 133-406.
Advantageously, the particle size of the copolymers B in the ready-prepared nylon molding materials is from 0.01 to 3 .mu.m, in particular from 0.03 to 1 .mu.m.
The novel nylon molding materials may additionally contain effective amounts of conventional additives C, examples of suitable additives being stabilizers and antioxidants, agents for inhibiting thermal decomposition and decomposition by ultraviolet light, lubricants, mold-release agents, colorants, such as dyes and pigments, and fibrous and pulverulent fillers and reinforcing agents. The stabilizers can be added to the materials at any stage of preparation. Preferably, they are added at an early stage in order to prevent decomposition beginning before the material can be protected. Such stabilizers should be compatible with the molding material.
Antioxidants and heat stabilizers which can be added to the thermoplastic materials according to the invention, include, for example, halides of metals of Group I of the Periodic Table, e.g. sodium, potassium and lithium halides, and copper(I) halides, e.g. iodides. Other suitable compounds are sterically hindered phenols or hydroquinones. As a rule, they are added in concentrations of not more than 1% by weight, based on the weight of the nylon.
The UV stabilizers used are those which are generally added to polymers, the amounts employed being not more than 2% by weight, based on the nylon. Examples of suitable UV stabilizers are various substituted resorcinols, salicylates, benzotriazoles and benzophenones.
Suitable lubricants and mold-release agents, which are added to the molding material in amounts of, for example, not more than 1% by weight, are stearic acid, stearyl alcohol and stearamides. Organic dyes, such as nigrosin, pigments, such as titanium dioxide or phthalocyanines, carbon black, fibrous and pulverulent fillers and reinforcing agents, such as carbon fibers, glass fibers, calcium silicate, aluminum silicate, magnesium carbonate, mica or feldspar, may also be added, for example in amounts of not more than 50% by weight, based on the molding material.
The molding materials according to the invention are usually compounded by mixing components A and B and, where releVant, C in conventional mixing apparatuses suitable for processing plastics, e.g. extruders, at above the melting point of the nylon A, copolymer B being finely dispersed at the same time. The novel molding materials are useful for the production of shaped articles by injection molding and extrusion.
The Examples which follow illustrate the invention.
US Referenced Citations (11)
Foreign Referenced Citations (1)
| Number |
Date |
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| 1019707 |
Feb 1966 |
GBX |
Divisions (1)
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Number |
Date |
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| Parent |
39763 |
Apr 1987 |
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Continuations (1)
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| Parent |
782927 |
Oct 1985 |
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Patent Grant
5003009
