Patent Application
20170245971
The present invention relates to a superstructure used for implants.
An implant includes a pure-titanium or titanium-alloy fixture planted in a jawbone and a superstructure coupled to the fixture. The superstructure includes a framework, an artificial tooth bonded to the framework, and a coupling member joined to a lower part of the inside of the framework to couple the framework to the fixture.
Conventionally, the framework is made of a gold alloy, a platinum alloy, pure titanium, a titanium alloy, zirconia, or the like in view of biocompatibility, workability, etc. The coupling member is made of an alloy of a noble metal such as gold or platinum, or a framework member is directly processed to serve as the coupling member, especially a gold alloy is preferred in view of corrosion resistance, hardness, and workability. The artificial tooth is made of porcelain, a hard resin, or the like, of which porcelain is preferred in view of wear resistance, cleanability, and self-cleaning properties.
An implant is provided inside the oral cavity of a patient as follows. First, the fixture is planted in the jawbone of the patient. Next, the framework and the coupling member are joined together, and then an artificial tooth is formed on the framework to form the superstructure. In the case where the artificial tooth is made of porcelain, a powder raw material is applied to the outer surface of the framework and fired at a high temperature to form the artificial tooth. Next, the coupling member of the superstructure is fastened with a screw to the fixture planted inside the oral cavity of the patient.
It has been proposed to use a cobalt-chromium alloy that is inexpensive and superior in rigidity to other materials such as a gold alloy, a platinum alloy, pure titanium, and a titanium alloy for the framework constituting a part of the superstructure.
However, a cobalt-chromium-alloy framework has a problem with the accuracy of the joint part due to an oxide film formed on the surface during firing of porcelain etc.
Another problem is the difficulty of joining together the cobalt-chromium-alloy framework and the gold-alloy coupling member.
If one attempts to join the two together by cast-joining, as the melting point of the cobalt-chromium alloy is close to the melting point of the gold alloy, the gold-alloy coupling member melts when the cobalt-chromium alloy is melted, which makes cast-joining itself difficult.
Joining the cobalt-chromium alloy and the gold-alloy coupling member by laser welding may result in lower accuracy of joint as the cobalt-chromium alloy is oxidized (corroded) during laser welding. As the characteristics laser welding that the welding area is small and only the surface layer is welded, the framework and the coupling member are poorly joined together and thus may be disjoined while in use inside the oral cavity. Moreover, air bubbles are generated at the joint part during laser welding which may cause the holes in the artificial tooth because air is released from the air bubbles while firing process of the powder raw material applied on to the framework to form the artificial tooth.
Joining together a cobalt-chromium alloy and a gold alloy by soldering is a possible solution to the above problems, but joining by soldering is not practiced at present.
Non Patent Literature 1: Isao Murata et al., “Bond Strength of Cobalt-Chromium Alloy for Metal Ceramics Joined with High-Fusing Gold Solder”, Journal of Japanese Society of Oral Implantology, Vol. 26, No. 3, Japanese Society of Oral Implantology, Oct. 18, 2013, pp. 425-432
The present inventors evaluated the soldering strength of cobalt-chromium alloys and evaluated the soldering strength of gold alloys too.(see Non Patent Literature 1), but failed to solder together a cobalt-chromium alloy and a gold alloy to evaluate the strength. Thus, we have yet to realize an abutment with a cobalt-chromium-alloy framework and a gold-alloy coupling member soldered together.
The present invention aims to provide a superstructure for which a cobalt-chromium alloy is used.
To achieve the above object, the present embodiment provides a superstructure coupled to a fixture that is made of pure titanium or a titanium alloy and planted in a jawbone, the superstructure including: a framework made of a cobalt-chromium alloy; an artificial tooth bonded to the framework; and a coupling member made of a gold alloy and joined to a lower part of the inside of the framework to couple the framework to the fixture, wherein the framework and the coupling member are integrated by being soldered together with a solder composed of a gold alloy containing gold and silver.
In the superstructure of the present embodiment, the cobalt-chromium-alloy framework and the gold-alloy coupling member are soldered together with the solder composed of a gold alloy containing gold and silver, and thus can be firmly joined together and integrated.
As the framework is made of a cobalt-chromium alloy, the superstructure of the present embodiment has excellent rigidity compared with conventional superstructures with the framework made of a material such as a gold alloy, a platinum alloy, pure titanium, or a titanium alloy. Thus, excellent rigidity can be secured even when the superstructure itself is reduced in diameter or height, which is a particularly beneficial for incisors for which thin artificial teeth are desired or molars for which short-height artificial teeth are desired.
The gold alloy composing the coupling member in the superstructure of the present embodiment has lower hardness than pure titanium or a titanium alloy composing the fixture. Accordingly, if an excessive force is accidentally exerted between the superstructure and the fixture while the superstructure is coupled to the fixture, the coupling member deforms but the fixture is prevented from deforming. Thus, the need for replacing the fixture is avoided and burden on patients can be reduced.
In the superstructure of the present embodiment, two or more lateral holes are bored in the framework. The lateral holes include a large-diameter hole with a larger opening diameter and a small-diameter hole with a smaller opening diameter.
The clearance between the framework and the coupling member is very narrow. Thus, a high level of skill is required to reliably introduce a solder into the clearance. If plurality of lateral holes is provided, one can introduce a solder through one lateral hole and recognize the solder overflowing through another lateral hole to thereby visually confirm that the clearance has been filled with the solder.
The plurality of lateral holes also allows one to introduce a solder through the plurality of lateral holes. It is preferable that the lateral holes include a large-diameter hole that is used mainly to introduce the solder, and a small-diameter hole with a smaller diameter. It is preferable that the small-diameter hole is provided on the side opposite from the large-diameter hole so that the solder filled through the large-diameter hole can be recognized. Reliable soldering allows the implant to maintain its strength.
In the superstructure of the present embodiment, a solder containing gold within a range of 80 to 85 mass % and silver within a range of 14 to 17 mass % can be used as the solder to reliably join together the cobalt-chromium-alloy framework and the gold-alloy coupling member.
In the superstructure of the present embodiment, it is preferable that the coupling member includes, at an end thereof on the side joined to the fixture in the axial direction of the coupling member, an engaging part that is formed so as to be engageable with the fixture and a flange that protrudes outward in the radial direction from the outer circumferential surface of the coupling member; that the framework includes a small-diameter cylindrical member that is provided on the side of the coupling member opposite from the side joined to the fixture, and a large-diameter cylindrical member that is provided on the side of the outer circumferential surface of the coupling member except for the flange and on the side of the outer circumferential surface of the small-diameter cylindrical member; and that the small-diameter cylindrical member and the large-diameter cylindrical member of the framework and the coupling member are integrated by being soldered together with the solder.
According to this configuration, the small-diameter cylindrical member and the large-diameter cylindrical member of the framework are joined together; the small-diameter cylindrical member is joined to the side of the coupling member opposite from the side joined to the fixture; and the large-diameter cylindrical member is joined to the outer circumferential surface of the coupling member except for the flange. Thus, the framework and the coupling member are joined together more firmly. Since the clearance between the small-diameter cylindrical member and the large-diameter cylindrical member and the clearance between the large-diameter cylindrical member and the coupling member communicate with each other, the solder can be spread throughout these clearances during soldering with the solder, so that the members can be reliably joined together.
It is preferable that the two or more lateral holes are bored in the large-diameter cylindrical member of the framework; that at least one lateral hole is bored at such a position as to allow the coupling member to be viewed before a solder is introduced; and that at least one lateral hole is bored at such a position as to allow the small-diameter cylindrical member to be viewed before a solder is introduced.
According to this configuration, the solder can be introduced into the clearances between the large-diameter cylindrical member of the framework and the coupling member and between the large-diameter cylindrical member and the small-diameter cylindrical member, and thus the solder can be spread reliably to the clearances.
Depending on the state inside the oral cavity of a patient, the superstructure may be coupled to the fixture with an abutment made of pure titanium or a titanium alloy interposed between the coupling member and the fixture. The superstructure of the present embodiment is also applicable to such cases.
Next, the present embodiments will be described in more detail with reference to the accompanying drawings.
Some superstructures used for implants are directly coupled to a fixture while others are coupled to a fixture through an abutment, and either type of structure can be selected appropriately according to the state inside the oral cavity of a patient. Superstructures of the present invention are applicable to both types of structures. First, referring to
A fixture-level implant (hereinafter simply an implant) 1 includes a fixture 2 planted in a jawbone (not shown) and a superstructure 3 coupled to the fixture 2.
The superstructure 3 includes a framework 5, an artificial tooth 4 bonded to the framework 5, and a coupling member 6 coupling the framework 5 to the fixture 2. The coupling member 6 is soldered with a solder 10 to the framework 5, and is fastened with an abutment screw (hereinafter simply a screw) 7 to the fixture 2.
The fixture 2 is made of pure titanium or a titanium alloy, and includes, at an end thereof on the side opposite from the side embedded in a jawbone in the axial direction, a hexagonal part 2a that is engaged with the coupling member 6 and acts as an anti-rotation mechanism and a threaded part 2b on which the screw 7 is fitted. The fixture 2 further includes a threaded part 2c in the outer circumferential surface on the side opposite from the side coupled to the coupling member 6, so that the fixture 2 can be screwed into a jawbone.
The artificial tooth 4 is made of porcelain in this embodiment, but may instead be made of a hard resin or the like.
The framework 5 is made of a cobalt-chromium alloy. For example, an alloy containing 60.2 mass % of cobalt, 25.0 mass % of chromium, 6.2 mass % of tungsten, 4.8 mass % of molybdenum, 2.9 mass % of gallium, less than 1 mass % of silicon, and less than 1 mass % of manganese (the product named Wirobond280 made by Bego, with the solid-phase point 1360° C. and the liquid-phase point 1400° C.) can be used as the cobalt-chromium alloy.
The framework 5 is composed of a small-diameter cylindrical member 8 and a large-diameter cylindrical member 9 joined with the solder to the outer circumferential surface of the small-diameter cylindrical member 8. The end of the framework 5 on the side opposite from the side joined to the coupling member 6 forms an annular slope that descends gradually from the outer circumferential side toward the inner circumferential side.
The coupling member 6 is a gold-alloy cylindrical body called a gold abutment. Hereinafter the coupling member 6 in this embodiment will be referred to as the gold abutment 6. For example, a gold alloy containing 60 mass % of gold, 20 mass % of palladium, 19 mass % of platinum, and 1 mass % of iridium (the product named GoldAdapt made by Nobel Biocare, with the solid-phase point 1400° C. and the liquid-phase point 1490° C.) can be used as the gold abutment 6.
A flange 6a protruding outward in the radial direction is provided at the end of the gold abutment 6 on the side coupled to the fixture 2 in the axial direction. A fitting part 6b on which the hexagonal part 2a of the fixture 2 is engaged and fitted is provided in the inner circumferential surface of the flange 6a. The side of the fitting part 6b opposite from the side coupled to the fixture 2 protrudes inward in the radial direction, and is provided with a locking portion 6c on which the gold abutment 6 is locked with the screw 7.
The small-diameter cylindrical member 8 is joined to the side of the gold abutment 6 opposite from the side coupled to the fixture 2. The small-diameter cylindrical member 8 is configured so that the inner circumferential surface thereof is flush with the inner circumferential surface of the gold abutment 6 when the small-diameter cylindrical member 8 is joined to the gold abutment 6.
The large-diameter cylindrical member 9 is joined with the solder to the outer circumferential side of the small-diameter cylindrical member 8 and to the outer circumferential side of the gold abutment 6 except for the flange 6a. The large-diameter cylindrical member 9 increases in diameter gradually in the axial direction from the side of the fixture 2 toward the opposite side, and is configured so that the outer circumferential surface thereof forms a smooth curved surface continuing to the outer circumferential surface of the flange 6a when the large-diameter cylindrical member 9 is joined to the gold abutment 6.
The large-diameter cylindrical member 9, the small-diameter cylindrical member 8, and the gold abutment 6 are joined together with the solder 10 composed of a gold alloy containing gold and silver. For example, a gold solder containing 80 mass % of gold, 17 mass % of silver, and 3 mass % of platinum (the product named S.G1080 made by Cendres+Métaux, with the solid-phase point 1060° C. and the liquid-phase point 1080° C.), or a gold solder containing 85 mass % of gold, 14 mass % of silver, and total 1 mass % of zinc, platinum, and iridium (the product named S.G1030 made by Cendres+Métaux, with the solid-phase point 990° C. and the liquid-phase point 1030° C.) can be used as the solder 10. The small-diameter cylindrical member 8 and the gold abutment 6 are joined together by laser welding.
The superstructure 3 is formed as follows. The fixture 2 is embedded into the jawbone of a patient, and the fixture 2 is integrated to the jawbone. Then, a mold (impression) is made of an area including the end face of the fixture 2 on the opposite side from the jawbone to produce a model.
Next, on the basis of the model produced, the cobalt-chromium alloy of the above composition (the product named Wirobond280) is cast and cut to form the large-diameter cylindrical member 9 and the small-diameter cylindrical member 8. To fill a flux described laterand a solder, the large-diameter cylindrical member 9 is provided with a lateral hole 9a that penetrates the circumferential wall in the thickness direction. The lateral hole 9a serves as an introduction hole through which the flux and the solder are introduced. To allow easy introduction of the flux and the solder, a cylindrical introduction chimney to be described later can be provided directly above the lateral hole. Instead of the casting and cutting, CAD/CAM processing may be performed to form the large-diameter cylindrical member 9 and the small-diameter cylindrical member 8.
The gold abutment 6 and the framework 5 are joined together with a gold solder and covered with an artificial tooth, as will be described below, and then coupled with the screw 7 to the fixture inside the oral cavity.
Next, the flux is poured through the lateral hole 9a so as to be filled in the clearance between the large-diameter cylindrical member 9 and the small-diameter cylindrical member 8 and the clearance between the large-diameter cylindrical member 9 and the gold abutment 6. For example, a mixture of the product named Fluxsol (made by Bego, containing less than 5 mass % of potassium hydrogen difluoride and less than 1 mass % of ethylene glycol) and the product named Minoxyd (made by Bego, containing less than 35 mass % of potassium hydroxide and less than 20 mass % of potassium fluoride) can be used as the flux.
Next, the above gold solder (the product named S.G.1080 or S.G1030) is heated to a temperature within the range of 1100 to 1130° C. and melted. Then, while the large-diameter cylindrical member 9, the small-diameter cylindrical member 8, and the gold abutment 6 are heated, the molten gold solder is poured through the lateral hole 9a. Thus, the fluidity of the flux filled in the clearances increases and the flux flows to the outside of the clearances, while the molten gold solder is filled into the clearances. Since the clearance between the large-diameter cylindrical member 9 and the small-diameter cylindrical member 8 and the clearance between the large-diameter cylindrical member 9 and the gold abutment 6 communicate with each other, the gold solder can be spread throughout these clearances. As a result, the large-diameter cylindrical member 9, the small-diameter cylindrical member 8, and the gold abutment 6 can be reliably joined together with the solder 10 that is the gold solder, and thus the framework 5 and the gold abutment 6 can be integrated. The lateral hole 9a of the large-diameter cylindrical member 9 is filled with the solder 10.
The gold solder can be introduced into the clearances more reliably, because the large-diameter cylindrical member 9 is provided with a plurality of lateral holes. The superstructure 3 itself is a very small structure and, as described above, the clearance among the large-diameter cylindrical member 9, the gold abutment 6, and the small-diameter cylindrical member 8 is as narrow as 10 to 50 μm. Thus, if there is only one lateral hole, reliably filling the gold solder is very difficult and requires skillfulness.
As shown in
It is preferable that the small-diameter hole that is a lateral hole with a smaller opening diameter is provided on the upper side (at the position of 9b in
In the case of an implant for a comparatively large tooth, such as a molar, it is preferable that an additional lateral hole with a smaller opening diameter as denoted by 9c in
The lateral holes shown in
Cylindrical introduction parts called chimneys (11a, 11b, 11c) that facilitate introduction of the gold solder can be provided on the outside of the respective lateral holes (9a, 9b, 9c ) to allow easy filling of the gold solder. The chimney may be provided for each lateral hole as shown in
Next, the integrated body of the framework 5 and the gold abutment 6 is cut and polished on the basis of the model so that the outer surface of the large-diameter cylindrical member 9 and the outer surface of the flange 6a of the gold abutment 6 form a smoothly continuous curved surface.
Next, in the case where porcelain is used for the artificial tooth 4, a paste containing a powder raw material and a solvent is applied to the outer surface of the framework 5 (except for an inner wall surface 8a of the small-diameter cylindrical member 8) into the shape of the artificial tooth 4. Then, the framework 5 is heated at a temperature of approximately 780 to 1000° C. to volatize the solvent and fire the powder raw material. Thus, the artificial tooth 4 that is bonded to the framework 5 and has a through-hole 4a serving as an access hole can be formed. For example, the products named Reflex Porcelain and Reflex Mixing Liquid (both made by Wieland) can be used as the powder raw material and the solvent, respectively. The through-hole 4a is filled by being packed with a hard resin etc. Thus, the superstructure 3 is formed.
The superstructure 3 of this embodiment has the framework 5 made of a cobalt-chromium alloy, and the cobalt-chromium alloy has a 0.2% proof stress of 720 MPa and a modulus of elasticity of 210 GPa. By contrast, pure titanium used for the frameworks of conventional superstructures has a 0.2% proof stress of 340 MPa, and the modulus of elasticity is 100 GPa in the case of a gold alloy and a platinum alloy.
Thus, the superstructure 3 of this embodiment has excellent rigidity and can secure the strength compared with conventional superstructures with the framework made of a gold alloy, a platinum alloy, pure titanium, or a titanium alloy.
The framework 5 and the gold abutment 6 of the superstructure 3 of this embodiment are firmly joined together with the solder 10, and thus are prevented from being disjoined from each other while the superstructure 3 is fixed to the fixture 2 with the fitting part 6b fitted on the hexagonal part 2a.
In the superstructure 3 of this embodiment, the gold alloy composing the gold abutment 6 coupled to the fixture 2 has lower hardness than pure titanium or the titanium alloy composing the fixture 2. Thus, if an excessive force is exerted between the superstructure 3 and the fixture 2 due to an improper joint position etc. while the superstructure 3 is coupled to the fixture 2, damage to the fixture 2 can be prevented as the fitting part 6b of the gold abutment 6 deforms (fail-safe mechanism). Thus, the need for replacing the fixture 2 embedded in the jawbone is avoided and burden on the patient can be reduced.
Since the framework 5 and the gold abutment 6 of the superstructure 3 are joined together by soldering, unlike when these are joined together by laser welding, air bubbles are rarely formed in the clearance between the framework 5 and the gold abutment 6. Accordingly, no air is released from the clearance while the powder raw material is fired, and the artificial tooth 4 can be prevented from being left with holes.
The artificial tooth 4 varies in shape according to the position inside the oral cavity at which the artificial tooth 4 is required. For example, the artificial tooth 4 is desired to be thin when used for an incisor, while the artificial tooth 4 is desired to be short in height when used for a molar.
As described above, the framework 5 has excellent rigidity, and that excellent rigidity can be secured even when the length orthogonal to the axial direction of the framework 5 is reduced (the diameter is reduced) or the length in the axial direction is reduced (the height is reduced). Thus, an artificial tooth 4 of a desired shape can be formed.
As the framework 5 of the superstructure 3 of this embodiment can be formed in a narrow shape, the superstructure 3 can have a shape that rises substantially vertically from the fixture 2. Thus, the periphery of the implant 1 is easy to clean, and periodontal disease etc. can be suppressed.
Next, referring to
An abutment-level implant (hereinafter simply an implant) 51 includes a fixture 52 planted in a jawbone B and a superstructure 53 coupled to the fixture 52.
The superstructure 53 includes a framework 54 made of a cobalt-chromium alloy and provided with a hole 54a at a center part, an artificial tooth 59 bonded to the framework 54, and a coupling member 55 (hereinafter a gold cylinder 55) made of a gold alloy and coupling the framework 54 to the fixture 52. The superstructure 53 is further provided with an abutment 56 that is made of pure titanium or titanium and interposed between the gold cylinder 55 and the fixture 52 to couple the gold cylinder 55 to the fixture 52.
The superstructure 53 is coupled to the fixture 52 as follows. First, the lower end of the abutment 56 is engaged with the upper end of the fixture 52, and the fixture 52 and the abutment 56 are coupled together with an abutment screw 57. Next, the lower end of the gold cylinder 55 with the framework 54 joined thereto is engaged with the upper end of the abutment 56, and the abutment 56 and the gold cylinder 55 are coupled together with a prosthetic screw 58. The gold cylinder 55 and the framework 54 are firmly joined together by soldering with a gold solder containing gold and silver (e.g., the product named S.G1080 or S.G1030).
The gold cylinder 55 and the framework 54 are joined together in the same way as with the above-described fixture-level implant. As shown in
As the framework 54 is made of a cobalt-chromium alloy, the superstructure 53 of this embodiment has excellent rigidity compared with conventional superstructures with the framework made of a material such as a gold alloy, a platinum alloy, pure titanium, or a titanium alloy.
The gold alloy composing the gold abutment 56 in the superstructure 53 of this embodiment has lower hardness than pure titanium or the titanium alloy composing the fixture 52 or the abutment 56. Thus, if an excessive force is accidentally exerted between the superstructure 53 and the fixture 52 while the superstructure 53 is coupled to the fixture 52, the gold cylinder 55 deforms but the fixture 52 and the abutment 56 can be prevented from damaging.
After an artificial tooth (not shown) is formed on the outside of the framework 63, the framework 63 and the gold cylinder 62 joined together with the gold solder is coupled with a prosthetic screw 67 to an abutment screw, which couples an abutment 68 to a fixture (not shown), and thus fixed inside the oral cavity.
As has been described above, implants include fixture-level implants and abutment-level implants, with various shapes within each type of implants, as one example is shown in
While the superstructures applied to implants that support one artificial tooth by one fixture have been described in the first embodiment and the second embodiment, the present invention is also applicable to implant bridges that support a plurality of artificial teeth in the entire upper jaw or lower jaw by a plurality of fixtures.
A superstructure 71 shown in
In the superstructure 71, five frameworks 54 of the second embodiment are joined together in the horizontal direction with pure titanium or a titanium alloy and extended at both ends so as to constitute the horseshoe-shaped framework 73 that covers the entire jawbone.
As the framework 54 is made of a cobalt-chromium alloy, the superstructure 71 of this embodiment has excellent rigidity compared with conventional superstructures with the framework made of a material such as a gold alloy, a platinum alloy, pure titanium, or a titanium alloy.
Next, an example and a comparative example regarding the strengths of the superstructures of the embodiments will be shown.
A cast body made of a cobalt-chromium alloy and measuring 2 mm in diameter and 20 mm in length was prepared as a first material to be soldered. The cobalt-chromium alloy used was Wirobond280 mentioned above.
A cast body made of a gold alloy and measuring 2 mm in diameter and 20 mm in length was prepared as a second material to be soldered. The gold alloy used was GoldAdapt mentioned above.
Next, the first and second materials to be soldered were each cut into 10 cm long pieces with a cutting disc (silicon-carbide, medium-fine “Ultra-thin Multi-Purpose Abrasive Discs” made by Keystone Industries, N.J. USA). Two pieces of the respective materials were butted together with a 30 μm clearance left therebetween and fixed at two points by spot welding with a laser welding machine (Mini-LASER XXS made by OROTIG S.r.l., Garda, Italy).
Next, the first and second materials to be soldered were subjected to soldering operation by a furnace soldering method, and were then taken out of the furnace and let cool in the atmosphere. Thus, a soldered specimen was produced.
The soldering operation was performed using a gold solder containing 80 mass % of gold, 17 mass % of silver, and 3 mass % of platinum (the product named S.G1080 made by Cendres+Métaux, with the solid-phase point 1060° C. and the liquid-phase point 1080° C.), at a soldering temperature of 1100 to 1130° C. and for a holding time of one minute under depressurized conditions.
With both ends clamped by a drill chuck, the soldered specimen produced was subjected to five times of tensile testing at a crosshead speed of 1.0 ram/min using a universal material testing machine (Autograph AG-I 20 kN made by Shimadzu Corporation). The soldering strength calculated from the maximum load at the time of fracture was 565.7 MPa (standard deviation: 36.0).
In this comparative example, cast bodies made of a gold alloy and measuring 2 mm in diameter and 20 mm in length were prepared as first and second materials to be soldered. The gold alloy contains 58 mass % of gold, 29 mass % of palladium, 8 mass % of silver, with the balance including iridium, tin, and ruthenium, and has a solid-phase point of 1215° C. and a liquid-phase point of 1305° C.
Next, the first and second materials to be soldered were fixed by spot welding with the laser welding machine in entirely the same way as in Example 1.
Next, the first and second materials to be soldered were subjected to the soldering operation in entirely the same way as in Example 1, and were then taken out of the furnace and let cool in the atmosphere. Thus, a soldered specimen was produced.
Next, the soldered specimen produced was subjected to tensile testing in entirely the same way as in Example 1. The soldering strength calculated was 460 MPa.
It is clear that the soldered specimen of Example 1 is superior in strength to the soldered specimen of Comparative example 1. From this result, it is clear that the superstructure of the embodiment of which the cobalt-chromium-alloy framework and the gold-alloy coupling member are joined together with the solder composed of a gold alloy containing gold and silver has excellent strength compared with superstructures of the related art of which the gold-alloy framework and coupling member are joined together with a solder composed of the gold alloy.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2014-201345 | Sep 2014 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2015/069636 | 7/8/2015 | WO | 00 |
