Claims
- 1. A process for activating a fluid bed catalyst by contacting a fluidized catalyst containing the mixed oxides of vanadium and phosphorus with oxygen and a reducing gas at least partially combustible with oxygen, the contacting conducted at an elevated temperature sufficient to cause combustion of the reducing gas, wherein the molar ratio of reducing gas to oxygen is greater than the stoichiometric ratio required for complete combustion of the reducing gas.
- 2. A process as in claim 1 wherein the ratio of reducing gas to oxygen is about 10:1 to about 1:3.
- 3. A process as in claim 1 wherein the ratio of reducing gas to oxygen is about 5:1 to about 1:2.
- 4. A process as in claim 1 wherein the catalyst is additionally contacted with an inert gas.
- 5. A process as in claim 1 wherein air is the source of oxygen.
- 6. A process as in claim 5 wherein the catalyst is contacted with an inert gas in addition to the inert gas contained in air.
- 7. A process as in claim 1 wherein the temperature is within a range of about 400.degree. C. to about 550.degree. C.
- 8. A process as in claim 1 wherein the reducing gas is selected from H.sub.2, H.sub.2 S, CO, hydrocarbons having from 1 to about 10 carbon atoms, and mixtures thereof.
- 9. A process as in claim 1 wherein said catalyst additionally contains a promoter element selected from at least one of an alkali metal, an alkaline earth metal, titanium, zirconium, hafnium, niobium, molybdenum, iron, cobalt, nickel, molybdenum, iron, cobalt, copper, zinc, cadmium, cerium, rare earths, uranium and mixtures thereof.
REFERENCES TO RELATED APPLICATIONS
This is a continuation application of application U.S. Ser. No. 550,276, filed Nov. 9, 1983, now abandoned, which was a continuation of application U.S. Ser. No. 334,693, filed Dec. 28, 1981, now abandoned.
US Referenced Citations (19)
Foreign Referenced Citations (1)
Number |
Date |
Country |
7314746 |
Oct 1973 |
NLX |
Non-Patent Literature Citations (1)
Entry |
Chem. Abst. 93 149763d, UPO Cat. for Oxide of Butane, Zozhigahov, vol. 93, 1980, p. 675. |
Continuations (2)
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Number |
Date |
Country |
Parent |
550276 |
Nov 1983 |
|
Parent |
334693 |
Dec 1981 |
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