Patent Grant
8580000
The present invention relates to an indirect heat-drying apparatus, including indirect-heating rotary dryers arranged in series therein that are used for drying in wide ranges from constant-rate drying range to decreasing-rate drying range, an indirect heat-drying method of drying a substance to be dried (hereinafter, may be referred to “substance for drying”) and a method of producing a solid fuel and a production system by using porous coal as a raw material.
Steam tube dryers, for example, are known as conventional indirect-heating rotary dryers. Such a steam tube dryer heats and dries a substance to be dried by a plurality of heating pipes installed in a revolving cylinder, into which a heating medium such as steam is introduced. These steam tube dryers are superior in drying potential because the heating area per capacity is large. They are also characteristic in high heat transfer rate and also superior in easiness of operation, and thus have been used for drying coal for coke furnace and chemical products.
The basic structure for these steam tube dryers is shown in
Traditionally known methods of producing a solid fuel from a raw porous coal include, for example, the method of producing a solid fuel described in Patent Document 2. The method will be described briefly with reference to
Generally in the final drying step of the method above, the modified porous coal separated in the solid-liquid separation step is dried as it is heated and conveyed in an indirect-heating rotary dryer and a carrier gas is fed thereto. The indirect-heating rotary dryer known is, for example, a so-called steam tube dryer. Specifically, as shown in
However, if a substance to be dried containing fine powder (porous coal in
When the carrier gas is fed in such a direction, the carrier gas flowing in the dryer is brought into contact with the substance for drying supplied into the dryer in the area of the dryer close to the substance inlet. Then, the carrier gas contains volatile matter sufficiently in the dryer, while the substance to be dried is relatively lower in temperature, because it is not heated sufficiently yet. Thus, the carrier gas is cooled by the substance to be dried, leading to adhesion of the volatile matter on the surface of the substance to be dried by condensation (dewing). As a result, the substance to be dried becomes more viscous, leading to adhesion of the substance to be dried in the area close to the substance inlet on the dryer internal surface, particularly on the heating pipes in the area close to the substance inlet.
Adhesion of the substance to be dried on heating pipes leads to decrease in heat energy transfer efficiency and drying efficiency. The decrease in drying efficiency results in decrease in production efficiency of the solid fuel.
Increase in the amount of adhesion on the heating pipes leads to decrease of the heat transfer coefficient of heating pipes; the heat transfer area should be increased for assurance of a particular capacity; and the dryer should be expanded in size and thus, becomes economically less attractive.
An object of the present invention is to provide an indirect heat-drying apparatus that is resistant to adhesion on heating pipes and gives a product having a desired and stabilized liquid content when a substance to be dried is dried in wide range from constant-rate drying range to decreasing-rate drying range, and a method of drying a substance to be dried.
Another object of the present invention is to provide an indirect heat-drying apparatus that can reduce the amount of scattered dust discharged from the dryer, thus allowing easier dust treatment, and a method of drying a substance to be dried.
Another object of the present invention is to provide a method of producing a solid fuel and a production system resistant to adhesion of porous coal on the dryer internal surface and improved in production efficiency of the solid fuel.
The present invention relates to an indirect heat-drying apparatus equipped with a indirect-heating rotary dryer,
wherein the indirect-heating rotary dryer comprising:
a revolving cylinder freely revolving about its axial direction;
a plurality of heating pipes arranged in the revolving cylinder in parallel with the revolving cylinder axis; and
a carrier gas treatment system supplying a carrier gas into the revolving cylinder from one side of the revolving cylinder and discharging the gas with evaporant out of the system from the other side,
a substance to be dried being supplied from a first side of the revolving cylinder and a dried substance being discharged out of a second side opposite thereto,
wherein the indirect-heating rotary dryer comprises a first indirect-heating rotary dryer and a second indirect-heating rotary dryer and the first and second rotary dryer are arranged in series so that a dried substance from the first indirect-heating rotary dryer is supplied to and dried in the second indirect-heating rotary dryer as a substance to be dried, and,
wherein a carrier gas-supplying means of supplying the carrier gas co-currently in the first indirect-heating rotary dryer and counter-currently in the second indirect-heating rotary dryer with respect to the flow direction from substance to be dried to dried substance is provided.
The present invention also relates to an indirect heat-drying apparatus above, further comprising:
a first bag filter for collecting dusts contained in the carrier gas discharged from the first indirect-heating rotary dryer;
a second bag filter for collecting dusts contained in the carrier gas from the second indirect-heating rotary dryer;
and a mixing means of mixing the collected dusts with the dried substance discharged from the first indirect-heating rotary dryer.
The present invention also relates to the indirect heat-drying apparatus above, further comprising carrier gas circulation systems circulating the carrier gas discharged from the first indirect-heating rotary dryer and the carrier gas discharged from the second indirect-heating rotary dryer respectively back to inlet sides, and a cooling means equipped at least in the second carrier gas circulation system to lower the dew point of the carrier gas sent back to the second indirect-heating rotary dryer.
The present invention also relates to an indirect heat-drying method of drying a substance to be dried, characterized in
using a plurality of indirect-heating rotary dryers comprising
a revolving cylinder freely revolving about its axial direction,
a plurality of heating pipes arranged in the revolving cylinder in parallel with the revolving cylinder axis, and
a carrier gas treatment system supplying a carrier gas into the revolving cylinder from one side of the revolving cylinder and discharging the gas with evaporant out of the system from the other side,
a substance to be dried being supplied from a first side of the revolving cylinder and a dried substance being discharged out of a second side opposite thereto, and
comprising
a first drying step of drying the substance to be dried as the carrier gas is supplied co-currently to a conveying direction of the substance to be dried in the first indirect-heating rotary dryer, and
a second drying step of drying the dried substance to be dried as the carrier gas is supplied counter-currently to a conveying direction of the substance to be dried in the second indirect-heating rotary dryer.
The present invention also relates to the above indirect heat-drying method of drying a substance to be dried, wherein a dew point of the carrier gas supplied to the second indirect-heating rotary dryer is lower than that of the carrier gas supplied to the first indirect-heating rotary dryer.
The present invention also relates to a method of producing a solid fuel, comprising;
a mixing step of obtaining a raw slurry by mixing a porous coal with a mixed oil containing a heavy oil fraction and a solvent oil fraction;
a vaporization step of obtaining a dehydrated slurry by heating the raw slurry for progress of dehydration of the porous coal and impregnation of the mixed oil into micropores of the porous coal;
a solid-liquid separation step of separating the modified porous coal and the mixed oil from the dehydrated slurry; and
a final drying step of drying the separated modified porous coal by supplying a carrier gas over it while heating and conveying it,
wherein the indirect heat-drying method of drying a substance to be dried, which is described above, is carried out in the final drying step.
The present invention also relates to an apparatus for producing a solid fuel, comprising;
a mixing means of obtaining a raw slurry by mixing a porous coal with a mixed oil containing a heavy oil fraction and a solvent oil fraction;
a vaporization means of obtaining a dehydrated slurry by heating the raw slurry for progress of dehydration of the porous coal and impregnation of the mixed oil into micropores of the porous coal;
a solid-liquid separation means of separating the modified porous coal and the mixed oil from the dehydrated slurry; and
a drying means of drying the separated modified porous coal by supplying a carrier gas over it while heating and conveying it,
wherein the drying means is an indirect heat-drying apparatus, which was described above.
In the indirect heat-drying apparatus, the indirect heat-drying method of drying a substance to be dried, the method of producing a solid fuel and the production system according to the present invention, a first indirect-heating rotary dryer and a second indirect-heating rotary dryer are arranged in series and the carrier gas is supplied co-currently in the first indirect-heating rotary dryer and counter-currently in the second indirect-heating rotary dryer with respect to the conveying direction of the substance to be dried. Such a combination provides many advantages.
Specifically, the substance to be dried at the outlet port of the first indirect-heating rotary dryer, which has a liquid content of close to the marginal liquid content, still contains liquid components and thus prevents generation of dust. Since a carrier gas not containing evaporant is supplied into the substance inlet side, i.e., the carrier gas inlet side, of the first indirect-heating rotary dryer, the dew point of the carrier gas is low, suppressing adhesion on heating pipes even when the liquid content of the substance to be dried is higher. The carrier gas contains evaporant and has a higher dew point on the carrier gas outlet side, i.e., the substance outlet side of the first indirect-heating rotary dryer, but the temperatures of the substance to be dried and the carrier gas are higher, and the temperature difference between the gas and the dew point is relatively large, thus preventing dewing.
In the second indirect-heating rotary dryer, the substance to be dried, supplied from the first indirect-heating rotary dryer, is heated to higher temperature and dried close to the marginal liquid content and thus, dewing or adhesion in the carrier gas outlet side, i.e., the substance inlet side, of the second indirect-heating rotary dryer is avoided even when the substance to be dried is supplied. Fine powder is carried as dust in the carrier gas when the substance to be dried is dried, but the powder is captured by the substance to be dried plowed on the carrier gas outlet side, i.e., the substance inlet side of the second indirect-heating rotary dryer, and thus, the amount of the dust discharged out of the system is reduced. In addition, because a carrier gas not containing evaporant is supplied into the substance outlet side, i.e., the carrier gas inlet side of the second indirect-heating rotary dryer, the carrier gas has a low dew point, which is advantageous for progress of decreasing-rate drying.
It is also possible according to the present invention, to collect dust at high dust-collecting efficiency and low liquid content of collected-dust, and to reduce the amount of the slurry to be processed, because bag filters can be used for recovery of scattered dust.
It is also possible according to the present invention, to reduce utility consumption and thus energy cost required for drying, by making each dryer have a separate carrier gas circulation system containing cooling means (such as condenser) and by making the dew point of the carrier gas supplied to the second indirect-heating rotary dryer lower than that of the carrier gas supplied to the first indirect-heating rotary dryer.
In particular, it is possible according to the method of producing a solid fuel and production system according to the present invention, to reduce adhesion of the porous coal on the dryer internal surface and thus, to raise drying efficiency and consequently improve production efficiency of solid fuel.
2: Mixing tank, 3: Heat exchanger, 4: Vaporizer, 5: Solid-liquid separation device, 6: Drying apparatus, 10: Modified porous coal (cake), 11: First indirect-heating rotary dryer (first dryer), 11a: First steam-tube dryer, 12: Second indirect-heating rotary dryer (second dryer), 12a: Second steam-tube dryer, 13: Gas cooler, 14: Gas heating device, 15: Dust-collecting device, 16: Heater, 41: Screw conveyor, 42: Supply cylinder, 43: Screw conveyor, 44: Discharge casing, 45: Conveyor, 46: Temporary reservoir, 47: First bag filter, 48: Second bag filter, 49: Screw conveyor, 51: Discharge casing, 52: Cooling tower, 53: Blower, 54: Circulation route, 55: Heating device, 56: Circulation route, 57: Second cooling tower, 58: Heating device, 310: Revolving cylinder, 311: Heating pipe, 321: Inlet port, 322: Outlet port, 331a: 331b: Support stand, 330a: 330b: Support roller, 312a: 312b: Tire, 350: Follower gear, 353: Drive gear, 351: Motor, 352: Speed reducer, 360: Revolving joint, 361: Heating medium inlet pipe, 101: Centrifugal separator, 102: Screw feeder, 103: Supply cylinder, 104: Screw feeder, 105: Revolving cylinder, 106: Discharge chute, 110: Screw feeder, 111: Wet scrubber, 112: Heating device, 113: Storage tank, 114: Condenser.
Indirect Heat-Drying Apparatus and Indirect Heat-Drying Method
Preferred embodiments of the indirect heat-drying apparatus and the indirect heat-drying method according to the present invention will be described in detail with reference to
The structure of the first and second dryers 11 and 12 is not particularly limited, if they have a revolving cylinder freely revolving around its axial direction, a plurality of heating pipes arranged in the revolving cylinder in parallel with the revolving cylinder axis, and a carrier gas treatment system supplying a carrier gas into the revolving cylinder from one side of the revolving cylinder and discharging the gas with evaporant out of the system from the other side, while a substance to be dried is fed into the revolving cylinder from the first side and discharged from the other second side. In the present invention, the carrier gas is supplied co-currently in the first dryer 11 and counter-currently in the second dryer 12, with respect to the flow direction from substance to be dried to dried substance (conveying direction of substance to be dried).
A specific example of the first and second dryers 11 and 12 is the steam tube dryer shown for example in
The size of the steam tube dryer is not particularly limited, but generally, the revolving cylinder 310 has a length of 5 to 30 m. In the revolving cylinder 310, a substance to be dried such as powder or granule is brought into contact with heating pipes 311 heated with a heating medium and conveyed sequentially to the outlet port 322 by revolution of the revolving cylinder 310 continuously. Thus, the revolving cylinder 310 is placed on a descending slope, so that the substance to be dried is conveyed smoothly from the substance to be dried inlet port 321 at one end to the dried substance outlet port 322. The revolving cylinder is mounted via tires 312a and 312b on support rollers 330a and 330b respectively formed on support stands 331a and 331b at two positions. The descending slope is adjusted by the height and the angle of the support stands 331a and 331b, and the support rollers 330a and 330b at two positions. For revolution of the revolving cylinder 310, a follower gear 350 is formed on the periphery of the revolving cylinder 310 and a drive gear 353 is connected thereto. The revolving force of a motor 351 is transmitted through a speed reducer 352, and the revolving cylinder revolves around the axis.
In the steam tube dryer, a plurality of heating pipes 311 are placed between both ends of the revolving cylinder 310 in parallel with the axis, and heated steam as a heating medium is supplied into these heating pipes 311 through a heating medium inlet pipe 361 attached in a revolution joint 360, fed through the heating pipes 311, and discharged from a heating medium outlet pipe 362.
On the other hand, the evaporant from the substance to be dried is discharged out of the revolving cylinder 310, as contained in the carrier gas G. In FIG. 2, the carrier gas G is supplied from the inlet port 341 on the dried substance-discharging side and discharged from the outlet port 342 on the substance-feeding side, and the direction of the carrier gas flow is counter-current with respect to the substance-conveying direction, and therefore, the steam tube dryer shown in
The constant-rate drying range (first drying step) will be described. In
The carrier gas is fed into the first dryer 11 from the substance inlet side, captures evaporant from the substance to be dried and additionally dust scattered into the carrier gas during drying of the substance to be dried in the first dryer 11, and is discharged out of the system from the substance outlet side of the first dryer 11 and sent to a first bag filter 47.
The dust separated in the first bag filter 47 is sent to a conveyor 45 and is finally fed to the second dryer 12 as the substance to be dried.
The dust-free carrier gas is sent to a cooling tower 52, where it is cooled. The cooled carrier gas is blown by a carrier gas-supplying means 53 along a circulation route 54 into the supply cylinder 42, as it is heated to a particular temperature in an intermediate heating device 55.
The decreasing-rate drying range (second drying step) will be described hereinafter. The half-dried substance is discharged from the temporary reservoir 46 and sent into a second dryer 12 by a supply screw conveyor 49. The dried substance dried in the second dryer 12, is discharged out of the system from a bottom of a discharge casing 51 via the discharge casing 51 for further treatment.
The carrier gas is blown counter-currently into the second dryer 12. The carrier gas is blown into the second dryer 12 from the dried substance outlet side and discharged from the substance inlet side. The carrier gas discharged from the substance inlet side is sent to a second bag filter 48.
The dust separated in the second bag filter 48 is sent to a screw conveyor 49 as the substance to be dried in the second dryer 12.
The dust-free carrier gas is fed into a common-use cooling tower 52, where it is cooled. The cooled carrier gas is sent to the second cooling tower 57, where it is cooled further, and to an intermediate heating device 58 where it is heated to a particular temperature, along the circulation route 56 by a common-use carrier gas-supplying means 53, and blown into the second dryer 12 from the dried substance outlet side through the discharge casing 51 region.
A part of the circulating liquids in the cooling tower 52 and the second cooling tower 57 are discharged out of the system as recovered solution. Nitrogen gas N2 is blown into the dryers 11 and 12 under pressure. The nitrogen gas N2 is supplied specifically, for example, into the first bag filter 47 and the second bag filter 48.
A reference mark S represents the steam fed into the heating pipe, and a reference mark C represents the condensate.
Preferably in the present embodiment, as shown in
In the present embodiment, as shown in
Method of Producing a Solid Fuel from a Porous Coal as Raw Material and Production System
Embodiments of the method of producing a solid fuel according to the present invention will be described in detail with reference to
In the present embodiment, a solid fuel is produced from a porous coal, fundamentally through:
a mixing step of obtaining a raw slurry by mixing a porous coal with a mixed oil containing a heavy oil fraction and a solvent oil fraction;
a vaporization step of obtaining a dehydrated slurry by heating the raw slurry for progress of dehydration of the porous coal and impregnation of the mixed oil into micropores of the porous coal;
a solid-liquid separation step of separating a modified porous coal and a mixed oil from the dehydrated slurry; and a final drying step of drying the separated modified porous coal by supplying a carrier gas over it while heating and conveying it.
In the present invention, the indirect heat-drying method of drying a substance to be dried is carried out in the final drying step, among the production steps above. A first drying step in which the carrier gas is supplied co-currently to the modified porous coal-conveying direction and a second drying step in which the carrier gas is supplied counter-currently to the modified porous coal-conveying direction are carried out sequentially.
Each step will be described in detail hereinafter. In the mixing step, a porous coal is mixed with a mixed oil containing a heavy oil fraction and a solvent oil fraction, to give a raw slurry (mixing step in
Porous coal contains a great amount of water, and is a so-called low-quality coal desired to be dehydrated and a coal containing water, for example, in an amount of 20 to 70 wt %. Examples of such porous coals include brown coals, lignite, subbituminous coals, and the like. Examples of the brown coals include Victoria coal, North Dakota coal, Beluga coal, and the like. Examples of the subbituminous coals include West Banco coal, Binungan coal, Samarangau coal, Ecocoal, and the like. The porous coals are not limited to those exemplified above, and any coal containing water in a great amount and thus desired to be dehydrated is also included and may be used as the porous coal according to the present invention. Such a porous coal is normally pulverized previously for use (pulverization step in
The heavy oil fraction is a heavy fraction, such as vacuum residue oil, that substantially has no vapor pressure, for example, even at 400° C. or an oil containing the same much. Thus, the porous coal itself is decomposed thermally if only a heavy oil fraction is used and heated to a fluidity allowing penetration of the oil into the micropores of the porous coal. As described above, because the heavy oil fraction for use in the present invention has almost no vapor pressure, it is more impossible to vaporize and distill it in carrier gas flow. If only a heavy oil fraction is used, it is difficult to obtain a preferable slurry because of high viscosity, and also to make it penetrate into the micropores because of almost no volatility. Thus, use of a solvent or a dispersant is needed.
Thus, in the present invention, the heavy oil fraction is dissolved in a solvent oil fraction for improvement in impregnation processability and slurry-forming efficiency, and then used. The solvent oil fraction for dispersing the heavy oil fraction is preferably a low-temperature-boiling oil fraction from the viewpoints of compatibility with the heavy oil fraction, handleability as slurry, easiness in penetration into micropores, and others, but, considering the stability at water vaporization temperature, use of a petroleum oil having a boiling point of 100° C. or higher, and preferably 300° C. or lower (for example, light oil or heavy oil) is recommended. Use of such a heavy oil fraction-containing mixed oil, which has suitable fluidity, permits accelerated penetration into micropores that is not possible only with a heavy oil fraction.
Such a heavy oil fraction-containing mixed oil may be (a) a mixed oil originally obtained as a mixed oil containing a heavy oil fraction and a solvent oil fraction, or (b) a mixed oil prepared by mixing a heavy oil fraction with a solvent oil fraction. Examples of the former oils (a) include petroleum heavy oil; petroleum light oil fractions, kerosene fraction, and lubricating oil components containing unpurified heavy oil; coal tar; light oils and kerosenes unintentionally containing impurities of heavy oil as they were used as a solvent or cleaner; heat transfer oils containing degradation products by repeated use; and the like. Examples of the latter oils (b) for use include petroleum asphalt, natural asphalt, coal-based heavy oils, petroleum or coal-based vaporization residues, or oils containing these in large amounts, mixtures thereof with petroleum light oil, kerosene, lubricating oil, or the like; mixtures of the former mixed oil (a) prepared by dilution thereof with petroleum light oil, kerosene or lubricating oil; and the like. Asphalts, which are inexpensive and characteristic in that they are not easily liberated when deposited on active sites, are used particularly preferably.
The content of the heavy oil fraction in the mixed oil is normally in the range of 0.25 to 15% by weight, with respect to the total amount of the mixed oil.
The mixing rate of the mixed oil to the porous coal is not particularly limited, and normally, the mixing ratio of the heavy oil fraction to the porous coal is preferably in the range of 0.5 to 30%, particularly 0.5 to 5% by weight, with respect to the anhydrous coal. Excessively low mixing ratio of the heavy oil fraction leads to insufficient absorption into micropores and thus to decrease in autoignition-reducing efficiency. Excessively high mixing ratio of the heavy oil fraction leads to decrease in economical advantage because of the oil cost.
The mixing conditions are not particularly limited, and mixing is normally carried out at 40 to 100° C. under atmospheric pressure.
The raw slurry obtained in the mixing step is normally preheated before the vaporization step (preheating process in
The preheating conditions are not particularly limited, and the raw slurry is normally heated almost to the water-boiling point under operational pressure.
In the vaporization step, a dehydrated slurry is obtained by heating the raw slurry for progress of dehydration of the porous coal and impregnation of the mixed oil into the micropores of the porous coal (vaporization step in
Heating is preferably carried out under a pressure, normally at 200 to 1500 kPa.
Because the series of steps is normally carried out by continuous operation, the heating time cannot be specified definitely, so far as dehydration of the porous coal and impregnation of the mixed oil into micropores are possible.
The steam generated by heating is removed in the vaporization step. The steam generated and removed in the step can be recovered and used as a heat source in the preheating and vaporization steps after pressurization.
In the solid-liquid separation step, a modified porous coal and a mixed oil are separated from the dehydrated slurry (solid-liquid separation step in
Various methods can be used as the separation method, and examples thereof include centrifugation, sedimentation, filtration, compression. and the like. These methods may be used in combination. The method for use is preferably centrifugation, from the viewpoint of separation efficiency.
The solid (modified porous coal) separated and recovered in the solid-liquid separation step normally contains the mixed oil and is still wet. Thus it needs to be dried (final drying step in
The drying method for use is preferably an indirect heat-drying method of drying a substance to be dried, including a first drying step in which the carrier gas is supplied co-currently to (in parallel with) the modified porous coal-conveying direction and a second drying step in which the carrier gas is supplied counter-currently to (in reverse parallel with) the modified porous coal-conveying direction are carried out sequentially.
For example as shown in
Flow of the carrier gas in such particular directions can reduce adhesion of the porous coal on the dryer internal surface. Although the mechanism is not understood in detail, it is seemingly based on the following mechanism: When a sufficiently wet material is dried, it is dried in a preheating range, a constant-rate drying range, and a decreasing-rate drying range. In the constant-rate drying range, the material temperature is almost constant and the heat applied to the material is all used for vaporization of oil. In the decreasing-rate drying range, the material temperature rises, forming a temperature distribution in the material. In the present invention, the modified porous coal cake and the carrier gas move co-currently in the first drying step and the cake is always exposed to a less oil-containing carrier gas in the inlet side of the first dryer X1. Thus in the first drying step, the cake surface is kept dry; the drying progresses to the final point of constant-rate drying range before the cake is conveyed to the outlet side Y1; and the oil present on the porous-coal surface portion in a relative large amount is separated by vaporization. In the second drying step, the cake and the carrier gas move counter-currently, but the cake from which most oil is previously removed by vaporization flows into the inlet side X2. Thus, also in the second drying step, the cake surface is kept dry; the drying progresses to the final point of decreasing-rate drying range before the cake advances to the outlet side Y2; and the residual oil in the porous coal diffuses and exudes onto the surface and removed by vaporization. As described above, the two-stage drying seems to be effective in preventing deposition of the porous coal on the dryer internal surface, because condensation of the vaporized oil is prevented effectively, and the cake surface is kept dry, while the oil contained in the porous coal is removed by vaporization in the final drying step. The second drying step is a drying step in the decreasing-rate drying range, only demanding a particular residence time, wherein steam consumption by oil vaporization is small and most of the steam heat is used for thermal preservation in the second drying step. Thus, only tubes needed for thermal preservation and agitation are desirably installed in the second dryer, and the apparatus in the second drying step can be simplified and the steam consumption is reduced.
The entire configuration of the first dryer 11 and the second dryer 12 may be an indirect connection type in which the two dryers are connected to each other via a connecting unit, as shown in
The first and second dryers are indirect-heating rotary dryers similar to those described above and may be any dryer, if the drying article is conveyed continuously and heated simultaneously. For example, a steam tube dryer having a plurality of steam tubes for heating installed in the axial direction on the inner surface of a drum may be used. The heating medium is not limited to steam and may be any known heating medium that can be heated to about 200° C., such as oil, alkylbenzene, or alkylnaphthalene.
The first and second dryers are preferably tubular dryers, and particularly preferably steam tube dryers. As described above, the oil present in a relatively large amount on the porous coal surface portion is vaporized, which is a process rate-limited by energy supply, and thus, relatively large heat energy is needed to be supplied even in a short period of time in the first drying step. In the second drying step, the residual oil in the porous coal diffuses and exudes onto the surface and vaporizes, which is a process rate-limited by time, and the heat energy should be supplied over a relatively long period. Thus, the heat energy supplied in the second drying step may be made smaller than that supplied in the first drying step, which is preferable, from the viewpoint of drying efficiency. In the case of the tubular dryer, it is possible, in such setting, to control the quantity of the heat energy easily, only by modifying the number of the tubes.
Specific examples of the steam tube dryer for the first dryer and the steam tube dryer for the second dryer are shown in
The carrier gas supplied through the first dryer 11 and the carrier gas supplied through the second dryer 12 may be regenerated and recycled together or separately. These carrier gases contain vaporized oil, and therefore are normally mixed together and recovered after condensation of the vaporized oil by cooling. Such a carrier gas contains porous coal fine powder (dust coal) and the fine powder coal may be captured and removed. As a result, the vaporized oil is recovered, and the carrier gas, from which dust coal is removed as needed, is circulated and reused.
For example as shown in
In the drying apparatus 6 shown in
The dried modified porous coal is cooled and molded as needed, to give a solid fuel (cooling step and molding step in
An example of the apparatus for production of a solid fuel according to the present invention is shown in
For example as shown in
a mixing tank 2 for obtaining a raw slurry by mixing a porous coal with a mixed oil containing a heavy oil fraction and a solvent oil fraction;
a vaporizer 4 for obtaining a dehydrated slurry by enhancing dehydration of the porous coal by heating the raw slurry and impregnation of the mixed oil into the micropores of the porous coal;
a solid-liquid separation device 5 for separating a modified porous coal and a mixed oil from the dehydrated slurry; and
a drying apparatus 6 for drying the separated modified porous coal by supplying a carrier gas (CG) over it while heating and conveying it, wherein
the drying apparatus 6 is an indirect heat-drying apparatus, specifically containing
a first dryer 11 in which the carrier gas (CG1) is supplied co-currently to the modified porous coal-conveying direction and a second dryer 12 in which the carrier gas (CG2) is supplied counter-currently to the modified porous coal-conveying direction, in the order from the upstream in the coal-conveying direction (D10) of the modified porous coal 10.
As shown in
The steam vaporized in the vaporizer 4 is compressed and used as the heat source for the preheater 3 and then exhausted.
Described is an example of the drying step of obtaining a product from a wet cake of a mineral containing high-boiling point hydrocarbons as liquid components by drying and recovering the hydrocarbons, and the amount of the product is about 30 Ton/h.
The liquid content of the raw wet cake is 20 to 30 wt % by weight WB, and the wet cake is supplied into a dryer at 100 to 150° C. The liquid content required for the product is 1.5 to 0.5 wt % by weight WB. The critical liquid content is 10 to 2 wt % by weight WB, and drying both in constant-rate drying range and decreasing-rate drying range is needed in the present drying step. A circulation system in which N2 gas is used as the carrier gas is employed for recovery of the vaporized liquid components. The boiling points of the liquid fraction are 150 to 250° C., and it is needed to keep the cake at a temperature of 210° C. or higher under low-dew point atmosphere in the decreasing-rate drying range for obtaining a liquid content preferable for the product.
Comparative Example 1 (conventional Example) is an apparatus wherein drying in constant rate drying range and decreasing-rate drying range is carried out in one steam tube dryer, having a circulation system in which the carrier gas is supplied counter-currently.
Example 1 (an example of the present invention shown in
The two drying steps are compared in Table 1.
The results in Table 1 show that use of two dryers in series (Example 1) is advantageous in that deposition amount on the inlet port of the dryer is smaller and a product having a stabilized liquid content is obtained. It is also advantageous in that the dust scattered with the exhaust gas can be recovered as a product and no slurry is generated. The heat transfer coefficient can be raised because the adhesion amount is smaller, and the heat transfer area of the dryer can be reduced. It is possible to reduce the carrier-gas flow rate and the amount of the vapor needed for heating the carrier gas. In addition, the liquid content of the dried substance is stabilized.
More specifically, if the drying step is carried out by using one dryer in the counter-current flow mode of the carrier gas, as in the conventional example (Comparative Example 1), the exhaust gas contains the evaporant and thus has a high dew point. The exhaust gas is brought into contact with the substance to be dried in the low-temperature wet state, resulting in drop of the gas temperature and decrease in temperature difference between the gas temperature and the dew point. Although the gas temperature is adjusted to about 140° C. with respect to the dew point of about 125° C. by adjusting the flow rate of the carrier gas, in the conventional example, the temperature difference may become only about 1 to 2° C. or lower, prohibiting installation of bag filter because of dewing.
When two dryers are installed in series and the carrier gas flow mode is co-current in the former stage and counter-current in the latter stage according to the present invention (Example 1), the exhaust gas from the dryer in the former stage has a high dew point, but the substance to be dried with which the exhaust gas becomes in contact in the gas outlet region is higher in temperature, and thus, the gas temperature does not drop. The exhaust gas from the dryer in the latter stage contains only the evaporant generated in the decreasing-rate drying range and thus can be set to a low dew point easily. In addition, the temperature of the substance to be dried in contact with the gas is also high, and the gas temperature remains high. In the present Example, the temperature difference between the substance to be dried and the exhaust gas is about 70 to 100° C., and thus, bag filters can be installed without dewing for treatment of the exhaust gases from both dryers in the former and latter stages.
On the other hand, the dew point of the carrier gas should be lowered, for reducing the liquid content to a particular point in a particular residence time by drying in decreasing-rate drying range. When the drying step is carried out in one dryer, as in the conventional example, the dew point of the entire carrier gas should be lowered and then, reheated before circulation into the dryer, which results in large loss of energy. According to the present invention, only the dew point of the carrier gas supplied into the dryer in latter stage which is used for drying in decreasing-rate drying range is dropped. In Example 1, a carrier gas having a dew point of about 45° C. is needed for drying in decreasing-rate drying range, but the gas heated to about 45° C. may be only the carrier gas supplied to the dryer in the latter stage, and the dew point of the carrier gas supplied to the dryer in the former stage is kept about 80° C. It is thus possible to reduce the amount of the steam needed for heating the carrier gas by about 20%.
The present invention will be described more in detail with reference to the following Examples. The term “part” below is to be understood to mean “part by weight”.
An apparatus similar to that shown in
Pulverization Step
Samarangau coal (maximum particle size: 3000 μm, average particle size: about 150 μm)
Mixing Step
A newly prepared mixed oil [kerosene: 1 kg/hour and asphalt: 1 kg/hour] was supplied to Samarangau coal (180 kg/hour) and a circulation oil (248 kg/hour), to give a raw slurry (70° C., 100 kPa).
Vaporization Step
Supply rate of the raw slurry into vaporizer: 430 kg/hour
137° C., 400 kPa
Solid-Liquid Separation Step
130° C., 100 kPa
Final Drying Step
The first dryer: steam-tube dryer (number of tubes: 12, length in axial direction: 5000 mm, heating temperature (carrier gas (CG1) temperature): about 210° C., modified porous coal residence time: 60 minutes.
The second dryer: steam-tube dryer (number of tubes: 6 (+6 tubes not supplying steam), length in axial direction: 5000 mm, heating temperature (carrier gas (CG2) temperature): about 210° C., modified porous coal residence time: 60 minutes
In Example 2, a modified porous coal was obtained immediately after the final drying step at a rate of 100 kg/hour.
Drying operation was carried out continuously in a manner similar to Example 2, except that the following drying apparatus was used.
Drying Apparatus;
Used was a drying apparatus similar to that shown in
In Comparative Example 2, sufficient drying was not possible under a condition similar to that in Example 2, because the modified porous coal deposited in the area around the porous coal inlet of the first dryer, particularly on the heating tubes. Thus, sufficient drying was carried out, as the conveying speed of the porous coal in the first and second dryers was reduced for assurance of drying period, to give a modified porous coal at a rate of 60 kg/hour, immediately after the final drying step.
The amount of the steam consumed with respect to the weight of the modified porous coal in Comparative Example 2 was increased by about 10%, compared to that in Example 2.
The indirect heat-drying apparatus and the indirect heat-drying method of drying a substance to be dried according to the present invention are useful in drying various powders or grains, such as those of porous coal and biomass.
The method and the apparatus of producing a solid fuel according to the present invention are useful in production of a solid fuel from a raw material of porous coal (coal), particularly of low-quality coal.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2007-269278 | Oct 2007 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2008/064907 | 8/21/2008 | WO | 00 | 8/16/2010 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2009/050939 | 4/23/2009 | WO | A |
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| 4601115 | Draper et al. | Jul 1986 | A |
| 4970803 | Keller | Nov 1990 | A |
| 5259756 | Urza | Nov 1993 | A |
| 5556436 | Yagaki et al. | Sep 1996 | A |
| 6083295 | Clark | Jul 2000 | A |
| Number | Date | Country |
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| 61 250097 | Nov 1986 | JP |
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| 2005 103437 | Apr 2005 | JP |
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| Entry |
|---|
| English Translation of JP 2005-016898A. |
| Number | Date | Country | |
|---|---|---|---|
| 20110041393 A1 | Feb 2011 | US |
