1. Field of the Invention
The present invention relates generally to induction melting apparatus for use in heating at least one material. More particularly, embodiments of the present invention relate to methods of control of induction heating apparatuses.
2. Background of the Invention
Induction heating apparatuses have been employed for heating a variety of materials without direct contact therewith. For instance, heat treating of metals and melting of materials may be accomplished by induction heating. Further examples of induction heating applications include, without limitation, annealing, bonding, brazing, forging, stress relief, and tempering. Additionally, powder metallurgy applications may relate to heating of a mold or other member which, in turn, heats a powder metallurgy composition to be melted. Metal or other casting applications may also utilize induction heating. Accordingly, as known in the art, induction heating may be useful in various industries and applications.
For instance, one particular application for induction heating relates to treatment and storage of such hazardous materials and is known as “vitrification.” Hazardous materials may be vitrified when they are combined with glass forming materials and heated to relatively high temperatures. During vitrification, some of the hazardous constituents, such as hazardous organic compounds, may be destroyed by the high temperatures, or may be recovered as fuels. Other hazardous constituents, which are able to withstand the high temperatures, may form a molten state, which then cools to form a stable vitrified glass. The vitrified glass may demonstrate relatively high stability against chemical and environmental attack as well as a relatively high resistance to leaching, as by water, of the hazardous components contained therein.
One type of apparatus that has proven to be effective to vitrify waste materials is a cold-crucible-induction melter (CCIM). A cold-crucible-induction melter may typically comprise a water-cooled crucible disposed proximate to an induction coil or another inductor; for instance, an induction coil may be formed along a helical path extending about the crucible. Generally, an induction coil may carry alternating electric current that generates associated varying electromagnetic fields for inducing eddy currents within electrically conductive materials encountered thereby. The varying electromagnetic fields generated by the current within an inductor may be described as the “flux” thereof.
Waste may be induction heated directly if it is sufficiently electrically conductive and thus vitrified. However, the waste and glass forming materials used in vitrification systems may be relatively non-electrically conductive at room temperatures. Therefore, an electrically conductive material may be used to initially indirectly heat at least a portion of the waste to a molten state, at which point the waste may become more electrically conductive so that when varying current is conducted through the induction coil, conductive molten waste may be induction heated by way of eddy currents generated therein. Of course, non-electrically-conductive waste materials nearby the electrically conductive molten waste, due to the heat generated therein, may be indirectly heated and thus, melted.
As a further advantage of cold-crucible-induction melter vitrification systems, molten glass within the water-cooled crucible may form a solid layer (skull layer), which inhibits or prevents direct contact of the high temperature molten glass with the interior surface of the crucible. Furthermore, because the crucible itself is cooled with water, in combination with the insulative properties of the skull layer, relatively high-temperature melting may be achieved without being substantially limited by the heat-resistance or melting point of the crucible.
During initial operation of the induction heating system 90 of the cold-crucible-induction melter 10, as shown in
Referring to
Also, cold cap 54, comprising granular material 55 and, possibly, condensed off-gas material, may preferably exist upon the upper surface of molten material 50 thereof under preferred conditions. Cold cap 54 may reduce volatization of molten material 50 and may also insulate molten material 50. Impact zone 59 indicates a region of cold cap 54 that granular material 55, shown as entering the cold-crucible-induction melter 10 through feedport 14, may fall upon and accumulate. Dust, volatized material, and evolved gases 57 may exit or move upwardly away from the impact zone 59 of cold cap 54 into the plenum volume 200. Ultimately, dust, volatized material, and evolved gases 57 may subsequently condense, deposit, or settle onto cold cap 54, adhere to the inner wall of disengagement spool 40 or head assembly 20, respectively, or exit the plenum volume 200 through offgas port 12.
Induction coils 26 surrounding crucible 56 may be energized with relatively large alternating currents to induce currents within the waste material to be heated. Typically, induction coils 26 may be fabricated from a highly electrically conductive material, such as copper, and are cooled by water or another fluid flowing therein. As known in the art, waste materials, such as radioactive waste or other waste may be combined with glass forming constituents, heated, and thereby vitrified.
Generally, conventional induction heating systems may be configured for heating in response to a temperature set-point. More particularly, conventional induction heating systems may be configured for varying the output power of the power source 100 in relation to the difference between a desired temperature and a measured temperature of the material to be heated. However, while such a temperature feedback control system may be relatively effective in controlling the temperature, it may not be particularly electrically efficient. Put another way, the transmission of electrical power between the induction coil 26 and the material that is heated therewith (e.g., the molten material 50, the susceptor 120, etc.) may be relatively inefficient.
Further, there may be difficulties in obtaining reliable temperature information relating to the molten material 50 that may complicate operation of the cold-crucible-induction melter 10. Therefore, conventional cold-crucible-induction melters may be often controlled manually. For example, conventional cold-crucible-induction melters may be controlled by “feel” or by secondary indications such as so-called “frequency pulling” in relation to the applied frequency of an induction power source 100. Such methods of control may be even more electrically inefficient than temperature feedback methods, and may also promote unintended variances from a desired temperature due to operator errors.
One approach for operating an induction melting furnace for glass (i.e., a cold-crucible-induction melter), disclosed by U.S. Pat. No. 6,185,243 to Boen et al., includes a melting furnace, including a cooled crucible having continuous metal side walls, a partitioned and cooled bottom and at least one induction coil positioned under the bottom of the crucible. The at least one induction coil is disclosed to be the sole heating means for materials within the crucible. The depth of the melting bath contained in the crucible and the excitation frequency of the induction coil are selected so that the depth and half of the inside radius of the crucible are less than the skin thickness of the bath.
In view of the foregoing problems and shortcomings with existing induction heating processing materials and systems, it would be advantageous to provide control methods relating to increased efficiency for operation of cold-crucible-induction melters.
The present invention relates to methods of operation of an induction heating apparatus. Particularly, a crucible having a wall disposed about a longitudinal axis and a bottom extending generally radially inwardly from the wall toward the longitudinal axis may be provided. Further, the walls of the crucible may be cooled and at least one material may be provided within the crucible. An inductor may be provided proximate to the crucible and in operable communication with an induction heating circuit including a power source.
A desired skin depth for heating the at least one material within the crucible may be selected and a frequency of an alternating current for energizing the inductor therewith and for producing an electromagnetic flux exhibiting a desired skin depth within the at least one material may be selected. Finally, the inductor may be energized with the alternating current having the selected frequency. Optionally, the frequency of the alternating current may be selected in response to a difference between a desired skin depth and the indicated skin depth of the electromagnetic flux within the at least one material. Further, additionally or alternatively, the frequency of the alternating current may be selected by selecting a net capacitance magnitude for inclusion within the induction heating circuit.
In one embodiment, the desired skin depth may be selected to be about 38% of a diameter of the at least one material. Such a desired skin depth may substantially maximize the electrical efficiency of inductively heating the at least one material.
In another aspect of the present invention, the at least one material may be heated while substantially maintaining a desired skin depth as the at least one material increases in temperature. More generally, a desired skin depth of the at least one material may be substantially maintained while the temperature thereof varies, without limitation.
For example, a molten material may be provided which substantially fills a crucible of an induction heating apparatus. An inductor may be provided proximate to the crucible and in operable communication with an induction heating circuit, the induction heating circuit including a power source. Additionally, a desired skin depth may be substantially maintained within the molten material, upon energizing the inductor, as the temperature of the molten material varies.
The present invention also relates to an induction heating apparatus. More specifically, an induction heating apparatus of the present invention may include a crucible and a cooling structure disposed about the crucible for cooling thereof. In addition, an inductor may be disposed proximate the crucible and a variable-frequency power supply having an electrical output may be operably coupled to the inductor and configured for delivering an alternating current therethrough. Further, a controller may be configured for selecting a frequency of the alternating current delivered from the variable-frequency power supply and for energizing the inductor and the frequency may be selected for producing an electromagnetic flux exhibiting a desired electromagnetic flux skin depth within an anticipated at least one material positioned within the crucible.
While the specification concludes with claims particularly pointing out and distinctly claiming that which is regarded as the present invention, the advantages of this invention can be more readily ascertained from the following description of the invention when read in conjunction with the accompanying drawings in which:
The present invention relates to an induction heating apparatus and methods of operation thereof. For example, one particular type of induction heating apparatus may be a cold-crucible-induction melter. While the following discussion relates to a cold-crucible-induction melter for melting at least one material, the present invention is not so limited. Rather, the present invention relates to induction heating apparatus for use as known in the art, without limitation.
In one aspect of the invention, the induction system 90 comprising a portion of the cold-crucible-induction melter 10 may be controlled or operated in relation to a so-called “skin depth” of the material being heated, as described in further detail hereinbelow. Such a method of operation may improve the electrical efficiency compared to conventional methods for controlling an induction heating process, since electrical efficiency between the alternating current carried by the induction coil 26 and the eddy currents induced therewith for heating a material may be a function of the skin depth or penetration depth of the electromagnetic flux generated by the alternating current passing through the induction coil 26 and penetrating into the material being heated. Therefore, in accordance with the present invention, the induction system 90 of the cold-crucible-induction melter 10 may be operated for maintaining or regulating a desired skin depth of an electromagnetic flux in relation to at least one material disposed within the crucible, during heating thereof.
Generally, the skin depth of an electromagnetic flux may be defined as the depth to which eddy-currents are induced within a material heated by electromagnetic flux. The theoretical depth of penetration or skin depth (d0) within a material to which an electromagnetic wave travels to is defined to be the depth at which the electromagnetic field is reduced to l/e or approximately 37 percent of its value at the surface. In the case of induction heating, the theoretical skin depth of the varying electromagnetic fields and the resulting eddy currents may be computed by the following equation:
Since the frequency of the oscillation of the electromagnetic wave is the only non-material dependent variable, influencing the skin depth d0 may be accomplished by varying the frequency of the alternating current communicated to the induction coil.
It should also be understood that while electromagnetic flux envelope 130 is depicted as having a relatively well-behaved shape, the actual shape and size of a flux field may be highly dependent on the particular configuration of the induction coil 26 and the materials and properties thereof proximate to the induction coil 26. Thus, electromagnetic flux envelope 130 is merely a representative, schematic depiction of the induction heating process and should not be construed as limiting of the present invention.
It should further be noted that while the electromagnetic flux envelope 130 may be described and may be mathematically treated as substantially symmetric, substantially cylindrical, or both substantially symmetric and substantially cylindrical, the distribution of electrical heating within molten material 50 by way of an induction coil 26 may be uneven in nature, depending on the geometry and material properties of the molten material 50, the proximity of the induction coil 26 to the molten material 50, the geometry of the induction coil 26, or other environmental conditions that may influence the electromagnetic flux of the induction coil 26 in relation to the molten material 50. The present invention contemplates that such unevenness may be modeled, predicted, or otherwise compensated for so as to increase the efficiency of the induction heating process.
Regarding induction power source 100, induction power source 100 may be configured for communicating an alternating current to induction coil 26 via an induction heating circuit. “Induction heating circuit,” as used herein, refers to the electrical circuit through which the alternating current for energizing the induction coil 26 passes. Induction power source 100 may comprise an induction heating power supply as known in the art, such as, for instance, a generator-type power supply or a solid state power supply. Further, induction power source 100 may include electrical transformers, inductors, or capacitors as known in the art and configured for supplying alternating current to the induction coil 26. According to the present invention, the alternating current may be selectively tailored to adjust the skin depth within the limits of the power source 100.
In addition, approximation of the induction power source 100, induction coil 26, net capacitance, and net inductance may yield a solution for the resonant frequency of the current within the induction heating circuit. The frequency (in Hertz) of oscillation of the current may be calculated by the following equation:
Thus, as may be appreciated by consideration of the above-equation, by adjusting or altering the capacitance of the induction heating circuit, the frequency of the alternating current communicated through the induction coil 26 may be changed. Accordingly, one approach for changing the electrical capacitance of the induction heating circuit may be to include at least one variable capacitor therein and to alter the capacitance of the at least one variable capacitor. For instance, one commercially available variable capacitor may comprise a vacuum capacitor having an adjustable capacitance magnitude of the type sold by Omnicor, Inc. of Foster City, Calif.
Alternatively, another approach for selecting the net capacitance of the induction heating circuit may be to electrically include or exclude one or more selected capacitors, each having a fixed capacitance magnitude, with respect to the induction heating circuit. Such a configuration may be possible by providing a so-called “bank” of capacitors, of which one or more thereof may be selectively included in or excluded from the induction heating circuit. Put another way, each of the plurality of capacitors may be configured to be individually and reversibly electrically coupled to the inductor. Conventional induction heating systems may include a bank of capacitors that are typically and manually used to tune the induction heating circuit to the load for delivering a selected magnitude of power to a material being heated therewith. Since a commercially available capacitor bank may comprise a plurality of capacitors, each capacitor having a fixed magnitude of capacitance, the degree of variation of the capacitance may be limited by the number of capacitors, their respective fixed magnitude of capacitance, and combinations thereof. Accordingly, the capacitance of a bank of capacitors may be selected so as to substantially correspond with a desired or selected net capacitance, but may not precisely equal the selected capacitance.
In addition, since a skin depth magnitude may be related to magnetic permeability and electrical resistance of the material being inductively heated, measurements or at least indications of the respective magnitude of these properties may be desirable for implementing a control or regulation algorithm wherein the alternating current communicated through the induction coil 26 is selected based substantially on a skin depth. However, one consideration may be that electrical resistivity, magnetic permeability, or both, may vary widely with temperature; thus, it may be desirable to indicate and adjust the alternating current with respect to material variations that influence the skin depth of an electromagnetic flux therein.
Specifically, a metal belonging to the ferromagnetic class (i.e., iron, cobalt, nickel, etc.) may exhibit a varying magnetic permeability. However, for other materials, magnetic permeability may be substantially constant. For instance, a paramagnetic material may have a magnetic permeability that is a little greater than 1 while a diamagnetic material may have a magnetic permeability that is a little less than 1. Accordingly, the variability of a magnetic permeability of a material for a given range of temperature may be estimated or, alternatively, may be assumed constant for purposes of calculating a skin depth. In the particular case of the glass-forming materials used in waste vitrification, the magnetic permeability thereof may be assumed to be substantially constant.
With respect to the electrical resistance of a material within the influence of an electromagnetic flux field, it may be desirable to measure the electrical resistance thereof. Particularly, it may be desirable, for instance, to measure the electrical resistivity of molten material 50, as one variable of interest in determining the skin depth of an electromagnetic flux field therein. For example, the resistivity of molten material 50 may be measured by a so-called “four-point” or Schlumberger resistivity measurement technique.
Alternatively, the resistivity of the molten material 50 may be estimated or indicated. For example, an induction heating circuit model 300 of an induction heating circuit is shown in
For instance, the induction heating system 90 and molten material 50 may be approximated or simulated as shown by the induction heating circuit model 300 shown in
Further, by Ohm's law,
Also,
Setting Equation 3 equal to Equation 4 and then solving for both the imaginary component and the real component gives respective solutions for RM. Thus, RM may be determined by substitution of measurements for the values of the imaginary component and the real component as well as the electrical resistance values and electrical inductance values that appear in Equation 4.
It should be noted that both
Thus, as discussed above, the variables for ascertaining a skin depth d0 may be indicated, estimated, or otherwise obtained and accordingly, a skin depth d0 may be obtained. Further, once a skin depth measurement, calculation, or indication may be obtained, a method of the present invention may be practiced, as described hereinbelow.
In one method of control or regulation of an induction heating system 90 of a cold-crucible-induction melter 10 of the present invention, a desired skin depth may be selected and a frequency of the alternating current communicated from the power source 100 through the induction coil 26 for producing the desired skin depth may be selected. Of course, the induction coil 26 may be energized with the alternating current having the selected frequency. Optionally, a difference between the desired skin depth set point and the indicated skin depth may be used to determine the selected frequency.
The following discussion relates to the operational conditions illustrated in
In one approach of the present invention for controlling induction heating system 90, an indicated skin depth may be provided for a user thereof, which may be compared to a desired skin depth set point and manual adjustment of the frequency of the alternating current to the induction coil 26, when energized, may be performed for minimizing the variance or difference between the skin depth set point and the measured skin depth. The decision to energize the induction coil 26 may also be left to a user or may be automatically performed by a controller that compares the error signal between a desired temperature set point and a measured or calculated temperature.
However, while a manual approach for adjusting the skin depth of the electromagnetic flux field may be satisfactory in some situations, it may be preferable to implement a so-called “closed loop” or automatic feedback control system, which may be configured to adjust the frequency of the alternating current to the induction coil 26 in response to a variance between the skin depth set point and the measured skin depth, without substantial user involvement.
For instance, a computerized data acquisition system or other measurement or control system may be employed to calculate substantially “real-time” values for the skin depth of a material within the influence of the electromagnetic flux of induction coil 26. Extrapolating further, the ability to calculate skin depth may provide a feedback signal for controlling the alternating current supplied from the induction power source 100 for energizing the induction coil 26. Thus, if material properties, such as resistance, change during heating thereof, the frequency of the alternating current may be adjusted for maintaining a desired skin depth therein.
As shown in
Optionally, the resistivity of the molten material 50 may be correlated to the temperature of the molten material 50, if the relationship therebetween is known or may be otherwise predicted or estimated. Alternatively, the temperature of the molten material 50 may be measured or indicated by a thermocouple, an optical pyrometer, or another temperature measurement device as known in the art.
The present invention relates to a method based on a construct that if the induction coil 26 is energized, the frequency of the alternating current flowing therein should be selected so as to generate, maintain, or endeavor toward a desired skin depth. Such an operational method may be used for maintaining a relatively high electrical efficiency, or as otherwise desired.
Thus, a heating feedback control loop 309 may be provided that is configured to control the temperature of the at least one material (i.e., determine or control whether or not the induction coil 26 should be energized). For instance, a desired temperature 301 may be compared to an indicated temperature 303. The difference between the desired temperature 301 and the indicated temperature 303 may be used as a so-called error signal 305 to form a basis for a control decision of whether or not to energize the induction coil 26.
In further detail, controller 306 may comprise an apparatus that selects a capacitance magnitude for inclusion within an induction heating circuit for supplying an alternating current for energizing the induction coil 26. As explained above, selection of a desired a capacitance value for inclusion within the induction heating circuit influences the frequency of the alternating current therein; therefore, the skin depth of the electromagnetic flux of the induction coil 26 within the material to be heated may be altered by changing the frequency of the alternating current passing therethrough. Thus, a difference (i.e., error signal 313) between the desired skin depth 311 and the indicated skin depth 307 may generate a control signal 308 via controller 306, which is used to select a magnitude of capacitance that reduces or minimizes the difference between the desired skin depth 311 and the indicated skin depth 307 by altering the frequency of the alternating current supplied to the induction coil 26 by induction power source 100.
Controller 306 may implement a so-called proportional, integral, and derivative type control algorithm for regulation or maintaining of the desired skin depth 311. Of course, other control approaches, such as optimal control, neural networks, or adaptive control methodologies may be utilized, without limitation. Furthermore, controller 306 may implement logic, timers, limits, alarms, or other control or safety devices or methodologies as known in the art or as otherwise desired. Thus, the control signal 308 may be developed in consideration of any number of inputs, measurements, or indications.
As described above, indicated skin depth 307 may be calculated by measurement of one or more electrical properties or operational conditions related to induction heating system 90. Sensor(s) 302 may measure voltage, resistance, inductance, capacitance, or other electrical parameters relating to the induction heating circuit.
The process and implementation for supplying the indicated skin depth 307 may be termed an “estimator” 310, because control or regulation of the induction power source 100 is performed via an indirect measurement of a skin depth d0 of the electromagnetic flux within the molten material 50. Put another way, the indicated skin depth 307 may be determined by indirect indication of a skin depth d0 within molten material 50.
It should be appreciated that if a desired temperature 301 is substantially attained, the material properties of molten material 50 may become substantially constant or steady state. In such a situation, assuming that the desired skin depth 311 is held constant, the frequency of the alternating current supplied to the induction coil 26 may be substantially constant.
Thus, the present invention contemplates a method including substantially maintaining the desired skin depth while maintaining a substantially constant temperature of the molten material. However, it should be recognized that the desired skin depth may be substantially maintained despite variations in the temperature of molten material 50. Accordingly, the present invention contemplates inductively heating the molten material via the induction coil 26 while substantially maintaining a desired skin depth within the molten material 50 as the temperature thereof varies or changes.
In such a situation, or as otherwise desired, heating feedback loop 309 may implement a time on, time off control approach (e.g., similar to pulse width modulation as used for varying the power of a direct current motor). In such an approach, a substantially constant input, may be energized for a selected percentage of time and may be turned off for the remaining percentage of time. By adjusting the ratio of the on time and the off time, relatively refined control of the power delivered by the induction coil 26 may be effected.
In another aspect of the present invention, configuring the skin depth to substantially correspond with a desired position or region of the molten material 50 or, more generally, at least one material, disposed within the crucible 56 may result in improved electrical efficiency in heating thereof. For instance, a skin depth of the electromagnetic flux of the induction coil 26 of between about ¼ to ⅖ of the diameter of the molten material 50 may be relatively efficient. Preferably, a skin depth set point of about 38% of a molten material 50 diameter may provide a maximum level of electrical efficiency of inductive heating of the molten material 50 therewithin.
Extrapolating further, the net capacitance within the induction heating circuit for producing a skin depth that maximizes the electrical efficiency of induction heating circuit may be calculated by substituting 38% of the diameter of a material to be heated for skin depth d0 in Equation 1. Setting Equation 1 equal to 38% of the diameter of the molten material yields:
Then, solving for f gives:
Then substituting Equation 2 for f in Equation 7 gives:
Further, solving for C yields:
Thus, a desired net capacitance C of the induction heating circuit for which the skin flux may substantially correspond to about 38% of the diameter of the molten material may be calculated by Equation 9. Thus, the net capacitance C of the induction heating circuit may be selected to substantially correspond to the calculated net capacitance C as calculated in Equation 9 by way of the feedback control loop illustrated in
While the method of the present invention may be particularly suited for controlling the output of induction power source 100 during an operational regime illustrated by
For instance, as shown in
As shown in
As may be appreciated from the above discussion, in a further extension of the present invention, control over the alternating current within an induction heating circuit may be selected in response to a desired skin depth during an operational regime depicted by
Since skin depth is a characteristic that is material dependent, if there is more than one distinct material having magnetic permeability and electrical resistance, the skin depth related to each distinct material may be different. Accordingly, the present invention contemplates consideration of one or more skin depths in selection of the characteristics of alternating current communicated through the induction coil 26. Of course, it is recognized that the skin depth within each distinct material may be related to one another, because the alternating current communicated through the induction coil 26 may generate an electromagnetic flux, which influences each of a plurality of distinct materials. Thus, in one aspect of the present invention, generally, the frequency of the alternating current communicated through the induction coil 26 may be selected in relation to more than one skin depths within different materials, respectively.
For instance, more than one skin depth may be considered in controlling the alternating current flowing through the induction coil 26. For instance, as shown in
One approach may be to predict the relative amount of power delivered within the susceptor 120 and the molten material 50 and then select a desired skin depth based on a weighted average of the respective skin depths, s0 and d0 thereof, respectively. For example, if the power is distributed 80% within the susceptor 120 and 20% within the molten material 50, and a desired skin depth for the susceptor 120 corresponds to an alternating current having a frequency of 1000 kHz and a desired skin depth for the molten material 50 corresponds to an alternating current having a frequency of 500 kHz, the weighted average thereof may be calculated by averaging 0.8 times 1000 kHz in addition to 0.2 times 500 kHz, which yields 900 kHz. Accordingly, a capacitance magnitude for producing an alternating current having a frequency of 900 Hz may be selected. As may be appreciated, there may be various mathematical approaches for maximizing the electrical efficiency between an induction coil 26 and two or more materials heated thereby, according to the present invention. Optionally, alternatively, or additionally, predictive modeling may be employed for selecting an alternating current that maximizes the electrical efficiency of induction heating of two or more materials by selection of a frequency of an alternating current within an inductor for heating thereof.
While the present invention has been described herein with respect to certain preferred embodiments, those of ordinary skill in the art will recognize and appreciate that it is not so limited. Rather, many additions, deletions and modifications to the preferred embodiments may be made without departing from the scope of the invention as hereinafter claimed. In addition, features from one embodiment may be combined with features of another embodiment while still being encompassed within the scope of the invention as contemplated by the inventors. Therefore, the invention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the following appended claims.
This application is related to U.S. application Ser. No. ______ entitled INDUCTION HEATING APPARATUS, METHODS OF OPERATION THEREOF, AND METHOD FOR INDICATION OF A TEMPERATURE OF A MATERIAL TO BE HEATED THEREWITH, filed on even date herewith.
The United States Government has rights in the following invention pursuant to Contract No. DE-AC07-991D13727 between the U.S. Department of Energy and Bechtel BWXT Idaho, LLC.