The present disclosure relates to an inductor device and an apparatus comprising the same. More particularly, the present disclosure relates to an inductor element that utilizes a spin structure of electrons and an apparatus comprising the same.
Among basic electronic devices, basic passive elements in electric circuits that provide a linear relationship between applied voltage and current are typically the R (resistance), C (capacitance), and L (inductance) elements. The physical function of each element is the generation of heat associated with electric current (R), storing energy by electric charge (C), and storing energy by magnetic field (L). Among these, elements responsible for inductance L (inductor elements) in particular have lagged behind in miniaturization. For instance, a product that shows the smallest size with a high inductance value has a size of 0.6×0.3×0.3 mm3 with inductance value of about L=130 nH to 270 nH.
On the other hand, there have been discoveries of physical phenomena with a different operating principle from those of conventional basic electronic elements, which primarily rely on electrons' spin in addition to charge. These physical phenomena are being used in passive devices, active devices, and memory devices. Such a field is sometimes referred to as spintronics, which has shown marked progress these days.
With the continuing progress in miniaturization of various electronic devices, the demand for miniaturization of various electronic circuit elements remains unabated. In particular, the volume of conventional inductor elements has to be increased in order to gain a higher inductance value. There has been no known operating principle that can realize miniaturization.
The present disclosure aims to solve at least some of the problems mentioned above. The present disclosure provides a new principle of inductor elements that utilizes the quantum phenomenon observed in the conduction electrons interacting with the spin structure of electrons, thereby contributing to the miniaturization and high density of electronic circuits employing inductor elements and apparatuses containing them.
The inventors came to the conclusion that it is difficult to miniaturize inductor devices as long as they operate on the principle of conventional inductor devices, i.e., the principle of coupling an electric current to magnetic energy generated within a space or in a magnetic material. Then, we have created a new concept of inductor elements adopting degree of freedom of electrons' spin, and completed the present disclosure.
That is, in certain aspects of the present disclosure provided is an inductor element comprising a metal medium with a spatially arrangement of ordered spins such that the ordered spins have a non-collinear spin structure when traced in a direction, wherein an electric current is applied through the metal medium in such a way that the electric current has a projection component in the direction.
The term “inductor element” includes elements and devices also referred to as reactance elements, reactors, etc., unless otherwise noted hereinafter. In addition, due to limitations in the notation of the application document, the term “vector” may be added to the alphabet denoting a variable in the text in place of indicating an arrow above the alphabet. Likewise, due to limitations in notation, the term h-bar may be used in the text to mean the Planck constant h divided by 2π. In addition, due to limitations in notation, academic conventions such as distinguishing variables among constants and variables by italicizing them are not expressed in characters, but only in embedded images. Inconsistencies with conventions due to these restrictions in notation and apparent inconsistencies occurring in written documents shall not affect the disclosure of this disclosure or the interpretation of the scope of rights, as they are caused by constraints imposed on the notation.
In a certain aspect of the present disclosure, there is provided an inductor element and an electronic device including the same, which are based on a novel operating principle and can be easily miniaturized.
Embodiments of the inductor elements of the present disclosure will be described by referring to the following drawings. Throughout the drawings, common parts or elements are denoted by common reference numerals in this description, unless otherwise noted. In addition, each element of each embodiment in the drawing should be understood as not being drawn to scale.
An illustration of the operating principle of a conventional inductor device is shown in
where L denotes the inductance. The most typical inductor element is the coil shown in
where n=N/l is the number of turns per unit length. With the increasing miniaturization of circuits, it is required to obtain a sufficiently large inductance L even though A and l are kept small. However, as shown in the rightmost side of Equation (2), if the number of turns n per unit length is constant, the inductance L becomes small in proportion to the volume lA of the inductor element. As mentioned above, the smallest size and high inductance values that have been commercialized make up a size of 0.6×0.3×0.3 mm3 to obtain an inductance value of about L=130 nH to 270 nH, for example. As long as it is based on the conventional principle, further miniaturization is difficult.
In stark contrast to the conventional one, the operating principle in this embodiment utilizes the interaction between the electron spin and the conduction electrons.
Electrons behave as tiny magnets due to the fact that they have an angular momentum h-bar/2. Here, h-bar is the Planck constant h divided by 2π. Generally speaking, electron spins are the building blocks for the higher-order structure (magnetic structure or magnetic order) that produces the magnetic properties of materials such as ferromagnetism. The magnetic order in a material is determined by the arrangement of ordered electron spins (ordered spin), or spin structure. The ordered spins that can generate a spin structure are typically spins of localized electrons (localized spins) or spins of conduction electrons when the conduction electrons themselves create a magnetic order. The spin structure may take on a parallel spin structure or an anti-parallel spin structure. Parallel and anti-parallel spin structures are the origin of ferromagnetic and antiferromagnetic order, respectively, and both are spatially uniform. Spatially uniform structures that are either parallel or antiparallel, such as parallel and antiparallel spin structures, are also called collinear spin structures. On the other hand, it is also known that spin structures with inclination, in which nearby spins are neither parallel nor antiparallel, can be realized in materials, and are called non-collinear spin structures. The inductor elements of the present embodiment are related to this non-collinear spin structure.
When the ordered spins have a non-collinear spin structure, the wavefunction of conduction electrons propagating through the non-collinear spins is affected by the spatial structure of the ordered spins through Hund's coupling, which leads to the spin Berry phase. In terms of the effect on the conduction electrons, the spin Berry phase acts in the same way as the vector potential of the electromagnetic field. For this reason, the effect of the said spin Berry phase on the conduction electrons can also be described by an electromagnetic field (“emergent electromagnetic fields”), which is a vector potential with an equivalent effect. We introduce a vector n, which typically represents a spin structure created by, for example, the spin orientation of localized electrons in a material. The vector n has one fixed direction for each position in the xyz Cartesian coordinate system and is time-dependent. The emergent electromagnetic field for describing the effects of the spin structure
[Formula 3]
{right arrow over (n)} (3)
on the conduction electrons can be described in general as
Here, the subscripts i, j, and k indicate the components of the Cartesian axes x, y, and z, and are chosen cyclically, ei and bi are the components of the emergent electric field and the emergent magnetic field, respectively, and ∂i and ∂t are the partial derivatives with respect to the spatial coordinate i and the time t, respectively. The motion of the conduction electrons is determined according to the superposition of the external electromagnetic field and also the emergent electromagnetic field determined in this way. This emergent electric field vector e=(ex, ey, ez) generates an electric current J vector of the form
[Formula 5]
{right arrow over (J)}=ρ{right arrow over (e)} (5)
where ρ is a resistivity. The corresponding voltage drop V in the conduction electrons is given by
Here, the current density vector J and the direction of the current-carrying line coincide with each other, and the component of the emergent electric field vector e in this direction is denoted as e, and the length of the line is denoted as l.
It is known that an example that has a non-collinear spin structure and results in a voltage drop is the magnetic wall dividing adjacent magnetic domains, and it has been theoretically investigated and experimentally confirmed that the magnetic wall can be driven by an electric current. The force (electric field) that can explain the voltage drop, such as imparting a potential to the charge, is known as electromotive force (emf). See, e.g., Non-Patent Documents 1 and 2 for the theory and Non-Patent Document 3 for experimental confirmation. Another non-collinear spin structure, a helical structure, has also been predicted to produce a voltage drop across the crystalline substance (Non-Patent Document 4). Non-Patent Document 4 suggests theoretically that the voltage drop in the helical structure is caused by a deformation of the spin structure of the helical structure by the magnetic field.
The inventors found that when an electric current is applied to a material with a non-collinear spin structure, an emf will be induced inside the material and the spin structure itself will also be deformed. In addition, we realized that the voltage drop could lead to an operation of inductance rather than simple resistance. In particular, we found that the dependence of the performance on the device size of inductor elements operated in this manner is advantageous for miniaturization.
The illustrations in
The inventors have found that the voltage drop (Eq. (6)) is efficiently generated by the emergent electric field e (Eq. (4)) in an arrangement where a time-varying alternating current is applied in the z-axis direction, which is the direction of the helix axis. When such an electric current is applied, the conduction electrons responsible for the current interact with the spin structure. One such interaction is the rotational operation that rotates the entire spin structure around the z-axis in
This section describes the configuration of the inductor element of this embodiment. The structure of the inductor element of the present embodiment is shown in
The performance of an inductor element, such as the inductance value, can be evaluated by estimating the degree of deformation of the spin structure caused by the interaction between the conduction electrons and the spin structure. The relationship between the deformation of the spin structure and the electric current due to the conduction electrons flowing through it can be analyzed by the equation of motion for the spin structure. The vector n, which represents the spin structure of the helix shown in
[Formula 7]
{right arrow over (n)}={right arrow over (e)}
1 cos(Qz+Ψ)+{right arrow over (e)}2 sin(Qz+Ψ)+m{right arrow over (e)}3 (7)
with vectors e1, e2, and e3 as unit vectors in each of the xyz Cartesian coordinates. The vector n, which indicates the orientation of the localized spins, is a vector whose length is 1 at each position, whose orientation is in the xy-plane when m is 0, and whose orientation is determined by z and the magnitude Q of the wavenumber vector of the helix structure. The tip of the vector n draws a helix when the vector n is traced along the direction (z-axis) of the wavenumber vector with magnitude Q. m is the component of tilt-up in the z-axis direction, which means that it has tilt-up if m is non-zero. Here, we introduce the translational motion coordinate X of the helix structure with respect to the position of the z-axis,
[Formula 8]
cos(Qz+Ψ)=cos(Q(z−X)) (8)
where X reflects Ψ, which represents the phase of the helix structure that maintains the wavenumber Q, indicating the position of, so to speak, the center of the helicity. The equation of motion governing spins is also known as the Landau-Lifshitz-Gilbert (LLG) equation. Additionally, taking into account the interaction with the electric current by the conduction electrons, the equation of motion for the spin structure is given by the following equations, where φ0 is the angle of elevation of the spin from the xy-plane to the z-direction
where α is the Gilbert damping term, β the non-adiabatic effect term, S the magnitude of the spins, P the spin polarizability, a the lattice constant, e the elementary charge, vpin a quantity with a dimension of velocity representing the pinning strength, vc a quantity proportional to the spin anisotropy energy, and j the current density of the conduction electrons. Performing the variable transformation as in
and assuming that the variable in sin is small, Equation (9) becomes
Equation (11) can be linearized using the time dependence term exp(−iωt) where i is an imaginary unit, assuming that the required physical quantity is represented by the real part of the complex number, and can be reduced into
Since Equation (12) is expressed in terms of a 2×2 matrix of complex variables, it can be solved analytically as
using a determinant D(ω). Here, the determinant D(ω) becomes
From this we obtain the elevation angle φ0, which is the deformation of the spin structure, and it is calculated as
Equation (15) is the general form expressing the deformation of the spin structure. Here, we introduce two physical quantities based on insights into physical aspects. These share the same physical dimension with the current density j, and have threshold aspects based on the pinning action, as follows
jint: threshold current density due to intrinsic pinning
ζjint=vc/2
jpin: threshold current density due to extrinsic pinning
ζβjpin=vpin
where jint is the current density corresponding to a threshold value for overcoming the spin anisotropy of the spin structure itself. On the other hand, jpin is the current density corresponding to the threshold value for overcoming impurity-induced pinning. In addition, by being substituted by two characteristic frequencies:
νint=vc/λ
νpin=vpin/λ
Equation (15) can be reduced into
Next, we divide into cases in terms of the relationship between νpin and νint, and investigate how the value of elevation angle φ0 is expressed for each range of values of ω (the time-dependent angular frequency of elevation angle φ0. The results can be easily understood by dividing them into two cases, Cases A and B, in terms of νpin and νint, and then dividing each case in terms of the value of angular frequency ω (six cases in total). At this point, it is assumed that vpin«vint as α, β«1. Therefore, the denominator of the right-hand side of Equation (16) is reduced to ≈ω2+1αωνint−νpinνint. The “Denominator” and “Numerator” in this and other cases are those in the right-hand side of Equation (16) unless otherwise noted.
νpin«ανint′νint (A)
ω«νpin/α«νint A-(i)
In this case, we have
Denominator≈−νpinνint
Then, we have
νpin/α«ω«νint A-(ii)
In this case, we have
Denominator≈iαωνint, Numerator≈iω(β−α)
Then, we have
νint«ω A-(iii)
In this case, we have
Denominator≈ω2, Numerator iω(β−α)
Then, we have
ανint«νpin«νint (B)
ω«ανint«νpin«νint B-(i)
In this case
Denominator≈iαωνint−νpinνint≈−νpinνint
(therefore, iαωνint«iα2νint)
Numerator≈νpin
Then, we have
ανint«ω«(νpinνint)1/2 B-(ii)
In this case,
Denominator≈−νpinνint
Numerator: αω/νpin«α(νint/νpin)1/2«α(1/α)1/2=α1/2
therefore, Numerator≈νpin
Then, we have
(νpinνint)1/2«ω«νint B-(iii)
In this case, we have
Denominator: ω2
Numerator: αω/νpin»(νint/νpin)1/2»1
therefore, Numerator≈iω(β−α)
Thus, we have
The elevation angle φ0 thus obtained is summarized in
To classify the emergent electric field in terms of the helical spin structure, we can calculate Equation (4) for the spin field structure shown in Equation (6). Since
[Formula 23]
∂t{right arrow over (n)}=∂tΨ(−{right arrow over (e)}1 sin(Qz+Ψ)+{right arrow over (e)}2 cos(Qz+Ψ))+∂tm{right arrow over (e)}3
∂z{right arrow over (n)}=Q(−{right arrow over (e)}1 sin(Qz+Ψ)+{right arrow over (e)}2 cos(Qz+Ψ))+∂zm{right arrow over (e)}3 (23)
holds, substituting these into Eq. (4.1) yields
Here, m≈φ0 is satisfied for small φ0. Therefore, we have
Note that Q=2π/(2λ)=π/λ. The partial derivative over time in Equation (25) can be replaced by −iω for the component of angular frequency ω.
The performance of the inductor elements is evaluated by estimating the relevant physical quantities by applying the values of the physical parameters of actual materials, realistic values, constant values, etc. to the formulated relational equations.
The spin anisotropy K⊥ of intrinsic pinning is about 0.03 K to 2.4 K. This intrinsic pinning is the effect of pinning the spins so that they do not tilt-up toward the z-axis, and the anisotropy K⊥ gives a strength of restoring force. This quantity becomes a measure to be overcome for spins to tilt-up. Based on the relationship between vcK1, the threshold current density jint, i.e., the minimum current threshold required to overcome the pinning, can be estimated to be jint=5×1011 to 4×1013 A/m2. However, since this value is the minimum current density required to tilt-up with a direct current (DC), the spin will tilt-up by an amount proportional to the current value when an alternating current (AC) is applied.
By substituting the partial derivative over time in Equation (25) with each frequency and taking its real part, ez can be expressed as
Here, we use the threshold current density, jint, estimated in the above, as well as the following
λ=20 nm=2×10−8 m
e=1.6×10−19 C
h-bar=10−31 J·sec,
the relationship between the z-component of the emergent electric field and the current density can be determined as the following:
Furthermore, when the length of the sample is l=1 mm and the current density J=109 A/m2, the voltage is
V=le
z=1.5×10−7×ν×10−3 (Volt)
=1.5×10−10×ν(Volt).
If the lower limit of detection voltage is set to nVolt (10−9 V), the lower limit of frequency ν (=ω/2π) can be detected from a few Hz, and the emergent electric field could be experimentally confirmed.
2-2. Estimation of νint and νPin
Next, we estimate the values of νint and νpin. For one of them, νint, assuming a material with the conduction properties of a common metal, we have the localized spin of magnitude S˜1, the electron density n, and the lattice constant a as na3˜1, and the threshold current density jint˜1012 A/m2, to obtain the following:
v
c/2=ξjint=a3Pjint/2eS.
Let P=0.1 and a=4 nm, we get
Hence, we can estimate as:
νint=νc/λ=(4×104)/(2×10−8)=2×1012 sec−1.
For the other one, νpin, assuming jpin=1010 A/m, we have
Let α˜10−2, we have νpinανint.
Next, we will explain the characteristics of the inductor element. We make an estimation of inductance L for a linear conductor of cross-sectional area A and length l, whose direction of extension is aligned with the wavenumber direction of the helical structure (
are used. Here, let η be η=−½ or (β−α/2α). Then, we get
From this, we obtain a relationship as follows:
Equation (32) allows us to estimate the order of L. For this purpose, we substitute the following approximate values having one effective digit: η˜1, l=1 μm, A=1 μm×1 μm=10−12 m2, λ=20 nm=2×10−8 m, jint=1012 A/m. By substituting the other physical constants and other values already mentioned into the above, we get
L≈½×10−10 [Henry].
This value of L is about 1/400 of the value of the existing device described above (L=130 nH to 270 nH approx.). What is completely different from the conventional one in this regard is a scaling law concerning the size of the inductor element itself. The dependence of the inductance value on the cross-sectional area A shows that L is proportional to A as shown in Equation (2) in the conventional case, while in the inductor element of the present embodiment L is inversely proportional to A as shown in Equations (31) and (32). In other words, the inductor device that operates on the principle of this embodiment has an innate property that is extremely favorable to device miniaturization in that L can be increased by reducing the cross-sectional area A.
In order to predict the performance of the inductor element, we further calculate the Q value, which is the performance index of the inductor element.
Since
Q=Lω/R=2πLν/R, and
R=ρl/A,
substituting Equation (32) into these equations yields
By substituting jint=1012 A/m and λ=20 nm=2×10−8 m and other values into the above, we obtain Q˜0.3×10−8 ν/ρ (sec−1/μΩ cm). For ρ˜1 μΩ cm and ν˜109 sec−1, we can obtain a value of about Q˜3, which predicts that the inductor element in the present embodiment can actually function as an inductor element. In general, a good conductor with small ρ and a material with small λ (i.e., small helical pitch of the spin structure) is suitable for increasing Q.
Returning to
The inductor element in the present embodiment can function equally well by adopting other non-collinear spin structures than a helical structure. One such spin structure is the cycloidal structure. In
In a typical cycloidal structure, the wavenumber of the periodic structure is oriented toward the z-axis while the spins at each position are contained in the xz-plane. As mentioned above, as a result of the spin Berry phase acted on the conduction electrons in the helical structure (Proper Helix structure), an elevation angle φ0 was generated in the direction of the helical axis. In contrast to that, in the cycloidal structure, when an electric current is applied in the z-axis direction, an elevation angle φ1 (not shown) is generated from the xz plane to the y-axis direction. This is because the cycloidal structure can be described by the same equation in which the components of the unit vector e2 and e3 are interchanged in Equations (6), (23), and (24) for the helical structure described above, and because an emergent electric field ez proportional to the component of the unit vector e2, i.e., the elevation angle φ1, is generated as well. In this way, the properties established for the helix structure (proper helix structure) are also found in the case of the cycloidal structure shown in
It should be noted that the voltage drop does not depend on the rotational plane of the spins. This is because the inductance is always in the same direction as the current flowing in the direction of the spin modulation vector, and the voltage appears in the same direction. Also, a structure combining a helical structure and a cycloidal structure can be used as an inductor element. For example, in
Even if the structure is not a helical or cycloidal structure, a fan structure, in which the spins swing left and right to form a fan, will in principle exhibit the same phenomenon as in the case of a helical structure. Furthermore, since the same inductance does not cause sign reversal in either of the crystal helicities (right-handed or left-handed systems), there is no need to fabricate the metal medium so that it has a single-domain structure with matching helicities of ordered spins.
In addition, other non-collinear spin structures can also be employed for this implementation of inductor elements. For example, inductor elements can be implemented in the same manner with materials that form a conical spin structure, where the spins tilt-up from the helix structure with a certain angle of elevation, or a tilted conical spin structure, where the spins are oriented along a conical surface whose conical axis is tilted from the wavenumber direction of the periodic structure. Helical structures, cycloidal structures, conical spin structures, tilted conical spin structures, and fan structures are all non-collinear spin structures; moreover, skyrmions, spin structures frustrated in three dimensions, etc. can also be employed to implement the present inductor element.
Following the filing of basic application of this disclosure application, the inventors conducted an experimental demonstration of the operation of the inductor element proposed in this embodiment as a research theme adopted by the Japan Science and Technology Agency's Core Research for Evolutionary Science and Technology (CREST) program in 2018.
What is to be measured is the voltage drop between the probe electrodes 122 and 124, or between the probe electrodes 126 and 128, with the AC current applied between the drive electrodes 114 and 116. The voltage drop is measured at the same frequency component as that of the applied AC current.
In general, the voltage drop V follows the relation
ImV=ωLI (34)
depending on the inductance L of the inductor element, the current I, and the angular frequency ω. Considering this, the measurement results in
If we use a measured value at a temperature of 5 K shown in
The size and mass of the inductor element sample 110 is extremely small. The effective volume of the metal medium 102 of the above sample, taking into account the distance between electrodes, is 0.3 μm×10 μm×7 μm=21×10−9 mm3 and its mass is 1n grams, or less than 10−9 g. Specifically, calculating the mass from the density and volume, based on the density of Gd3 Ru4 Al12 (10.8 g/cm3) and the volume in the sample (approx. 10×20×0.3 μm3), the size of the metal medium 102 alone, not including the electrodes and substrate, is about 0.65 ng.
The volume of a conventional inductor element of 130 nH to 270 nH, which is available in the market and disclosed in Non-Patent Document 5, is about
(0.6 mm×0.3 mm×0.3 mm)=54×10−3 mm3.
Thus, the inductor element provided in this embodiment can have a similar inductance value with a size and mass of about 10−6 of that of a conventional inductor element.
Next, we will explain materials that can realize the non-collinear spin structure and operate as the inductor element of the present embodiment. From the above explanation, a typical selection criterion is a metallic material that substantially has a ferromagnetic order (roughly parallel order) between adjacent spins, realizes a non-collinear spin structure as a result of modulation from the ferromagnetic order, and exhibits practical electrical conductivity. Examples of non-limiting materials that satisfy these properties are given in Table 1.
One example of these is MnSi, which is a chiral magnetic material and can exhibit a helical structure. Note that MnSi can also exhibit a skyrmion structure under certain conditions. [Ir(10)/Fe(0-6)/Co(4-6)/Pt(10)]20 is a composite material of platinum-based heterostructures with a unit structure of Ir/Co/Pt or Ir/Fe/Co/Pt, and within the unit structure, each metal layer has the thickness indicated in parentheses (unit: angstrom=0.1 nm). In this example, the stacked structure consists of 20 unit structures stacked repeatedly. Also, [Pt (3 nm)/Co (0.9 nm)/Ta (4 nm)]15 is a composite material heterostructure of platinum-based heterostructure with a unit structure of Pt/Co/Ta. Each metal layer in the unit structure has the thickness (in nm) in parentheses, and is fabricated in a stacked structure with 15 unit structures repeatedly stacked. The lower limits of the domain wall widths of [Ir(10)/Fe(0-6)/Co(4-6)/Pt(10)]20 and [Pt(3 nm)/Co(0.9 nm)/Ta(4 nm)]15 are about 80 nm (Non-Patent Document 6) and 90 nm (Non-Patent Document 7), respectively. Therefore, it is expected that the pitch of the helical structure can be shortened to a considerable extent.
In general, materials with a non-collinear spin structure can be employed in the present embodiment. The non-collinear spin structure is a spin structure of localized spins that are modulated from the ferromagnetic order by spin-orbit coupling, represented by the Dzyaloshinskii-Moriya interaction, and can be selected from those described above, such as helical structures. Such materials can be selected from alloys, typically containing transition metals. Materials that realize a non-collinear spin structure among localized spins as a result of the RKKY interaction, which is another generation mechanism than the spin-orbit interaction, can also be employed. In addition, a non-collinear spin structure can also be realized among localized spins by magnetic frustration, and suitable materials for the inductor device can be selected from such a group of materials.
The present disclosure also includes apparatus that incorporates electrical and electronic circuits containing the inductor elements described above. The inductor elements of the embodiments described above can be employed as basic elements for general electrical and electronic circuits, including, for example, resonant and filter circuits. The applicability of the inductor elements described above in principle is not specifically limited, but includes general electrical and electronic equipment including these electronic circuits, and includes electrical and electronic equipment, communication equipment, audio-visual equipment, and medical-related electronic equipment, whether for industrial or home use application. Since the inductor elements provided in the present disclosure can be fabricated in a lightweight and compact package, they can also be applied to hearing aids, cardiac pacemakers, and microelectromechanical systems (MEMS).
In the above description, the embodiment of the present disclosure has been described specifically. Any description in this Specification is for the purpose of explaining the present disclosure, therefore the scope of the invention of this disclosure should be determined based on recitations of the claims. Furthermore, other variation based on any combination of the embodiment is included in the present disclosure, which variation should be also within a scope of the claims.
Number | Date | Country | Kind |
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2018-145483 | Aug 2018 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2019/030236 | 8/1/2019 | WO | 00 |