The present invention relates to an information recording medium used for reproduction or the recording and reproduction, and to a method for manufacturing the same.
As the amount of information that information devices, audio/video devices, and so forth are required to handle has risen in recent years, there has been increasing attention give to optical disks and other such information recording media that provide easy data access, allow large volumes of data to be stored, and afford devices that are more compact, and this has led to higher density of recorded information. For instance, an optical recording medium with a capacity of about 25 GB with a single layer and about 50 GB with two layers, using a reproduction head with a numerical aperture (NA) of 0.85 as a converging lens for focusing a laser beam and using a laser beam with a wavelength of approximately 400 to 405 nm, has been proposed as a means for increasing the density of an optical disk, and has been marketed under the name of “Blu-ray disc.”
The signal substrate 201 is generally made by injection compression molding or the like, and the information face is transferred onto one side by a die called a stamper. An information recording layer is formed by forming a thin-film layer over this upper face. The thickness of the signal substrate 201 is about 1.1 mm. The thin-film layer 202 includes a recording film or reflective film, and is formed by sputtering, vapor deposition, or another such method on the side of the signal substrate 201 on which the pits or guide grooves are formed. The transparent substrate 204 is composed of a material that is transparent to the recording and reproduction light (has transmissivity), and its thickness is about 0.1 mm. The transparent layer 203 is provided to bond the two transparent substrates 204 and 205 together, and is formed from an adhesive agent such as a photosetting resin or a pressure-sensitive adhesive. The transparent substrate 204 and the transparent layer 203 are collectively referred to as a cover layer. Sometimes the cover layer is formed by just curing the transparent layer, without affixing a transparent substrate. The recording and reproduction of this multilayer information recording medium are accomplished by directing a recording and reproduction laser beam from the transparent substrate 204 side.
With an information recording medium such as this, the cover layer is usually made by spin coating with an ultraviolet curing resin or the like (see Patent Citation 1, for example).
Patent Citation 1: Japanese Laid-Open Patent Application 2005-259331
However, a problem is that when the cover layer is formed by spin coating, there are slight fluctuations in film thickness in the peripheral direction, and major fluctuations in film thickness in the radial direction. Also, since the resin extends all the way to the end face of the coated substrate, when the spinning is halted and the resin is cured by optical irradiation, surface tension can cause the resin to build up at the end face of the coated substrate, resulting in a thicker film there. Consequently, the following problems are encountered in the recording and reproduction of signals to a medium with a laser. Spherical aberration caused by film thickness fluctuation can result in fluctuation in the focusing of the light spot, and can affect focus control of the light spot on the information face or tracking control in which the light spot is made to track a signal string. Also, with spin coating, controlling the conditions for achieving a uniform coating thickness is complicated, and performing spin coating for each layer results in a longer takt time.
Meanwhile, there is a method that employs screen printing technology, in which the information face of a substrate is coated (printed) with an ultraviolet curing resin or the like by sliding a squeegee over a screen, so as to form a resin layer. Advantages of this method are that it is relatively easy to shorten the takt time, the resin can be applied to the desired places by controlling the shape of the screen, and so forth.
However, screen printing involves applying a resin to a substrate through the mesh of a screen, so the resin tends not to adhere to the substrate at the lines that make up the screen or at the intersecting portions where the lines cross. Accordingly, the texturing reflects the shape of the screen.
As discussed above, when a laser is used to record and reproduce a signal, resin build-up can affect tracking control and focus control of the laser beam. Therefore, although screen printing is easy and affords a short takt time, a problem seems to be the condition of the resin surface. It is an object of the present invention to provide an information recording medium with which a stable reproduction signal can be obtained, and a method for manufacturing this information recording medium inexpensively.
The method for manufacturing a cover layer in the information recording medium of the present invention is a method for manufacturing an information recording medium in which a laser beam is directed at an information recording medium having an information recording film to perform signal recording and reproduction, and a resin layer on the side at which the laser beam is directed is formed from at least two kinds of ultraviolet curing resin, said method comprising the following steps.
The thickness of the first resin layer is preferably greater than the thickness of the second resin layer.
The method for forming the second resin layer is preferably screen printing.
The mesh count of the screen used in the screen printing to form the second resin layer is preferably greater than the mesh count of the screen used in the screen printing to form the first resin layer.
The method for forming the second resin layer is preferably inkjetting.
The method for forming the second resin layer is preferably spin coating.
Also, this method preferably further comprises the following steps.
In a step following the formation of the first ultraviolet curing resin, ultraviolet rays are preferably directed at the first ultraviolet curing resin for the purpose of curing it.
When an information recording medium is produced by the above method, the time it takes to form the resin layers can be shortened, and higher productivity can be anticipated. Also, since the equipment used for production is relatively simple, it will not require maintenance as often. Accordingly, a large-capacity information recording medium can be provided to the market inexpensively.
The information recording medium pertaining to another aspect of the present invention is an information recording medium which has an information recording layer, and in which a resin layer is formed over the information recording layer, wherein the resin layer is formed from at least two layers of resin. Of the resin layers, the center line average roughness of the first resin layer surface formed on the information recording layer is greater than the center line average roughness of the resin layer surfaces other than the first resin layer.
With this information recording medium, the center line average roughness of the first resin layer surface in the information recording medium is preferably greater than the center line average roughness of the outermost resin layer.
With the information recording medium of the present invention and the method for manufacturing the same, a resin layer can be formed on a recording layer in a short time. Also, since the center line average roughness of the surface of the second resin layer is very low, tracking control and focus control of the laser beam that records and reproduces signals can be stabilized, and an information recording medium with which signals can be favorably recorded and reproduced can be realized.
101 squeegee fixing jig
102 squeegee
103 first type of ultraviolet curing resin
104 screen
105 screen frame
106 table
107 signal substrate
108 thin-film layer
109 arrow
110 first type of resin layer
111 ultraviolet irradiation device
112 second type of ultraviolet curing resin
113 screen
114 squeegee fixing jig
115 squeegee
116 arrow
117 second type of resin layer
118 ultraviolet irradiation device
Embodiments of the present invention will now be described through reference to the drawings. These embodiments illustrate structural examples of information recording media in the form of optical disks, but the commercial product that is produced is not limited to being in the form of an optical disk. A manufacturing method and manufacturing apparatus with which a resin layer can be formed at high speed and in a uniform thickness are proposed below.
The steps of producing a recording medium and of recording and reproducing information span a number of processes, so each process will be described through reference to the drawings.
First, the process up to the formation of a cover layer in a Blu-ray disc will be described through reference to
The signal substrate 201 is formed from a disk of polycarbonate or acrylic resin, with an outside diameter of 120 mm and a thickness of about 1.0 to 1.1 mm, so that the substrate will have good rigidity and be resistant to warping, and so that there will be good thickness interchangeability with CD's, DVD's, and other such optical disks. An information face such as pits or guide grooves formed by texturing is produced on one side of the signal substrate 201 by using a die called a stamper to mold the resin by injection compression molding or the like. A center hole (not shown) with a diameter of 15 mm is provided to the center part of the substrate in order to support and rotate the disk when a player records or reproduces a signal. In this embodiment, a case in which polycarbonate is used will be described as a typical example.
Since the transparent layer 203 and so forth composed of a photosetting resin material are laminated over the signal substrate 201, if the information face is on top, for example, the information recording medium ends up warping in a concave shape due to photosetting constriction, which is a characteristic inherent in photosetting resins. Therefore, to deal with warping of the signal substrate 201, the information face is put on top and formed warped in a convex shape ahead of time, so that after the cover layer has been laminated, the warping of the information recording medium is flattened out.
A characteristic of the thin film layer 202 is that it reflects the reproducing laser beam if the information recording medium is intended to be a ROM. For example, a thin film of a dielectric, a semiconductor, or a metal such as aluminum, silver, gold, silicon, or SiO2 is formed by sputtering, vapor deposition, or another such method.
The configuration of a recording film when the information recording medium is intended for write-once application will now be described through reference to
As for the steps, a cover layer is formed over the signal substrate on which the reflective film or recording film has been formed, but since this step is discussed in detail below, first we will describe the method for recording and reproducing the information recording medium.
Here, the method for recording and reproducing information to and from a multilayer information recording medium, and an example of the mechanism of a recording and reproduction device, will be described through reference to
This drawing shows a state in which an information recording medium 401 has been loaded. This recording and reproduction device has the various devices listed below. A spindle motor 402 mounts and turns the information recording medium 401. A controller 403 executes various kinds of control. A modulator 404 converts the data to be recorded into a recording signal. A laser drive circuit 405 drives a semiconductor laser according to a recording signal. An optical head 406 has a semiconductor laser, converges a laser beam on the medium, and performs the recording of information, and also obtains reproduction signals from reflected light. A pre-amplifier 407 amplifies reproduction signals, and generates an information reproduction signal 407S, a focus error signal 407F, and a tracking error signal 407T. A binarization circuit 408 converts the information reproduction signal 407S into a binary signal. A data demodulation circuit 409 demodulates data from the binary signal. A signal quality determiner 410 determines the quality of a signal obtained by the test recording of specific data in a test recording region of the medium. A recording condition storage unit 411 stores optimal recording conditions obtained by a learning operation. A pulse condition setting unit 412 controls laser pulses according to the above-mentioned recording conditions. A recording track information storage unit 413 stores recording track information read from the information recording medium 401. A focus control circuit 414 controls the optical head 406 on the basis of the focus error signal 407F so that the laser beam will be focused on the recording layer of the information recording medium 401. A tracking control circuit 415 controls the optical head 406 on the basis of the tracking error signal 407T so that the laser beam will properly scan the track of the information recording medium 401. A movement unit 416 moves the optical head 406 in the radial direction of the information recording medium 401.
Here, the focus error signal 407F is generated by a standard method called the astigmatism method. The tracking error signal 407T is generated by a standard method called the push-pull method.
First, in the start-up step, the information recording medium 401 is loaded onto the spindle motor 402 and rotated, after which a laser beam for reproducing information is directed onto the information recording medium 401 by the optical head 406, and focused on the recording layer.
The reproduction of recording track information and so forth is performed by using the data demodulation circuit 409 to demodulate a signal obtained by binarizing the information reproduction signal 407S with the binarization circuit 408, and sending this product to the controller 403. The information reproduction signal 407S is obtained by the optical head 406 from reflected light from the information recording medium 401. The binarization circuit 408 is set to a predetermined binarization slice level. Thus, the recording track information recorded to the information recording medium is read out.
Also, in recording, specific data outputted from the controller 403 is converted by the modulator 404 into a laser drive signal, and the laser drive circuit 405 drives a semiconductor laser disposed at the optical head 406 according to the laser drive signal. The optical head 406 records the signal in the recording region of the information recording medium 401. More specifically, light outputted from the semiconductor laser is converged on the information recording medium 401, and the laser beam tracks the grooves or lands of the track on the basis of the recording track information.
The following method is used to determine whether or not the signal is properly recorded or reproduced to or from the information recording medium 401. A signal obtained by binarizing with the binarization circuit 408 the reproduction signal for data recorded as above is compared with data outputted from the controller 403 during recording.
With a reproduction-only multilayer information recording medium, pits consisting of bumps and recesses and that serve as information are formed on the multilayer information recording medium, and the tracking error signal 407T is reproduced by a standard method called a differential push-pull method. Therefore, the laser beam tracks the string of pits, and only the reproduction of information is performed.
The mechanism by which the reliability of information is lost depending on the presence of surface roughness of the cover layer will be described through reference to
In the drawings, 501 is a signal substrate, which is a substrate on which pits, guide grooves, or another such information face consisting of texturing has been formed on one side. This phenomenon occurs regardless of whether the texturing formed on the signal substrate 501 is pits or guide grooves, but the drawings illustrate a case of guide grooves. In the texturing formed on the signal substrate 501, the portions that are convex as seen from the laser beam incident side are called grooves 503, and the portions that are concave are called lands 502. In the case of a Blu-ray disc, at a disk capacity of 25 GB, the track pitch is about 320 nm. Thus, the length of one set of a groove 503 and a land 502 is about 320 nm. If the sizes of the lands 502 and grooves 503 are substantially the same, the width of a groove is about 160 nm. 509 is a thin-film layer on which the information face of the signal substrate 501 face is formed, and 504 is a cover layer formed over the thin-film layer 509. The cover layer surface is numbered 505. In this drawing, a case is shown in which the cover layer is formed from a single layer of resin. 507 is a laser beam for reproducing or recording information, 506 is a beam spot converged on the thin-film layer 509, and 508 is an objective lens 508 that converges the laser beam 507 on the thin-film layer 509, and is disposed in an ordinary optical head (not described).
The effect of defects in the reproduction of information from an information recording medium will now be described, but the same thing happens during recording.
When a signal is reproduced from an information recording medium, the laser beam 507 is focused on the desired thin-film layer. In the drawing, it is converged on the beam spot 506.
Here, if we follow the path of the laser beam, we see that first the laser beam 507 converged by the objective lens 508 passes through in a luminous energy obtained by multiplying the transmissivity of the cover layer 504 by the amount of incident light. Here, since air and the cover layer 504 have different indexes of refraction, the sine ratio between the laser beam incidence angle and the refraction angle of the cover layer 504 is different.
The wavelength of the laser beam used with a Blu-ray disc is close to 405 nm, and the refractive index with respect to this wavelength is 1.00 in air, while the refractive index used for the cover layer 504 varies with the material, but a resin or a sheet with an index of at least 1.45 and no more than 1.70 is generally used.
The laser beam 507 that has passed through the cover layer 504 is converged on the thin-film layer 509, goes back in the opposite direction from that of the incident light, and is incident on a detector (not shown) that converts the intensity of the light into an electrical signal. The laser beam 507 is reflected by the thin-film layer 509 in a luminous energy obtained by multiplying the reflectivity of the thin-film layer 509 by the emitted luminous energy, and the luminous energy is thereby reduced again by the transmissivity of the cover layer 504. As a result, data is read.
In the recording and reproduction of an information recording medium, the lens is designed so as to minimize various kinds of aberration in order to record and reproduce signals more accurately. Furthermore, a focus control circuit 414 words to reduce the light spot diameter on the thin-film layer 509 in order to reduce variance even with a smaller recording mark.
As in
In
The above is an example of a method for manufacturing a multilayer information recording medium, and a method for the recording and reproduction of information. In the embodiments that follow, a method for manufacturing a cover layer will be described in detail as a specific example of the effect of the invention.
A method for manufacturing the cover layer of the multilayer information recording medium of the present invention will now be described through reference to
When a screen printing apparatus is used to apply the resin, first the setting of the printing apparatus is performed. First, the squeegee 102 is attached to the squeegee fixing jig 101. Here, the bottom face of the squeegee 102 with respect to the table 106 is adjusted so that the degree of parallelism is low. This degree of parallelism affects thickness unevenness of the resin layer in the disk plane, so the lower the degree of parallelism between the squeegee 102 and the table 106, the better.
The squeegee fixing jig 101 is preferably made of a material with excellent rigidity, such as stainless steel. The squeegee 102 is preferably made of a material that is chemically stable with respect to the ultraviolet curing resin 103, and that exhibits rubber-like elasticity. This is because during printing, the squeegee 102 is repeatedly rubbed against the gauze of the screen 104 in a state of being in contact with the ultraviolet curing resin 103.
Next, the screen 104 is put in place. Here again, just as with the squeegee 102, the degree of parallelism with the table 106 is important.
Then, the thin-film layer 108, which contains a recording film material or a reflective film material, is formed on the upper surface of the signal substrate 107 by sputtering, vapor deposition, or another such method on the side on which the information face (pits or guide grooves) is formed. If needed, the opposite side of the signal substrate 107 from the side on which the thin-film layer 108 is formed is fixed on the table 106 by vacuum chucking or other such means.
Meanwhile, the screen 104 is provided so that the film can be formed in a uniform thickness by limiting the amount of ultraviolet curing resin 103 that passes through the openings.
The method for producing the screen 104 will now be described. Gauze that serves as the screen material is stretched over the screen frame 105 and coated with a photosensitive emulsion. Then, a light-blocking mask is placed over everywhere except the specific locations coated with the screen material (locations that form a plurality of holes), and the screen material is irradiated for a specific length of time with ultraviolet rays from an exposure apparatus. The photosensitive emulsion exposed to this ultraviolet ray irradiation is developed by rinsing it with water (such as a water jet), which gives the screen 104.
The relation between the screen and the coated region of the signal substrate will be described through reference to
Wood, aluminum, stainless steel, plastic, or another such material can be used, for example, for a screen frame 601, but aluminum is particularly favorable because of its light weight and high rigidity. The gauze that serves as the screen material can be silk, Nylon®, Tetoron®, V-Screen®, stainless steel, or the like. Since the screen directly touches the surface of the signal substrate, it is preferably made of a pliant material. Accordingly, it is better to use an organic material such as Nylon rather than a metal material such as stainless steel. The photosensitive emulsion can be one obtained, for example, by mixing and dissolving a diazonium salt or a dichromate in a PVA or vinyl acetate emulsion. The mesh count at a specific location of the screen material (the number of lines per inch) is preferably from 50 to 600. If the mesh count is within this range, the screen can be coated with the resin-containing material without encountering problems such as coating unevenness or the resin-containing material not passing through properly. Furthermore, the holes in the screen are not limited to being in mesh form.
In this embodiment, a case is described in which lightweight and highly rigid aluminum is used as the screen frame 601, and V-Screen is used so as to reduce the load on the signal substrate, but the same effect can be obtained using other materials.
If the viscosity of the resin is low, the resin will flow after coating, so the resin will end up bulging out at the end faces or building up. If the resin viscosity is high, it will be difficult for the resin to be transferred through the screen. If we take into account such factors as the effect of decreased resin viscosity due to temperature changes during the process, the viscosity of the resin is preferably between 30 and 10,000 cps.
The range of coating of the signal substrate 606 with the ultraviolet curing resin can be limited by selecting the opening formation region 603 of the screen 604. Thus, in this embodiment, the end position of the resin that is formed can be controlled by varying the boundary between the opening formation region 603 and the portion 602A where the photosensitive emulsion remains on the gauze.
When resin coating is performed by screen printing using the screen 604, the resin coated region is indicated by 606. In this embodiment, the signal substrate 605 is one in which the diameter of the hole 607 is 15 mm, and the outside diameter is 120 mm. The screen 604 is such that the boundary between the portion 602A where the photosensitive emulsion remains on the gauze and the opening formation region 603 is at a diameter of 20 mm, and the boundary between the portion 602B where the photosensitive emulsion remains on the gauze and the opening formation region 603 is at a diameter of 119.8 mm.
As shown in
In
In
In
Thus, with a cover layer composed of the first type of resin layer 110 and the second type of resin layer 117, the center line average roughness of the surface of the second type of resin layer 117 is greater than the center line average roughness of the surface of the first type of resin layer 110.
It is important for a thick-film resin layer of about 80 μm, as in this embodiment, to be formed by screen printing, and, to improve the surface condition, for the viscosity of the first type of resin to be greater than the viscosity of the second type of resin.
Another condition is that when the second resin layer is also formed by screen printing, it is important for the mesh count of the screen used in forming the first resin layer to be less than the mesh count of the screen used in forming the second resin layer.
According to the above conditions, at least half of the desired thickness is formed by the thickness of the first type of resin layer.
Thus, the following outstanding effect is obtained since the mesh count of the screen used in screen printing for forming the second resin layer is greater than the mesh count of the screen used in screen printing for forming the first resin layer. In forming the first resin layer, a thick first resin layer can be formed in a short time by using a coarse screen. In this case, it is effective for the resin to have a higher viscosity. In forming the second resin layer, a resin with a low viscosity is passed through a fine screen. The second resin layer ensures an excellent surface condition. As a result, a stable reproduction signal is obtained with the information recording medium.
The mesh count of the screen used to form the first resin layer is 70, and is preferably between 50 and 80. The mesh count of the screen used to form the second resin layer is 300, and is preferably between 150 and 450.
The thickness of the first resin layer is 80% of the total resin layer, and is preferably at least 50%. More preferably, the thickness of the first resin layer is from 80 to 90% of the total resin layer.
Next, the surface condition of each resin layer will be described. In this embodiment, the center line average roughness Ra of the surface of the first type of resin layer 110 is 14 μm, as mentioned above. This center line average roughness is measured according to standard No. JIS B 0601. In the case of screen printing, this center line average roughness Ra is generally proportional to the coating film thickness. This is because if the goal is to apply a thick coating of the resin layer, a large opening area must be obtained by using a coarse screen that has thick threads.
The resin coating thickness and the mesh shape of the screen will be described through reference to
(resin layer thickness 707)=(spacing width 703 between threads)2×(screen thickness 706)÷(spacing width 703 between threads+thread diameter 704)2
In actual screen printing, not all of the resin injected into the spacing width between threads actually adheres to the substrate and forms a resin layer, so the resin layer is formed on the substrate 709 in a resin volume that is a certain percentage lower than what is calculated from the formula. Thus, if the goal is to increase the thickness 707 of the resin layer, it is better to use a screen with a greater thickness 706, that is, a greater thread diameter 704.
Also, the resin layer tends not to be formed where the screen threads 701 and the substrate 709 are in contact, and the resin layer is instead formed where the substrate 709 is in contact with the spaces 705 between threads. Therefore, the texturing on the surface of the resin layer 708 that is formed closely reflects this screen shape. That is, when a screen with a large thread diameter 704 is used, there will be a larger surface area over which it is difficult to form a resin layer on the substrate, and the thickness 706 of the screen will increase. As a result, a greater volume of resin will be encompassed within the spacing width between threads, so the texturing width of the resin layer 708 that is formed will be greater.
In other words, when screen printing is used to form a thick resin layer, there is greater surface texturing of the resin layer that is formed. Accordingly, this is not suited to the formation of resin layers that need to have very good surface condition, such as the resin layer on the side where a laser beam is incident on a Blu-ray disc or the like.
In view of this, just as in this embodiment, two or more resin layers of different viscosity are used, so that even though the surface condition is poor with the first layer, it does provide resin layer thickness, and a second resin layer with a lower viscosity is formed for the sake of leveling, which improves the surface condition of the first layer. As a result, it is possible to ensure the desired surface condition of the resin layer.
Two kinds of ultraviolet curing resin were used in this embodiment, but the following problems are assumed. When the laser beam is incident and a signal is recorded or reproduced, the laser beam passes through the interface between the two ultraviolet curing resins. If the two kinds of ultraviolet curing resin here have greatly different indexes of refraction, then the laser beam will be scattered at the interface between the two ultraviolet curing resins, resulting in a loss of energy of the outputted laser beam. Accordingly, this leads to problems such as the inability to record a distinct mark during recording. To avoid these problems, it is preferable if the difference between the indexes of refraction of the two kinds of ultraviolet curing resin is as small as possible with respect to the wavelength of the laser beam used for recording and reproduction. At the least, it is preferable is the difference between the indexes of refraction of the two kinds of ultraviolet curing resin with respect to the wavelength of the laser beam used for recording and reproduction is 0.1 or less.
In this embodiment, just as in Embodiment 1, the step of forming two types of ultraviolet curing resin is described. The difference from Embodiment 1 is the method for curing the first resin layer. In this embodiment, the surface condition of the first layer of ultraviolet curing resin is improved by affixing a substrate with an excellent surface condition in a vacuum atmosphere after the first layer of ultraviolet curing resin has been formed by screen printing. Also, in this embodiment spin coating, rather than screen printing, is used to product the second layer of ultraviolet curing resin. In spin coating, the ultraviolet curing resin is dripped onto the inner peripheral part of the substrate, and the substrate is spun to spread out the ultraviolet curing resin from the inner peripheral part.
The affixing method for improving the surface condition of the first layer of ultraviolet curing resin will be described through reference to
Since the resin layer 803 has to be cured through the transfer substrate 806 in the ultraviolet ray irradiation ray (a subsequent step), the transfer substrate 806 preferably has high transmissivity to ultraviolet rays. Therefore, it is preferably made from a thin polycarbonate material or acrylic material, or from a quartz glass material or the like that has high transmissivity to ultraviolet rays, for example.
Next, in
After the affixing step is completed, the inside of the vacuum chamber 808 is returned to atmospheric pressure, and the affixed signal substrate 801 and transfer substrate 806 are taken out of the vacuum chamber 808. As shown in
As shown in
A spinning step will now be described as the step of applying the second type of ultraviolet curing resin.
In
In this embodiment, a method is employed in which the surface condition of the first layer of ultraviolet curing resin is improved by affixing a substrate with an excellent surface condition in a vacuum atmosphere after the first layer of ultraviolet curing resin has been formed by screen printing, so the center line average roughness of the surface of the first type of resin layer 904 is lower than that in Embodiment 1. Therefore, either the center line average roughness of the surface of the second type of resin layer 907 is lower, or the conditions will be less stringent for obtaining the same surface center line average roughness.
Thus, with a cover layer composed of the first type of resin layer 904 and the second type of resin layer 907, the center line average roughness of the surface of the second type of resin layer 907 is lower than the center line average roughness of the surface of the first type of resin layer 904.
In this embodiment, the process of forming two ultraviolet curing resins is described just as in Embodiment 1, but inkjetting will be used to produce the second type of ultraviolet curing resin.
Just as in Embodiments 1 and 2, a recording film is coated with a first type of ultraviolet curing resin, and then cured by being irradiated with ultraviolet rays. With inkjetting, as shown in
With this embodiment, the mesh count of the screen is 50 lines per inch, and a first type of ultraviolet curing resin with a viscosity of 2500 cps is used, and is applied in a thickness of 80 μm so as to cover the recording film. Also, with inkjetting, an ultraviolet curing resin with a viscosity of 3 cps is used, and a second type of ultraviolet curing resin is formed in a thickness of 20 μm so as to cover the first type of ultraviolet curing resin.
In this embodiment, an optical information recording medium with a single-layer structure is used as an example, but the same applies to an information recording medium with a multilayer structure in which there are a plurality of recording layers, and resin layers are formed in between the recording layers.
The first signal substrate 1001 is formed from a disk of polycarbonate or acrylic resin with an outside diameter of 120 mm and a thickness of about 1.0 to 1.1 mm, and has an information face such as pits or guide grooves formed on one side by injection compression molding or other such resin molding, so that the information recording medium will have good rigidity and be resistant to warping, and so that there will be good thickness interchangeability with CD's, DVD's, Blu-ray discs, and other such optical disks. A center hole (not shown) with a diameter of 15 mm is provided in the center part of the substrate and is used to hold and rotate the disk when a player records and reproduces a signal. The use of polycarbonate is described as a typical example in this embodiment.
The second signal substrate 1003, the third signal substrate 1005, and the fourth signal substrate 1007, which are intermediate layers composed of photosensitive resin materials, and the transparent layer 1009 are formed by lamination over the first signal substrate 1001. Accordingly, photosensitive contraction, which is a characteristic feature of photosensitive resins, causes the shape of the information recording medium after lamination to warp into a concave form when the information face is on top, for example. Therefore, to deal with warping of the first signal substrate 1001, the information face is put on top and formed warped in a convex shape ahead of time. As a result, after the second signal substrate 1003, the third signal substrate 1005, the fourth signal substrate 1007, and the transparent layer 1009 have been laminated, the warping of the information recording medium is flattened out.
A characteristic of the first thin-film layer 1002, the second thin-film layer 1004, and the third thin-film layer 1006 is that they reflect the reproducing laser beam if the information recording medium is intended to be a ROM. For example, a thin film of a dielectric, a semiconductor, or a metal such as aluminum, silver, gold, silicon, or SiO2 is formed by sputtering, vapor deposition, or another such method.
The configuration of a recording film when the information recording medium is intended for write-once application will now be described through reference to
The second signal substrate 1003 is formed, for example, from an ultraviolet curing resin whose main component is acrylic, and which is substantially transparent (transmissive) with respect to the recording and reproduction light. Since ultraviolet curing resins have the following two characteristics, they are effective in terms of controlling the shape of the resin layers. First, since an ultraviolet curing resin has its curing light wavelength in the ultraviolet region, this prevents the resin from being cured by wavelengths other than ultraviolet rays. Second, an ultraviolet curing resin can be cured by irradiating it with ultraviolet rays whenever the opportunity presents itself. In this embodiment, after the first thin-film layer 1002 has been coated with the liquid ultraviolet curing resin, a signal transfer substrate, such as a substrate having an information face such as pits or guide grooves, is pressed against the coating. After this, the ultraviolet curing resin is cured by being irradiated with ultraviolet rays, and finally the signal transfer substrate is separated at the interface with the ultraviolet curing resin, thereby forming the second signal substrate 1003. The ultraviolet curing resin coating is formed smaller than the outside diameter of the first signal substrate 1001 and larger than the center hole in the first signal substrate 1001 (not shown). The third signal substrate 1005 and the fourth signal substrate 1007 are formed in the same shape and by the same method as the second signal substrate 1003 discussed above. The transparent layer 1009 is formed from an ultraviolet curing resin whose main component is acrylic, and which is substantially transparent (transmissive) with respect to the recording and reproduction light. The ultraviolet curing resin is used in liquid form, and is applied over the fourth thin-film layer 1008. The ultraviolet curing resins are formed so as to cover the various signal substrates and thin-film layers, and to be bonded to the first signal substrate at the inner peripheral part and outer peripheral part.
Again with a recording medium with multiple recording layers, if a conventional optical disk structure is employed, the length from the outermost surface of the transparent layer 1009 to the first thin-film layer 1002 is preferably about 100 μm. In this case, if we assume the minimum thickness of the second signal substrate 1003, the third signal substrate 1005, and the fourth signal substrate 1007 for the purpose of separating the thin-film layers, then the thickness of the resin layer of the transparent layer 1009 is to be 60 μm or less.
The method for forming the transparent layer 1009 in this embodiment will be described. This formation method can also be applied to the formation of the first signal substrate 1001, the second signal substrate 1003, the third signal substrate 1005, and the fourth signal substrate 1007. In particular, since the second signal substrate 1003, the third signal substrate 1005, and the fourth signal substrate 1007 have a thickness of about 10 μm, it is effective to use screen printing to form the first resin layer.
When the resin is applied with a screen printing apparatus, first the printing apparatus setup is performed. The squeegee 102 is attached to the squeegee fixing jig 101. At this point the squeegee 102 is adjusted so that its degree of parallelism with respect to the table 106 is low. This degree of parallelism affects the thickness unevenness of the resin layers in the disk plane, so the lower is the degree of parallelism between the squeegee 102 and the table 106, the better. Also, the squeegee fixing jig 101 is preferably made of a material with excellent rigidity, such as stainless steel.
The squeegee 102 is preferably made of a material that is chemical stable with respect to the ultraviolet curing resin 103, and that exhibits rubber-like elasticity. This is because during printing, the squeegee 102 is repeatedly rubbed against the gauze of the screen 104 in a state of being in contact with the ultraviolet curing resin 103.
Next, the screen 104 is put in place. Here again, just as with the squeegee 102, the degree of parallelism with the table 106 is important.
Then, information layers containing a recording film material or reflective film material are formed on the upper surface of the signal substrate 107 by sputtering, vapor deposition, or another such method on the side on which the information face (pits or guide grooves) is formed, with an intermediate layer sandwiched in between, thus the multilayer thin-film layer 108′ is formed. If needed, the opposite side from the side on which the multilayer thin-film layer 108′ is formed is fixed on the table 106 by vacuum chucking or other such means.
Meanwhile, the screen 104 is provided so that the film can be formed in a uniform thickness by limiting the amount of ultraviolet curing resin 103 that passes through the openings.
The method for producing the screen 104 will not be described, since it is the same as what was discussed above. Nor will the relation between the screen and the coated region of the signal substrate be described, since it is the same as in the above embodiment.
As shown in
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In
Thus, with a cover layer composed of the first type of resin layer 110 and the second type of resin layer 117, the center line average roughness of the surface of the second type of resin layer 117 is less than the center line average roughness of the surface of the first type of resin layer 110.
It is important for a thick-film resin layer of about 60 μm, as in this embodiment, to be formed by screen printing, and, to improve the surface condition, for the viscosity of the first type of resin to be greater than the viscosity of the second type of resin.
Another condition is that when the second resin layer is also formed by screen printing, it is important for the mesh count of the screen used in forming the first resin layer to be less than the mesh count of the screen used in forming the second resin layer.
According to the above conditions, at least half of the desired thickness is formed by the thickness of the first type of resin layer.
Next, the surface condition of each resin layer will be described. In this embodiment, the center line average roughness Ra of the surface of the first type of resin layer 110 is 14 μm, as mentioned above. This center line average roughness is measured according to standard No. JIS B 0601. In the case of screen printing, this center line average roughness Ra is generally proportional to the coating film thickness. This is because if the goal is to apply a thick coating of the resin layer, a large opening area must be obtained by using a coarse screen that has thick threads.
The resin coating thickness and the mesh shape of the screen are the same as in the above embodiments, and therefore will not be described again. The effect of this embodiment is also the same as that in the above embodiments.
Embodiments of the present invention were described above, but the present invention is not limited to or by these embodiments, and various modifications are possible without departing from the gist of the invention.
In Embodiment 2, a method is disclosed in which the surface condition of a first layer of ultraviolet curing resin is improved by forming the first layer of ultraviolet curing resin by screen printing, and then affixing a substrate with an excellent surface condition in a vacuum atmosphere. This method can also be applied to a combination of screen printing and screen printing (Embodiment 1), or a combination of screen printing and inkjetting (Embodiment 3).
In Embodiment 4, screen printing and screen printing are combined to produce a signal substrate that is an intermediate layer, and not just a cover layer. A combination of screen printing and spin coating (Embodiment 2) or a combination of screen printing and inkjetting (Embodiment 3) may also be used to produce a signal substrate that is an intermediate layer.
In the above embodiments, a cover layer or an intermediate layer is formed by two resin application steps, but the resin application step may be performed three or more times, in which case two or more types of ultraviolet curing resin may be used. In this case, the viscosity of the resin that is applied last is preferably lower than the viscosity of the other resins, and must be lower than the viscosity of the resin applied first. As a result, the center line average roughness of the outermost resin layer will be lower than the center line average roughness of the first resin layer surface.
Alternatively, the above-mentioned effect will also be obtained when the center line average roughness of the surface of the first resin layer to be formed on the information recording layer is greater than the center line average roughness of the surface of the resin layers besides the first resin layer. It is particularly favorable for the center line average roughness of the first resin layer surface to be greater than the center line average roughness of the outermost resin layer.
The multilayer recording medium and method for manufacturing the same pertaining to the present invention make it possible to manufacture a multilayer recording medium with few defects at high speed, and are useful as a multilayer recording medium with which a large volume of information can be reproduced accurately, a means for applying a liquid resin uniformly, and so forth. The invention can also be applied to the manufacture of a large-capacity memory and other such applications.
Number | Date | Country | Kind |
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2007-301489 | Nov 2007 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2008/003045 | 10/27/2008 | WO | 00 | 5/18/2010 |