The present invention is directed generally to injection molding methods and machines and more particularly to a device and method for reducing the leakage of liquid past the piston in an injection molding machine.
One conventional method used to produce molded metal alloys is the die cast method. In this method, the metal to be injected is heated above its liquidus temperature and then forced into the mold by the extension of a piston in the injection chamber. Another conventional method is the thixotropic injection molding method. In this method, the metal is first heated to a thixotropic state rather than to a completely liquid state, and then injected into a mold from an injection chamber. In this method, a screw rather than a piston is often used to inject the metal into the mold. The piston and the screw contain a shaft portion, which is attached to a drive mechanism. The drive mechanism is typically a motor, however, hydraulic mechanisms have also been used.
Although conventional liquid metal injection molding and thixotropic metal injection molding have been used successfully in the past, conventional machines suffer from metal leaking backwards past the piston or screw into the drive mechanism, rather than being injected forward into the mold. This occurs because high pressure is required to force the metal completely into the mold and it impossible to manufacture an apparatus without some clearance between the piston or screw and the inner wall of the injection chamber. Thus, the metal is forced past the piston or screw into the shaft housing. Some of this metal may reach the driving mechanism of the piston or screw and damage it. Thus, a device reducing the leakage of metal to the rear of the shaft housing in the injection molding of liquid and thixotropic metals is desired.
A preferred embodiment present invention provides an injection molding apparatus, comprising an injection chamber, an injection member comprising a head and a shaft located in the injection chamber, and at least one protrusion adjacent to the shaft.
Another preferred embodiment of the present invention provides an injection molding apparatus, comprising an injection chamber comprising a shaft housing portion having a polygonal internal cross section, and an injection member comprising a head and a shaft located in the injection chamber.
Another preferred embodiment of the present invention provides an injection molding apparatus, comprising an injection chamber comprising an accumulation portion and a shaft housing portion, at least one opening in a side wall of the shaft housing portion of the injection chamber, and an injection member comprising a head and a shaft located in the injection chamber.
Another preferred embodiment of the present invention provides an injection molding apparatus, comprising an injection chamber comprising an accumulation portion and a shaft housing portion, an injection member comprising a head and a shaft located in the injection chamber, a first means for heating the accumulation portion of the injection chamber to a first temperature above a liquidus temperature of a metal injected by the injection member, and a second means for heating the shaft housing portion of the injection chamber to a second temperature below a liquidus temperature of the metal injected by the injection member.
Another preferred embodiment of the present invention provides an injection molding apparatus, comprising a piston comprising a head and a shaft, the shaft having a diameter smaller than a diameter of the head, a first injection chamber portion having a front end, a back end and a cavity having a circular internal cross section and containing the piston head. The apparatus further comprises a second injection chamber portion joined to the back end of the first chamber portion, the second chamber portion having a front end, a back end and a cavity having a polygonal internal cross section and containing the piston shaft, at least one opening in at least one side wall of the second injection chamber portion, and at least one piston ring circumscribing the piston shaft.
Another preferred embodiment of the present invention provides a method of making an injection molded metal part, comprising providing a metal into an accumulation portion of an injection chamber, maintaining the accumulation portion of the injection chamber at a first temperature above the liquidus temperature of the metal, maintaining a shaft portion of the injection chamber at a second temperature below the liquidus temperature of the metal, and advancing an injection member having a head and a shaft in the injection chamber to inject the metal from the accumulation portion into a mold cavity.
The foregoing and other features, aspects and advantages of the present invention will become apparent from the following description, appended claims and the exemplary embodiments shown in the drawings, which are briefly described below. It should be noted that unless otherwise specified like elements have the same reference numbers.
a is a schematic side cross sectional view of an apparatus according to a first preferred embodiment of the invention.
b is schematic cross sectional view according to another aspect of the first embodiment of the invention.
a is a perspective view of an apparatus according to another preferred embodiment of the invention.
b is a perspective view of an alternative aspect of a portion of the apparatus illustrated in
c is a side cross sectional view of an alternative aspect of the apparatus illustrated in
The present inventor has discovered several features which either singly or in combination reduce the amount of metal flowing through the shaft housing into the drive mechanism. These features provide significant protection for the drive mechanism and extend the life of the injection molding apparatus. These features include shaft rings, openings in the shaft housing, a shaft housing having a polygonal cross section, and maintaining the shaft housing at a lower temperature than the metal accumulation portion of the injection chamber.
a illustrates an injection chamber 50 of an injection molding apparatus. Preferably, the apparatus is used to inject a metal into a mold. Preferably the metal is injected in the liquid state. However, if desired, the apparatus may also be adapted to inject metal in the thixotropic state or even plastic into a mold cavity. The material to be injected, such as a liquid or thixotropic metal, enters the injection chamber through an entry opening 51. The opening 51 may be a passageway connected to another chamber of the injection molding apparatus which provides liquid or thixotropic metal. The opening 51 may also be a direct passageway to a hopper which provides solid metal particles into the injection chamber. Alternatively, the opening 51 may be an opening in the top of the injection molding apparatus through which the metal in the liquid, thixotropic or solid state is provided.
The injection chamber contains an injection member, which injects the metal present in the injection chamber 50 into a mold cavity through a nozzle aperture 57. Preferably, the injection member comprises a piston or plunger 45. The piston 45 has a head 80, a spacer 81, and a shaft 82. Preferably, the head 80 and the spacer 81 have the same diameter, while the shaft 82 has a smaller diameter. In the most preferred embodiment of the invention, the head 80 is removable from the spacer 81 and can be easily replaced when worn. However, the head 80 and the spacer 81 may be formed integrally.
Typically, the head 80 has a diameter slightly smaller than the inner diameter of the injection chamber 50. The head 80 is used to push the metal from the injection chamber 50 out through the nozzle aperture 57. Circumscribing the head 80 are one or more seals 41. The piston head 80 is attached to a spacer 81 which has the same diameter as the piston head 80. A piston shaft is connected to the other side of the spacer 81. The piston shaft 82 has a diameter smaller than the spacer 81. The shaft 82 is connected to a drive mechanism 47 which is used to move the piston 45 back and forth in the injection chamber 50. The drive mechanism may be a motor or a hydraulic mechanism. The diameter of the piston shaft 82 may be selected to optimize leakage reduction. Factors which may effect the choice of diameter include, but are not limited to, the metal to be injected, the casting temperature, and the casting pressure.
In an alternative aspect of the present invention, the injection member comprises a screw. The screw contains a head portion which is the threaded portion which advances the metal in the injection chamber forward, and a shaft portion which is connected to the screw drive mechanism.
In a first preferred embodiment of the present invention, at least one protrusion or ridge is present on or adjacent to the shaft 82 to reduce the amount of metal flowing past the piston head 80 into the piston drive mechanism 47. Preferably, the protrusion or ridge is shaped as a ring 60, as shown in
The diameter and width of each piston ring 60 is preferably similar to the diameter and width of the piston head 80. However the width of the rings 60 may be varied to be either greater or smaller than that of the piston head 80. The spacing between the piston head 80 and the first piston ring 60 is preferably about 0.5 to 2 mm, most preferably about 1 mm, but may be varied as necessary. If more than one piston ring is used, the spacing between successive piston rings is preferably about 0.5 to 2 mm, most preferably about 1 mm, but may be varied as necessary.
Another preferred aspect of the first embodiment of the invention is illustrated in
In another alternative, and less preferred aspect of the first embodiment, the rings 60 are attached to or comprise portions of the injection chamber (i.e., protrusions on the inner wall of the injection chamber). In this case, the rings 60 are positioned in the shaft housing portion of the injection chamber 50 and do not move with the shaft. In this aspect of the invention, the shaft 82 has a smaller outer diameter than the inner diameter of the rings 60. If desired, the rings 60 may be located both on the shaft and on the inner wall of the injection chamber. In this case, the outer diameter of the shaft rings should be smaller than the inner diameter of the chamber rings to allow the shaft rings to move with the shaft through the chamber rings.
The method by which the piston rings reduce the flow of metal to the rear of the injection chamber 50 is not known with certainty. While not wishing to be bound by any theory of operation, it is believed that some of the liquid or thixotropic metal gets temporarily trapped in the space between the spacer 81 and the first ring and in the space between the rings 60, where the metal viscosity increases. In some cases, solid metal then falls off the shaft 82 and is pulverized into harmless dust by the movement of the shaft 82. In other cases, rings 60 prevent high viscosity metal from leaking past the rings.
In a second preferred embodiment of the present invention, the injection chamber 50 has different portions having different cross sectional shapes. The first chamber portion 52, referred to as the accumulation portion, has an internal cavity 53 with a generally circular cross section. This portion 52 of the injection chamber 50 preferably extends from the injection nozzle 57 at least up to the position of the head 80 of the piston 45, when the piston is in the fully retracted position. The accumulation portion may extend beyond the position of the fully retracted head 80 of the piston, as shown in
Adjacent to the rear of the accumulation portion 52 is a second chamber portion (shaft housing) 54 which has an internal cavity 58 with a generally polygonal cross section. The second portion 54, referred to as the shaft housing, preferably extends from the piston drive mechanism to at least a location behind the position of the head 80 of the piston 45, when the piston is in the fully retracted position, as shown in
Spanning the rear portion of the shaft housing 54 and the housing of the drive mechanism 47 is a window 46. Through this window 47, technicians can monitor leakage of metal through the shaft housing 54 toward the drive mechanism 47. Additionally, the window allows access to the drive mechanism 47. Thus, adjustments and minor repairs can be made to the drive mechanism 47 without disassembling the drive mechanism 47.
The first 52 and second 54 injection chamber 50 portions may comprise different vessels attached to each other. Optionally, an insulating gasket 56 is provided in between the first chamber portion 52 and the second chamber portion 54. Alternatively, the first 52 and second 54 portions of the injection chamber 50 may comprise portions of the same vessel (i.e., having a continuous outer side wall between portions 52 and 54), but having different internal cross sections.
The injection chamber 50 is preferably made of steel. However, it may be made of any structural material suitable for the injection molding of metals. Other materials include, but are not limited to, superalloys, nickel alloys, cobalt alloys, and titanium alloys. The insulator material of the gasket 56 is preferably made of asbestos, a heat insulating ceramic or any other suitable heat resistant material.
a illustrates one preferred design of the shaft housing 254 of an injection chamber 250 according to the second preferred embodiment of the invention. In the preferred aspect shown in
At either end of the shaft housing 254, there are flanges 262. One of the flanges can be attached to a corresponding flange on the end of the accumulation portion 52 of the injection chamber 50. The other flange may be attached to the drive mechanism 47. The flanges may be bolted, welded, clamped or affixed in any suitable manner. If an optional insulating gasket 56 is included, it is preferable to bolt the chambers together. A shaft hole 264 is included in the flanges 262. In this aspect of the invention, the shaft hole 264 is square.
At either end of the shaft housing 354 there are flanges 362. The flanges may be bolted, welded, clamped or affixed in any suitable manner. If an optional insulating gasket 56 is included, it is preferable to bolt the chamber portions together. The shaft holes 364 are included in the flanges 362. The shaft hole may be of any shape including, for example, circular rectangular, hexagonal and octagonal.
The shaft housing having a rectangular internal cross section contains the cylindrical shaft 82. Thus, empty space is provided at the corners of the polygonal shaft housing. Without wishing to be bound by specific theory of operation, it is believed that the liquid or thixotropic metal accumulates and solidifies in these empty space prior to entering the drive mechanism. Thus, the amount of metal entering the drive mechanism is reduced.
According to a third preferred embodiment of the present invention, the amount of metal leaking into the drive mechanism is reduced by providing at least one opening in the side walls of the shaft housing. The openings allow air to enter the shaft housing. As shown in
The openings 266 provide at least two benefits. First, they allow cooling air to enter and solidify molten metal which managed to get past the piston head 80 and rings 60. Second, they are sufficiently unobstructed and have a sufficient size to allow the undesirable molten metal or solidified metal dust or particles (i.e., the metal that was supposed to be injected, but which entered the shaft housing instead) to exit out of the shaft housing 254, 354. Thus, the amount of molten metal which enters the drive mechanism 47 is reduced.
If desired, the openings 266 may be used in conjunction with the protrusions or rings 260 formed on the inner side wall of the shaft housing 254, as shown in
According to a fourth embodiment of the present invention, the injection chamber 50 is divided into two temperature zones 90, 92. The first temperature zone extends approximately from the injection nozzle 57 of the injection chamber 50 to the back of the head 80 of the piston 45 when the piston is in a fully retracted state. The second temperature zone extends approximately from the back of the head of the piston when the piston is in a fully retracted state to the back end of the injection chamber 50. In a preferred aspect of the fourth embodiment, the first temperature zone corresponds to the accumulation portion 52 of the injection chamber, while the second temperature zone corresponds to the shaft housing 54. However, as illustrated in
As shown in
It should be noted that the features of the preferred embodiments of the present invention may be used alone or in any combination. Thus, all four features comprising piston rings, polygonal cross section in the shaft housing, openings in the shaft housing and below liquidus temperature in the second (i.e., rear) temperature zone may be used together, separately or in any combination of two or three features.
In a preferred aspect of the invention, the feeder 23 further contains an outlet screening element 24. For example, as illustrated in
The feeder 23 may contain an atmosphere of an inert gas to minimize oxidizing of the pre-heated and melted metal. A mixture of carbon dioxide (CO2) and sulfur fluoride (SF6) gas is preferred. However, other gasses, such as CO2, SF6, nitrogen or argon may be used alone or in any combination with each other. The inert gas may be introduced (e.g. from a pressurized tank) into the feeder 23 through port 11 to create an inert gas atmosphere above the bath.
The melted metal is subsequently supplied into a temperature-controlled barrel 30 by way of gravity through a feeder port 27 which may optionally be supplied with a valve serving as a stopper (not shown). Preferably, no valve is present. The temperature is controlled with heating elements 70a-70e. A ram 32 is arranged coaxially with the barrel 30 and extends along the center axis of the barrel 30. The outer diameter of the ram 32 is smaller than the inner diameter of the barrel 30 such that melted metal flows in the space between the ram 32 and the barrel 30. The ram 32 is controlled by motor 33 for axial movement in both retracting and advancing directions along the barrel 30 and for rotation around its own axis if stirring of the melted metal is desired inside barrel 30. If desired, the ram 32 may optionally contain fins which stabilize the ram 32 and which assist in stirring the metal present in the barrel 30.
The ram 32 shown in
After piston 45 is stopped, the ram 32 is advanced downward, and, as a result, a portion of the metal collected in the lower portion of barrel 30 is pushed into the injection chamber 50 through the outlet port 37. The pressure of the metal entering into injection chamber 50 assists in driving out gas present in the injection chamber 50 that accumulates between the melted metal and piston 45. The ram 32 preferably advances through barrel 30 until its end closes off outlet port 37, and the ram 32 preferably remains in this position to keep outlet port 37 sealed off until injection is complete and the next shot is started.
Simultaneously, the piston 45 is pushed to the left, relative to the injection chamber 50, to force the melted metal in the injection chamber 50 through the die 14 into a mold cavity 13. This further increases the pressure in injection chamber 50. Although most of the metal is pushed into the die, the pressure causes some of the metal to flow backwards, past seals 41. By utilizing the features of any one or more preferred embodiments of the present invention, the amount of metal which gets into the drive mechanism 47 is reduced. Thus, the injection chamber 50 contains any one or more of the following: piston rings, polygonal cross section in the shaft housing, openings in the shaft housing and below liquidus temperature in the second (i.e., rear) temperature zone.
Heating elements referenced and prefixed by the numeral 70 are preferably resistance heating elements, but may be inductive heating elements. For the AZ91 Mg alloy, heating elements 25 are preferably controlled so that the temperature in the feeder 23 is between about 630° C. and about 670° C. In the barrel 30, the temperature near the heating elements 70a-e is preferably maintained between about 610 and about 660° C. for the AZ91 Mg alloy.
In the injection chamber 50, the temperature near heating elements 70g, 70h, 70i, and 70j is preferably maintained between about 620° C. and about 705° C., preferably between about 635° C. and about 685° C. for the AZ91 Mg alloy. These temperatures are sufficiently high to maintain the melted metal entirely in the liquid state from the time it exits the feeder 23 into the barrel 30 to the time the melted metal is injected into the mold 14 from the injection chamber 50. The temperature near heating elements 70f, 70k and 70m is preferably maintained below the liquidus temperature of the metal, such as at about 550° C. to about 600° C., preferably at about 560° C. to about 580° C. for the AZ91 Mg alloy. The lower temperature behind the seal 41 helps prevent the metal from flowing past the seal 41.
The foregoing description of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed, and modifications and variations are possible in light of the above teachings or may be acquired from practice of the invention. The drawings and description were chosen in order to explain the principles of the invention and its practical application. It is intended that the scope of the invention be defined by the claims appended hereto, and their equivalents.
This application is a continuation-in-part of application Ser. No. 09/842,092, filed Apr. 26, 2001, which is a divisional of application Ser. No. 09/330,147, filed Jun. 11, 1999, which is a divisional application Ser. No. 09/160,792, filed Sep. 25, 1998, now U.S. Pat. No. 5,983,976, which claims the benefit of U.S. Provisional Application No. 60/080,078, filed Mar. 31, 1998, which are hereby incorporated by reference in their entirety.
Number | Name | Date | Kind |
---|---|---|---|
2386966 | MacMillin | Oct 1945 | A |
2505540 | Goldhard | Apr 1950 | A |
2529146 | Feitl | Nov 1950 | A |
2785448 | Hodler | Mar 1957 | A |
3048892 | Davis, Jr. et al. | Aug 1962 | A |
3106002 | Bauer | Oct 1963 | A |
3123875 | Madwed | Mar 1964 | A |
3172174 | Johnson | Mar 1965 | A |
3189945 | Strauss | Jun 1965 | A |
3201836 | Nyselius | Aug 1965 | A |
3254377 | Morton | Jun 1966 | A |
3268960 | Morton | Aug 1966 | A |
3270378 | Madwed | Sep 1966 | A |
3270383 | Hall et al. | Sep 1966 | A |
3286960 | Hall et al. | Nov 1966 | A |
3319702 | Hartwig et al. | May 1967 | A |
3344848 | Hall et al. | Oct 1967 | A |
3447593 | Nyselius et al. | Jun 1969 | A |
3474854 | Mace | Oct 1969 | A |
3491827 | Mace | Jan 1970 | A |
3529814 | Werner | Sep 1970 | A |
3550207 | Strauss | Dec 1970 | A |
3693702 | Piekenbrink et al. | Sep 1972 | A |
3773873 | Spaak et al. | Nov 1973 | A |
3810505 | Cross | May 1974 | A |
3814170 | Kahn | Jun 1974 | A |
3819313 | Josephsen et al. | Jun 1974 | A |
3874207 | Lemelson | Apr 1975 | A |
3893792 | Laczko | Jul 1975 | A |
3902544 | Flemings et al. | Sep 1975 | A |
3936298 | Mehrabian et al. | Feb 1976 | A |
3976118 | Kahn | Aug 1976 | A |
4049040 | Lynch | Sep 1977 | A |
4088178 | Ueno et al. | May 1978 | A |
4168789 | Deshais et al. | Sep 1979 | A |
4212625 | Shutt | Jul 1980 | A |
4287935 | Ueno et al. | Sep 1981 | A |
4330026 | Fink | May 1982 | A |
4347889 | Komatsu et al. | Sep 1982 | A |
4387834 | Bishop | Jun 1983 | A |
4434839 | Vogel | Mar 1984 | A |
4436140 | Ebisawa et al. | Mar 1984 | A |
4473103 | Kenney et al. | Sep 1984 | A |
4476912 | Harvill | Oct 1984 | A |
4510987 | Collot | Apr 1985 | A |
4534403 | Harvill | Aug 1985 | A |
4537242 | Pryor et al. | Aug 1985 | A |
4559991 | Motomura et al. | Dec 1985 | A |
4586560 | Ikeya et al. | May 1986 | A |
4635706 | Behrens | Jan 1987 | A |
4687042 | Young | Aug 1987 | A |
4694881 | Busk | Sep 1987 | A |
4694882 | Busk | Sep 1987 | A |
4714423 | Hattori et al. | Dec 1987 | A |
4730658 | Nakano | Mar 1988 | A |
4732206 | Hildreth et al. | Mar 1988 | A |
4771818 | Kenney | Sep 1988 | A |
4820787 | Kataoka et al. | Apr 1989 | A |
4828460 | Saito et al. | May 1989 | A |
4834166 | Nakano | May 1989 | A |
4884621 | Ban et al. | Dec 1989 | A |
4898714 | Urban et al. | Feb 1990 | A |
4952364 | Matsuda et al. | Aug 1990 | A |
4997027 | Akimoto | Mar 1991 | A |
5040589 | Bradley et al. | Aug 1991 | A |
5109914 | Kidd et al. | May 1992 | A |
5143141 | Frulla | Sep 1992 | A |
5144998 | Hirai et al. | Sep 1992 | A |
5161598 | Iwamoto et al. | Nov 1992 | A |
5181551 | Kidd et al. | Jan 1993 | A |
5186236 | Gabathuler et al. | Feb 1993 | A |
5191929 | Kubota et al. | Mar 1993 | A |
5205338 | Shimmell | Apr 1993 | A |
5244033 | Ueno | Sep 1993 | A |
5375645 | Brueker et al. | Dec 1994 | A |
5380187 | Fujikawa | Jan 1995 | A |
5388633 | Mercer, II et al. | Feb 1995 | A |
5394931 | Shiina et al. | Mar 1995 | A |
5413644 | Marder et al. | May 1995 | A |
5501266 | Wang et al. | Mar 1996 | A |
5531261 | Yoshida et al. | Jul 1996 | A |
5533562 | Moschini et al. | Jul 1996 | A |
5571346 | Bergsma | Nov 1996 | A |
5575325 | Sugiura et al. | Nov 1996 | A |
5577546 | Kjar et al. | Nov 1996 | A |
5601136 | Shimmell | Feb 1997 | A |
5622216 | Brown | Apr 1997 | A |
5623984 | Nozaki et al. | Apr 1997 | A |
5630463 | Shimmell | May 1997 | A |
5630466 | Garat et al. | May 1997 | A |
5632321 | Hegel et al. | May 1997 | A |
5638889 | Sugiura et al. | Jun 1997 | A |
5657812 | Walter et al. | Aug 1997 | A |
5662159 | Iwamoto et al. | Sep 1997 | A |
5664618 | Kai et al. | Sep 1997 | A |
5665302 | Benni et al. | Sep 1997 | A |
5680894 | Kilbert | Oct 1997 | A |
5685357 | Kato et al. | Nov 1997 | A |
5697422 | Righi et al. | Dec 1997 | A |
5697425 | Nanba et al. | Dec 1997 | A |
5701942 | Adachi et al. | Dec 1997 | A |
5704411 | Suzuki et al. | Jan 1998 | A |
5716467 | Marder et al. | Feb 1998 | A |
5730198 | Sircar | Mar 1998 | A |
5730202 | Shimmell | Mar 1998 | A |
5735333 | Nagawa | Apr 1998 | A |
5770245 | Takizawa et al. | Jun 1998 | A |
5836372 | Kono | Nov 1998 | A |
5839497 | Fujino et al. | Nov 1998 | A |
5861182 | Takizawa et al. | Jan 1999 | A |
5913353 | Riley et al. | Jun 1999 | A |
5983976 | Kono | Nov 1999 | A |
6059012 | Vining et al. | May 2000 | A |
6065526 | Kono | May 2000 | A |
6135196 | Kono | Oct 2000 | A |
6241001 | Kono | Jun 2001 | B1 |
6276434 | Kono | Aug 2001 | B1 |
6283197 | Kono | Sep 2001 | B1 |
6284167 | Fujikawa | Sep 2001 | B1 |
6306231 | Sakamoto et al. | Oct 2001 | B1 |
Number | Date | Country |
---|---|---|
2 320 761 | Nov 1994 | DE |
196 11 419 | Sep 1996 | DE |
0 476 843 | Mar 1992 | EP |
0 761 344 | Mar 1997 | EP |
1.447.606 | Jun 1966 | FR |
1166874 | Jun 1989 | JP |
1-178345 | Jul 1989 | JP |
1-192447 | Aug 1989 | JP |
2-202420 | Aug 1990 | JP |
2-274360 | Nov 1990 | JP |
5-8016 | Jan 1993 | JP |
05 008017 | Jan 1993 | JP |
5-285625 | Nov 1993 | JP |
5-285626 | Nov 1993 | JP |
5-285627 | Nov 1993 | JP |
6-47515 | Feb 1994 | JP |
6-306507 | Nov 1994 | JP |
7-51827 | Feb 1995 | JP |
8-72110 | Mar 1996 | JP |
8-174172 | Jul 1996 | JP |
8-252661 | Oct 1996 | JP |
9-103859 | Apr 1997 | JP |
9-155524 | Jun 1997 | JP |
9-155526 | Jun 1997 | JP |
9-155527 | Jun 1997 | JP |
9-295122 | Nov 1997 | JP |
153528 | Mar 1991 | TW |
9213662 | Aug 1992 | WO |
9721509 | Jun 1997 | WO |
9745218 | Dec 1997 | WO |
9928065 | Jun 1999 | WO |
9950007 | Oct 1999 | WO |
Number | Date | Country | |
---|---|---|---|
20040074626 A1 | Apr 2004 | US |
Number | Date | Country | |
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60080078 | Mar 1998 | US |
Number | Date | Country | |
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Parent | 10286866 | Nov 2002 | US |
Child | 10682958 | US | |
Parent | 09949952 | Sep 2001 | US |
Child | 10286866 | US | |
Parent | 09330147 | Jun 1999 | US |
Child | 09842092 | US | |
Parent | 09160792 | Sep 1998 | US |
Child | 09330147 | US |
Number | Date | Country | |
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Parent | 09842092 | Apr 2001 | US |
Child | 09949952 | US |