1. Field of the Invention
This invention relates to an injection molding apparatus, and more particularly to a system for isolating a nozzle from a mold component in the injection molding apparatus.
2. Background Art
It is known for a nozzle in hot runner injection molding apparatus to include a thermally conductive body and a thermally conductive tip. Furthermore, it is known for the nozzle to include a separate piece that joins to the nozzle body and retains the tip in place in the nozzle body. The tip surrounding piece is also typically used to form a seal surrounding the space between the nozzle and the mold component to which the nozzle transfers melt. Because the mold component is usually maintained at a different temperature than the tip at least for a portion of an injection molding cycle, the tip surrounding piece is typically made from a material that is less thermally conductive than the tip itself.
An example of such a nozzle construction is shown in U.S. Pat. No. 5,299,928 (Gellert). A problem with such nozzle constructions, however, is that the tip surrounding piece, which has a lower thermally conductive material than the tip, can impede heat transfer from a heater on the nozzle, to melt that is in the tip.
Thus, a need exists for a nozzle and injection molding apparatus that has improved heat transfer efficiency.
In accordance with one aspect of the present invention, there is provide an injection molding apparatus comprising a runner component, including at least one runner that receives melt from a melt source, a nozzle in fluid communication with the runner, a mold contacting piece that is proximate to the nozzle, and a mold component that is proximate to the mold contacting piece, the mold component including a mold cavity for receiving melt from said nozzle. The nozzle is comprised of a heated nozzle body, including a melt passage therethrough, a nozzle tip, including a tip melt passage therethrough, wherein the tip melt passage is in fluid communication with the melt passage of the nozzle body, and a thermally conductive tip surrounding piece that is removably coupled to the nozzle body. The nozzle may also include a chamber defined by the space between the inner surface of the tip surrounding piece and the outer surface of the tip. The tip surrounding piece retains the nozzle tip in position with respect to the nozzle body. The nozzle tip is formed of a thermally conductive material, such as H13. The tip surrounding piece is preferably formed of a material having a thermal conductivity that is substantially equal to that of the nozzle tip; optimally H13. The tip surrounding piece is preferably threadably engaged with the nozzle body. The mold contacting piece is in contact with, but not attached to, the tip surrounding piece. The mold contacting piece preferably surrounds the nozzle tip and is formed of a material having a thermal conductivity that is less than that of the nozzle tip and tip surrounding piece. The mold contacting piece is generally adapted to isolate the nozzle body, nozzle tip, and tip surrounding piece from the mold component when the nozzle is positioned to deliver melt to a gate of the mold component; thus limiting heat loss from the nozzle to the mold component. The mold contacting piece may also be adapted to align the nozzle with respect to a gate of the mold component, and the injection molding apparatus may further include a second mold contacting piece adapted to inhibit leakage of melt from the chamber to the area surrounding the nozzle. The tip melt passage may take a generally linear path, or may alternatively take a diverted path in which the tip melt passage includes an exit that is off-center from the longitudinal axis of the tip melt passage.
In accordance with another aspect of the present invention, there is provided an injection molding apparatus comprising a runner component including at least one runner, a nozzle in fluid communication with at least the runner, and a mold contacting piece that is positioned between the nozzle and a mold component such that the nozzle is isolated from contacting the mold component. The injection molding apparatus may further include a heat source thermally coupled to the nozzle. The nozzle is formed of a nozzle body, defining a body melt passage, a nozzle tip, defining a tip melt passage, and a tip surrounding piece that is removably coupled to the nozzle body. Optimally, the tip surrounding piece is threadably engaged with the nozzle body. The tip surrounding piece is preferably formed of a material that has a thermal conductivity that is equivalent to that of the nozzle tip. The nozzle may also include a chamber defined by a space between the inner surface of the tip surrounding piece and the outer surface of the nozzle tip. The nozzle tip includes a retaining surface, which may take the form of a shoulder, abutting with the tip surrounding piece to thereby retain the nozzle tip in position with respect to the nozzle body.
In accordance with yet another aspect of the present invention, there is provided an injection molding apparatus comprising a runner component, a mold component, a nozzle in fluid communication with the runner component, a heat source thermally coupled to the nozzle, and a mold contacting piece that is positioned between the nozzle and the mold component. The mold contacting piece acts to isolate the nozzle from contacting the mold component. The nozzle includes a nozzle body having a body melt passage therethrough, a nozzle tip formed of a metallic material, and a tip surrounding piece formed of said metallic material. The tip surrounding piece is removably coupled, and preferably threadably engaged, to the nozzle body and retains the tip in position with respect to the nozzle body. The metallic material is typically thermally conductive and may be Beryllium-Copper, tool steel, H13, or titanium. The nozzle tip typically has a retaining surface, which may take the form of a shoulder, mating with the tip surrounding piece to thereby retain the nozzle tip in position with respect to the nozzle body.
In accordance with still another aspect of the present invention, there is provided an injection molding apparatus having a runner component, a mold component, a nozzle in fluid communication with the runner component, a heater thermally coupled to the nozzle, and a mold contacting piece positioned between the nozzle and the mold component to thereby form a thermal barrier between the nozzle and the mold component. The nozzle is formed of a nozzle body, a nozzle tip, and a tip surrounding piece which is removably coupled to the nozzle body and retains the nozzle tip in position with respect to the nozzle body. The tip surrounding piece is formed of a material that has a thermal conductivity which is equivalent to that of the material which forms the nozzle tip. Such a material may be Beryllium-Copper, Copper, Titanium/Zirconium carbide, Aluminum, Aluminum alloy, Molybdenum, Molybdenum alloy, mold steel, Tungsten Carbide, tool steel, titanium, or H13. The tip surrounding piece is preferably threadably engaged with the nozzle body. The nozzle body may include outward threads along at least a portion of its outer surface, such outward threads engaging with inward threads along at least a portion of the inner surface of the tip surrounding piece to thereby couple the tip surrounding piece to the nozzle body. Alternatively, the nozzle body may include inward threads along at least a portion of its inner surface, such inward threads engaging with outward threads along at least a portion of the outer surface of the tip surrounding piece to thereby couple the tip surrounding piece to the nozzle body. The nozzle tip may also include an exit that is off-center from the longitudinal axis of the tip melt passage.
For a better understanding of the present invention, and to show more clearly how it may be carried into effect, reference will now be made by way of example to the accompanying drawings.
a is a magnified sectional view of a portion of one of the nozzles and the mold component shown in
b is a magnified section view of a portion of a nozzle and a mold component, in accordance with a variant of the first embodiment of the present invention.
a and 12b are magnified sectional views of a portion of a nozzle and a mold component in accordance with a twelfth embodiment of the present invention.
Reference is made to
The runner component 12 includes a plurality of runners 18, which transfer melt from a main runner inlet 20 to the nozzles 16. The runner component 12 may be heated by a heater 22.
The mold component 14 is made up of a plurality of mold components, which together define a plurality of mold cavities 24. A gate 26 into each mold cavity 24 is defined in the mold component 14 and has an axis 27. Each gate 26 is positioned downstream from one of the nozzles 16.
A plurality of cooling channels 28 may be included in the mold component 14. The cooling channels 28 transport a cooling fluid throughout the mold component 14 to cool and solidify melt in the mold cavities 24.
Reference is made to
The nozzle body 31 defines a nozzle body melt passage 37, which receives melt from one of the runners 18. The heater 32 is connected to the nozzle body 31 for heating melt in the nozzle 16. The heater 32 may be any suitable kind of heater, such as a resistive wire heater, or a sleeve heater, as long as it is thermally connected to the nozzle body 31, i.e. the heater 32 is connected such that heat is transferable from the heater 32 to the nozzle body 31. For example, the heater 32 may wrap around the nozzle body 31 in a groove on the outer surface of the nozzle body 31.
The tip 33 defines a tip melt passage 38, and is removably connected to the nozzle body 31 so that the tip melt passage 38 is in fluid communication with and downstream from the nozzle body melt passage 37. The tip melt passage 38 has an exit, which may be offset from axis 27, as shown in
The tip 33, and more particularly the tip melt passage 38, transports the melt from the body melt passage 37 to chamber 30. The tip 33 is made from a first material that is preferably thermally conductive to reduce losses in the heat transferred from the heater 32 to the melt in the tip melt passage 38. Some examples of suitable first materials for the tip 33 are Be—Cu (Beryllium-Copper), Beryllium-free Copper, such as AMPCO 940, TZM (Titanium/Zirconium carbide), Aluminum or Aluminum-based alloys, Nickel-Chromium alloys, such as INCONEL, Molybdenum or suitable Molybdenum alloys, H13, mold steel or steel alloys, such as AERMET 100.
Also, however, because of the melt flow through the tip 33, the tip 33 may be exposed to a highly abrasive environment, and may be made from a wear resistant first material. An example of such a first material that is both thermally conductive and wear resistant is Tungsten Carbide. U.S. Pat. No. 5,658,604 (Gellert et al.) discloses the construction of a nozzle tip using Tungsten Carbide. The tip 33 may be made using the construction taught in U.S. Pat. No. 5,658,604.
The tip 33 may be removable from the nozzle body 31. The tip 33 may, for example, seat against a shoulder 39 in the nozzle body 31. The shoulder 39 may be an internal shoulder, as shown in
The tip surrounding piece 34 may retain the tip 33 in place on the nozzle body 31. The tip surrounding piece 34 may be removably connected to the nozzle body 31. For example, tip surrounding piece 34 may include a tip surrounding piece threaded portion 40, which mates with a corresponding nozzle body threaded portion 41 on the nozzle body 31. In the present embodiment, shown in
For example, for users who mold several different types of articles from a variety of different materials, it may be desirable to have several different types of tips 33 available for use in the nozzles of their injection molding apparatus. A user may, for example, have many different sets of tips 33 for use with their injection molding apparatus, each set of tips 33 being suited to one or more molding applications. Rather than machining threaded portion 40 on each set of tips 33, the tips 33 may be free of threads or other connecting means, and the tip surrounding piece 34 can include the connecting means, such as threads 40, as shown in
The tip surrounding piece 34 is made from a second material that may be less wear resistant than the first material from which the tip 33 is made, because the tip surrounding piece 34 does not have an internal melt passage. Accordingly, the tip surrounding piece 34 may be made from a second material that is relatively easily machined with threaded portion 40.
The tip surrounding piece 34 may also include a gripping portion 42 to facilitate the removal of the tip surrounding piece 34 from the nozzle body 31. The gripping portion 42 may be, for example, hexagonal for receiving a removal tool (not shown), such as a wrench.
The tip surrounding piece 34 and the tip 33 may be two separate, distinct pieces, as shown in the Figures. However, it can sometimes be difficult to remove the tip 33 from the nozzle body 31 due, for example, to a buildup of plastic between their mating surfaces. To facilitate the removal of the tip 33 from the nozzle body 31, the tip surrounding piece 34 and the tip 33 may alternatively be brazed or otherwise joined together, rather than being separate.
The tip surrounding piece 34 is at least in part, positioned between the tip melt passage 38 and the heater 32 along at least a portion of the length of the tip melt passage 38. In order to improve the heat flow from the heater to the tip melt passage 38, the tip surrounding piece 34 may be made from a thermally conductive second material. However, as explained above, the tip surrounding piece 34 is not necessarily made from a wear resistant second material. The tip surrounding piece 34 may be made from such second materials as, Copper, Be—Cu (Beryllium-Copper), Beryllium-free Copper, such as AMPCO 940, TZM (Titanium/Zirconium carbide), Aluminum or Aluminum-based alloys, Nickel-Chromium alloys, such as INCONEL, Molybdenum or suitable Molybdenum alloys, H13, steel, mold steel or steel alloys, such as AERMET 100.
The mold component contacting piece 35 contacts the mold component 14, and may inhibit melt leakage out of the chamber formed between the nozzle 16 and the mold component 14. The mold component contacting piece 35 may, for example, be positioned between the tip surrounding piece 34 and the mold component 14, as shown in
The mold component contacting piece 35 may align the nozzle 16 with respect to the gate 26. The alignment means may be provided by the same surfaces that provide the seals 44 and 46. For example, seals 44 and 46 may be mechanical seals, formed by a close fit between the mold component contacting piece 35 and the bore 48 and between the mold component contacting piece 35 and the tip surrounding piece 34, thereby aligning the nozzle 16 with respect to the gate 26. Alternatively, a separate alignment means may be used to position nozzle 16 with respect to the gate 26.
The mold component contacting piece 35 may be positioned outside of the path between the melt passage 38 and the heater 32. The mold component contacting piece 35 may instead be positioned between the mold component 14 and at least one of the tip surrounding piece 34, the tip 33 and the nozzle body 31. Typically, at least for some portion of an injection molding cycle, the mold component 14 and the nozzle 16 are maintained at different temperatures. For example, once the mold cavity 24 is filled with melt, the mold component 14 may be cooled to cause solidification of the melt in the mold cavity 24. However, the nozzle 16 may be heated to keep the melt contained therein hot and ready for the next injection phase. In order to reduce unwanted heat transfer between the nozzle 16 and the mold component 14, the mold component contacting piece 35 may be made from a material that is comparatively less thermally conductive than the material of the nozzle tip 33. Furthermore, the material of the mold component contacting piece 35 may be less thermally conductive than the material of the tip surrounding piece 34. For example, the mold component contacting piece 35 may be made from titanium, H13, stainless steel, mold steel or chrome steel. Other alternative materials include ceramics and plastics. Other suitable materials for the mold component contacting piece 35 are disclosed in U.S. Pat. No. 5,879,727 (Puri), which is hereby incorporated by reference. Puri discloses such materials for use as an insulative layer for a nozzle.
The mold component contacting piece 35 may be a separate piece that is mechanically joined to tip surrounding piece 34 by a suitable joint, such as an interference fit, as shown. Alternatively, the mold component contacting piece 35 may be made by spraying a coating onto the tip surrounding piece 34, and then machining the coating as required, to a suitable dimension for mating and sealing appropriately with the mold component 14. U.S. Pat. No. 5,569,475 (Adas et al.) discloses a method of spraying an insulating layer onto a portion of a nozzle, and is hereby incorporated by reference.
The mold component contacting piece 35 may be joined to the tip surrounding piece 34, as shown in
Reference is made to
Thus, a nozzle in accordance with the present invention may have a tip that inserts into the gate 26 and has an off-centre melt passage exit (as shown in
Reference is made to
The tip melt passage 203, has an exit 208, which may be concentric about axis 27, as shown in
Reference is made to
Reference is made to
The downstream end 404 is subject to increased wear from the melt flow for several reasons. A first reason is that the available cross-sectional area through which the melt can flow (i.e. the gate area minus the area of the end 404) is relatively small and as a result the melt flow velocity through the gate 26 is relatively high. The higher melt flow velocity increases the wear on the end 404. A second reason is that the end 404 has a relatively high surface-to-volume ratio, relative to other portions of the tip 402 that are exposed to the melt flow, and is therefore particularly easily damaged by wear from the melt flow.
The end 404 may be made from a wear resistant, thermally conductive material, such as Tungsten Carbide. The main portion of the tip 402, shown at 405, may be made from a less wear resistant material than the end 404, and may be made from a greater selection of materials. For example, a highly thermally conductive material may be selected for the main portion 405, such as Aluminum, an Aluminum alloy, or Be—Cu (Beryllium-Copper). By making the tip 402 with the compound construction described above, it can be wear resistant in a selected portion, and may be less wear resistant but highly thermally conductive elsewhere. It will be appreciated that the materials for the end 404 and for the main portion 405 may be selected for any desirable characteristics and not only for wear resistance and thermal conductivity. It will also be appreciated that the tip 402 may include one or more other portions having selected properties, instead of, or in addition to the end 404. It will also be appreciated, that the end 404 may be made by heat treating or coating the tip 402.
Reference is made to
The tip surrounding piece 453 may be similar to the tip surrounding piece 34 (
Aside from remaining in the mold component 452, the mold component contacting piece 454 may be similar to the mold component contacting piece 35 (
Reference is made to
The nozzle body 502 may be similar to the nozzle body 31 (
The tip 504 may be similar to the tip 33 (
The tip surrounding piece 506 may be similar to the tip surrounding piece 34 (
The tip surrounding piece 502 may include a first sealing surface 516, which may be similar to the sealing surface 456 on the tip surrounding piece 453 (
Reference is made to
The nozzle body 552 may be similar to the nozzle body 502 (
The tip 554 may be similar to the tip 504 (
The tip surrounding piece 556 may be similar to the tip surrounding piece 502 (
Reference is made to
The tip surrounding piece 602 may be similar to the tip surrounding piece 556 (
Reference is made to
The nozzle body 652 may be similar to the nozzle body 31 (
The tip 654 may be similar to the tip 554 (
The tip surrounding piece 656 may be similar to the tip surrounding piece 602 (
The mold component contacting piece 658 may be L-shaped in cross-section, and may have a first sealing face 672 that seals in the bore 48 of the mold component 14, and may also align the nozzle 650 in the bore 48. The mold component contacting piece 658 may also have a second sealing face 674, which may include both a vertical portion 676 and a horizontal portion 678. The vertical and horizontal portions 676 and 678 may cooperate with a vertical sealing surface 680 and a horizontal sealing surface 682 on the tip surrounding piece 656 to inhibit melt leakage therepast.
Reference is made to
The mold component contacting piece 704 may be generally rectangular in cross-section and may have a sealing and aligning surface 708 which seals and aligns against a bore 710 in the mold component 702. The mold component contacting piece 704 may have another sealing and aligning surface 712, which may have a first portion 714 that is vertical and a second portion 716 that is horizontal. The first and second portions 714 and 716 cooperate with a mating third, optionally vertical, portion 718 and a mating fourth, optionally horizontal, portion 720 on the nozzle body 707. The nozzle body 707 may be otherwise similar to the nozzle body 652 (
The mold component 702 may be similar to the mold component 14 (
Thus, the combination of the nozzle 700 and mold component 702 may be similar to the combination of the nozzle 650 and the mold component 14 (
Reference is made to
The mold component contacting piece 755 may be generally washer-shaped, having an outer face 758, an inner face 760, a lower face 762 and an upper face 764. The outer face 758 may cooperate with the bore 757 of the mold component 751 to align the mold component contacting piece 755 relative to the gate 26. The inner face 760 in turn, cooperates with a portion of the nozzle 750, in this case, an alignment and sealing surface 765 on the tip 753, to align the nozzle 750 relative to the gate 26. The lower face 762 of the mold component contacting piece 755 may form a seal with the bottom shoulder 756 to prevent melt leakage out of the chamber 30.
The tip 753 may have a jam surface 767 for resting against the shoulder 667b in the nozzle body 652. The tip 753 may be retained in place by the cooperation between a shoulder 768a on the tip 753 and a shoulder 766b on the tip surrounding piece 754. The tip defines a tip melt passage 771 therethrough that is downstream from and in fluid communication with the body melt passage 660
The tip surrounding piece 754 has a bottom shoulder 769. In the ‘cool’ position, shown in
The tip surrounding piece may have a threaded portion 770 for mating with the threaded portion 662 on the nozzle body 652.
It will be noted that in this embodiment, the mold component contacting piece 755 is not necessarily specifically attached to either of the mold component 751 or the rest of the nozzle 652.
Reference is made to
The alignment piece 802 may be generally L-shaped in cross-section, and may have a lower face 806, a first upper face 808, a second upper face 810, an inner face 812, a first outer face 814 and a second outer face 816. The alignment piece 802 may rest against a shoulder 818 in the mold component 801. The second outer face 816 and the bore 820 cooperate to align the alignment piece 802 relative to the gate 26. The inner face 812 cooperates with a portion of the nozzle 800, in this case, an alignment surface 819 on the tip 753 to align the nozzle 800 relative to the gate 26. A gap exists between the second upper face 810 and the bottom face 769 of the tip surrounding piece 754.
The seal piece 804 may be an O-ring that is resilient and that can seal effectively for the pressures and temperature in the general environment of an injection molding apparatus. The seal piece 804 is positioned in a pocket form by a bore 820 in the mold component 801, the first upper face 808 and the first outer face 814 and the bottom face 769 of the tip surrounding piece 754. In the ‘cool’ position, shown in
It will be noted that, in the embodiment shown in
During an injection molding cycle, the nozzle 800 is heated and expands, and the gap between the bottom shoulder 769 of the tip surrounding piece 754 and the second upper face 810 of the alignment piece 802 is reduced or may be eliminated, due to the thermal expansion. The bottom shoulder 769 of the tip surrounding piece 754 further compresses the seal piece 804, thereby further strengthening the seals formed between the seal piece 804 and the nozzle 800 and the mold component 801.
Reference is made to
The tip 904 may be similar to the tip 33 (
The tip surrounding piece 906 is not required to contact the tip 904 in the embodiment shown in
The tip surrounding piece 906 may or may not form a seal with the tip 904 for inhibiting melt leakage therebetween. Thus, melt may be permitted to exist between the tip 904 and the tip surrounding piece 906.
The mold component contacting piece 908 may be similar to the mold component contacting piece 35 (
The mold component contacting piece 908 may align the nozzle 900 with respect to the bore 48 of the mold component 14. Alternatively, the mold component contacting piece 908 may form a seal with the bore 48 in the mold component 14 to prevent melt leakage therebetween. As a further alternative, the mold component contacting piece 908 may provide both a sealing function and an aligning function.
In the above described embodiments, the tip surrounding piece has been attached to the nozzle body by means of mating threaded portions. It is alternatively possible for the tip surrounding piece to be attached to the nozzle body in any suitable way that permits the tip surrounding piece to be removed.
In the embodiment shown in
A particular example of an injection molding apparatus is shown in
While the above description constitutes the preferred embodiments, it will be appreciated that the present invention is susceptible to modification and change without departing from the fair meaning and scope of the accompanying claims.
Number | Date | Country | Kind |
---|---|---|---|
2358148 | Oct 2001 | CA | national |
This application is a continuation of U.S. application Ser. No. 10/262,982, filed Oct. 3, 2002 (now U.S. Pat. No. 6,921,257 that issued Jul. 26, 2005), the entire disclosure of which is hereby incorporated by reference, which claims the benefit of U.S. Provisional Application No. 60/356,170, filed Feb. 14, 2002, and U.S. Provisional Application No. 60/346,632, filed Jan. 10, 2002, and U.S. Provisional Application No. 60/330,540, filed Oct. 24, 2001.
Number | Name | Date | Kind |
---|---|---|---|
2865050 | Strauss | Dec 1958 | A |
3488810 | Gellert | Jan 1970 | A |
3677682 | Putkowski | Jul 1972 | A |
3716318 | Erik et al. | Feb 1973 | A |
3741704 | Beasley | Jun 1973 | A |
3952927 | Schaumburg et al. | Apr 1976 | A |
4004871 | Hardy | Jan 1977 | A |
4010903 | Sakuri et al. | Mar 1977 | A |
4013393 | Gellert | Mar 1977 | A |
4043740 | Gellert | Aug 1977 | A |
4053271 | Gellert | Oct 1977 | A |
4173448 | Rees et al. | Nov 1979 | A |
4212627 | Gellert | Jul 1980 | A |
4268240 | Rees et al. | May 1981 | A |
4268241 | Rees et al. | May 1981 | A |
4279588 | Gellert | Jul 1981 | A |
4286941 | Gellert | Sep 1981 | A |
4306852 | Mateev et al. | Dec 1981 | A |
4312630 | Travaglini | Jan 1982 | A |
4318686 | Morgan | Mar 1982 | A |
4330258 | Gellert | May 1982 | A |
4368028 | Grish et al. | Jan 1983 | A |
4412807 | York | Nov 1983 | A |
4450999 | Gellert | May 1984 | A |
4517453 | Tsutsumi | May 1985 | A |
4652230 | Osuna-Diaz | Mar 1987 | A |
4662837 | Anderson | May 1987 | A |
4768283 | Gellert | Sep 1988 | A |
4768945 | Schmidt et al. | Sep 1988 | A |
4771164 | Gellert | Sep 1988 | A |
4781572 | Boring | Nov 1988 | A |
4787836 | Osuna-Diaz et al. | Nov 1988 | A |
4832593 | Brown | May 1989 | A |
4875848 | Gellert | Oct 1989 | A |
4902218 | Leonard et al. | Feb 1990 | A |
4911636 | Gellert | Mar 1990 | A |
4925384 | Manner | May 1990 | A |
4945630 | Gellert | Aug 1990 | A |
4950154 | Moberg | Aug 1990 | A |
4954072 | Zimmerman | Sep 1990 | A |
4981431 | Schmidt | Jan 1991 | A |
5015170 | Gellert | May 1991 | A |
5028227 | Gellert et al. | Jul 1991 | A |
5030084 | Gellert et al. | Jul 1991 | A |
5053271 | Mori et al. | Oct 1991 | A |
5067893 | Osuna-Diaz | Nov 1991 | A |
5135377 | Gellert | Aug 1992 | A |
5139724 | Hofstetter et al. | Aug 1992 | A |
5141696 | Osuna-Diaz | Aug 1992 | A |
5208052 | Schmidt et al. | May 1993 | A |
5208228 | Ok et al. | May 1993 | A |
5238378 | Gellert | Aug 1993 | A |
5254305 | Fernandez et al. | Oct 1993 | A |
5268184 | Gellert | Dec 1993 | A |
5269677 | Gauler | Dec 1993 | A |
5299928 | Gellert | Apr 1994 | A |
5324191 | Schmidt | Jun 1994 | A |
5334008 | Gellert | Aug 1994 | A |
5360333 | Schmidt | Nov 1994 | A |
5374182 | Gessner | Dec 1994 | A |
5421716 | Gellert | Jun 1995 | A |
5443381 | Gellert | Aug 1995 | A |
5474439 | McGrevy | Dec 1995 | A |
5492467 | Hume et al. | Feb 1996 | A |
5501594 | Glozer et al. | Mar 1996 | A |
5505613 | Krummenacher | Apr 1996 | A |
5518393 | Gessner | May 1996 | A |
5545028 | Hume et al. | Aug 1996 | A |
5554395 | Hume et al. | Sep 1996 | A |
5569475 | Adas et al. | Oct 1996 | A |
5652003 | Gellert | Jul 1997 | A |
5658604 | Gellert et al. | Aug 1997 | A |
5674439 | Hume et al. | Oct 1997 | A |
5686122 | Huntington et al. | Nov 1997 | A |
5695793 | Bauer | Dec 1997 | A |
5700499 | Bauer | Dec 1997 | A |
5707667 | Galt et al. | Jan 1998 | A |
5736171 | McGrevy | Apr 1998 | A |
5795599 | Gellert | Aug 1998 | A |
5804228 | Kofsman et al. | Sep 1998 | A |
5811140 | Manner | Sep 1998 | A |
5820899 | Gellert et al. | Oct 1998 | A |
5834041 | Sekine et al. | Nov 1998 | A |
5845853 | Frideman | Dec 1998 | A |
5849343 | Gellert et al. | Dec 1998 | A |
5871785 | Van Boekel | Feb 1999 | A |
5871786 | Hume et al. | Feb 1999 | A |
5879727 | Puri | Mar 1999 | A |
5885628 | Swenson et al. | Mar 1999 | A |
5894025 | Lee et al. | Apr 1999 | A |
5895669 | Seres, Jr. et al. | Apr 1999 | A |
5925386 | Moberg | Jul 1999 | A |
5941637 | Maurer | Aug 1999 | A |
5948450 | Swenson et al. | Sep 1999 | A |
5955121 | Gellert et al. | Sep 1999 | A |
5980234 | Harley | Nov 1999 | A |
5980237 | Swenson et al. | Nov 1999 | A |
5984661 | Vorkoper | Nov 1999 | A |
6003182 | Song | Dec 1999 | A |
6009616 | Gellert | Jan 2000 | A |
6017209 | Gellert et al. | Jan 2000 | A |
6022210 | Gunther | Feb 2000 | A |
6030202 | Gellert et al. | Feb 2000 | A |
6036467 | Jameson | Mar 2000 | A |
6050806 | Ko | Apr 2000 | A |
6074195 | Belous | Jun 2000 | A |
6089468 | Bouti | Jul 2000 | A |
6113381 | Gellert et al. | Sep 2000 | A |
6135757 | Jenko | Oct 2000 | A |
6143358 | Singh et al. | Nov 2000 | A |
6164945 | Mortazavi et al. | Dec 2000 | A |
6164954 | Mortazavi et al. | Dec 2000 | A |
6220851 | Jenko | Apr 2001 | B1 |
6227461 | Schroeder et al. | May 2001 | B1 |
6234783 | Shibata et al. | May 2001 | B1 |
6245278 | Lausenhammer et al. | Jun 2001 | B1 |
6254377 | Kazmer et al. | Jul 2001 | B1 |
6261084 | Schmidt | Jul 2001 | B1 |
6264460 | Wright et al. | Jul 2001 | B1 |
6273706 | Gunther | Aug 2001 | B1 |
6287107 | Kazmer et al. | Sep 2001 | B1 |
6309208 | Kazmer et al. | Oct 2001 | B1 |
6315549 | Jenko et al. | Nov 2001 | B1 |
6318990 | Gellert et al. | Nov 2001 | B1 |
6331106 | Helldin | Dec 2001 | B1 |
6358038 | Rozenberg | Mar 2002 | B1 |
6358039 | Manner et al. | Mar 2002 | B1 |
6394785 | Ciccone | May 2002 | B1 |
6419116 | Eigler et al. | Jul 2002 | B1 |
6428305 | Jenko | Aug 2002 | B1 |
6533571 | Fikani | Mar 2003 | B1 |
6609902 | Blais et al. | Aug 2003 | B1 |
6709262 | Fong | Mar 2004 | B1 |
6726467 | Lefebure | Apr 2004 | B1 |
6769901 | Babin et al. | Aug 2004 | B1 |
6789745 | Babin et al. | Sep 2004 | B1 |
6821112 | Eigler et al. | Nov 2004 | B1 |
6832909 | Bazzo et al. | Dec 2004 | B1 |
6869276 | Babin et al. | Mar 2005 | B1 |
6921257 | Olaru | Jul 2005 | B1 |
6921259 | Gellert | Jul 2005 | B1 |
6962492 | Olaru | Nov 2005 | B1 |
6971869 | Olaru | Dec 2005 | B1 |
6988883 | Babin et al. | Jan 2006 | B1 |
20030082264 | Babin et al.. | May 2003 | A1 |
20030086997 | Olaru | May 2003 | A1 |
20030170340 | Sicilia et al. | Sep 2003 | A1 |
20030235638 | Gellert | Dec 2003 | A1 |
20040058031 | Niewels | Mar 2004 | A1 |
20040071817 | Fischer et al. | Apr 2004 | A1 |
20040131721 | Babin et al. | Jul 2004 | A1 |
20040137107 | Babin et al. | Jul 2004 | A1 |
20040146598 | Sicilia et al. | Jul 2004 | A1 |
20040208949 | Niewels | Oct 2004 | A1 |
20040258788 | Olaru | Dec 2004 | A1 |
20040265417 | Olaru | Dec 2004 | A1 |
20050106283 | Olaru | May 2005 | A1 |
20050118298 | Babin et al. | Jun 2005 | A1 |
20050136151 | Babin | Jun 2005 | A1 |
20050214403 | Olaru | Sep 2005 | A1 |
Number | Date | Country |
---|---|---|
2082700 | May 1994 | CA |
2190569 | May 1998 | CA |
2261367 | Aug 2000 | CA |
2358148 | Mar 2003 | CA |
2473920 | Aug 2003 | CA |
032 45 571 | Jun 1984 | DE |
296 02 484 | May 1996 | DE |
196 08 676 | Jan 1997 | DE |
100 08 722 | Aug 2001 | DE |
10037739 | Feb 2002 | DE |
0 590 677 | Apr 1994 | EP |
0 638 407 | Feb 1995 | EP |
0743158 | Nov 1996 | EP |
0 750 975 | Jan 1997 | EP |
0835176 | Apr 1998 | EP |
0 873 841 | Oct 1998 | EP |
0920969 | Jun 1999 | EP |
0743158 | Aug 1999 | EP |
0 962 296 | Dec 1999 | EP |
1 188 537 | Mar 2002 | EP |
1321274 | Jun 2003 | EP |
2537497 | Jun 1984 | FR |
1 540 698 | Feb 1979 | GB |
05-261770 | Oct 1992 | JP |
05-177664 | Jul 1993 | JP |
05-309695 | Nov 1993 | JP |
6-143358 | May 1994 | JP |
7-148786 | Jun 1995 | JP |
8-90598 | Apr 1996 | JP |
9-123222 | May 1997 | JP |
10-034708 | Feb 1998 | JP |
10-264222 | Oct 1998 | JP |
10-296798 | Nov 1998 | JP |
11-254488 | Sep 1999 | JP |
2002-273768 | Sep 2002 | JP |
2002-307492 | Oct 2002 | JP |
2003-11173 | Jan 2003 | JP |
2003-11174 | Jan 2003 | JP |
2003-11176 | Jan 2003 | JP |
2003-071873 | Mar 2003 | JP |
WO 8400922 | Mar 1984 | WO |
WO 9702129 | Jan 1997 | WO |
WO 0048814 | Aug 2000 | WO |
WO 0128750 | Apr 2001 | WO |
WO 0178961 | Oct 2001 | WO |
WO 0240245 | May 2002 | WO |
WO 03004243 | Jan 2003 | WO |
WO 03028973 | Apr 2003 | WO |
WO 03028974 | Apr 2003 | WO |
WO 03070446 | Aug 2003 | WO |
WO 03086734 | Oct 2003 | WO |
WO 200412923 | Feb 2004 | WO |
WO 2005090051 | Sep 2005 | WO |
Number | Date | Country | |
---|---|---|---|
20050214403 A1 | Sep 2005 | US |
Number | Date | Country | |
---|---|---|---|
60356170 | Feb 2002 | US | |
60346632 | Jan 2002 | US | |
60330540 | Oct 2001 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 10262982 | Oct 2002 | US |
Child | 11135525 | US |