Claims
- 1. A process for injection molding a polymer prepared by polymerizing components consisting essentially of at least one aromatic tricarboxylic acid derivative, said acid having two carboxyl groups ortho to one another, and at least one aromatic diprimary diamine having 6 to 10 carbon atoms or composed of two aromatic moieties of 6 to 10 carbon atoms each, each of said moieties containing one primary amino group and being linked to the other moiety directly or through --O--, --S--, --SO.sub.2 --, --CO--, or --CH.sub.2 --, the molecular weight of said polymer being controlled such that the spiral flow rate thereof is at least about 4 inches at 600.degree. F. and 20,950 psi., said injection molding comprising plasticating and compacting said polymer between the flights of a high-compression ratio screw under reciprocating screw injection molding conditions.
- 2. The process according to claim 1 wherein the compression ratio ranges from about 1.8 to 3.5 and the aromatic tricarboxylic acid derivative is a derivative of trimellitic acid.
- 3. The process according to claim 2 wherein the polymer is a predominantly amic acid group containing polymer prepared by polymerizing the 4-acyl chloride derivative of trimellitic acid anhydride and a mixture of oxybis(aniline) and meta-phenylenediamine, and drying the resultant polymer at below 300.degree. F. whereby substantial imidization of amic acid units and increases in molecular weight are avoided.
- 4. The process according to claim 3 wherein the polymer has a spiral flow ranging from about 5 to 10 inches at 600.degree. F. and 20,950 psi.
- 5. The process according to claim 2 wherein the polymer is prepared by polymerizing a mixture of the 4-acyl chloride derivative of trimellitic acid anhydride and trimellitic acid anhydride and a mixture of oxybis(aniline) and meta-phenylenediamine, said trimellitic acid anhydride being present in an amount which is effective to control the molecular weight of said polymer.
- 6. The process according to claim 5 wherein the polymer has a spiral flow ranging from about 5 to 10 inches at 600.degree. F. and 20,950 psi.
- 7. The process according to claim 1 further comprising heat treating the molded article.
- 8. A process for preparing a molded article which comprises plasticating and compacting between the flights of a reciprocating screw having a compression ratio ranging from about 1 to about 2.5 under reciprocating screw injection molding conditions a composition comprising (1) from about 40 to 95 wt.% of a polymer prepared by polymerizing components consisting essentially of at least one aromatic tricarboxylic acid derivative, said acid having two carboxyl groups ortho to one another, and at least one aromatic diprimary diamine having 6 to 10 carbon atoms or composed of two aromatic moieties of 6 to 10 carbon atoms each, each of said moieties containing one primary amino group and being linked to the other moiety directly or through --O--, --S--, --SO.sub.2 --, --CO--, or --CH.sub.2 --, the molecular weight of said polymer being controlled such that the spiral flow rate thereof is at least about 4 inches at 600.degree. F. and 20,950 psi; and (2) from about 5 to about 60 wt.% filler.
- 9. The process according to claim 8 wherein the aromatic tricarboxylic acid derivative is a derivative of trimellitic acid.
- 10. The process according to claim 9 wherein the polymer is a predominantly amic acid group containing polymer prepared by polymerizing the 4-acyl chloride derivative of trimellitic acid anhydride and a mixture of oxybis(aniline) and meta-phenylenediamine, and drying the resultant polymer at below 300.degree. F. whereby substantial imidization of amic acid units and increases in molecular weight are avoided.
- 11. The process according to claim 10 wherein the composition contains from about 20 to about 40 wt.% filler.
- 12. The process according to claim 9 wherein the polymer is prepared by polymerizing a mixture of the 4-acyl chloride derivative of trimellitic acid anhydride and trimellitic acid anhydride and a mixture of oxybis(aniline) and meta-phenylenediamine, said trimellitic acid anhydride being present in an amount which is effective to control the molecular weight of said polymer.
- 13. The process according to claim 12 wherein the composition contains from about 20 to 40 wt.% filler.
- 14. The process according to claim 13 wherein the filler is a fibrous filler.
- 15. The process according to claim 13 wherein the filler is a particulate filler.
- 16. The process according to claim 13 wherein the filler is a compatible polymeric filler.
- 17. The process according to claim 8 further comprising heat treating the molded article.
Parent Case Info
This is a continuation-in-part of my copending application Ser. No. 850,397, filed Nov. 10, 1977, now abandoned.
US Referenced Citations (7)
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
850397 |
Nov 1977 |
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