The present invention generally relates to a fluid injector of a reductant delivery unit (RDU), and particularly to a robust RDU fluid injector for non-purge applications.
Emissions regulations in Europe and North America are driving the implementation of new exhaust aftertreatment systems, particularly for lean-burn technologies such as compression-ignition (diesel) engines, and stratified-charge spark-ignited engines (usually with direct injection) that are operating under lean and ultra-lean conditions. Lean-burn engines exhibit high levels of nitrogen oxide emissions (NOx) that are difficult to treat in oxygen-rich exhaust environments characteristic of lean-burn combustion. Exhaust aftertreatment technologies are currently being developed that treat NOx under these conditions.
One of these technologies includes a catalyst that facilitates the reactions of ammonia (NH3) with the exhaust nitrogen oxides (NOx) to produce nitrogen (N2) and water (H2O). This technology is referred to as Selective Catalytic Reduction (SCR). Ammonia is difficult to handle in its pure form in the automotive environment, therefore it is customary with these systems to use a diesel exhaust fluid (DEF) and/or liquid aqueous urea solution, typically at a 32% concentration of urea (CO(NH2)2). The solution is referred to as AUS-32, and is also known under its commercial name of AdBlue. The reductant solution is delivered to the hot exhaust stream typically through the use of an injector, and is transformed into ammonia prior to entry in the catalyst. More specifically, the solution is delivered to the hot exhaust stream and is transformed into ammonia in the exhaust after undergoing thermolysis, or thermal decomposition, into ammonia and isocyanic acid (HNCO). The isocyanic acid then undergoes a hydrolysis with the water present in the exhaust and is transformed into ammonia and carbon dioxide (CO2), the ammonia resulting from the thermolysis and the hydrolysis then undergoes a catalyzed reaction with the nitrogen oxides as described previously.
AUS-32, or AdBlue, has a freezing point of −11 C, and system freezing is expected to occur in cold climates. Since these fluids are aqueous, volume expansion happens after the transition to the solid state upon freezing. The expanding solid can exert significant forces on any enclosed volumes, such as an injector. This expansion may cause damage to the injection unit, so different SCR strategies exist for addressing reductant expansion.
There are two known SCR system strategies in the marketplace: purge systems and non-purge systems. In purge SCR systems, the reductant urea and/or DEF solution is purged from the RDU when the vehicle engine is turned off. In non-purge SCR systems, the reductant remains in the RDUs throughout the life of the vehicle. During normal operation of a non-purge SCR system, the RDU injector operates at temperatures which are above the freezing point of the reductant such that reductant in the RDU remains in the liquid state. When the vehicle engine is turned off in the non-purge SCR system, however, the RDU injector remains filled with reductant, thereby making the RDU injector susceptible to damage from reductant expanding in freezing conditions.
Example embodiments overcome shortcomings found in existing RDU fluid injectors and provide an improved fluid injector for non-purge SCR systems in which the adverse effects from the RDU being in temperatures that are below the freezing point of reductant are reduced.
In an example embodiment, an RDU includes a fluid injector having a fluid inlet disposed at a first end of the fluid injector for receiving a reductant, and a fluid outlet disposed at a second end of the fluid injector for discharging the reductant, the fluid injector defining a fluid path for the reductant from the fluid inlet to the fluid outlet. The fluid injector includes a tube member having an end disposed at or near the fluid inlet of the fluid injector, the tube member configured to pass reductant along the fluid path; a calibration filter tube disposed in the tube, the calibration filter tube having a first end portion adjacent the filter and a second end, and further including a bore defined in an axial direction through the calibration filter tube, the bore defining at least a portion of the fluid path through the fluid injector; an actuator unit disposed within the fluid injector downstream of the calibration filter tube, the actuator unit engaging the second end of the calibration filter tube; a valve assembly operatively coupled to the actuator unit, wherein a position of the calibration filter tube within the tube member at least partly sets an opposing opening force for the valve assembly; and a volume reduction member having a bore though which the calibration filter tube extends, the volume reduction member occupying a space between an outer surface of the calibration filter tube and an inner surface of the tube member. The calibration filter tube includes one or more apertures extending between the bore of the calibration filter tube and the outer surface thereof.
The volume reduction member is formed from a resilient, compressible material. The resilient, compressible material includes one of a rubber composition and closed cell foam.
The fluid injector further includes a filter and a cap member including a sidewall defining an inner space into which the filter is disposed, the sidewall contacting the first end of the calibration filter tube.
The one or more holes of the calibration filter tube is adjacent the volume reduction member such that freezing or frozen reductant disposed in the calibration filter tube expands through the holes and at least partially compresses the volume reduction member. Melting reductant allows for the volume reduction member to expand so as to be adjacent the holes of the calibration filter tube.
Aspects of the invention will be explained in detail below with reference to an exemplary embodiment in conjunction with the drawings, in which:
The following description of the example embodiment(s) is merely exemplary in nature and is in no way intended to limit the invention, its application, or uses.
Example embodiments are generally directed to an RDU for a non-purge SCR system in which damaging effects from a reductant, DEF and/or urea solution freezing in the RDU injector are reduced.
Fluid injector 12 is disposed in an interior carrier 18 of RDU 10, as shown in
An inlet cup structure of RDU 10, generally indicated at 24 in
Injector 12 includes an injector body structure in which the components of injector 12 are disposed. The injector body structure includes a first injector body portion 38 in which coil 14 and armature 16 are disposed, and a valve body portion 40 in which a valve assembly of injector 12 is at least partly disposed. First injector body portion 38 and valve body portion 40 are fixedly connected, either directly or indirectly, to each other.
Referring to
The actuator unit of fluid injector 12 further includes a pole piece 46 which is fixedly disposed within first injector body portion 38. Coil 14 at least partly surrounds pole piece 46 and armature 16. Pole piece 46 is disposed upstream of armature 16 within injector 12. Pole piece 46 includes a central bore defined axially therethrough.
Armature 16 includes a U-shaped section which defines a pocket in which at least part of a spring 50 is disposed. Spring 50, which is part of the actuator unit, biases movable armature 16 so that armature 16 is spaced apart from pole piece 46 when no current is passed through coil 14. Spring 50 partly extends within the central bore of pole piece 46. An end of spring 50 which extends within pole piece 46 contacts a spring adjustment tube 52. Spring adjustment tube 52 is at least partly disposed within the central bore of pole piece 46, upstream (relative to a direction of flow of reductant through injector 12) of spring 50. Spring adjustment tube 52 includes a bore defined axially therethrough. The throughbore of spring adjustment tube 52 partly defines the fluid path for reductant in fluid injector 12, and defines the only fluid path for reductant through pole piece 46. Due to its engagement with spring 50, spring adjustment tube 52 is used to calibrate the dynamic flow of reductant through fluid injector 12.
Armature 16 further includes one or more channels 60 (
Referring to
As mentioned above, RDU 10 forms part of a non-purge SCR exhaust aftertreatment system. As a result, reductant remains in fluid injector 12 following the vehicle engine being turned off. In example embodiments, fluid injector 12 is configured so that the amount of reductant in fluid injector 12 is reduced. In other words, the total volume of the fluid path for reductant through fluid injector 12 is reduced. By having less space for reductant in injector 12, the amount of reductant in RDU 10 that may potentially freeze is reduced, thereby reducing the susceptibility of injector 12 being damaged by expansion forces from frozen reductant.
In order to reduce the volume of the reductant fluid path in fluid injector 12, the thickness of valve body portion 40 is increased. In addition, pin member 58 is constructed as a solid element such that reductant flows around the outer surface of pin member 58, instead of therethrough. The spacing between the outer surface of pin 58 and the inner surface of valve body portion 40, which partly defines the fluid path for reductant through injector 12, is narrowed. This narrowed portion of the fluid path is the only fluid path for reductant between armature 16 and seat 56 in fluid injector 12. The narrowed fluid path between pin 58 and valve body portion 40 provides a sufficient reductant flow rate through fluid injector 12 for performing reductant injection during normal operation of RDU 10 while at the same time maintaining a relatively small volume of reductant within injector 12 so as to lessen the risk of injector 12 being damage from the reductant therein freezing.
Further, the diameter of the pocket of armature 16, in which spring 50 is at least partly disposed, is reduced, which allows for the thickness of pocket wall 16A of armature 16 to be increased. In an example embodiment, the thickness of pocket wall 16A is between 45% and 75% of the diameter of pocket, such as about 60%. The increase in thickness of pocket wall 16A, as well as the increased thickness of valve body portion 40 and pin member 50 being a solid pin, result in the components of injector 12 being strengthened and thus more resistant to reductant freezing forces.
Still further, the bore of spring adjustment tube 52 is sized for reducing the volume of the reductant fluid path in injector 12. In an example embodiment, the diameter of the bore of spring adjustment tube 52 is between 12% and 22% of the outer diameter of pole piece 46, and particularly between 16% and 19% thereof.
Injector 12 further includes a retaining ring 207 which is disposed in tube member 42 upstream of, and in contact with, cap member 206, as shown in
Referring to
Volume reduction member 208 further includes a bore 208A (
With reference to
According to an example embodiment, fluid injector 12 includes a plurality of orifice discs 212 disposed in a stacked arrangement. The orifice disc stack is disposed against the downstream end of seat 56. In the example embodiment illustrated in
As discussed above, fluid injector 12, and particularly the components thereof, are configured to reduce the volume of the reductant fluid path in injector 12. In example embodiments, the ratio of the volume of the fluid path in fluid injector 12 to a volume of the components of injector 12 (including but not necessarily limited to coil 14, armature 16, pole piece 46, spring adjustment tube 52, volume reduction member 208, volume compensation member 210, filter 204, retaining ring 207, spring 50, pin member 58, seal member 54, seat 56, first injector body portion 20A and valve body portion 40) is between 0.08 and 0.30, and particularly between 0.12 and 0.20, such as about 0.15. These volume amounts are calculated between orthogonal planes relative to the longitudinal axis of fluid injector 12—from a first plane along the open end of tube member 42 (i.e., fluid inlet 30) and a second plane along the lowermost (downstream) surface of second disc 212B (i.e., fluid outlet 32). It is understood that the particular ratio of volume of the reductant path to injector component volume within fluid injector 12 may vary depending upon a number of cost and performance related factors, and may be any value between about 0.08 and about 0.30. Providing a fluid injector having a reduced ratio of reductant fluid path volume to injector component volume to fall within the above range advantageously results in less reductant in injector 12 which reduces the susceptibility of RDU 10 being damaged if the reductant in injector 12 freezes.
In another example embodiment, shown in
As mentioned, the outer diameter of first portion 308A of volume reduction member 308 is less than the outer diameter of second portion 308B thereof. As shown in
Volume reduction member 308 further includes a bore 308C defined in the axial direction through volume rejection member 308, from one axial (top) end to the other axial (bottom) end. Bore 308C is located along the longitudinal axis of volume reduction member 308 and itself forms part of the reductant fluid path for passing reductant through injector 12, and the only reductant fluid path through or around volume reduction member 308. In an example embodiment, the diameter of the bore 308C is between 12% and 20% of the outer diameter of volume reduction member 308, such as about 16%. Because volume reduction member 308 extends to the inner surface of tube member 42 and because the diameter of bore 308C is relatively small relative to the outer diameter of volume reduction member 308, volume reduction member 308 occupies a volume within injector 12 which reduces the space or volume of the reductant fluid path through injector 12, thereby reducing the amount of reductant in injector 12 that could freeze and potentially damage injector 12.
Cap member 306 includes a number of the same characteristics of cap member 206 described above with respect to
In example embodiments, cap member 306 is engaged with and secured to volume reduction member 308. In this way, filter 204, cap member 306 and volume reduction member 308 form a single, unitary and integrated component, as shown in
In the example embodiments, cap member 306 fits over and engages with or otherwise attaches to at least a part of first portion 308A of volume reduction member 308, as shown in
With cap member 306 fitting over first portion 308A of volume reduction member 308, the outer diameter of sidewall 306A is the same or nearly the same as the outer diameter of second portion 308A. See
As discussed above, volume reduction member 308 is constructed from metal, such as stainless steel, according to an example embodiment. In another example embodiment, a part of second portion 308B is constructed from plastic or like compositions. Specifically, as illustrated in
During assembly of injector 12, the single assembly component (filter 204, cap member 306 and volume reduction member 308) is inserted within tube member 42 under pressure while contacting volume compensator 212. Following insertion and while still under pressure, cap member 306 is welded to tube member 42 all along the intersection thereof along the top portion of tube member 42. In an embodiment, the weld connection is a fillet weld.
As shown in
Calibration filter tube 402 further includes elongated second portion 402D which extends in an axial direction from first portion 402A, as shown in
As mentioned, second end 402E of calibration filter tube 402 contacts and engages with spring 50. Due to the engagement between calibration filter tube 402 and spring 50, and the engagement between armature 16 and spring 50, calibration filter tube 402 is used to calibrate the dynamic flow of reductant through fluid injector 12. Specifically, with cap member 306, filter 204 and calibration filter tube 402 being formed as a single, unitary and integrated subassembly component, positioning calibration filter tube 402 in the desired position within tube member 42, prior to welding cap member 306 thereto, is simplified for providing the desired calibrated force for spring 50.
Calibration filter tube 402 is formed from a metal composition, such as stainless steel.
With continued reference to
In an example embodiment, volume reduction member 408 is constructed from a resilient and compressible material, and is compressible in at least the axial direction along fluid injector 12. Volume reduction member 408 being compressible in the axial direction allows for the single assembly component (cap member 306, filter 204 and calibration filter tube 402) to be adjustably positioned within tube member 42 relative to pole piece 46 so that the opening and closing force of the valve assembly of fluid injector 12 may be easily calibrated as desired. In one embodiment, volume reduction member 408 is constructed from closed cell foam. It is understood, though, that volume reduction member 408 may be constructed from other compressible material. If constructed from closed cell foam, volume reduction member 408 is compressible in both axial (longitudinal) and radial (lateral) directions. In an example embodiment, volume reduction member 408 is in a compressed state in fluid injector 12.
Calibration filter tube 502 includes a bore 502A which is axially defined through calibration filter tube 502. At one (upstream) end of calibration filter tube 502, bore 502A is in fluid communication with filter 204 for receiving reductant therefrom. At the other (downstream) end of calibration filter tube 502, bore 502A provides reductant to armature 16. In this way, calibration filter tube 502 forms part of the fluid path for reductant through fluid injector 12, and forms the only such fluid path from filter 204 to armature 16. With the diameter of bore 502A of calibration filter tube 502 being small relative to the inner diameter of tube member 42, the volume of the fluid path for reductant through injector 12 is reduced so as to lessen the adverse impact of reductant freezing therein.
As shown in
Calibration filter tube 502 further includes an elongated second portion 502D which extends in an axial direction from first portion 502A, and an elongated third portion 502E which extends in the axial direction from second portion 502D, as shown in
In an example embodiment, the outer diameter of second portion 502D is larger than the outer diameter of third portion 502E. The outer diameter of third portion 502E is sized for being received in the central bore of pole piece 46.
Calibration filter tube 502 further includes annular tab 502G (
Calibration filter tube 502 is formed from a metal composition, such as stainless steel.
As mentioned, second end 502F of calibration filter tube 502 contacts and engages with spring 50. Due to the engagement between calibration filter tube 502 and spring 50, and the engagement between spring 50 and armature 16, calibration filter tube 502 is used to calibrate the dynamic flow of reductant through fluid injector 12. Specifically, with cap member 306, filter 204 and calibration filter tube 502 being formed as a single, unitary and integrated subassembly component, positioning of calibration filter tube 502 in the desired position within tube member 42, prior to welding cap member 306 thereto, is simplified for providing the desired calibrated force for spring 50 for setting the opposed opening and closing force for the valve assembly of fluid injector 12.
With continued reference to
In an example embodiment, volume reduction member 508 is constructed from compressible material, such as being compressible in at least the axial direction along fluid injector 12. Volume reduction member 508 being compressible in at least the axial direction allows for the single assembly component (cap member 306, filter 204 and calibration filter tube 502) to be adjustably positioned within tube member 42 relative to pole piece 46 so that the valve assembly of fluid injector 12 may be calibrated as desired. In an example embodiment, volume reduction member 508 is in a compressed state in fluid injector 12.
As shown in
Sidewall 508A of volume reduction member 508 undulates in an axial direction, as shown in
In an example embodiment, spacer member 180 is constructed from a compressible, resilient material, such as a rubber composition and closed cell foam. In this way, expansion forces from freezing and/or frozen reductant located in or around armature 16 cause spacer member 180 to be compressed, thereby allowing the expanding/expanded reductant to occupy the space occupied by spacer member 180 absent its compression. This provides available space for the reductant to expand when freezing so that reductant expansion forces are not directed to other components of fluid injector 12. When the frozen reductant melts, spacer member 180 resiliently expands and returns to its largely uncompressed state.
Use of spacer members 180, 180′ results in a compression seal to reduce fluid volume in fluid injector 12, compressing as reductant freezes and expanding as frozen reductant melts, preventing component displacement of other components of injector 12 from freezing forces from the reductant. This is achieved with spacer member 180, 180′ being compressible which can expand and contract at varying temperatures to ensure the space in fluid injector 12 for holding reductant is reduced or minimized. Spacer member 180, 180′ reduces the volume of the reductant fluid path in injector 12 while being compressible so as to absorb reductant freezing forces, thereby resulting in a more robust fluid injector 12. The compressible material of spacer member 180, 180′ is such that the material will expand and contract at various temperatures so as to ensure that the available space for reductant in fluid injector 12 is reduced. Spacer member 180, 180′ absorbs freezing forces and compresses as a result, thereby reducing freezing forces directed to other components and interfaces within fluid injector 12.
Fluid injector 12 of
Freezing reductant that is disposed within bore 502A of calibration filter tube 502 is allowed to expand through holes 502G so that calibration filter tube 502 is less likely to being damaged from expanding reductant disposed therein. With holes 502G being adjacent volume reduction member 408, freezing reductant expanding through holes 502G contact and compress volume reduction member 408 so as to allow for expanding (freezing) reductant to easily exit calibration filter tube 502, thereby reducing or eliminating freezing forces acting thereon.
The reductant flow path through fluid injector 12 may include a fluid path from bore 502A, through holes 502G and into pocket 16A before passing through channels 60 and along the outer surface of pin member 58 before exiting fluid outlet 32. In this case, holes 502G of calibration filter tube 502 form part of the fluid (reductant) path through fluid injector 12.
The example embodiments have been described herein in an illustrative manner, and it is to be understood that the terminology which has been used is intended to be in the nature of words of description rather than of limitation. Obviously, many modifications and variations of the invention are possible in light of the above teachings. The description above is merely exemplary in nature and, thus, variations may be made thereto without departing from the spirit and scope of the invention as defined in the appended claims.
The present application claims the benefit of U.S. provisional application 62/625,317, filed Feb. 1, 2018, and entitled “INJECTOR FOR REDUCTANT DELIVERY UNIT HAVING FLUID VOLUME REDUCTION ASSEMBLY,” the content of which is hereby incorporated by reference herein in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
4957085 | Sverdlin | Sep 1990 | A |
5275341 | Romann et al. | Jan 1994 | A |
5383606 | Stegmaier et al. | Jan 1995 | A |
5516424 | Strohschein | May 1996 | A |
5634597 | Krohn et al. | Jun 1997 | A |
5775600 | Wildeson | Jul 1998 | A |
5794856 | Nally | Aug 1998 | A |
5996910 | Takeda | Dec 1999 | A |
6076802 | Maier | Jun 2000 | A |
6173915 | Cohen et al. | Jan 2001 | B1 |
6199775 | Dallmeyer | Mar 2001 | B1 |
6264112 | Landschoot | Jul 2001 | B1 |
6325049 | Nally | Dec 2001 | B1 |
6328232 | Haltiner, Jr. | Dec 2001 | B1 |
6454192 | Perry | Sep 2002 | B2 |
6676044 | Dallmeyer et al. | Jan 2004 | B2 |
6685112 | Hornby et al. | Feb 2004 | B1 |
6698664 | Dallmeyer et al. | Mar 2004 | B2 |
6834667 | Sumiya et al. | Dec 2004 | B2 |
7128281 | Cho et al. | Oct 2006 | B2 |
7296781 | Akabane | Nov 2007 | B2 |
7309033 | Dallmeyer | Dec 2007 | B2 |
7389952 | Dallmeyer | Jun 2008 | B2 |
7422160 | Dallmeyer | Sep 2008 | B2 |
7429006 | Dallmeyer | Sep 2008 | B2 |
7431226 | Cho et al. | Oct 2008 | B2 |
7481049 | Huber et al. | Jan 2009 | B2 |
7506826 | Miller | Mar 2009 | B2 |
7552880 | Dallmeyer | Jun 2009 | B2 |
7617605 | Fochtman | Nov 2009 | B2 |
7617991 | Wells et al. | Nov 2009 | B2 |
7673818 | Akabane | Mar 2010 | B2 |
7721713 | Hayatani et al. | May 2010 | B2 |
7798131 | Hornby | Sep 2010 | B2 |
7832660 | Imoehl | Nov 2010 | B2 |
7866577 | Yoshimaru et al. | Jan 2011 | B2 |
7886718 | Manubolu et al. | Feb 2011 | B2 |
7931217 | Matsusaka et al. | Apr 2011 | B2 |
7942348 | Reiter | May 2011 | B2 |
7942381 | Sugiyama et al. | May 2011 | B2 |
8002287 | Wagner | Aug 2011 | B2 |
8037868 | Kannan et al. | Oct 2011 | B2 |
8087239 | Bugos et al. | Jan 2012 | B2 |
8215573 | Hornby | Jul 2012 | B2 |
8347605 | Bugos et al. | Jan 2013 | B2 |
8646704 | Yamamoto et al. | Feb 2014 | B2 |
8740113 | Roessle et al. | Jun 2014 | B2 |
8857743 | Shingu et al. | Oct 2014 | B2 |
8973895 | Thomas et al. | Mar 2015 | B2 |
8997463 | Bugos et al. | Apr 2015 | B2 |
8998114 | Olivier et al. | Apr 2015 | B2 |
9033264 | Stier | May 2015 | B2 |
9200604 | Derenthal et al. | Dec 2015 | B2 |
9273581 | Van Vuuren | Mar 2016 | B2 |
9422901 | Suzuki et al. | Aug 2016 | B2 |
9587603 | Hanjagi et al. | Mar 2017 | B2 |
9605638 | Falaschi et al. | Mar 2017 | B2 |
9683472 | Thomas et al. | Jun 2017 | B2 |
9777859 | van Vuuren et al. | Oct 2017 | B2 |
9822749 | Derenthal et al. | Nov 2017 | B2 |
10502112 | Hatfield | Dec 2019 | B2 |
10539057 | VanVuuren | Jan 2020 | B2 |
10655523 | Upadhye | May 2020 | B2 |
20020104904 | McFarland | Aug 2002 | A1 |
20030094513 | Luft | May 2003 | A1 |
20030201343 | Dallmeyer | Oct 2003 | A1 |
20040056113 | Peterson, Jr. | Mar 2004 | A1 |
20040262333 | Huber et al. | Dec 2004 | A1 |
20050023383 | Morton | Feb 2005 | A1 |
20050133630 | Hornby | Jun 2005 | A1 |
20050133639 | Hornby | Jun 2005 | A1 |
20050173869 | Wagner | Aug 2005 | A1 |
20050269426 | Cho | Dec 2005 | A1 |
20060254648 | Maisch et al. | Nov 2006 | A1 |
20070033927 | Homby et al. | Feb 2007 | A1 |
20070057095 | Bayer | Mar 2007 | A1 |
20070095745 | Sebastian | May 2007 | A1 |
20070114299 | Scheffel | May 2007 | A1 |
20070194152 | Abe | Aug 2007 | A1 |
20090065608 | Vogel et al. | Mar 2009 | A1 |
20090179090 | Reiter | Jul 2009 | A1 |
20090184184 | Schwegler | Jul 2009 | A1 |
20090229575 | Giorgetti et al. | Sep 2009 | A1 |
20090230677 | Mannucci et al. | Sep 2009 | A1 |
20100025500 | Pollard et al. | Feb 2010 | A1 |
20100213286 | Grandi | Aug 2010 | A1 |
20100264229 | Facchin | Oct 2010 | A1 |
20100313553 | Cavanagh et al. | Dec 2010 | A1 |
20110192140 | Olivier et al. | Aug 2011 | A1 |
20110258983 | Vosz | Oct 2011 | A1 |
20110309166 | Thomas et al. | Dec 2011 | A1 |
20120031996 | Harvey et al. | Feb 2012 | A1 |
20130026257 | Jalal | Jan 2013 | A1 |
20130061578 | Van Vuuren | Mar 2013 | A1 |
20130292498 | Olivier | Nov 2013 | A1 |
20140001290 | Nishida | Jan 2014 | A1 |
20140008468 | Graner | Jan 2014 | A1 |
20140054394 | Bugos | Feb 2014 | A1 |
20140075923 | Hodgson | Mar 2014 | A1 |
20140138568 | van Vuuren et al. | May 2014 | A1 |
20150059322 | Bugos | Mar 2015 | A1 |
20150102241 | Sebastian | Apr 2015 | A1 |
20150115051 | Van Vuuren | Apr 2015 | A1 |
20150369176 | Ittlinger et al. | Dec 2015 | A1 |
20170101966 | Filippi et al. | Apr 2017 | A1 |
20180023438 | McFarland | Jan 2018 | A1 |
20180058291 | Bugos et al. | Mar 2018 | A1 |
20180179938 | Shaull et al. | Jun 2018 | A1 |
20180202404 | Jovovic et al. | Jul 2018 | A1 |
20180230955 | Bleeck | Aug 2018 | A1 |
20180238217 | Devito | Aug 2018 | A1 |
20190078482 | Cosby | Mar 2019 | A1 |
20190078485 | VanVuuren | Mar 2019 | A1 |
20190078486 | Hatfield | Mar 2019 | A1 |
20190078487 | Hatfield | Mar 2019 | A1 |
20190078488 | Hatfield | Mar 2019 | A1 |
20190234274 | Hatfield | Aug 2019 | A1 |
20190293040 | Pobuda | Sep 2019 | A1 |
20190308206 | Ummel | Oct 2019 | A1 |
Number | Date | Country |
---|---|---|
10058015 | May 2002 | DE |
102007026892 | Dec 2008 | DE |
102008041544 | Mar 2010 | DE |
102008042987 | Apr 2010 | DE |
102009000107 | Jul 2010 | DE |
102010029254 | Dec 2011 | DE |
102010039052 | Feb 2012 | DE |
102010045509 | Mar 2012 | DE |
102011018181 | Feb 2014 | DE |
102012021664 | May 2014 | DE |
102015217673 | Mar 2017 | DE |
1965049 | Sep 2008 | EP |
2002327660 | Nov 2002 | JP |
4200003 | May 2004 | JP |
2004316520 | Nov 2004 | JP |
2009504985 | Feb 2009 | JP |
2010216483 | Sep 2010 | JP |
307891 | Feb 1994 | KR |
20130140871 | Dec 2013 | KR |
102014092848 | Jul 2014 | KR |
20170045845 | Mar 2017 | WO |
Entry |
---|
“Marvac 125—Mechanical Properties Tape,” Vacuumschmelze GmbH & Co., http://www.vacuumschmelze.de/de/produkte/halbzeug-teile/physikalisch/federlegierungen/marvac-125/marvac-125-mechanische-eigenschaften-band.html (English language web page is http://www.vacuumschmelze.com/en/products/materials-parts/physical/spring-alloys/marvac-125/marvac-125-mechanische-eigenschaften-band.html); May 15, 2013 (as reported by Vacuumschmlze GmbH and listed on web page; content captured Mar. 14, 2018). |
“Marvac 125—Physical Properties,” Vacuumschmelze GmbH & Co., http://www.vacuumschmelze.de/de/produkte/halbzeug-teile/physikalisch/federlegierungen/marvac-125/marvac-125-physikalische-eigenschaften.html (English language web page is http://www.vacuumschmelze.com/en/products/materials-parts/physical/spring-alloys/marvac-125/marvac-125-physical-properties.html); May 15, 2013 (as reported by Vacuumschmlze GmbH and listed on web page; content captured Mar. 14, 2018). |
“Marvac 125—Chemical Composition,” Vacuumschmelze GmbH & Co., http://www.vacuumschmelze.de/de/produkte/halbzeug-teile/physikalisch/federlegierungen/marvac-125/marvac-125-chemische-zusammensetzung.html (English language web page is http://www.vacuumschmelze.com/en/products/materials-parts/physical/spring-alloys/marvac-125/marvac-125-chemical-composition.html); May 15, 2013 (as reported by Vacuumschmlze GmbH and listed on web page; content captured on Mar. 14, 2018). |
European Search Report dated Mar. 26, 2019 for counterpart EP patent application 19154813.0. |
File History of U.S. Appl. No. 15/704,402, including non-final Office Action dated Nov. 25, 2019. |
File History of U.S. Appl. No. 15/704,268, now U.S. Pat. No. 10,539,057, including non-final Office Action dated May 1, 2019. |
File History of U.S. Appl. No. 15/704,294, now U.S. Pat. No. 10,502,112, including non-final Office Action dated Apr. 4, 2019. |
File History of U.S. Appl. No. 15/922,548, including non-final Office Action dated Dec. 12, 2019. |
Final Office Action for U.S. Appl. No. 15/922,548, dated Jun. 15, 2020. |
Final Office Action for U.S. Appl. No. 15/704,402, dated Jun. 2, 2020. |
Number | Date | Country | |
---|---|---|---|
20190234274 A1 | Aug 2019 | US |
Number | Date | Country | |
---|---|---|---|
62625317 | Feb 2018 | US |