Information
-
Patent Grant
-
6471318
-
Patent Number
6,471,318
-
Date Filed
Wednesday, January 23, 200222 years ago
-
Date Issued
Tuesday, October 29, 200222 years ago
-
Inventors
-
Original Assignees
-
Examiners
- Barlow; John
- Stephens; Juanita
Agents
- Morgan, Lewis & Bockius LLP
-
CPC
-
US Classifications
Field of Search
US
- 347 5
- 347 9
- 347 10
- 347 11
- 347 57
- 347 60
- 347 13
- 347 14
- 347 15
- 347 56
- 347 42
- 347 65
- 347 94
-
International Classifications
-
Abstract
A driving condition setting method of an ink jet recording head enables stable discharge of an ink drop irrespective of a difference in a channel volume. In a thermal ink jet recording head, the displacement of a distance (channel volume) from a heating element to a nozzle surface is stored as data into a memory. The ink jet recording head is mounted on an ink jet recording device. A control unit of the ink jet recording device reads the data so as to set a driving condition (the number of pre-pulses) of the heating element based on the data. Therefore, even when the channel volume is displaced by a production error, an ink discharge state can be almost constant, and stable printing performance can be ensured.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an ink jet recording head which can discharge an ink drop onto a recording medium corresponding to image information for recording, a driving condition setting method thereof, and an ink jet recording device.
2. Description of the Related Art
As an ink jet recording method which can discharge an ink drop from a nozzle onto paper corresponding to an image signal for recording, there is a thermal ink jet method including the steps of: applying an electric pulse, as a driving force for discharging an ink drop from a nozzle, to an electrothermal conversion element (hereinafter, referred to as heating element); producing a bubble by heat generation of a heating element; and discharging an ink drop from the nozzle by pressure of the bubble.
The thermal ink jet method has the problem that the ink temperature is raised by discharge of an ink drop so that the volume of the ink drop is varied due to viscosity change.
To solve this, as shown in U.S. Pat. No. 2,783,647 (hereinafter, referred to as a Related Art
1
), there is proposed an ink jet recording method in which a bubble produced on a heating element grows to be communicated to atmosphere so as to discharge an ink drop having a constant volume irrespective of environment temperature and head temperature. This will not allow a bubble to disappear on the heating element. Therefore no cavitation damage when a bubble disappears can be given to the heating element. The life of the heating element can be increased.
The Related Art
1
also discloses that, in order to prevent image contamination due to splash or mist produced when a bubble is communicated to atmosphere, a bubble is communicated to atmosphere on condition that the internal pressure of the bubble is lower than the atmospheric pressure.
Ink mist is attached onto paper because a bubble is communicated to atmosphere before the internal pressure of the bubble produced by driving a heating element is lower than the atmospheric pressure, whereby a pressure gradient is produced from a nozzle to atmosphere. A bubble is communicated to atmosphere after the internal pressure of the bubble is lower than the atmospheric pressure to provide a pressure gradient toward the inside of a nozzle, whereby ink mist is prevented from being attached onto paper.
To achieve the abovementioned relation, the relation between timing for communicating atmosphere and a bubble to each other and a channel volume from a heating element to a nozzle will be described with reference to
FIG. 13
showing typical change of bubble internal pressure with time.
FIG. 13
shows results of head constructions a, b and c which change a distance from a heating element to a nozzle to vary a channel volume in which the driving condition (bubble volume produced) of a heating element is constant to calculate timing for communicating a bubble to atmosphere by a fluid simulation. Here, when the respective channel volumes are Va, Vb and Vc, the relation is Va<Vb<Vc.
As shown in
FIG. 13
, in the construction a in which a channel volume from a heating element to a nozzle is too small, a bubble is communicated to atmosphere (the bubble internal pressure is higher than the atmospheric pressure) before time t
1
at which the bubble internal pressure and the atmospheric pressure are equal to each other, whereby ink mist is attached onto paper. In the construction c in which a channel volume from a heating element to a nozzle is too large, a bubble is not communicated to atmosphere, whereby the abovementioned effect for discharging an ink drop having a constant volume irrespective of temperature and for increasing the life of the heating element cannot be obtained.
The relation between a channel volume from a heating element to a nozzle and a driving condition of the heating element (the volume of a bubble produced by the heating element) governs timing for communicating atmosphere and a bubble to each other.
From such a point of view, U.S. Pat. No. 2,877,589 (hereinafter, referred to as a Related Art
2
) discloses that the size of a heating element and a channel volume to a nozzle are defined within a certain range.
The Related Arts
1
and
2
each disclose a construction which can prevent ink mist contamination and discharge an ink drop having a constant volume irrespective of temperature.
It is difficult, however, to produce a channel volume within a certain range due to a production error of an ink jet recording head. In the production process of an ink jet recording head (head chip), the following factors which fluctuate a channel volume from a heating element to a nozzle can be considered.
For example, in an ink jet recording head in which a nozzle plate is stuck onto a member formed with an ink channel to form a nozzle in the nozzle plate, the thickness of the nozzle plate may not be a desired thickness and, when forming a nozzle, a nozzle of a desired size may not be formed.
In addition, in an ink jet recording head in which a channel substrate formed with a channel and a heating element substrate formed with a heating element are joined together so as to form a nozzle surface by dicing, the dicing position may be displaced.
In such a case, the channel volume from a heating element to a nozzle is outside the defined range. As in the Related Arts
1
and
2
, atmosphere and a bubble cannot be communicated to each other at a predetermined timing, so that desired operations (discharge of an ink drop having a constant volume and prevention of ink mist contamination) cannot be achieved.
However, when the allowed volume of a channel size is strictly defined in order to allow a bubble volume and a channel volume to be in a predetermined relation, the yield of the ink jet recording head in the head production process can be lowered and the production cost can be increased.
SUMMARY OF THE INVENTION
The present invention has been made in view of the above circumstances and provides a driving condition setting method of an ink jet recording head, an ink jet recording head, and an ink jet recording device, which can ensure desired printing performance irrespective of fluctuation of the channel volume for each head chip.
According to the present invention, a driving condition setting method of an ink jet recording head having an individual channel in which a heating element is placed for heating ink to produce a bubble and an ink discharge portion at an edge of the individual channel, includes the step of setting a driving condition of the heating element corresponding to a difference in a channel volume of the individual channel from the heating element to the ink discharge portion due to a production error.
In this manner, a driving condition applied to a heating element corresponding to a difference in a channel volume of an individual channel from the heating element to the ink discharge portion is set. Specifically, in the ink jet recording head production process, when a channel volume from the heating element to the ink discharge portion is displaced from a predetermined value, the condition to drive a heating element is changed corresponding to the displacement amount to vary the volume of a bubble produced by the heating element. The channel volume from the heating element to the nozzle and the bubble volume are allowed to be in a predetermined relation. For example, when a channel volume is small, energy to applied to the heating element is lowered to decrease the volume of a bubble produced in ink. When a channel volume is large, energy to be applied to the heating element is raised to increase the volume of a bubble produced in ink.
The bubble volume and the channel volume are allowed to be in a predetermined relation. When ink is discharged, a bubble can be communicated to atmosphere at any time at the internal pressure of the bubble lower than the atmospheric pressure. Therefore, an ink drop having a constant volume can be discharged irrespective of environment temperature and head temperature, and image deterioration due to splash or mist can be prevented.
An ink jet recording head of the present invention includes: an individual channel in which a heating element is placed for heating ink to produce a bubble; an ink discharge portion at an edge of the individual channel; and a data holding unit for storing channel volume data based on a channel volume of the individual channel from the heating element to the ink discharge portion.
The ink jet recording head is provided with a data holding unit for storing channel volume data. Therefore, even when the production accuracy of the ink jet recording head is low, a driving condition of a heating element is set based on the channel volume data so as to allow the channel volume and the bubble volume to be in a predetermined relation. The ink jet recording head which can suppress the volume fluctuation of an ink drop with temperature change and achieve prevention of ink mist contamination can be obtained without lowering the yield.
An ink jet recording device of the present invention includes a driving condition setting part which reads channel volume data of the recording head to set a driving condition of the heating element by mounting the ink jet recording head according to one aspect of the present invention.
The abovementioned ink jet recording head is mounted to read the channel volume data of the ink jet recording head and set a driving condition of a heating element according to the data. Therefore, the bubble size and the channel volume of the ink jet recording head are allowed to be in a predetermined relation, and prevention of ink mist contamination and a constant ink drop volume can be achieved.
In the ink jet recording head, a position of the heating element is set so that a bubble produced on the heating element grows to be communicated to atmosphere, thereby discharging an ink drop.
In the ink jet recording head, a unique driving condition data corresponding to head chip dicing displacement due to a production error is held for each head chip.
BRIEF DESCRIPTION OF THE DRAWINGS
Preferred embodiments of the present invention will be described in detail based on the followings, wherein:
FIG. 1
is a schematic sectional view of an ink jet recording head according to an embodiment of the present invention;
FIG. 2
is a cross-sectional view taken along line A—A of
FIG. 1
;
FIG. 3
is a diagram of assistance in explaining an ink jet recording head production state according to the embodiment of the present invention;
FIG. 4
is a plan view showing an example of a pattern for inspecting a distance from a heating element to a nozzle formed on a substrate according to the embodiment of the present invention;
FIG. 5
is a front view of an ink jet recording head showing a state that the pattern is exposed from the nozzle surface;
FIG. 6
is a table showing classification based on a dicing position in the embodiment;
FIG. 7
is a perspective view showing an ink jet recording device according to the embodiment of the present invention;
FIG. 8
is a block diagram showing a control unit of an ink jet recording head according to the embodiment of the present invention;
FIG. 9
is a driving pulse setting condition table corresponding to classification of a nozzle dicing position according to the embodiment of the present invention;
FIG. 10
is a pulse waveform diagram showing driving pulses for driving a heating element according to the embodiment of the present invention;
FIG. 11
is a diagram showing the relation between head temperature and discharged ink drop amounts according to the embodiment;
FIGS. 12A
to
12
E is a schematic diagram of assistance in explaining ink drop phenomena in the ink jet recording head according to the embodiment of the present invention; and
FIG. 13
is a graph showing change over time of bubble internal pressure of the ink jet recording head.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
An ink jet recording head, a driving condition setting method thereof, and an ink jet recording device according to an embodiment of the present invention will be described.
As shown in
FIGS. 1 and 2
, an ink jet recording head
10
is formed by joining a heating element substrate
12
to a channel substrate
14
. Ink supplied from an ink supply opening
16
opened into the surface of the channel substrate
14
passes through a common liquid chamber
18
and an individual channel
20
and is discharged, as an ink drop, from a nozzle
22
opened into a nozzle end surface
21
.
As shown in
FIG. 2
, near the individual channel
20
of the common liquid chamber
18
, a filter
24
formed with pillars at fixed intervals is formed so as to prevent the individual channel
20
from being clogged by particles of dust flowed into the common liquid chamber
18
and ink drop discharge from being disabled.
The individual channel
20
is provided at the nozzle side with a forward throttle
26
and at the common liquid chamber side with a rearward throttle
28
, and with a recession
30
. An ink drop can be efficiently discharged by the later-described bubble.
The heating element substrate
12
is formed in its surface with a protective layer
31
in order to protect a circuit formed on the substrate surface from ink and a heating element
32
exposed to the surface of the protective layer
31
is placed in the position corresponding to the recession
30
of the channel substrate
14
.
The ink jet recording head
10
has a memory
64
(see
FIG. 8
) which stores the later-described class information corresponding to a channel volume of the individual channel
20
from the heating element
32
to the nozzle
22
. In this embodiment, the class information is a production error (displacement) amount of a distance (dicing position) L from the edge of the heating element
32
to the nozzle end surface
21
of the individual channel
20
.
A method for detecting the production error amount will be described simply hereinbelow with a method for producing the ink jet recording head
10
.
The method for producing the ink jet recording head
10
will be simply described with reference to FIG.
3
.
Plural channel substrates
14
are produced on a disk-like substrate
14
A. As shown in Japanese Published Unexamined Patent Application No. Hei 11-227208, into a portion corresponding to each of the channel substrates
14
formed on the substrate
14
A, the ink supply opening
16
and the common liquid chamber
18
for supplying ink from an external ink tank to the ink jet recording head
10
are produced by wet anisotropic etching. The individual channel
20
is produced by reactive ion etching because the shape accuracy is required.
Plural heating element substrates
12
are produced on a disk-like substrate
12
A. The heating element
32
is formed into a portion corresponding to each of the heating element substrates
12
formed on the substrate
12
A.
The channel substrate
14
and the heating element substrate
12
formed in this manner are joined together after alignment and are then cut in a rectangular shape along a dicing line
38
by means of, e.g., a dicer for separation, thereby providing the individual ink jet recording heads
10
. At this time, the diced end surface of the substrates
12
A and
14
A is the nozzle surface
21
of the ink jet recording head
10
and the nozzle
22
is opened into the nozzle surface
21
.
As shown in Japanese Published Unexamined Patent Application No. 2000-243674, a pattern which can detect the dicing position (production error) from the nozzle surface
21
in the position across the dicing line
38
on the substrate
12
A is formed on the substrate
12
A by, for example, A
1
. One example of this pattern is shown in FIG.
4
.
Two linear patterns
34
A and
34
B which are not parallel with each other are formed across the dicing line
38
. The dicing position (a distance L from the edge of the heating element
32
to the nozzle surface
21
) is detected by a distance J between the patterns
34
A and
34
B exposed from the nozzle surface
21
by dicing (see FIGS.
4
and
5
).
When the dicing position is displaced from the designed value, the distance J between the patterns
34
A and
34
B is changed in the cut nozzle surface
21
. The distance J is measured in the head production process or the inspection process to detect the dicing position, that is, the displacement amount of the distance L from the heating element
32
to the nozzle
22
.
The displacement amount of the channel volume should be obtained here. In the head production method, the individual channel
20
and the nozzle
22
are formed by reactive ion etching. The production accuracy of the channel is very high, so that the channel cross-sectional area and the nozzle area can be produced as designed mostly. When the displacement amount of the dicing position is detected, a displacement amount of a channel volume from the heating element
32
to the nozzle
22
from the designed value can be assumed.
A displacement amount of the dicing position (the distance L from the heating element
32
to the nozzle surface
21
) is calculated based on the distance J detected in the inspection process to perform five-stage class classification as shown in
FIG. 6
based on the displacement amount. The class information is written into the memory
64
(see
FIG. 8
) of the ink jet recording head
10
by an input device. For example, when a displacement amount of the dicing position due to a production error of the ink jet recording head
10
is within ±2 μm, information of class
3
is written. The class information is written into the memory
64
, but may be written into a fuse circuit to cut off wiring.
An ink jet recording device mounting an ink cartridge formed integrally with such an ink jet recording head
10
will be described.
As shown in
FIG. 7
, an ink jet recording device
40
has an ink cartridge
46
mounted on a carriage
44
moved along a guide shaft
42
. An ink drop is discharged from the ink jet recording head
10
integrally provided at the edge of the ink cartridge onto paper
48
to record an image onto the paper
48
.
As shown in
FIG. 8
, the ink jet recording device
40
has a control unit
50
. The control unit
50
has a CPU
52
, a ROM
54
, a RAM
56
and an I/O
58
, which are connected by a bus
60
. The ROM
54
stores the later-described driving condition setting table. The control unit
50
also has a pulse generator
62
for outputting a pulse signal for driving the heating element
32
.
A pulse signal outputted from the pulse generator
62
to the heating element
32
has pre-pulses
66
and a main pulse
68
, as shown in FIG.
10
and changes the number of the pre-pulses based on the later-described driving condition set based on the class information.
As shown in
FIG. 9
, the driving condition setting table sets a driving pulse condition for driving the heating element
32
based on the class information read from the memory
64
of the ink jet recording head
10
.
The ink jet recording head
10
inputs a driving pulse corresponding to a channel volume to the heating element
32
. As shown in schematic diagrams of
FIGS. 12A
to
12
E, the ink jet recording head
10
changes the volume of a bubble
72
produced in ink
70
of the individual channel
20
by the heating element
32
, and communicates the bubble
72
to atmosphere when discharging an ink drop
74
, thereby discharging the ink drop
74
having a constant volume.
The internal pressure of the bubble
72
produced by driving the heating element
32
is changed as shown in FIG.
13
. After the internal pressure of the bubble is lower than the atmospheric pressure (after time t
1
), the bubble is communicated to atmosphere. The driving pulse condition is set in this manner so that the bubble internal pressure is lower than the atmospheric pressure when the bubble is communicated to the atmosphere, and ink mist is drawn into the nozzle and cannot be attached onto the paper.
However, when the channel volume is fluctuated due to a production error of the ink jet recording head
10
, the ink discharge state is changed in the case where the driving condition (driving pulse) of the heating element
32
is constant. For example, in the case where a channel volume is decreased, the bubble
72
is communicated to atmosphere when the internal pressure of the bubble
72
is higher than the atmospheric pressure, whereby ink mist is attached onto the paper. When a channel volume is increased, the bubble
72
cannot be communicated to atmosphere so that the volume of the ink drop
72
is fluctuated due to environment temperature and head temperature.
A table for setting a driving condition (the number of the pre-pulses) corresponding to the displacement amount of the dicing position (channel volume) is provided.
Specifically, as shown in
FIG. 6
, driving conditions A to E respectively correspond to classes
1
to
5
of the head. The condition C of these is a normal driving pulse condition. To the ink jet recording head
10
having a channel volume smaller than a predetermined channel volume, that is, to the ink jet recording head
10
classified into class
1
or
2
, a driving condition having the number of the pre-pulses
66
smaller than that of the condition C is applied so as to make the volume of the bubble
72
produced by the heating element
32
smaller than normal. This makes the volume of the bubble
72
produced by the heating element
32
small. The bubble volume and the channel volume are allowed to be in a predetermined relation. The bubble
72
is thus communicated to atmosphere with predetermined timing. To the ink jet recording head
10
having a channel volume larger than a predetermined channel volume, that is, to the ink jet recording head
10
classified into class
4
or
5
, the number of the pre-pulses
66
is larger than that of the condition C and the volume of the bubble
72
produced by the heating element
32
is larger than normal to discharge ink with predetermined timing. In this embodiment, in both cases, the interval between the pre-pulses is 0.3 μs.
The operation (the driving condition setting method) of the ink jet recording head
10
(the ink jet recording device
40
) thus constructed will be described.
The ink cartridge
46
is mounted on the ink jet recording device
10
. The control unit
50
reads the class information from the memory
64
of the ink jet recording head
10
to set a driving condition based on the driving condition setting table stored into the ROM
54
.
For example, when a displacement amount of the dicing position due to a production error of the ink jet recording head
10
is within ±2 μm, the class information shows class
3
. The driving condition C with four pre-pulses
66
of 0.1 μs and one main pulse
68
of 1.8 μs is set. The driving condition C is stored into the RAM.
When an image output signal is inputted to the ink jet recording device
40
, the pulse generator
62
of the control unit
50
generates a pulse signal based on the driving condition C stored into the RAM
54
and then outputs the pulse signal to the ink jet recording head
10
(the heating element
32
). In other words, a pulse signal with four pre-pulses
66
of 0.1 μs and one main pulse
68
of 1.8 μs for discharge of one ink drop is outputted to drive the heating element
32
. As a result, the channel volume and the volume of the bubble
72
produced in ink of the individual channel
20
are allowed to be in a predetermined relation. Atmosphere and the bubble
72
are communicated to each other before discharging the ink drop
74
to make the volume of the ink drop
74
constant irrespective of the head temperature. The internal pressure of the bubble
72
is lower then the atmospheric pressure when the bubble
72
is communicated to the atmosphere. Thus, ink mist cannot be attached onto the paper.
In this manner, the ink jet recording head
10
holds as class information the respective channel volume information (the displacement amount of the dicing position). The ink jet recording head
10
(the ink cartridge
46
) is mounted on the ink jet recording device
40
. The control unit
50
of the ink jet recording device
40
reads the class information to set a driving condition of the heating element
32
according to the channel volume. An ink drop having a constant volume can be discharged regardless of a production error of the ink jet recording head
10
irrespective of change of the environment temperature and head temperature. Ink mist attachment onto the paper
48
can be prevented.
FIG. 11
shows the relation between the head temperature and the discharged ink drop amount when the ink jet recording heads classified into classes
1
to
5
are driven under the respective driving conditions. The designed ink drop volume is 15 pl.
The discharged ink drop volumes are displaced from the designed value of 15 pl based on the classes (the displacement amounts of the dicing position). It is confirmed that ink drops having an almost constant volume can be discharged even when the head temperature is changed. Image deterioration due to splash or mist cannot be found in any of the ink jet recording heads.
The ink drop amount difference based on the head class is varied for each printer. When it is above the minimum print density required, the difference of this degree will not be a significant problem.
In this embodiment, the type in which a bubble is communicated to atmosphere when discharging ink is described. This embodiment can also be applied to a type in which a bubble is not communicated to atmosphere.
As a pattern for inspecting a distance from the heating element
32
to the nozzle surface
21
, that is, a channel volume, as shown in Japanese Published Unexamined Patent Application No. Hei 5-24203, grooves are provided at the channel substrate side by the same method as the channel production method, and the number of the grooves is counted from the nozzle surface to measure a distance from the heating element
32
to the nozzle surface
21
.
When the method for producing the ink jet recording head
10
is different, a driving condition may be set based on the displacement amount of a channel volume (or a parameter thereof) in place of displacement of the dicing position.
In an ink jet recording head which can communicate a bubble to atmosphere so as to discharge an ink drop having a constant volume irrespective of environment temperature and head temperature, a driving condition of the heating element is changed by a channel volume from the heating element to the nozzle surface. Discharge of an ink drop having a constant volume can be implemented irrespective of the displacement of the channel volume and image deterioration due to splash or mist can be prevented. The ink jet recording head having the abovementioned effect can be produced without lowering the yield.
The entire disclosure of Japanese Patent Application No. 2001-37441 filed on Feb. 14, 2001 including specification, claims, drawings and abstract is incorporated herein by reference in its entirety.
Claims
- 1. A driving condition setting method of an ink jet recording head having an individual channel in which a heating element is placed for heating ink to produce a bubble and an ink discharge portion at an edge of the individual channel, the method comprising:setting a driving condition of the heating element corresponding to a difference in a channel volume of the individual channel from the heating element to the discharge portion due to a production error.
- 2. The driving condition setting method of an ink jet recording head according to claim 1, wherein the difference in a channel volume from the heating element to the discharge portion is a difference in a distance from the heating element to the discharge portion.
- 3. The driving condition setting method of an ink jet recording head according to claim 1, wherein a driving condition of the heating element is set so that a bubble produced in ink by driving the heating element is communicated to atmosphere when an ink drop is discharged from the ink discharge portion.
- 4. An ink jet recording head comprising:an individual channel in which a heating element is placed for heating ink to produce a bubble; an ink discharge portion at an edge of the individual channel; and a data holding unit that stores channel volume data based on a channel volume of the individual channel from the heating element to the ink discharge portion.
- 5. The ink jet recording head according to claim 4, wherein the channel volume data is distance data from the heating element to the ink discharge portion.
- 6. The ink jet recording head according to claim 4, wherein the channel volume data is production error data.
- 7. The ink jet recording head according to claim 4, wherein the bubble produced in the ink by driving the heat element is communicated to the atmosphere when an ink drop is discharged from the ink discharge portion.
- 8. The ink jet recording head according to claim 4, comprising a substrate with a groove as the individual channel and a substrate with a heating element formed, the both substrates being joined and cut to form a nozzle surface as the discharge portion.
- 9. The ink jet recording head according to claim 8, wherein the individual channel and an opening at the ink discharge portion are formed by reactive ion etching.
- 10. The ink jet recording head according to claim 4, wherein a position of the heating element is set so that a bubble produced on the heating element grows to be communicated to the atmosphere, thereby discharging an ink drop.
- 11. The ink jet recording head according to claim 4, wherein unique driving condition data is held for each head chip.
- 12. An ink jet recording device comprising:a driving condition setting part which reads, when an ink jet recording head is mounted to the device, channel volume data of the ink jet recording head to set a driving condition of a heating element of the ink jet recording head, wherein the ink jet recording head comprises: an individual channel in which the heating element is placed for heating ink to produce a bubble; an ink discharge portion at an edge of the individual channel; and a data holding unit that stores the channel volume data based on a channel volume of the individual channel from the heating element to the ink discharge portion.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2001-037441 |
Feb 2001 |
JP |
|
US Referenced Citations (5)
Foreign Referenced Citations (5)
Number |
Date |
Country |
5-24203 |
Feb 1993 |
JP |
2783647 |
May 1998 |
JP |
2877589 |
Jan 1999 |
JP |
11-227208 |
Aug 1999 |
JP |
2000-243674 |
Sep 2000 |
JP |