The present disclosure relates to an ink storage container.
There has heretofore been known an ink storage container for replenishing ink into an ink tank of an ink ejection apparatus such as an ink jet printer. Functions required for the ink storage container include visibility of contents, ease of pouring ink, and storage reliability (see Japanese Patent Laid-Open No. JP_H10-245080 (hereinafter referred to as Document 1) and the like). For example, poor visibility of contents leads to a possibility of a user misunderstanding that there is more ink remaining than there actually is as he/she visually checks an ink storage container that is being used. It is therefore desirable to ensure the transparency of the container so that the contents can be seen at a glance.
At the same time, the ease of pouring is also important. There are various ideas, for example, such as providing a bottle with a tapered nozzle that can be inserted into a tank of a printer, providing a filling pin at the tip of a bottle that can be inserted into a tank of a printer, and providing a pin on the tank side of a printer while providing a bottle with a slot.
Document 1 also mentions the improvement in visibility of the remaining amount and the convenience of filling ink.
A wide variety of inks have recently been developed, and their characteristics also vary. Examples include inks for printing on materials other than paper, some of which are even used for a material such as vinyl chloride that is difficult for ink to penetrate.
In order to ensure print fixability on a material that is difficult for water to penetrate, such inks can use more organic solvents than typical inks intended for printing on paper. Such an ink containing a large amount of organic solvent tends to have a low surface tension. Therefore, in some cases, even in an ink storage container made of a material described in Patent Document 1, ink may soak and spread on its inner wall.
Also, as for the ease of pouring, a bellows structure described in Patent Document 1 is a movable part, and thus may wear out and break if used repeatedly.
The present disclosure provides an ink storage container having an ink storage unit that stores ink therein, and an ink filling unit communicated with the ink storage unit, wherein the ink storage unit is a region where surface free energy of its inner wall is lower than a surface tension of the ink, and the ink filling unit is a region where surface free energy of its inner wall portion that comes into contact with the ink in a case of pouring the ink from the ink storage unit is higher than the surface tension of the ink.
Further features of the present invention will become apparent from the following description of exemplary embodiments with reference to the attached drawings.
Preferred exemplary embodiments of the present disclosure will be described. Note that, in all of the following exemplary embodiments, shapes and structures are not limited to those exemplified as the exemplary embodiments, and the designer may arbitrarily change, add or omit them within the scope of the claims.
First, a configuration of an ink ejection apparatus to which an ink storage container according to the present embodiment can be applied will be described. In the present embodiment, the ink ejection apparatus will be described as an ink jet printer, but the ink storage container according to the present embodiment may be used in other ink ejection apparatuses.
The ink jet printer 1 repeats reciprocating of the print head (main scanning) and conveyance of printing sheets such as general printing paper, special paper, and OHP film at a predetermined pitch (sub scanning). The ink jet printer 1 according to the present embodiment is a serial ink jet printer that forms characters, symbols, images, and the like by selectively ejecting ink as an example from the print head and depositing the ink on the printing sheet while synchronizing with the main scanning and sub scanning.
In
The print head has a plurality of ejection port arrays, each of which ejects ink of a different color. The print head is equipped with a printing element unit. In the printing element unit, a plurality of electrothermal conversion elements (heaters) or piezoelectric elements are arranged as ejection energy generating elements for ejecting ink. The ejection energy generating element ejects ink supplied through an ink supply path (the tube 3 and the like) from the ejection port. In a case of using the electrothermal conversion element as the ejection energy generating element, for example, the heater generates heat to generate bubbles in the ink, and this bubble generating energy is used to eject the ink from the ejection port.
The ink tank 2 has a gas-liquid exchange membrane 7, which can always keep the pressure inside the ink tank 2 equal to atmospheric pressure even if the ink in the tank is consumed with the plug 6 attached to the tank.
Next, a configuration of an ink storage container 100 will be described.
The ink storage container 100 may have a cap unit 30 to prevent ink from leaking or drying. A packing or the like (not shown) may also be sandwiched, if necessary, between the ink storage unit 10 and the ink filling unit 20 to improve their sealability.
In the present embodiment, description is given of an example where the ink storage unit 10 and the ink filling unit 20 are plugged with a screw structure, and the cap unit 30 and the ink filling unit 20 are plugged by fitting, but the present disclosure is not limited thereto and any form or combination may be used as long as the ink does not spill.
In the present embodiment, the entire inner surface area of the ink storage unit 10 is referred to as an ink storage unit inner wall, and is denoted by reference numeral 11 in
In the present embodiment, the surface free energy of the ink storage unit inner wall 11 is lower than the surface tension of the ink accommodated therein. On the other hand, the surface free energy of the ink filling unit inner wall 21 is higher than the surface tension of the ink accommodated therein. As for the threaded part 22, the surface free energy is not particularly specified, but may be the same as or different from that of the ink filling unit inner wall 21.
In a case of using ink with a surface tension of about 25 mN/m, for example, it is preferable that the ink storage unit inner wall 11 is made of a material whose surface free energy is less than or equal to about 18 mN/m, and that the ink filling unit inner wall 21 is made of a material whose surface free energy is more than or equal to about 29 mN/m.
Here, the relationship between the surface tension of ink and the surface free energy of a solid in contact with the ink will be described.
For example, if the ink dries as it soaks and spreads on a wall surface 11 of the ink storage unit 10, ink components remain on the wall surface, leading to poor visibility. Therefore, it is preferable for the ink to show a tendency of aggregating in the ink storage unit 10, so that the user can visually confirm the contents accurately. During ink filling, on the other hand, the ink flows along the ink filling unit inner wall 21 into the ink tank. Therefore, the filling is facilitated if the ink soaks and spreads as much as possible.
The surface free energy of a solid is generally defined as a value measured using a method generally called an OWRK method. The OWRK method is a method wherein two or more types of ink reagents with known physical properties are used to measure the contact angle of each reagent and the solid and calculate the surface free energy from the physical property values of the ink and the measured value of the contact angle.
The surface tension of the ink is defined as a value measured using the Wilhelmy method (also known as the plate method). The Wilhelmy method is a method of calculating surface tension by inserting a solid platinum plate into ink to be measured and measuring the force generated in the direction in which the ink pulls the plate.
Furthermore, there are a variety of ways, in general, for adjusting the surface tension of ink, but the present disclosure does not limit the adjustment method. For example, there is a method of adjusting the surface tension by adjusting the amount of surfactant in ink. Examples of the surfactant include acetylene glycol-based surfactant, polyoxyethylene alkyl ether, and the like.
In the present embodiment, the ink surface tension (about 25 mN/m) exceeds the surface free energy (about 18 mN/m) of the ink storage unit inner wall 11. This increases the aggregating force of the ink on the inner wall surface of the ink storage unit 10, preventing the ink from soaking and spreading. It is important that the surface free energy of the ink storage unit inner wall 11 is lower than the surface tension of the ink. It is preferable that the materials are selected based on the condition as described above that the surface free energy of the ink storage unit inner wall 11 is smaller than the surface tension of the ink by 5 mN/m or more.
The surface free energy (about 29 mN/m) of the ink filling unit inner wall 21 exceeds the ink surface tension (about 25 mN/m), and thus the ink tends to soak and spread.
Therefore, in the present embodiment, it is possible to facilitate smooth filling of ink into the printer while maintaining good visibility by preventing the ink from soaking and spreading on the ink storage unit inner wall 11. As the ink can be smoothly filled into the printer while preventing the ink from soaking and spreading on the ink storage unit inner wall 11, the amount of ink remaining inside the ink storage container 100 that is used and discarded or reused is reduced. That is, the amount of ink to be discarded while remaining in the ink storage container 100 can be reduced. Furthermore, also in a case of cleaning the inside of the used ink storage container 100 and reusing the ink storage container 100, if the amount of ink remaining in the ink storage container 100 is reduced, the amount of liquid such as water required for cleaning can also be reduced. This can reduce the cost of reusing the ink storage container 100, thus promoting the reuse of the ink storage container 100. That is, the technology described in the present specification can contribute to the realization of a sustainable society such as a decarbonized, recycling society.
The materials forming the ink storage unit 10 and the ink filling unit 20 may be any material that can satisfy the surface free energy described above.
Examples of the material with the surface free energy of about 18 mN/m include a resin having a perfluoroalkyl group in its molecular structure, such as PTFE. The perfluoroalkyl group, also called a fluoroalkyl carbide group, has all hydrogen atoms in the alkyl chain replaced with fluorine atoms, and is characterized by extremely small intermolecular force. Examples of the material with the surface free energy of about 29 mN/m include PP. These materials may be surface-modified using ways such as plasma irradiation, light irradiation, a surface modifier, or a coating. In an ink storage container made of a single material, for example, an area A having a surface free energy higher than the surface tension of ink stored in a spout portion may be provided as the ink filling unit 20. In an ink storage container 150 shown in
It is preferable that the thickness of the ink storage container 100 according to the present embodiment is adjusted so that a haze value of the substrate forming the ink storage unit 10 is 30% or less, more preferably 10% or less.
The haze value is defined as a value measured by a method based on JIS K7136. The haze value can be obtained by cutting a test piece into an appropriate size (for example, 3×3 cm) and fixing it on a movable measuring stand, and by using Haze Meter NDH4000 manufactured by Nippon Denshoku Industries Co., Ltd. as a measuring instrument. This haze value is a value related to the visibility of contents, indicating the degree of scattering as light passes through a certain member. As for the principles of measuring a haze value, light is made incident on the test piece in a straight line, and scattered light is detected using a photodetector installed at a position away from the line of incidence of the light. The degree of scattering is defined by measuring the proportion of the scattered light. Even for the same substance, the thicker the thickness through which light passes, the higher the probability of collision with molecules, and the higher the haze value tends to be.
As a second exemplary embodiment, an example is given where an ink having a surface tension of about 35 mN/m is used, the ink storage unit inner wall 11 is made of a resin having a surface free energy of about 29 mN/m or less, and the ink filling unit inner wall 21 is made of a resin having a surface free energy of about 42 mN/m. Furthermore, the thickness is adjusted so that the haze value of the ink storage unit 10 is 30% or less. In exemplary embodiment 2, again, the relationship between the surface free energy of the ink storage unit inner wall 11, the surface tension of the stored ink, and the surface free energy of the ink filling unit inner wall 21 is as follows: ink storage unit inner wall 11<ink<ink filling unit inner wall 21.
Examples of the resin with the surface free energy of about 29 mN/m include PP. Examples of the resin with the surface free energy of about 42 mN/m include ABS resin.
The major difference between Exemplary Embodiment 1 and Exemplary Embodiment 2 is the surface tension of the stored ink, which is 35 mN/m in Exemplary Embodiment 2 that is higher than 25 mN/m in Exemplary Embodiment 1. Therefore, in a case where the ink of Exemplary Embodiment 1 and the ink of Exemplary Embodiment 2 are dropped onto PP whose surface free energy is about 29 mN/m, the ink of Exemplary Embodiment 1 tends to soak and spread, while the ink of Exemplary Embodiment 2 tends to aggregate.
Although PP is described as a material suitable for the filling unit in Exemplary Embodiment 1, PP is more suitable as a material for the storage unit than for the filling unit for the ink of Exemplary Embodiment 2. Even the same resin material thus has a preferred form that differs depending on the physical properties of the stored ink.
As a matter of course, using PTFE for the storage unit in Exemplary Embodiment 2 as in Exemplary Embodiment 1 does not contradict the intention of the present disclosure, and there is nothing wrong with using ABS resin for the filling unit in Exemplary Embodiment 1. Furthermore, metal such as SUS may be used for the filling unit. The surface free energy of the metal is generally 400 mN/m or more, and thus ink tends to soak and spread.
The materials that can be used for the ink storage container 100 according to the present disclosure, including substances not described in the exemplary embodiments, can be used in any combination as appropriate within the scope of the claims of the present disclosure.
In the ink storage container according to the present disclosure, the ink storage unit 10 and the ink filling unit 20 may be composed of a plurality of members. In that case, as in Exemplary Embodiments 1 and 2, the relationship between the surface free energy of the ink storage unit inner wall 11, the surface tension of the stored ink, and the surface free energy of the ink filling unit inner wall 21 is as follows: ink storage unit inner wall 11<ink<ink filling unit inner wall 21. Even if the ink storage container is composed of a plurality of members, it is preferable that the haze value of the ink storage container is 30% or less.
In an ink storage container 110 shown in
For example, a combination of using a material with low surface free energy for the inner storage part 41 and a material with excellent impact resistance for the outer storage part 43 is conceivable. In this case, even if there are concerns about the impact resistance of a member to be used for the inner storage part 41, a reinforcing effect can be expected from the member to be used for the outer storage part 43. There is also an advantage that the surface free energy is not a concern because the member to be used for the outer storage part 43 does not come into direct contact with ink.
In an ink storage container 120 shown in
As one of the combinations of the ink filling unit 20 of the ink storage container 120, an example is given where a substance with high surface free energy is used for the inner filling part 42 and a porous member into which ink easily permeates is used for the outer filling part 44. In such a structure, the surface free energy of the inner filling part 42 is increased to maintain the ease of pouring ink. At the same time, such a structure can expect an effect of minimizing the area of contamination by the porous material absorbing ink running down and leaking from the tip of the filling part as the user finishes pouring the ink into the ink tank 2.
An ink storage container 130 shown in
There are various manufacturing methods and techniques that can be used to realize the configuration of the present embodiment, but the method is not limited. The components may be individually created and fitted or combined, regardless of whether they are used for the inner or outer members. Further, a film may be formed by coating or the like, and a method of attaching a separately prepared film or thin film is also included. Examples of a coating method include a method wherein a solvent having a desired resin dissolved therein is sprayed or applied, and then the solvent is evaporated.
Such a coating method and the method of applying a film or a thin film have the advantage of reducing the thicknesses of the members, thus expecting an effect of reducing the material cost. As for the ink storage unit 10, a thinner member has the advantage of making it easier to set a lower haze value. The reason why a thinner member makes it possible to set a lower haze value is as already described in Exemplary Embodiment 1.
The ink storage container according to the present embodiment may further have a valve mechanism in the ink filling unit 20.
In a case of supplying ink from the ink storage container 200 to the ink tank 2, a communication channel of the ink tank 2 is inserted into the opening of the ink filling unit 20 of the ink storage container 200. The ink filling unit 20 of the ink storage container 200 is provided with a recess that engages with the protrusion of a socket of the ink jet printer 1. The ink storage container 200 is positioned as the communication channel is inserted into the opening of the ink filling unit 20. The ink in the ink storage container 200 is supplied to a storage chamber of the ink tank main body through the communication channel due to the water head difference.
The ink storage container 200 has two sealable parts (hereinafter referred to as sealing parts).
The first sealing part will be described with reference to
The second sealing part will be described with reference to
With this liquid stop valve structure, the valve 25 is biased against the opening of the seal 24 by the spring 26, so that the inside of the ink storage container 200 can be kept sealed even if the cap unit 30 is removed from the ink filling unit 20. In a case of supplying ink from the ink storage container 200 to the ink tank 2, the communication channel is inserted into the ink filling unit 20 through the opening of the seal 24, and the valve 25 is opened. As described above, the ink in the ink storage container 200 is supplied to the storage chamber of the ink tank main body through the communication channel due to the water head difference.
In the present embodiment, these two sealing parts are configured to be temporarily opened at the same time as the cap unit 30 is opened from the ink filling unit 20 and as the cap unit 30 is closed with respect to the ink filling unit 20. The inside of the ink storage container 200 is thus communicated with the atmosphere, and the inner pressure of the ink storage container 200 can be set equal to the outside pressure. This will be described in detail below.
First, in a closed state of the cap unit 30, the first sealing part is in a sealed state, as shown in
With the configuration described above, the first sealing part and the second sealing part are temporarily opened at the same time as the cap unit 30 is opened, and thus the inside of the ink storage container 200 is communicated with the atmosphere, making it possible to set the inner pressure of the ink storage container 200 equal to the outside pressure. This prevents ink from spouting out due to an increase in internal pressure of the ink storage container 200 as the cap unit 30 is opened to replenish the ink tank main body with ink from the ink storage container 200. Furthermore, overflow of ink from the ink tank main body can be suppressed. The inside of the ink storage container 200 is kept sealed by the second sealing part even if the cap unit 30 is opened. This makes it possible to prevent ink leakage even if the ink storage container 200 is turned upside down.
The ink filling unit 20 has an filling port 122c for filling ink and a sealing part 122d made of an annular rib provided along the peripheral edge of the filling port 122c. The filling port 122c is provided with a slit valve 124 that opens and closes depending on the internal pressure of the ink storage container 300. The slit valve 124 has a valve body 124a made of a flexible material and three mutually intersecting slits 124b formed in the valve body 124a. The slit valve 124 can seal the filling port 122c in a closed state. The valve body 124a has six divided pieces 124c formed by the three slits 124b. Note that the number of slits 124b is not limited thereto and may be two or four or more. In this case, the plurality of slits 124b are preferably formed so as to have 2n-fold symmetry with respect to the center of the circular valve body 124a as shown in
A cap sealing part 123b made of an annular rib and a protrusion 123c protruding toward the slit valve 124 are provided on the bottom surface of the cap unit 30 (the surface facing the filling port 122c). The cap sealing part 123b fits into the sealing part 122d as the cap unit 30 is attached to the ink filling unit 20, and thus functions as a sealing unit for sealing the filling port 122c together with the sealing part 122d. The protrusion 123c has its tip facing the valve body 124a of the slit valve 124 at a position away from an intersection point 124d of the plurality of slits 124b in a lateral direction (radial direction of the ink filling unit 20) with the filling port 122c sealed by the cap sealing part 123b and the sealing part 122d. With this configuration of the protrusion 123c, as will be described later, in a case where the internal pressure of the ink storage container 300 is higher than the external pressure as the cap unit 30 is opened, the internal pressure can be released. In the present embodiment, the protrusion 123c is provided integrally with the cap unit 30, but may be provided separately from the cap unit 30.
In a state where the cap unit 30 is attached to the ink filling unit 20 and the filling port 122c is sealed, the protrusion 123c faces the valve body 124a at the position laterally away from the intersection point 124d of the slit 124b, as described above, and the protrusion 123c is not in contact with the valve body 124a. Here, as the cap unit 30 starts to open (starts to move in the arrow direction), the fitting between the cap sealing part 123b and the sealing part 122d is released, and the sealing of the filling port 122c is released. In this event, if the internal pressure of the ink storage container 300 is higher than the external pressure, the valve body 24a of the slit valve 124 deforms by expanding outward due to the internal pressure of the ink storage container 300, as shown in
When the internal pressure of the ink storage container 300 increases in a state where the cap unit 30 is not attached to the ink filling unit 20, the valve body 124a of the slit valve 124 deforms by expanding outward, as shown in
With such a configuration, even if the internal pressure of the ink storage container 300 increases, the internal pressure can be released to the outside by bringing the protrusion 123c into contact with the slit valve 124 as the cap unit 30 is opened or closed. Note that the length of the protrusion 123c is not particularly limited, and can be set to an optimal length depending on the amount of actual deformation of the valve body 124a due to the increase in internal pressure of the ink storage container 300. Therefore, when the amount of deformation of the valve body 124a is relatively small, for example, the tip of the protrusion 123c may be in contact with the valve body 124a to the extent that it does not deform the valve body 124a, in a state where while the filling port 122c is sealed by the cap sealing part 123b and the sealing part 122d.
To simply bring the protrusion 123c into contact with the expanded valve body 124a, it is also conceivable to make the tip of the protrusion 123c face the intersection point 124d of the slits 124b in a state where the cap unit 30 is attached to the ink filling unit 20 (where the filling port 122c is sealed) as shown in
The ink filling unit 20 may have one channel or may have two channels.
The nozzle 410 has a roughly cylindrical shape. The nozzle 410 has an outer circumferential surface 412 with a circumferential cross section. An outer circumferential surface 413, which is a part of the outer circumferential surface 412, has a tapered shape and is inclined in a direction in which the diameter of the outer circumferential circle decreases from the bottom wall 411 toward the first direction 434. Such a shape enables smooth operation in a case of inserting the nozzle 410 into the tank sequentially from the distal end side away from the ink storage unit. However, the nozzle 410 may have the same outer circumferential diameter from the bottom wall 411 to the tip, and the outer circumferential surface thereof may extend in the vertical direction. Further, the shape of the nozzle 410 may be other than a cylindrical shape, for example, a quadrangular prism shape.
The nozzle 410 has a channel 490 through which ink or gas flows. The channel 490 passes through the ink filling unit 420 along the first direction 434. Although the channel 490 extends along the first direction 434, the channel 490 is not limited thereto and may be curved. The cross-sectional shape of the channel 490 may be circular or a shape other than the circular shape. In a state where the ink filling unit 420 is attached to the ink storage unit, one end of the channel 490 is communicated with the ink storage unit through an opening 493. The other end of the channel is communicated with the outside of the ink filling unit 420 through an opening 494 on the distal end side of the nozzle. The opening 493 has a circular shape. Note that the opening 493 may have a shape other than the circular shape. The opening 493 may be formed at a base end of the nozzle 410, and the position thereof is not limited to a base end face 414. The opening 494 is formed in a tip surface 415 that forms the end of the nozzle 410 facing in the first direction 434. The opening 494 has a circular shape. Note that the opening 494 may have a shape other than the circular shape.
As shown in
The tip of the nozzle 510 is, for example, a portion of the nozzle 510 that is formed of the tip surface 515 and an outer circumferential surface 512. The nozzle 510 has a recess 516 on the outer circumferential surface 512. The recess 516 is defined by the tip surface 515 and an inner circumferential surface 518 (one side surface) of an annular rib 517 protruding from the outer edge of the tip surface 515 in the first direction 534. That is, the tip surface 515 is recessed from the tip of the nozzle 510 (the tip of the annular rib 517). The inner circumferential surface 518 extends from the tip surface 515 toward the outer edge of the tip surface 515 in the first direction 534. In other words, the inner circumferential surface 518 extends in the first direction 534 while being inclined in a direction in which the diameter of the recess 516 increases. Note that the inner circumferential surface 518 may extend along the first direction 534 without being inclined. Further, the nozzle 510 does not need to have the recess 516. In other words, the tip of the nozzle 510 does not need to be recessed.
While the present disclosure has been described with reference to exemplary embodiments, it is to be understood that the disclosure is not limited to the disclosed exemplary embodiments. The scope of the following claims is to be accorded the broadest interpretation so as to encompass all such modifications and equivalent structures and functions.
This application claims the benefit of Japanese Patent Applications No. 2023-113904, filed Jul. 11, 2023, and No. 2024-059410, filed Apr. 2, 2024, which are hereby incorporated by reference wherein in their entirety.
Number | Date | Country | Kind |
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2023-113904 | Jul 2023 | JP | national |
2024-059410 | Apr 2024 | JP | national |