The invention relates to an insulating glazing with a spacer having a reinforcing profile, a method for its production, and its use.
The thermal conductivity of glass is lower by roughly a factor of 2 to 3 than that of concrete or similar building materials. However, since, in most cases, panes are designed significantly thinner than comparable elements made of brick or concrete, buildings frequently lose the greatest share of heat via external glazing. This effect is particularly significant in high-rise buildings with partial or complete glass façades. The increased costs necessary for heating and air-conditioning systems make up a part of the maintenance costs of a building that must not be underestimated. Moreover, as a consequence of more stringent construction regulations, lower carbon dioxide emissions are required. An important approach to a solution for this involves insulating glazings, without which, primarily as a result of increasingly rapidly rising prices of raw materials and more stringent environmental protection constraints, it is no longer possible to imagine the building construction sector.
Insulating glazings are manufactured from at least two panes that are joined to one another via at least one circumferential spacer. Depending on the design, the interpane space between the two panes, referred to as the “glazing interior”, is filled with air or gas, but in any case is free of moisture. An excessive moisture content in the interpane space of the glazing results, in particular in the case of cold exterior temperatures, in the condensation of drops of water in the interpane space, which absolutely must be avoided. To absorb the residual moisture remaining in the system after assembly, hollow body spacers filled with a desiccant can, for example, be used. However, since the absorption capacity of the desiccant is limited, even in this case, the sealing of the system is of enormous importance to prevent the penetration of additional moisture. In the case of gas-filled insulating glazings, into whose glazing interior an argon filling, for example, is introduced, gas tightness must also be ensured.
In order to ensure improved leak tightness of insulating glazings, a wide variety of modifications in the field of the spacers are already known. Already in DE 40 24 697 A1, the problem is discussed that the customary single or double sealed insulating glass edge bonds made of materials such as polysulfide polymers, butyl hot melt, silicone rubber, polymercaptan, or polyurethane cannot ensure adequate long-term sealing and, over time, an undesirable gas exchange between the glazing interior and the surroundings occurs. Improved sealing is accomplished according to DE 40 24 697 A1 by means of a modification of the spacer, onto whose pane contact surfaces polyvinylidene chloride films or coatings are applied.
Another measure for improving the leak tightness of insulating glazings is the coating of polymeric spacers with metal foils or alternating metal polymer layer systems, as disclosed, for example, in EP 0 852 280 A1 and WO 2013/104507 A1. These barrier films ensure high leak tightness of the spacer. Adjacent the spacer with a barrier film, there is generally a primary sealant that serves to bond the spacer to the adjacent panes of the insulating glazing. This primary sealant is water- and gas-impermeable. An outer seal in the form of a secondary sealant is introduced into the outer interpane space adjacent the spacer with the primary sealant. The outer sealing of the insulating glazing is done with materials such as silicone or polysulfide, which have very good adhesion properties but are water- and gas-permeable. The secondary sealant thus serves primarily for the mechanical stability of the glazing.
EP 0 470 373 A1 discloses an insulating glazing with a hollow profile spacer, wherein a metal strip is applied to the outer face of the spacer. Metallic reinforcement elements that are attached in the corner region of a polymeric spacer are known from IT UA20 163 892 A1. WO 2019/201530 A1 discloses metallic reinforcement elements of a polymeric spacer, wherein they are inserted flush into indentations of the spacer. In the installed state of these spacers with reinforcement elements in an insulating glazing, a secondary sealant is introduced on the outer face of the spacers in the outer interpane space in order to achieve adequate mechanical stability of the insulating glazing.
The sealing system described, consisting of spacer, primary sealant, and secondary sealant has to be attached in the insulating glass production in a method comprising multiple production steps. First, the spacer is bonded to a first pane and a second pane simultaneously or successively by means of the primary sealant. Only after that can the secondary sealant be introduced, usually by extrusion, into the outer interpane space created.
The object of the present invention is to provide an insulating glazing that enables simplified assembly, as well as a method for its production.
The object of the present invention is accomplished, according to the invention, by an insulating glazing with a spacer, a method for its production, and the use of the spacer according to the independent claim 1. Preferred embodiments of the invention emerge from the dependent claims.
The insulating glazing according to the invention contains at least a first pane, a second pane, and a circumferential spacer surrounding the panes and having a reinforcing profile. The first pane is attached to the first pane contact surface and the first side surface of the spacer, and the second pane is attached to the second contact surface and the second side surface of the spacer. Adjacent the glazing interior surface of the spacer is the glazing interior of the insulating glazing. The outer surface of the polymeric main body, to which the reinforcing profile is attached, delimits the glazing interior from the outer interpane space. The space enclosed by the panes and the glazing interior surface of the spacer is referred to as the “glazing interior”. The outer interpane space is the space enclosed by the panes and the main body that is adjacent the outer surface of the main body. The reinforcing profile is thus positioned in the outer interpane space. The reinforcing profile is directly adjacent the surroundings of the glazing at the open edge of the outer interpane space. An outer seal with a secondary sealant according to the prior art is dispensed with completely. In the context of the invention, completely eliminating a secondary sealant means that the continuous layer of a secondary sealant used according to the prior art in the outer interpane space is absent and the outer surface of the reinforcing profile is exposed, i.e., has a surface exposed to the surroundings. Dispensing with an outer seal enables a larger through-vision area of the glazing, since the reinforcing profile can be implemented in a more space-saving manner than the seal used according to the prior art. The spacer comprises at least one polymeric main body and the reinforcing profile. The polymeric main body comprises two pane contact surfaces, a glazing interior surface and an outer surface, wherein the reinforcing profile is attached to the outer surface of the polymeric main body. The reinforcing profile has an inner face that faces the outer surface of the polymeric main body, and an outer face that designates the surface opposite the inner face. The lateral surfaces of the reinforcing profile, via which the inner face and outer face are joined to one another, are referred to as “side surfaces”. The inner face of the reinforcing profile is materially bonded to the outer surface of the polymeric main body. The width of the reinforcing profile is equal to at most the width of the polymeric main body, but can also be less than this. The width of the reinforcing profile is defined as the distance between the two side surfaces and the width of the polymeric main body is defined as the distance between the two pane contact surfaces. In the installed state in the glazing, the reinforcing profile absorbs mechanical loads and causes a stiffening of the edge seal. The reinforcing profile thus assumes the role of the secondary sealant used according to the prior art as an outer seal. A secondary sealant can thus be dispensed with. This is accompanied by a substantial simplification of the insulating glass production, since an extrusion system and an extrusion step for introducing the secondary sealant can be dispensed with.
Furthermore, the reinforcing profile is integrated directly into the spacer via the material connection with the main body such that no additional steps are required in the production process for assembling the reinforcing profile. Thus, the spacer is available as a component consisting of the main body and the reinforcing profile already ready for assembly. This results in a saving of time in the production process by which production costs can be reduced. Since the spacer is manufactured independently of the assembly line for insulated glazing and no modifications of the production plant are necessary for the assembly of the spacer, the spacer can be used universally without additional expenditure. Furthermore, the reinforcing profile provides a space-saving and effective stiffening of the edge region of the insulating glazing.
Preferably, the reinforcing profile ends directly flush with the pane edges of the insulating glazing, or is set back by a maximum of 3 mm, preferably a maximum of 1 mm in the direction of the glazing interior. This results in an enlarged through-vision area of the glazing.
The two pane contact surfaces of the polymeric main body comprise a first pane contact surface and a second pane contact surface. The first pane contact surface and the second pane contact surface are the sides of the main body on which the panes (first pane and second pane) of the insulating glazing are mounted during installation of the spacer. The first pane contact surface and the second pane contact surface run parallel to one another.
The glazing interior surface is defined as the surface of the polymeric main body that faces in the direction of the interior of the glazing after installation of the spacer in the insulating glazing. The glazing interior surface is positioned between the panes mounted on the spacer.
The outer surface of the polymeric main body is the side opposite the glazing interior surface, which faces away from the interior of the insulating glazing in the direction of an outer interpane space.
The inner face of the reinforcing profile is the surface that faces the outer surface of the polymeric main body and, in the installed state, faces in the direction of the glazing interior of the insulating glazing. The surface of the reinforcing profile opposite the inner face is referred to as the “outer face” and faces, in the installed state, in the direction of the external surroundings. The side surfaces of the reinforcing profile connect its outer face to the inner face and are, in the installed state of the spacer, the sections of the reinforcing profile facing the panes. The inner face of the reinforcing profile forms its base from which, optionally, legs and/or protrusions of the reinforcing profile protrude in the direction of the glazing interior and/or the outer interpane space.
The reinforcing profile is materially bonded to the polymeric main body in order to ensure simple assembly without additional process steps and without modification of the existing insulating glazing plants. A wide variety of adhesives and/or sealants can be used for bonding the reinforcing profile and the main body. The bonding primarily has the role of fixing the reinforcing profile and the main body such that the components of the spacer can be processed together on an insulating glazing line. The permanent fixation of the reinforcing profile and of the main body occurs via installation in a glazing. The polymeric main body and the reinforcing profile are preferably materially bonded to one another continuously along the spacer via at least one section of the spacer cross-section along the outer surface of the polymeric main body and the inner face of the reinforcing profile. Particularly preferably, the connection of the components is done via a section of the outer surface of the spacer that runs parallel to the glazing interior surface, in particular via a section that is arranged centrally along the cross-section, i.e., is approx. equidistant from both pane contact surfaces. Preferably, the polymeric main body and the reinforcing profile are materially connected to one another continuously along the spacer at least along the section of the outer surface that runs parallel to the glazing interior surface. This ensures a particularly secure connection and prevents displacement of the components during the production process.
In a possible embodiment, the polymeric main body and the reinforcing profile are bonded via a strand of sealant applied continuously or at points, preferably continuously, along the spacer. Suitable sealants are, for example, the sealants used for bonding the panes of the insulating glazing to the pane contact surfaces of the polymeric main body. The same sealant or even a different sealant from the sealant used for bonding the panes can be selected. Such sealants have the advantage that they begin to flow under the action of heat and thus compensate stresses in the installed state of the glazing. Particularly suitable in this context are the sealants often referred to as primary sealants and used in the prior art for bonding the pane contact surfaces of spacers to adjacent panes. Particularly preferably, butyl rubber, polyisobutylene, polyolefin rubber, copolymers, and/or mixtures thereof are used. These enable advantageous flexibility of the bond.
In another embodiment of the invention, the polymeric main body and the reinforcing profile are materially bonded to another via an adhesive. The adhesive can be selected from the adhesives commonly used industrially, taking into account compatibility with the adjacent materials of the polymeric main body, the reinforcing profile, and, if applicable, a barrier film attached to the polymeric main body. For example, adhesives from the groups cyanoacrylate adhesives, methyl methacrylate adhesives, epoxy adhesives, polyurethane adhesives, and silicones, as well as mixtures and copolymers thereof, can be used. The adhesives can be used either as a liquid adhesive and/or in the form of an adhesive tape or a double-sided adhesive tape, with the adhesives mentioned being attached to the opposite outer sides of the adhesive tape. Adhesive tapes can also perform other functions in addition to the bonding of the components, for example, foam adhesive tapes can compensate stresses. Foam adhesive tapes, including polyacrylate adhesives, known under the term “structural glazing tape”, are suitable, for example.
In another possible embodiment, the reinforcing profile is coextruded with the polymeric main body. In that case, a barrier film can, optionally, be applied to the outer surface of the polymeric main body. This film is inserted in the extrusion process and is thus directly integrated during coextrusion. Moreover, other layers, such as a layer of a sealant, can also be coextruded during coextrusion of a polymeric main body and a reinforcing profile. Coextrusion of a reinforcing profile and a polymeric main body offers the advantage that after extrusion of the polymeric main body, no further process steps are necessary to apply the reinforcing profile, but, instead, this is already integrated.
The reinforcing profile can assume a wide variety of shapes. Within the width along which is applied, the reinforcing profile is preferably attached over the entire surface of the outer surface. However, alternatively, the reinforcing profile can also have cutouts. Full-surface designs are advantageous in terms of the stiffness of the reinforcing profile, whereas reinforcing profiles with cutouts result in lower thermal conductivity of the resulting insulating glazing. Generally, materials of low thermal conductivity are used for producing the reinforcing profile such that cutouts can preferably be dispensed with. This is also advantageous in terms of simple production.
In a possible embodiment, the reinforcing profile is implemented as a flat profile that can be cut in a simple manner from plate-shaped materials. This is advantageous in terms of the most efficient and economical production.
An advantageous shape of the reinforcing profile is a U-shaped design, in which the reinforcing profile encloses the corners of the polymeric main body and protrudes all the way to sub-regions of the pane contact surfaces. Compared to a flat profile, a U-shaped cross-section provides better stiffening of the profile. The sub-regions of the pane contact surfaces to which the reinforcing profile protrudes are to be provided with a recess that corresponds to the thickness of the reinforcing profile in this region. This ensures that the width of the reinforcing profile does not protrude beyond the width of the polymeric main body. Alternatively, a U-shaped reinforcing profile can be arranged such that the regions of the U-shape running perpendicular to the outer surface of the polymeric main body face away from the pane contact surfaces. In this case, recesses of the polymeric main body can be dispensed with; however, this disadvantageously increases the overall structural height of the spacer. In order to keep the structural height of the spacer as low as possible, the sections of the U-shaped reinforcing profiles facing away from the pane contact surfaces can be designed as short as possible. However, the stability advantages compared to a flat profile also disappear.
In a preferred embodiment, the shape of the reinforcing profile is adapted to the shape of the main body such that the reinforcing profile is implemented in the shape of a counter profile. The counter profile is adapted in its course to the shape of the outer surface of the polymeric main body. Such an embodiment is considered in particular when the outer surface of the main body is, at least in sub-regions, not perpendicular to the pane contact surfaces of the main body. A reinforcing profile as a counter profile is optimally joined to the main body, wherein, in contrast to filling with secondary sealant, no undesirable cavities can develop. The outer face of the reinforcing profile facing away from the outer surface of the polymeric main body can run independently of the inner face of the reinforcing profile. Preferably, the outer face of the reinforcing profile runs substantially parallel to the glazing interior surface of the polymeric main body. Thus, in the installed state, the outer interpane space of the insulating glazing is optimally filled and good stability is achieved.
A reinforcing profile in the form of a counter profile is particularly preferred when the regions of the outer surface of the main body that are adjacent the pane contact surfaces are inclined in the direction of the pane contact surfaces.
In a preferred embodiment of the spacer, the section of the outer surface adjacent the pane contact surfaces of the main body is inclined at an angle of 20° to 70°, preferably of 30° to 60°, relative to the outer surface in the direction of the pane contact surfaces. This angled geometry improves the stability of the polymeric main body. The reinforcing profile of the spacer is implemented as a counter profile, of which the inner face facing the outer surface of the main body has the course accordingly adapted to the geometry of the outer surface. The sections of the inner face adjacent the side surfaces of the reinforcing profile thus run inclined, in sections that correspond in their width to the width of the angled sections of the outer surface. The degree of inclination of the inner face of the reinforcing profile is derived from the inclination of the outer surface of the main body. This enables a flush connection of the inner face of the reinforcing profile to the outer surface of the polymeric main body. Without the use of a counter profile, there would be corner regions set back in angled regions that would have to be filled with a sealant. Undesirable air pockets can develop in the hard-to-reach corner regions. This is avoided by a reinforcing profile adapted to the course of the outer surface. The outer face of the reinforcing profile preferably runs substantially parallel to the glazing interior surface. This creates a planar surface directed toward the surroundings of the glazing, which provides a flat finish. Moreover, the combination of the angled regions of the inner face and the planar outer face produces a stiffening of the reinforcing profile. Protrusions having a substantially triangular cross-section develop in the angled regions of the inner face providing advantageous stabilization. The protrusions having a substantially triangular cross-section are optionally implemented solid, i.e., as solid material, or as a hollow profile section. In the case of a hollow profile section, the cavity is located within the protrusions and is largely or completely enclosed by them. A solid design of the reinforcing profile within the corner protrusions is advantageous in terms of stability, whereas hollow profile shaped corner protrusions offer lower weight with hardly significant stability losses.
In all the embodiments described, the reinforcing profile does not protrude laterally beyond the pane contact surfaces of the polymeric main body. The reinforcing profile is preferably set back in each case by 0.0 mm to 1.5 mm, particularly preferably by 0.3 mm to 1.2 mm, relative to the first pane contact surface and/or the second pane contact surface in the direction of the surface center of the outer surface. This ensures that the layer thickness of the sealant used for bonding the polymeric main body can be adjusted as desired. Primary sealants commonly used for bonding polymeric main bodies in insulating glazings are preferably used in a layer thickness of 0.2 mm to 0.5 mm, measured after pressing of the insulating glazing. A reinforcing profile protruding beyond the pane contact surfaces is a hindrance when using such conventional sealants, since a sufficiently thin layer thickness of the primary sealant is difficult to achieve. The adhesive used for bonding the reinforcing profile can also be used in greater layer thicknesses, with deviations due to manufacturing tolerances being compensated for by the adhesive. Preferably, the width of the reinforcing profile is less than the width of the polymeric main body such that in the event of production-related deviations, it can be ensured that the reinforcing profile does not protrude beyond the width of the polymeric main body under any circumstances.
Preferably, the wall thickness of the reinforcing profile is 0.5 mm to 5.0 mm, preferably 0.5 mm to 2 mm, particularly preferably 0.7 mm to 1.5 mm. The wall thickness is the thickness of the reinforcing profile at the point of least thickness. Thus, regions of greater thickness, such as corner protrusions of the reinforcing profile, are not considered in the determination of the wall thickness. The thickness of the reinforcing profile is determined in the direction parallel to the pane contact surfaces of the main body. In the thickness ranges mentioned, good stiffening of the edge region of an insulating glazing can be achieved. Furthermore, in the preferred ranges of the wall thickness, a larger through-vision area of the glazing can be achieved. In particular, when no further secondary sealants are used and the outer seal is ensured only by the reinforcing profile, a substantial saving of space in the height of the edge region of the insulating glazing is possible.
The height of the reinforcing profile is determined at the point of the reinforcing profile with the greatest thickness. The height is, i.e., at least the amount of the thickness of the reinforcing profile. When using flat profiles, the height is identical to the thickness. In the case of U-shaped reinforcing profiles, the height of the reinforcing profile exceeds the thickness or wall thickness of the reinforcing profile by the amount by which the legs of the U-profile protrude beyond the base of the U-profile. Here, “base of the U-profile” refers to the section of the inner face of the reinforcing profile running parallel to the glazing interior surface. In an embodiment of the spacer in which the corner regions of the main body are angled and the reinforcing profile is implemented as a counter profile, the height of the reinforcing profile is defined by the wall thickness plus the amount by which the protrusions in the corner regions of the reinforcing profile protrude beyond its base. In this case as well, the section of the inner face of the reinforcing profile running parallel to the glazing interior surface is referred to as the “base”. For reinforcing profiles that are not implemented as flat profiles, the height of the reinforcing profile is preferably 0.7 mm to 5.0 mm with a wall thickness of preferably 0.5 mm to 3.0 mm, particularly preferably 1.0 mm to 4.0 mm with a wall thickness of 0.7 mm to 2.0 mm, in particular 1.0 mm to 3.0 mm with a wall thickness of 0.7 mm to 1.2 mm.
The polymeric main body preferably contains polyethylene (PE), polycarbonates (PC), polypropylene (PP), polystyrene, polybutadiene, polynitriles, polyesters, polyurethanes, polymethyl methacrylates, polyacrylates, polyamides, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), preferably polyethylene terephthalate (PET), acrylonitrile butadiene styrene (ABS), acrylonitrile styrene acrylester (ASA), acrylonitrile butadiene styrene/polycarbonate (ABS/PC), styrene acrylonitrile (SAN), PET/PC, PBT/PC, SAN/PC, and/or copolymers or mixtures thereof. In particular, styrene acrylonitrile (SAN), acrylonitrile butadiene styrene (ABS), acrylonitrile styrene acrylester (ASA), and copolymers and/or mixtures thereof are preferred components, since they have good mechanical properties and high breaking strength. The use according to the invention of a reinforcing profile enables, in principle, a large range of main body materials. Due to the fact that mechanical loads that act on the edge region of the glazing are primarily absorbed by the reinforcing profile, the material of the main body can be freely selected within wide limits. Thus, even economical main body materials can be used that are, due to poorer mechanical properties, only suitable for use in insulating glazings to a limited extent.
The reinforcing profile according to the invention can be made of plastics and/or metals. Plastics are preferred due to their lower thermal conductivity compared to metals.
In principle, the plastics mentioned for the main body can also be used for the reinforcing profile. These have low thermal conductivity. Preferably, the reinforcing profile comprises polyethylene terephthalate (PET), styrene acrylonitrile (SAN), acrylonitrile butadiene styrene (ABS), acrylonitrile styrene acrylester (ASA), acrylonitrile butadiene styrene/polycarbonate (ABS/PC), styrene acrylonitrile/polycarbonate (SAN/PC), and/or copolymers or mixtures thereof.
The reinforcing profile and the polymeric main body can be made from the same polymeric base material or can even be based on different polymers. Manufacturing the polymeric main body and the reinforcing profile from the same plastic base material has the advantage that recycling of the spacer after the end of the service life of the glazing is simplified. The components of the main body other than the polymeric base material can differ even with the selection of the same base material. For example, the mechanical properties of the reinforcing profile and of the main body can be selectively adjusted by the addition of further components, such as glass fibers.
Some advantageous material combinations of a polymeric main body and a reinforcing profile are mentioned in the following by way of example:
Such a combination is advantageous due to improved recyclability and good customer acceptance of SAN as main body material.
Reinforcing profiles made of SAN have good stiffness, which can be further increased by the addition of polycarbonate. ABS is characterized by improved stiffness compared to SAN, which can likewise be increased by the addition of polycarbonate. Reinforcing profiles made of materials with high stiffness enable an almost free selection of the material of the main body.
PET has very good strength, is economical and readily recyclable.
In another embodiment, the reinforcing profile can comprise metals, preferably aluminum and/or stainless steel. Aluminum and stainless steel are characterized by suitable mechanical properties, but have higher thermal conductivity than plastics. Metallic reinforcing profiles can be combined with all of the main body materials mentioned. To reduce the thermal conductivity of a metallic reinforcing profile, cutouts can be provided in the reinforcing profile. By way of example, elongated cutouts that extend from one side surface to the opposite side surface of the reinforcing profile can be mentioned. Alternatively, the reinforcing profile can also be implemented in multiple pieces, wherein, along the spacer, a strip of a material with low thermal conductivity is embedded, which inhibits thermal conduction from one side surface of the reinforcing profile to the opposite side surface. Said insulating material strip runs, for example, substantially parallel to the side surfaces of the reinforcing profile. Such multi-part embodiments of metallic reinforcing profiles and also metallic reinforcing profiles with cutouts require higher production outlays compared to polymeric reinforcing profiles, which are, for this reason, preferably used.
Preferably, the main body and/or the reinforcing profile contain one or more reinforcement means. With regard to the reinforcing profile, this applies to reinforcing profiles comprising plastics.
A wide variety of reinforcement means in the form of fiber, powder, or platelets are known to the person skilled in the art as reinforcement means. The powder- and/or platelet-formed reinforcement means include, for example, mica and talc. Particularly preferred, in terms of mechanical properties are reinforcing fibers, including glass fibers, aramide fibers, ceramic fibers, or natural fibers. Alternatives to these are also ground glass fibers or hollow glass spheres. These hollow glass spheres have a diameter of 10 μm to 20 μm and improve the stability of the hollow profile. Suitable hollow glass spheres are commercially available under the name “3M™ Glass Bubbles”. In one possible embodiment, the polymeric main body contains both glass fibers and, preferably, also hollow glass spheres. An admixture of hollow glass spheres results in a further improvement of the thermal properties of the hollow profile.
Preferably, one or more of the reinforcement means mentioned, particularly preferably glass fibers, are likewise added to a reinforcing profile according to the invention comprising a plastic base material.
Particularly preferably, glass fibers are used as reinforcement means in the polymeric main body, being added at a proportion of 25 wt.-% to 40 wt.-%, in particular at a proportion of 30 wt.-% to 35 wt.-%. Within these ranges, good mechanical stability and strength of the main body can be observed. Furthermore, a glass fiber content of 30 wt.-% to 35 wt.-% is quite compatible with the multilayer barrier film composed of alternating polymeric layers and metallic or ceramic layers applied to the outer surface of the main body in a preferred embodiment. By adapting the coefficient of thermal expansion of the polymeric main body and the barrier film or barrier coating, temperature-induced stresses between the different materials and flaking of the barrier film will barrier coating can be avoided.
The glass fiber content of the reinforcing profile is preferably 30 wt.-% to 60 wt.-%, particularly preferably 37 wt.-% to 50 wt.-%. The higher glass fiber content of the reinforcing profile compared to the polymeric main body results in advantageously improved stiffness of the reinforcing profile.
The main body preferably comprises a gas- and vapor-tight barrier that serves to improve the gas-tightness of the main body. Preferably, this is applied to at least the outer surface of the polymeric main body, preferably to the outer surface and to a portion of the pane contact surfaces. The gas- and vapor-tight barrier improves the tightness of the spacer against gas loss and moisture penetration. Preferably, the barrier is applied to about one half to two thirds of the pane contact surfaces. Particularly preferably, barrier films are used, with a suitable barrier film being disclosed, for example, in WO 2013/104507 A1.
In a preferred embodiment, the gas- and vapor-tight barrier on the outer surface of a polymeric main body is implemented as a film. This barrier film contains at least one polymeric layer and one metallic layer or one ceramic layer. The layer thickness of the polymeric layer is between 5 μm and 80 μm, while metallic layers and/or ceramic layers with a thickness of 10 nm to 200 nm are used. Within the layer thicknesses mentioned, particularly good tightness of the barrier film is achieved. The barrier film can be applied to the polymeric main body, for example, glued. Alternatively, the film can be coextruded together with the main body.
Particularly preferably, the barrier film contains at least two metallic layers and/or ceramic layers, arranged alternatingly with at least one polymeric layer. The layer thicknesses of the individual layers are preferably as described in the preceding paragraph. Preferably, the outer layers are formed by a metallic layer. The alternating layers of the barrier film can be bonded or applied to one another in a wide variety of methods known from the prior art. Methods for depositing metallic or ceramic layers are sufficiently known to the person skilled in the art. The use of a barrier film with an alternating layer sequence is particularly advantageous in terms of the tightness of the system. A defect in one of the layers does not lead to a loss of function of the barrier film. In comparison, even a small defect in a single layer can lead to a complete failure. Furthermore, the application of multiple thin layers is advantageous compared to one thick layer, since the risk of internal adhesion problems increases with increasing layer thickness. Also, thicker layers have higher conductivity such that such a film is less suitable thermodynamically.
The polymeric layer of the film preferably comprises polyethylene terephthalate, ethylene vinyl alcohol, polyvinylidene chloride, polyamides, polyethylene, polypropylene, silicones, acrylonitriles, polyacrylates, polymethyl acrylates, and/or copolymers or mixtures thereof. The metallic layer preferably contains iron, aluminum, silver, copper, gold, chromium, and/or alloys or oxides thereof. The ceramic layer of the film preferably contains silicon oxides and/or silicon nitrides.
In an alternative preferred embodiment, the gas- and vapor-tight barrier is preferably implemented as a coating. The coating contains aluminum, aluminum oxides, and/or silicon oxides and is preferably applied by a PVD method (physical vapor deposition). The coating with the materials mentioned provides particularly good results in terms of tightness and additionally exhibits excellent adhesion properties to the materials of the outer seal used in insulating glazings.
In a particularly preferred embodiment, the gas- and vapor-tight barrier has at least one metallic layer or ceramic layer, which is implemented as a coating and contains aluminum, aluminum oxides, and/or silicon oxides, and is preferably applied by a PVD method (physical vapor deposition).
In the insulating glazings known in the prior art, a layer of a sealant, also referred to as a primary sealant, or an outer seal, also referred to as a secondary sealant, is adjacent the gas- and vapor-tight barrier. The manufacturer of the insulating glazing is supplied with a spacer including assembly instructions listing the sealants that can be used in combination with the barrier film. The use of different sealants may result in compatibility problems of the film and sealant or outer seal. In the spacer of the insulating glazing according to the invention including a reinforcing profile, the barrier film is at least largely covered by the reinforcing profile such that the compatibility problem described can at least be reduced. Moreover, the reinforcing profile replaces the secondary sealant, as a result of which the insulating glazing manufacturer does not have to make any critical sealant selection in this regard. The problem of mechanical damage to the barrier film during transport or assembly is also eliminated when the insulating glazing according to the invention is used.
The polymeric main body can be formed as a hollow profile, as a body including a silicon foam, and/or as a solidly molded thermoplastic body. Spacers made of silicone foams and so-called TPS spacers are known to the person skilled in the art.
Preferably, the polymeric main body is designed as a hollow profile, whereby, on the one hand, a weight reduction is possible compared to a solidly molded main body, and, on the other, a cavity is available in the interior of the main body for accommodating other components, such as a desiccant.
Preferably, the glazing interior surface of the polymeric main body has at least one opening. Preferably, multiple openings are provided in the glazing interior surface. The total number of openings depends on the size of the insulating glazing. The openings connect the cavity to the inner interpane space, as a result of which a gas exchange between them becomes possible. This allows absorption of humidity by a desiccant situated in the cavity and thus prevents fogging of the panes. The openings are preferably implemented as slots, particularly preferably as slots with a width of 0.2 mm and a length of 2 mm. The slots ensure optimum air exchange without desiccant being able to penetrate out of the cavity into the inner interpane space.
The polymeric main body preferably contains a desiccant, preferably silica gels, molecular sieves, CaCl2, Na2SO4, activated carbon, silicates, bentonites, zeolites, and/or mixtures thereof. The desiccant is preferably incorporated into the main body. Particularly preferably, the desiccant is situated in the cavity of the main body.
The spacer of the insulating glazing according to the invention optionally includes a pressure equalization body that is preferably embedded flush in the outer face of the reinforcing profile. In the prior art, a wide variety of pressure equalization systems for insulating glazings are known, which are intended to enable pressure equalization between an inner interpane space of the insulating glazing and the surroundings. Particularly advantageous are pressure equalization bodies which, although they enable pressure equalization, do not allow any passage of water in drop form and inhibit water-vapor diffusion as much as possible. The use of a reinforcing profile in the spacer offers the capability of integrating such pressure equalization bodies and also, if necessary, other cylindrical components in a simple manner. A pressure equalization body to be integrated in the spacer in a simple manner is disclosed, for example, in WO 2019/110409. The insulating glazing described there includes a pressure equalization body that is inserted into an opening on the outer surface of the spacer. By means of a combination of capillary and gas-permeable membrane, the pressure equalization body brings about an exchange of air and the associated pressure equalization between the inner interpane space and the ambient air. Pressure equalization takes place via a diffusion process through the capillary and the membrane. According to the prior art, the pressure equalization bodies described are inserted in an insulating glazing whose outer interpane space is filled with secondary sealant. For this purpose, an opening is first created on the outer surface of the polymeric main body, in the region of which the secondary sealant is also removed. The pressure equalization body is inserted into this bore at the outer surface of the main body and remaining gaps are sealed with a sealant. This method is difficult to automate; however, in this way, no changes are necessary when filling the edge region with secondary sealant. Alternatively, the prior art pressure equalization body can also be inserted before introducing the secondary sealant; however, in this case, the system for introducing the secondary sealant must be modified such that it recognizes the pressure equalization body as an obstacle and bypasses it. From these statements concerning the prior art, it is clear that the integration of a pressure equalization body requires additional effort in the manufacture of insulating glass. In a preferred embodiment of the insulating glazing according to the invention, the spacer having a reinforcing profile already includes a pressure equalization body. Thus, additional effort on the part of the insulating glass manufacturer can be mostly avoided; the manufacturer merely has to insert the desired spacer module including a pressure equalization body into the spacer frame. According to the invention, the outer interpane space is sealed by the reinforcing profile such that the described problem of the filling with a secondary sealant does not arise.
Optionally, before assembly, the spacer can already be provided with sealants and/or adhesives that are situated as pre-applied strips on the pane contact surfaces of the main body and/or the side surfaces of the reinforcing profile. These adhesive strips and sealant strips are preferably provided with a protective film to prevent unwanted bonding with adjacent spacers and/or other components during transport and storage of the spacers. To apply the spacer on a pane, the insulating glass manufacturer only has to remove the protective film and press the spacer onto the pane surface. The spacer can optionally include the same adhesive with the same sealant or different adhesives and/or sealants in the region of the pane contact surfaces and the side surface.
Preferably, a primary sealant is pre-applied in the region of the first and/or the second pane contact surface as a sealant strip in the form of an extruded strand of sealant. The primary sealant preferably comprises butyl rubber, polyisobutylene, polyethylene vinyl alcohol, ethylene vinyl acetate, polyolefin rubber, copolymers, and/or mixtures thereof. The strand of sealant is preferably covered by a protective film that is removed before assembly of the spacer.
Preferably, a pre-applied adhesive strip is also attached in the region of the side surfaces of the reinforcing profile. The adhesives used for bonding the reinforcing profile have greater stiffness than the sealants used for bonding the main body. This is advantageous in terms of the stiffening of the edge region. Adhesives particularly suitable for bonding the reinforcing profile are acrylate adhesives, polyurethane adhesives, silicones, silane-modified polymer adhesives, as well as mixtures and copolymers thereof. If the spacer is provided with a pre-applied adhesive strip in the region of the side surfaces of the reinforcing profile, adhesive tapes including acrylate adhesives are preferably used for this purpose. Suitable adhesive tapes including acrylate adhesives are commercially available, for example, under the term “structural glazing tape”. Even at low thicknesses in the range from 0.3 mm to 0.5 mm, these provide a good seal against water and moisture. Moreover, no time for curing of the adhesives has to be taken into account in the production process.
The spacer can optionally include another adhesive strip extending circumferentially on the outer face of the reinforcing profile. This is likewise covered by a protective film. At the time of assembly of the insulating glazing in a window frame, the protective film is removed and the insulating glazing can be bonded in the frame in addition to the customary attachment in the frame element. Preferably, for this purpose, a foam adhesive tape based on a foam tape provided with acrylate adhesive is used.
Optionally, all surfaces of the spacer that are intended for bonding with a sealant and/or adhesive can be prepared with a plasma and/or corona treatment. This improves the adhesion of the surfaces. This has proved useful in particular for polymeric main bodies and/or reinforcing profiles comprising SAN and/or PET.
The polymeric main body of the spacer has, along the pane contact surfaces, a height of 5 mm to 15 mm, particularly preferably of 5 mm to 10 mm.
The width of the glazing interior surface is 4 mm to 30 mm, preferably 8 mm to 16 mm.
In a preferred embodiment, the polymeric main body and the reinforcing profile are fixed to the first pane and/or second pane via the same adhesive. This is advantageous in terms of simplified manufacture of the insulating glazing. A suitable adhesive is, for example, a reactive two-component hotmelt adhesive to which additives for chemical cross-linking are preferably added.
In another preferred embodiment, the polymeric main body is bonded via a sealant; and the reinforcing profile, via an adhesive in each case to the first pane and/or second pane. This is advantageous in order, on the one hand, to be able to select an elastic sealant for the polymeric main body, which ensures good sealing even when climate loads occur; and, on the other, to use an adhesive with high stiffness for bonding the reinforcing profile.
In this case, the two panes are attached to the pane contact surfaces, preferably via a primary sealant, which is applied between the first pane contact surface and the first pane and/or the second pane contact surface and the second pane.
The primary sealant preferably contains butyl rubber, polyisobutylene, polyethylene vinyl alcohol, ethylene vinyl acetate, polyolefin rubber, polypropylene, polyethylene, copolymers, and/or mixtures thereof. The sealant is gas- and water-tight such that the glazing is sealed against the ingress of atmospheric humidity as well as the escape of a filler gas (if present).
The primary sealant is preferably introduced into the gap between spacer and the panes with a thickness of 0.1 mm to 0.8 mm, particularly preferably of 0.2 mm to 0.4 mm.
The reinforcing profile is preferably attached to both panes via an adhesive that is applied between the first side surface and the first pane and/or the second side surface and the second pane.
The adhesive for bonding the reinforcing profile is preferably an acrylate adhesive, polyurethane adhesive, silicone adhesive, silane-modified polymer adhesive, a mixture, and/or copolymer thereof.
An acrylate adhesive for bonding the reinforcing profile is used, in particular, in the form of an adhesive tape, which can, optionally, already be pre-applied to the spacer. Such acrylate adhesive types suitable for glazing applications are commercially available, provide a good seal against moisture, and require no curing time.
Alternatively, the adhesive for bonding the reinforcing profile can also be applied in liquid form.
In this case, two-component silicones, reactive polyurethane hotmelt adhesives, and/or silane-modified polymer adhesives in particular have proved to be advantageous. Two-component silicones have good mechanical strength and elasticity as well as rapid curing. Due to the good elastic properties, surface unevenness can be smoothed out well. Reactive polyurethane hotmelt adhesives have fast initial strength and high final strength, with permanent full curing achievable within approx. 24 hours. Silane-modified polymer adhesives are particularly hard.
The adhesive for bonding the reinforcing profile is preferably introduced into the gap between the reinforcing profile and the panes with a thickness of 0.2 mm to 1.6 mm, particularly preferably 0.3 mm to 1.4 mm, with said thicknesses existing after the pressing of the insulating glazing. The liquid adhesives mentioned as preferred can be used flexibly within these layer thicknesses. The adhesive layer thickness used can be flexibly adapted to the required layer thickness of the sealant and to any offset of the side surfaces of the reinforcing profile in the direction of the surface center of the outer surface.
The glazing interior of the insulating glazing is preferably filled with a protective gas, preferably with a noble gas, preferably argon or krypton, which reduce the heat transfer value in the insulating glazing interpane space.
In a possible embodiment, the insulating glazing comprises more than two panes.
In this case, for example, a third pane can be fixed in or on the spacer between the first pane and the second pane. In this embodiment, only a single spacer is used, which carries a reinforcing profile on its outer face.
Alternatively, multiple spacers can also be used. A further spacer is fixed to the first pane and/or second pane parallel to the spacer situated between the first and second pane. According to this embodiment, the insulating glazing has multiple spacers having a reinforcing profile.
The first pane and the second pane of the insulating glazing contain glass and/or polymers, preferably quartz glass, borosilicate glass, soda lime glass, polymethyl methacrylate, and/or mixtures thereof. Possible additional panes likewise comprise these materials, wherein the composition of the panes can also be different.
The panes of the insulating glazing according to the invention have a thickness of 1 mm to 50 mm, preferably 3 mm to 16 mm, particularly preferably 3 mm to 10 mm, wherein the two panes can also have different thicknesses.
At the corners of the insulating glazing, two mitered spacers abut and are, for example, welded to one another. To ensure good sealing of these welds, use of a primary sealant for bonding the main body to the reinforcing profile is advantageous. This sealant begins to flow during the welding operation and fills any gaps. As a result, good sealing of the welds is achieved. Alternatively, or additionally, any voids in the reinforcing profile can be filled with sealant to further improve the sealing of the welds.
In another embodiment, the corners of the spacer frame can be provided with corner connectors. Corner connectors can, for example, be implemented as a plastic molded part with or without a seal, in which two spacers abut. The legs of the corner connectors are inserted into the cavities of the spacer. The corner conductors optionally contain a seal that is compressed and thus sealed upon assembly of the individual parts, or are sealed by additional application of a sealant.
In principle, a wide variety of geometries of the insulating glazing are possible, for example, rectangular, trapezoidal, and rounded shapes. To produce rounded geometries, the spacer can, for example, be bent in the heated state. To facilitate bending of the spacer, the reinforcing profile can be cut at the outer bending radius and have, for example, V-shaped milling.
The invention further includes a method for producing an insulating glazing according to the invention, wherein a spacer according to the invention having a reinforcing profile is provided, a first pane is attached to the first pane contact surface of the polymeric main body and the first side surface of the reinforcing profile; and a second pane is attached to the second pane contact surface of the polymeric main body and the second side surface of the reinforcing profile, and the pane assembly is pressed to form an insulating glazing.
The first pane and the second pane can be attached to the spacer successively or simultaneously. The panes are preferably bonded to the pane contact surfaces via a primary sealant. At the side surfaces of the reinforcing profile, bonding is preferably carried out via one of the adhesives described for this purpose. The sealant and the adhesive can already be pre-applied to the spacer and are thus provided together with it. In this case, prior to attaching the panes, it is necessary only to remove a protective film protecting the sealant and adhesive strips. Alternatively, the sealant is applied to the pane contact surfaces prior to attaching the panes, preferably as a strand, for example, with a diameter of 1 mm to 2 mm. Before, after, or at the same time, but in any case prior to attaching the panes, the adhesive is applied on the side surfaces of the reinforcing profile. During the pressing of the pane assembly, the sealant and the adhesive are distributed evenly in the gap between the pane contact surface and the adjacent pane and between side surface and the adjacent pane, resulting in sealing of the gap. Alternatively, the panes can be fixed, as described, via adhesive tapes, or the main body and the reinforcing profile can be bonded with the same adhesive.
Preferably, the glazing interior between the panes is filled with a protective gas prior to the pressing of the assembly.
The invention further includes the use of an insulating glazing according to the invention as building glazing or façade glazing.
The invention is explained in detail in the following with reference to drawings. The drawings are purely schematic representations and are not to scale. They in no way restrict the invention. They depict:
U-shaped reinforcing profile 5.2. The insulating glazing 20 of
In another possible embodiment, the embodiments of
In all embodiments depicted in
1 first pane
2 second pane
3 glazing interior
4 sealant
5 spacer
5.1 polymeric main body
5.2 reinforcing profile
5.3 protrusions of the reinforcing profile
5.4 legs of the reinforcing profile
6 adhesive
7 pane contact surfaces
7.1 first pane contact surface
7.2 second pane contact surface
8 glazing interior surface
9 outer surface
10 cavity
11 desiccant
12 openings
13 outer interpane space
14 barrier film
15 inner face of the reinforcing profile 5.2
16 outer face of the reinforcing profile 5.2
17 side surfaces of the reinforcing profile 5.2
17.1 first side surface of the reinforcing profile 5.2
17.2 second side surface of the reinforcing profile 5.2
18 pressure equalization body
18.1 capillary
18.2 membrane
19 recesses of the polymeric main body 5.1
20 insulating glazing
Number | Date | Country | Kind |
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20181383.9 | Jun 2020 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2021/065811 | 6/11/2021 | WO |