1. Field of the Invention
The invention relates to an insulation material board composed of wood material/binder fiber mixture, to a method for producing an insulation material board and to an additive for improving the compressive strength and improving the structure of insulation material boards composed of a wood material/binder fiber mixture.
2. Background Description
The invention relates to an insulation material board composed of wood material/binder fiber mixture, to a method for producing an insulation material board and to an additive for improving the compressive strength and improving the structure of insulation material boards composed of a wood material/binder fiber mixture.
The production of insulation materials from fibers, for example fibers of wood, of flax, of hemp or of wool or the like, if appropriate with the addition of thermo-plastic binder fibers, is known. The production of these insulation materials and fleeces is carried out by the dry method, for example by means of aerodynamic fleece folding methods with a spatial orientation of the fiber/binder fiber matrix in a drum opening and distributing the fiber stock and with a subsequent thermal consolidation of the fiber/binder fiber matrix in a hot-air throughflow dryer. This is described, for example in DE 100 56 829 A1.
Where wood fiber insulation materials are concerned, the production of the insulation materials boards may also be carried out by the wet method with a subsequent hot-pressing method.
In the previous methods for the production of insulation materials from natural and synthetic fibers, there is still often an insufficient spatial orientation of the wood fibers and binder fibers. On account of the predominantly parallel orientation of the fibers, these insulation material boards can easily be split perpendicularly to the surfaces of the board in spite of thermal consolidation in the hot-air throughflow dryer. Moreover, the compressive strength of these insulation material boards is relatively low because of the low bulk density.
The result of this is that the use of such boards as insulation material and plaster base, particularly on the outside, presents problems, since the insulation materials having low compressive strength and low transverse tensile strength have to be fastened to the substrate by special fastening means. Moreover, too low a compressive strength has an adverse effect on the impact resistance of the composite heat insulation system.
To achieve a sufficient structural strength of the insulation material board, binder fibers are used, which, as a rule, consist of a polyester or of a polypropylene core with thicknesses of 2.2 to 4.4 detex in which are added in a proportion of up to 25 percent by weight. Since the costs of these binder fibers are relatively high in comparison with wood fibers, such insulation materials are comparatively costly. Furthermore, the addition of binder fibers has only a limited improving effect in increasing the compressive strength. An optimum bulk density for a wood fiber board as a plaster base board is approximately 100 kg/m3. Higher bulk densities have an adverse effect on the thermal conductivity of the insulation plate, in such a way that the required thermal conductivity group WLG 040 is not achieved, but, on the other hand, increased stability is achieved.
The object of the present invention is to provide an insulation material board, an additive for an insulation material board and a method for producing an insulation material board, by means of which the compressive strength and structural strength of insulation material boards composed of wood materials, in particular of wood fibers, with low bulk densities can be increased cost-effectively.
This object is achieved, according to the invention, by means of an insulation material board which is composed of a wood material/binder fiber mixture and in which an additive composed of a thermally resistant core is added to the mixture, the core being provided with a thermally activatable coating.
Advantageously, the core consists of perlite or of a thermosetting plastic material, thus resulting in an improvement in the moisture resistance of the insulation material board on account of the hydrophobic properties of the additive. This arises due to a mass of hydrophilic wood materials, in particular wood fibers, which is reduced according to the addition of the additive.
Furthermore, there is provision for the core to take the form of granulate or of a fiber material, in order to come into contact with as many wood material components or wood fibers and also binder fibers as possible.
To increase the compressive strength and transverse tensile strength, the dry wood fiber/binder fiber mixture has added to it a fine-grained granulate or fine-grained particles composed of bituminized perlite, of different thermoplastic groups, of thermoplastically encased thermosetting plastic groups or of comparable particles with a thermally resistant core and with a thermally activatable or thermoplastic casing. The grain sizes of the additives are in this case between 0.3 and 2.5 mm.
To increase the compressive and structural strength, the proportion of the additive in relation to the overall mass of the wood material/binder fiber mixture is at least 20%, but may even be 40% or more.
Advantageously, the additive is distributed homogeneously within the wood material/binder fiber mixture, in order to ensure a uniform compressive and structural strength of the insulation material board.
In contrast to the hydrophilic wood materials, there is provision for the additive to be hydrophobic, so that a higher moisture resistance of the insulation material board is achieved in addition to the improved compressive strength.
The insulation material board preferably has a bulk density of more than 20 kg/m3, but may even have a bulk density of above 100 kg/m3, in order to have, on the one hand, optimum strength and, on the other hand, optimum thermal conductivity, so that, when it is used as a stable plaster base, good insulation is ensured.
By the additive being used, the proportion of the binder fibers can be reduced to approximately 10 percent by weight in relation to the overall mass of the insulation material board, thus reducing the costs of the insulation material board.
The additive according to the invention for improving the compressive strength and improving the structure of insulation material boards composed of a wood material/binder fiber mixture provides a thermally resistant core and a thermally activatable coating, so that both the wood materials and the binder fibers can be connected to the additive by the supply of energy. The supply of heat takes place, for example, by means of a hot-air throughflow dryer, hot-steam throughflow or HF heating. Other heating possibilities are likewise provided, for example by means of heated press plates.
The thermally activatable coating is preferably a thermoplastic or bitumen, and other thermally activatable coatings may likewise be arranged on a corresponding core, in order bring about a cross-linking of the wood materials and binder fibers with the additive.
The coating may surround the core completely, but alternatively only a partial coating of the surface of the core is provided.
The core consists of a granulate, for example of perlite or of another mineral basic material or of a fiber, while, alternatively to a mineral material, the core may also consist of a thermosetting plastic. It is likewise possible, in coordination with the process management, to employ a thermoplastic which remains dimensionally stable at the prevailing temperatures.
Advantageously, the additive may be a mixed plastic which, in addition to thermosetting plastic fractions, also has thermoplastic fractions. Mixed plastics of this type are, for example, products of the Dual System (DS) with average fractions of 50 to 70% polyolefins, 15 to 20% polystyrene, 5 to 15% PET and 1 to 5% of other packaging plastics. Such mixed plastics are produced by dry preparation methods, in particular mixed plastics from household garbage being used. The initial material is first comminuted in a comminution stage, magnetic substances are removed from the comminuted material, and the comminuted material is thermally agglomerated or compacted under pressure, that is to say press-agglomerated. During the agglomerating operation, volatile substances, water vapor, ash and paper can be suction-extracted by means of suction extraction devices.
The agglomerated material is subsequently dried to a desired residual moisture and screened. As a result of the agglomeration process, thermoplastic constituents, for example polyethylene (LDPE, HDPE) and thermosetting plastic constituents, for example polyesters or polyurethanes, are connected to form a granulate-like material. In this case, a thermosetting core composed, for example, of polyurethane is surrounded completely or partially by a thermally activatable thermoplastic casing composed, for example, of polyethylene, or a thermoplastic core melting at high temperatures is surrounded by a casing melting at low temperatures.
Mixed plastics agglomerated in this way have a sufficiently high proportion of thermally activatable (thermoplastic) fractions and of thermosetting constituents and are therefore particularly suitable as an additive for improving the compressive strength and improving the structure and/or as a binder for an insulation material board, since the thermoplastic casing of the additive can be thermally activated by means of the supply of sufficient temperature, for example in a hot-pressing operation. Advantageously, mixed plastics agglomerated in this way can be added to wood material fibers and known binder fibers on insulation material production lines, since the agglomerated mixed plastics have thermally activatable constituents which are activated by pressure and temperature for the production of insulation material boards, the thermosetting cores or the thermoplastic cores remaining stable. For this purpose, the press temperature is to be set in such a way that it is always lower than the melting temperature or the decomposition temperature of the core materials.
By agglomerated mixed plastic being added to the production of the insulation material boards, improved compressive strength and transverse tensile strength values of the boards can be achieved, without the proportion of costly binder fibers (with a polypropylene core and a polyethylene casing) having to be increased. Advantageously, the increase in the strength properties is possible solely by the addition of cost-effective agglomerated mixed plastics which originate from the Dual System.
The additive is hydrophobic, in order to improve moisture resistance.
In the method for producing an insulation material board with a wood material/binder fiber mixture, an additive with a thermally resistant core and with a thermally activatable coating is added to the mixture. The thermally activatable coating is activated by the supply of heat, so that the wood material/binder fiber mixture and the additive are cross-linked with one another. An insulation material board is thereby provided, which comes within the optimum bulk density range of approximately 100 kg/m3 and in this case has sufficient compressive strength and transverse tensile strength, at the same time with moisture resistance.
The coating of the core is in this case activated in a hot-air stream, although alternative activation methods, for example by heated rollers, HF heating or infrared emitters, are likewise possible.
For the uniform intermixing of the wood materials and of the binder fibers, these are mixed in an aerodynamic fleece forming machine, and the additive is subsequently admixed in a separate fleece forming machine. In this case, the spatial orientation of the fiber matrix is also carried out, this taking place in a separate aerodynamic fleece forming machine.
A uniform formation of the structure of the insulation material board is carried out by means of a homogeneous distribution of the additive within the wood material/binder fiber mixture.
The invention is explained in more detail below with reference to the single FIGURE.
The FIGURE shows the embedding of an additive into a wood fiber/binder fiber matrix.
The FIGURE illustrates a mixture of wood fibers 1 and of binder fibers 2 which are intermixed homogeneously in a first aerodynamic fleece forming machine. Alternatively to wood fibers 1, other wood materials, for example wood chips or the like, may also be used, for example also alternative raw materials, such as hemp, wool, flax or other renewable raw materials.
An admixing of an improving additive subsequently takes place, the latter consisting of a core 4 with a thermally activatable coating 3. This thermally activatable coating 3 may consist, for example, of bitumen or of a thermoplastic. This coating 3 may either surround the core 4 completely or be arranged only partially on the surface of the latter.
The additive 3, 4 is added to the dry mixture of wood fibers 1 and of binder fibers 2 as a fine-grained granulate or as particles composed of corresponding materials, such as bituminized perlites, coated thermo-plastic groups or thermoplastically encased thermo-setting groups. The grain sizes of the additive 3, 4 should be 0.3-2.5 mm, preferably 0.5-2 mm, for this intended use. To increase the compressive or structural strength, the proportion of the additive in the overall mass of the insulation board should be at least 20%, but even values of above 40% are possible.
The admixing of the additive 3, 4 and the spatial orientation of the fiber matrix take place, after the intermixing of the wood fibers 1 and binder fibers 2, in a separate second aerodynamic fleece forming machine. Owing to the addition of the additive 3, 4 along with the additional connecting action of the thermally activatable coating 3, the proportion of binder fibers 2 in the overall weight can be lowered to 10%.
Owing to the aerodynamic fleece or fiber folding method with spatial orientation, the particles of the additive 3, 4 are distributed homogeneously within the matrix of the wood fibers and binder fibers 1, 2. Activation advantageously takes place in a hot-air throughflow dryer, so that, as a result of the heat supplied to the thermoplastic casings 3 of the core 4, the additive particles form additional contact points with the wood fibers 1 and with the binder fibers 2. A fiber/binder additive matrix having compressive strength and improved structural strength is thereby provided.
The insulation materials improved by means of the additive 3, 4 may be employed as heat insulation material on the outside, for example for composite heat insulation systems and as impact sound insulation materials in the floor area, for example under laminate or finished parquet floors.
Heat insulation material board for heat insulation with a target bulk density of 100 kg/m3 and with a thickness of 100 mm by the addition of the additive.
Apparent density overall 10.056 g m2, proportion of the additive composed of various thermoplastic groups 3.394 g/m2 (proportion 60% in relation to absolutely dry wood fibers), proportion of the binder fiber 1.006 g/m2 (10%), proportion of wood fibers 5.656 g/m2, intermixing and folding of the fiber fleece in a drum, activation of the thermoplastic constituent in a hot-air throughflow dryer at 170° C.
Insulation material board for impact sound insulation, target bulk density 135 kg/m3 and with a thickness of 6 mm by the addition of the additive:
Apparent density overall 800 g/m2, proportion of the additive composed of various thermoplastic groups 206 g/m2 (proportion 40% in relation to absolutely dry wood fibers), proportion of the binder fiber 80 g/m2 (10%), proportion of wood fibers 514 g/m2, intermixing and folding of the fiber fleece in a drum, activation of the thermoplastic constituents in a hot-air throughflow dryer at 170° C.
Number | Date | Country | Kind |
---|---|---|---|
10 2004 011 931 | Mar 2004 | DE | national |
This application is a continuation of U.S. patent application Ser. No. 11/076,044, filed Mar. 10, 2005, now U.S. Pat. No. 7,550,202 and claims priority under 35 U.S.C. §119 to German Application No. 10 2004 011 931.7, filed Mar. 11, 2004, the disclosures of which are expressly incorporated by reference herein in their entirety.
Number | Name | Date | Kind |
---|---|---|---|
213740 | Conner | Apr 1879 | A |
623562 | Rider | Apr 1899 | A |
714987 | Wolfe | Dec 1902 | A |
753791 | Fulghum | Mar 1904 | A |
1124228 | Houston | Jan 1915 | A |
1407679 | Ruthrauff | Feb 1922 | A |
1454250 | Parsons | May 1923 | A |
1468288 | Een | Sep 1923 | A |
1477813 | Daniels | Dec 1923 | A |
1510924 | Daniels et al. | Oct 1924 | A |
1540128 | Houston | Jun 1925 | A |
1575821 | Daniels | Mar 1926 | A |
1602256 | Sellin | Oct 1926 | A |
1602267 | Karwisch | Oct 1926 | A |
1615096 | Meyers | Jan 1927 | A |
1622103 | Fulton | Mar 1927 | A |
1622104 | Fulton | Mar 1927 | A |
1637634 | Carter | Aug 1927 | A |
1644710 | Crooks | Oct 1927 | A |
1660480 | Daniels | Feb 1928 | A |
1714738 | Smith | May 1929 | A |
1718702 | Pfiester | Jun 1929 | A |
1734826 | Pick | Nov 1929 | A |
1764331 | Moratz | Jun 1930 | A |
1776188 | Langb'aum | Sep 1930 | A |
1778069 | Fetz | Oct 1930 | A |
1779729 | Bruce | Oct 1930 | A |
1787027 | Wasleff | Dec 1930 | A |
1823039 | Gruner | Sep 1931 | A |
1859667 | Gruner | May 1932 | A |
1898364 | Gynn | Feb 1933 | A |
1906411 | Potvin | May 1933 | A |
1921164 | Lewis | Aug 1933 | A |
1929871 | Jones | Oct 1933 | A |
1940377 | Storm | Dec 1933 | A |
1946648 | Taylor | Feb 1934 | A |
1953306 | Moratz | Apr 1934 | A |
1986739 | Mitte | Jan 1935 | A |
1988201 | Hall | Jan 1935 | A |
2023066 | Curtis et al. | Dec 1935 | A |
2044216 | Klages | Jun 1936 | A |
2065525 | Hamilton | Dec 1936 | A |
2123409 | Elmendorf | Jul 1938 | A |
2220606 | Malarkey et al. | Nov 1940 | A |
2276071 | Scull | Mar 1942 | A |
2280071 | Hamilton | Apr 1942 | A |
2324628 | Kähr | Jul 1943 | A |
2328051 | Bull | Aug 1943 | A |
2398632 | Frost et al. | Apr 1946 | A |
2430200 | Wilson | Nov 1947 | A |
2740167 | Rowley | Apr 1956 | A |
2894292 | Gramelspacker | Jul 1959 | A |
3045294 | Livezey, Jr. | Jul 1962 | A |
3100556 | De Ridder | Aug 1963 | A |
3125138 | Bolenbach | Mar 1964 | A |
3182769 | De Ridder | May 1965 | A |
3203149 | Soddy | Aug 1965 | A |
3204380 | Smith et al. | Sep 1965 | A |
3267630 | Omholt | Aug 1966 | A |
3282010 | King, Jr. | Nov 1966 | A |
3310919 | Bue et al. | Mar 1967 | A |
3347048 | Brown et al. | Oct 1967 | A |
3460304 | Braeuninger et al. | Aug 1969 | A |
3481810 | Waite | Dec 1969 | A |
3526420 | Brancaleone | Sep 1970 | A |
3538665 | Gohner | Nov 1970 | A |
3553919 | Omholt | Jan 1971 | A |
3555762 | Costanzo, Jr. | Jan 1971 | A |
3608258 | Spratt | Sep 1971 | A |
3694983 | Couquet | Oct 1972 | A |
3714747 | Curran | Feb 1973 | A |
3720027 | Christensen | Mar 1973 | A |
3731445 | Hoffmann et al. | May 1973 | A |
3759007 | Thiele | Sep 1973 | A |
3760548 | Sauer et al. | Sep 1973 | A |
3768846 | Hensley et al. | Oct 1973 | A |
3859000 | Webster | Jan 1975 | A |
3878030 | Cook | Apr 1975 | A |
3902293 | Witt et al. | Sep 1975 | A |
3908053 | Hettich | Sep 1975 | A |
3936551 | Elmendorf et al. | Feb 1976 | A |
3988187 | Witt et al. | Oct 1976 | A |
4006048 | Cannady, Jr. et al. | Feb 1977 | A |
4044087 | Robitschek et al. | Aug 1977 | A |
4090338 | Bourgade | May 1978 | A |
4091136 | O'Brian et al. | May 1978 | A |
4099358 | Compaan | Jul 1978 | A |
4118533 | Hipchen et al. | Oct 1978 | A |
4131705 | Kubinsky | Dec 1978 | A |
4164832 | Van Zandt | Aug 1979 | A |
4169688 | Toshio | Oct 1979 | A |
4242390 | Nemeth | Dec 1980 | A |
4243716 | Kosaka et al. | Jan 1981 | A |
4245689 | Grard et al. | Jan 1981 | A |
4246310 | Hunt et al. | Jan 1981 | A |
4290248 | Kemerer et al. | Sep 1981 | A |
4299070 | Oltmanns et al. | Nov 1981 | A |
4426820 | Terbrack et al. | Jan 1984 | A |
4431044 | Bruneau | Feb 1984 | A |
4471012 | Maxwell | Sep 1984 | A |
4501102 | Knowles | Feb 1985 | A |
4561233 | Harter et al. | Dec 1985 | A |
4585685 | Forry et al. | Apr 1986 | A |
4612745 | Hovde | Sep 1986 | A |
4641469 | Wood | Feb 1987 | A |
4653242 | Ezard | Mar 1987 | A |
4654244 | Eckert et al. | Mar 1987 | A |
4703597 | Eggemar | Nov 1987 | A |
4715162 | Brightwell | Dec 1987 | A |
4738071 | Ezard | Apr 1988 | A |
4752497 | McConkey et al. | Jun 1988 | A |
4769963 | Meyerson | Sep 1988 | A |
4819932 | Trotter, Jr. | Apr 1989 | A |
4831806 | Niese et al. | May 1989 | A |
4845907 | Meek | Jul 1989 | A |
4905442 | Daniels | Mar 1990 | A |
4947602 | Pollasky | Aug 1990 | A |
5029425 | Bogataj | Jul 1991 | A |
5103614 | Kawaguchi et al. | Apr 1992 | A |
5113632 | Hanson | May 1992 | A |
5117603 | Weintraub | Jun 1992 | A |
5136823 | Pellegrino | Aug 1992 | A |
5165816 | Parasin | Nov 1992 | A |
5179812 | Itill | Jan 1993 | A |
5205091 | Brown | Apr 1993 | A |
5216861 | Meyerson | Jun 1993 | A |
5251996 | Hiller et al. | Oct 1993 | A |
5253464 | Nilsen | Oct 1993 | A |
5283102 | Sweet et al. | Feb 1994 | A |
5295341 | Kajiwara | Mar 1994 | A |
5335473 | Chase | Aug 1994 | A |
5348778 | Knipp et al. | Sep 1994 | A |
5349796 | Meyerson | Sep 1994 | A |
5390457 | Sjölander | Feb 1995 | A |
5413834 | Hunter et al. | May 1995 | A |
5433806 | Pasquali et al. | Jul 1995 | A |
5474831 | Nystrom | Dec 1995 | A |
5489655 | Shimoda et al. | Feb 1996 | A |
5497589 | Porter | Mar 1996 | A |
5502939 | Zadok et al. | Apr 1996 | A |
5540025 | Takehara et al. | Jul 1996 | A |
5567497 | Zegler et al. | Oct 1996 | A |
5570554 | Searer | Nov 1996 | A |
5597024 | Bolyard et al. | Jan 1997 | A |
5630304 | Austin | May 1997 | A |
5653099 | MacKenzie | Aug 1997 | A |
5660926 | Skowronski et al. | Aug 1997 | A |
5671575 | Wu | Sep 1997 | A |
5688583 | Asai et al. | Nov 1997 | A |
5694734 | Cercone et al. | Dec 1997 | A |
5706621 | Pervan | Jan 1998 | A |
5736227 | Sweet et al. | Apr 1998 | A |
5749954 | Law et al. | May 1998 | A |
5768850 | Chen | Jun 1998 | A |
5797175 | Schneider | Aug 1998 | A |
5797237 | Finkell, Jr. | Aug 1998 | A |
5823240 | Bolyard et al. | Oct 1998 | A |
5827592 | Van Gulik et al. | Oct 1998 | A |
5860267 | Pervan | Jan 1999 | A |
5935668 | Smith | Aug 1999 | A |
5943239 | Shamblin et al. | Aug 1999 | A |
5953878 | Johnson | Sep 1999 | A |
5968625 | Hudson | Oct 1999 | A |
5985397 | Witt et al. | Nov 1999 | A |
5987839 | Hamar et al. | Nov 1999 | A |
6006486 | Moriau et al. | Dec 1999 | A |
6023907 | Pervan | Feb 2000 | A |
6065262 | Motta | May 2000 | A |
6094882 | Pervan | Aug 2000 | A |
6101778 | Martensson | Aug 2000 | A |
6119423 | Costantino | Sep 2000 | A |
6134854 | Stanchfield | Oct 2000 | A |
6148884 | Bolyard et al. | Nov 2000 | A |
6168866 | Clark | Jan 2001 | B1 |
6182410 | Pervan | Feb 2001 | B1 |
6186703 | Shaw | Feb 2001 | B1 |
6205639 | Pervan | Mar 2001 | B1 |
6209278 | Tychsen | Apr 2001 | B1 |
6216403 | Belbeoc'h | Apr 2001 | B1 |
6216409 | Roy et al. | Apr 2001 | B1 |
D442296 | Külik | May 2001 | S |
D442297 | Külik | May 2001 | S |
D442298 | Külik | May 2001 | S |
D442706 | Külik | May 2001 | S |
D442707 | Külik | May 2001 | S |
6224698 | Endo | May 2001 | B1 |
6238798 | Kang et al. | May 2001 | B1 |
6247285 | Moebus | Jun 2001 | B1 |
D449119 | Külik | Oct 2001 | S |
D449391 | Külik | Oct 2001 | S |
D449392 | Külik | Oct 2001 | S |
6324803 | Pervan | Dec 2001 | B1 |
6345481 | Nelson | Feb 2002 | B1 |
6363677 | Chen et al. | Apr 2002 | B1 |
6397547 | Martensson | Jun 2002 | B1 |
6418683 | Martensson et al. | Jul 2002 | B1 |
6421970 | Martensson et al. | Jul 2002 | B1 |
6427408 | Krieger | Aug 2002 | B1 |
6436159 | Safta et al. | Aug 2002 | B1 |
6438919 | Knauseder | Aug 2002 | B1 |
6446405 | Pervan | Sep 2002 | B1 |
6449913 | Shelton | Sep 2002 | B1 |
6449918 | Nelson | Sep 2002 | B1 |
6453632 | Huang | Sep 2002 | B1 |
6458232 | Valentinsson | Oct 2002 | B1 |
6460306 | Nelson | Oct 2002 | B1 |
6461636 | Arth et al. | Oct 2002 | B1 |
6465046 | Hansson et al. | Oct 2002 | B1 |
6490836 | Moriau et al. | Dec 2002 | B1 |
6497961 | Kang et al. | Dec 2002 | B2 |
6510665 | Pervan | Jan 2003 | B2 |
6516579 | Pervan | Feb 2003 | B1 |
6517935 | Kornfalt et al. | Feb 2003 | B1 |
6519912 | Eckmann et al. | Feb 2003 | B1 |
6521314 | Tychsen | Feb 2003 | B2 |
6532709 | Pervan | Mar 2003 | B2 |
6533855 | Gaynor et al. | Mar 2003 | B1 |
6536178 | Pålsson et al. | Mar 2003 | B1 |
6546691 | Leopolder | Apr 2003 | B2 |
6553724 | Bigler | Apr 2003 | B1 |
6558754 | Velin et al. | May 2003 | B1 |
6565919 | Hansson et al. | May 2003 | B1 |
6569272 | Tychsen | May 2003 | B2 |
6588166 | Martensson et al. | Jul 2003 | B2 |
6591568 | Palsson | Jul 2003 | B1 |
6601359 | Olofsson | Aug 2003 | B2 |
6606834 | Martensson et al. | Aug 2003 | B2 |
6617009 | Chen et al. | Sep 2003 | B1 |
6635174 | Berg et al. | Oct 2003 | B1 |
6641629 | Safta et al. | Nov 2003 | B2 |
6646088 | Fan et al. | Nov 2003 | B2 |
6647690 | Martensson | Nov 2003 | B1 |
6649687 | Gheewala et al. | Nov 2003 | B1 |
6659097 | Houston | Dec 2003 | B1 |
6672030 | Schulte | Jan 2004 | B2 |
6675545 | Chen et al. | Jan 2004 | B2 |
6681820 | Olofsson | Jan 2004 | B2 |
6682254 | Olofsson et al. | Jan 2004 | B1 |
6685993 | Hansson et al. | Feb 2004 | B1 |
6711864 | Erwin | Mar 2004 | B2 |
6711869 | Tychsen | Mar 2004 | B2 |
6715253 | Pervan | Apr 2004 | B2 |
6723438 | Chang et al. | Apr 2004 | B2 |
6729091 | Martensson | May 2004 | B1 |
6745534 | Kornfalt | Jun 2004 | B2 |
6761008 | Chen et al. | Jul 2004 | B2 |
6761794 | Mott et al. | Jul 2004 | B2 |
6763643 | Martensson | Jul 2004 | B1 |
6766622 | Thiers | Jul 2004 | B1 |
6769217 | Nelson | Aug 2004 | B2 |
6769218 | Pervan | Aug 2004 | B2 |
6769835 | Stridsman | Aug 2004 | B2 |
6772568 | Thiers et al. | Aug 2004 | B2 |
6786019 | Thiers | Sep 2004 | B2 |
6803109 | Qiu et al. | Oct 2004 | B2 |
6805951 | Kornfält et al. | Oct 2004 | B2 |
6823638 | Stanchfield | Nov 2004 | B2 |
6833188 | Semmens | Dec 2004 | B2 |
6841023 | Mott | Jan 2005 | B2 |
20010029720 | Pervan | Oct 2001 | A1 |
20010034992 | Pletzer et al. | Nov 2001 | A1 |
20020007608 | Pervan | Jan 2002 | A1 |
20020007609 | Pervan | Jan 2002 | A1 |
20020014047 | Thiers | Feb 2002 | A1 |
20020020127 | Thiers et al. | Feb 2002 | A1 |
20020046528 | Pervan et al. | Apr 2002 | A1 |
20020056245 | Thiers | May 2002 | A1 |
20020106439 | Cappelle | Aug 2002 | A1 |
20020160680 | Laurence et al. | Oct 2002 | A1 |
20030024200 | Moriau et al. | Feb 2003 | A1 |
20030024201 | Moriau et al. | Feb 2003 | A1 |
20030029115 | Moriau et al. | Feb 2003 | A1 |
20030029116 | Moriau et al. | Feb 2003 | A1 |
20030029117 | Moriau et al. | Feb 2003 | A1 |
20030033777 | Thiers et al. | Feb 2003 | A1 |
20030033784 | Pervan | Feb 2003 | A1 |
20030115812 | Pervan | Jun 2003 | A1 |
20030115821 | Pervan | Jun 2003 | A1 |
20030134556 | Christie et al. | Jul 2003 | A1 |
20030159385 | Thiers | Aug 2003 | A1 |
20030167717 | Garcia | Sep 2003 | A1 |
20030196405 | Pervan | Oct 2003 | A1 |
20030205013 | Garcia | Nov 2003 | A1 |
20030233809 | Pervan | Dec 2003 | A1 |
20040014382 | MacAulay | Jan 2004 | A1 |
20040016196 | Pervan | Jan 2004 | A1 |
20040035078 | Pervan | Feb 2004 | A1 |
20040092006 | Lindekens et al. | May 2004 | A1 |
20040105994 | Lu et al. | Jun 2004 | A1 |
20040139678 | Pervan | Jul 2004 | A1 |
20040159066 | Thiers et al. | Aug 2004 | A1 |
20040177584 | Pervan | Sep 2004 | A1 |
20040200165 | Garcia et al. | Oct 2004 | A1 |
20040206036 | Pervan | Oct 2004 | A1 |
20040237447 | Thiers et al. | Dec 2004 | A1 |
20040237448 | Thiers et al. | Dec 2004 | A1 |
20040241374 | Thiers et al. | Dec 2004 | A1 |
20040244322 | Thiers et al. | Dec 2004 | A1 |
20040250493 | Thiers et al. | Dec 2004 | A1 |
20040255541 | Thiers et al. | Dec 2004 | A1 |
20040258907 | Kornfalt et al. | Dec 2004 | A1 |
20050003149 | Kornfalt et al. | Jan 2005 | A1 |
20050016099 | Thiers | Jan 2005 | A1 |
Number | Date | Country |
---|---|---|
005566 | Aug 2002 | AT |
713628 | May 1998 | AU |
200 020703 | Jan 2000 | AU |
417526 | Sep 1936 | BE |
557844 | Jun 1957 | BE |
557844 | Mar 1960 | BE |
09 600527 | Jun 1998 | BE |
09 700344 | Oct 1998 | BE |
991373 | Jun 1976 | CA |
2226286 | Dec 1997 | CA |
2252791 | May 1999 | CA |
2289309 | Jul 2000 | CA |
200949 | Jan 1939 | CH |
211877 | Jan 1941 | CH |
562377 | May 1975 | CH |
314207 | Jun 1919 | DE |
531989 | Aug 1931 | DE |
740235 | Oct 1943 | DE |
1 0899696 | Sep 1960 | DE |
1089966 | Sep 1960 | DE |
1534278 | Feb 1966 | DE |
1212225 | Mar 1966 | DE |
1212275 | Mar 1966 | DE |
1534802 | Apr 1970 | DE |
7102476 | Jun 1971 | DE |
2007129 | Sep 1971 | DE |
1534278 | Nov 1971 | DE |
2106690 | Sep 1972 | DE |
2252643 | Oct 1972 | DE |
2238660 | Feb 1974 | DE |
7402354 | May 1974 | DE |
2448319 | Apr 1976 | DE |
2502992 | Jul 1976 | DE |
2616077 | Oct 1977 | DE |
2 917025 | Nov 1980 | DE |
2917025 | Nov 1980 | DE |
7911924 | Mar 1981 | DE |
7928703 | May 1981 | DE |
3041781 | Jun 1982 | DE |
3214207 | Nov 1982 | DE |
8226153 | Jan 1983 | DE |
3343601 | Jun 1985 | DE |
86 040049 | Jun 1986 | DE |
3512204 | Oct 1986 | DE |
3246376 | Feb 1987 | DE |
4 004891 | Sep 1990 | DE |
4004891 | Sep 1990 | DE |
4002547 | Aug 1991 | DE |
4134452 | Apr 1993 | DE |
4215273 | Nov 1993 | DE |
4242530 | Jun 1994 | DE |
4011656 | Jan 1995 | DE |
4324137 | Jan 1995 | DE |
4107151 | Feb 1995 | DE |
29 517128 | Feb 1996 | DE |
4242530 | Sep 1996 | DE |
3544845 | Dec 1996 | DE |
29 710175 | Sep 1997 | DE |
19 616510 | Mar 1998 | DE |
19 651149 | Jun 1998 | DE |
19 709641 | Sep 1998 | DE |
19 718319 | Nov 1998 | DE |
19 735189 | Jun 2000 | DE |
20001225 | Aug 2000 | DE |
19 925248 | Dec 2000 | DE |
20 017461 | Mar 2001 | DE |
20 018284 | Mar 2001 | DE |
1 0022008 | Nov 2001 | DE |
1 0056829 | Jun 2002 | DE |
20 206460 | Aug 2002 | DE |
20 218331 | May 2004 | DE |
0 248127 | Dec 1987 | EP |
0248127 | Dec 1987 | EP |
0623724 | Nov 1994 | EP |
0652340 | May 1995 | EP |
0667936 | Aug 1995 | EP |
0690185 | Jan 1996 | EP |
0849416 | Jun 1998 | EP |
0698162 | Sep 1998 | EP |
0903451 | Mar 1999 | EP |
0855482 | Dec 1999 | EP |
0 969164 | Jan 2000 | EP |
0877130 | Jan 2000 | EP |
0969163 | Jan 2000 | EP |
0969164 | Jan 2000 | EP |
0974713 | Jan 2000 | EP |
1038898 | Sep 2000 | EP |
0843763 | Oct 2000 | EP |
1200690 | May 2002 | EP |
0958441 | Jul 2003 | EP |
1026341 | Aug 2003 | EP |
163421 | Sep 1968 | ES |
460194 | May 1978 | ES |
283331 | May 1985 | ES |
00 06854 | Dec 1991 | ES |
1019585 | Jan 1992 | ES |
2168045 | May 2002 | ES |
843060 | Aug 1984 | FI |
1293043 | Apr 1962 | FR |
2691491 | Nov 1983 | FR |
2 568295 | May 1986 | FR |
2623544 | May 1989 | FR |
2 630149 | Oct 1989 | FR |
26379232 | Apr 1990 | FR |
2675174 | Oct 1991 | FR |
2667639 | Apr 1992 | FR |
2691491 | Nov 1993 | FR |
2697275 | Apr 1994 | FR |
2712329 | May 1995 | FR |
2776956 | Oct 1999 | FR |
2781513 | Jan 2000 | FR |
2785633 | May 2000 | FR |
424057 | Feb 1935 | GB |
585205 | Jan 1947 | GB |
599793 | Mar 1948 | GB |
636423 | Apr 1950 | GB |
812671 | Apr 1959 | GB |
1033866 | Jun 1966 | GB |
1034117 | Jun 1966 | GB |
1044846 | Oct 1966 | GB |
1237744 | Jun 1968 | GB |
1127915 | Sep 1968 | GB |
1275511 | May 1972 | GB |
1 399402 | Jul 1975 | GB |
1399402 | Jul 1975 | GB |
1430423 | Mar 1976 | GB |
2 117813 | Oct 1983 | GB |
2117813 | Oct 1983 | GB |
2126106 | Mar 1984 | GB |
2152063 | Jul 1985 | GB |
2238660 | Jun 1991 | GB |
2243381 | Oct 1991 | GB |
2256023 | Nov 1992 | GB |
54-65528 | May 1979 | JP |
57-119056 | Jul 1982 | JP |
59-186336 | Oct 1984 | JP |
3-169967 | Jul 1991 | JP |
4-106264 | Apr 1992 | JP |
5-148984 | Jun 1993 | JP |
6-56310 | May 1994 | JP |
6-146553 | May 1994 | JP |
6-200611 | Jul 1994 | JP |
6-320510 | Nov 1994 | JP |
7-76923 | Mar 1995 | JP |
7-180333 | Jul 1995 | JP |
7-300979 | Nov 1995 | JP |
7-310426 | Nov 1995 | JP |
8-109734 | Apr 1996 | JP |
8-270193 | Oct 1996 | JP |
2001181432 | Jul 2001 | JP |
7601773 | Feb 1976 | NE |
157871 | Feb 1988 | NO |
305614 | Jun 1999 | NO |
363795 | Dec 1972 | RU |
711 4900-9 | Sep 1974 | SE |
450411 | Jun 1987 | SE |
450141 | Sep 1987 | SE |
501014 | Oct 1994 | SE |
501914 | Jun 1995 | SE |
502994 | Apr 1996 | SE |
506254 | Nov 1997 | SE |
509059 | Nov 1998 | SE |
509060 | Nov 1998 | SE |
512290 | Feb 2000 | SE |
512313 | Feb 2000 | SE |
0000200-6 | Aug 2001 | SE |
8402155 | Jun 1984 | WO |
8703839 | Jul 1987 | WO |
8908539 | Sep 1989 | WO |
9217657 | Oct 1992 | WO |
9313280 | Jul 1993 | WO |
9319910 | Oct 1993 | WO |
9401628 | Jan 1994 | WO |
94 26999 | Nov 1994 | WO |
9426999 | Nov 1994 | WO |
9506176 | Mar 1995 | WO |
9627719 | Sep 1996 | WO |
9627721 | Sep 1996 | WO |
9630177 | Oct 1996 | WO |
9747834 | Dec 1997 | WO |
9824495 | Jun 1998 | WO |
9824994 | Jun 1998 | WO |
9838401 | Sep 1998 | WO |
99 40273 | Aug 1999 | WO |
9966151 | Dec 1999 | WO |
99 66152 | Dec 1999 | WO |
00 06854 | Feb 2000 | WO |
00 66856 | Nov 2000 | WO |
01 66876 | Sep 2001 | WO |
Number | Date | Country | |
---|---|---|---|
20090142611 A1 | Jun 2009 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 11076044 | Mar 2005 | US |
Child | 12143229 | US |