The present invention is related to a mechanism for coupling motion of an actuator in axisymmetric devices like modulating proportional valves and is especially useful with regard to piezoelectric actuators. The mechanism uses actuator extension motion to cause translation away from a mechanism mounting plane and thereby enables lifting open of a valve element instead of the usual pushing closed of the valve element. The present inventive Interlace Lifting Mechanism can also be combined with the inventor's Multiflex Coupling, as disclosed in related application Ser. No. 13/794,517, already expressly incorporated by reference, in its entirety, herein, to provide increased stroke. The invention is particularly useful in valves intended for proportional, or modulating, control of fluid delivery within industrial processes making semiconductor devices, pharmaceuticals, or fine chemicals, and many similar fluid delivery systems.
The field of control valves intended for use within automated process control systems is broad and well known. Many proportional control valves have one or more movable elements that may be actively positioned, anywhere between an extreme open condition and an extreme closed condition, to adjust the flow of fluid passing therethrough. Fluid delivery apparatuses intended for manipulating process materials within semiconductor manufacturing equipment usually require attention to maintaining high purity of the delivered reactants and also are typically much smaller than valves used in petrochemical plants, for example. Nonetheless, many different types of powered valve actuators are found in high purity instrumentation and control apparatus such as mass flow controllers. U.S. Pat. No. 4,695,034 issued to Shimizu et al. describes use of a stack of piezoelectric disc elements to effect movement of valve parts in a mass flow controller. U.S. Pat. No. 4,569,504 issued to Doyle describes use of a magnetic solenoid with interleaved magnetic circuit elements. U.S. Pat. No. 5,660,207 issued to Mudd describes use of a heated resistance wire that changes length with temperature to effect valve element movement. U.S. Pat. No. 6,178,996 issued to Suzuki describes use of a pressurized fluid, such as nitrogen gas, in a bellows actuator to control the degree of opening of a diaphragm-operated control valve.
One disadvantage of both magnetic solenoid and thermal expansion type actuators is inherent constant power consumption when controlling valve elements are positioned at an intermediate condition, such as when actively regulating fluid flow. A piezoelectric actuator is effectively a capacitor in an electrical circuit, and therefore does not consume current when an applied voltage is constant. Consequently, typical piezoelectric control valve applications only require low power and avoid the undesirable generation of heat found in electromagnetic actuators. A piezoelectric actuator advantageously may produce substantially more force than a solenoid actuator of comparable size, but achievable strain severely limits the distance a piezoelectric stack can move. Valve power consumption is of particular concern in instrumentation devices such as compact mass flow controllers.
Piezoelectric actuators nearly always are used in a manner wherein applying an activation voltage causes an extensional increase in the stack length (see Shimizu et al. '034 and U.S. Pat. No. 5,094,430 to Shirai et al.). Shimizu et al. increase the available movement by interposing a force transmission member, comprising a plurality of radial lever-arm fingers, between the stack of piezoelectric disc elements and the moving portion of the control valve. These force transmission members are complicated and difficult to manufacture correctly. Piezoelectric actuators are typically associated with normally open valves wherein increasing applied voltage then causes the valve to decrease fluid flow. Normally closed valves using piezoelectric actuators, wherein increasing applied voltage then causes the valve to increase fluid flow, often have a complicated fluid flow path structure with a poppet driven by a shaft passing through the valve seat orifice (e.g. see FIG. 3 and FIG. 10 of Shimizu et al. '034) which may adversely impact fluid purity. A valve designer will benefit from having a mechanism to seemingly reverse the direction of actuator extension motion which thereby allows normally closed valves to use a piezoelectric actuator lifting a diaphragm to open the valve while avoiding the complexities and compromises of a shaft through the valve seat.
In consideration of the foregoing, the inventor has invented a mechanism that surrounds a piezoelectric stack actuator and contacts opposite ends of the piezoelectric stack, whereby extension motion (lengthening) of the actuator causes a lifting portion of the mechanism to translate toward the bulk of the actuator while the proximally adjacent mounting portion of the mechanism remains at a fixed location. The mechanism does not contain any gears nor leadscrew threads, and in usual practice is constantly loaded, so apparent change of direction is achieved without mechanical backlash introducing hysteresis. The following description may use notional directions (up and down, above and below, left and right, front and back, etc.) to assist understanding of relationships among the mechanism pieces, and illustrative drawing figures generally will match said notional directions, but it should be appreciated that an apparatus using the invention may attain any orientation in space, including actively translating or rotating or tumbling, without effect on the mechanism function.
In a typical embodiment the inventive mechanism is comprised of a mounting portion, a lifting portion, a cross-over support, and a coupling disc. The mounting portion has a central opening through which part of the lifting portion projects and the cross-over support sits against the mounting portion astride the lifting portion projection. The coupling disc functions as a resilient element uniting the mounting portion and the lifting portion, while maintaining radial and angular alignment, yet it allows axial movement of the lifting portion relative to the mounting portion and cross-over support. This over and under relationship among the fixed and moving parts of the mechanism prompts the inventor to identify his invention as an “Interlace Lifting Mechanism” for convenience of identification, but no additional significance nor limitation shall be thereby presumed.
In one embodiment 100 of an Interlace Lifting Mechanism a mounting portion may be formed as a circular mounting nut 10 with a threaded region 11 for engaging a mating thread formed in the body 99 of a fluid delivery apparatus. The mounting nut 10 is pierced axially by an oblong slot 12 and has a step feature 15 beyond the periphery of the oblong slot 12 to receive and locate a cross over plate 20. A cross over plate 20 may conveniently be a disk shape with alignment 21 and clearance 22 features on its upper and lower surfaces. A lifting portion of the one embodiment may be comprised of three parts including a lifting housing 30, an actuator housing 40, and a housing lock nut 50. The lifting housing 30 may be formed as a circular shell having an outward axially projecting traverse bar 32 of shape and dimension similar to the oblong slot 12 and extending diametrically across the open lower end 35 of the shell only partially covering the shell open lower end 35. The lifting housing 30 is connected to a coupling disc 60 and the coupling disc 60 is connected to the mounting nut 10 thereby locating the traverse bar 32 projection within the oblong slot 12. The cross over plate 20 may be positioned inside the lifting housing 30 against the partially exposed mounting nut 10 and located by the step feature 15 to be astride the traverse bar 32 axial projection and oblong slot 12.
In the embodiment 100 of an Interlace Lifting Mechanism a lower end 91 of an actuator 90 may be coupled against the cross over plate 20. The actuator housing 40 may be formed as a circular tube shape having threads 41 to engage mating threads 31 formed on the lifting housing 30 and an inward directed lip 45 may be formed on the upper end of the actuator housing 40 to contact the upper end 95 of the actuator 90. Engagement between the actuator housing 40 and the lifting housing 30 may thus be adjusted until the actuator 90 is properly captured between the cross over plate 20 and the lip 45. The housing lock nut 50 may then be used to prevent unintended changes of this engagement. An actuator preload spring 88 may be located between an inward lip 37 at the lower end of the lifting housing 30 and the lower end 91 of the actuator 90 to provide static compression of the actuator. Such preload spring 88 is particularly useful in the application of piezoelectric stack actuators. Applying an activation voltage to the piezoelectric stack causes an extensional increase in the actuator length that translates the actuator housing 40 away from the cross over plate 20 which rests upon the mounting nut 10, and thereby moves the lifting housing 30 with its traverse bar 32 relative to the mounting nut 10 while deflecting the coupling disc 60. A fluid driven actuator of hermetic design (without sliding seals) such as a hydraulic bellows may also be considered for use with the one embodiment 100 of an Interlace Lifting Mechanism.
It should be appreciated that a circular cross-section is chosen for the axisymmetric lifting housing 30 and actuator housing 40 merely for convenience, while an open frame type (typically but not solely bilaterally symmetric) structure would also suffice. In the situation of an open frame, a rectangular structure may surround a piezoelectric stack similar to a picture frame with the bottom of the frame comprising the lifting portion of the mechanism. It should also be appreciated that a flange may be used for attachment of the mounting portion of the mechanism and threaded fasteners, or other attachment methods such as welding or adhesives, can be used to secure the mechanism to a fluid delivery apparatus body 99.
Another embodiment 500 of an Interlace Lifting Mechanism is constructed with a Multiflex Coupling, as described in detail within U.S. patent application Ser. No. 13/794,517, placed in series with a piezoelectric stack actuator within the inventive mechanism. A mounting portion of this other embodiment may be formed as a circular mounting nut 510 with a threaded region 511 for engaging a mating thread formed in the body 599 of a fluid delivery apparatus. The mounting nut 510 is pierced axially by an oblong slot 512 and has a step feature 515 beyond the periphery of the oblong slot 512 to receive and locate a cross over plate 520. A cross over plate 520 may conveniently be a disk shape with alignment 521 and clearance 522 features on its upper and lower surfaces. A lifting portion of this other embodiment may be comprised of four parts including a lifting housing 530, a Multiflex Coupling assembly, an actuator housing 540, and a housing lock nut 550. The lifting housing 530 may be formed as a circular shell having an outward axially projecting traverse bar 532 of shape and dimension similar to the oblong slot 512 and extending diametrically across the open lower end of the shell only partially covering the shell open lower end. The lifting housing 530 is connected to a coupling disc 560 and the coupling disc 560 is connected to the mounting nut 510 thereby locating the traverse bar 532 projection within the oblong slot 512. The cross over plate 520 may be positioned inside the lifting housing 530 against the partially exposed mounting nut 510 and located by the step feature 515 to be astride the traverse bar 532 axial projection and oblong slot 512.
In this other embodiment 500, a Multiflex Coupling is placed in contact with the cross over plate 520 and also engaged with the lifting housing 530. A threaded post feature 521 on the upper surface of the cross over plate 520 may conveniently fit into a mating threaded hole 579 in the lower reactive element 578 portion of the Multiflex Coupling. The upper passive element 575 portion of the Multiflex Coupling may be held against a shoulder 535 of the lifting housing 530 by a locking ring 584 (or other means such as threads, pins, crimping, or welding) whereby the passive element 575 and lifting housing 530 remain in located contact with each other and move in unison. A preload spring 588 between the cross over plate 520 and the Multiflex Coupling reactive element 578 provides force which is additional to that resulting from the mere zero-clearance adjustment of the mechanism elements and is particularly useful with piezoelectric actuator stacks.
In this other embodiment 500 of an Interlace Lifting Mechanism the lower end 591 of an actuator 590 may be placed in contact with the upper active shaft element 580 portion of the Multiflex Coupling. The actuator housing 540 may be formed as a circular tube shape having threads 541 to engage mating threads 531 formed on the lifting housing 530 and a top capping end 545 may be formed on the upper end of the actuator housing 540 to contact the upper end 595 of the actuator 590. Engagement between the actuator housing 540 and the lifting housing 530 may thus be adjusted until the actuator 590 is properly captured between the Multiflex Coupling and the top capping end 545. The housing lock 550 nut may then be used to prevent unintended changes of this engagement. Applying an activation voltage causes an extensional increase in the actuator stack length that translates the actuator housing 540 away from the active shaft element 580 which is connected to the pivot pin 582 within the Multiflex Coupling. The actuator housing 540 being in fixed engagement with the lifting housing 530, in combination with the lifting housing 530 being in located contact with the passive element 575, causes the passive element 575 to move relatively away from the active shaft 580 and pivot pin 582. Relative motion between the pivot pin 582 and passive element 575 causes the rockers 576,577 to tip slightly and thereby increase the distance between the reactive element 578 and the passive element 575 by an amount defined by the mechanical gain of the Multiflex Coupling and the actuator extensional length increase. The passive element 575 being in located contact with the lifting housing 530, while the reactive element 578 contacts the cross over plate 520 resting against the mounting nut 510, thus moves the lifting housing 530 with its traverse bar 532 relative to the mounting nut 510 while deflecting the coupling disc 560.
In one particular aspect of the invention, there is provided a mechanism for coupling motion of an actuator, the mechanism being adapted to surround the actuator and to contact opposite ends of the actuator, whereby an extension motion lengthening the actuator causes a lifting portion of the mechanism to translate toward a bulkier portion of the actuator while a proximally adjacent mounting portion of the mechanism remains at a fixed location. This mechanism is axisymmetric. The actuator may be a piezoelectric stack actuator. An actuator preload spring provides a compressive force against the actuator which is independent from valve closing forces. A coupling is interposed between the actuator and the mounting portion of the mechanism for increasing a stroke of the actuator. An actuator spring provides a compressive force against the actuator which is independent from valve closing forces. The axisymmetric mechanism comprises a modulating proportional valve.
In another aspect of the invention, there is provided a mechanism used for lifting a valve actuator which is powered by a piezoelectric stack. The mechanism comprises a mounting portion, a lifting portion, a cross-over support, and a coupling disc. The mounting portion comprises a mounting nut. The mounting nut is threaded for connection to a valve body. A shutoff spring is positioned by the mounting portion. In certain embodiments, the shutoff spring comprises a Belleville spring washer. The cross-over support comprises a cross-over plate. The lifting portion comprises a lifting housing, an actuator housing, and a housing lock nut. The coupling disc comprises a substantially flat ring fabricated from a resilient material having spring-like characteristics.
The invention, together with additional features and advantages thereof, may best be understood by reference to the following description taken in conjunction with the accompanying illustrative drawings.
This invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the drawings. The invention is capable of other embodiments and of being practiced or of being carried out in various ways. Also, the phrasing and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of “including,” “comprising,” or “having,” “containing,” “involving,” and variations thereof herein, is meant to encompass the items listed thereafter and equivalents thereof as well as additional items.
Referring now more particularly to the drawings, a representative example of an Interlace Lifting Mechanism 100 may be affixed to a body 99 of a typical fluid delivery apparatus as illustrated in the assembly cross sectional views of
The mounting nut 10 may also axially position a shutoff spring 89 used to provide valve closing force which urges the movable flow modulating element 97 in the flow stopping direction. Such a spring provides valve closing force which is additional to the simple flexural characteristics of the valve diaphragm 98. In one particular convenient implementation, the shutoff spring 89 may comprise a Belleville spring washer interposed between the mounting nut 10 and a thrust bushing 93, which rides on the central shaft 96 to impart valve closing force to the diaphragm 98 and the flow modulating element 97. One or more shims 87a may optionally be placed between the shutoff spring 89 and the thrust bushing 93 for purposes of finely adjusting the added valve closing force, and additional shims 87b may also function as a hardened bearing surface for the shutoff spring 89 to push against the mounting nut 10.
The mounting nut 10 is pierced axially by an oblong slot 12 and has on its upper surface a step feature 15 beyond the periphery of the oblong slot 12 to receive and locate a cross-over plate 20. The cross-over plate 20 may conveniently be a disk shape with alignment and clearance features on its upper and lower surfaces.
A lifting portion of the illustrated embodiment may be comprised of three parts, including a lifting housing 30, an actuator housing 40, and a housing lock nut 50. The lifting housing 30 (as illustrated in
The lifting housing 30 is connected to the coupling disc 60 (as illustrated in
An alternative design using interference fit pins to connect a lifting housing to a coupling disc and the coupling disc to a mounting nut is described further below in conjunction with
The actuator housing 40 in the embodiment 100 may be formed as a circular tube shape having threads 41 to engage mating threads in the threaded region 31 formed on the lifting housing 30 and an inwardly directed lip 45 may be formed on the upper end of the actuator housing 40 to contact an upper end 95 of the actuator 90. Engagement between the actuator housing 40 and the lifting housing 30 may thus be adjusted until the actuator 90 is properly captured between the cross-over plate 20 and the lip 45. The ring-shaped housing lock nut 50 may then be used to prevent unintended changes of this engagement. The housing lock nut 50 may have one or more inward radial penetrations 53a, 54a, 53b, 54b (passing either partially or fully through the ring wall) that serve as points of engagement for a spanner wrench to help assemble the mechanism. A simple sliding fit between the actuator housing 40 and the lifting housing 30 may be used as an alternative to threads 31, 41 along with other locking means such as pins, crimping, adhesives, or welding which are also contemplated. The actuator housing 30 may be made from materials having a chosen low coefficient of thermal expansion, such as Invar alloys or Molybdenum metal, in applications having potentially problematic temperature variations. One or more annular elastomeric elements 55, 56 such as O-rings may be placed between the actuator periphery and the actuator housing interior to assist with assembly, handling, and mounting.
The cross-over plate 20 may be positioned inside the lifting housing 30 against the partially exposed mounting nut 10 and located by the step feature 15 to be astride the axial projection and oblong slot 12 of the traverse bar 32. In embodiment 100, the lower end 91 of the piezoelectric stack actuator 90 may be coupled against the cross-over plate 20 by use of a hard spherical ball engaging the conical alignment feature 21. Applying an activation voltage causes an extensional increase in the actuator stack length that translates the actuator housing 40 away from the cross-over plate 20, which rests upon the mounting nut 10, and thereby moves the lifting housing 30 with its traverse bar 32 relative to the mounting nut 10 while deflecting the coupling disc 60. This motion may be observed as a decrease of a clearance 18 between the retaining nut 94 and a cross-over plate clearance feature 22, a decrease of a clearance 17 between the top of the traverse bar 32 and the bottom of the cross-over plate 20, and an increase of a clearance 16 between the bottom of the traverse bar 32 and the mounting nut 10 as illustrated in
The aforementioned alternative embodiment 500 of an Interlace Lifting Mechanism is constructed with a Multiflex Coupling, as described in detail within U.S. patent application Ser. No. 13/794,517, placed in series with an actuator within the inventive Interlace Lifting Mechanism. This alternative example of an Interlace Lifting Mechanism 500 may be affixed to a body 599 of a typical fluid delivery apparatus as illustrated in the assembly cross-sectional views of
The mounting nut 510 may also axially position a shutoff spring 589 used to provide valve closing force, which urges the movable flow modulating element 597 in the flow stopping direction. Such shutoff spring provides valve closing force which is additional to the simple flexural characteristics of the valve diaphragm 598. In one convenient implementation, the shutoff spring 589 may comprise a Belleville spring washer interposed between the mounting nut 510 and a thrust bushing 593, which rides on the central shaft 596 to impart a valve closing force to the diaphragm 598 and flow modulating element 597. One or more shims 587a may optionally be placed between the shutoff spring 589 and the thrust bushing 593 for purposes of finely adjusting the added valve closing force, and additional shims 587b may also function as a hardened bearing surface for the shutoff spring 589 to push against the mounting nut 510.
The mounting nut 510 is pierced axially by an oblong slot 512 and has on its upper surface a step feature 515 beyond the periphery of the oblong slot 512 to receive and locate a cross-over plate 520. The cross-over plate 520 (shown sectioned in
A lifting portion of this alternative embodiment may be comprised of four parts including a Multiflex Coupling, a lifting housing 530, an actuator housing 540, and a housing lock nut 550. The lifting housing 530 (as illustrated in
The lifting housing 530 is connected to a coupling disc 560 (as illustrated in
The cross-over plate 520 may be positioned inside the lifting housing 530 against the partially exposed mounting nut 510, and located by the step feature 515 to be astride the traverse bar 532 axial projection and oblong slot 512, as may be appreciated by considering
The actuator housing 540 may be formed as a circular tube shape having threads 541 to engage mating threads 531 formed on the lifting housing 530. A top capping end 545 may be formed on the upper end of the actuator housing 540 to contact most of the upper end 595 of the piezoelectric stack actuator 590 excepting any electrical connections. Engagement between the actuator housing 540 and the lifting housing 530 may thus be adjusted until the piezoelectric stack 590 is properly captured between the Multiflex Coupling upper active shaft 580 and the top capping end 545. The housing lock nut 550 may then be used to prevent unintended changes of this engagement. The ring-shaped housing lock nut 550 may have one or more inward radial penetrations 553a, 554a, 553b, 554b (passing either partially or fully through the ring wall) that serve as points of engagement for a spanner wrench to help assemble the mechanism. In a similar manner the actuator housing 540 may have one or more inward radial penetrations 551a, 552a, 551b, 552b (passing either partially or fully through the tube wall) that serve as points of engagement for a spanner wrench to help assemble the mechanism. A simple sliding fit between the actuator housing 540 and the lifting housing 530 may be used as an alternative to threads 531, 541 along with other locking means such as pins, crimping, adhesives, or welding which are also contemplated. The actuator housing 540 may be made from materials having a chosen low coefficient of thermal expansion, such as Invar alloys or Molybdenum metal, in applications having potentially problematic temperature variations. One or more annular elastomeric elements 555, 556 such as O-rings may be placed between the actuator periphery and the actuator housing interior to assist with assembly, handling, and mounting.
Operation of the Multiflex Coupling is fully described in U.S. patent application Ser. No. 13/794,517, entitled Multiflex Coupling, as already referenced above. A complete Multiflex Coupling assembly for the instant embodiment includes an upper disk shaped element 575, two rocker elements 576, 577 placed side by side and below the upper disk, and a lower disk shaped element 578 under the rocker elements. A single pivot pin 582 passes through the pivot pin hole of the two semicircular rocker elements and lock pins (four pins 571, 572, 573, 574 being shown in
Applying an activation voltage to the piezoelectric stack actuator 590 causes an extensional increase in the actuator length that translates the actuator housing 540 away from the active shaft element 580, which is connected to the pivot pin 582 within the Multiflex Coupling. The actuator housing 540, being in fixed engagement with the lifting housing 530, in combination with the passive element 575 being in fixed contact with the lifting housing shoulder 535, causes the passive element 575 to move relatively away from the pivot pin 582. Relative motion between the pivot pin 582 and passive element 575 cause the rockers 576, 577 to tip slightly and to thereby increase the distance between the reactive element 578 and the passive element 575 by an amount defined by the mechanical gain of the Multiflex Coupling and the actuator extensional length increase. The passive element 575 being axially fixed with the lifting housing 530, while the reactive element 578 contacts the cross over plate 520 resting against the mounting nut 510, thus moves the lifting housing 530 with its traverse bar 532 relative to the mounting nut 510 while deflecting the coupling disc 560. This motion may be observed as a decrease of the clearance 518 between the retaining nut 594 and cross-over plate clearance feature 522, a decrease of the clearance 517 between the top of the traverse bar 532 and the bottom of the cross over plate 520, and an increase of the clearance 516 between the bottom of the traverse bar 532 and the mounting nut 510 as illustrated in
Another alternative design using interference fit pins to connect a lifting housing to a coupling disc and the coupling disc to a mounting nut will now be described. This pinned attachment design may be used with a simple Interlace Lifting Mechanism as illustrated in
The pinned attachment design lifting housing 630 is connected to a coupling disc 660 (detailed in
In a typical manufacturing sequence, the lifting housing shell 630, the coupling disc 660, and the mounting nut 610 are inverted and stacked in angular alignment as illustrated in
Having thus described several aspects of this invention, it is to be appreciated that various alterations, modifications, and improvements will readily occur to those skilled in the art. Such alterations, modifications, and improvements are intended to be part of this disclosure, and are intended to be within the scope of the invention. Accordingly, the foregoing description and drawings are by way of example only.
This application claims the benefit under 35 U.S.C. 119 of the filing date of Provisional U.S. Application Ser. No. 61/959,865, entitled Interlace Lifting Mechanism to Change Actuator from Push to Pull in Proportional Valve, filed on Sep. 4, 2013. This application is also related to U.S. patent application Ser. No. 13/794,517 entitled Multiflex Coupling, filed 11 Mar. 2013. Both of the foregoing applications are expressly incorporated herein by reference, in their entirety.
Number | Name | Date | Kind |
---|---|---|---|
4569504 | Doyle | Feb 1986 | A |
4695034 | Shimizu et al. | Sep 1987 | A |
4784102 | Igashira et al. | Nov 1988 | A |
5094430 | Shirai et al. | Mar 1992 | A |
5145147 | Nakazawa et al. | Sep 1992 | A |
5660207 | Mudd | Aug 1997 | A |
6178996 | Suzuki | Jan 2001 | B1 |
6345803 | Sakurai | Feb 2002 | B2 |
8162286 | Sawada | Apr 2012 | B2 |
8181932 | Matsumoto | May 2012 | B2 |
9280161 | Vu | Mar 2016 | B2 |
20040003786 | Gatecliff et al. | Jan 2004 | A1 |
20040104367 | Parsons et al. | Jun 2004 | A1 |
20090200406 | Kronberger | Aug 2009 | A1 |
20100127196 | Sawada | May 2010 | A1 |
20120273061 | Hidaka et al. | Nov 2012 | A1 |
20140374634 | Ohtsuki | Dec 2014 | A1 |
Number | Date | Country |
---|---|---|
0749058 | Dec 1996 | EP |
1975485 | Oct 2008 | EP |
2034047 | Mar 2009 | EP |
H06012146 | Feb 1994 | JP |
2000205428 | Jul 2000 | JP |
2003156167 | May 2003 | JP |
4119109 | Jul 2008 | JP |
2014190387 | Oct 2014 | JP |
Entry |
---|
International Search Report and Written Opinion issued Mar. 11, 2015, corresponding PCT App. No. PCT/US2014/054090. |
European Patent Office, Extended European Search Report Issued in Application No. 14842647.1, Feb. 23, 2017, Germany, 7 pages. |
Number | Date | Country | |
---|---|---|---|
20150059877 A1 | Mar 2015 | US |
Number | Date | Country | |
---|---|---|---|
61959865 | Sep 2013 | US |