Patent Application
20160004191
This patent application is based on and claims priority pursuant to 35 U.S.C. §119(a) to Japanese Patent Application No. 2014-136726, filed on Jul. 2, 2014, in the Japan Patent Office, the entire disclosure of which is hereby incorporated by reference herein.
1. Technical Field
The present disclosure relates to an intermediate transfer belt for use in electrophotography.
2. Description of the Related Art
In an electrophotographic image forming apparatus, for the purpose of reliably obtaining high quality image, a toner image is formed on an intermediate transfer belt to establish a standard of toner concentration. Imaging conditions, such as developing condition, are controlled in accordance with the detected toner concentration. The toner concentration is detected by emitting light from light emitting diode or the like to the toner image portion and the surface of the intermediate transfer belt, and detecting a difference in reflective light quantity between the toner image portion and the surface of the intermediate transfer belt. The greater the reflective light quantity from the intermediate transfer belt, the greater the dynamic range with respect to detection of the toner image and the better detection accuracy. Accordingly, the intermediate transfer belt is required to have a high degree of surface glossiness.
Materials usable for the intermediate transfer belt include thermosetting resins, such as polyimide, and thermoplastic resins, such as polyetheretherketone (PEEK) and polyvinylidene difluoride (PVDF). Because of being high in unit price and poor in processability and productivity, polyimide adversely raises component cost.
On the other hand, thermoplastic resins are low in unit price and easily moldable by extrusion, which is advantageous. In extrusion molding of thermoplastic resins, melt viscosity of the resin and surface roughness of a mold in use have a great influence on the surface roughness, as well as glossiness, of the molded belt. It is already known that the molded belt can be more improved in glossiness by post-processing, such as polishing with a polishing film for forming a mirror surface or formation of a coating layer on its surface.
However, such post-processing for enhancing the glossiness adversely increases the number of processing steps and raises component cost to the level of polyimide without taking advantage of low-cost thermoplastic resins.
In accordance with some embodiments of the present invention, an intermediate transfer belt for use in electrophotography is provided. The intermediate transfer belt includes a thermoplastic resin having a vinylidene difluoride (VdF) structure. The intermediate transfer belt has a degree of crystallinity in the range of 17% to 39%.
A more complete appreciation of the disclosure and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein:
Embodiments of the present invention are described in detail below with reference to accompanying drawings. In describing embodiments illustrated in the drawings, specific terminology is employed for the sake of clarity. However, the disclosure of this patent specification is not intended to be limited to the specific terminology so selected, and it is to be understood that each specific element includes all technical equivalents that operate in a similar manner and achieve a similar result.
One object of the present invention is to provide an intermediate transfer belt given a high glossiness without post-processing while taking advantage of good processability and low cost of thermoplastic resin.
A specific thermosetting resin having a low degree of crystallinity in a specific range is capable of giving glossiness to the extrusion-molded belt without post-processing such as polishing and coating.
In extrusion molding, materials in melt state flow out form a mold and pass through a calibrator while being cooled, thereby being molded into a tubular shape. Given a crystallization process of a polymer having a vinylidene difluoride structural site, the degree of crystallinity is determined by the time it takes to pass a crystallization temperature region in the process of transiting from melted state to solid state while being cooled. It is assumed that shortening of the transit time in the crystallization temperature region decreases the degree of crystallinity and increases the gloss. Accordingly, in actual extrusion molding, increasing the difference between the mold temperature (for melting) and the calibrator temperature (for cooling) can shorten the transit time in the crystallization temperature region, and as a result, the degree of crystallinity is decreased and the glossiness is increased.
Referring to
Having generally described this invention, further understanding can be obtained by reference to certain specific examples which are provided herein for the purpose of illustration only and are not intended to be limiting. In the descriptions in the following examples, the numbers represent weight ratios in parts, unless otherwise specified.
A polyvinylidene difluoride (KYNAR® 721 from Arkema) in an amount of 87.5 parts and a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) in an amount of 12.5 parts are dry-blended.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
In Table 1, X1 represents the addition amount of KYNAR® 721.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y1 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y2 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2851 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y2 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y2 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2851 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y2 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y2 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2851 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y2 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y2 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2851 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y2 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
X1 parts of a polyvinylidene difluoride (KYNAR® 721 from Arkema), Y2 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2851 from Arkema), and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended. Specific numeral values for X1 and Y2 are described in Table 1.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
Y1 parts of a copolymer of vinylidene difluoride and hexafluoropropylene (KYNAR® 2751 from Arkema) and 12.5 parts of a carbon black (DENKA BLACK having an average primary particle diameter of 35 nm from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
In Table 1, Y1 represents the addition amount of KYNAR® 2751.
X2 parts of a polyetheretherketone (VICTREX® PEEK 450P from Victrex plc.) and 15.0 parts of a carbon black (DENKA BLACK from Denki Kagaku Kogyo Kabushiki Kaisha) are dry-blended.
The blended material is kneaded with a kneader at a temperature equal to or less than the melting point of the resin for 80 minutes. The kneaded material is subjected to a dispersion treatment of the carbon black, serving as a conductive agent, with double rolls for 30 minutes, and then pelletized with a pelletizer.
In Table 1, X2 represents the addition amount of PEEK 450P.
The above-prepared compounds are subjected to melt extrusion molding and formed into seamless intermediate transfer belts.
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The pelletized compound is extrusion-molded into a belt shape having a thickness of T1 (described in Table 1) at a temperature of T2 (described in Table 1). The molded belt is passed through a calibrator at a winding speed described in Table 1 so as to have a temperature of T1 (described in Table 1).
The degree of crystallinity is measured with a differential scanning calorimeter (DSC). Specifically, an instrument DSC 6200 from Seiko Instruments Inc. is used.
An extrusion-molded belt-like sample in an amount of 5 mg is weighed in an aluminum pan, set to the DSC instrument, and subjected to a measurement. In the measurement, the temperature is raised from room temperature to 200° C. at a rate of 10° C./min. The measurement result shows a relation between temperature and heat quantity, as illustrated in
The melting heat of perfect crystal of PVDF and PEEK is 93.1 mJ/mg and 130 mJ/mg, respectively. The degree of crystallinity is calculated using these values.
ΔH1, ΔH2, and ΔH3 are measured with a differential scanning calorimeter (DSC). The used instrument, amount of the sample, and temperature settings are the same as those in the measurement of degree of crystallinity.
ΔH1, ΔH2, and ΔH3 represent heat of crystal melting generated at temperature ranges of 130° C. to 138° C., 155° C. to 160° C., and 165° C. to 172° C., respectively, and calculated from the areas of endothermic peak.
Glossiness is measured with an instrument GROSS CHECKER IG-320 from Horiba, Ltd.
The light source is an LED having a wavelength of 880 nm. The incidence angle and light-receiving angle are both 20 degrees.
Evaluation results in Table 1 are based on the following criteria.
Mechanical strength of an intermediate transfer belt is evaluated in terms of flex resistance.
Flex resistance is evaluated by a folding endurance test using an MIT type folding endurance tester. To conduct the folding endurance test under a condition as close as possible to the actual machine, the curvature radius of the folding surface of the folding clamp is set to 4.0 mm. The test is conducted under a load of 9.8 N and a folding angle of 135 degrees using a test specimen having width of 10 mm.
The number of times of folding until the test specimen fractures is defined as the number of times of folding endurance. In Table 1, mechanical strength is evaluated in terms of the number of times of folding endurance based on the following criteria.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2014-136726 | Jul 2014 | JP | national |
