The present invention relates in general to intra-cavity frequency-converted optically-pumped semiconductor (OPS) lasers. The invention relates in particular to intra-cavity frequency-converted OPS lasers generating third-harmonic radiation using a frequency-doubling stage followed by sum-frequency mixing stage.
Optically-pumped semiconductor lasers are now extensively used as compact sources of high-quality continuous-wave (CW) laser-radiation for flow-cytometry and other bio-instrumentation applications. An OPS laser employs as a gain-medium a multilayer structure of semiconductor gain-providing layers (“quantum well layers”) separated by semiconductor spacer layers. An advantageous feature of OPS lasers is that an arbitrary fundamental operating wavelength can be coarsely selected using a particular semiconductor composition for the quantum well layers. Such an OPS gain-structure is typically energized by radiation provided by one or more diode-lasers.
An OPS gain-element (“OPS chip”) includes an OPS gain-structure attached to a distributed Bragg reflector (DBR), which has repeating pairs of quarter-wavelength thick layers of semiconductor material with contrasting refractive indices. The DBR is a cavity mirror in the OPS laser. A detailed description of OPS lasers including intra-cavity frequency converted OPS lasers is provided in U.S. Pat. No. 5,991,318 and in U.S. Pat. No. 6,097,742, both assigned to the assignee of the present invention, and the complete disclosure of each of which is hereby incorporated herein by reference.
In theory, at least, there are semiconductor compositions that could be used as quantum-well layers to generate fundamental laser-radiation at any wavelength in the electromagnetic spectrum between the ultraviolet and the infrared. OPS lasers generate laser-radiation most efficiently and conveniently at near-infrared wavelengths, between about 800 nanometers (nm) and 1100 nm, using quantum-well layers in the gallium indium arsenide phosphide (Ga/In/As/P) system. Because of the high efficiency and corresponding high gain of OPS lasers that employ this system, shorter wavelength laser-radiation can be generated through intra-cavity frequency conversion of the fundamental laser-radiation. Intra-cavity frequency conversion includes frequency-doubling and sum-frequency-mixing operations.
In bio-instrumentation applications, there is a growing demand for compact sources providing CW laser-radiation at ultraviolet wavelengths less than about 400 nm. These are most efficiently generated by sum-frequency mixing (third-harmonic generation) using two intra-cavity optically nonlinear crystals. One of the crystals is arranged for frequency doubling to generate second-harmonic (2H) radiation from the fundamental laser radiation, the other crystal is arranged for sum-frequency mixing to generate third-harmonic (3H) radiation from the second-harmonic radiation and the residual fundamental radiation. By way of example, a fundamental wavelength of 1064 nm can be frequency-doubled to provide second-harmonic radiation having a wavelength of 532 nm. Sum-frequency mixing the fundamental and second-harmonic radiations generates third-harmonic radiation having a wavelength of about 355 nm.
A convenient arrangement for generating third-harmonic radiation is to employ type-I frequency-doubling followed by type-II sum-frequency mixing. In type-I frequency doubling, fundamental radiation is plane-polarized in a first polarization-orientation. The second-harmonic radiation is generated plane-polarized in a second polarization-orientation that is orthogonal to the first polarization-orientation. This arrangement provides that the fundamental radiation and second-harmonic radiation automatically have the relative orientations required for type-II sum-frequency mixing. An OPS gain-structure is not polarization selective, so an optical element must be provided in an OPS laser to cause the fundamental radiation to be plane-polarized in the first polarization-orientation. The polarizing element is typically a birefringent filter arranged at its Brewster angle. The birefringent filter also selects a fundamental wavelength from a relatively broad (about 30 nm) gain bandwidth of the OPS gain-structure.
A problem with the above described third-harmonic radiation generating arrangement is that the efficiency of type-II sum-frequency mixing falls off steeply at wavelengths less than 355 nm. This can be overcome by using type-I sum-frequency mixing, which can generate third-harmonic radiation with practical efficiencies for wavelengths as low as 280 nm. Unfortunately, in an arrangement wherein both frequency-doubling and sum-frequency mixing are type-I operations, an additional birefringent optical element is necessary between the second-harmonic generating and third-harmonic generating crystals to bring the fundamental radiation and second-harmonic radiation into the same first polarization-orientation.
In many of the above-discussed bio-instrumentation applications, it is usual to have several radiation sources, providing radiation at a different wavelengths. The cost of the radiation sources can be a critical issue. Birefringent optical elements contribute significantly to the cost of OPS laser-radiation sources. In an intra-cavity frequency-tripled OPS laser, there must be at least three birefringent elements, two of which are the optically nonlinear crystals used for the frequency-conversion. It would be advantageous to be able to perform the above-described type-I third-harmonic generation without need for the additional birefringent element.
In one aspect, laser apparatus in accordance with the present invention comprises a laser-resonator including an optically-pumped semiconductor gain-structure for generating laser radiation having a fundamental wavelength. The laser-resonator is arranged to circulate the fundamental-wavelength radiation in the laser-resonator. First and second optically nonlinear crystals are provided and located in the laser-resonator. A birefringent filter is provided and located in the laser-resonator between the first and second optically nonlinear crystals. The birefringent filter is arranged to select the fundamental wavelength from within a gain-bandwidth of the optically-pumped semiconductor gain-structure and to cause the circulating fundamental-wavelength radiation to be plane-polarized in a first polarization-orientation. The first optically nonlinear crystal is arranged to generate from the plane-polarized fundamental-wavelength radiation second-harmonic radiation that is plane-polarized in a second polarization-orientation. The second polarization location is orthogonal to the first polarization-orientation. The birefringent filter is further arranged to pass the fundamental-wavelength radiation with the polarization-orientation unchanged and to rotate the polarization-orientation of the second-harmonic radiation from the second polarization-orientation to about the first polarization-orientation. The second optically nonlinear crystal is arranged to generate third-harmonic radiation from the circulating fundamental-wavelength radiation and the polarization-rotated second-harmonic radiation.
The accompanying drawings, which are incorporated in and constitute a part of the specification, schematically illustrate a preferred embodiment of the present invention, and together with the general description given above and the detailed description of the preferred embodiment given below, serve to explain principles of the present invention.
Turning now to the drawings,
Fundamental-wavelength radiation is generated when pump-radiation is delivered to gain-structure 18 of the OPS-chip. Resonator 20 is arranged to circulate the fundamental-wavelength radiation in resonator 20 along a path designated by single arrowheads F. A birefringent filter (BRF) 40 in accordance with the present invention is located between fold mirrors 26 and 28. BRF 40 is inclined at about the Brewster angle to the circulating fundamental radiation and causes the circulating fundamental radiation to be plane-polarized about in the plane-of-incidence (plane-of-inclination) of the BRF, here, in the plane of the drawing. This polarization-orientation is indicated in the drawing by arrows PF. This polarization-orientation can be arbitrarily described as a vertical polarization-orientation. BRF 40 also selects a wavelength for the fundamental radiation from within a gain-bandwidth of the OPS-gain-structure.
An optically nonlinear crystal 30 is located in resonator 20 between end mirror 22 and fold mirror 28. Crystal 30 is arranged for type-I frequency-doubling of the fundamental-wavelength radiation thereby generating radiation having a wavelength which is the second-harmonic of the fundamental wavelength. The generated second-harmonic radiation follows a path designated in the drawing by double arrowheads 2H. The second-harmonic radiation leaving crystal 30 is plane-polarized in an orientation orthogonal to that of the fundamental-wavelength radiation as indicated by arrowheads P2H. This polarization-orientation can be described as a horizontal polarization-orientation. Those skilled in the art will appreciate that the second-harmonic-radiation path is depicted in the drawing as laterally separated from the fundamental-radiation path for convenience of illustration. In practice, the radiation paths are collinear.
Second-harmonic radiation exiting crystal 30 is reflected by fold mirror 28, together with residual fundamental-wavelength radiation, towards BRF 40. BRF 40 transmits fundamental-wavelength radiation with the polarization-orientation thereof unchanged, while rotating the polarization-orientation of the second-harmonic radiation by 90° into alignment with the polarization-orientation of the fundamental-wavelength radiation.
The similarly-polarized fundamental and second-harmonic radiations are reflected from fold mirror 26 towards an optically nonlinear crystal 32. Crystal 32 is arranged for type-I sum-frequency mixing of the fundamental radiation and second-harmonic radiation and thereby generates radiation having a wavelength which is the third-harmonic of the fundamental wavelength. The third-harmonic radiation is indicated in the drawing by triple arrowheads 3H. The third-harmonic-radiation path is depicted laterally separated from the fundamental-radiation path merely for convenience of illustration, as discussed above with reference to the second-harmonic-radiation and fundamental-radiation paths.
The third-harmonic radiation and residual second-harmonic radiation from the sum-frequency mixing can be transmitted out of resonator 20 through fold mirror 24, for example, by providing a coating on fold mirror 24 in the form of a short-wavelength-pass filter. The transmitted second-harmonic radiation and third-harmonic radiation can be separated outside of the resonator, for example, by a dichroic filter.
BRF 40, also not shown in
To effect polarization-rotation of the fundamental radiation and second-harmonic radiation, optic-axis 50 of the BRF is oriented at an angle ϕ with respect to polarization-orientation PF. In an ideal case, angle θ would be 45°. When phase retardations for fundamental radiation and second-harmonic radiation traversing BRF 40 are n2π and m2π+π, respectively, the polarization-orientation PF is unchanged and the polarization-orientation P2H is rotated by 90° into alignment with orientation PF. This condition sets up the fundamental radiation and second-harmonic radiation for type-I sum-frequency mixing in crystal 32, as discussed above.
In practice it would prohibitively expensive to manufacture a BRF with a precise thickness t that would produce exactly the required relative phase-retardation for the fundamental radiation and second-harmonic radiation, with a tuning angle θ of 45°. It was determined through calculation and experiment, however, that for a BRF having an arbitrarily-selected thickness t there will be a tuning angle θ acceptably close to 45° that will provide the required relative phase retardation. A description of these calculations and experiments is set forth below beginning with reference to
It is assumed in the calculations of
In practice it is very difficult to repeatedly fabricate a BRF having an exact thickness and precise orientation of optic-axis 50 with respect to surfaces of the BRF. However, as indicted by the graphs of
The measurement was made by locating the BRF between crossed polarizers; illuminating the BRF with white light through one of the polarizers, and analyzing light transmitted through the other polarizer with a spectrometer. The tuning angle θ of the BRF was initially set at 45°. The transmission orders n are indicated by a plurality of minima of transmission. It can be seen that there is a minimum M at a wavelength of two or three nanometers short of the required 920 nm fundamental wavelength. The BRF was held in a fixture which allowed the tuning angle θ to be varied as indicated by arrow R in
In practice the BRF would be fabricated to perform the functions described above, arranged in the laser-resonator between the optically non-linear crystals, and then aligned empirically as follows. To generate a third-harmonic wavelength of 306.7 nm corresponding to a second-harmonic wavelength of 460.0 nm, the BRF tuning angle θ would be adjusted to about 45.6°, which is a point E in
Sum-frequency mixing is tolerant of imperfect alignment of the polarization-orientations of the fundamental radiation and second-harmonic radiation. Although the selected second-harmonic wavelength of 460.0 nm may not correspond to exactly 90° polarization rotation of the second-harmonic radiation, the polarization-orientations PF and P2H exiting the birefringent filter will be sufficiently aligned to enable efficient generation of third-harmonic radiation and efficient operation of the laser-resonator. Alignment to within a few degrees is acceptable.
Returning to
In summary, an intra-cavity frequency-tripled OPS laser is described having a single optical element performing the three functions of polarizing the fundamental radiation, selecting the wavelength of the laser-radiation generated, and rotating the polarization the second-harmonic radiation by about 90°. The present invention is described above with reference to a preferred embodiment. The invention, however, is not limited to the embodiment described and depicted herein. Rather, the invention is limited only by the claims appended hereto.