Patent Application
20220139587
The present application claims priority from Japanese application JP2020-184811, filed on Nov. 5, 2020, the contents of which is hereby incorporated by reference into this application.
The present invention relates to an iodine trapping apparatus and a nuclear power structure.
An iodine trapping trap apparatus such as a filtered containment venting apparatus is installed in a nuclear power structure such as a reactor facility, in order to prevent a radioactive substance discharged from a nuclear power structure main body such as a reactor from leaking into the environment. For example, when the pressure in a containment vessel abnormally rises due to core damage caused by a reactor accident, the containment vessel will be damaged and a large-scale leak will occur, so that steam in the containment vessel is vented in advance, and overpressure damage of the containment vessel is prevented. When high-temperature and high-pressure steam is discharged from the reactor into the containment vessel, the high-temperature and high-pressure steam is passed through the iodine trapping apparatus, and major radioactive substances are trapped before the high-temperature and high-pressure steam is discharged into the atmosphere.
Examples of radioactive substances discharged when a reactor accident occurs include noble gas, aerosol, inorganic iodine, and organic iodine. The iodine trapping apparatus traps these radioactive substances excluding noble gas and prevents these radioactive substances from being discharged to the environment. Organic iodine discharged from the reactor, including methyl iodide, is hardly soluble in water (that is, hydrophobic), and is not sufficiently trapped even if introduced into pool water or scrubbing water in a pressure reduction chamber at the time of venting. In addition, the organic iodine may be newly generated by a reaction of elemental iodine in an exhaust process from the reactor. For these reasons, an iodine trapping apparatus capable of efficiently trapping the organic iodine is required.
PTL 1 describes a filtered containment venting apparatus as an example of the iodine trapping apparatus. PTL 1 describes a filtered containment venting apparatus that is connected to a venting pipe connected to a containment vessel of a reactor and configured to remove radioactive substances, and the filtered containment venting apparatus includes a filtered containment venting vessel having a filter for removing scrubbing water and radioactive substances therein, and a nonvolatile liquid disposed in the filtered containment venting apparatus and capable of trapping organic iodine, in which the nonvolatile liquid is an ionic liquid.
PTL 1: JP-A-2020-42040
There are various temperatures of gases generated in the nuclear power structure main body when an accident occurs. As a result of studies by the present inventors, it is found that there is room for improvement in trapping efficiency in the technique described in PTL 1 for the organic iodine in a gas that is in a relatively low temperature range (for example, 100° C. to 130° C.) among the temperature ranges of the gases generated in the nuclear power structure main body.
An object of the invention is to provide an iodine trapping apparatus and a nuclear power structure capable of trapping organic iodine in a wide temperature range with high efficiency.
An iodine trapping apparatus of the invention includes a first trapping agent capable of trapping organic iodine in a gas in a nuclear power structure main body. The first trapping agent contains a generating and trapping component which generates an iodide ion from organic iodine and traps the generated iodide ion, and a generating component which is different from the generating and trapping component, generates an iodide ion from the organic iodine at least at 100° C. to 130° C., and traps the generated iodide ion in the generating and trapping component. Other solutions will be described later in embodiments for carrying out the invention.
According to the invention, it is possible to provide an iodine trapping apparatus and a nuclear power structure capable of trapping organic iodine in a wide temperature range with high efficiency.
Hereinafter, embodiments of the invention will be described with reference to the drawings. However, the invention is not limited to the following embodiments, and for example, different embodiments may be combined, or the invention may be arbitrarily modified within a range in which the effects of the invention are not significantly impaired. In addition, the same members are designated by the same reference numerals, and redundant description will be omitted. Further, members having the same functions are denoted by the same names. The contents shown in the drawings are merely schematic, and may be changed from an actual configuration to the extent that the effect of the invention is not significantly impaired for convenience of illustration.
Although the filtered containment venting apparatus 30 is an example of an iodine trapping apparatus, the containment vessel 4 is an example of a nuclear power structure main body, and the nuclear power plant 20 is an example of a nuclear power structure, the iodine trapping apparatus, the nuclear power structure main body, and the nuclear power structure are not limited thereto. For example, the nuclear power structure main body may be, for example, a suppression pool of a nuclear power plant, an off-gas device of a nuclear power plant, a storage vessel or transport vessel of a nuclear fuel material, or a storage vessel of an in-core structure. Therefore, these can be used as a nuclear power structure main body, and further as a nuclear power structure including the iodine trapping apparatus.
When applying the iodine trapping apparatus to a nuclear power plant, the form of the reactor is not particularly limited, and the reactor can be applied in various forms such as a boiling water reactor (BWR), an advanced boiling water reactor (ABWR), a pressurized water reactor (PWR).
For example, although situations are different depending on individual plant outputs and accident scenarios, it is evaluated that, among radioactive substances generated in an accident, about 1 kg of organic iodine and about 20 kg of inorganic iodine are generated in a severe accident accompanied by fuel breakage such as breakage of a pressure vessel (not shown) inside the containment vessel 4. Especially, it is evaluated that methyl iodide (CH3I) is mainly generated as the organic iodine and iodine molecule (I2) is mainly generated as the inorganic iodine. Therefore, the filtered containment venting apparatus 30 has a role of being used for trapping aerosol, inorganic iodine, and organic iodine, which are radioactive substances.
The filtered containment venting apparatus 30 includes a filtered containment venting vessel 1 (an example of a first vessel) that accommodates a first trapping agent 2 and a second trapping agent 13 (both of which will be described later), and a dry well venting pipe 7, a wet well venting pipe 8, and an inlet pipe 9 (all of which are examples of a venting pipe) that are connected to the containment vessel 4. The dry well venting pipe 7 and the wet well venting pipe 8 include isolation valves 5 and 6, respectively. One end side of the inlet pipe 9 is connected to the dry well venting pipe 7 and the wet well venting pipe 8, and the other end side of the inlet pipe 9 is open to the inside of the second trapping agent 13. Accordingly, the filtered containment venting vessel 1 communicates with the containment vessel 4 through the dry well venting pipe 7, the wet well venting pipe 8, and the inlet pipe 9.
The filtered containment venting apparatus 30 includes a fiber filter 10 (an example of a radioactive substance removal filter) that removes a radioactive substance in a gas inside the filtered containment venting vessel 1, an outlet pipe 11 connected to the fiber filter 10, and an exhaust cylinder 12. Accordingly, other radioactive substances are further removed from the gas containing organic iodine, inorganic iodine, and aerosol by the first trapping agent 2 and the second trapping agent 13, and the decontaminated gas is discharged to the outside through the exhaust cylinder 12, which will be described in detail later.
The first trapping agent 2 accommodated in the filtered containment venting vessel 1 is capable of trapping the organic iodine in the gas in the containment vessel 4 and discharged from the containment vessel 4. The first trapping agent 2 contains a generating and trapping component and a generating component. The generating and trapping component generates (that is, decomposes) iodide ions (I−) from the organic iodine (RI, R is an optional organic group) and traps (for example, dissolves) the generated iodide ions. The organic iodine on which the generating and trapping component acts is, for example, organic iodine that acts at 130° C. to 160° C.
The generating component is a component different from the generating and trapping component, and generates iodide ions from the organic iodine at least at 100° C. to 130° C., and traps the generated iodide ions in the generating and trapping component. The organic iodine on which the generating component acts may be any organic iodine that acts at least at 100° C. to 130° C., and is preferably organic iodine that acts at 70° C. to 130° C.
The temperature of the gas generated inside the containment vessel 4 due to the breakage of the pressure vessel in a severe accident is, for example, about 100° C. to 160° C. Therefore, the first trapping agent 2 contains the generating and trapping component and the generating component, and in particular, the organic iodine decomposing action of the generating component in a relatively low temperature range, that is, at least 100° C. to 130° C. is enhanced. Accordingly, the organic iodine trapping performance is exerted in a wide temperature range of, for example, about 100° C. to 160° C., preferably about 70° C. to 160° C.
Although the specific type of the generating and trapping component is not particularly limited, the generating and trapping component is preferably a nonvolatile liquid. The nonvolatile liquid has a function of decomposing organic iodine and dissolving iodide ions, and is preferably nonvolatile (substantially nonvolatile) at, for example, 160° C. or lower, preferably 200° C. or lower, and is preferably not thermally decomposed. When an accident of the containment vessel 4 occurs, it is assumed that steam is vented at about 100° C. to 160° C., and therefore, if the liquid acting as a wet filter is nonvolatile, volatilization of the nonvolatile liquid can be prevented even if a high-temperature and high-pressure gas is introduced at the time of venting. The nonvolatile liquid may be a liquid at an operating temperature (for example, 100° C. to 160° C.) and may be a solid at room temperature (for example, 25° C.), but is preferably a liquid also at room temperature.
The nonvolatile liquid is hydrophobic in the illustrated example. By using the hydrophobic nonvolatile liquid, the first trapping agent 2 can be made hydrophobic, the first trapping agent 2 can easily act on the organic iodine, which is also hydrophobic, and the trapping efficiency can be improved.
Specific examples of the nonvolatile liquid include at least one of an ambient temperature molten salt, an ionic liquid, a quaternary salt, a surfactant, a phase transfer catalyst, and a mixture thereof. These nonvolatile liquids have sufficient heat resistance even under the condition of about 200° C., which is a temperature of gas to flow into the filtered containment venting apparatus 30 in an accident. Therefore, by using the nonvolatile liquid which is in a liquid phase even at 200° C. or higher, the nonvolatile liquid can be stably present in a liquid phase even in an accident, and the organic iodine can be sufficiently trapped.
An ionic liquid composed of only a combination of a cation (X+) and an anion (Y−) is preferable. The ionic liquid is also excellent in radiation resistance, and has a property of trapping a substrate such as a radioactive substance at a high concentration in the ionic liquid. In particular, since the organic iodine is a substance that is poorly soluble in water and highly volatile, the trapping efficiency for the organic iodine can be increased by using the ionic liquid.
Examples of the cation constituting the ionic liquid include organic cations containing at least one functional group such as phosphonium, sulfonium, ammonium, pyrrolidinium, piperidinium, and morpholinium. Specific examples thereof include a quaternary ammonium salt, a quaternary phosphonium salt, a tertiary sulfonium salt, a pyrrolidinium salt, a piperidinium salt or a morpholinium salt. Among these, a cation mainly composed of a phosphorus element, a sulfur element or a nitrogen element and mainly bonded to a substituent such as carbon, is preferable. In addition, the cation is preferably composed mainly of a single bond carbon chain in order to maintain high solubility of the iodide ion, but apart of the cation may be crosslinked with a double bond, a triple bond, or an oxygen element.
For example, methyl iodide, which is an example of the organic iodine, is separated without being dissolved in hydrophobic 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide, but is dissolved in and uniformly mixed with hydrophobic trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)amide having the same anion structure but different cation structures. Therefore, it is preferable to select and use a hydrophobic nonvolatile liquid capable of dissolving the organic iodine from the viewpoint of promoting decomposition.
Since a methyl group or the like, which is a substance having a carbon chain number of 1, is easily decomposed and volatilized at a high temperature of 160° C., the carbon chain number is preferably 2 or more. For example, in 1-butyl-3-methylimidazolium iodide, a methyl group of a cation is eliminated at 160° C., and self-decomposition is likely to occur. From such a viewpoint, when the organic cation is a bulky organic cation having a long carbon chain number, the solubility and heat resistance of the organic iodine are increased, and thus the organic iodine can be trapped with high trapping efficiency.
Examples of the anion include an organic anion containing at least one functional group of
a functional group such as H3C−, H2RC−, HR2C−, R3C−, NC−, or RCC−, which is an anion-charged carbon element,
a functional group such as RS− which is an anion-charged sulfur element,
a functional group such as N3−, H2N−, HRN−, or R2N−, which is an anion-charged nitrogen element, and
a functional group such as RO−, RCO2−, RPO3−, RSO3−, RPO4−, R2PO2−, and R3CO−, which is an anion-charged oxygen element.
In addition, examples of the anion include an inorganic anion containing at least a functional group of
a functional group such as HO−, NO2−, FO3−, ClO3−, BrO3−, IO3−, FO4−, ClO4−, BrO4−, or IO4−, and
a functional group such as F−, Cl−, Br−, I−, F3−, Cl3−, Br3−, or I3−, which is an anion-charged halogen element.
Among these, since the anion has a strong action of decomposing the organic iodine, an ion having a high nucleophilic property is preferable, and an anion in which a charged element excluding a hydrogen element is present at an end is particularly preferable.
For example, as compared with H2N−, an anion molecule composed mainly of a charged nitrogen element such as R2N− (R—N−—R) and an element other than a hydrogen element has a lower nucleophilic property and lower decomposition performance for methyl iodide. Since the anion has a high nucleophilic property and hardly causes hydrolysis, and it is difficult to change the pH of scrubbing water when the anion is injected into the filtered containment venting vessel 1, an anion containing at least one functional group selected from H3C−, H2RC−, HR2C−, R3C−, NC−, RCC−, RS−, N3−, H2N−, HRN−, R2N−, RO−, RCO2, RPO3−, RSO3−, RPO4−, R2PO2−, R3CO−, HO−, NO2−, FO3−, ClO3−, BrO3−, IO3−, FO4−, ClO4−, BrO4−, IO4−, F−, Cl−, Br−, I−, F3−, Cl3−, Br3−, and I3− is preferable.
In order to achieve high trapping performance for the organic iodine, it is preferable that both dissolution of the organic iodine by cations in an ionic liquid suitable as a nonvolatile liquid and decomposition of the organic iodine caused by a nucleophilic attack of an anion on the organic iodine occur. Examples of the nonvolatile liquid that causes such a phenomenon include hydrophobic trihexyl(tetradecyl)phosphonium chloride.
When an ionic liquid is used as the nonvolatile liquid, it is considered that the ionic liquid (X+—Y−) and the organic iodine (RI, R is an optional organic group) have an action represented by the following Formula (1).
X+-Y−+RI→X+-Y−+I−+R+ Formula (1)
In the organic iodine (RI), the organic group (R) is positively charged and iodine (I) is negatively charged. Therefore, the ionic liquid can decompose the organic iodine by attacking the organic group in a high temperature range of, for example, 130° C. to 160° C. to generate iodide ions. The iodide ion is more stable in a liquid phase than the organic iodine, and can stably retain the iodide ions by interacting with the cation constituting the nonvolatile liquid. As a result, the organic iodine can be retained in the liquid phase, and leakage to the environment can be prevented.
Even in the case of a nonvolatile liquid other than the ionic liquid, the organic iodine is attacked in the nonvolatile liquid as in the case of the ionic liquid, and iodide ions are generated. Accordingly, the organic iodine can be retained in the nonvolatile liquid.
The specific type of the generating component contained in the first trapping agent 2 is not particularly limited, but the generating component is preferably a first reducing agent. The “first reducing agent” is a name given to be distinguished from a “second reducing agent” described later, and is synonymous with a simple “reducing agent” from the viewpoint of chemical properties. Hereinafter, the invention will be described by exemplifying the nonvolatile liquid as the generating and trapping component and exemplifying the first reducing agent as the generating component. However, the generating and trapping component and the generating component are not limited to the nonvolatile liquid and the first reducing agent, respectively, and the following description is similarly applied to materials other than the nonvolatile liquid and the first reducing agent.
The first reducing agent decomposes the organic iodine in the nonvolatile liquid by the same action as the action represented by the above Formula (1). However, the decomposition of the organic iodine by the first reducing agent proceeds in a low temperature range of 100° C. to 130° C., preferably 70° C. to 130° C., which is lower than the temperature (for example, 130° C. to 160° C.) at the time of decomposition by the nonvolatile liquid. The first reducing agent may be dissolved or dispersed, but is preferably dissolved in the nonvolatile liquid from the viewpoint of improving the trapping efficiency. The iodide ions generated by the decomposition are trapped in the nonvolatile liquid.
The first reducing agent (an example of the generating component) is preferably a first reducing agent having an oxidation-reduction potential of lower than 0.54 V, which is a standard electrode potential at which iodine is reduced. By using such a first reducing agent, iodide ions can be liberated by reduction of iodine contained in the organic iodine, and the iodide ions stable in the liquid phase can be easily retained in the first trapping agent 2 in a liquid state.
The content of the first reducing agent in the first trapping agent 2 is preferably 0.07 mass % (700 ppm) or more with respect to the nonvolatile liquid. Accordingly, organic iodine trapping can be promoted even at a low temperature of about 70° C., and a decontamination factor (DF, the vertical axis of a graph shown in
Examples of the first reducing agent include at least one of H2O2, (COOH)2, NH2OH, BH4Na, N2H5OH, C6H8O6 (ascorbic acid), (NH4)2S, and H2NC2H4SH. Among these, it is desirable that the first reducing agent is determined according to stability even at a high temperature, ease of handling, availability, or the like.
In
Meanwhile, as shown by the plot of diamonds, if the first reducing agent is not contained, the decontamination factor is 50 or less and the organic iodine trapping is insufficient in the low temperature range of 70° C. to 130° C. This result is considered to be caused by the non-use of the first reducing agent that decomposes the organic iodine and retains the organic iodine in the nonvolatile liquid in a low temperature range of, for example, 70° C. to 130° C., as described above with reference to
In addition, although not illustrated, it is also found from a separate experiment that the organic iodine is hardly trapped in an aqueous solution containing the first reducing agent (corresponding to the second trapping agent 13 described later). It is considered that this is because the first reducing agent in water does not sufficiently act on the hydrophobic organic iodine since the organic iodine is hydrophobic but the aqueous solution is hydrophilic. Therefore, it is clarified by the experiment that the organic iodine trapping performance can be improved by coexisting the nonvolatile liquid and the first reducing agent.
Therefore, since the nonvolatile liquid having a relatively small volume of, for example, 0.2 m3 is sufficient, it is possible to efficiently trap the organic iodine in a wide temperature range without significantly changing the design described in the above PTL 1. Accordingly, the treatment cost can be reduced. In addition, since it is not necessary to introduce a large-scale apparatus, a static system of the filtered containment venting apparatus 30 can be maintained even when the nonvolatile liquid is applied to the existing filtered containment venting apparatus 30.
In addition, since the hydrophobic nonvolatile liquid and the first reducing agent are made coexist and the nonvolatile liquid and the first reducing agent are present in the same form in the first trapping agent 2, the first reducing agent can promote the organic iodine trapping of the nonvolatile liquid, and the trapping performance can be efficiently improved. In addition, since the first reducing agent is contained in the hydrophobic nonvolatile liquid, the first reducing agent of the first trapping agent 2 and the second trapping agent 13 can be brought into contact with each other only at a liquid-liquid interface in a static state in which no accident occurs, and the contact area can be reduced. Accordingly, it is possible to prevent hydrolysis of the first reducing agent of the first trapping agent 2 and deterioration of the first reducing agent due to a pH variation of the second trapping agent 13, and to stably retain the first reducing agent in the first trapping agent 2.
Returning to
The filtered containment venting apparatus 30 includes the second trapping agent 13, which is an aqueous solution containing the second reducing agent, inside the filtered containment venting vessel 1. The second trapping agent 13 is capable of trapping at least one component of the inorganic iodine and aerosol discharged from the containment vessel 4 and further contained in the gas in the containment vessel 4. In the illustrated example, the second trapping agent 13 is scrubber water for cleaning the gas. The above first trapping agent 2 can trap the organic iodine, and the second trapping agent 13 can trap at least one component of the aerosol and the inorganic iodine by, for example, dissolution. In the illustrated example, both the first trapping agent 2 and the second trapping agent 13 are liquids, and the first trapping agent 2 is disposed on an upper layer of the second trapping agent 13. The second reducing agent may be the same type as or different from the first reducing agent.
The pH of a liquid phase containing the second trapping agent 13 is preferably alkaline. The pH of the liquid phase containing the second trapping agent 13 referred to here is the pH of the second trapping agent 13 when the nonvolatile liquid is hydrophobic and the hydrophobic nonvolatile liquid and the second trapping agent 13 which is an aqueous solution are separated into two phases as described above. Since the pH of the liquid phase containing the second trapping agent 13 is alkaline, the re-volatilization of the inorganic iodine can be particularly prevented. Specifically, the pH is, for example, 10 or more and 14 or less.
In addition, as described above, by opening the other end of the inlet pipe 9 to the inside of the second trapping agent 13, at least one component of the aerosol and the inorganic iodine in the gas supplied to the second trapping agent 13 can be trapped by the second trapping agent 13 through the inlet pipe 9. On the other hand, after the component is trapped, the gas becomes bubbles, rises inside the second trapping agent 13, and reaches the first trapping agent 2 in the upper layer. Accordingly, the organic iodine in the bubbles can be trapped by the first trapping agent 2.
The operating principle of the filtered containment venting apparatus 30 will be described with reference to
The first trapping agent 2 or the like (to be described later) contaminated with the radioactive substance can be extracted through, for example, a sampling port (not shown) provided in the filtered containment venting vessel 1, and can be treated and reproduced by, for example, the method described in JP-T-2003-507185.
According to the above filtered containment venting apparatus 30, in a gas having a wide temperature range generated when an accident occurs, for example, the organic iodine can be trapped with high efficiency (for example, 98% or more) in a relatively low temperature range, that is, in a wide temperature range of, for example, 100° C. to 160° C., and preferably 70° C. to 160° C.
First, an alkaline aqueous solution and a nonvolatile liquid are mixed (step S1), and the pH of the mixed liquid is measured (step S2). The pH is adjusted using an acid or alkali aqueous solution such that the pH is, for example, 6 or more, and preferably 10 or more (step S3). Then, the nonvolatile liquid is fractionated (step S4), water is evaporated from the fractioned nonvolatile liquid by, for example, heating (step S5) to obtain a nonvolatile liquid whose pH has been adjusted. Next, the nonvolatile liquid whose pH has been adjusted and the aqueous solution containing the first reducing agent (the concentration of the first reducing agent is known) are mixed (step S6), the nonvolatile liquid is fractionated (step S7), and the moisture is evaporated (step S8) in the same manner as in steps S4 and S5, to obtain the first trapping agent 2.
As the concentration of the first reducing agent in the first trapping agent 2, if possible, the concentration of the first reducing agent in the first trapping agent 2 may be directly measured, but when the concentration of the first reducing agent (the concentration is known) in the aqueous solution used in step S6 is compared with the amount of the first reducing agent remaining in step S8, the reduced amount can be set as the concentration of the first reducing agent in the nonvolatile liquid.
It is considered that the first reducing agent is contained in the hydrophilic nonvolatile liquid or interacts with the nonvolatile liquid in water. Therefore, it is considered that, even in a case of hydrophobic organic iodine, the first reducing agent containing the hydrophilic nonvolatile liquid and the first reducing agent acts in water, and iodide ions are generated and trapped in the nonvolatile liquid.
Similar to the first embodiment, the nonvolatile liquid is preferably an ionic liquid. Examples of the cation constituting the ionic liquid include organic cations containing at least one functional group such as imidazolium, pyridinium, ammonium, phosphonium, sulfonium, pyrrolidinium, piperidinium, and morpholinium. Specific examples thereof include an imidazolium salt, a pyridinium salt, a quaternary ammonium salt, a quaternary phosphonium salt, a tertiary sulfonium salt, a pyrrolidinium salt, a piperidinium salt or a morpholinium salt.
For example, methyl iodide, which is organic iodine, is slightly dissolved in hydrophilic 1-butyl-3-methylimidazolium iodide, but is dissolved in and uniformly mixed with hydrophilic 1-butyl-3-dodecylimidazolium bromide having the same halogen anion structure and different cation structures. Therefore, it is preferable to select and use a hydrophilic nonvolatile liquid capable of dissolving the organic iodine.
Examples of the anion include
organic anions such as RO−, RCO2−, RPO3−, RSO3−, RPO4−, R2PO2−, or R3CO−, and inorganic anions such as HO−, NO2−, FO3−, ClO3−, BrO3−, IO3−, FO4−, ClO4−, BrO4−, or IO4−, which are anion-charged oxygen elements, and
inorganic anions such as F−, Cl−, Br−, I−, F3−, Cl3−, Br3−, or I3−, which is an anion-charged halogen element.
Among these, since the anion has a strong action of decomposing the organic iodine, an ion having a high nucleophilic property is preferable, and an anion in which a charged element excluding a hydrogen element is present at the end is particularly preferable. Further, since the anion has a high nucleophilic property and hardly causes hydrolysis, and it is difficult to change the pH of the second trapping agent 13 when the anion is injected into the filtered containment venting vessel 1, an anion containing at least one functional group selected from RO−, RCO2−, RPO3−, RSO3−, RPO4−, R2PO2−, R3CO−, HO−, NO2−, FO3−, ClO3−, BrO3−, IO3−, FO4−, ClO4−, BrO4−, IO4−, F−, Cl−, Br−, I−, F3−, Cl3−, Br3− and I3− is preferable.
Examples of the hydrophilic nonvolatile liquid include 1-butyl-3-dodecylimidazolium bromide. In the liquid in which the first trapping agent 2 and the second trapping agent 13 are compatible with each other, the concentration of the nonvolatile liquid is preferably 10 mass % or more (100,000 ppm or more). In addition, the content of the first reducing agent (an example of the generating component) is preferably 0.07 mass % or more (700 ppm or more) with respect to a total of the first reducing agent and the second reducing agent. Accordingly, the above decontamination factor can be set to 50 or more. When the first reducing agent and the second reducing agent are of the same type, the reducing agents cannot be distinguished in the liquid, and therefore, in this case, the concentration of the reducing agent is preferably 0.07 mass % or more, for example.
Similar to the above first embodiment, it is preferable that the pH of the liquid phase containing the second trapping agent 13 is alkaline. The pH of the liquid phase containing the second trapping agent 13 referred to here is the pH of the mixed liquid of the nonvolatile liquid and the second trapping agent 13 when the nonvolatile liquid is hydrophilic and the hydrophilic nonvolatile liquid and the second trapping agent 13 which is an aqueous solution are mixed as described above. Since the pH of the liquid phase containing the second trapping agent 13, that is, the mixed liquid is alkaline, the re-volatilization of the inorganic iodine can be particularly prevented.
The operating principle of the filtered containment venting apparatus 31 will be described with reference to
As described above, although the organic iodine is not sufficiently trapped only by the second trapping agent 13 which is an aqueous solution containing the reducing agent, the organic iodine can be trapped with high efficiency by using the first trapping agent 2 in which the hydrophilic nonvolatile liquid and the reducing agent are used in combination (water may also be used in combination).
In the filtered containment venting apparatus 32, at least one component of the aerosol and the inorganic iodine in the gas supplied to the second trapping agent 13 is trapped by the second trapping agent 13 through the inlet pipe 9. On the other hand, bubbles containing the organic iodine which is not trapped rise inside the second trapping agent 13, and is supplied to the accommodation vessel 14 through the fiber filter 10 and the outlet pipe 11. Since the outlet pipe 11 is open to the inside of the first trapping agent 2, the organic iodine in the bubbles is trapped by the first trapping agent 2.
According to the filtered containment venting apparatus 32, since the first trapping agent 2 and the second trapping agent 13 are accommodated in different vessels, deterioration (hydrolysis or the like) caused by the interaction between the first trapping agent 2 and the second trapping agent 13 can be prevented over a long period of time until the use of the filtered containment venting apparatus 32 in an accident. In addition, since the accommodation vessel 14 accommodating the first trapping agent 2 is disposed outside the filtered containment venting vessel 1, it is possible to particularly prevent such an interaction.
When an accident occurs, the valve 17 is opened, so that the first trapping agent 2 is supplied to the filtered containment venting vessel 1. At this time, by supplying an inert gas to the storage vessel 15 by using an inert gas supply mechanism (not shown), discharge of the first trapping agent 2 from the storage vessel 15, that is, supply of the first trapping agent 2 to the filtered containment venting vessel 1 may be promoted. By the supply of the first trapping agent 2, the first trapping agent 2 and the second trapping agent 13 can coexist in the filtered containment venting vessel 1, and the organic iodine or the like is trapped by the operation described in each of the above embodiments.
As described in the third embodiment (
According to the filtered containment venting apparatus 34 (
| Number | Date | Country | Kind |
|---|---|---|---|
| 2020-184811 | Nov 2020 | JP | national |
