Iron golf club head

Information

  • Patent Grant
  • 6769998
  • Patent Number
    6,769,998
  • Date Filed
    Friday, September 20, 2002
    22 years ago
  • Date Issued
    Tuesday, August 3, 2004
    20 years ago
Abstract
The iron golf club head (20) of the present invention is preferably composed of three main components: a periphery member 22, a central member 24 and a face plate 26. The periphery member (22) is preferably composed of a high density material such as a iron-nickel tungsten alloy. The central member (24) is preferably composed of a bulk molding compound. The face plate (26) is preferably composed of a titanium alloy material. The iron golf club head (20) preferably has high moments of inertia Izz and Ixx.
Description




CROSS REFERENCE TO RELATED APPLICATIONS




Not Applicable




FEDERAL RESEARCH STATEMENT




[Not Applicable]




BACKGROUND OF INVENTION




1. Field of the Invention




The present invention relates to an iron golf club. More specifically, the present invention relates to a multiple material iron golf club.




2. Description of the Related Art




Irons are typically composed of a stainless steel or titanium material, and are typically cast or forged. Most golfers desire that their irons have a large sweet spot for greater forgiveness, a low center of gravity to get the ball in the air, a solid sound, reduced vibrations during impact, and a trim top line for appearance. Unfortunately, these desires are often in conflict with each other as it pertains to an iron.




The use of iron club heads composed of different materials has allowed some prior art irons to achieve some of these desires.




One example is U.S. Pat. No. 5,228,694 to Okumoto et al., which discloses an iron club head composed of a stainless steel sole and hosel, a core composed of a bulk molding compound or the like, a weight composed of a tungsten and polyamide resin, and an outer-shell composed of a fiber-reinforced resin.




Another example is set forth in U.S. Pat. Nos. 4,792,139, 4,798,383, 4,792,139 and 4,884,812, all to Nagasaki, et al., which disclose an Iron club head composed of stainless steel with a fiber reinforced plastic back plate to allow for weight adjustment and ideal inertia moment adjustment.




Another example is U.S. Pat. No. 4,848,747 which discloses a metal iron club head with a carbon fiber reinforced plastic back plate to increase the sweet spot. A ring is used to fix the position of the back plate.




Another example is set forth in U.S. Pat. Nos. 4,928,972 and 4,964,640 which disclose an iron club head composed of stainless steel with a fiber reinforcement in a rear recess to provide a dampening means for shock and vibrations, a means for increasing the inertial moment, a means for adjusting the center of gravity and a means for reinforcing the back plate.




Another example is U.S. Pat. No. 5,190,290 to Take, which discloses an iron club head with a metal body, a filling member composed of a light weight material such as a plastic, and a fiber-reinforced resin molded on the metal body and the filling member.




Another example is U.S. Pat. No. 5,411,264 to Oku, which discloses a metal body with a backwardly extended flange and an elastic fiber face plate in order to increase the moment of inertia and minimize head vibrations.




Another example is U.S. Pat. No. 5,472,201 to Aizawa et al., which discloses an iron club head with a body composed of stainless steel, a face member composed of a fiber reinforced resin and a protective layer composed of a metal, in order to provide a deep center of gravity and reduce shocks.




Another example is U.S. Pat. No. 5,326,106 to Meyer, which discloses an iron golf club head with a metal blade portion and hosel composed of a lightweight material such as a fiber reinforced resin.




Another example is U.S. Pat. No. 4,664,383 to Aizawa et al., which discloses an iron golf club head with a metal core covered with multiple layers of a reinforced synthetic resin in order to provide greater ball hitting distance.




Another example is U.S. Pat. No. 4,667,963 to Yoneyama, which discloses an iron golf club head with a metal sole and a filling member composed of a fiber reinforced resins material in order to provide greater hitting distance.




The prior art fails to disclose an iron golf club head that is composed of multiple materials, has a low center of gravity, reduced vibrations, and a greater moment of inertia.




SUMMARY OF INVENTION




The present invention provides an iron golf club head which has a low center of gravity, a high moment of inertia, reduced vibrations and a solid feel and appearance. The present invention is able to provide these features through use of a multiple material iron club head.




One aspect of the present invention is an iron golf club head composed of a periphery member, a central member and a face plate. The periphery member is composed of a metal material. The periphery member has a sole wall, a toe wall extended upward from the sole wall at a first end of the sole wall, a hosel extending upward from the sole wall at a second end of the sole wall, and a heel wall extending upward from the sole wall. The central member is composed of a non-metal material. The central member has a body portion with a forward surface, a sole surface, a top surface, a toe surface, a heel surface and a flange extending from the top surface at an intersection of the top surface and the forward surface. The central member has a rear cavity defined by the body portion. The face plate is composed of a metal material and is disposed over the forward surface of the central member. A top line of the face plate is in contact with the flange of the central member.




Having briefly described the present invention, the above and further objects, features and advantages thereof will be recognized by those skilled in the pertinent art from the following detailed description of the invention when taken in conjunction with the accompanying drawings.











BRIEF DESCRIPTION OF DRAWINGS





FIG. 1

is an exploded view of an iron club head of the present invention.





FIG. 2

is a side exploded view of an iron club head of the present invention.





FIG. 3

is a front plan view of the an iron club head of the present invention.





FIG. 4

is a rear plan view of the iron club head of FIG.


1


.





FIG. 5

is a toe side view of the iron club head of FIG.


1


.





FIG. 6

is a heel side view of the iron club head of FIG.


1


.





FIG. 7

is a top plan view of the iron club head of FIG.


1


.





FIG. 8

is a bottom plan view of the iron club head of FIG.


1


.





FIG. 9

is a toe side view of a golf club head of the present invention illustrating the moments of inertia through the center of gravity.





FIG. 10

is a top plan view of a golf club head of the present invention illustrating the moments of inertia through the center of gravity.





FIG. 11

is a front plan view of a golf club head of the present invention illustrating the moments of inertia through the center of gravity.





FIG. 12

is a front perspective view of a golf club head of the present invention illustrating the moments of inertia through the center of gravity.











DETAILED DESCRIPTION




As shown in

FIGS. 1-8

, an iron golf club head of the present invention is generally designated


20


. The club bead


20


is preferably composed of three main components: a periphery member


22


, a central member


24


and a face plate


26


. The club head


20


can range from a 1-iron to a lob-wedge, with the loft angle preferably ranging from fifteen degrees to sixty degrees. The three main components are assembled into the club head


20


using a process such as disclosed in co-pending U.S. patent application Ser. No. 10/065,150, filed on an even date herewith, entitled Method For Manufacturing Iron Golf Club Head, which is hereby incorporated in its entirety by reference.




The periphery member


22


is preferably composed of a material having a density greater than 7.86 grams per centimeter cubed (g/cm


3


). A preferred material is an iron-nickel-tungsten alloy having a density preferably ranging from 8.0 g/cm


3


to 12.0 g/cm


3


, more preferably ranging from 10.0 g/cm


3


to 11.0 g/cm


3


, and most preferably 10.5 g/cm


3


. An alternative material is a stainless steel material. Those skilled in the pertinent art will recognize that other materials may be used for the periphery member


22


without departing from the scope and spirit of the present invention.




The periphery member


22


has sole wall


28


, a toe wall


30


extending upward from a toe end of the sole wall


28


, a heel wall


32


extending upward from the sole wall


28


near a heel end of the sole wall


28


, and a hosel


34


extending outward from the sole wall


28


at the heel end of the sole wall


28


. The hosel


34


is preferably offset. The hosel


34


has a bore


36


for receiving a shaft, and the upper end of the hosel


34


preferably lies below an upper end of the toe wall


30


when the club head


20


is in the address position for striking a golf ball, not shown. The bore


36


preferably extends through the entire hosel


34


providing a short straight hollow hosel such as disclosed in U.S. Pat. No. 4,995,609, which pertinent parts are hereby incorporated by reference.




The sole wall


28


preferably has a cambered exterior surface, which contacts the ground during a golf swing. As shown in

FIG. 8

, the sole wall


28


has a width, Ws, that preferably ranges from 1.00 inch to 1.75 inch, and is most preferably 1.25 inch. The sole wall


28


also has a length, Ls, from a toe end to the beginning of the bore


36


, which preferably ranges from 2.5 inches to 3.5 inches, and is most preferably 3.0 inches.




As shown in

FIG. 5

, the toe wall


30


preferably has a length, Lt, which preferably ranges from 1.5 inches to 2.5 inches, and is most preferably 2.0 inches. The toe wall


30


preferably has a width that tapers from a lower end to an upper end of the toe wall


30


.




As shown in

FIG. 6

, the heel wall


32


preferably has a length, Lh, which preferably ranges from 0.5 inch to 1.5 inches, and is most preferably 1.0 inch. The heel wall


32


preferably has a width that tapers from a lower end to an upper end of the heel wall


32


.




In general, the periphery member


22


provides the club head


20


with a greater moment of inertia due to its relatively large mass at the periphery of the club head


20


. Further, mass attributable to the sole wall


28


lowers the center of gravity of the club head


20


to promote a higher trajectory during ball striking. The periphery member


22


is preferably 15% to 50% of the volume of the club head


20


and preferably 50% to 80% of the mass of the club head


20


.




The central member


24


is composed of a non-metal material. Preferred materials include bulk molding compounds, sheet molding compounds, thermosetting materials and thermoplastic materials. A preferred bulk molding compound is a resinous material with reinforcement fibers. Such resins include polyesters, vinyl esters and epoxy. Such fibers include carbon fibers, fiberglass, aramid or combinations. A preferred sheet molding compound is similar to the bulk molding compounds, however, in a sheet form. A preferred thermoplastic material includes injection moldable materials integrated with fibers such as disclosed above. These thermoplastic materials include polyesters, polyethylenes, polyamides, polypropylenes, polyurethanes, and the like.




The central member


24


is primarily a support for the face plate


26


, and thus the central member should be able to withstand impact forces without failure. The central member


24


also reduces vibrations of the club head


20


during ball striking. The central member


24


is preferably 25% to 75% of the volume of the club head


20


and preferably 10% to 30% of the mass of the club head


20


.




The central member


24


preferably has a body portion


38


, a recess


40


, a forward surface


42


, a rear surface


43


, a sole surface


44


, a top surface


46


, a toe surface


48


, a heel surface


50


and a flange


52


. The forward surface


42


is preferably at an angle approximate that of the club head


20


. Thus, if the club head


20


is a 5-iron, then the forward surface preferably has an angle of approximately 27 degrees. The body portion


38


preferably tapers upward from the sole surface


44


.




The central member


24


is disposed on an interior surface of the sole wall


28


of the periphery member


22


. The toe surface


48


of the central member


24


preferably engages the interior surface of the toe wall


30


of the periphery member


22


. The heel surface


50


of the central member


24


preferably engages the heel wall


32


of the periphery member


22


. The top surface


46


preferably creates the top line of the club head


20


. The flange


52


extends from the top surface


46


outward over the forward surface


42


thereby creating a top cover for securing the face plate


26


. The face plate


26


is also secured within a ledge


60


of the periphery member


22


.




The face plate


26


is preferably composed of a light-weight material. Such materials include titanium materials, stainless steel, amorphous metals and the like. Such titanium materials include pure titanium and titanium alloys such as 6-4 titanium alloy, 6-22-22 titanium alloy, 4-2 titanium alloy, SP-700 titanium alloy (available from Nippon Steel of Tokyo, Japan), DAT 55G titanium alloy available from Diado Steel of Tokyo, Japan, Ti 10-2-3 Beta-C titanium alloy available from RTI International Metals of Ohio, and the like. The face plate


26


is preferably manufactured through casting, forging, forming, machining, powdered metal forming, metal-injection-molding, electro-chemical milling, and the like.




The face plate


26


has an interior surface


56


which preferably engages the forward surface


42


of the central member


24


, and an exterior surface


54


which preferably has scorelines (not shown) thereon. The face plate preferably has a thickness that ranges from 0.04 inch to 0.250 inch, more preferably from 0.06 inch to 0.130 inch and most preferably 0.075 inch.




The club head


20


preferably has a total volume that ranges from 40.0 cm


3


to 60.0 cm


3


, more preferably from 45.0 cm


3


to 55.0 cm


3


, and most preferably 50.8 cm


3


. The club head


20


preferably has a mass that ranges from 240 grams to 270 grams, more preferably from 245 grams to 260 grams, and most preferably 253 grams.




The periphery member


22


preferably has a total volume that ranges from 10.0 cm


3


to 32.0 cm


3


, more preferably from 15.0 cm


3


to 20.0 cm


3


, and most preferably 18.8 cm


3


. The periphery member


22


preferably has a mass that ranges from 100 grams to 240 grams, more preferably from 150 grams to 200 grams, and most preferably 185 grams.




The central member


24


preferably has a total volume that ranges from 7.0 cm


3


to 35.0 cm


3


, more preferably from 15.0 cm


3


to 30.0 cm


3


, and most preferably 28.0 cm


3


. The central member


24


preferably has a mass that ranges from 9 grams to 70 grams, more preferably from 25 grams to 60 grams, and most preferably 45 grams.




The face plate


26


preferably has a total volume that ranges from 4.0 cm


3


to 8.0 cm


3


, more preferably from 4.5 cm


3


to 6.0 cm


3


, and most preferably 5.3 cm


3


. The face plate


26


preferably has a mass that ranges from 15 grams to 50 grams, more preferably from 20 grams to 30 grams, and most preferably 24 grams.





FIGS. 9-12

illustrate the axes of inertia through the center of gravity of the golf club head. The axes of inertia are designated X, Y and Z. The X axis extends from rear of the golf club head


20


through the center of gravity, CG, and to the face plate


26


. The Y axis extends from the heel end


75


of the golf club head


20


through the center of gravity, CG, and to the toe end


70


of the golf club head


20


. The Z axis extends from the sole wall through the center of gravity, CG, and to the top line


80


.




As defined in


Golf Club Design, Fitting, Alteration & Repair


, 4


th


Edition, by Ralph Maltby, the center of gravity, or center of mass, of the golf club head is a point inside of the club head determined by the vertical intersection of two or more points where the club head balances when suspended. A more thorough explanation of this definition of the center of gravity is provided in


Golf Club Design, Fitting, Alteration & Repair.






The center of gravity and the moment of inertia of a golf club head


20


are preferably measured using a test frame (X


T


, Y


T


, Z


T


), and then transformed to a head frame (X


H


, Y


H


, Z


H


). The center of gravity of a golf club head


20


may be obtained using a center of gravity table having two weight scales thereon, as disclosed in co-pending U.S. patent application Ser. No. 09/796,951, filed on Feb. 27, 2001, entitled High Moment Of Inertia Composite Golf Club, and hereby incorporated by reference in its entirety. If a shaft is present, it is removed and replaced with a hosel cube that has a multitude of faces normal to the axes of the golf club head. Given the weight of the golf club head, the scales allow one to determine the weight distribution of the golf club head when the golf club head is placed on both scales simultaneously and weighed along a particular direction, the X, Y or Z direction.




In general, the moment of inertia, Izz, about the Z axis for the golf club head


20


preferably ranges from 2200 g-cm


2


to 3000 g-cm


2


, more preferably from 2400 g-


2


to 2700 g-cm


2


, and most preferably from 2472 g-cm


2


to 2617 g-cm


2


. The moment of inertia, Iyy, about the Y axis for the golf club head


20


preferably ranges from 400 g-cm


2


to 700 g-cm


2


, more preferably from 500 g-cm


2


to 600 g-cm


2


, and most preferably from 530 g-cm


2


to 560 g-cm


2


. The moment of inertia, Ixx, about the X axis for the golf club head


20


preferably ranges from 2450 g-cm


2


to 3200 g-cm


2


, more preferably from 2500 g-cm


2


to 2900 g-cm


2


, and most preferably from 2650 g-cm


2


to 2870 g-cm


2


.




For comparison, the new BIG BERTHA® 5-iron from Callaway Golf Company has a moment of inertia, Izz, of 2158 g-cm


2


, a moment of inertia, Iyy, of 585 g-cm


2


, and a moment of inertia, Ixx, of 2407 g-cm


2


.




From the foregoing it is believed that those skilled in the pertinent art will recognize the meritorious advancement of this invention and will readily understand that while the present invention has been described in association with a preferred embodiment thereof, and other embodiments illustrated in the accompanying drawings, numerous changes, modifications and substitutions of equivalents may be made therein without departing from the spirit and scope of this invention which is intended to be unlimited by the foregoing except as may appear in the following appended claims. Therefore, the embodiments of the invention in which an exclusive property or privilege is claimed are defined in the following appended claims.



Claims
  • 1. An iron golf club head comprising:a periphery member composed of a metal material, the periphery member having a sole wall, a toe wall extending upward from the sole wall at a first end of the sole wall, a hosel extending upward from the sole wall at a second end of the sole wall, and a heel wall extending upward from the sole wall; a central member composed of a non-metal material, the central member having a body portion with a forward surface, a sole surface, a top surface, a toe surface, a heel surface and a flange extending from the top surface at an intersection of the top surface and the forward surface, the central member having a rear cavity defined by the body portion; and a face plate composed of a metal material, the face plate disposed over the forward surface of the central member, a top line of the face plate in contact with the flange of the central member.
  • 2. The iron golf club head according to claim 1 wherein the face plate is composed of a titanium alloy material and has a thickness ranging from 0.050 inch to 0.250 inch.
  • 3. The iron golf club head according to claim 1 wherein the central member is composed of a bulk molding compound.
  • 4. The iron golf club head according to claim 1 wherein the periphery member is composed of an iron-nickel-tungsten alloy having a density of 8 g/cm3 to 11 g/cm3.
  • 5. The iron golf club head according to claim 1 wherein the club head has a moment of inertia Ixx through the center of gravity of at least 2600 g-cm2.
  • 6. The iron golf club head according to claim 1 wherein an upper end of the hosel is located below the top line of the face plate when the golf club head is in the address position.
  • 7. The iron golf club head according to claim 1 wherein the central member has a volume percentage of the golf club head ranging from 25% to 75%, and a mass percentage of the golf club head ranging from 10% to 30%.
  • 8. The iron golf club head according to claim 1 wherein the periphery member has a volume percentage of the golf club head ranging from 15% to 50%, and a mass percentage of the golf club head ranging from 50% to 80%.
  • 9. The iron golf club head according to claim 1 wherein the club head has a moment of inertia Izz through the center of gravity of at least 2600 g-cm2.
  • 10. An iron golf club head comprising:a periphery member composed of an iron-nickel-tungsten alloy, the periphery member having a sole wall, a toe wall extending upward from the sole wall at a first end of the sole wall, a hosel extending upward from the sole wall at a second end of the sole wall, and a heel wall extending upward from the sole wall, the periphery member having a volume percentage of the golf club head ranging from 15% to 50%, and a mass percentage of the golf club head ranging from 50% to 80%; a central member composed of an epoxy resin with non-continuous carbon fibers, the central member having a body portion with a forward surface, a sole surface, a top surface, a toe surface, a heel surface and a flange extending from the top surface at an intersection of the top surface and the forward surface, the central member having a rear cavity defined by the body portion, the central member having a volume percentage of the golf club head ranging from 25% to 75%, and a mass percentage of the golf club head ranging from 10% to 30%; and a face plate composed of a titanium alloy, the face plate disposed over the forward surface of the central member, a top line of the face plate in contact with the flange of the central member.
  • 11. An iron golf club head comprising:a periphery member composed of a metal material, the periphery member having a sole wall, a toe wall extending upward from the sole wall at a first end of the sole wall, a hosel extending upward from the sole wall at a second end of the sole wall, and a heel wall extending upward from the sole wall; a central member composed of a non-metal material, the central member having a body portion with a forward surface, a sole surface, a top surface, a toe surface, a heel surface and a flange extending from the top surface at an intersection of the top surface and the forward surface, the central member having a rear cavity defined by the body portion; and a face plate composed of a metal material, the face plate disposed over the forward surface of the central member, an upper perimeter of the face plate in contact with the flange of the central member; wherein the club head has a moment of inertia Izz through the center of gravity of at least 2600 g-cm2 and a moment of inertia Ixx through the center of gravity of at least 2600 g-cm2.
US Referenced Citations (105)
Number Name Date Kind
3961796 Thompson Jun 1976 A
4521022 Schmidt Jun 1985 A
4534558 Yoneyama Aug 1985 A
4630827 Yoneyama Dec 1986 A
4635941 Yoneyama Jan 1987 A
4645207 Teramoto et al. Feb 1987 A
4653756 Sato Mar 1987 A
4664383 Aizawa May 1987 A
4667963 Yoneyama May 1987 A
4671513 Swanson Jun 1987 A
4687205 Tominaga et al. Aug 1987 A
4690408 Kobayashi Sep 1987 A
4697814 Yamada Oct 1987 A
4699383 Kobayashi Oct 1987 A
4708347 Kobayashi Nov 1987 A
4728105 Kobayashi Mar 1988 A
4754971 Kobayashi Jul 1988 A
4754975 Aizawa Jul 1988 A
4792140 Yamaguchi et al. Dec 1988 A
4798383 Nagasaki et al. Jan 1989 A
4798384 Kobayashi Jan 1989 A
4809978 Yamaguchi et al. Mar 1989 A
4824110 Kobayashi Apr 1989 A
4836550 Kobayashi Jun 1989 A
4852880 Kobayashi Aug 1989 A
4874171 Ezaki et al. Oct 1989 A
4884812 Nagasaki et al. Dec 1989 A
4964640 Nakanishi et al. Oct 1990 A
4986541 Teramoto et al. Jan 1991 A
4995609 Parente et al. Feb 1991 A
5004242 Iwanaga et al. Apr 1991 A
5009425 Okumoto et al. Apr 1991 A
5016882 Fujimura et al. May 1991 A
5016883 Kobayashi May 1991 A
5078397 Aizawa Jan 1992 A
5090702 Viste Feb 1992 A
5121918 Teramoto et al. Jun 1992 A
5176384 Sata et al. Jan 1993 A
5184823 Desboilles et al. Feb 1993 A
5190290 Take Mar 1993 A
5228694 Okumoto et al. Jul 1993 A
5282625 Schmidt et al. Feb 1994 A
5344150 Schmidt et al. Sep 1994 A
5346213 Yamada Sep 1994 A
5348302 Sasamoto et al. Sep 1994 A
5398929 Kitaichi Mar 1995 A
5409229 Schmidt et al. Apr 1995 A
5411264 Oku May 1995 A
5413336 Iwanaga May 1995 A
5447311 Viollaz et al. Sep 1995 A
5465968 Aizawa et al. Nov 1995 A
5472201 Aizawa et al. Dec 1995 A
5499819 Nagamoto Mar 1996 A
5544885 Besnard et al. Aug 1996 A
5564705 Kobayashi et al. Oct 1996 A
5588922 Schmidt et al. Dec 1996 A
5599243 Kobayashi Feb 1997 A
5601501 Kobayashi Feb 1997 A
5611740 Nagamoto Mar 1997 A
5626530 Schmidt et al. May 1997 A
5628698 Sumitomo May 1997 A
5643103 Aizawa Jul 1997 A
5658208 Shimasaki Aug 1997 A
5704849 Schmidt et al. Jan 1998 A
5735755 Kobayashi Apr 1998 A
5749794 Kobayashi et al. May 1998 A
5755624 Helmstetter May 1998 A
5766092 Mimeur et al. Jun 1998 A
5776010 Helmstetter et al. Jul 1998 A
5792004 Nagamoto Aug 1998 A
5792005 Sieleman et al. Aug 1998 A
5807191 Nakahara Sep 1998 A
5816936 Aizawa Oct 1998 A
5827131 Mahaffey et al. Oct 1998 A
5833551 Vincent et al. Nov 1998 A
5836830 Onuki et al. Nov 1998 A
5885166 Shiraishi Mar 1999 A
5890971 Shiraishi Apr 1999 A
5899820 Minematsu et al. May 1999 A
5921869 Blough et al. Jul 1999 A
5971868 Kosmatka Oct 1999 A
6001032 Onuki et al. Dec 1999 A
6030293 Takeda Feb 2000 A
6030295 Takeda Feb 2000 A
6045455 Kosmatka et al. Apr 2000 A
6077171 Yoneyama Jun 2000 A
6089992 Onuki et al. Jul 2000 A
6093112 Peters et al. Jul 2000 A
6117023 Onuki et al. Sep 2000 A
6186905 Kosmatka Feb 2001 B1
6200228 Takeda Mar 2001 B1
6210290 Erickson et al. Apr 2001 B1
6220971 Takeda Apr 2001 B1
6238301 Takeda May 2001 B1
6277326 Vecchio et al. Aug 2001 B1
6309309 Beach et al. Oct 2001 B1
6319147 Nakamura et al. Nov 2001 B1
6406382 Deshmukh et al. Jun 2002 B1
6440009 Guibaud et al. Aug 2002 B1
6440010 Deshmukh et al. Aug 2002 B1
6481088 Inoue et al. Nov 2002 B1
6491593 Takeda Dec 2002 B2
6497629 Takeda Dec 2002 B2
6517448 Takeda Feb 2003 B1
6592468 Vincent et al. Jul 2003 B2