Claims
- 1. In a method for the trimerization of an organic isocyanate in the presence of a trimerization catalyst the improvement which comprises employing as said catalyst a composition comprising a solution of the product obtained by reacting, in an inert solvent, substantially equimolar proportions of a ketene-aminal and an olefin having the respective formulae (I) and (II) ##STR4## wherein R.sub.1 R.sub.2, R.sub.3, and R.sub.4 when taken separately are independently selected from the group consisting of lower-alkyl, aralkyl, cycloalkyl, and, when taken together as R.sub.1 with R.sub.2 and R.sub.3 with R.sub.4 with the respective nitrogen atoms to which they are attached represent independently heterocyclic groups having 6 or 7 ring atoms wherein the heterocyclic radical contains at least the basic valence ring nitrogen and optionally containing one or more additional hetero atoms selected from the group consisting of nitrogen, oxygen, and sulfur, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower-alkyl, aryl, aralkyl, and cycloalkyl, R.sub.7 and R.sub.8 when taken separately are independently selected from the group consisting of hydrogen, lower-alkyl, aryl, aralkyl, and cycloalkyl, provided that R.sub.7 and R.sub.8 are not both hydrogen at the same time, and, R.sub.7 and R.sub.8, when taken together with the carbon atom to which they are attached represent a cyclic hydrocarbon group having 5 or 6 carbon atoms in the ring, and R.sub.9 and R.sub.1O represent the same or different electron withdrawing groups.
- 2. A method for the preparation of an aliphatic polyisocyanate prepolymer containing isocyanurate linkages said method comprising contacting an aliphatic polyisocyanate with a catalyst composition according to claim 1.
- 3. A method according to claim 2 wherein said polyisocyanate is hexamethylene diisocyanate.
- 4. A method according to claim 2 wherein said catalyst composition comprises a solution of the product obtained by reacting, 1,1-bisacetyl-2-phenylethylene with 1,1-bis(N-piperidinyl)-2-methylethylene in an organic polyol.
- 5. A method according to claim 2 wherein said polyisocyanate is hexamethylene diisocyanate and said catalyst compositon comprises a solution of the product obtained by reacting 1,1-bis-acetyl-2-phenylethylene with 1,1-bis(N-piperidinyl-2-methlethylene in an organic polyol.
- 6. A method for the preparation of an aromatic polyisocyanate prepolymer containing isocyanurate linkages said method comprising contacting an aromatic polyisocyanate with a catalyst composition according to claim 1.
- 7. A method according to claim 6 wherein said polyisocyanate is methylenebis(phenyl isocyanate).
- 8. A method according to claim 6 wherein said polyisocyanate is a liquefied methylenebis(phenyl isocyanate).
- 9. A method according to claim 6 wherein said catalyst composition comprises a solution of the product obtained by reacting benzylidene malononitrile with 1,1-bis(N-morpholinyl)ethylene in an organic polyol.
- 10. A method according to claim 6 wherein said polyisocyanate is methylenebis(phenyl isocyanate) and said catalyst composition comprises a solution of the product obtained by reacting benzylidene malononitrile with 1,1-bis(N-morpholinyl)ethylene in an organic polyol.
Parent Case Info
This application is a division of application Ser. No. 587,429 filed Mar. 8, 1984, now U.S. Pat. No. 4,536,490.
US Referenced Citations (5)
Non-Patent Literature Citations (1)
Entry |
Gompper et al., Angewandte Chemie, Int. Ed., 6, 453 (1967). |
Divisions (1)
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Number |
Date |
Country |
Parent |
587429 |
Mar 1984 |
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