Not applicable
Not applicable
1. Field of the Invention
Enhancement of surfaces that may be permanently or temporarily re-designed, decorated, and/or re-colored with a design device is disclosed herein.
2. Description of the Background of the Invention
Improving the aesthetics in homes has long been practiced by many consumers. There is a plethora of home products and techniques for cleaning surface areas of soft surfaces such as carpets, rugs, draperies, curtains, upholstery, and the like. However, for more sullied and/or worn surfaces, subtractive processes (for example, a process that chemically or physically removes something from the carpet, such as cleaning or shaving) cannot truly restore the surface to its original state; this is often very frustrating for consumers. Oftentimes, spots and stains reappear after treatment.
Additive processes (for example, a process that layers, covers, or masks something undesirable underneath) and techniques for improving the aesthetics of surfaces include painting, faux painting, stenciling, bordering, wallpapering, tiling, wainscoting, paneling, decorative plastering, adding appliqués (for example, pictures, cut-outs, stickers, or the like), laminating, and molding (for example, crown, shoe, and chair) are also known. However, these products and techniques have not been applied to soft surfaces such as carpets, rugs, draperies, curtains, upholstery, and the like.
According to one aspect of the present disclosure, a kit for applying a design to a desired surface includes a low-slip stencil that inhibits lateral movement of the stencil on the desired surface and a first dispensing device comprising a colorant composition that comprises a liquid carrier and particles. At least one particle comprises a homogeneous mixture of a colorant and a polymer.
In another aspect of the present disclosure, a kit for applying a design to a desired surface includes a low-slip stencil that inhibits lateral movement of the stencil on the desired surface, the stencil including one or more layers and a bottom surface comprising an adhesive. The kit further includes a first dispensing device containing a composition, the composition including a liquid carrier, at least one particle comprising a homogeneous mixture of a colorant and a resin, the resin comprising at least one of an acrylic, an acrylic latex, a polyester, a urethane, or an epoxy, and an optional additive; and an optional second dispensing device containing a sealant composition.
In still another aspect of the present disclosure, a kit for applying a design to a desired surface includes a low-slip stencil having a bottom surface that has an average static coefficient of friction of about 0.3 to about 0.8 and an average kinetic coefficient of friction of about 0.2 to about 0.8 as measured against a bottom surface of another surface having the same bottom surface as the fourth layer. The bottom surface inhibits lateral movement of the stencil on the desired surface. The further includes a container including a colorant composition that includes: a) decor particles having a homogeneous mixture of a colorant and a resin selected from the group consisting of an acrylic, acrylic latex, a polyester, a urethane, and an epoxy; b) an emulsifier, and c) a liquid carrier.
The present disclosure is directed to compositions, methods, apparatuses, kits, and combinations, for permanently or temporarily re-designing, decorating, and/or re-coloring a surface. While several specific embodiments are discussed herein, it is understood that the present disclosure is to be considered only as an exemplification of the principles of the invention, and it is not intended to limit the disclosure to the embodiments illustrated.
For example, a composition useful in the present disclosure includes a décor product that is formulated to be applied and affixed to a surface. The décor product may also be utilized in the form of a kit or in conjunction with a design device, such as a stencil, to control the application of the décor product to create, for example, a pattern on the surface.
Any surface is contemplated to which the décor product may be applied and/or affixed, including, for example, soft surfaces such as carpets, rugs, draperies, curtains, upholstery, and the like. In addition, the décor product may be applied to hard surfaces as well, including, for example, wood, metal, ceramic, glass, a polymer, a hard floor tile, a painted surface, paper, masonry material, rock, a fiber/composite material, rubber, concrete, and the like. It is contemplated that the décor product may be applied to any prepared surface, including, for example, pre-dyed, post-dyed, pre-manufactured, and post-manufactured surfaces. Further, the décor product may be applied during the manufacturing process of a particular good or object that includes a surface in which the décor product may be applied. Surfaces to which the décor product may be applied and/or affixed may be substantially dry, substantially wet, moist, or humid depending on the particular décor product utilized. Further, a décor product of the present disclosure may be applied to a substantially flat, smooth, and/or level surface or any other surface including rough, bumpy, non-smooth, stepped, sloped, slanted, inclined, declined, and/or disturbed surfaces.
Examples of carpets to which the décor product may be applied and/or affixed include modular tiles and panels such as Milliken LEGATO®, Milliken TESSERAE®, INTERFACEFLOR™, Tandus/C&A floorcovering, and from manufacturers such as Mohawk Industries and Shaw Industries, Inc. Additional examples of carpets include broadloom carpets, cut pile (velvet/plush, Saxony, frieze, shag), loop pile (level loop, multi-level loop, and Berber), and cut and loop pile (random sheared and tip sheared) carpets. Additional examples of soft surfaces to which a décor product may be applied and/or affixed thereto include, for example, area rugs (hand woven or machine woven), draperies, curtains, upholstery, and cellulosic materials, among others. Constituent materials of candidate soft surfaces include, for example, natural fibers such as wool and cotton, or synthetic fibers such as nylon 6, nylon 6-6, polyester, polypropylene (olefin), and acrylic, among others.
Decor products of the present disclosure may be formulated, designed, produced, manufactured, applied, removed, and/or packaged by any formulaic, chemical, and/or physical preparation appropriate for the specific embodiment desired, as would only be limited by the inherent nature of the constituent ingredients. Illustrative formulations of the décor products include a solid that may be dissolved or dispersed in a liquid to make a liquid-based décor product, a liquid carrier, an emulsion, a suspension, a colloid, a sol, a dispersion, a solution, a gel, a paste, a foam, a powder, a spray, a tablet, a solid, a gas, a diluent such as water or other solvent, an aerosol, and combinations thereof. Examples of chemical preparations include polyester polymerizations, latex aggregation, chemical milling, and microencapsulization, and other methods known to those skilled in the art. Physical preparation may consist of physically grinding the décor product ingredients or other means known to those skilled in the art. Décor products may be either synthesized from a molecular route, in which polymer resin molecules incorporate colorants, dyes, and/or pigment particles at the molecular scale, such as in the method of manufacture used in chemically prepared toners, or the resin and pigment particles may be physically blended together and crushed to appropriate size by mechanical means known to those skilled in the art.
Examples of applicators and/or dispensers of the décor product of the present disclosure include, for example, an intermittent pressurized sprayer (such as PULL 'N SPRAY® liquid applicator marketed by The Scotts and Miracle-Gro Company), an actuator spray bottle, a trigger sprayer, a mechanical spray bottle, a pump and/or pump system, a liquid refill containing the décor product for a pressurized air chamber, an aerosol barrier pack containing the décor product with a driving chamber (with a propellant, for example, carbon dioxide or a hydrocarbon), and a liquid or gel chamber for containing the décor product where use would allow pressurized spraying with reduced propellant release to the atmosphere or room being decorated by the user. Other useful sprayers include those disclosed in, for example, U.S. Pat. No. 6,872,444. Yet other dispensers useful in the present invention include those disclosed in, for example, U.S. Ser. No. 12/152,311, filed May 14, 2008.
A stencil may be used to assist in the application of the décor product to a surface for the purpose of creating, for example, a pattern on the surface to enhance the aesthetic effect of the décor product. Possible décor product patterns on surfaces contemplated in the present disclosure include any and all images, patterns, shapes, and/or designs. Preselected or random patterns may also be imparted to a surface using an inherent dispersal pattern from a décor product applicator with or without movement of the applicator over a selected surface during application of the décor product. For example, by using a spray applicator with a cone-shaped dispersal pattern, a user may choose to apply discrete spots and/or circles having diameters that are varied by varying the distance from which the applicator is held from the surface during application of the décor product. Further, a user may move the applicator during application of the décor product over the surface in a predetermined or random pattern to achieve a predetermined or random pattern on the surface. As such, preselected patterns and/or random patterns may be imparted to a surface with or without a design device.
Stencils or other design devices contemplated for use in the present disclosure may be designed, constructed, shaped, and/or reshaped, in a predetermined, ordered, disorganized, and/or random manner by means of laser, knife, die cutting, and/or any other appropriate means as determined by the nature of the stencil material (for example, hardness or softness of the stencil materials) to render a predetermined, ordered, disorganized, and/or random shape that allows a predetermined, ordered, disorganized, and/or random deposition of at least a visual design by introducing a décor product on a surface. The stencils may further be laminated and have additional layers applied thereto post-construction and/or post-designing.
The present disclosure also provides kits that contain one or more components herein described, including, for example, a design device and/or a décor product that may be substantially removed from a surface prior to being affixed thereon. A set of instructions may also be included in the kit instructing the user how to apply the design to a soft surface such as a carpet. The kit may further comprise one or more application devices for transferring the décor product to the carpet and/or one or more fixative devices for affixing the décor product to the surface. In addition, the kit may include a protective covering for protecting the décor product after it has been applied to the carpet, especially while it is drying. The kit may further include an iron screen that is used to provide a user with an indication of what areas of the décor product have already been ironed or affixed.
As an example, the kit may be provided having one or more stencils, for example, five stencils, a décor product, an application device such as a sprayer, an affixing device such as a heating device (for example, an iron or a radio frequency emitting device), and/or a set of instructions. The kit may also include a system to identify, choose, make, modify, and/or prepare the surface on which the décor product is to be applied.
A cross-section along the line A of an embodiment of the stencil 2210 is shown in
When the stencil 2210 is placed on a surface 2228 (for example, a floor and/or a wall), the various layers that comprise the stencil 2210 may be configured to inhibit and/or prevent excess decor product that is applied to the stencil 2210, but does not pass through the cutouts, from reaching the surface 2228. The absorptive layer 2230 acts as a material containment layer that absorbs the excess decor product. For example, one embodiment of the stencil 2210 comprises an absorptive layer 2230 that is able to absorb an amount of liquid equal to several times the weight thereof, such as between about eight to about eleven times the weight of the absorptive layer 2230. The absorptive layer 2230 may be manufactured from, for example, a combination of woven and non-woven, natural and synthetic materials including pulp, paper, synthetic fibers, cotton, cotton fabrics, rayon, polyester, lycocell, lyocel, polypropylene, etc. The absorptive layer 2230 in some embodiments of the stencil 2210 may comprise, by weight, from about 50% to about 90% rayon, from about 60% to about 80% rayon, from about 50% rayon, from about 60% rayon, about 70% rayon, about 80% rayon, or about 90% rayon. Some embodiments of the stencil 2210 comprise an absorptive layer 2230 that may comprise from about 10% to about 50% polyester, from 20% to about 40% polyester, about 10% polyester, about 20% polyester, about 30% polyester, about 40% polyester, or about 50% polyester. In some embodiments, the absorptive layer 2230 may comprise a blend that has a greater portion, by weight, of polyester than rayon. Other embodiments of the absorptive layer 2230 may include a blend having about equal portions, by weight, of rayon and polyester. Illustratively, the absorptive layer 2230 comprises about 70% rayon and about 30% polyester by weight, or about 60% rayon and about 40% polyester by weight, or about 50% rayon and about 50% polyester by weight, or about 40% rayon and about 60% polyester by weight. In another embodiment, the absorptive layer 2230 comprises a spunbond textured (for example, having a 3 mm dot pattern) blend of about 70% rayon (for example, lyocel, manufactured by Lenzing Inc., under the trademark TENCEL®, or other cellulose fabric that is obtained by an organic solvent spinning process) and about 30% polyester by weight. Other components, for example, anti-static materials, may also be incorporated as desired into the absorptive layer 2230 in addition to the woven and/or non-woven materials.
The top surface 2238 of the absorptive layer 2230 may be embossed to reduce overspray that may be generated when a liquid is sprayed thereon. The top surface 2238 may be embossed using a process compatible with the materials that includes the absorptive layer 2230 including, for example, hydro-embossing, heat embossing, and/or mechanical embossing (for example, stamping).
In this embodiment, the attachment and barrier layer 2232 enables attachment of the absorptive layer 2230 to the structured layer 2234. The attachment and barrier layer 2232 may be an adhesive material that bonds the absorptive layer 2230 to the structured layer 2234. Alternately or in addition to, the attachment and barrier layer 2232 may include a moisture resistant adhesive and/or a moisture resistant polymer such as polyethylene. In such cases, the attachment and barrier layer 2232 may both bond the absorptive layer 2230 to the structured layer 2234 and/or provide a liquid impermeable layer by providing a barrier that prevents or inhibits liquids absorbed by the absorptive layer 2230 from being released to the structured layer 2234.
A material that combines together the absorptive layer 2230 and the attachment and barrier layer 2232 may also be used. An example of such a material includes the commercially available GOTCHA COVERED® drop cloth by Kimberly-Clark Corp.
If desired, the structured layer 2234 may provide rigidity to the stencil 2210. The structured layer 2234 may also form a moisture barrier that blocks or retards the release of liquids absorbed by the absorptive layer 2230 to the surface 2228. The structured layer 2234 may be comprised of a cellulosic material such as cardboard or paper, polymer-based films such as MYLAR®, a polymer-based foam, a foil film, semi-stiff nonwoven (for example, needle punched) materials, poly-coated nonwoven materials, corrugated board, and combinations thereof In some embodiments, paperboard between about 12-point to about 22-point may comprise the structured layer 2234. For example, 18-point paperboard may be sufficiently rigid for use as a material for the structured layer 2234. For certain applications, described below, the material selected for the structured layer 2234 may allow the stencil 2210 to be folded or to be cut into a desired shape using common tools such as a utility knife or scissors.
In yet other embodiments, the low-slip and flatness coating layer 2236 allows the stencil 2210 to lay flat and remain static on the surface 2228 but has sufficient slip to allow the stencil 2210 to be repositioned by a user by sliding across the surface 2228, as necessary. For example, the low-slip and flatness coating layer 2236 has coefficient of friction properties that prevent or inhibit lateral movement of the stencil 2210 against the surface 2228 sufficient for a user to apply the stencil to the surface and readjust the location thereof as needed, but also to allow the application of the décor product thereto without the stencil moving inappropriately before, during, and/or after the application of the décor product to the surface. Illustratively, the low-slip and flatness coating layer 2236 is a coating that is applied to the bottom surface of the structured layer 2234. The coating may comprise, for example, a wax, a polymer (for example, polyethylene), a thermoplastic, silicone, and/or polytetrafluoroethylene. Further examples of coatings useful in the present disclosure include water-based coatings, water-based emulsions and dispersions, solvent-borne dispersions, and micronized powders for paper, film and foil packaging, such as those available from Michelman, Inc., Cincinnati, Ohio, including, for example, Michem® Prime, a ethylene-acrylic acid co-polymer dispersion, MILLWHITE™, a non-waxable white coating, SOFTAK®, a water-based coating to increase skid angle, and WAX DISPERSION 40®, a solvent dispersion of paraffin wax. Combinations of the above coating may also be used to achieve the desired slip resistance or static or kinetic coefficient of friction properties.
In one embodiment, the low-slip and flatness coating layer 2236 may comprise a low-tack adhesive that is applied to the bottom surface of the structured layer 2234. In some embodiments, the low-slip and flatness coating layer 2236 may also be liquid impermeable and provide a barrier that prevents or inhibits liquids absorbed by the absorptive layer 2230 from being released to the surface 2228 on which the stencil is placed. For example, by including a moisture resistant material in the low-slip and flatness coating layer 2236.
In one embodiment, a stencil 2210 includes a structured layer 2234 of 16-18 point paperboard and a low-slip and flatness coating layer 2236 formed by coating the structured layer 2234 with about 7 to about 10 pounds per 100 square feet of mirror finished polyethylene. In other embodiments, a low density polyethylene may be used. In still other embodiments, a coated paperboard may be used whereby the paperboard may supply the structured layer 2234 and the coating may supply the low-slip and flatness coating layer 2236. Examples of such coated paperboard products include polyethylene extrusion or wax coated CARTONMATE® bleached boards or coated recycled boards (for example, ANGELCOTE®) manufactured by Rock-Tenn Company, Norcross, Ga.
Illustratively, the bottom surfaces 2240 of a plurality of such stencils (for example, the bottom surfaces of the low-slip and flatness coating layers 2236) may have static coefficients of friction that range from about 0.4 to about 0.7 and kinetic coefficients of friction that range from about 0.3 to about 0.5 when measured relative to a bottom surface of another stencil in the manufacturing (grain) direction of the paperboard. The bottom surface 2240 of some embodiments of the stencil 2210 may have a static coefficient of friction from about 0.3 to about 0.8 and a kinetic coefficient of friction from about 0.2 to about 0.6. Static and kinetic coefficient of friction may be determined using methods known in the art including, for example, standardized method such as the ASTM D-2047 or using a frictionometer as known by those skilled in the art.
When measured relative to the bottom surface of another stencil having the same or identical bottom surface in the cross direction of the paperboard, the bottom surface 2240 of an embodiment of the stencil 2210 may have a static coefficient of friction that ranges from about 0.4 to about 1.0, from about 0.3 to about 1.1, or from about 0.2 to about 1.2. Some embodiments of the stencil 2210 may have a bottom surface 2240 that has a kinetic coefficient of friction that ranges from about 0.3 to about 0.9, from about 0.2 to about 1.0, or from about 0.1 to about 1.1.
Some embodiments of the stencil 2210 may have a bottom surface 2240 with an average static coefficient of friction that range from about 0.3 to about 0.8, from about 0.4 to about 0.7, or from about 0.5 to about 0.6. The average kinetic coefficients of friction of the bottom surface 2240 of some embodiments of the stencil 2210 may range from about 0.4 to about 0.6, from about 0.3 to about 0.7, or from 0.2 to about 0.8.
In some embodiments, the layers that comprise the stencil 2210 have substantially identical planar dimensions. In other embodiments, adjusting the sizes of the individual layers that comprise the stencil may retain properties of the stencil (for example, absorbency and rigidity) while optimizing other aspects (for example, material cost) of the stencil. For example,
It should be apparent that the layers that comprise the stencil 2210 do not have to have identical thickness. For example, the absorptive layer 2230 may be thicker than the structured layer 2234, and each of these may be thicker than either the attachment and barrier layer 2232 or the low-slip and flatness coating layer 2236. The thickness of the individual layers and the stencil 2210 as a whole may be optimized according to the environment and application in which the stencil 2210 may be used and/or to the specific composition that is being applied with the stencil 2210 and the liquid content thereof. For example, in some applications, the thickness of the stencil 2210 may be minimized to reduce bulk while maintaining the absorptive properties and structural integrity thereof. In other applications, the thickness of the stencil 2210 may not matter and production cost may be optimized. In some embodiments, the thickness of the structured layer 2234 may be from about 0.011 inches to 0.025 inches thick, from about 0.013 to about 0.023 inches thick, from about 0.015 to about 0.021 inches thick, from about 0.013 to about 0.015 inches thick, about 0.014 inches thick, about 0.016 inches thick, about 0.018 inches thick, about 0.020 inches thick, or about 0.22 inches thick. In some embodiments, the thickness of the attachment and barrier layer 2232 and/or the low-slip and flatness coating layer 2236 may be from about 0.0002 inches to 0.0008 inches thick, from about 0.0004 inches to about 0.0006 inches thick, about 0.0003 inches thick, about 0.0005 inches thick, or about 0.0007 inches thick.
It is contemplated that any of the layers that comprise the stencil 2210 may be liquid impermeable and prevent or reduce passage of liquid deposited onto the surface of the stencil 2238 from migrating to the surface 2228 onto which the stencil is placed. It is further contemplated that any of the layers that comprise the stencil 2210 may provide structure to the stencil. In addition, any of the layers of the stencil 2210 may have absorptive properties and may provide containment of materials deposited onto the surface of the stencil 2238.
Similarly, the portion of the weight that the individual layers of a stencil 2210 comprise may not be identical. For example, in one embodiment of the stencil 2210, the absorptive layer 2230 comprised approximately 25% of the weight of the stencil 2210 and the structured layer 2234 comprised approximately 75% of the weight of the stencil 2210. In some embodiments, the attachment and barrier layer 2232 and/or low-slip and flatness coating layer 2236 may comprise from about 0.5% to about 1.5% of the total weight of the stencil 2210 or, in other embodiments, may comprise less than about 1% of the total weight of the stencil 2210.
Additional layers may be incorporated into the stencil 2210. For example,
The additional support layer 2242 may also be positioned on the top surface 2238 of the absorptive layer 2230. For example, an additional layer 2242 comprising threads may be attached to the top surface 2238 of the stencil 2210. The additional support layer 2242 may be attached either during the manufacture of the stencil 2210 and/or as an additional post processing step. Similarly, the additional support layer 2242 may be added to the bottom surface 2240 of the stencil 2210.
Two or more additional support layers 2242 may also be used. For example, a first additional support layer 2242 may be situated between the absorptive layer 2230 and the attachment and barrier 2232 layer and a second additional support layer 2242 may be situated between the structured layer 2234 and the low-slip and flatness coating layer 2236. In such embodiments, the first and second additional support layers 2242 may be identical or different. For example, the first additional support layer 2242 may be comprised of threads and the second additional support layer may comprise a mesh.
Although not shown, in some embodiments, a web of material used for the absorptive layer 2230 is laminated with the material used for the attachment and barrier layer 2232 to form a first laminated web. Similarly, a web of the material used for the structured layer 2234 is coated with the material used for the low-slip and flatness coating layer 2236 to form a second laminated web. Thereafter the first and second laminated webs may be introduced into a production line that includes a bonding unit for joining the first and second laminated webs together into a web of stencil material. The bonding unit may include a heating unit to activate the adhesive in the attachment and barrier layer 2232. Alternately, the bonding unit may include a pressure unit that activates the adhesive. A combination of heat and pressure may also be used. Other ways of joining the first and second laminate webs to form the web stencil material known in the art may be used. For example, an embodiment of the stencil 2210 comprises a non-woven absorptive layer 2230 laminated (for example, via poly coating, extrusion application, or extrusion lamination using molten polymer) using an attachment and barrier layer 2232 to a 16-18 point paperboard structured layer 2234 substrate that is poly-coated to form a low-slip flatness layer 2236 on an exterior surface. Such embodiment may provide a liquid barrier and a degree of surface tension when placed on a soft surface to reduce movement of the stencil during application of the decor product. The production line may include embossing units to emboss the top surface of the web of stencil material (for example, if the absorptive layer had not been embossed prior to forming the first laminated web). Die cutting units in the production line may be used to form regularly spaced cutouts in the web of stencil material and sheeting units may be used to cut the web of stencil material into individual stencils.
In some embodiments, a roll of uncoated paperboard that comprises the structured layer 2234 may be extrusion laminated to a roll of non-woven material, which comprises the absorptive layer 2230, using molten polyethylene, which comprises the attachment and barrier layer 2232. The laminated material may thereafter be wound up onto a master roll. The master roll may coated on the paperboard side with molten polyethylene, which forms the low-slip and flatness layer 2236, and the coated material may be wound up onto a roll to form a coated master roll. The coated master roll may thereafter be cut into stencil sized sheets (for example, about 20-inches square) and stacked in columns. The stacked columns of cut sheets may thereafter be cut, for example on a flat bed die-cutting machine, to form the cutout portions of the stencil. In other embodiments, the coated master roll may be cut into sheets larger than the stencil and such sheets may be later trimmed to a final size.
Further embodiments of the present disclosure may incorporate value adding chemistries including powder coatings, toner and/or ink chemistries, carpet stain removers and/or maskers, odor eliminators and/or absorbers, bleaching agents. Compositions, methods of carpet stain removing and/or masking, methods of composition affixation, design aids, including stencils, and dispensing devices useful in the present disclosure include those disclosed in U.S. Pat. Nos. 7,556,841, 7,763,083, and 7,423,002, each filed on Jun. 6, 2006, U.S. Pat. No. 7,727,289, filed on May 14, 2008, U.S. Ser. No. 11/447,694, filed on Jun. 6, 2006, and U.S. Ser. Nos. 12/152,322 and 12/152,311, each filed on May 14, 2008. Further, technologies used in aftermarket carpet dyeing in the automotive industry may be useful in the present disclosure, including, for example, the “Pro Dye System” available from Top of the Line. An additional contemplated chemistry includes ultraviolet radiation cross-linking agents that crosslink décor product particles in preparation for affixation of the décor product to a surface or removal therefrom.
The present disclosure describes kits useable for the application of a décor product to be applied to a surface. By applying the décor product to the surface, perceived aesthetic quality of the soft surface is improved and may extend the useful life of the surface before need for replacement.
The disclosure has been presented in an illustrative manner in order to enable a person of ordinary skill in the art to make and use the disclosure, and the terminology used is intended to be in the nature of description rather than of limitation. It is understood that the disclosure may be practiced in ways other than as specifically disclosed, and that all modifications, equivalents, and variations of the present disclosure, which are possible in light of the above teachings and ascertainable to a person of ordinary skill in the art, are specifically included within the scope of the impending claims. All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention.
This application is a divisional application of U.S. patent Ser. No. 12/152,405, filed May 4, 2008, now U.S. Pat. No. 8,061,269, which is hereby incorporated by reference in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
2802713 | Olpin et al. | Aug 1957 | A |
2959461 | Murray | Nov 1960 | A |
3030227 | Clifford et al. | Apr 1962 | A |
3236586 | Humphreys | Feb 1966 | A |
3377412 | Franks | Apr 1968 | A |
3486929 | Anspon et al. | Dec 1969 | A |
3595166 | Sherman | Jul 1971 | A |
3652198 | Farber et al. | Mar 1972 | A |
3663262 | Cogan | May 1972 | A |
3716330 | Kitamura et al. | Feb 1973 | A |
3723323 | Morgan et al. | Mar 1973 | A |
3821066 | Tillotson et al. | Jun 1974 | A |
3849159 | Palmer et al. | Nov 1974 | A |
3861869 | Schwindt et al. | Jan 1975 | A |
3867171 | Ellsworth | Feb 1975 | A |
3904358 | James | Sep 1975 | A |
3910848 | Froehlich et al. | Oct 1975 | A |
3929068 | Budden | Dec 1975 | A |
3945791 | Bohm | Mar 1976 | A |
3963820 | Blakey | Jun 1976 | A |
3988521 | Fumel et al. | Oct 1976 | A |
4006273 | Wolinski et al. | Feb 1977 | A |
4013594 | Froehlich et al. | Mar 1977 | A |
4016327 | Fumei et al. | Apr 1977 | A |
4046505 | Cobb et al. | Sep 1977 | A |
4085159 | Marsiat | Apr 1978 | A |
4089722 | Holoubek | May 1978 | A |
4093415 | Defago et al. | Jun 1978 | A |
4129669 | Lopez | Dec 1978 | A |
4131422 | Thomas et al. | Dec 1978 | A |
4131424 | Cocoros et al. | Dec 1978 | A |
4140728 | Hahn et al. | Feb 1979 | A |
4147508 | Perrig | Apr 1979 | A |
4147737 | Sein et al. | Apr 1979 | A |
4180527 | Schmid et al. | Dec 1979 | A |
4194140 | Hamano et al. | Mar 1980 | A |
4239490 | Kelly et al. | Dec 1980 | A |
4243565 | Nishino et al. | Jan 1981 | A |
4263352 | Kaltenbach et al. | Apr 1981 | A |
4286959 | Horn et al. | Sep 1981 | A |
4293596 | Furendal et al. | Oct 1981 | A |
4397650 | Gregorian et al. | Aug 1983 | A |
4434198 | Clark | Feb 1984 | A |
4468230 | Thomas et al. | Aug 1984 | A |
4471108 | Belder et al. | Sep 1984 | A |
4476976 | Smith | Oct 1984 | A |
4502867 | Reinhardt | Mar 1985 | A |
4522864 | Humason et al. | Jun 1985 | A |
4545481 | Smith | Oct 1985 | A |
4560604 | Shimizu et al. | Dec 1985 | A |
4568606 | Hart et al. | Feb 1986 | A |
4604308 | Widmer et al. | Aug 1986 | A |
4681791 | Shibahashi et al. | Jul 1987 | A |
4702742 | Iwata et al. | Oct 1987 | A |
4713084 | Bohrn et al. | Dec 1987 | A |
4726976 | Karami et al. | Feb 1988 | A |
4778742 | Ong et al. | Oct 1988 | A |
4782672 | Secolo | Nov 1988 | A |
4836828 | Hussamy | Jun 1989 | A |
4871604 | Hackler | Oct 1989 | A |
4913952 | Fowler | Apr 1990 | A |
4960433 | Renton | Oct 1990 | A |
4965172 | Matrick | Oct 1990 | A |
4978390 | Snedeker | Dec 1990 | A |
4981488 | Cates et al. | Jan 1991 | A |
4985115 | De Rossett, Jr. | Jan 1991 | A |
4990369 | Burchill et al. | Feb 1991 | A |
5010131 | Wagner | Apr 1991 | A |
5041488 | Meades | Aug 1991 | A |
5047261 | Moussa et al. | Sep 1991 | A |
5057392 | McCabe et al. | Oct 1991 | A |
5064443 | Ricci | Nov 1991 | A |
5071440 | Hines et al. | Dec 1991 | A |
5091213 | Silbermann et al. | Feb 1992 | A |
5091257 | Nonogaki et al. | Feb 1992 | A |
5098497 | Brinley | Mar 1992 | A |
5110317 | Hangey et al. | May 1992 | A |
5110625 | Burchill et al. | May 1992 | A |
5110626 | Burchill et al. | May 1992 | A |
5110634 | Silbermann et al. | May 1992 | A |
5112678 | Gay et al. | May 1992 | A |
5112715 | DeMejo et al. | May 1992 | A |
5112883 | Gallas | May 1992 | A |
5116243 | Wills | May 1992 | A |
5122404 | Fowler | Jun 1992 | A |
5124519 | Roy et al. | Jun 1992 | A |
5126191 | Fourezon | Jun 1992 | A |
5131914 | Kelley | Jul 1992 | A |
5131918 | Kelley | Jul 1992 | A |
5143754 | Long et al. | Sep 1992 | A |
5147747 | Wilson et al. | Sep 1992 | A |
5164226 | Burchill et al. | Nov 1992 | A |
5176745 | Moore et al. | Jan 1993 | A |
5193457 | Hahn | Mar 1993 | A |
5199957 | Pascoe | Apr 1993 | A |
5217255 | Lin et al. | Jun 1993 | A |
5232535 | Brinley | Aug 1993 | A |
5238465 | Fritzsche | Aug 1993 | A |
5242994 | Nield et al. | Sep 1993 | A |
5243906 | Okusawa | Sep 1993 | A |
5245932 | Ujiie | Sep 1993 | A |
5250634 | Toyoda et al. | Oct 1993 | A |
5252379 | Kuribayashi et al. | Oct 1993 | A |
5258471 | Nield et al. | Nov 1993 | A |
5262510 | Kwon et al. | Nov 1993 | A |
5284902 | Huber et al. | Feb 1994 | A |
5298035 | Okamoto | Mar 1994 | A |
5302223 | Hale | Apr 1994 | A |
5303647 | Seo et al. | Apr 1994 | A |
5321063 | Shimada et al. | Jun 1994 | A |
5330627 | Grutter et al. | Jul 1994 | A |
5353701 | Casagrande | Oct 1994 | A |
5355793 | Sato et al. | Oct 1994 | A |
5358537 | Kelly et al. | Oct 1994 | A |
5362415 | Egraz et al. | Nov 1994 | A |
5362417 | Ziolo | Nov 1994 | A |
5374687 | Cooperman et al. | Dec 1994 | A |
5379947 | Williams et al. | Jan 1995 | A |
5389108 | Fritzsche et al. | Feb 1995 | A |
5409772 | Yabusa et al. | Apr 1995 | A |
5415090 | Natori et al. | May 1995 | A |
5417156 | Tateishi et al. | May 1995 | A |
5453459 | Roberts | Sep 1995 | A |
5456725 | Bruhnke | Oct 1995 | A |
5460087 | Ogorzalek | Oct 1995 | A |
5460881 | Hsu | Oct 1995 | A |
5462996 | Portelli et al. | Oct 1995 | A |
5466527 | Jenkins | Nov 1995 | A |
5472764 | Kehr et al. | Dec 1995 | A |
5483883 | Hayama | Jan 1996 | A |
5490866 | Guth | Feb 1996 | A |
5498464 | Ikejima et al. | Mar 1996 | A |
5514462 | Endo et al. | May 1996 | A |
5522313 | Okusawa | Jun 1996 | A |
5525125 | Cole et al. | Jun 1996 | A |
5536762 | Hinojosa | Jul 1996 | A |
5542351 | Roth | Aug 1996 | A |
5571444 | Fisher et al. | Nov 1996 | A |
5575877 | Hale et al. | Nov 1996 | A |
5576361 | Craun | Nov 1996 | A |
5578245 | Ziolo | Nov 1996 | A |
5587408 | Burns et al. | Dec 1996 | A |
5589256 | Hansen et al. | Dec 1996 | A |
5601023 | Hale et al. | Feb 1997 | A |
5603735 | Zimin, Sr. et al. | Feb 1997 | A |
5626634 | Goldmann et al. | May 1997 | A |
5630850 | Schaffutzel et al. | May 1997 | A |
5637654 | Panandiker et al. | Jun 1997 | A |
5640180 | Hale et al. | Jun 1997 | A |
5645609 | Andrean et al. | Jul 1997 | A |
5646240 | Oishi et al. | Jul 1997 | A |
5655446 | Watanabe | Aug 1997 | A |
5669300 | Watanabe | Sep 1997 | A |
5674923 | Subbaraman et al. | Oct 1997 | A |
5681620 | Elgarhy | Oct 1997 | A |
5698303 | Caldwell | Dec 1997 | A |
5708039 | Daly et al. | Jan 1998 | A |
5709146 | Watanabe | Jan 1998 | A |
5718170 | Watanabe | Feb 1998 | A |
5725605 | Maunz et al. | Mar 1998 | A |
5734396 | Hale et al. | Mar 1998 | A |
5760122 | Susa et al. | Jun 1998 | A |
5763016 | Levenson et al. | Jun 1998 | A |
5800866 | Myers et al. | Sep 1998 | A |
5809880 | Okuda et al. | Sep 1998 | A |
5820638 | Houser et al. | Oct 1998 | A |
5824362 | Watanabe | Oct 1998 | A |
5843560 | Ohta et al. | Dec 1998 | A |
5851595 | Jones, Jr. | Dec 1998 | A |
5852072 | Banning et al. | Dec 1998 | A |
5869172 | Caldwell | Feb 1999 | A |
5875711 | Tateishi et al. | Mar 1999 | A |
5876792 | Caldwell | Mar 1999 | A |
5879746 | Tomihashi et al. | Mar 1999 | A |
5908663 | Wang et al. | Jun 1999 | A |
5908687 | Mori | Jun 1999 | A |
5919858 | Loftin | Jul 1999 | A |
5922088 | Cole et al. | Jul 1999 | A |
5924359 | Watanabe | Jul 1999 | A |
5924360 | Adachi et al. | Jul 1999 | A |
5924361 | Watanabe | Jul 1999 | A |
5929145 | Higgins et al. | Jul 1999 | A |
5948534 | Altavilla | Sep 1999 | A |
5955523 | Stephens et al. | Sep 1999 | A |
5958137 | Caldwell et al. | Sep 1999 | A |
5958547 | Fukunishi et al. | Sep 1999 | A |
5968689 | Torikoshi et al. | Oct 1999 | A |
5981021 | McCulloch | Nov 1999 | A |
5981459 | Verbiest et al. | Nov 1999 | A |
5989638 | Nielsen | Nov 1999 | A |
5992315 | Lorenz | Nov 1999 | A |
5992316 | Komata et al. | Nov 1999 | A |
6007955 | Verhecken et al. | Dec 1999 | A |
6024770 | de Lathauwer | Feb 2000 | A |
6025066 | Terasawa et al. | Feb 2000 | A |
6032576 | Collins | Mar 2000 | A |
6035778 | Uchiyama | Mar 2000 | A |
6036726 | Yang et al. | Mar 2000 | A |
6040359 | Santini et al. | Mar 2000 | A |
6048575 | Altavilla | Apr 2000 | A |
6050183 | Tanaka et al. | Apr 2000 | A |
6063476 | Kinoshita | May 2000 | A |
6069221 | Chasser et al. | May 2000 | A |
6073554 | Cutcher, Sr. | Jun 2000 | A |
6086636 | Mheidle et al. | Jul 2000 | A |
6090447 | Suzuki et al. | Jul 2000 | A |
6092461 | Tanaka et al. | Jul 2000 | A |
6092462 | Watanabe | Jul 2000 | A |
6099995 | Altavilla | Aug 2000 | A |
6121408 | Aoki et al. | Sep 2000 | A |
6136046 | Fukunishi et al. | Oct 2000 | A |
6138561 | Watanabe | Oct 2000 | A |
6147041 | Takahaski et al. | Nov 2000 | A |
6194106 | Bretscher et al. | Feb 2001 | B1 |
6207768 | Sato et al. | Mar 2001 | B1 |
6209453 | Watanabe | Apr 2001 | B1 |
6211308 | Saint Victor | Apr 2001 | B1 |
6214898 | Barrio et al. | Apr 2001 | B1 |
6225026 | Lifshitz et al. | May 2001 | B1 |
6250219 | Garvin | Jun 2001 | B1 |
6251987 | Sacripante et al. | Jun 2001 | B1 |
6254995 | Kohno et al. | Jul 2001 | B1 |
6284845 | Panandiker et al. | Sep 2001 | B1 |
6294222 | Cohen et al. | Sep 2001 | B1 |
6294610 | Daly et al. | Sep 2001 | B1 |
6306930 | Tsujio | Oct 2001 | B1 |
6314875 | Steenbergen | Nov 2001 | B1 |
6341856 | Thompson et al. | Jan 2002 | B1 |
6348679 | Ryan et al. | Feb 2002 | B1 |
6348939 | Xu et al. | Feb 2002 | B1 |
6349640 | Takebe et al. | Feb 2002 | B1 |
6352563 | Kusaki et al. | Mar 2002 | B1 |
6357347 | Yoshida | Mar 2002 | B1 |
6358461 | Law et al. | Mar 2002 | B1 |
6376589 | Tanaka et al. | Apr 2002 | B1 |
6379401 | Legrand et al. | Apr 2002 | B1 |
6393979 | Tateishi | May 2002 | B1 |
6393980 | Simons | May 2002 | B2 |
6403150 | Ohta et al. | Jun 2002 | B1 |
6443996 | Mihelich et al. | Sep 2002 | B1 |
6446551 | Watanabe | Sep 2002 | B1 |
6447895 | Kamir et al. | Sep 2002 | B1 |
6458192 | Tsujio | Oct 2002 | B1 |
6488719 | Lomasney et al. | Dec 2002 | B2 |
6497936 | Desai et al. | Dec 2002 | B1 |
6506221 | Macholdt et al. | Jan 2003 | B1 |
6506445 | Popat et al. | Jan 2003 | B2 |
6509555 | Reiss et al. | Jan 2003 | B1 |
6521287 | Jiang et al. | Feb 2003 | B2 |
6532867 | Nakamura et al. | Mar 2003 | B2 |
6533824 | Roper | Mar 2003 | B1 |
6536338 | Nakamura et al. | Mar 2003 | B2 |
6539856 | Jones et al. | Apr 2003 | B2 |
6550380 | Kinoshita et al. | Apr 2003 | B2 |
6572951 | Hasegawa et al. | Jun 2003 | B2 |
6584897 | Cobbley et al. | Jul 2003 | B2 |
6585369 | Sievert et al. | Jul 2003 | B1 |
6593401 | Park et al. | Jul 2003 | B1 |
6595129 | Mori | Jul 2003 | B2 |
6600142 | Ryan et al. | Jul 2003 | B2 |
6602566 | Steenbergen | Aug 2003 | B2 |
6618066 | Hale et al. | Sep 2003 | B2 |
6623576 | Mitchell et al. | Sep 2003 | B2 |
6645569 | Cramer et al. | Nov 2003 | B2 |
6649317 | Wagner et al. | Nov 2003 | B2 |
6649888 | Ryan et al. | Nov 2003 | B2 |
6653265 | Rossi et al. | Nov 2003 | B2 |
6655271 | Contompasis | Dec 2003 | B1 |
6659003 | Nakamura et al. | Dec 2003 | B2 |
6662719 | Adachi | Dec 2003 | B1 |
6673503 | Wagner et al. | Jan 2004 | B2 |
6675705 | Yamamoto et al. | Jan 2004 | B2 |
6679166 | Nakamura et al. | Jan 2004 | B2 |
6681691 | Foster et al. | Jan 2004 | B2 |
6686314 | Xu et al. | Feb 2004 | B2 |
6703089 | DeProspero et al. | Mar 2004 | B2 |
6719467 | Hess et al. | Apr 2004 | B2 |
6723413 | Walters | Apr 2004 | B2 |
6723428 | Foss et al. | Apr 2004 | B1 |
6743848 | Nakahara et al. | Jun 2004 | B2 |
6758138 | Nakamura et al. | Jul 2004 | B2 |
6766736 | Regner et al. | Jul 2004 | B2 |
6779443 | Martinez et al. | Aug 2004 | B2 |
6790819 | Trinh et al. | Sep 2004 | B2 |
6794007 | Carr et al. | Sep 2004 | B2 |
6805048 | Pearson et al. | Oct 2004 | B2 |
6807904 | Ohshima et al. | Oct 2004 | B2 |
6815005 | Stevenson et al. | Nov 2004 | B2 |
6820546 | Wynne | Nov 2004 | B2 |
6841233 | Kinoshita et al. | Jan 2005 | B2 |
6841244 | Foss et al. | Jan 2005 | B2 |
6844392 | Suman | Jan 2005 | B2 |
6849370 | Wagner et al. | Feb 2005 | B2 |
6863933 | Cramer et al. | Mar 2005 | B2 |
6866924 | Yamaguchi | Mar 2005 | B2 |
6872443 | Franke | Mar 2005 | B2 |
6872444 | McDonald et al. | Mar 2005 | B2 |
6887640 | Zhang et al. | May 2005 | B2 |
6887916 | Zhou et al. | May 2005 | B2 |
6889605 | Natori et al. | May 2005 | B1 |
6890974 | Park et al. | May 2005 | B2 |
6893662 | Dittmar et al. | May 2005 | B2 |
6894090 | Shinzo et al. | May 2005 | B2 |
6916774 | Trinh et al. | Jul 2005 | B2 |
6927253 | Lassmann et al. | Aug 2005 | B2 |
6936075 | Vogt et al. | Aug 2005 | B2 |
6946049 | Yamaguchi | Sep 2005 | B2 |
6946149 | Cleveland | Sep 2005 | B2 |
6951670 | Stroppiana | Oct 2005 | B2 |
6962111 | Tanaka et al. | Nov 2005 | B2 |
6968780 | Birch | Nov 2005 | B2 |
6977098 | Gurer et al. | Dec 2005 | B2 |
6977111 | Yamaguchi et al. | Dec 2005 | B2 |
6982108 | Janssen et al. | Jan 2006 | B2 |
6992028 | Thomaschefsky | Jan 2006 | B2 |
7008889 | Black et al. | Mar 2006 | B2 |
7018429 | Wenstrup | Mar 2006 | B1 |
7022377 | Kanada et al. | Apr 2006 | B2 |
7041424 | Xu et al. | May 2006 | B2 |
7066993 | Wuzik et al. | Jun 2006 | B2 |
7105597 | Soda et al. | Sep 2006 | B2 |
7108728 | Sunamori et al. | Sep 2006 | B2 |
7112621 | Rohrbaugh et al. | Sep 2006 | B2 |
7134390 | Cobbley et al. | Nov 2006 | B2 |
7156017 | Ingraselino | Jan 2007 | B1 |
7186450 | Foxon | Mar 2007 | B2 |
7223477 | Muthiah | May 2007 | B2 |
7226607 | Uchiyama et al. | Jun 2007 | B2 |
7264861 | Zafiroglu et al. | Sep 2007 | B2 |
7279212 | Foxon | Oct 2007 | B2 |
7288288 | Milic et al. | Oct 2007 | B2 |
7288585 | Moad et al. | Oct 2007 | B2 |
7316832 | Steinhardt et al. | Jan 2008 | B2 |
7348374 | Martinazzo | Mar 2008 | B2 |
7374808 | Sellman, Jr. et al. | May 2008 | B2 |
7405000 | Takikawa et al. | Jul 2008 | B2 |
7435765 | McCovick et al. | Oct 2008 | B2 |
7503940 | Donaldson et al. | Mar 2009 | B2 |
7521085 | Hall et al. | Apr 2009 | B2 |
7556841 | Kimball et al. | Jul 2009 | B2 |
7563498 | Shimizu et al. | Jul 2009 | B2 |
7592041 | Fulton | Sep 2009 | B2 |
7622154 | Eriksson et al. | Nov 2009 | B2 |
7622175 | Pallotta et al. | Nov 2009 | B2 |
7654660 | Hale et al. | Feb 2010 | B2 |
7709070 | Kinsey et al. | May 2010 | B2 |
7976947 | Magnin et al. | Jul 2011 | B2 |
20020011159 | Mazaki | Jan 2002 | A1 |
20020040503 | Pace et al. | Apr 2002 | A1 |
20020077261 | Hwang et al. | Jun 2002 | A1 |
20020166468 | Schmid et al. | Nov 2002 | A1 |
20030070569 | Bulthaup et al. | Apr 2003 | A1 |
20030092589 | Todini et al. | May 2003 | A1 |
20030157377 | Muthiah | Aug 2003 | A1 |
20030194560 | Spera et al. | Oct 2003 | A1 |
20040110867 | McCovick | Jun 2004 | A1 |
20040154106 | Oles et al. | Aug 2004 | A1 |
20040230008 | Correll et al. | Nov 2004 | A1 |
20040237814 | Caplan | Dec 2004 | A1 |
20050089703 | Tamaguchi | Apr 2005 | A1 |
20050090627 | Wenning et al. | Apr 2005 | A1 |
20050095933 | Kimbrell et al. | May 2005 | A1 |
20050155693 | Zafiroglu | Jul 2005 | A1 |
20050183207 | Chan et al. | Aug 2005 | A1 |
20060009591 | Wu | Jan 2006 | A1 |
20060051571 | Steinhardt et al. | Mar 2006 | A1 |
20060134384 | Vinson et al. | Jun 2006 | A1 |
20060135668 | Hayes | Jun 2006 | A1 |
20060165979 | Kinsey et al. | Jul 2006 | A1 |
20070037902 | McCovick | Feb 2007 | A1 |
20070089621 | Kimball et al. | Apr 2007 | A1 |
20070232179 | Polat et al. | Oct 2007 | A1 |
20070270064 | Aseere | Nov 2007 | A1 |
20070275207 | Higgins et al. | Nov 2007 | A1 |
20070286982 | Higgins et al. | Dec 2007 | A1 |
20080064802 | Abecassis et al. | Mar 2008 | A1 |
20080280059 | Adams et al. | Nov 2008 | A1 |
20090022957 | Aso et al. | Jan 2009 | A1 |
20100028586 | Enlow et al. | Feb 2010 | A1 |
Number | Date | Country |
---|---|---|
2122714 | Oct 1972 | DE |
10224984 | Dec 2003 | DE |
0103407 | Aug 1988 | EP |
0103344 | Oct 1988 | EP |
0307624 | Mar 1989 | EP |
0569921 | Nov 1993 | EP |
0752498 | Jan 1997 | EP |
0803351 | Oct 1997 | EP |
0993876 | Apr 2000 | EP |
1132439 | Sep 2001 | EP |
1283296 | Feb 2003 | EP |
531766 | Jan 1941 | GB |
669739 | Apr 1952 | GB |
721827 | Jan 1955 | GB |
774078 | May 1957 | GB |
1366343 | Sep 1974 | GB |
1461049 | Jan 1977 | GB |
2152841 | Aug 1985 | GB |
1111081 | Apr 1989 | JP |
2002142956 | May 2002 | JP |
9808915 | Mar 1998 | WO |
2004066793 | Aug 2004 | WO |
2010018094 | Feb 2010 | WO |
2010018096 | Feb 2010 | WO |
Entry |
---|
United States Patent and Trademark Office, Office Action Summary and Detailed Action, U.S. Appl. No. 12/152,405, Mar. 18, 2011. |
United States Patent and Trademark Office, Office Action Summary and Ex-Parte Quayle Action, U.S. Appl. No. 12/152,405, Jul. 5, 2011. |
United States Patent and Trademark Office, Notice of Allowability and Examiner's Amendment and Comment, U.S. Appl. No. 12/152,405, Sep. 13, 2011. |
Rohm and Haas Company, Material Safety Data Sheet for Rhoplex(TM) TR-407 Acrylic Binder for Textile and Nonwoven Applications, Jun. 9, 2005. |
www.carpetdyeing.com/commercial, Home Page, 2 Pages. |
PCT International Search Report and Written Opinion, Application No. PCT/US2006/021848, Jul. 20, 2007. |
PCT International Search Report and Written Opinion, Application No. PCT/US2006/021884, Feb. 28, 2007. |
PCT International Search Report and Written Opinion, Application No. PCT/US2006/021885, Oct. 23, 2006. |
Number | Date | Country | |
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20120006213 A1 | Jan 2012 | US |
Number | Date | Country | |
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Parent | 12152405 | May 2008 | US |
Child | 13232354 | US |