The present disclosure relates generally to knitted components and methods of manufacturing knitted components, for example, knitted components for use in footwear applications, apparel applications, or the like.
A variety of articles are formed from textiles. As examples, articles of apparel (e.g., shirts, pants, socks, footwear, jackets and other outerwear, briefs and other undergarments, hats and other headwear), containers (e.g., backpacks, bags), and upholstery for furniture (e.g., chairs, couches, car seats) are often at least partially formed from textiles. These textiles are often formed by weaving or interlooping (e.g., knitting) a yarn or a plurality of yarns, usually through a mechanical process involving looms or knitting machines. One particular object that may be formed from a textile is an upper for an article of footwear.
Knitting is an example of a process that may form a textile. Knitting may generally be classified as either weft knitting or warp knitting. In both weft knitting and warp knitting, one or more yarns are manipulated to form a plurality of intermeshed loops that define a variety of courses and wales.
Although knitting may be performed by hand, the commercial manufacture of knitted components is generally performed by knitting machines. An example of a knitting machine for producing a weft knitted component is a V-bed flat knitting machine, which includes two needle beds that are angled with respect to each other. Rails extend above and parallel to the needle beds and provide attachment points for feeders, which move along the needle beds and supply yarns to needles within the needle beds. Standard feeders have the ability to supply a yarn that is utilized to knit, tuck, and float. In situations where an inlay yarn is incorporated into a knitted component, an inlay feeder is typically utilized.
The embodiments of the present disclosure may be better understood with reference to the following drawings and description. The components in the FIGS. are not necessarily to scale, with emphasis instead being placed upon illustrating the principles of the present disclosure. Moreover, in the figures, like referenced numerals designate similar or identical features in certain instances.
Various aspects are described below with reference to the drawings in which like elements generally are identified by like numerals. The relationship and functioning of the various elements of the aspects may better be understood by reference to the following detailed description. However, aspects are not limited to those illustrated in the drawings or explicitly described below. It also should be understood that the drawings are not necessarily to scale, and in certain instances details may have been omitted that are not necessary for an understanding of aspects disclosed herein, such as conventional fabrication and assembly.
The present embodiments generally relate to textiles. A textile may be defined as a structure manufactured from fibers, filaments, or yarns characterized by flexibility, fineness, and a high ratio of length to thickness. Textiles generally fall into two categories. The first category includes textiles produced directly from webs of filaments or fibers by randomly (or non-randomly) interlocking or interconnecting to construct non-woven fabrics and felts. The second category includes textiles formed through a mechanical manipulation of yarn(s) (e.g., by interlacing or interlooping), thereby producing a woven fabric or a knitting fabric, for example.
Textiles may include one or more yarns. In general, a yarn is defined as an assembly having a substantial length and relatively small cross-section that is formed of at least one filament or a plurality of fibers. Fibers have a relatively short length and require spinning or twisting processes to produce a yarn of suitable length for use in textiles. Common examples of fibers are cotton and wool. Filaments, however, have an indefinite length and may merely be combined with other filaments to produce a yarn suitable for use in textiles. Modern filaments include a plurality of synthetic materials such as rayon, nylon, polyester, and polyacrylic, with silk being the primary, naturally-occurring exception. Yarn may be formed of a single filament, which is conventionally referred to as a “monofilament yarn,” or a plurality of individual filaments grouped together. Yarn may also include separate filaments formed of different materials, or the yarn may include filaments that are each formed of two or more different materials. Similar concepts also apply to yarns formed from fibers. Accordingly, yarns may have a variety of configurations that generally conform to the definition provided above.
While the present embodiments may be formed with any type of textile, the following description is generally related to knitted textiles, or “knitted components.” For example, referring to FIG., certain articles may be at least partially formed as, and potentially fully formed as, a knitted component 100. Advantageously, forming articles that include a knitted component 100 may impart advantageous characteristics including, but not limited to, a particular degree of elasticity (for example, as expressed in terms of Young's modulus), breathability, bendability, strength, moisture absorption, weight, abrasion resistance, and/or a combination thereof. These characteristics may be accomplished by selecting a particular single layer or multi-layer knit structure (e.g., a ribbed knit structure, a single jersey knit structure, or a double jersey knit structure), by varying the size and tension of the knit structure, by using one or more yarns formed of a particular material (e.g., a polyester material, a relatively inelastic material, or a relatively elastic material such as spandex), by selecting yarns of a particular size (e.g., denier), and/or a combination thereof. The weight of the article (e.g., such as an upper 300 as shown in
In some embodiments, and referring to
As described herein, a thermoplastic material (e.g., a thermoplastic polymer) is a substance that may become plastic on heating and hardens when cooling without undergoing a chemical transformation. The thermoplastic polymer may comprise a natural polymeric material, a regenerated material, a synthetic polymeric material, or some combination thereof.
The natural polymeric materials may be either plant-derived or animal-derived. Plant-derived natural polymeric materials may include cotton, flax, hemp, jute, or similar. Animal-derived natural polymeric materials may include spider silk, silkworm silk, sheep wool, alpaca wool, or similar. The regenerated material is created by dissolving the cellulose area of plant fiber in chemicals and making it into fiber again (by viscose method). Since it consists of cellulose like cotton and hemp, it is also called “regenerated cellulose fiber.” The regenerated material may include materials such a rayon and modal, among others.
The synthetic polymeric material may include any of a variety of homopolymers or copolymers or a combination of homopolymers and copolymers. For instance, the thermoplastic polymer may comprise: a thermoplastic polyurethane homopolymer or copolymer; a thermoplastic polyethylene homopolymer or copolymer; a thermoplastic polypropylene homopolymer or copolymer; a thermoplastic polyester homopolymer or copolymer; a thermoplastic polyether homopolymer or copolymer, a thermoplastic polyamide homopolymer or copolymer; or any combination thereof. These may include homopolymers or copolumers of polyethylene terephtalates, ethylene-vinyl acetates, Nylons, such as Nylon 6, Nylon 11, or Nylon 6,6, among others.
Additionally, in other embodiments the thermoplastic material comprises a thermosetting thermoplastic material. As described herein, a thermosetting material may cure when exposed to specific thermosetting conditions at which point the thermosetting thermoplastic material undergoes a chemical change. A thermosetting material is uncured and, thus, may be thermoplastic. The cured thermosetting material has undergone a chemical change and is thermoset. The thermosetting conditions that trigger the thermosetting thermoplastic material to cure may include a specific temperature, an amount of UV light exposure, actinic radiation, microwave radiation, radiowave radiation, electron beam radiation, gamma beam radiation, infrared radiation, ultraviolet light, visible light, or a combination thereof, among other conditions.
In some embodiments, the thermosetting thermoplastic material further comprises a cross-linking agent. As understood in the art, cross-linking agents are chemical products that chemically form bonds between two hydrocarbon chains. The reaction can be either exothermic or endothermic, depending on the cross-linking agent used. One skilled in the art would be able to select any number of appropriate cross-linking agents that would be compatible with the thermoplastic polymer and allow for cross-linking of the thermoplastic material under the desired processing conditions including temperature, pressure, UV light exposure, and the like.
In some instances a suitable cross-linking agent comprises a homobifunctional cross-linking agent. Homobifunctional reagents consist of identical reactive groups on either end of a spacer arm. Examples of homobifunctional cross-linking agents include: dimethyl pimelimidate dihydrochloride, 3,3′-dithiodipropionic acid di(N-hydroxysuccinimide ester), suberic acid bis(3-sulfo-N-hydroxysuccinimide ester) sodium salt, among others.
In other instances, a suitable cross-linking agent comprises a heterobifunctional cross-linking agent. Heterobifunctional cross-linking agents have two distinct reactive groups, allowing for cross-linking reactions to progress in a controlled, two-step reaction. This can reduce the prevalence of dimers and oligomers while crosslinking. Examples of heterobifunctional cross-linking agents include: S-acetylthioglycolic acid N-hydroxysuccinimide ester, 5-azido-2-nitrobenzoic acid N-hydroxysuccinimide ester, 4-azidophenacyl bromide, bromoacetic acid N-hydroxysuccinimide ester, N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride, N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride, N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride, N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride purum, N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride, iodoacetic acid N-hydroxysuccinimide ester powder, among others.
The foamable material of the foamable yarn 102 further comprises a blowing agent. As understood in the art, blowing agents are substances that decompose or vaporize at an activation temperature to produce quantities of gases or vapors. Accordingly, they can be categorized as either chemical or physical blowing agents. A chemical blowing agent is a compound which can release a gas at its activation temperature. Generally, this released gas does not chemically react with the thermoplastic polymer serving as the polymer matrix. The process of evolving gas from the blowing agent is usually exothermic; however, certain compounds that decompose through thermal dissociation, such as bicarbonates, evolve gas in a reversible and endothermic reaction. Chemical blowing agents can be further subcategorized as inorganic and organic agents. Inorganic blowing agents are used mainly in rubber technology but may be used in plastic applications to create additional cross-linking during the blowing process.
A physical blowing agent is a compound which can phase transition to a gas when the temperature, pressure, or temperature and pressure are changed. At a given pressure, the temperature at which the physical blowing agent transitions to a gas is the activation temperature. Physical blowing agents include low-boiling-point hydrocarbons or supercritical fluids.
The choice of blowing agent can influence foam quality, density, homogeneity, and the costs of the foamed product. As discussed below, the characteristic property of these compounds is their decomposition temperature, which determines their practical use as blowing agents for a given thermoplastic material and for its processing conditions. In order for the yarn to be able to form a stable foam, the thermoplastic material must be deformable or plastic at the activation temperature of the blowing agent. To that end, the thermoplastic-material deformation temperature may be lower than the blowing-agent activation temperature.
In some embodiments, the thermoplastic-material deformation temperature is greater than about 10 degrees Celsius below the blowing-agent activation temperature. In some embodiments, the thermoplastic-material deformation temperature is greater than about 20 degrees Celsius below the blowing-agent activation temperature. In other embodiments, the first thermoplastic material 110 has a softening temperature from about 50 degrees Celsius to about 145 degrees Celsius.
In some embodiments, the chemical blowing agent has an activation temperature that is at least 5 degrees Celsius above a melting temperature of the first thermoplastic material. In other embodiments, the activation temperature of the blowing agent is at least 10 degrees Celsius above the melting temperature of the first thermoplastic material. In further embodiments, the activation temperature of the blowing agent is at least 20 degrees above the melting temperature of the first thermoplastic material.
Other properties that may be considered when selecting a chemical blowing agent include the following: affinity with the thermoplastic polymer, maximum production of gases; activation temperature at which the blowing agent evolves gas, rate of gas evolution, toxicity, corrosiveness, odor of decomposition products, effect of decomposition products on the color and other physicochemical properties of the thermoplastic polymer, cost, availability, stability against decomposition during storage, and others.
In some embodiments, the blowing agent comprises a chemical blowing agent. In some embodiments, the chemical blowing agent comprises sodium bicarbonate, ammonium carbonate, ammonium bicarbonate, calcium azide, azodicarbonamide, hydrazocarbonamide, benzenesulfonyl hydrazide, dinitrosopentamethylene tetramine, toluenesulfonyl hydrazide, p,p′-oxybis(benzenesulfonylhydrazide), azobisisobutyronitrile, barium azodicarboxylate, or any combination thereof.
In some embodiments, the blowing agent comprises a physical blowing agent. In addition to partially halogenated fluorochlorohydrocarbons, hydrocarbons (e.g. isobutene and pentane) and inert gases, such as carbon dioxide or nitrogen, can serve as physical blowing agents. Inert gases offer many advantages, including, low environmentally harmful outputs, low gas consumption, increased foam volume per weight of blowing agent used, high cost-effectiveness, non-flammable, non-toxic, chemically inert, minimal or no residues left behind in the polymeric foam after processing. Additionally, carbon dioxide has the advantage of having a higher solubility in many thermoplastic polymers than other inert gases, such nitrogen.
In some embodiments, the blowing agent is present in the first thermoplastic material in an amount effective to foam the first thermoplastic material into a multicellular foam structure when the foamable yarn 102 is processed (as discussed in more detail below). The amount of blowing agent may be measured as the concentration of blowing agent by weight in the thermoplastic material. An amount of blowing agent is considered effective when activating the blowing results in at least a 10 percent increase in the volume of the thermoplastic material.
In some embodiments, more than one blowing agent may be used. The combination of blowing agents may comprise at least two chemical blowing agents, at least two physical blowing agents, or a combination of a physical blowing agent and a chemical blowing agent. Each blowing agent has an activation temperature at the given processing pressure. These activations temperatures may be about the same or may differ. By utilizing blowing agents with different activation temperatures, processing of a foamable yarn into a multicellular foam structure can take place over a larger operation window of temperatures. Additionally, by controlling the temperature to activate a first blowing agent and then increasing the temperature of the foamable yarn to activate the second blowing agent, a variety of different desirable foam structures can be achieved. In some embodiments, two blowing agents may have activation temperatures that differ by at least about 5 degrees Celsius. In some embodiments, two blowing agents may have activation temperatures that differ by at least about 10 degrees Celsius. In some embodiments, two blowing agents may have activation temperatures that differ by at least about 20 degrees Celsius.
A wide range of additives may also be used in the foamable yarn 102. For example, catalysts speed up the reaction or, in some cases, reduce the reaction initiation temperature. As discussed above, blowing agents that form gas bubbles in the polymer or polymerizing mixture produce foam. Surfactants may be added to control the size of bubbles. Other additives that may be used include cross-linking agents, chain-extending agents, fillers, flame retardants and coloring materials (such as dyes or pigments), ultraviolet light absorbers, antioxidants, lubricants, plasticizers, emulsifiers, rheology modifier, odorants, deodorants, or halogen scavenger, depending on the application.
The molecular structure, amount, and reaction temperature of each ingredient determine the characteristics and subsequent use of the foamable yarn 102 after processing. Therefore, each formulation may be designed with the proper ingredients to achieve the desired properties of the final material. By way of an example, different blowing agents may require additional additives to maintain thermal properties. Ultimately, the density of the foam after the foamable yarn 102 is processed is determined by the number and size of the cells, which is affected, at least in part, by the amount of blowing that takes place during processing. By mixing different combinations of the starting materials, the rates of the reactions and overall rate of cure during processing can be controlled.
In some embodiments, the foamable yarn 102 may include a core having a material that is different from the foamable material. Advantageously, the core of the foamable yarn 102 may remain in substantially in-tact when subjected to an amount of heat for processing the yarn such that, even when the foamable material is softened due to its thermoplastic component being heated, the core of the foamable yarn 102 may retain structural integrity such that the core and/or the processing foamable material (and/or resulting foam) remains in a desirable location. Examples of core materials and structure are described in U.S. Provisional Application No. 62/937,092, which is incorporated by reference in the above description.
At least a portion of the foamable yarn 102 may be inlaid between certain loops of the knitted component 100 on a knitting machine during the manufacturing of the knitted component 100. For example, the foamable yarn 102 may be inserted within a course of the knitted component during on a knitting machine, such as by utilizing an inlay process. For example, an inlay process may include using an inlay feeder or other mechanical inlay device on a knitting machine (e.g., a combination feeder) to place the foamable yarn 102 between two needle beds (e.g., front and back needle beds) during a knitting process. One example of an inlay process, along with a combination feeder for enabling such a process, is described in U.S. Patent Application Publication No. 2013/0145652, published Jun. 13, 2013, and having an applicant of NIKE, Inc., which is hereby incorporated by reference in its entirety. While inlaying the foamable yarn 102 may be desirable, it is contemplated that the foamable yarn 102 may be attached to the remainder of the knitted component 100 in a different way, such as by using an adhesive to secure the foamable yarn 102 directly to the exterior surface of the knitted component 100, by embroidering or otherwise sewing the foamable yarn 102 such that it extends through the knitted component 100, etc. Further, while not shown, it is contemplated that the foamable yarn may be included in at least one of the loops forming the courses of the knitted component 100.
Still referring to
Still referring to
Additionally or alternatively, it is contemplated that different knitting techniques may be used to control the amount of surface exposure of the foamable yarns 102. In
As shown in
The second region 204 of
The third region 206 of
The methods and features discussed above may be incorporated into any suitable article. For example,
The resulting exposed length of the foamable yarn 102 may be equal to or greater than the length of a portion of a knitted course comprising at least two consecutive loops, for example, and perhaps much larger (e.g., at least three, four, five, ten, fifteen, or even twenty or more consecutive loops). In metric units, this exposed length may be equal to at least 2 mm, for example, and potentially much larger (e.g., about equal to or greater than 5 mm, 10 mm, 20 mm, or more). The process of
While various embodiments of the present disclosure have been described, the present disclosure is not to be restricted except in light of the attached claims and their equivalents. One skilled in the relevant art will recognize that numerous variations and modifications may be made to the embodiments described above without departing from the scope of the present invention, as defined by the appended claims. Moreover, the advantages described herein are not necessarily the only advantages of the present disclosure and it is not necessarily expected that every embodiment of the present disclosure will achieve all of the advantages described.
The subject-matter of the disclosure may also relate, among others, to the following aspects:
In a 1st aspect. a knitted component, comprises the following: a first area.
where the first area includes a plurality of knit loops comprising a first yarn; and a second yarn at least partially inlaid within the first area of the knitted component such that the second yarn extends between at least a first loop and a second loop of the plurality of knit loops, where the second yarn includes a foamable material comprising a blowing agent and a thermoplastic polymer.
A 2nd aspect includes the knitted component of aspect 1, where the second yarn includes a first portion that is exposed on a first surface in the first area.
A 3rd aspect includes the knitted component of aspect 2, where the first portion has a length that is greater than or equal to the length of a portion of a first course that includes at least three consecutive knit loops, the first course being in the first area.
A 4th aspect includes the knitted component of aspect 2, where the second yarn additionally includes a second portion that is exposed on the first surface in the first area, and where the second yarn includes a covered portion extending from the first portion to the second portion.
A 5th aspect includes the knitted component of aspect 4, where a length of the second portion is larger than a length of the first portion.
A 6th aspect includes the knitted component of aspect 2, where a second course extends through a second area with a second surface, where the second yarn is at least partially inlaid within the second course, and where the second yarn includes a second portion that is exposed on the second surface in the second area.
A 7th aspect includes the knitted component of aspect 6, where the second portion of the second yam includes a length that is larger than a length of the first portion of the second yarn.
An 8th aspect includes the knitted component of any of aspects 1-7, where the first area includes a tubular knit construction having a first layer and a second layer, where at least one of the first layer and the second layer includes the first yarn, and where at least a portion of the second yarn is located within a pocket between the first layer and the second layer.
A 9th aspect includes the knitted component of any of the aspects of aspects 1-8, further comprising a third yarn that is included in at least one loop of a first course, where the third yarn includes a second thermoplastic polymer, and where the second thermoplastic polymer has a melting temperature of about 120 C. or less.
A 10th aspect include a knitted component, comprising: a first area having a first surface, where the first area is at least partially formed by a first knit course, the first knit course having a plurality of loops formed by a first yarn; and a multicellular foam material at least partially surrounding the first yam in in the first area of the knitted component, where the multicellular foam material forms a first protrusion extending from the first surface of the first area.
An 11th aspect includes the knitted component of aspect 10, where the at least one protrusion includes a height of at least 2 mm.
A 12th aspect includes the knitted component of any of aspects 10-11, where the multicellular foam material is the reaction product of foaming at least a portion of a second yarn, the second yarn comprising a first thermoplastic material.
A 13th aspect includes the knitted component of any of aspects 10-12, where the at least one protrusion has a length that is at least 5 mm.
A 14th aspect includes the knitted component of any of aspects 10-13, where the at least one protrusion includes a first foam protrusion and a second foam protrusion, and where the second foam protrusion includes at least 20% more of the multicellular foam material, by mass, than the first foam protrusion.
A 15th aspect includes the knitted component of any of aspects 10-14, where the at least one protrusion includes a first foam protrusion and a second foam protrusion, and where a covered portion of a second yarn extends from the first foam protrusion to the second foam protrusion, the covered portion including at least one of the multicellular foam material and a foamable material with a blowing agent.
A 16th aspect includes the knitted component of any of aspects 10-15, where the covered portion of the second yarn is inlaid through the knitted component.
A 17th aspect includes the knitted component of any of aspects 10-16, further comprising a third yarn that is included in at least one loop of the first knit course, where the third yarn includes a second thermoplastic polymer material, and where the second thermoplastic polymer material having a melting temperature of about 120 C. or less.
An 18th aspect includes a method, comprising: knitting a course with a first yarn, where the course comprises a plurality of loops; inlaying a foamable yarn at least partially within the first course; and transferring a loop of the first course from one needle bed to another needle bed such that at least a portion of the foamable yarn is exposed on a surface of a resulting knitted component.
A 19th aspect includes the method of aspect 18, further comprising heating the knitted component such that the foamable yarn forms at least one foam protrusion on a surface of the knitted component.
A 20th aspect includes the method of any of aspects 18-19, further comprising knitting at least one loop with a fusible yarn that is separate from the foamable yarn, and further comprising heating the fusible yarn such that the fusible yarn deforms when a foamable material of the foamable yarn expands.
This application claims the benefit of four (4) U.S. Provisional Patent Applications: U.S. Provisional Patent Application No. 62/937,133, filed Nov. 18, 2019, U.S. Provisional Patent Application No. 62/937,117, filed Nov. 18, 2019, U.S. Provisional Patent Application No. 62/937,092, filed Nov. 18, 2019, and U.S. Provisional Patent Application No. 62/939,110, filed Nov. 22, 2019. Each patent application listed in this paragraph is hereby incorporated by reference in its entirety.
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