L, R, C method and equipment for continuous casting amorphous, ultracrystallite and crystallite metallic slab or strip

Abstract

This invention discloses an L,R,C method and equipment for casting amorphous, ultracrystallite and crystallite metal slabs or other shaped metals. A workroom (8) with a constant temperature of tb=−190° C. and a constant pressure of pb=1 bar, and liquid nitrogen of −190° C. and 1.877 bar is used as a cold source for cooling the casting blank. A liquid nitrogen ejector (5) ejects said liquid nitrogen to the surface of ferrous or non-ferrous metallic slabs or other shaped metals (7) with various ejection quantity v and various jet velocity k. Ejected liquid nitrogen comes into contact with the casting blank at cross section c shown in FIG. 2. This method adopts ultra thin film ejection technology, with a constant thickness of said film at 2 mm and ejection speed Kmax of said liquid nitrogen at 30 m/s. During the time interval Δτ; corresponding to different cooling rates Vk, a guiding traction mechanism (6) at different continuous casting speed u pulls different lengths Δm of metal from the outlet of the hot casting mold (4). Under the action of heat absorption and gasification of ejected liquid nitrogen, molten metal is solidified and cooled rapidly to form an amorphous, ultracrystallite or crystallite metal structure.

Description

TECHNICAL FIELD OF THE INVENTION

The invention relates to producing amorphous, ultracrystallite or crystallite structure of ferrous and nonferrous alloys by using the technique of rapid solidification, the technique of a low temperature workroom, low temperature liquid nitrogen ejection at high speed and an extremely thin liquid film ejection, and the technique of continuous casting.

EXISTING TECHNIQUES PRIOR TO THE INVENTION

The tensile strength of amorphous metal is higher than that of common metal and a little lower than that of metal filament. The strength of iron filament with a diameter of 1.61 μm reaches 13400 Mpa, which is over 40 times higher than that of industry pure iron. At present, the amorphous metal with highest strength is Fe₈₀B₂₀, and its strength reaches 3630 Mpa. Besides high strength, amorphous metal also has high toughness and special physical properties, such as super conduction property, anti-chemical corrosion property etc. However, in normal conditions, the Young's modulus and shear modulus of amorphous metal are about 30%-40% lower than those of crystal metal, and the Mozam ratio v is high—about 0.4. The tensile strength of amorphous metal greatly depends on temperature. An obvious softening phenomenon appears at the temperature which is near the amorphous transformation temperature T_g. When liquid Al—Cu alloy is sprinkled on a strong cooling base, the cooling rate of the alloy reaches 10⁶° C./S. After solidification, alloy grains obtained have dimensions of less than 1 μm, with tensile strength over 6 times higher than that of the alloy produced by a common casting method. The dimension of a fine grain is 1˜10 μm, resulting in a very detailed microstructure in the fine grain and a great improvement to the mechanical properties of the fine grain.^[1][2][3]

Obviously, producing different brands of amorphous, ultracrystallite and crystallite metallic slabs or other shaped metals of ferrous and nonferrous metal by the method of rapid solidification is very important in civil, military and aerospace industries. However, at present, none of the ferrous or nonferrous companies in the world can do it. The main reasons for this are as follows:

• • 1. The cold source is not strong enough. Generally, the working media of the cold source are air or water, and the working temperature is of atmospheric environment.
  • 2. In the method of continuous casting and directional solidification, the temperature of molten metal is only made to fall rapidly when passing through the liquid-to-solid phase-change region. After solidification, low speed cooling is used. As a result, the temperature of the metal is still very high after solidification. When the dimension of the metal being cast increases, the heat resistance to heat transfer increases, and so is the difficulty of heat dissipation. Rapid solidification cannot proceed.

THE TECHNIQUES OF THE INVENTION

The name of the invention is “the L,R,C method and equipment for casting amorphous, ultracrystallite, crystallite metallic slabs or other shaped metals”.

L—represents low temperature. “L” is the first letter of “Low temperature”.

R—represents rapid solidification. “R” is the first letter of “Rapid solidification”.

C—represents continuous casting. “C” is the first letter of “Continuous casting” (Translator note: this was written in English in the Chinese version as “Continuous foundry”.)

The equipment is a continuous casting machine and the system thereof. The product produced by the L,R,C method and continuous casting system is a metallic slab or other shaped metal of amorphous, ultracrystallite, crystallite, or fine grain. In other words, a metallic slab or other shaped metal of amorphous, ultracrystallite, crystallite or fine grain of ferrous and nonferrous metal can be produced for different brands and specifications using the method of low temperature and rapid solidification with a continuous casting system.

The threshold cooling rate V_k to form metal structures of amorphous, crystallite, and fine grain depends on the type and chemical composition of the metal. According to the references, it is generally considered that:

When molten metal is solidified and cooled at cooling rate V_K, V_K≧10⁷° C./S, amorphous metal can be obtained after solidification. The latent heat L released during solidification of molten metal is =0;

When molten metal is solidified and cooled at cooling rate V_K between 10⁴° C./S and 10⁶° C./S, crystallite metal can be obtained after solidification. The latent heat L released during solidification of molten metal is ≠0;

When molten metal is solidified and cooled at cooling rate V_K=10⁴° C./S, fine grain metal can be obtained after solidification. The latent heat L released during solidification of molten metal is ≠0.

To facilitate the analysis, after the type and the composition of the metal is determined, the production parameters can be calculated according to the range of metal cooling rate V_k used to get the metal structures of amorphous, crystallite, or fine grain. After a production experiment, the production parameters can be modified according to the results.

When molten metal is solidified and cooled at cooling rate V_K=10⁷° C./S or V_K=10⁶° C./S, a metal structure of amorphous or a metal structure of crystallite can be obtained respectively after solidification. If molten metal is solidified and cooled at cooling rate V_K between 10⁶° C./S to 10⁷° C./S, a new metal structure, which is between amorphous metal structure and crystallite metal structure, is obtained, and the new metal structure is named ultracrystallite metal structure herein by the inventor. The estimated tensile strength of the new metal structure should be higher than that of crystallite metal structure and should approach the tensile strength of amorphous metal as the cooling rate V_K increases. However, the Young's modulus, shear modulus and Mozam ratio v of the new structure should approach those of crystallite metal. The tensile strength of the new metal structure is independent of temperature. It can be expected that a metallic slab or other shaped metal of ultracrystallite structure should be a new and more ideal metallic slab or other shaped metal. The present invention will recognize this by doing more experiments and researches in order to develop a new product.

The principle of using the L,R,C method and its continuous casting system to cast metallic slabs or other shaped metals of amorphous, ultracrystallite, crystallite and fine grain are as follows: In order to better describe it, metallic slabs will be used as an example. According to the requirements for producing different types of ferrous and nonferrous metal, different specifications of metallic slabs and different requirements for getting amorphous, ultracrystallite, crystallite, and fine grain structures, the invention provides complete calculating methods, formulae and programs to determine all kinds of important production parameters. The invention also provides the way of using these parameters to design and make continuous casting system to produce the above-mentioned metallic slabs. When using the L,R,C method and its continuous casting system to cast metallic slabs or other shaped metals of amorphous, ultracrystallite, crystallite and fine grain, if we make the shape and dimension of the outlet's cross sections of the hot casting mould (4) shown in FIG. 1 and FIG. 2 the same as those of a desired metallic slab or other shaped metal, the desired metallic slab or other shaped metal can be produced. The production parameters can be determined according to the calculating methods, formulae and calculating programs of metallic slabs or shaped metals.

FIG. 1 is the schematic diagram of the L,R,C method and its continuous casting system used to cast metallic slabs or other shaped metals of amorphous, ultracrystallite, crystallite and fine grain. The size of an airtight workroom (8) with low temperature and low pressure is determined according to the specification of the metallic slab or other shaped metal, and the equipment and devices in the workroom. Firstly, switch on the low temperature refrigerator with three-component and compound refrigeration cycle to drop the room temperature to −140° C., then use other liquid nitrogen ejection devices (not shown in FIG. 1) which do not include liquid nitrogen ejection device (5), to eject the right amount of liquid nitrogen to further drop the room temperature to −190° C. and maintain the room temperature with the workroom pressure P being a little higher than 1 bar. The shape and dimension of the outlet's cross sections of hot casting mould (4) depend on that of the cross sections of metallic slabs or other shaped metals to be produced. Molten metal is poured into the mid-ladle (2) continuously by a casting ladle on the turntable (1). Molten metal (3) is kept at the level shown.

FIG. 2 is a schematic diagram to show the process of molten metal's rapid solidification and cooling at the outlet of the hot casting mould. The electric heater (9) heats up the hot casting mould (4) so that the temperature of the hot casting mould's inner surface, which is in contact with molten metal, is a little higher than the temperature of molten metal's liquidus temperature. As a result, molten metal will not solidify on the inner surface of the hot casting mould. When starting to cast a metallic slab of amorphous, ultracrystallite, crystallite and fine grain continuously using L,R,C method, the first thing to do is to turn the liquid nitrogen ejector (5) on and continuously eject fixed amounts of liquid nitrogen to traction bar (the metallic slab) (7) whose temperature is −190° C. As shown in FIG. 2, the location where the liquid nitrogen being ejected comes into contact with the metallic slab is set at the Cross Section C of the outlet of the hot casting mould. Then, the guidance traction device (6) shown in FIG. 1 is started immediately, and draws the traction bar (7) towards the left as shown in FIG. 1 at a continuous casting speed u. A thin metal minisection of Δm long is drawn out in a time interval Δτ. In order to continuously cast amorphous, ultracrystallite, crystallite and fine grain metallic slabs, molten metal in the minisection of Δm long is solidified and cooled at the initial temperature t₁ until ending temperature t₂, at the same cooling rate V_k in this whole process. The V_k for an amorphous, ultracrystallite, crystallite or fine grain metal structure is 10⁷° C./S, 10⁶° C./S˜10⁷° C./S, 10⁴° C./S˜10⁶° C./S, 10⁴° C./S respectively, where:

t₁—represents the initial solidification temperature of molten metal, ° C.;

t₂—represents the ending cooling temperature, ° C. t₂=−190° C.

For the different cooling rates V_k, mentioned above and molten metal within a length of Δm, the time interval Δτ required for cooling from the initial temperature t₁ until ending temperature t₂ can be calculated by the following formula:

$\begin{array}{cc}\mathrm{\Delta \tau }=\frac{\Delta t}{\mathrm{Vk}}s& \left(1\right)\end{array}$

wherein Δt=t₁−t₂.

The meaning of each symbol has been explained previously.

For a 0.23C low carbon steel, t₁=1550° C., t₂=−190° C. The time interval Δτ required for rapid solidification and cooling in continuous casting of amorphous, ultracrystallite, crystallite and fine grain metal structures are calculated and the results are listed in table 1.

TABLE 1
Δ τ REQUIRED FOR RAPID SOLIDIFICATION
OF DIFFERENT METAL STRUCTURES
Metal
structure	Amorphous	Ultracrystallite	Crystallite	Fine grain
Δ τ s	1.74 × 10−4	1.74 × 10−3~	1.74 × 10−1~	1.74 × 10−1
		1.74 × 10−4	1.74 × 10−3

If the time interval Δτ for drawing out a length of Δm is the same as the time interval Δτ for, molten metal of length Δm to rapidly solidify and cool to form amorphous, ultracrystallite, crystallite and fine grain metal structures, and in the same time interval Δτ, by using gasification to absorb heat, the ejected liquid nitrogen absorbs all the heat produced by molten metal of length Δm during rapid solidification and cooling from initial temperature t₁ to ending temperature t₂, the molten metal of length Δm can be rapidly solidified and cooled to form amorphous, ultracrystallite, crystallite and fine grain structures in the thin metal minisection. In the section with a length of Δm shown in FIG. 2, on the right side of Cross Section A there is molten metal, and cross section b-c is the minisection of the metal which has just left the outlet of the hot casting mould and solidified completely. It can be seen from table 1 that the time interval Δτ of rapid solidification to form amorphous structure of 0.23C carbon steel is only 1.74×10⁻⁴ S, and the time interval Δτ to form fine grain metal structure is only 1.74×10⁻¹ S too. In such a short time interval Δτ, the length of Δm being continuously cast is also of very minimal value. The following calculations show that the Δm for 0.23C amorphous carbon steel is only 0.03 mm, the Δm for ultracrystallite carbon steel is between 0.03 mm and 0.09 mm, the Δm for crystallite carbon steel is between 0.09 mm and 0.3 mm, and the Δm for fine grain is 0.9 mm. According to the theory of heat conduction of flat slabs, if both the length and width exceed the thickness by 10 times, the heat conduction can be deemed to be one dimensional stable-state heat conduction in engineering. That is to say, in using the L,R,C method to continuously cast 0.23C amorphous steel slabs, if all the dimensions of the section are greater than 0.3 mm; and in using the L,R,C method to continuously cast 0.23C ultracrystallite steel slabs, if all the dimensions of the section are greater than 0.3 mm˜0.9 mm; in using the L,R,C method to continuously cast 0.23C crystallite steel slabs, if all the dimensions of the section are greater than 0.9 mm˜3 mm, then heat conduction between Cross Section A and Cross Section C can be considered as one-dimensional stable-state heat conduction. Cross Section a, Cross Section b, Cross Section C and any other sections parallel to them are isothermal surfaces.

FIG. 3 shows the temperature distribution during rapid solidification and cooling of molten metal at the outlet of the hot casting mould. The ordinate is temperature, ° C., and the abscissa is distance, Xmm. Under the powerful cooling action caused by gasification of ejected liquid nitrogen, the temperature of molten metal on Cross Section a falls to initial solidification temperature t₁, which is the liquidus temperature of the metal. The temperature of metal on Cross Section b falls to the metal's solidification temperature t_s, which is the solidus temperature of that metal. The location of Cross Section b is set at the outlet of the hot casting mould. This location can be adjusted through the time difference between the start of liquid nitrogen ejector (5) and the start of guidance traction mechanism (6). The segment with a length of ΔL between Cross Section a and Cross Section b is a region where liquid-solid coexist, and the segment between Cross Section b and Cross Section c is a region of solid state. The temperature of metal at Cross Section c is the solidification ending temperature t₂, which is −190° C. As the process of heat conduction in the whole section with a length of Δm is one-dimensional stable-state heat conduction, the temperature distribution of the metal between Cross Section a and Cross Section c should have a linear feature as shown in FIG. 3. It can be seen that Cross Section b is an interface of solid-liquid state of metal. As metal solidifies on Cross Section b, it is drawn out immediately. Newly molten metal continues to solidify on Cross Section b, and thus amorphous, ultracrystallite, crystallite or fine grain metallic slab can be continuously cast. The solidified metal does not have contact with the hot casting mould. They are kept with each other by the interfacial tension of molten metal and so there is no friction between solid metal and the hot casting mould. This makes it possible to cast metallic slabs with smooth surfaces. On the other hand, as the process of using the L,R,C method to cast amorphous, ultracrystallite, crystallite or fine grain metallic slab proceeds steadily and continuously, the length of the metallic slab being cast continues to increase. However, both the location and temperature of Cross Section c is unchanged: t₂ is still −190° C. Thus, the thermal resistance of the solid metal would not increase, the process of rapid solidification and cooling would not be affected, and the cooling rate V_k of molten metal and solid metal with a length of Δm remains unchanged from the beginning to the end. In addition, to facilitate the description, the length Δm shown in FIG. 2 and FIG. 3 is for illustration and has been magnified. A powerful exhaust system (not shown in FIG. 1, and FIG. 2) is to be set up on the left facing the liquid nitrogen ejector (5) to rapidly release from the workroom all the nitrogen gas produced by gasification of the ejected liquid nitrogen after heat absorption. This ensures that the temperature in the workroom is maintained at a constant temperature of −190° C. and the pressure at a constant a little higher than 1 bar.

DESCRIPTION OF THE ATTACHED DRAWINGS

FIG. 1 is the schematic diagram of the L,R,C method and its continuous casting system used to cast metallic slabs or other shaped metals of amorphous, ultracrystallite, crystallite and fine grain;

FIG. 2 is a drawing that illustrates the principle of molten metal's rapid solidification and cooling process at the outlet of the hot casting mould;

FIG. 3 is a drawing that illustrates the temperature distribution during rapid solidification and cooling of molten metal at the outlet of the hot casing mould.

FIG. 4 is a drawing that illustrates the principle of casting amorphous, ultracrystallite, crystallite and fine grain metallic slabs or other shaped metals through a hot casting mould with an upward outlet, by using the L,R,C method and its continuous casting system.

EMBODIMENT

1. In determining the formulae for calculating the production parameters of the L,R,C method and its continuous casting system.

1) Determine the cooling rate V_k

See above for determining the cooling rate V_k from the production of amorphous, ultracrystallite, crystallite or fine grain metallic slabs.

2) Determine the time interval Δτ of rapid solidification and cooling

See above.

$\begin{array}{cc}\mathrm{\Delta \tau }=\frac{\Delta t}{\mathrm{Vk}}s& \left(1\right)\end{array}$

3) Determine the length Δm of continuous casting in the time interval Δτ

As the heat conduction between Cross Section a and Cross Section c is a one-dimensional stable-state heat conduction, the quantity of heat conduction between Cross Section a and Cross Section b is calculated by the following formula.

$\begin{array}{cc}{Q}_1=\lambda c_{P}A\frac{\Delta t}{\Delta m}w& \left(2\right)\end{array}$

Where:

λ_CP—average thermal conductivity W/m·° C.^[appendix1]

A—area of the cross section perpendicular to the direction of heat conduction m²

Δt—temperature difference between Cross Sections a and c Δt=t₁−t₂° C.

Δm—distance between Cross Sections a and c m

In the time interval Δτ, which corresponds to the cooling rate V_k in getting amorphous, the quantity of heat conduction from Cross Sections a to c is ΔQ₁.ΔQ₁=Q₁Δτ  KJ

Substituting the Δτ in formula (1) into the above formula,

$\begin{array}{cc}\Delta Q_1=Q_1\frac{\Delta t}{\mathrm{Vk}}\mathrm{KJ}& \left(3\right)\end{array}$

FIG. 2 shows the quantity of heat ΔQ₁ which conducts from Cross Section a to c, and the quantity of heat ΔQ₁/2 which conducts to the top or bottom surface of the slab. If the liquid nitrogen ejected to the top and the bottom surface of the slab can absorb the quantity of heat ΔQ₁ through gasification in the time interval Δτ, which corresponds to the cooling rate V_k for getting amorphous, amorphous metallic slabs with a length and a thickness of Δm and E respectively can be cast. Ultracrystallite, crystallite, or fine grain metallic slabs with a length of Δm can be cast according to the same principle. ΔQ₁ is the quantity of heat which is absorbed by the ejected liquid nitrogen through gasification in the time interval Δτ, and so ΔQ₁ is the basis for calculating the quantity of liquid nitrogen ejected in the time interval Δτ.

In the same time interval Δτ, molten metal in Cross Section a moves to Cross Section c where metal cooling has ended. The internal heat energy in molten metal with length Δm and thickness E should be:ΔQ₂=AΔmρ_CP(C_CPΔt+L)  KJ (4)Where

A—area of the cross section perpendicular to the direction of heat conduction m²

• • A=B×E

B—width of metallic slab m

E—thickness of metallic slab m

Δm—length of metal with thickness E which is continuously cast in the time interval Δτ, i.e. distance between Cross Section a and Cross Section c m

ρ_CP—average density of metal g/cm^{3[appendix 1]}

C_CP—average specific heat KJ/Kg° C.^{[appendix 1]}

Δt—the temperature difference between Cross Sections a and c Δt=t₁−t₂° C.

L—latent heat of metal KJ/Kg

For amorphous metal, V_K≧10⁷° C./S, L=0ΔQ₂=BEΔmτ_CPC_CPΔt  KJ (5)For ultracrystallite, crystallite or fine grain metal structure L≠0ΔQ₂=BEΔmτ_CP(C_CPΔt+L)  KJ (6)

If ΔQ₁>ΔQ₂, the heat absorbed by ejected liquid nitrogen is more than internal heat energy in molten metal with length Δm and thickness E. As shown in FIG. 2, in the mid-ladle, the heat of molten metal on the right of Cross Section a at the outlet of the hot casting mould (4) would conduct to Cross Section c so as to compensate for the deficiency of internal heat energy of molten metal with length Δm. Thus, Cross Section b will gradually move towards the right, and finally the outlet of the hot casting mould (4) would be filled with solidified metal, which would stop the continuous casting. There are two ways to solve this problem. One of them is to increase the continuous casting speed u and Δm so that ΔQ₁ decreases and ΔQ₂ increases, until ΔQ₁=ΔQ₂. However this is subject to the limitation of the traction device (6). Another way is to increase the power of the electric heater (9) to compensate for the deficiency of heat for ΔQ₂. However, as additional energy is required, this is obviously not economical.

If ΔQ₁<ΔQ₂, internal heat energy in molten metal with length Δm and thickness E is more than the heat absorbed by ejected liquid nitrogen, part of internal heat energy would remain in molten metal with length Δm, which would affect the rapid solidification and cooling processes. In order to get the expected result of rapid solidification and cooling, the continuous casting speed u and length Δm must be reduced so that ΔQ₁ increases and ΔQ₂ decreases, until ΔQ₁=ΔQ₂.

If ΔQ₁=ΔQ₂, in producing amorphous metal in the time interval Δτ corresponding to cooling rate V_k, ejected liquid nitrogen takes away the quantity of heat ΔQ₁ which conducts from Cross Section a to c. ΔQ₁ is exactly all the internal heat energy ΔQ₂ in molten metal with length and thickness Δm and E respectively. Then, molten metal with length Δm would be rapidly solidified and cooled at the predetermined cooling rate V_k, producing the expected amorphous metallic slabs. By the same token, in producing ultracrystallite, crystallite or fine grain metal, if in the time interval Δτ corresponding to cooling rate V_k, the quantity of heat absorbed ΔQ₁=ΔQ₂, molten metal with length Δm and thickness E would form the expected ultracrystallite, crystallite or fine grain metallic slabs.

Let ΔQ₁=ΔQ₂, substitute ΔQ₁ in formula (3) and ΔQ₂ in formula (4):

$\begin{array}{cc}{\lambda }_{\mathrm{CP}}A\frac{\Delta t}{\Delta m}\Delta \tau =A\Delta m{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}\Delta t\Delta \tau }{{\rho }_{\mathrm{CP}}\left(\mathrm{Ccp}\Delta t+L\right)}}\mathrm{mm}& \left(7\right)\end{array}$

For amorphous metal, L=0

$\begin{array}{cc}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}\Delta \tau }{{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}}}\mathrm{mm}\Delta m=\sqrt{{\alpha }_{\mathrm{CP}}\Delta \tau }& \left(8\right)\end{array}$

Where α_CP—the average thermal conductivity coefficient of metal

$\begin{array}{cc}{\alpha }_{\mathrm{CP}}=\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}}{m}^2\text{/}s& \end{array}$ For ultracrystallite, crystallite or fine grain metal structure, substitute

$\Delta \tau =\frac{\Delta t}{V_k}$ into formula (7):

$\begin{array}{cc}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)V_K}}·\Delta t\mathrm{mm}& \left(9\right)\end{array}$

Formulae (6), (7) and (8) show that Δm depends on parameters such as λ_CP, ρ_CP, C_CP, L, Δt and Δτ, wherein λ_CP, ρ_CP, C_CP and L all being physical parameters of metal, and Δt=t₁−t₂, wherein t₁ being the initial solidification temperature and t₂ being the cooling ending temperature, which is a constant −190° C. So, Δt can also be considered as a physical parameter of metal. These parameters can be determined once the composition of a metallic slab is determined. On the other hand Δτ depends on the metal structure of the slab being produced. For example, if it is decided to produce slabs of amorphous metal structure, the cooling rate V_k is equal to 10⁷° C./S, V_k is thus determined. This indicates that Δτ is determined once the composition and the structure of metal to be produced are determined. It can be seen that Δm depends on two factors. One is the type and composition of the metal and the other is the required metal structure.

4) Determine the continuous casting speed u

For amorphous, ultracrystallite, crystallite and fine grain metal structures, the continuous casting speed u can be obtained from the following formula.

$\begin{array}{cc}u=\frac{\Delta m}{\mathrm{\Delta \tau }}m\text{/}s& \left(10\right)\end{array}$

5) Determine the quantity V of ejected liquid nitrogen

In order to produce slabs of amorphous, ultracrystallite, crystallite or fine grain metal structure, in the time interval Δτ corresponding to the required metal structure, ΔV amount of ejected liquid nitrogen must be able to absorb all the internal heat energy ΔQ₂ of molten metal with thickness E and length Δm by gasification. Accordingly, the quantity ΔV of liquid nitrogen ejected in the time interval Δτ can be calculated with the following formula:

$\begin{array}{cc}\Delta V=\frac{\Delta Q_2}{r}{V}^{\prime }{\mathrm{dm}}^3& \left(11\right)\end{array}$ Where

• • ΔV—quantity of liquid nitrogen ejected in the time interval Δτ dm³
  • r—latent heat of liquid nitrogen
    • the heat energy that 1 Kg of liquid nitrogen absorbed to become gas in the condition of p=1.877 bar, t=−190° C. KJ/Kg
  • V′ specific volume of liquid nitrogen
    • volume of 1 Kg liquid nitrogen in the condition of p=1.877 bar and t=−190 dm³/Kg^{[appendix 2]}
  • ΔQ₂—internal energy in the molten metal with thickness E and length Δm in the time interval Δτ, which is the quantity of heat ΔQ₁ that conducts form Cross Section a to Cross Section c KJ

For amorphous metal, ΔQ₂ can be calculated with formula (5).

For ultracrystallite, crystallite, or fine grain metal, ΔQ₂ can be calculated with formula (6).

Values of r and V′ can be found in Appendix 2. With r and V′, ΔV can be calculated using formula (11). Once ΔV is determined, the quantity of ejected liquid nitrogen V can be calculated with the following formula:

$\begin{array}{cc}V=\frac{\Delta V}{\mathrm{\Delta \tau }}·60{\mathrm{dm}}^3\text{/}\min & \left(12\right)\end{array}$

Where V is the quantity of ejected liquid nitrogen dm³/min

6) Determine the thickness h of the ejected liquid nitrogen layer

The thickness h of the ejected liquid nitrogen layer on the top or bottom surface of the metallic slab can be calculated with the following formula:

$\begin{array}{cc}h=\frac{\Delta V}{2\mathrm{BK}\Delta \tau }\mathrm{mm}& \left(13\right)\end{array}$ where:

h—thickness of ejected liquid nitrogen layer mm

K—ejection speed of liquid nitrogen m/s

B—width of the top and bottom surface plus the converted thickness of the two sides mm

• • ΔV and Δτ as above

7) Determine the volume Vg of gas produced by gasification of volume V of ejected liquid nitrogen

• • After the parameters such as ΔQ₂ and r are determined, V can be calculated with the following formula:

$\begin{array}{cc}{V}_g=\frac{\Delta Q_2}{r}{V}^{″}\frac{60}{\Delta \tau }d{m}^3\text{/}\min & \left(14\right)\end{array}$ Where:

• • Vg—volume of nitrogen gas produced by the gasification of volume V of the ejected liquid nitrogen, in the condition of p=1.877 bar and t=−190° C. dm³/min
  • V″—volume of nitrogen gas produced by the gasification of 1 Kg liquid nitrogen in the condition of p=1.877 bar and t=−190° C. dm³/Kg^{[appendix 2]}
  • ΔQ₂, r and Δτ as above.

The calculated Vg can be used to design the throughput of a powerful exhaust system.

2. Heat conduction within a metallic slab

As shown in FIG. 2, in the process of rapid solidification and cooling, the quantity of heat ΔQ₁ must conduct from the inner of a metallic slab to its surface, and then be taken away from the surface of the slab through gasification of the liquid nitrogen ejected to the surface of the slab. However, can the quantity of heat conduct from the inside to surface of the slab quickly? If it can, then ΔQ₁ does have the possibility of being taken away completely by ejecting liquid nitrogen to the surface of the slab. Obviously, the speed of heat conduction from the inside to the surface of the slab has become a limiting factor.

Because all cross sections a-c between and parallel to Cross Section a and Cross Section c are isothermal surfaces, all cross sections on the left of Cross Section c are also isothermal surfaces with a temperature of −190° C. When the quantity of heat inside the slab conducts through the above-said isothermal surfaces to the surface of the slab, according to the heat conduction formula:Δt=QR_λWhere:

• • Q—quantity of heat conducting through isothermal surfaces, its value depending on quantity of heat conduction of Cross Sections a-c. W
  • Δt—temperature difference of heat conduction between the isothermal surfaces ° C.
  • R_λ—thermal resistance of heat conduction in the isothermal surfaces ° C./W

As there is no temperature difference in isothermal surfaces, Δt=0. Quantity of heat conduction Q depends on ΔQ₂, which means Q depends on the quantity of ejected liquid nitrogen. Therefore, Q≠0, R_λ must be zero, and so R_λ=0.

R_λ=0 infers that when heat conducts through isothermal surfaces from the inside to surface of a slab, there is no thermal resistance in the heat conduction. The metal on the left of Cross Section c is an isothermal surface with a temperature of −190° C., and there is no any thermal resistance for inner heat conducting to the slab surface in any direction. Therefore, on the left of Cross Section c, when the heat inside the slab conducts to the slab's surface, it can conduct completely to the slab's surface duly and rapidly without affecting heat absorption of ejected liquid nitrogen on the slab surface.

3. Application of liquid nitrogen in the L,R,C method and its continuous casting system

Liquid nitrogen is a colorless, transparent and easy-flowing liquid with the properties of a common fluid. In a liquid nitrogen ejecting system, the pressure p and the flowing speed V can be controlled using a common method. When liquid nitrogen approaches its threshold state, abnormal changes of its physical properties will occur, especially the peak value of specific heat C_p and thermal conductivity λ. However, in the process of rapid solidification and cooling, ejected liquid nitrogen is not operating in its threshold region. Thus it is not necessary to consider the abnormal change in its physical properties in threshold state. The standard boiling point of liquid nitrogen is t_boil=−195.81° C., in p=1.013 bar^{[appendix 2]}.

In other studies, when carbon steel is stirred and quenched directly in liquid nitrogen, its hardness is far lower than that of carbon steel quenched in water^[4]. The phenomenon indicates that when a red-hot part is put into liquid nitrogen in a large vessel, liquid nitrogen will absorb heat and gasify rapidly. The nitrogen gas produced in the large vessel will surround the part, thus forming a nitrogen gas layer that separates the part from liquid nitrogen. The gas layer does not conduct heat and becomes a heat insulating layer for the part. As a result, the heat does not dissipate well, the cooling rate drops and the hardness of carbon steel quenched in liquid nitrogen is much lower than that of carbon steel quenched in water.

At pressure p=1 bar, the water in a large vessel is heated until boiling starts, and then the temperature distribution in the water is measured. In the thin water layer of 2-5 mm thickness immediately next to the heating surface, the temperature rises sharply from about 100.6° C. to 109.1° C. Because of the rapid temperature change, a vast temperature gradient close to the wall appears in the water. However, the water temperature outside the thin layer does not vary much. The vast temperature gradient close to the wall makes the boiling heat transfer coefficient α_c of the water far higher than the convective heat transfer coefficient of the water without phase changing. An important conclusion can be drawn from this that the heat transfer from the heating surface to the water and the gasification of the water mainly take place in the thin water layer of 2-5 mm thickness, and the water outside the thin water layer has little effect on that. Furthermore, it is found that such property of vast temperature gradient in the thin layer close to the heating surface exists in all other boiling processes. People begin to use heating methods such as shallow pools, with liquid depth not exceeding 2-5 mm, and flow boiling with the fluid's thickness within 2-5 mm. Both of them produce a more significant temperature gradient close to the wall. This kind of boiling in a low liquid level is called liquid film boiling. As for flow boiling of thin liquid film, because of the effect of the liquid's flow speed, the temperature gradient close to the wall is even larger, resulting in an even higher heat transfer capability of this kind of flow boiling of thin liquid film. In order to utilize the effect of high flow speed, some studies use water at high flow speed of 30 m/s, flowing into a cylindrical pipe with a diameter of 5 mm, achieving q_w=1.73×10⁸ W/m^{2 [5]}.

Based on the analysis for the above data, the L,R,C method uses the technology of ejection heat transfer with high ejection speed and extremely thin liquid film. In the following formula:

$\begin{array}{cc}h=\frac{\Delta V}{2\mathrm{BK}\Delta \tau }\mathrm{mm}& \left(13\right)\end{array}$ The meaning of the symbols in the formula is provided above.

After determining Δτ and ΔV, raising liquid nitrogen's ejection speed K to 30 m/s or higher and keeping the ejected liquid nitrogen layer's thickness h within 2-3 mm or even 1-2 mm can realize high ejection speed and extreme thin liquid film ejection technology.

At the outlet of the liquid nitrogen ejector (5) shown in FIG. 2, the parameters relating to ejected liquid nitrogen and workroom (8) are as follows:

• • p—liquid nitrogen's ejection pressure p=1.887 bar
  • t—temperature of liquid nitrogen t=−190° C.
  • Kmax—liquid nitrogen's maximum ejection speed Kmax=30 m/s
  • h—thickness of ejected liquid nitrogen layer h=2˜3 mm or 1-2 mm
  • P_b—pressure of the workroom P_b=1 bar
  • t_b—temperature of the workroom t_b=−190° C.

Liquid nitrogen is ejected from the ejector (5)'s outlet, which has a height of 2-3 mm or 1-2 mm, into the whole of the workroom space. Since the jet stream of liquid nitrogen is very thin and the its speed is extremely high, when the jet beam reaches the slab after a short distance, the pressure of the whole cross section of the jet beam from edge to center drops rapidly from 1.887 bar to 1 bar. At this pressure, the saturated temperature of liquid nitrogen is also its boiling temperature t_boil, t_boil=−195.81° C.^{[appendix 2]}. However, the temperature of ejected liquid nitrogen is still t=−190° C., which is higher than the boiling temperature. So, liquid nitrogen is in the boiling state. When heat conducts therein, liquid nitrogen can be gasified rapidly. The gasification speed relates to the temperature difference between the liquid nitrogen's temperature and the boiling point temperature. At present, the temperature difference is 5.75° C. If the temperature difference further increases, the speed of liquid nitrogen's gasification will be even higher.

When the above mentioned ejected liquid nitrogen's pressure falls from 1.887 bar to 1 bar, the liquid nitrogen's temperature is still higher than the saturated temperature (boiling point temperature) at pressure 1 bar^[6]. This conforms to the physical condition of volume boiling. As long as the heat supply is sufficient, equal phase gasification will occur to the whole of the ejected liquid nitrogen layer instantly. Naturally, a nitrogen gas layer isolating ejected liquid nitrogen will not occur.

The liquid nitrogen's flowing speed is set up at up to 30 m/s and the thickness of the ejected liquid nitrogen layer is controlled at only 2-3 mm, or even 1-2 mm. The purpose is to make the thin layer with high flowing speed to be exactly the thin layer which exhibits extremely high temperature gradient close to the wall. Thus, the whole thin layer of liquid nitrogen is within the extremely high temperature gradient close to the wall and takes part in the strong heat transfer. Furthermore, the high flowing speed makes the heat transfer even stronger, causing all liquid nitrogen in the thin layer to absorb heat and gasify. The evaporation produced in gasification is taken away rapidly by an exhaust system so that even in the bottom surface of a metal slab, there is no nitrogen gas layer to isolate ejected liquid nitrogen. It can be seen that the effects of rapid solidification and cooling from ejected liquid nitrogen are the same at the top or bottom surface. The temperature of the metal slab's surfaces also affects the temperature close to the wall and the strength of heat transfer.

From the above analysis, it can be seen that: in the L,R,C method and its continuous casting system, by using high ejection speed and extremely thin liquid film ejection technology, ejected liquid nitrogen through heat absorption and gasification takes away ΔQ of heat in the required time interval Δτ, without forming any nitrogen layer that isolates ejected liquid nitrogen on the metal slab's surface.

4. Heat exchange between ejected liquid nitrogen and metal slab

When the L,R,C continuous casting system begins casting, as shown in FIG. 2, ejected liquid nitrogen will come into contact with the metal slab at Cross Section c. In the beginning of casting, the temperatures of the metal slab and ejected liquid nitrogen are both −190° C. So at the beginning instant of the time interval Δτ, there is no heat exchange between liquid nitrogen and the metal slab. However, after an extremely short interval in the time interval Δτ, a small portion of the quantity of heat ΔQ₁/2 gets transmitted to the slab's surface at the contact point. The temperature of the slab's surface immediately rises rapidly, thus creating a temperature difference between liquid nitrogen and the slab's surface. Liquid nitrogen begins to exchange heat with the slab's surface and takes away this portion of heat through gasification, so that the temperature of the slab's surface drops to −190° C. immediately. It is also in such an extremely short time interval that all nitrogen produced by gasification of liquid nitrogen ejected to the contact point is taken away from the workroom (8) by a powerful exhaust system. This extremely short time interval within the time interval Δτ is followed by another extremely short time interval, during which the metal slab moves left for another extremely short distance, New liquid nitrogen is then ejected onto the newly arrived portion of the slab's surface. Heat exchange between liquid nitrogen and the slab repeats itself in the above-mentioned process. After the time interval Δτ, ejected liquid nitrogen eventually takes away ΔQ₁/2 of heat. Because a metal slab has a top and a bottom surface, ejected liquid nitrogen eventually takes away all ΔQ₁. of heat. Rapid solidification and cooling will proceed as anticipated, eventually producing metallic slabs of amorphous, ultracrystallite, crystallite and fine grain metal structures.

It is possible that the actual situation of heat exchange between liquid nitrogen and a metallic slab is a little different from the above mentioned, and the final cooling ending temperature t₂ of a slab is 10-20° C. higher than −190° C., i.e. t₂=−180° C. 170° C. However, this will not affect the production of metallic slabs of amorphous, ultracrystallite, crystallite and fine grain metal structures. The final temperature of the metallic slab will still be 190° C.

Lastly, the working pressure of the workroom (8), p_b=1 bar, should be kept constant by a powerful air exhaust system. The working temperature t_b=−190° C. can be adjusted according to the results of a production trial.

5. Formulae for calculating production parameters in casting amorphous, ultracrystallite, crystallite and fine grain metal slabs with maximum thickness E_Max

The object in research is a metal slab with width B=1 m.

The thickness h of the ejected liquid nitrogen layer is determined as h=2 mm and kept constant. Under the dual action of an extremely high temperature gradient close to the wall and volume gasification of equal phase, which is caused by a pressure reduction of ejected liquid nitrogen, all the ejected liquid nitrogen layer with h=2 mm can absorb heat and gasify to produce amorphous, ultracrystallite, crystallite and fine grain metal slabs. If h>2 mm, slabs of metal structure cast may not meet the requirements. If h is kept constant at 2 mm, the ejection nozzle of the liquid nitrogen ejector (5) will not need to replace as its size is fixed.

The maximum ejection speed K_max of liquid nitrogen is determined as K_max=30 m/s. When B=1 m, h=2 mm, and K_max=30 m/s, the liquid nitrogen ejector (5) ejects a maximum quantity of V_max of liquid nitrogen. Under the action of this quantity of liquid nitrogen, amorphous, ultracrystallite, crystallite or fine grain metal slabs of maximum thickness E_max can be continuously cast.

Detailed calculation as follows:

1) Determine cooling rate V_k

Different cooling rates V_k are determined according to whether amorphous, ultracrystallite, crystallite or fine grain metal structure is required.

2) Calculate the time interval Δτ of rapid solidification and cooling

Δt is calculated with formula (1)

$\begin{array}{cc}\Delta \tau =\frac{\Delta t}{V_K}s& \left(1\right)\end{array}$

3) Calculate the length Δm of slabs cast in the time interval Δτ

For amorphous metal structure, Δm is calculated with formula (8)

$\begin{array}{cc}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}}\Delta \tau }\mathrm{mm}& \left(8\right)\end{array}$

For ultracrystallite, crystallite and fine grain metal structure, Δm is calculated with formula (9)

$\begin{array}{cc}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)V_K}}·\Delta \tau \mathrm{mm}& \left(9\right)\end{array}$

4) Calculate the continuous casting speed u

u is calculated with formula (10)

$\begin{array}{cc}u=\frac{\Delta m}{\Delta t}m\text{/}s& \left(10\right)\end{array}$

Parameters Vk, Δτ, Δm, and u only depend on the thermophysical properties of metal and the different amorphous, ultracrystallite, crystallite and fine grain metal structures. They are independent of the thickness of a metal slab. After the type and composition of a metal and the desired metal structure are determined, the values of parameters Vk, Δτ, Δm, and u are also determined. Changing the thickness of a metal slab would not affect these values.

5) Calculate ΔV_max

When the maximum ejection speed of liquid nitrogen K_max=30 m/s, the thickness of the ejected liquid nitrogen layer h=2 mm and the width of the metallic slab B=1 m are kept constant, ΔV_max is the volume of liquid nitrogen ejected by liquid nitrogen ejector (5) in the time interval Δτ. This volume of ejected liquid nitrogen is the maximum volume of ejected liquid nitrogen in the time interval Δτ. ΔV_max can be calculated with formula (13). Substitute ΔV with ΔV_max in formula (13) to become formula (15), from which ΔV_max can be calculated.ΔVmax=2BKmaxΔτh dm³  (15)

6) Calculate ΔQ_2max

ΔQ_2max is the quantity of heat absorbed by the maximum ejection volume ΔV_max of liquid nitrogen during complete gasification. Substitute ΔV and ΔQ with ΔV_max and ΔQ_2max respectively in formula (11) to become formula (16), from which the value of ΔQ_2max can be calculated.

$\begin{array}{cc}\Delta Q_{2\max }=\frac{\Delta V_{\max }r}{V^{\prime }}\mathrm{KJ}& \left(16\right)\end{array}$

7) Calculate the maximum thickness E_max of an amorphous, ultracrystallite, crystallite or fine grain metal slab

Q_2max is the maximum ejection volume ΔV_max of liquid nitrogen during complete gasification, and is also the internal heat energy contained in molten metal of an amorphous, ultracrystallite, crystallite or fine grain metal slab with length Δm. Therefore, the maximum thickness E_max), can be calculated with the following formulae.

For amorphous metal slabs, substitute ΔQ₂ and E with ΔQ_2max and E_max respectively in formula (5) to become formula (17), from which the value of E_max can be calculated.

$\begin{array}{cc}{E}_{\max }=\frac{\Delta Q_{2\max }}{B\Delta m{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}\Delta t}\mathrm{mm}& \left(17\right)\end{array}$

For ultracrystallite, crystallite or fine grain metal slabs substitute ΔQ₂ and E with ΔQ_2max and E_max respectively in formula (6) to become formula (18), from which the value of E_max can be calculated.

$\begin{array}{cc}{E}_{\max }=\frac{\Delta Q_{2\max }}{B\Delta m{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)}\mathrm{mm}& \left(18\right)\end{array}$

8) Calculate V_max

Substitute V and ΔV with ΔQ_2max and E_max respectively in formula (12) to become formula (19), from which the value of V_max can be calculated.

$\begin{array}{cc}{V}_{\max }=\frac{\Delta V_{\max }}{\Delta \tau }·60{\mathrm{dm}}^3\text{/}\min & \left(19\right)\end{array}$

Substitute formula (15) into the above formula:V_max=120BK_maxh dm³/min  (19)′

When B, E_max and h are constant, E_max is also constant.

9) Calculate V_gmax

Substitute V_g and ΔQ₂ with V_gmax and ΔQ_2max respectively in formula (14) to become formula (20), from which the value of V_gmax can be calculated.

$\begin{array}{cc}{V}_{g\max }=\frac{\Delta Q_{2\max }}{r}{V}^{″}\frac{60}{\Delta \tau }{\mathrm{dm}}^3\text{/}\min & \left(20\right)\end{array}$

Substitute the formula for calculating ΔQ₂max into the above formula, after simplification:

$\begin{array}{cc}{V}_{g\max }=\frac{120{\mathrm{BK}}_{\max }h}{V^{\prime }}{V}^{″}{\mathrm{dm}}^3\text{/}\min & {\left(20\right)}^{\prime }\end{array}$

V′ and V″ are parameters of the thermophysical properties of liquid nitrogen. They vary with temperature t. When the temperature of liquid nitrogen t is −190° C., the V′ and V″ are also determined. If B, K_max and h are constant, Vmax will also be constant.

6. Formulae for calculating the production parameters for casting an amorphous, ultracrystallite, crystallite and fine grain metal slab with thickness E.

From the above, parameters V_k, Δτ, Δm and u are independent of a metal slab's thickness. Their values are still the same as the values in casting an amorphous, ultracrystallite, crystallite and fine grain metallic slab with maximum thickness E_max. However, parameters ΔV, ΔQ₂, V, V_g, which are dependent of quantity of heat, will decrease along with the thickness of a slab with length Δm from E_max to E, and the quantity of molten metal and internal heat energy. Their calculations are as follows:

1) Calculate the proportional coefficient X.

$\begin{array}{cc}X=\frac{E_{\max }}{E}& \left(21\right)\end{array}$ Where

E_max—maximum thickness of an amorphous, ultracrystallite, crystallite or fine grain metal slab mm;

E—thickness of an amorphous, ultracrystallite, crystallite or fine grain metal slab mm.

X—the proportional coefficient.

2) Calculate ΔQ₂, ΔV, V and Vg

Because the internal heat energy in molten metal with length Δm is directly proportional to the thickness of the metal slab, the following formula is tenable.

$\begin{array}{cc}X=\frac{\Delta Q_{2\max }}{\Delta Q_2}=\frac{\Delta V_{\max }}{\Delta V}=\frac{V_{\max }}{V}=\frac{V_{g\max }}{V_g}& \left(22\right)\end{array}$

3) Calculate the liquid nitrogen's ejection speed K

If the liquid nitrogen layer's thickness h=2 mm is kept constant, the liquid nitrogen's ejection speed will drop from K_max to K when the quantity of ejected liquid nitrogen drops from V_max to V. The relationship between K_max and K conforms to formula (23).

$\begin{array}{cc}X=\frac{K_{\max }}{K}& \left(23\right)\end{array}$

The above formula indicates that by using the proportional coefficient formulae (21), (22) and (23), the production parameters for amorphous, ultracrystallite, crystallite and fine grain metal slabs with thickness E can be calculated with parameters relating to E_max.

According to the above formulae, the production parameters for different metal types and thickness of amorphous, ultracrystallite, crystallite or fine grain metal slabs can be calculated. The calculated results can be used for a production trial and the design and manufacture of the L,R,C method continuous casting system to produce the desired slabs.

In order to illustrate how to determine the production parameters and how to organize production for casting amorphous, ultracrystallite, crystallite and fine grain metal slab through the L,R,C method and its continuous casting system using the calculation formulae, the 0.23C steel slab with width B=1 m and the aluminum slab with width B=1 m are used as ferrous and nonferrous examples respectively to illustrate how to apply the formulae to determine the production parameters and how to organize production.

7. Casting amorphous, ultracrystallite, crystallite and fine grain steel slabs using the L,R,C method and its continuous casting system, and the determination of the production parameters.

The relevant parameters and the thermal parameters of the 0.23C steel slabs are as follows:

B—width of the steel slab, B=1 m

E—thickness of the steel slab, E=Xm

L—the latent heat, L=310 KJ/Kg

λ_CP—average thermal conductivity, λ_CP=36.5×10⁻³ KJ/m·° C.s^{[appendix 1]}

ρ_CP—average density, τ_CP=7.86×10³ Kg/m^{3[appendix 1]}

C_CP—average specific heat, C_CP=0.822 KJ/Kg° C.^{[appendix 1]}

t₁—initial solidification temperature, t₁=1550° C.

t₂—ending solidification and cooling temperature, t₂=−190° C.

The thermal parameters of liquid nitrogen are as follows^[appendix2]

TABLE 2
The thermal parameters of liquid nitrogen
t ° C.	p bar	V′ dm3/Kg	V″ dm3/Kg	r KJ/Kg
−190	1.877	1.281	122.3	190.7

In the table

t—temperature of liquid nitrogen, ° C., t=−190° C.

p—pressure of the liquid nitrogen at t=−190° C., bar, p=1.877 bar

V′—volume of 1 Kg liquid nitrogen at t=−190° C. and p=1.877 bar, dm³/Kg

V″—volume of 1 Kg nitrogen gas at t=−190° C. and p=1.877 bar, dm³/Kg

r—the latent heat at t=−190° C. and p=1.877 bar; that is, the quantity of heat which is absorbed when 1 Kg liquid nitrogen is gasified at t=−190° C. and p=1.877 bar, KJ/Kg

1) Using the L,R,C method and its continuous casting system to cast 0.23C amorphous steel slab and the determination of the production parameters

1.1) Using the L,R,C method and its continuous casting system to cast 0.23C amorphous steel slab of maximum thickness E_max, and the determination of the production parameters

(1) Determine the cooling rate V_k in the whole solidification and cooling process of the 0.23C amorphous slab

• • Let V_K=10⁷° C./s

(2) Calculate Δτ

Substitute the data of V_K, t₁, t₂ into the formula (1) to get

$\begin{array}{c}\Delta \tau =\frac{t_1-t_2}{V_K}\\ =\frac{1550-\left(-190\right)}{{10}^7}\\ =1.74\times {10}^{-4}s\end{array}$

(3) Calculate Δm

For amorphous steel slabs, Δm is calculated with formula (8)

$\begin{array}{c}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}}\Delta \tau }\\ =\sqrt{\frac{36.5\times {10}^{-3}}{7.86\times {10}^3\times 0.822}\times 1.74\times {10}^{-4}}\\ =0.03135\mathrm{mm}\end{array}$

(4) Calculate u

u is calculated with formula (10)

$\begin{array}{c}u=\frac{\Delta m}{\Delta \tau }\\ =\frac{0.03135}{1.74\times {10}^{-4}}\\ =10.81m/\min \end{array}$

(5) Calculate ΔV_max,

ΔV_max is calculated with formula (15)

• • Let K_max=30 m/sΔV_max=2BK_maxΔτh=2×1×10³×30×10³×1.74×10⁻⁴×2=0.02088 dm³

(6) Calculate ΔQ_2max

ΔQ_2max is calculated with formula (16)

$\begin{array}{c}\Delta Q_{2\max }=\frac{\Delta V_{\max }r}{V^{\prime }}\\ =\frac{0.02088\times 190.7}{1.281}\\ =3.1084\mathrm{KJ}\end{array}$

(7) Calculate E_max

E_max is calculated with formula (17)

$\begin{array}{c}{E}_{\max }=\frac{\Delta Q_{2\max }}{B\Delta m{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}\Delta t}\\ =\frac{3.1084}{100\times 0.003135\times 7.8\times {10}^{-3}\times 0.822\times 1740}\\ =8.9\mathrm{mm}\end{array}$

(8) Calculate V_max

V_max is calculated with formula (19),V_max=120BK_maxh=120×1×10³×30×10³×2=7200 dm³/min

(9) Calculate V_gmax

V_gmax is calculated with formula (20),

$\begin{array}{c}{V}_{g\max }=\frac{120{\mathrm{BK}}_{\max }h}{V^{\prime }}{V}^{″}\\ =\frac{120\times 1\times {10}^3\times 30\times {10}^3\times 2}{1.281}\times 122.3\\ =687400.5{\mathrm{dm}}^3/\min \end{array}$

The above calculation indicates that when liquid nitrogen in liquid nitrogen ejector (5) is ejected to the 0.23C steel slab at the outlet of the hot casting mould (4) with an ejection layer of thickness h=2 mm, a maximum ejection speed of K_max=30 m/S and a maximum ejection quantity of V_max=7200 dm³/min, the guidance traction device (6) draws the slabs to leave the outlet of the hot casing mould (4) with a continuous casting speed u=10.81 m/min. The L,R,C method and its continuous casting system can make molten metal with temperature t₁=1550° C., cross section 1000×8.9 mm² and length Δm=0.03135 mm solidified and cooled to t₂=−190° C. at a cooling rate V_K=10⁷° C./S and finally continuously casting a 0.23C amorphous steel slab with maximum thickness E_max=8.9 mm and width B=1000 mm.

1.2) Using the L,R,C method and its continuous casting system to cast a 0.23C amorphous steel slab of thickness E and the determination of the production parameters

(1) Let E=5 mm. The values of parameters V_k, Δτ, Δm, u corresponding to E=5 mm are the same as those corresponding to E_max=8.9 mm. That is, V_k=10⁷° C./S, Δτ=1.74×10⁻⁴ s, Δm=0.03135 mm, u=10.81 m/min.

(2) Calculate X

X is calculated with formula (21).

$\begin{array}{c}X=\frac{E_{\max }}{E}\\ =\frac{8.9}{5}\\ =1.78\end{array}$

(3) Calculate ΔV

ΔV is calculated with formula (22)

$\begin{array}{c}\Delta V=\frac{V_{\max }}{V}\\ =\frac{0.02088}{1.78}\\ =0.01173{\mathrm{dm}}^3\end{array}$

(4) Calculate ΔQ₂

ΔQ₂ is calculated with formula (22)

$\begin{array}{c}\Delta Q_2=\frac{\Delta Q_{2\max }}{X}\\ =\frac{3.1084}{1.78}\\ =1.746\mathrm{KJ}\end{array}$

(5) Calculate V

V is calculated with formula (22)

$\begin{array}{c}V=\frac{V_{\max }}{X}\\ =\frac{7200}{1.78}\\ =4044.9{\mathrm{dm}}^3/\min \end{array}$

(6) Calculate V_g

V_g is calculated with formula (22)

$\begin{array}{c}{V}_g=\frac{V_{g\max }}{X}\\ =\frac{687400.5}{1.78}\\ =386180.1{\mathrm{dm}}^3/\min \end{array}$

(7) Calculate K

K is calculated with formula (23)

$\begin{array}{c}K=\frac{K_{\max }}{X}\\ =\frac{30}{1.78}\\ =16.9m/s\end{array}$

The above calculation indicates that when the continuous casting speed u is fixed at 10.81 m/min and the thickness of ejected liquid nitrogen layer is fixed at 2 mm, the ejected quantity of liquid nitrogen falls to V=4044.9 dm³/min, and the corresponding liquid nitrogen's ejection speed drops to K=16.9 m/s. This will cast E=5 mm thick 0.23C amorphous steel slabs continuously.

2) Using the L,R,C method and its continuous casting system to cast 0.23C ultracrystallite steel slab and the determination of the production parameters

In the study on continuous casting of 0.23C ultracrystallite steel slab, the production parameters for producing slabs with maximum thickness E_max or other thickness E is explored at different cooling rates V_k. The combination of cooling rates V_k used are 2×10⁶° C./s, 4×10⁶° C./s, 6×10⁶° C./s, or 8×10⁶° C./s respectively.

2.1) Determining the maximum thickness E_max when using the L,R,C method and its continuous casting system to cast 0.23C ultracrystallite steel slabs at cooling rates V_k=2×10⁶° C./s, and the determination of the production parameters

Let K_max=30 m/s and h=2 mm remain constant, and V_K=2×10⁶° C./s.

(1) Calculate Δτ

Δτ is calculated with formula (1).

$\begin{array}{c}\Delta \tau =\frac{t_1-t_2}{V_K}\\ =\frac{1550-\left(-190\right)}{2\times {10}^6}\\ =8.7\times {10}^{-4}s\end{array}$

(2) Calculate Δm

For ultracrystallite steel slabs, latent heat exists in the solidification process, and Δm is calculated with formula (9).

$\begin{array}{c}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)V_K}·}\Delta t\\ =\sqrt{\frac{36.5\times {10}^{-3}}{7.86\times {10}^3\left(0.822\times 1740+310\right)\times 2\times {10}^6}}\times 1740\\ =0.0636\mathrm{mm}\end{array}$

(3) Calculate u

u is calculated with formula (10)

$\begin{array}{c}u=\frac{\Delta m}{\Delta \tau }\\ =\frac{0.0636}{8.7\times {10}^{-4}}\\ =4.39m/\min \end{array}$

(4) Calculate ΔV_max

ΔV_max is calculated with formula (15).ΔV_max=2BK_maxΔτh=2×1×10³×30×10³×8.7×10⁻⁴×2=0.1044 dm³

(5) Calculate ΔQ_2max

ΔQ_2max is calculated with formula (16)

$\begin{array}{c}\Delta Q_{2\max }=\frac{\Delta V_{\max }r}{V^{\prime }}\\ =\frac{0.1044\times 190.7}{1.281}\\ =15.55\mathrm{KJ}\end{array}$

(6) Calculate E_max

For ultracrystallite steel slabs, E_max is calculated with formula (18)

$\begin{array}{c}{E}_{\max }=\frac{\Delta Q_{2\max }}{B\Delta m{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)}\\ =\frac{15.55}{100\times 0.00636\times 7.8\times {10}^{-3}\left(0.822\times 1740+310\right)}\\ =18\mathrm{mm}\end{array}$

(7) Calculate V_max

V_max is calculated with formula (19)′V_max=120BK_maxh=120×1×10³×30×10³×2=7200 dm³/min

(8) Calculate V_gmax

V_gmax is calculated with formula (20)′

$\begin{array}{c}{V}_{g\max }=\frac{120{\mathrm{BK}}_{\max }h}{V^{\prime }}{V}^{″}\\ =\frac{120\times 1\times {10}^3\times 30\times {10}^3\times 2}{1.281}\times 122.3\\ =687400.5{\mathrm{dm}}^3/\min \end{array}$

2.2) Using the L,R,C method and its continuous casting system to cast 0.23C ultracrystallite steel slabs with cooling rate V_k=2×10⁶° C./s and thickness E, and the determination of the production parameters

(1) Let E=15 mm. The values of parameters V_k, Δτ, Δm, u corresponding to E=15 mm are the same as those corresponding to E_max=18 mm. That is, V_k=2×10⁶° C./s, Δτ=8.7×10⁻⁴ S. Δm=0.0636 mm, u=4.39 m/min.

(2) Calculate X

X is calculated with formula (21)

$\begin{array}{c}X=\frac{E_{\max }}{E}\\ =\frac{18}{15}\\ =1.2\end{array}$

(3) Calculate ΔV

ΔV is calculated with formula (22)

$\begin{array}{c}\Delta V=\frac{V_{\max }}{X}\\ =\frac{0.1044}{1.2}\\ =0.087{\mathrm{dm}}^3\end{array}$

(4) Calculate ΔQ₂

ΔQ₂ is calculated with formula (22)

$\begin{array}{c}\Delta Q_2=\frac{\Delta Q_{2\max }}{X}\\ =\frac{15.55}{1.2}\\ =12.96\mathrm{KJ}\end{array}$

(5) Calculate V

V is calculated with formula (22)

$\begin{array}{c}V=\frac{V_{\max }}{X}\\ =\frac{7200}{1.2}\\ =6000{\mathrm{dm}}^3/\min \end{array}$

(6) Calculate V_g

V_g is calculated with formula (22)

$\begin{array}{c}{V}_g=\frac{V_{g\max }}{X}\\ =\frac{687400.5}{1.2}\\ =572833.8{\mathrm{dm}}^3/\min \end{array}$

(7) Calculate K

K is calculated with formula (23)

$\begin{array}{c}K=\frac{K_{\max }}{X}\\ =\frac{30}{1.2}\\ =25m\text{/}s\end{array}$

The formulae (programs) used for calculating the production parameters at other cooling rates combinations V_k to produce 0.23C ultracrystallite steel slabs with maximum thickness E_max or other thickness E are the same as those for cooling rate V_k=2×10⁶° C./s. The calculation results are listed in table 3, table 4, table 5, table 6, table 7 and table 8. The calculation process will not be repeated herein.

3) Using the L,R,C method and its continuous casting system to cast 0.23C crystallite steel slabs at maximum thickness E_max or other thickness E and the determination of the production parameters

The range of cooling rates V_k for crystallite structures is V_k≧10⁴° C./s˜10⁶° C./s. Steel slabs which are continuously cast at cooling rate V_k=10⁶° C./s in solidification and cooling are called Crystallite Steel Slab A. Steel slab which are continuously cast at cooling rate V_k=10⁵° C./s in solidification and cooling are called Crystallite Steel Slab B. The L,R,C method and its continuous machine system's production parameters used to continuously cast Crystallite Steel Slab A and Crystallite Steel Slab B with maximum thickness E_max or other thickness E are calculated. The application of the calculation programs and formula is the same as those for ultracrystallite steel slabs. The relevant production parameters are listed in table 3, table 4, table 5, table 6, table 7 and table 8. The calculating process will not be repeated herein.

4) Using the L,R,C method and its continuous casting system to cast 0.23C fine grain steel slabs at maximum thickness E_max or other thickness E and the determination of the production parameters

The range of cooling rates V_k for fine grain structure is V_k≦10⁴° C./s. The relevant production parameters are listed in table 3, table 4, table 5, table 6, table 7 and table 8. The calculating process will not be repeated herein.

TABLE 3
Maximum thickness Emax and the production parameters of 0.23 C amorphous,
ultracrystallite, crystallite and fine grain steel slabs (B = 1 m, Kmax = 30 m/s, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	Grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
Δτ	s	1.74 × 10−4	2.175 × 10−4	2.9 × 10−4	4.35 × 10−4	8.7 × 10−4	1.74 × 10−3	1.74 × 10−2	1.74 × 10−1
Δm	mm	0.03135	0.0318	0.0367	0.0449	0.0636	0.0899	0.284	0.899
u	m/min	10.81	8.77	7.59	6.20	4.39	3.1	0.98	0.31
ΔVmax	dm3	0.02088	0.0261	0.0348	0.0522	0.1044	0.209	2.09	20.9
ΔQ2max	KJ	3.1084	3.89	5.18	7.771	15.54	31.113	311.13	3111.3
Emax	mm	8.9	9	10.4	12.8	18	25.5	80.6	255
Vmax	dm3/min	7200	7200	7200	7200	7200	7200	7200	7200
Vgmax	dm3/min	687400.5	687400.5	687400.5	687400.5	687400.5	687400.5	687400.5	687400.5

TABLE 4
E =20 mm, the production parameters of 0.23 C amorphous,
ultracrystallite, crystallite and fine grain steel slabs (B = 1 m, h = 2 mm)
	Metal structure
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	Fine grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	10.81	8.77	7.59	6.20	4.39	3.1	0.98	0.31
X							1.275	4.03	12.75
V	dm3/min						5647.1	1786.6	564.7
K	m/s						23.53	7.4	2.35

TABLE 5
E = 15 mm, the production parameters of 0.23 C amorphous,
ultracrystallite, crystallite and fine grain steel slabs (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	10.81	8.77	7.59	6.20	4.39	3.1	0.98	0.31
X						1.2	1.7	5.37	17
V	dm3/min					6000	4235.3	1340	423.5
K	m/s					25	17.6	5.6	1.76

TABLE 6
E = 10 mm, the production parameters of 0.23 C amorphous,
ultracrystallite, crystallite and fine grain steel slabs (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	10.81	8.77	7.59	6.20	4.39	3.1	0.98	0.31
X				1.04	1.28	1.8	2.55	8.06	25.5
V	dm3/min			6923.1	5625	4000	2823.4	893.3	282.4
K	m/s			28.9	23.4	16.7	11.8	3.72	1.18

TABLE 7
E = 5 mm, the production parameters of 0.23 C amorphous,
ultracrystallite, crystallite and fine grain steel slabs (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	10.81	8.77	7.59	6.20	4.39	3.1	0.98	0.31
X		1.78	1.8	2.08	2.56	3.6	5.1	16.12	51
V	dm3/min	4044.9	4000	3461.5	2812.5	2000	1411.7	446.7	141.18
K	m/s	16.9	16.7	14.4	11.7	8.3	5.9	1.86	0.59

TABLE 8
E = 1 mm, the production parameters of 0.23 C amorphous,
ultracrystallite, crystallite and fine grain steel slabs (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	crystal
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	10.81	8.77	7.59	6.20	4.39	3.1	0.98	0.31
X		8.9	9	10.4	12.8	18	25.5	80.6	255
V	dm3/min	809	800	692.3	562.5	400	282.4	89.3	28.2
K	m/s	3.37	3.3	2.9	2.3	1.7	1.18	0.37	0.12

Table 3 provides maximum thickness E_max and its corresponding production parameters for continuously casting 0.23C amorphous, ultracrystallite, crystallite and fine grain steel slabs. Table 4-8 provides the corresponding production parameters of 0.23C amorphous, ultracrystallite, crystallite or fine grain steel slabs when thickness E=20 mm, 15 mm, 10 mm, 5 mm and 1 mm. In the above mentioned thickness range, corresponding production parameters can be determined by referring to the tables.

As for Crystallite Steel Slab B, because Δm=0.284 mm, if the thickness of the steel slab is less than 2.84 mm, Δm>E/10, it does not meet the condition for one-dimensional stable-state heat conduction. Similarly for fine grain steel slabs with Δm=0.899 mm, if the thickness of the steel slab is less than 9 mm, it does not meet the condition for one-dimensional stable-state heat conduction as well. That is, the data of Crystallite B shown in table 8 and the data of fine grain shown in table 7 and 8 cannot be used.

In order to meet the requirements of the production parameters in table 3-8, the ejection system of the continuous casting machine of the L,R,C method should have the following features:

For 0.23C amorphous steel slabs with E=1 mm-8.9 mm, the quantity of ejected liquid nitrogen should be adjustable within the range of 809 dm³/min˜7200 dm³/min, and the liquid nitrogen's ejection speed should be adjustable within the range of 3.37 m/s˜30 m/s.

For 0.23C ultracrystallite steel slabs with E=1 mm-18 mm, the quantity of ejected liquid nitrogen should be adjustable within the range of 400 dm³/min˜7200 dm³/min, and the liquid nitrogen's ejection speed should be adjustable within the range of 1.7 m/s˜30 m/s.

For 0.23C Crystallite Steel Slab A with E=1 mm-25.5 mm, the quantity of ejected liquid nitrogen should be adjustable within the range of 282.4 dm³/min˜7200 dm³/min, and the liquid nitrogen's ejection speed should be adjustable within the range of 1.18 m/s-30 m/s.

For 0.23C Crystallite Steel Slab B with E=1 mm-80.6 mm, the quantity of ejected liquid nitrogen should be adjustable within the range of 89.3 dm³/min˜7200 dm³/min, and the liquid nitrogen's ejection speed should be adjustable within the range of 0.37 m/s˜30 m/s.

For 0.23C fine grain steel slabs with E=1 mm-255 mm, the quantity of ejected liquid nitrogen should be adjustable within the range of 28.2 dm³/min˜7200 dm³/min, and the liquid nitrogen's ejection speed should be adjustable within the range of 0.12 m/s˜30 m/s.

8. Casting amorphous, ultracrystallite, crystallite and fine grain aluminum slabs using the L,R,C method and its continuous casting system, and the determination of production parameters

The relevant parameters and the thermal parameters of aluminum slabs are as follows:

B—width of aluminum slab, B=1 m

E—thickness of aluminum slab, E=X m

L—the latent heat, L=397.67 KJ/K g

λ_CP—average thermal conductivity, λ_CP=256.8×10⁻³ KJ/m·° C.s^{[appendix 1]}

ρ_CP—average density, ρ_CP=2.591×10³ Kg/m^{3 [appendix 1]}

C_CP—average specific heat, C_CP=1.085 KJ/Kg° C.^{[appendix 1]}

t₁—initial solidification temperature, t₁=750° C.

t₂—ending solidification and cooling temperature, t₂=−190° C.

The condition of the cold source is the same as that used in continuous casting 0.23C steel slabs. The thermal parameters of the liquid nitrogen are shown in table 2.

1) Using the L,R,C method and its continuous casting system to cast amorphous aluminum slabs and the determination of the production parameters

1.1) Using the L,R,C method and its continuous casting system to cast amorphous aluminum slabs of maximum thickness E_max and the determination of the production parameters

(1) Determine cooling rate V_K in the whole solidification and cooling process of aluminum slabs

Let V_K=10⁷° C./s

(2) Calculate Δτ

Δτ is calculated with formula (1)

$\begin{array}{c}\Delta \tau =\frac{t_1-t_2}{V_K}\\ =\frac{750-\left(-190\right)}{{10}^7}\\ =9.4\times {10}^{-5}s\end{array}$

(3) Calculate Δm

Δm is calculated with formula (8).

$\begin{array}{c}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}}\Delta \tau }\\ =\sqrt{\frac{256.8\times {10}^{-3}}{2.591\times {10}^3\times 1.085}\times 9.4\times {10}^{-5}}\\ =0.093\mathrm{mm}\end{array}$

(4) Calculate u

u is calculated with formula (10).

$\begin{array}{c}u=\frac{\Delta m}{\Delta \tau }\\ =\frac{0.093}{9.4\times {10}^{-5}}\\ =59.15m/\min \end{array}$

(5) Calculate ΔV_in.

ΔV_max is calculated with formula (15)

• • Let Kmax=30 m/sΔV_max=2BK_maxΔτh=2×1×10³×30×10³×9.4×10⁻⁵×2=0.01128 dm³

(6) Calculate ΔQ_2max

ΔQ_2max is calculated with formula (16)

$\begin{array}{c}\Delta Q_{2\max }=\frac{\Delta V_{\max }r}{V^{\prime }}\\ =\frac{0.01128\times 190.7}{1.281}\\ =1.679\mathrm{KJ}\end{array}$

(7) Calculate E_max

E_max is calculated with formula (17)

$\begin{array}{c}{E}_{\max }=\frac{\Delta Q_{2\max }}{B\Delta m{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}\Delta t}\\ =\frac{1.679}{100\times 0.0093\times 2.591\times {10}^{-3}\times 1.085\times 940}\\ =6.8\mathrm{mm}\end{array}$

(8) Calculate V_max

V_max is calculated with formula (19)′V_max=120BK_maxh=120×1×10³×30×10³×2=7200 dm³/min

(9) Calculate V_gmax

V_gmax is calculated with formula (20)′

$\begin{array}{c}{V}_{g\max }=\frac{120{\mathrm{BK}}_{\max }h}{V^{\prime }}{V}^{″}\\ =\frac{120\times 1\times {10}^3\times 30\times {10}^3\times 2}{1.281}\times 122.3\\ =687400.5{\mathrm{dm}}^3/\min \end{array}$

1.2) Using the L,R,C method and its continuous casting system to cast amorphous aluminum slabs of thickness E and the determination of the production parameters

(1) Let E=5 mm. The values of V_k, Δτ, Δm, u corresponding to E=5 mm are still the same as those corresponding to E_max=6.8 mm. That is, V_k=10⁷° C./s, Δτ=9.4×10⁻⁵ s, Δm=0.093 mm, u=59.15 m/min.

(2) Calculate X

X is calculated with formula (21)

$\begin{array}{c}X=\frac{E_{\max }}{E}\\ =\frac{6.8}{5}\\ =1.36\end{array}$

(3) Calculate ΔV

ΔV is calculated with formula (22)

$\begin{array}{c}\Delta V=\frac{\Delta V_{\max }}{X}\\ =\frac{0.0128}{1.36}\\ =0.00583{\mathrm{dm}}^3\end{array}$

(4) Calculate ΔQ₂

ΔQ₂ is calculated with formula (22)

$\begin{array}{c}\Delta Q_2=\frac{\Delta Q_{2\max }}{X}\\ =\frac{1.679}{1.36}\\ =1.24\mathrm{KJ}\end{array}$

(5) Calculate V

V is calculated with formula (22)

$\begin{array}{c}V=\frac{V_{\max }}{X}\\ =\frac{7200}{1.36}\\ =5294.1{\mathrm{dm}}^3/\min \end{array}$

(6) Calculate V_g

V_g is calculated with formula (22)

$\begin{array}{c}{V}_g=\frac{V_{g\max }}{X}\\ =\frac{687400.5}{1.36}\\ =505441.5{\mathrm{dm}}^3/\min \end{array}$

(7) Calculate K

K is calculated with formula (23)

$\begin{array}{c}K=\frac{K_{\max }}{X}\\ =\frac{30}{1.36}\\ =22.1m/s\end{array}$

Comparing the production parameters of the L,R,C method used for continuous casting of 0.23C amorphous steel slab with those used for continuous casting of aluminum slabs, we can find that when the production parameters of liquid nitrogen are the same (V_max=7200 dm³/min, K_max=30 m/s, h=2 mm), the maximum thickness of 0.23C amorphous steel slabs is E_max=8.9 mm while the maximum thickness of amorphous aluminum slabs is E_max=6.8 mm. The E_max of steel slabs is 1.31 times thicker than the E_max of aluminum slabs. The casting speed of amorphous steel slabs is u=10.81 m/min while the casting speed of amorphous aluminum slabs is u=59.15 m/min; that is, in one minute, 10.81 m of 0.23C amorphous steel slabs with thickness 8.9 mm can be cast while 59.15 m of amorphous aluminum slabs with thickness 6.8 mm can be cast. The main reason is that the Δm values of these two kinds of slabs are different. The Δm value of amorphous metal structure is determined by formula (8).Δm=√{square root over (α_CPΔτ)}  (8)

Where α_CP—average thermal diffusivity coefficient of the metal

${\alpha }_{\mathrm{CP}}=\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}{C}_{\mathrm{CP}}}{m}^2/s$

When using the L,R,C method to continuously cast metal slabs, if λ_CP of a certain metal is larger and ρ_CPC_CP is smaller, the quantity of heat transmitted by that metal is larger and the quantity of heat stored is smaller, thus causing the value of that metal's Δm to be larger. The quantity of heat transmitted through cross section a-c shown in FIG. 2 is ΔQ₁ and

$\Delta Q_1={\lambda }_{\mathrm{CP}}A\frac{\Delta t}{\Delta m}\Delta \tau$

When λ_CP increases, the value of ΔQ₁ increases. In order to maintain ΔQ₁=ΔQ₂, the value of ΔQ₂ must increase. ΔQ₂ is the internal heat in molten metal with length Δm.ΔQ₂=BEΔmρ_CPC_CPΔt

ρ_CPC_CP of aluminum is smaller. So if the value of ΔQ₂ is to increase, the value of Δm must increase. The increase in Δm's value makes ΔQ₂ increase but ΔQ₁ decrease. When Δm increases to a certain value where ΔQ₁=ΔQ₂, then the value of Δm is determined.

According to the calculations, for 0.23C steel α_CP=0.0203 m²/h and Δτ=1.74×10⁻⁴ s, for aluminum α_CP=0.329 m²/h and Δτ=9.4×10⁻⁵ s. The combined action of α_CP and Δτ makes Δm=0.093 mm for amorphous aluminum and Δm=0.03135 mm for 0.23C steel. There is a 3 times difference between the two Δm's. The larger Δm value of aluminum causes the continuous casting speed to increase to u=59.15 m/min. It not only requires the traction speed of the guidance traction device (6) shown in FIG. 1 to reach 59.15 m/min, but also requires steady movement, without any fluctuation, resulting in a certain degree of difficulty in the mechanism's setup.

2) Using the L,R,C method and its continuous casting system to cast ultracrystallite aluminum slabs and the determination of the production parameters

The combination of cooling rates V_k used for ultracrystallite aluminum slabs are: 2×10⁶° C./s, 4×10⁶° C./s, 6×10⁶° C./s and 8×10⁶° C./s respectively.

2.1) Determining maximum thickness E_max when using the L,R,C method and its continuous casting system to cast ultracrystallite aluminum slabs at cooling rate V_K=2×10⁶° C./s, and the determination of the production parameters

Let Kmax=30 m/s and h=2 mm remain constant.

(1) Calculate Δτ

Δτ is calculated with formula (1)

$\begin{array}{c}\Delta \tau =\frac{t_1-t_2}{V_K}\\ =\frac{750-\left(-190\right)}{2\times {10}^6}\\ =4.7\times {10}^{-4}s\end{array}$

(2) Calculate Δm

For ultracrystallite aluminum slabs, the latent heat is released in the solidification process. Δm is calculated with formula (9)

$\begin{array}{c}\Delta m=\sqrt{\frac{{\lambda }_{\mathrm{CP}}}{{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)V_K}·}\Delta t\\ =\sqrt{\frac{256.8\times {10}^{-3}}{2.591\times {10}^3\left(1.085\times 940+397.67\right)\times 2\times {10}^6}}\times 940\\ =0.176\mathrm{mm}\end{array}$

(3) Calculate u

u is calculated with formula (10)

$\begin{array}{c}u=\frac{\Delta m}{\Delta \tau }\\ =\frac{0.176}{4.7\times {10}^{-4}}\\ =22.5m/\min \end{array}$

(4) Calculate ΔV_max

ΔV_max is calculated with formula (15)ΔV_max=2BK_maxΔτh=2×1×10³×30×10³×4.7×10⁻⁴×2=0.0564 dm³

(5) Calculate ΔQ_2max

ΔQ_2max is calculated with formula (16)

$\begin{array}{c}\Delta Q_{2\max }=\frac{\Delta V_{\max }r}{V^{\prime }}\\ =\frac{0.0564\times 190.7}{1.281}\\ =8.4\mathrm{KJ}\end{array}$

(6) Calculate E_max

For the ultracrystallite aluminum slab, E_max is calculated with formula (18)

$\begin{array}{c}{E}_{\max }=\frac{\Delta Q_{2\max }}{B\Delta m{\rho }_{\mathrm{CP}}\left(C_{\mathrm{CP}}\Delta t+L\right)}\\ =\frac{8.4}{100\times 0.0176\times 2.591\times {10}^{-3}\times \left(1.085\times 940+397.6\right)}\\ =13\mathrm{mm}\end{array}$

(7) Calculate V_max

V_max is calculated with formula (19)′V_max=120BK_maxh=120×1×10³×30×10³×2=7200 dm³/min

(8) Calculate V_gmax

V_gmax is calculated with formula (20)′

$\begin{array}{c}{V}_{g\max }=\frac{120{\mathrm{BK}}_{\max }h}{V^{\prime }}{V}^{″}\\ =\frac{120\times 1\times {10}^3\times 30\times {10}^3\times 2}{1.281}\times 122.3\\ =687400.5{\mathrm{dm}}^3/\min \end{array}$

The production parameters in using cooling rate V_K=2×10⁶° C. Is to produce ultracrystallite aluminum slabs with other thickness E are calculated. The production parameters in using cooling rate V_K=4×10⁶° C. Is, 6×10⁶° C./s, or 8×10⁶° C./s to produce ultracrystallite aluminum slab with maximum thickness or other thickness E are calculated. The production parameters in using cooling rate V_K=10⁶° C./S, 10⁵° C./S or 10⁴° C./s to produce Crystallite A, Crystallite B or fine grain aluminum slabs with maximum thickness or other thickness E are calculated. All the above calculation results are listed in table 9, table 10, table 11, table 12, table 13 and table 14. The description for the calculation process will not be repeated herein.

TABLE 9
The maximum thickness Emax and production parameters of amorphous, ultracrystallite, crystallite
and fine grain aluminum slabs (B = 1 m, Kmax = 30 m/s, h = 2 mm)
	Metal Structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
Δτ	S	9.4 × 10−5	1.18 × 10−4	1.57 × 10−4	2.35 × 10−4	4.7 × 10−4	9.4 × 10−4	9.4 × 10−3	9.4 × 10−2
Δm	mm	0.093	0.088	0.102	0.124	0.176	0.249	0.786	2.49
u	m/min	59.15	44.8	38.8	31.7	22.5	15.87	5.02	1.59
ΔVmax	dm3	0.01128	0.0142	0.0188	0.0282	0.0564	0.1128	1.128	11.28
ΔQ2max	KJ	1.679	2.11	2.8	4.2	8.4	16.792	167.92	1679.2
Emax	mm	6.8	6.5	7.5	9.2	13	18.4	52.8	188.6
Vmax	dm3/min	7200	7200	7200	7200	7200	7200	7200	7200
Vgmax	dm3/min	687400.5	687400.5	687400.5	687400.5	687400.5	687400.5	687400.5	687400.5

TABLE 10
E = 20 mm, the production parameters of amorphous, ultracrystallite, crystallite and fine grain
aluminum slabs (B = 1 m, h = 2 mm)
	Metal Structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	59.15	44.8	38.8	31.7	22.5	15.87	5.02	1.59
X								2.91	9.18
V	dm3/min							2474.2	784.3
K	m/s							10.31	3.27

TABLE 11
E = 15 mm, the production parameters of amorphous, ultracrystallite, crystallite and
fine grain aluminum slabs (B = 1 m, h = 2 mm)
	Metal Structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	59.15	44.8	38.8	31.7	22.5	15.87	5.02	1.59
X							1.23	3.88	12.2
V	dm3/min						5853.7	1855.7	590.2
K	m/s						24.4	7.73	2.5

TABLE 12
E = 10 mm, the production parameters of amorphous, ultracrystallite, crystallite and
fine grain aluminum slab (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	59.15	44.8	38.8	31.7	22.5	15.87	5.02	1.59
X						1.3	1.84	5.82	18.4
V	dm3/min					5538.5	3913	1237.1	391.3
K	m/s					23.1	16.3	5.16	1.63

TABLE 13
E = 5 mm, the production parameters of amorphous, ultracrystallite, crystallite and
fine grain aluminum slab (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	59.15	44.8	38.8	31.7	22.5	15.87	5.02	1.59
X		1.36	1.3	1.5	1.84	2.6	3.68	11.64	36.72
V	dm3/min	5294.1	5538.5	4800	3913	2769.2	1956.5	618.6	196.1
K	m/s	22.1	23.1	20	16.3	11.5	8.2	2.6	0.82

TABLE 14
E = 1 mm, the production parameters of amorphous, ultracrystallite, crystallite and
fine grain aluminum slabs (B = 1 m, h = 2 mm)
	Metal structure
					Fine
	Amorphous	Ultracrystallite	Crystallite A	Crystallite B	grain
Vk	° C./s	107	8 × 106	6 × 106	4 × 106	2 × 106	106	105	104
u	m/min	59.15	44.8	38.8	31.7	22.5	15.87	5.02	1.59
X		6.8	6.5	7.5	9.2	13	18.4	58.2	183.6
V	dm3/min	1058.5	1107.7	960	782.6	553.8	391.3	123.7	39.2
K	m/s	4.4	4.6	4	3.26	2.31	1.63	0.52	0.16

Table 9 provides the maximum thickness E_max and its corresponding production parameters for continuously casting amorphous, ultracrystallite, crystallite and fine grain aluminium slabs. Table 10-14 provides the corresponding production parameters for continuously cast amorphous, ultracrystallite, crystallite and fine grain aluminium slabs when thickness E=20 mm, 15 mm, 10 mm, 5 mm and 1 mm respectively. If the thickness is in the above ranges, the corresponding parameters can be determined by referring to these tables.

As for ultracrystallite aluminum slabs, cooling rate V_k is within the range of 2×10⁶° C./s˜6×10⁶° C./s, and Δm is within the range of 0.176 mm˜0.102 mm. When the thickness of aluminum slabs is less than 1.76 mm˜1.02 mm, then Δm>E/10, which does not meet the requirement for one-dimensional stable-state heat conduction. For Crystallite A aluminum slab, Δm=0.249 mm. When the thickness of aluminum slabs is less than 2.5 mm, it does not meet the requirement for one-dimensional stable-state heat conduction. For Crystallite B aluminum slab, Δm=0.786 mm. When the thickness of aluminum slabs is less than 7.86 mm, it does not meet the requirement for one-dimensional stable-state heat conduction. For fine grain aluminum slab, because Δm=2.49 mm, the thickness of aluminum slabs must be larger than 25 mm to meet the requirement for one-dimensional stable-state heat conduction.

Table 9-table 14 also provide the relevant data of adjustment range for L, R, C method and its continuous casting ejection system at liquid nitrogen's ejection quantity V and ejection speed K.

In order to keep Cross Section b at the outlet of the hot casting mould shown in FIG. 2, when designing the guidance traction device (6) and liquid nitrogen ejector (5), one must consider to fine-tune the continuous casting speed u and the ejection quantity V of liquid nitrogen according to the actual position of Cross Section b to ensure that Cross Section b is at the right position of the hot casting mould's outlet. For Cross Section C where the liquid nitrogen's ejection comes into contact with the shaped metal (slab) (7), the structure of the nozzle shown in FIG. 2 should be amended to ensure that the liquid nitrogen's ejection comes into contact with the shaped metal (slab) on Crosse Section c.

The application of the L,R,C method and its continuous casting machine is diversified. They can continuously cast amorphous, ultracrystallite, crystallite and fine grain metallic slabs or other shaped metals in all kinds of models and specifications. These metals include ferrous and nonferrous metals, such as steel, aluminum, copper and titanium. To determine the working principles and production parameters, one can refer to the calculations for continuously casting amorphous, ultracrystallite, minicystal and fine grain metal slabs of 0.23C steel and aluminum.

FIG. 4 shows the principle of casting metal slabs or other shaped metals of amorphous, ultracrystallite, crystallite and fine grain structures by using hot casting mould with an upward outlet. This is an alternative scheme, and will not be described in detail herein.

Using L,R,C method and its continuous casting system to cast amorphous, ultracrystallite, crystallite and fine grain metallic slabs or other shaped metals has the following economic benefits.

So far there is no factory or business in the world which can produce ferrous and nonferrous slabs or other shaped metals of amorphous, ultracrystallite, crystallite and fine crystal structures. However, this invention can do so. Products produced by the L,R,C method and its continuous casting system will dominate the related markets in the world for their excellent features and reasonable price.

The whole set of equipment of the L,R,C method and its continuous casting machine production line designed and manufactured according to the principle of L,R,C method and the relevant parameters shown in FIG. 1 and FIG. 2 will also dominate the international markets.

For large conglomerates which continuously cast amorphous, ultracrystallite, crystallite and fine grain metallic slabs or other shaped ferrous and nonferrous metals using the L,R,C method and its continuous casting machines, other than mines and smelteries, the basic compositions are smelting plants, air liquefaction and separation plants and L,R,C method continuous casting plants. There will be significant changes in old iron and steel conglomerates.

From the above, the economic benefits of the invention are beyond estimation,

APPENDIX I

Thermophysical Properties of Steel, Aluminum, Titanium and Copper at Different Temperatures

TABLE 15
Thermophysical properties of 0.23 C steel at different temperatures[7]
Temp-
erature	Specific heat	Enthalpy	Thermal conductivity
K	° C.	J/Kg · K	kcal/Kg · K	KJ/Kg	kcal/Kg	W/m · K	kcal/m · h · K	cal/cm · s · K
273	0	469	0.112	0	0	51.8	44.6	0.124	ρ = 7.86(15° C.)
373	100	485	0.116	47.7	11.4	51.0	43.9	0.122	BOH 930° C.
473	200	519	0.124	98.7	23.6	48.6	41.8	0.116	anneal
573	300	552	0.132	153.1	36.6	44.4	38.2	0.106	0.23 C, 0.11Si
673	400	594	0.142	211.7	50.6	42.6	36.7	0.102	0.63Mn, 0.034S
773	500	661	0.158	276.1	66.0	39.3	33.8	0.094	0.034P, 0.07Ni
873	600	745	0.178	348.5	83.3	35.6	30.6	0.085	the specific
973	700	845	0.202	430.1	102.8	31.8	27.4	0.076	heat is the
1023	750	1431	0.342	501.7	119.9	28.5	24.5	0.068	mean value
1073	800	954	0.228	549.4	131.3	25.9	22.3	0.062	below 50° C.
1173	900	644	0.154	618.4	147.8	26.4	22.7	0.063
1273	1000	644	0.154	683.2	163.6	27.2	23.4	0.065
1373	1100	644	0.154	748.1	178.8	28.5	24.5	0.068
1473	1200	661	0.158	814.2	194.6	29.7	25.6	0.071
1573	1300	686	0.164	882.4	210.9

TABLE 16
Thermophysical properties of common nonferrous metals
at different temperatures [8] Aluminum Al
		Specific heat at
temper-		constant pressure CP	Thermal conductivity λ
ature	density	KJ/Kg · ° C.	W/m · ° C.
° C.	g/cm3	(kcal/· ° C.)	(kcal/m · h · ° C.)
20	2.696	0.896	(0.214)	206	(177)
100	2.690	0.942	(0.225)	205	(176)
300	2.65	1.038	(0.248)	230	(198)
400	2.62	1.059	(0.253)	249	(214)
500	2.58	1.101	(0.263)	268	(230)
600	2.55	1.143	(0.273)	280	(241)
800	2.35	1.076	(0.257)	63	(54)

Melting point=(660±1)° C.Boiling point=(2320±50)° C.Latent heat of melting q_melt=(94±1) kcal/KgThe mean specific heat at constant pressure C_p=0.214+0.5×10⁻⁴ t, kcal/Kg·° C.(the above formula applies at 0˜600° C.).The mean specific heat at constant pressure C_p=−0.26 kcal/Kg·° C.(applies at 658.6˜1000° C.).

Determining the Mean Value of Thermophysical Properties of Metal

The data of thermophysical properties of ferrous and nonferrous metals varies with the temperature. When calculating production parameters, the mean value of thermophysical properties is adopted in the process. However, at present, in the data of a metal's thermophysical properties and temperature, the range of temperatures only contains normal temperatures. There is no data for thermophysical properties under 0° C. For convenience, the data of thermal properties at low temperature only adopts data of thermal properties at 0° C. However, the mean value of thermal properties obtained in this way tends to be higher than the actual value. Thus, production parameters obtained by using the mean value of thermophysical properties are also higher than actual values. Correct production parameters must be determined through production trials.

Determining the Mean Value of Thermophysical Properties of 0.23C Steel

Determining the Mean Specific Heat C_cp

The data of the relationship between temperature and specific heat of 0.23C steel obtained from table 15 is listed in table 17.

TABLE 17
The relationship between temperature and specific heat of 0.23 C steel
	t ° C.
	0	100	200	300	400	500	600	700	750	800	900	1000	1100	1200	1300
C KJ/Kg · K	0.469	0.485	0.519	0.552	0.594	0.661	0.745	0.854	1.431	0.954	0.644	0.644	0.644	0.661	0.686

From table 17, when temperature is below 750° C., specific heat falls with temperature. All data of specific heat below 0° C. is deemed as data of specific heat at 0° C., which is 0.469 KJ/Kg·K. The value is higher than it actually is.

In the process of rapid solidification and cooling, the transformation temperature T_g and melting point temperature T_melt of amorphous metal has a relationship of T_g/T_m>0.5^[1].

The 0.23C molten steel rapidly dropping from 1550° C. to 750° C. is the temperature range in which amorphous transformation takes place. From the data of the relationship between t and C shown in FIG. 17, it can be seen that the mean value of specific heat, calculated at this temperature range is higher than actual. Taking this mean value of specific heat as the mean value of the specific heat in the whole process of temperature dropping from 1550° C. to −190° C. should be higher than actual and should be reliable.

The mean value of specific heat at a temperature range of 1330° C.-1550° C. Let the value C₁ of molten steel's specific heat be the mean value of the specific heat at this temperature range.C_L=0.84KJ/Kg·° C.^[8]

Calculate the mean value C_cp1 of specific heat at 1300° C.-750° C.C_CP1=(0.686+0.661+0.644+0.644+0.644+0.954+1.431)÷7=0.8031 KJ/Kg·° C.

Calculate the mean value C_cp1 of specific heat at 1550° C.-750° C.C_CP2=(C_LC_CP1)÷2=(0.84+0.8031+2=0.822 KJ/Kg·° C.

Let the mean value of specific heat of 0.23C steel C_CP=0.822 KJ/Kg·° C.

Determining the Mean Thermal Conductivity λ_CP

TABLE 18
Relationship between temperature and the thermal conductivity of 0.23 C steel
	t ° C.
	0	100	200	300	400	500	600	700	750	800	900	1000	1100	1200
λW/m · ° C.	51.8	51.0	48.6	44.4	42.6	39.3	35.6	31.8	28.5	25.9	26.4	27.2	28.5	29.7

Calculate the mean value of thermal conductivity at temperatures 0° C.-120° C. λ_CP

$\begin{array}{c}{\lambda }_{\mathrm{CP}}=\left(\begin{array}{c}51.8+51.0+48.6+44.4+42.6+39.3+35.6+\\ 31.8+28.5+25.9+26.4+27.2+28.5+29.7\end{array}\right)/14\\ =36.5W/m.\mathrm{°C}\end{array}$

Let the mean value of thermal conductivity of 0.23 λ_CP=36.5×10⁻³ KJ/m·s.° C. From the value of λ at the temperature range 750° C.-1200° C., it can seen that λ_CP=36.5 KJ/m·s.° C. is higher than actual. Using it to calculate the quantity of heat transmission and the quantity of ejected liquid nitrogen is also higher than actual and is reliable.

Determining the Mean Value of the Thermophysical Properties of Aluminum

Determining the Mean Specific Heat C_cp

TABLE 19
Relationship between temperature and specific heat of aluminum
	T ° C.
	20	100	300	400	500	600	800
CP KJ/Kg · K	0.896	0.942	1.038	1.059	1.101	1.143	1.076

Calculate the mean value of specific heat of aluminum C_CP C_CP=(1.038+1.059+1.101+1.143)/4=1.085 KJ/Kg·° C.

Let the mean value of specific heat of aluminum C_CP=1.085 KJ/Kg·° C.

Determining the Mean Thermal Conductivity λ_CP

TABLE 20
Relationship between temperature and
thermal conductivity of aluminum
	T ° C.
	20	100	300	400	500	600	800
λ KJ/m · s · ° C.	206	205	230	249	268	280	63

Calculate the mean value λ_CP of thermal conductivity of aluminum at temperatures 300° C.-600° C.λ_CP=(230+249+268+280)/4=256.8×10⁻³ KJ/m·s.° C.

Let the mean value of thermal conductivity of aluminum λ_CP=256.8×10⁻³ KJ/m·s.° C.

Determining the Mean Density ρ_CP

TABLE 21
Relationship between temperature and density of aluminum
	T ° C.
	20	100	300	400	500	600	800
ρ g/cm3	2.696	2.690	2.65	2.62	2.58	2.55	2.35

Calculate the mean value ρ_CP of density of aluminum at temperatures 300° C.-600° C.ρ_CP=(2.65+2.62+2.58+2.55)/4=2.591×10³ Kg/m³ Let the mean value of density of aluminum ρ_CP=2.591×10³ Kg/m³

The thermophysical properties of other nonferrous metals, such as aluminum alloy, copper alloy, titanium alloy, can be found in the relevant manual. So they will not be repeated herein.

Appendix 2 the thermophysical properties of the liquid nitrogen^[10]

Chapter 5
NITROGEN AND AMMONIA
NITROGEN (N2)
Molecular weight 28.016
Tboil = 77.35k at 760 mmHg; tmelt = 63.15k; tcr = 126.25k
Pcr = 33.96 bar; ρcr = 304 Kg/m3
Thermodynamic properties of saturated nitrogen [141, 142]
V (dm3/Kg), Cp (KJ/Kg · deg), i and r (KJ/Kg) and S (KJ/Kg · deg)
T ° K	P bar	V′	V″	Cp′	I′	i″	r	S′	S″
63.15	0.1253	1.155	1477.00	1.928	−148.5	64.1	212.6	2.459	5.826
64.00	0.1462	1.159	1282.00	1.929	−146.8	64.9	211.7	2.435	5.793
65.00	0.1743	1.165	1091.00	1.930	−144.9	65.8	210.7	2.516	5.757
66.00	0.2065	1.170	933.10	1.931	−142.9	66.8	209.7	2.545	5.722
67.00	0.2433	1.176	802.60	1.932	−141.0	67.7	208.7	2.753	5.688
68.00	0.2852	1.181	693.80	1.933	−139.1	68.7	207.8	2.600	5.656
69.00	0.3325	1.187	602.50	1.935	−137.1	69.6	206.7	2.629	5.625
70.00	0.3859	1.193	525.60	1.935	−135.2	70.5	205.7	2.657	5.595
71.00	0.4457	1.199	460.40	1.939	−133.3	71.4	204.7	2.683	5.566
72.00	0.5126	1.205	405.00	1.941	−131.4	72.3	203.7	2.709	5.538
73.00	0.5871	1.211	357.60	1.943	−129.4	73.2	202.6	2.736	5.511
74.00	0.6696	1.217	316.90	1.945	−127.4	74.1	201.4	2.763	5.485
75.00	0.7609	1.224	281.80	1.948	−125.4	74.9	200.3	2.789	5.460
76.00	0.8614	1.230	251.40	1.951	−123.4	75.7	199.1	2.816	5.436
77.00	0.9719	1.237	224.90	1.954	−121.4	76.5	197.9	2.842	5.412
78.00	1.0930	1.244	201.90	1.957	−119.5	77.3	196.8	2.866	5.389
79.00	1.2250	1.251	181.70	1.960	−117.6	78.1	195.7	2.890	5.367
80.00	1.3690	1.258	164.00	1.964	−115.6	78.9	194.5	2.913	5.345
81.00	1.5250	1.265	148.30	1.968	−113.6	79.6	193.2	2.938	5.324
82.00	1.6940	1.273	134.50	1.973	−111.6	80.3	191.9	2.963	5.303
83.00	1.8770	1.281	122.30	1.978	−109.7	81.0	190.7	2.986	5.283
84.00	2.0740	1.289	111.40	1.983	−107.7	81.7	189.3	3.009	5.263
85.00	2.2870	1.297	101.70	1.989	−105.7	82.3	188.0	3.032	5.244
86.00	2.5150	1.305	93.02	1.996	−103.7	82.9	186.6	3.055	5.225
87.00	2.7600	1.314	85.24	2.003	−101.7	83.5	185.1	3.078	5.206
88.00	3.0220	1.322	78.25	2.011	−99.7	84.0	183.7	3.100	5.118
89.00	3.3020	1.331	71.96	2.019	−97.7	84.5	182.2	3.123	5.170
90.00	3.6000	1.340	66.28	2.028	−95.6	85.0	180.5	3.147	5.152
91.00	3.9180	1.349	61.14	2.037	−93.5	85.4	178.9	3.169	5.134
92.00	4.2560	1.359	56.48	2.048	−91.5	85.8	177.3	3.190	5.117
93.00	4.6150	1.369	52.25	2.060	−89.4	86.2	175.6	3.212	5.100
94.00	4.9950	1.379	48.39	2.073	−87.3	86.5	173.8	3.235	5.084
95.00	5.3980	1.390	44.87	2.086	−85.2	86.8	172.0	3.256	5.067
96.00	5.8240	1.400	41.66	2.101	−83.1	87.1	170.2	3.277	5.050
97.00	6.274	1.411	38.720	2.117	−81.0	87.3	168.3	3.299	5.034
98.00	6.748	1.423	36.020	2.135	−78.8	87.5	166.3	3.320	5.017
99.00	7.248	1.435	33.540	2.155	−76.6	87.6	164.2	3.342	5.001
100.00	7.775	1.447	31.260	2.176	−74.5	87.7	162.2	3.363	4.985
101.00	8.328	1.459	29.160	2.199	−72.3	87.7	160.0	3.385	4.969
102.00	8.910	1.472	27.220	2.225	−70.1	87.7	157.8	3.406	4.953
103.00	9.520	1.485	25.430	2.254	−67.8	87.7	155.5	3.426	4.936
104.00	10.160	1.499	23.770	2.285	−65.6	87.6	153.2	3.447	4.920
105.00	10.830	1.514	22.230	2.319	−63.8	87.4	150.7	3.469	4.904
106.00	11.530	1.529	20.790	2.356	−61.0	87.2	148.2	3.489	4.887
107.00	12.270	1.544	19.460	2.398	−58.6	86.5	142.8	3.532	4.854
108.00	13.030	1.560	18.220	2.445	−56.2	86.5	142.8	3.532	4.854
109.00	13.830	1.578	17.060	2.500	−53.8	86.1	139.9	3.554	4.837
110.00	14.670	1.597	15.980	2.566	−51.4	85.6	137.0	3.575	4.820
111.00..	15.540	1.617	14.960	2.645	−48.9	85.1	134.0	3.596	4.803
112.00	16.450	1.639	14.000	2.736	−46.3	84.4	130.7	3.618	4.785
113.00	17.390	1.662	13.100	2.836	−43.7	83.6	127.3	3.640	4.767
114.00	18.360	1.687	12.260	2.945	−41.0	82.8	123.8	3.662	4.748
115.00	19.400	1.714	11.470	3.063	−38.1	81.8	119.9	3.687	4.729
116.00	20.470	1.744	10.710		−35.1	80.7	115.8	3.711	4.709
117.00	21.580	1.776	9.996		−31.9	79.4	111.3	3.737	4.688
118.00	22.720	1.811	9.314		−28.6	77.9	106.5	3.764	4.666
119.00	23.920	1.849	8.660		−25.1	76.2	101.3	3.792	4.643
120.00	25.150	1.892	8.031		−21.4	74.3	95.7	3.821	4.619
121.00	26.440	1.942	7.421		−17.3	72.1	89.4	3.853	4.592
122.00	27.770	2.000	6.821		−12.9	69.4	82.3	3.887	4.562
123.00	29.140	2.077	6.225		−8.0	66.4	74.4	3.924	4.529
124.00	30.570	2.177	5.636		−2.3	62.6	64.9	3.968	4.491
125.00	32.050	2.324	5.016		5.1	57.9	52.8	4.024	4.444
126.00	33.570	2.637	4.203		17.4	49.5	32.1	4.118	4.365
126.25	33.960	3.289	3.289		34.8	34.8	0.0	4.252	4.252

REFERENCES

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Claims

1. A method for casting a metal article, the method comprising providing an enclosed area comprising a traction bar configured to move at a continuous casting speed, wherein the enclosed area is kept at a substantially constant ambient temperature of −190° C. and a pressure of 1 Bar;ejecting liquid nitrogen to cool a portion of the traction bar located at the outlet of an hot casting mould; wherein the liquid nitrogen is ejected at a rate sufficient to maintain a predetermined cooling rate over a selected time interval when molten metal is extruded from the hot casting mould onto the traction bar;extruding molten metal from the outlet of the hot casting mould onto the traction bar to form a solidified metal portion, wherein the traction bar is moved as the molten metal is extruded to maintain a continuous casting speed within the selected time interval;cutting the solidified metal portion to form the metal article.

2. The method of claim 1, wherein the metal article comprises amorphous metal.

3. The method of claim 1, wherein the metal article comprises ultracrystalline metal.

4. The method of claim 1, wherein the metal article comprises fine grain metal.

5. The method according to claim 1, wherein the metal article comprises a ferrous metal.

6. The method according to claim 1, wherein the metal article comprises a nonferrous metal.