Patent Grant
7364816
1. Field of the Invention
The present invention relates to a laminate type battery formed by stacking a plurality of layers and to a method for manufacturing the same.
2. Description of the Related Art
There is a known bipolar battery which is constructed in a manner that bipolar electrodes are formed by applying a positive electrode material and a negative electrode material on both sides of a metal foil serving as a collector by the use of a coater, and a plurality of these bipolar electrodes sandwiches a plurality of electrolyte sheets. This bipolar battery is sealed by a laminate film, and at least two collectors are extended to the outside from the laminate film. These two collectors are connected to electrode terminals, enabling the battery and an external device to be connected to each other through the electrode terminals.
However, this bipolar battery has a construction in which many members are combined together and thus has a problem of poor space efficiency.
The present invention was made in consideration of the above-described problems. It is an object of the present invention to provide a laminate type battery with high space efficiency and a method for manufacturing the same.
The first aspect of the present invention provides a laminate type battery, comprising: a substrate; a power generating element which has at least one single cell made by a positive electrode layer, an electrolyte layer and a negative electrode layer, the positive electrode layer, the electrolyte layer and the negative electrode layer being sandwiched by collecting layers from both sides thereof; and an electric circuit portion having electrode terminals which connect the collecting layers to an external device and circuitries which connect the collecting layers and the electrode terminals, wherein the power generating element and the electric circuit portion are formed by stacking a plurality of layers on the substrate, and each of the layers is configured such that the power generating element and the electric circuit portion are formed by stacking the layers.
The second aspect of the present invention provides an assembled battery, comprising: laminate type batteries, each having a substrate; a power generating element which has at least one single cell made by a positive electrode layer, an electrolyte layer and a negative electrode layer, the positive electrode layer, the electrolyte layer and the negative electrode layer being sandwiched by collecting layers from both sides thereof; and an electric circuit portion having electrode terminals which connect the collecting layers to an external device and circuitries which connect the collecting layers and the electrode terminals, wherein the power generating element and the electric circuit portion are formed by stacking a plurality of layers on the substrate, each of the layers is configured such that the power generating element and the electric circuit portion are formed by stacking the layers, and the laminate type batteries are provided on the same substrate and connected to each other in series or parallel.
The third aspect of the present invention provides an assembled battery module, comprising: assembled batteries, each comprising: laminate type batteries, each having a substrate; a power generating element which has at least one single cell made by a positive electrode layer, an electrolyte layer and a negative electrode layer, the positive electrode layer, the electrolyte layer and the negative electrode layer being sandwiched by collecting layers from both sides thereof; and an electric circuit portion having electrode terminals which connect the collecting layers to an external device and circuitries which connect the collecting layers and the electrode terminals, wherein the power generating element and the electric circuit portion are formed by stacking a plurality of layers on the substrate, each of the layers is configured such that the power generating element and the electric circuit portion are formed by stacking the layers, and the laminate type batteries are provided on the same substrate and connected to each other in series or parallel.
The fourth aspect of the present invention provides a method for manufacturing a laminate type battery, the method comprising: stacking a collecting layer, a positive electrode layer, an electrolyte layer and a negative electrode layer on a substrate, wherein at least one layer among the collecting layer, the positive electrode layer, the electrolyte layer and the negative electrode layer is formed by applying at least one fluid for forming each layer on the substrate.
The fifth aspect of the present invention provides a method for manufacturing a laminate type battery, the method comprising: preparing a positive electrode fluid for forming a positive electrode layer, a negative electrode fluid for forming a negative electrode layer, an electrolyte fluid for forming a electrolyte layer, a conductive fluid for forming a collector layer and a electric circuit portion, the electric circuit portion having electrode terminals which connect the collecting layers to an external device and circuitries which connect the collecting layers and the electrode terminals; applying the positive electrode fluid, the negative electrode fluid, the electrolyte fluid and the conductive fluid on a substrate to form the electric circuit portion and a power generating element, the power generating element having at least one single cell made by the positive electrode layer, the electrolyte layer and the negative electrode layer, the positive electrode layer, the electrolyte layer and the negative electrode layer being sandwiched by the collecting layers from both sides thereof, wherein the power generating element and the electric circuit portion are formed by applying the positive electrode fluid, the negative electrode fluid, the electrolyte fluid and the conductive fluid onto a predetermined region on the substrate in a predetermined order while overlaying the fluids.
The invention will now be described with reference to the accompanying drawings wherein;
Preferred embodiments of a laminate type battery and a manufacturing method thereof according to the present invention will be detailed hereinbelow with reference to the attached drawings.
The laminate type battery according to the first embodiment will be described hereinbelow with reference to the drawings.
As shown in
The electric circuit portion 300 has electrode terminals 310 for connecting the laminate type battery to an external device, and circuitries 320 for connecting the electrode terminals 310 and the power generating element 200. The electrode terminals 310 are exposed outside, and the power generating element 200 and the electric circuit portion 300 are covered with an insulating portion 400. The power generating element 200 and the electric circuit portion 300 are insulated and sealed by the insulating portion 400. In this embodiment, a cell controller 2000 (see
As shown in
The electric circuit portion 300 has circuitries 320 for connecting these electrode terminals 310 and corresponding collecting layers 212. The circuitries 320 include a first circuitry 321 which connects the positive electrode terminal 311 and the collecting layer 212a, a second circuitry 323 which connects the negative electrode terminal 313 and the collecting layer 212c, and a third circuitry 322 which connects the intermediate electrode terminal 312 and the collecting layer 212b.
The insulating portion 400 is provided for preventing short circuits among each of the members of the laminate type battery, that is, each layer of the power generating element 200, the electrode terminals 310 and the circuitries 320, in particular, short circuits between the positive and negative electrode layers 211a and 211c, and between each members of the laminate type battery and the external device. Moreover, the insulating portion 400 also acts as a sealing member for the power generating element 200 and the circuitries 320.
As described in the forgoing, the laminate type battery according to this embodiment is constructed by the plurality of layers stacked on the substrate, thus realizing the laminate type battery having high space efficiency.
Further, each of the layers is configured (patterned) such that the power generating element 200 and the electric circuit portion 300 are formed by stacking these layers. Therefore, the power generating element 200 and the electric circuit portion 300 are integrally formed and thereby achieving easy manufacturing of the laminate type battery.
Each of the layers mentioned above is configured (patterned) such that the power generating element 200, the electric circuit portion 300 and the insulating portion 400 are integrally formed by stacking these layers. Therefore, the power generating element 200 and the electric circuit portion 300 to be sealed and the insulating portion 400 serving as the sealing member can be integrally formed, thus improving sealability. This effect is significant when the electrode terminals 310 are drawn out from the respective single cells 210 in the laminate type battery in which the many single cells 210 are connected in series.
Furthermore, each of the layers mentioned above is configured (patterned) such that the insulating portion 400 is formed by stacking the layers, and thereby preventing short circuits among the respective members of the laminate type battery and between each of the members and the outside.
Moreover, in general, capacity, resistance and the like of these single cells 210 are slightly different from each other. Therefore, when the plurality of single cells 210 is connected to each other in series, voltages of the single cells 210 vary due to repeated charges and discharges. As a result, deterioration gradually progresses from the cell with a relatively high voltage, which shortens the life of the entire battery. However, in the laminate type battery according to this embodiment, the electrode terminals 310 are connected to the cell controller 2000 for adjusting the voltages. Therefore, a favorable charge can be carried out, and a long life of the laminate type battery can be achieved.
In this embodiment, the collecting layers contacting with the positive and negative electrode layers 211a and 211c, respectively, are made of the same material. However, the collecting layers can be made of different materials. Specifically, the collecting layers 212 may include two types of layers.
Moreover, the laminate type battery according to this embodiment has the construction where the plurality of single cells 210 is connected in series. However, the laminate type battery may have a construction where the plurality of single cells 210 is connected in parallel. Further, if construction of the layers is changed, various laminate type batteries can be constructed where series and parallel connections are mixed.
Next, a method for manufacturing the laminate type battery according to this embodiment will be described. In the method for manufacturing this embodiment, the respective layers of the laminate type battery are formed by applying fluids, which is for forming the respective layers of the laminate type battery, onto the substrate in a predetermined order. The method for forming the layers by applying fluids includes an ink-jet method, spray printing, electrostatic spraying, sputtering and the like, and the ink-jet method is employed in this embodiment.
In this embodiment, the laminate type battery is manufactured by the use of an ink-jet printer having five printer heads. The five printer heads are for applying a positive electrode fluid for forming the positive electrode layers 211a, a negative electrode fluid for forming the negative electrode layers 211c, an electrolyte fluid for forming the electrolyte layers 211b, a conductive fluid for forming the collector layers 212 and the electric circuit portion 300, and an insulating fluid for forming the insulating portion 400, respectively. By controlling these printer heads, each of the fluid types mentioned above is ejected onto the substrate in a predetermined pattern respectively. After a solvent contained in the fluid is evaporated and the fluid is solidified, each of the fluid types is ejected to overlay the solidified fluid in a predetermined pattern to be formed next. Here, after the fluid is applied, it is preferable to perform heat or optical treatment for the film (the layer) formed by the fluid in order to accelerate evaporation of the solvent or solidification of the fluid. By repeating these operations for predetermined times, a desirable laminate type battery is manufactured.
First of all, the insulating fluid is ejected from the inkjet printer onto the substrate and then dried, thus forming an insulating layer serving as the lowermost layer. Next, the conductive fluid and the insulating fluid are ejected onto the insulating layer and then dried, thus forming a collecting layer 212c serving as the second layer. At this time, the insulating portion and the electric circuit portion 300 are formed in the periphery of the collecting layer 212c. Next, the negative electrode fluid and the insulating fluid are ejected onto the collecting layer 212c and then dried, thus forming the negative electrode layer 211c serving as the third layer. At this time, the insulating portion is formed in the periphery of the negative electrode layer 211c. Next, the electrolyte layer 211b that is the fourth layer and the positive electrode layer 211a that is the fifth layer are sequentially formed on the negative electrode layer 211c. These layers can be made similarly to the above-mentioned insulating layer and the like. As described above, the respective layers are formed by ejecting the fluids from the ink-jet printer, and thereby the laminate type battery of the present invention can be obtained.
Next, details will be given regarding manufacturing such as materials and a manufacturing apparatus used for the method for manufacturing the laminate type battery according to this embodiment. The laminate type battery described hereinbelow is a laminate type polymer battery.
The substrate 100 is made of an electric insulating material, for example, metal with a thin film of SiO2 insulator deposited thereon.
The positive electrode fluid is made by mixing a positive electrode active material, polymer, a polymerization initiator, a conductive material and a solvent and by adjusting viscosity thereof. In this embodiment, LiMn2O4, polyethylene oxide PEO), azobisisobutyronitrile (AIBN), acetylene black and N-methyl-2-pyrrolidone (NP) are used as the respective materials. Here, the particle size of the positive electrode active material is within a range of 0.1 μm to 20 μm. This is because, if the particle size is smaller than 0.1 μm, particles of the active materials cannot contact with each other, and thereby contact resistance increases. In addition, if the particle size is larger than 20 μm, a reactive surface of the active material becomes small, and thereby the cell resistance increases. Moreover, if the particle size is larger than 20 μm, the surfaces of the electrode layers become increasingly uneven. Therefore, when a thin electrolyte film is used, a force is applied to a part of the film, and consequently, it becomes more likely that the electrolyte film will break and a short circuit will occur. Preferably, the mass ratio of the positive electrode active material to the entire positive electrode fluid is 80 to 90% in a gel polymer battery and 20 to 60% in an intrinsic polymer (all-solid polymer) battery.
The negative electrode fluid is made by mixing a negative electrode active material, polymer, a polymerization initiator and a solvent and by adjusting viscosity thereof. In this embodiment, a carbon-based material (crushed to have a particle size of 5 μm or smaller), polyethylene oxide PEO), AIBN and NP are used as the respective materials. Here, for the same reason as for the positive electrode active material, the particle size of the negative electrode active material is within a range of 0.1 μm to 20 μm. In addition, it is preferable that the mass ratio of the negative electrode active material to the entire negative electrode fluid is 80 to 90% in a gel polymer battery and 20 to 60% in an intrinsic polymer battery.
The conductive fluid is made by paste of copper fine particles or carbon fine particles and a solvent (NP) used for reducing viscosity of the paste. In this embodiment, the fluid used for forming the collecting layers 212 and the one used for electric circuit portion are the same. However, different fluids may be used therefor. In addition, in this embodiment, the same fluid is used for the collecting layers 212a and 212c contacting with the positive and negative electrode layers 211a and 211c, respectively. However, different fluids can be used therefor. In this case, it is preferable that the fluid for forming the collecting layer 212a on the side of the positive electrode layer 211a contains carbon fine particles, and the fluid for forming the collecting layer 212c on the side of the negative electrode layer 211c contains copper fine particles. Needless to say, in this case, printer heads are required for the fluids, respectively.
The insulating fluid is a polysilazane solution, and the electrolyte fluid is a mixture of polyethylene oxide and NMP.
It is more preferable that the particle sizes of all particles (constituent materials for the battery) contained in each of the fluids are 5 μm or smaller. This is to avoid clogging of a nozzle of the printer head with these particles. Further, in order to prevent the clogging of the nozzle of the printer head, it is preferable to provide the printer head with a clogging prevention filter.
As for the thickness of each of the aforementioned layers, it is preferable that both of the positive and negative electrode layers 211a and 211c have a thickness of 0.5 to 20 μm, the electrolyte layer 211b has a thickness of 0.5 to 50 μm, and the collecting layer 212 has a thickness of 0.1 to 20 μm.
In order to enable application by an existing inkjet printer, the viscosity of the fluid is preferably 20 Pa·s or lower. The viscosity of the fluid can be reduced by adding a solvent. However, if a solvent is added, the active materials become sparse, and thereby electric contact resistance increases between the active materials. Accordingly, it is preferable to reduce the viscosity of the fluid by heating the printer head, instead of adding the solvent. In this embodiment, a ribbon heater is wound on the printer head to heat the fluid inside the printer head. Note that a heating temperature is preferably a temperature at which the solvent does not evaporate and thermal polymerization of the polymer does not occur.
The polymer contained in the foregoing fluids is preferably encapsulated in microcapsules for its stability. In this case, it is necessary to dissolve the microcapsules by heat treatment after the fluids are applied.
Preferably, the substrate 100 is heated. This is for evaporating the solvent contained in the applied fluids or for thermally polymerizing a polymer component which is not polymerized yet. In this embodiment, the substrate 100 is heated to about 130° C. Further, it is preferable from the viewpoint of efficient heating that the substrate 100 has high thermal conductivity. Furthermore, in order to prevent chemical reactions between the fluids and gasses in the atmosphere, it is preferable to apply and dry the fluids in an inert atmosphere. In this embodiment, the fluids are applied and dried within a chamber with 3% of hydrogen and 97% of nitrogen.
The method for manufacturing the laminate type battery according to the present invention has the following effects.
Since the laminate type battery is manufactured by sequentially applying the plurality of fluids, the manufacturing process can be reduced in comparison with the conventional manufacturing method. In addition, easy manufacturing of the laminate type battery can be realized.
Further, since the fluids are applied while configuring (patterning) required portions only, amounts of the materials to be used can be reduced.
Furthermore, since the pattern and the film thickness of each of the layers can be freely controlled, batteries having various capacities, sizes and shapes can be designed and manufactured easily.
Moreover, uniform thin films can be formed on a plate, and thereby easy manufacturing of a thin high-power battery can be realized. In particular, single cells can be easily stacked, and thereby a high-voltage bipolar battery can be manufactured.
Here, in this embodiment, the fluids are applied using the ink-jet method. Hence, the aforementioned effects can be obtained significantly. This is because the ink-jet method does not require a template unlike the printing method. Additionally, it is easy to control fine sizes with the ink-jet method, whereas it is difficult to control the same with the spraying method and the electrostatic spraying method. Further, since the ink-jet method is used, the shape of the battery, the positions of the electrode terminals 310 and the like can be freely changed. Therefore, patterns, information of the battery or the like can be simultaneously printed as required.
Incidentally, the battery is not necessarily a finished product once the application of each of the fluids has been completed. There may be additional steps for cutting or sticking the batteries and the like after the fluids are applied and dried.
An assembled battery according to the present invention is constituted in a manner that a plurality of the laminate type batteries of the first embodiment is provided on the same substrate and connected to each other either in series or parallel. This embodiment will be described hereinbelow with reference to the drawings, but description of the constituents corresponding to those of the first embodiment will be omitted.
In
The assembled battery 5000 according to this embodiment is manufactured by use of the manufacturing method similar to that for the laminate type battery according to the first embodiment. With the ink-jet method, in particular, the assembled battery 5000 according to this embodiment can be easily manufactured.
In the assembled battery 5000 according to this embodiment, the plurality of laminate type batteries 1000 is provided on the same substrate. Therefore, a thin high-power battery can be realized.
In this embodiment, the plurality of the laminate type batteries 1000 is connected to each other in series. However, the laminate type batteries may be connected to each other in parallel.
Moreover, an assembled battery module can be constructed by connecting a plurality of the assembled batteries of this embodiment in series or parallel. Using this assembled battery module, a thin high-power battery with even higher power can be realized.
As shown in
The entire content of a Japanese Patent Application No. P2002-380598 with a filing date of Dec. 27, 2002 is herein incorporated by reference.
Although the invention has been described above by reference to certain embodiments of the invention, the invention is not limited to the embodiments described above will occur to these skilled in the art, in light of the teachings. The scope of the invention is defined with reference to the following claims.
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| P 2002-380598 | Dec 2002 | JP | national |
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| 20040126655 A1 | Jul 2004 | US |
