The present invention relates to processes for forming a laminated product. More particularly, the present invention relates to an apparatus and a method for forming a laminated product.
The demand for reduction in the size of portable electronics products has driven innovations in interconnecting material used in electronics assemblies and processes for manufacturing electronics assemblies.
Adhesives are used as an interconnecting material for bonding various substrates such as polycarbonate, glass, and flexible film substrates to form laminated products including a display panel assembly, or a layered product.
Conventional lamination processes have encountered problems such as presence of air voids in the laminated product. When the laminated product is used in a display device having a viewing area, it is undesirable and generally not acceptable for air voids to be present within the viewing area.
Further, control of the adhesive flow is an important consideration in the lamination process. For example, “under flow” may occur when the adhesive stops flowing at an edge before the intended area of coverage on the first substrate is being covered. Alternatively, “overflow” may occur when the adhesive flow out of the intended area of coverage which upon curing can cause mechanical fitting problems in assemblies in which the laminated product is used. Still further, overflow of adhesive may cause problems in the manufacturing process of an electronic assembly such as a display assembly. For example, the overflow of the adhesive may contaminate adjacent components in the display assembly, and cause difficulty in transportation in the manufacturing process. As a result, additional cleaning steps may be required prior to curing and having such additional cleaning steps will increase the cycle time of the manufacturing process.
Currently, there are manufacturing methods that use a dam around the area of coverage of the substrate to form a dam area for receiving liquid adhesive overflowing from the area of coverage on the substrate. The dam is broken at corners of the dam to create an outgassing outlet at each corner of the dam to allow outgassing of gases in the adhesive. Liquid adhesive is dispensed into the dam area on the first substrate and a second substrate is press bonded to the first substrate. Gases such as air trapped in the laminated substrate may be released through the outgassing outlets.
However, such manufacturing methods require critical control of the timing of the adhesive flow which is difficult to control because the rate of flow of the adhesive may vary according to the viscosity of the liquid adhesives. Still further, any air void trapped will remain trapped in the laminated product.
The abovementioned problems in conventional lamination processes have resulted in low product yield in production which increases manufacturing costs since the defective substrate assemblies cannot be used and have to be disposed. Further, a laminated product whereby the adhesive is cured cannot be reworked.
There exists a need to address the abovementioned problems to obtain better yield in processes for forming laminated products.
In accordance with an aspect of the present invention, there is a method for forming a laminated product having a first substrate and a second substrate. The method may comprise applying a liquid adhesive on a surface of the first substrate for bonding the first substrate to the second substrate. The liquid adhesive located on a circumferential periphery of the first substrate may be cured so as to form a circumferential adhesive wall structure for limiting movement of the liquid adhesive within the circumferential adhesive wall structure. Pressure may be applied on a bond area between the first substrate and the second substrate in a vacuum environment for incrementally increasing the bond area between the first substrate and the second substrate to incrementally bond the first substrate to the second substrate. The liquid adhesive may be cured to bond the first and second substrates to form the laminated product.
Prior to the step of curing the liquid adhesive to form the circumferential adhesive wall structure, uneven application of liquid adhesive on the first substrate may be wiped to maintain uniform thickness of the liquid adhesive on the first substrate.
The liquid adhesive may be applied on the surface of the first substrate via a stencil with a cut out aperture corresponding to a shape of the intended lamination area on the surface of the first substrate. The stencil may be made of stainless steel.
Applying the pressure on the bond area, may include tilting the first substrate to lie in a plane inclined relative to the second substrate prior to incrementally increasing the bond area between the second substrate and the first substrate.
Tilting the first substrate may include:
A first end of the support may be arranged to pivot about a base and the biasing mechanism is disposed between the base and the support.
The biasing mechanism may include a biasing member such as for example, a spring element or a rubber pad or an actuator. The actuator may be a spring based piston assembly.
The biasing mechanism may include two biasing members disposed between the support and a base whereby each of the two biasing members is disposed at one of two opposing ends of the support.
Curing the liquid adhesive located on the circumferential periphery of the first substrate may include partially curing liquid adhesive on the circumferential periphery of an adhesive print area. By partial curing, it is meant to include curing the liquid adhesive to an extent or degree such that the liquid adhesive on the first substrate may have a higher resistance to flow during lamination where pressure is applied on the first substrate such that the first and second substrates are compressed.
Curing the liquid adhesive may include providing a mask on the first substrate, the mask having an aperture for exposing the liquid adhesive on the circumferential periphery to a curing source. The liquid adhesive may be partially cured by using the curing source on the circumferential periphery of the first substrate to form the circumferential adhesive wall structure. The curing source may be a Ultra Violet (UV) curing source.
Curing the liquid adhesive may include partial curing the liquid adhesive on the circumferential periphery to form the circumferential adhesive wall structure using a spot Light Emitting Diode (LED) UV light source.
The step of applying a liquid adhesive on a surface of the first substrate for bonding the first substrate to the second substrate may include:
The stencil portion may include a tapered portion to minimize liquid adhesive from being scooped back to the adhesive print area on the surface. The scooping back of the liquid adhesive may form a hump at the edge of the adhesive print area which may cause air to be trapped in the laminated product.
The stencil portion may include a recess adapted to accommodate excess flow of liquid adhesive from the aperture.
The recess may have a depth of less than the thickness of the stencil portion and an area extending along an edge of the stencil portion adjacent to the aperture.
The first and the second substrates may be made of a rigid material. Alternatively, the first substrate or the second substrate may be made of a flexible material.
The first substrate may be a LCD module having a viewing area, and the second substrate may be a glass substrate having a bottom surface for bonding with the viewing area. The bottom surface of the glass substrate may include a coloured masking extending from an outer circumferential periphery of the glass substrate to an outer circumferential periphery of the viewing area.
Curing the liquid adhesive may include curing the liquid adhesive on a circumferential periphery of the LCD substrate and under the coloured masking of the glass substrate. The curing may include UV curing.
According to an aspect of the present invention, there is an apparatus for forming a laminated product having a first substrate and a second substrate, the lamination system comprising:
The curing device may be used with a mask to form the circumferential adhesive wall structure.
According to an aspect of the present invention, there is a stencil for printing adhesive in a process for forming a laminated product for a display device having a first substrate and a second substrate. The stencil may comprise a stencil portion with an aperture. The aperture may be of a size corresponding to a surface of the first substrate for receiving a liquid adhesive on the surface of the first substrate.
Embodiments of the invention will be better understood and readily apparent to one of ordinary skill in the art from the following written description, by way of example only and in conjunction with the drawings, in which:
These figures are not drawn to scale and are intended merely for illustrative purposes.
A process for forming a laminated product having a first substrate and a second substrate begins with applying liquid adhesive on the first substrate. Applying of the liquid adhesive on the first substrate may be done by stencil printing the liquid adhesive on an intended print area of the surface of the first substrate. In particular, liquid adhesive may be a printable adhesive which may be stencil printed on the first substrate using a stencil 4 as shown in
Referring to
Due to the rheological properties of liquid adhesives, the liquid adhesive 3 may not be released completely from the aperture 6 of the stencil 4. Referring to
Process controls may be introduced in the printing process to ensure that a height H1 of the hump profile 7 of the scooping or a height H2 of the tail profile 8 does not exceed the thickness T1. Alternatively, during substrate and stencil separation, a stencil design may be modified to address the scooping and tailing effects.
Printing of the adhesive on the first substrate 11 may be done by screen printing liquid adhesive through the aperture 14 to the surface of the first substrate, using printing methods such as stencil printing or depositing/dispensing adhesive through the aperture 14.
A second recess (shown in
The stencil 4, 10 may be made of a material suitable for printing adhesives such as for example, stainless steel. The thickness of the stencil 4, 10 may vary according to the required thickness of the adhesive.
In an embodiment, the liquid adhesive printed on the first substrate may be partially cured prior to applying pressure to bond a second substrate to a first substrate having liquid adhesive printed thereon.
It will be appreciated that there are several methods for performing the circumferential cure. For example, a mask having an aperture for exposing the liquid adhesive to a curing source may be used for performing the circumferential cure. If the curing source is an Ultra violet (UV) light source, the mask may have a UV obstructing stencil portion adapted for blocking UV light directed to a center portion of the liquid adhesive printed onto the first substrate 23. The mask may also have an aperture for exposing the liquid adhesive on a circumferential periphery of an adhesive printed area of the first substrate 23 to the UV light source. The UV light source may include a plurality of UV Light Emitting Diodes (LEDs) arranged in a line array, or a UV lamp such as for example, a Xenon lamp.
Alternatively, the liquid adhesive on the circumferential periphery of the print area may be partially cured to form the circumferential adhesive wall structure by using a spot UV LED light source.
In an embodiment, there is an apparatus (not shown) for forming a laminated product having a first substrate and a second substrate. The apparatus includes a stencil printing device for applying a liquid adhesive on a surface of the first substrate for bonding the first substrate to the second substrate, a bonding device for bonding the first substrate to the second substrate, and a curing device for curing the liquid adhesive. The liquid adhesive located on a circumferential periphery of the first substrate may be cured by the curing device in a manner such that a circumferential adhesive wall structure is formed for limiting movement of the liquid adhesive within the circumferential adhesive wall structure before pressure is applied on the bond area by the actuator. The curing device may be used with a mask having an aperture for exposing the liquid adhesive to a curing source to form the circumferential adhesive wall structure. Further details of the bonding device is illustrated in
The vacuum chamber 40 has an upper part 41 and a lower part 42 in sealed connection with the upper part 41 to define a vacuum environment 43. The upper part 41 may be movable relative to the lower part 42 to provide an outlet 44 to allow air to enter the vacuum environment 43 when it is desired to return a pressure setting to the vacuum chamber 40 to atmospheric pressure quickly. The vacuum pressure determines the pressure of the air void trapped during lamination. The vacuum pressure in the vacuum chamber 40 may be set close to perfect vacuum or a pressure up to 5000 pascal. Most preferably, for high yield production, the vacuum chamber 40 may be set at a vacuum chamber pressure below 5000 pascal. A lower vacuum chamber pressure will result in a lower pressure in the vacuum voids present in the substrate assembly if there is air trapped in the liquid adhesive. Such air voids may disappear after the substrate assembly is brought from a predetermined vacuum pressure to atmospheric pressure whereby the pressure difference will compress the voids to a size not visible to the naked eye.
The bonding device 30 has a platen 33 configured for holding a second substrate 32. The platen 33 is also configured for applying pressure on a bond area between the first substrate 31 with liquid adhesive 37 printed thereon and the second substrate 32. For example, the platen 33 may be part of a press machine coupled within the vacuum chamber 40.
The bonding device 30 also includes a support 34 configured for holding a first substrate 31 and a biasing mechanism 35 configured to bias the support 34 between a first position wherein the support 34 lies in a plane inclined relative to the second substrate 32 and a second position wherein the support 34 is biased to apply pressure on the bond area through the first substrate 31 to incrementally increase the bond area on which the pressure is applied to incrementally bond the first substrate 31 to the second substrate. The support 34 may be for example a plate or a planar support adapted or configured for holding the first substrate 31.
It will be appreciated that the support 34 may have a flatness of 20 microns (μm) or less so as to maintain a substantially planar surface during the incremental increase of the bond area between the first substrate 31 and second substrate 32. Optionally, the bonding device 30 may include a guide member located on the support 34 (not shown) and movable towards a central longitudinal axis of the support 34 to align the first substrate with the second substrate prior to applying pressure.
It will be appreciated that the support may have a tilted configuration as shown in
After the second substrate 32 is bonded to the first substrate 31 with the liquid adhesive 37 printed thereon to form a substrate assembly 39, it is required to cure the liquid adhesive 37 to form the laminated product.
Optionally, in display applications such as a touch screen mobile device whereby the laminated product is a touch screen display and one of the two substrates in the laminated product is a cover glass with a coloured periphery, a two step curing process may be implemented to cure the liquid adhesive in the lamination process.
The liquid adhesive 64 on the outer circumferential periphery 62 of the LCD module 61 and under the coloured masking of the glass substrate 63 may be cured by an edge cure by introducing a UV light directly at an adhesive edge 67 as shown in
Step 83 may include tilting the first substrate to lie in a plane inclined relative to the second substrate prior to incrementally increasing the bond area between the second substrate and the first substrate.
Optionally, after step 83 and prior to step 84, a pressure in the vacuum chamber may be set at atmospheric pressure to compress all vacuum voids created during the lamination process. Air may be introduced into the vacuum chamber to enable the chamber pressure to reach atmospheric pressure quickly. A compressive force may be applied when the two substrates are in a compressed position to eliminate voids that may be present after the substrates are bonded at step 82. Dependent on the process requirements of the adhesive used in the lamination process and the substrates to be laminated, the compressive force may be varied accordingly. For example, where one of the substrates is a LCD display, the compressive force may be in the range of 1 to 4.5 kg/cm2.
Optionally, an alignment process can be introduced by providing a side guide on the biasing structure to align the first substrate prior to lamination or to align the first and second substrates prior to curing.
An inspection step may also be introduced to inspect for defects prior to subjecting the substrate assembly to a complete UV cure as shown in
In an embodiment, uneven application of liquid adhesive on the substrate may be wiped using a wiper, prior to forming the circumferential adhesive wall structure for limiting movement of the liquid adhesive. The wiper may be coupled to a stencil printing device for printing the liquid adhesive and arranged such that as the liquid adhesive is printed on a substrate, the wiper simultaneously wipes any uneven application of liquid adhesive. The advantage of wiping the liquid adhesive is to maintain uniform thickness of the liquid adhesive in the aperture and to control planarity of the liquid adhesive printed on the substrate.
During a liquid adhesive printing step, liquid adhesive 113 is dispensed from a dispenser 108 such as for example a slot die 108 to be printed on the first substrate 106. The slot die 108 has an inlet 109 for receiving liquid adhesive, an outlet 110 for dispensing liquid adhesive and a passageway 111 in communication with the inlet 108 and the outlet 110. The passageway 111 may be configured to allow liquid adhesive to be dispensed from the outlet 110. It will be appreciated that the slot die 108 is positioned such that the slot die 108 does not contact the liquid adhesive printed on the first substrate 106 and that there is a gap between a bottom surface of the slot die 108 and a top surface of the printed liquid adhesive. The stencil printing device 103 is configured to be movable across the aperture so as to print liquid adhesive dispensed from the slot die 108.
A wiper 112 may be coupled to the stencil printing device 103 at a rear end 113 of the stencil printing device 103 for wiping uneven application of liquid adhesive 113 printed on the first substrate 106. The wiper 112 may be configured to apply a controlled pressure to wipe any uneven application of liquid adhesive. The wiper 112 may be adjustable along its length to control the liquid adhesive thickness across the whole aperture of the stencil. The wiper 112 may be configured to be movable relative to the stencil printing device 103 in a substantially vertical direction for applying pressure on the stencil 104 to contact the stencil 104 before wiping. An actuator 114 may be coupled to the wiper 112 to enable the wiper 112 to be lowered towards or raised away from the stencil 104 along the vertical direction. Still further, the wiper 112 may be moved across the stencil 104 via movement of the stencil printing device 103 and has a curved profile 115 adapted for wiping liquid adhesive and to maintain uniform thickness of the liquid adhesive 113 on the first substrate 106. For example, the thickness of the liquid adhesive 113 may be controlled within 10% of an adhesive thickness profile defined by the requirements of an end product in which the laminated product is used. The wiper 112 may be an elongate rod member 116 having a curved profile 115 for line contact with the liquid adhesive 113 on the first substrate 106.
As the liquid adhesive 113 is dispensed and printed on the first substrate 106 by movement of the stencil printing device 103 in a first direction 117, the wiper 112 simultaneously wipes any uneven application of the liquid adhesive 113 printed on the first substrate 106 to control planarity of the liquid adhesive 113 and to maintain a consistent volume of the liquid adhesive 113. Although the wiping may be done after printing of the liquid adhesive 113 on the first substrate 106 is complete, wiping the uneven application of the liquid adhesive 113 simultaneously with printing of the liquid adhesive 113 enables reduction in production cycle time required in transfer of substrates with printed adhesive to a separate process module or station to perform wiping. In high volume production, such reduction in production cycle time lead to significant savings in time costs.
After the printing of the liquid adhesive 113 on the first substrate 106 is complete, any excess liquid adhesive wiped by the wiper 112 may be moved through movement of the stencil printing device 103 to the recess 107 of the stencil 104. The wiper 112 may further include a guide surface 118 for moving the excess liquid adhesive onto a next substrate to be used for forming a laminated product.
A wiper 128 comprising a first wiper member 129 and a second wiper member 130 may be arranged on the stencil printing device 120 for wiping uneven application of liquid adhesive 131 printed on the first substrate 126. Specifically, the first wiper member 129 is attached to a rear end 131 of the stencil printing device 120 and the second wiper member 130 is attached to a front end 132 of the stencil printing device 120. Each of the first and second wiper members 129, 130 may be adjustable along its length to control the liquid adhesive thickness across the whole aperture of the stencil 121. Still further, the wiper 128 may be moved across the stencil 121 via movement of the stencil printing device 120.
The wiper 128 may be configured to be movable relative to the stencil printing device 120 in a substantially vertical direction for applying pressure on the stencil 104 to contact the stencil 121 before wiping. In particular, an actuator 114 may be coupled each of the first and second wiper member 129, 130 to enable the wiper members 129, 130 to be lowered towards for wiping or raised away from the stencil 104. For example, each of the wiper members 129, 130 may include an elongate rod member having a curved profile 132, 133 adapted for wiping liquid adhesive and to maintain uniform thickness of the liquid adhesive 131 on the first substrate 106. For example, the thickness of the liquid adhesive 131 may be controlled within 10% of an adhesive thickness profile defined by the requirements of an end product in which the laminated product is used.
In a liquid adhesive printing step as shown in
After the printing of the liquid adhesive 131 on the first substrate 126 is complete, any excess liquid adhesive wiped by the first wiper member 129 may be moved to the first recess 122 of the stencil 121 as shown in
After removing the first substrate 126 with the liquid adhesive 131 printed thereon, the stencil printing device 120 is at a position of the end of a liquid adhesive printing step, i.e. adjacent or at the first recess 122 of the stencil 121. As shown in
After the printing of the liquid adhesive 140 on the first substrate 138 is complete, any excess liquid adhesive wiped by the second wiper member 130 may be moved to the second recess 123 of the stencil 121 in a similar manner as shown in
Wipers with circular cross section areas having a quadrant shaped slot have been used as examples in the description for the wipers in
The present invention may be used for lamination of two or more substrates to form a laminated product in various applications which use laminated products such as for example, displays. The laminated product may include a touch screen assembly, a display panel, a composite laminate, or a layered product having at least two layers bonded together with an adhesive layer. An advantage of using the biasing structure in the lamination process is to obtain a good sealing effect in the laminated product. Consequently, good dimensional accuracy, optical clear appearance, good holding strength as well as good capacitive or resistive response can be achieved in laminated products such as displays with touch sensitive properties.
Although rigid materials have been used as examples in the above description for the substrates in the lamination process, it will be appreciated that a flexible substrate having a thickness and rigidity suitable to form a planar surface for stencil printing of the liquid adhesive, may also be a substrate. For example, the flexible substrate may be made of a material include but not limited to polyester, polyimide, or printable polymer material having mechanical and thermal properties suitable for forming laminated products. The first substrate and the second substrate may include more than one layer. It will be appreciated that the adhesive used in the lamination process should not be volatile if used in a vacuum environment.
For ease of description, UV curable adhesives and UV curing of the liquid adhesives have been described herein, but it is to be understood that other types of printable liquid adhesives or other curing methods such as visible light curing may be used in the process for forming the laminated product.
The printable adhesives used in forming laminated products may include adhesives that are thixotropic or non-thixotropic provided that the adhesive material is able to flow freely into the aperture of the stencil and then recover quickly to resist slump after printing. The printable adhesives may include adhesives having a viscosity in the range of 15,000 centipoise (cps) to 100,000 cps at a shear rate of 1 sec−1 or adhesives having a lower viscosity. The liquid adhesive should also have good wetting properties in that it should not flow after printing within a specified processing time, such as for example, 20 seconds.
For manufacturing of laminated products for use in displays, the liquid adhesive may be a liquid optically clear adhesive with properties suitable for bonding display substrates such as glass, plastics, LCD, touch screen substrate or the like. The liquid adhesive may include a UV curable adhesive.
Still further, liquid adhesives of different viscosities may be used for printing on the first substrate. Table 1 lists examples of liquid adhesives that may be used in forming a laminated product such as for example, a touch screen LCD display device. The liquid adhesives Examples 1 to 3 have a range of viscosity measurements measured over a shear rate range of 0.001 to 100 sec−1 at 25 degrees Celsius (° C.).
Example 1 is a thixotropic liquid optically clear adhesive having a viscosity over a shear rate range of 0.001 to 100 sec−1 as listed in Table 1. Example 1 may be printed on a first substrate such as a LCD display panel using a stencil as. The aperture may be of a size: 481.7 millimeters (mm) by 273.8 millimeters (mm) which may be bigger than a viewing area of the LCD panel by 5 millimeters (mm). The adhesive thickness may be about 300 microns (μm), with a tolerance of +1-15 microns (μm). Prior to applying pressure to bond a cover glass to the LCD panel with printed liquid adhesive, the printed adhesive may be partially circumferentially cured to limit movement of the liquid adhesive by UV light curing based on 15% dosage of a full UV curing of the liquid adhesive. The circumferential width of the partially cured adhesive may be 2 millimeters (mm).
The display panel with the liquid adhesive printed thereon and a cover glass may be bonded or laminated by applying a pressure in a vacuum environment set at a pressure of 100 pascal or process conditions as described in
Example 2 is a thixotropic liquid optically clear adhesive having a range of viscosity measurements lower than the viscosity measurements that of Example 1. Example 2 may be used to form a laminated product and the process conditions may be similar to as the process conditions for forming the laminated product using the liquid adhesive of Example 1.
In Example 3, a non-thixotropic liquid optically clear adhesive having a lower viscosity than that used in Example 2 may be used. The process conditions in forming a laminated product using Example 3 may be similar to as the process conditions for forming the laminated product using the liquid adhesive of Example 1. The above viscosity measurements may be determined over a shear rate range of 0.001 to 100 sec−1 at 25 degrees Celsius (° C.) using a rheometer such as for example a AR2000 Rheometer (manufactured by TA Instruments) equipped with a 40 millimeters (mm) diameter by 1° cone. Advantageously, after curing, the laminated LCD panels or products formed using the liquid adhesives in Examples 1, 2, and 3 do not show presence of defects such as for example, yellow band, mura, void. A further advantage of the present invention is that the overflow of liquid adhesive may be controlled.
A description has heretofore been given of the invention, using the embodiments, but the configuration described so far in each embodiment being only one example, the invention can be appropriately modified without departing from the scope of the technological idea. Also, it is also acceptable that the configurations described in the individual embodiments are used in combination unless they conflict with each other.
Number | Date | Country | Kind |
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201108644-4 | Nov 2011 | SG | national |
Filing Document | Filing Date | Country | Kind |
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PCT/SG2012/000438 | 11/22/2012 | WO | 00 |