The invention relates to material coloring, particularly to a laminated structure with color and a method for changing color thereof, especially to presenting metallic luster.
With advances of electroplating and deposition technologies, various technologies can be applied to surface treatment of objects, for example, changing color of an object by coating. This is different from conventional painting.
For the sake of lightweight, some mobile phones adopt reinforced plastic to form their outer casings and the outer casings are further coated with a coating containing metal components to generate metallic luster. However, because an antenna of a mobile phone usually abuts against its outer casing, the coating with metal components will adversely affect transmission of the antenna.
An object of the invention is to provide a laminated structure with color and a method for changing color thereof, which uses metalloid material to be passed by visible light to present color and the presented color can be changed by adjusting a thickness of the metalloid material.
Another object of the invention is to provide a laminated structure with color, which can present color with metallic luster.
To accomplish the above objects, the invention provides a laminated structure including a base layer, a color layer and a reflective layer. The color layer is formed by a metalloid material, has a thickness and is superposed on the base layer. The reflective layer is superposed with the base layer and the color layer. Visible light passes through the thickness of the color layer and is reflected by the reflective layer to present a color.
To accomplish the above objects, the invention provides a method for changing color of a laminated structure, in which wave length and color of visible light can be changed by controlling a thickness of the color layer.
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The base layer 1 is an object, a material or its surface to be colored. The base layer 1 is made of a material with certain strength or hardness, such as metal, alloy, glass or plastic. In this embodiment, the base layer 1 is used to serve as an outer casing of a mobile phone or the like. Under this situation, the base layer 1 is made of plastic and has an outer surface 11 and an inner surface 12. The outer surface 11 is used for being superposed by the color layer 2 and the reflective layer 10. The inner surface 12 can be attached by an electronic component such as an antenna 3.
The color layer 2 is formed by a metalloid material such as boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te), polonium (Po) and astatine (At). Preferably, silicon is adopted, and pure silicon (purity above 99%) is more preferable. To prevent interference to wireless communication of mobile phones, the metalloid material used by the color layer 2 has no metal component. This makes the invention more suitable for 5G mobile communication.
The color layer 2 has a thickness d and superposed on the base layer 1. The color layer 2 may be coated on the base layer 1 or the reflective layer 10 by silicon coating which may be vacuum evaporation, magnetic sputtering or cathode arc vapor. To increase adhesion between the base layer 1 and the color layer 2, sandblasting roughening, atmospheric plasma, corona treatment, vacuum plasma treatment or vacuum ion source can also be used. In addition, the color layer 2 may be further added with surface treatment such as anti-fingerprint or paint protection to increase service life of the color layer 2. The surface treatment of anti-fingerprint may be spraying or vacuum physical vapor deposition.
The reflective layer 10 is superposed with the base layer 1 and the color layer 2. In this embodiment, the reflective layer 10 is superposed on the outer surface 11 of the base layer 1 and sandwiched between the base layer 1 and color layer 2. When visible light pass through the thickness d of the color layer 2, the visible light can be reflected by the reflective layer 10 to make the light source present color on the color layer 2. When visible light has passed through the thickness d of the color layer 2 to reach the base layer 1 or the reflective layer 10, the refraction to the visible light in the color layer 2 can change wavelength of the visible light by the optical property of material such as silicon. Furthermore, both a surface of the base layer 1 or the reflective layer 10 as a background color and its surface roughness will cause spectrum variation to the color presented. Accordingly, users can view different colors with the naked eye.
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It will be appreciated by persons skilled in the art that the above embodiments have been described by way of example only and not in any limitative sense, and that various alterations and modifications are possible without departure from the scope of the invention as defined by the appended claims.