The present invention relates to the casting of steel slabs and more specifically to upper tundish nozzles used in such casting. Most specifically, the invention relates to argon injected upper tundish nozzle designs by which argon leakage therefrom is minimized/eliminated.
The present invention relates to an improved design for an upper tundish nozzle. The nozzle is designed to be used in continuous casting of steel into slabs.
The ceramic inner portion 6 of such nozzles are often formed from a porous, gas permeable refractory material which may be a ceramic oxide of aluminum, silicon, magnesium, chromium, or zirconium, or mixtures thereof. Alternatively, and more preferably, the ceramic inner portion 6 of the nozzle may be formed of a ceramic material having pierced/tunneled holes in the ceramic to provide set gas flow paths within the ceramic inner portion 6.
The porous, gas permeable refractory material and/or the pierced/tunneled holes provide flow paths for Argon gas which is injected into the upper tundish nozzle 4 during continuous casting to deter clogging of the upper tundish nozzle 4 with solid inclusions. The argon flow also affects the flow pattern of steel in the upper tundish nozzle 4, the gate valve and subsequently in the casting mold 3.
As alluded to above, the inside surface of the ceramic inner portion 6 of the upper tundish nozzle 4 defines a bore for conducting a flow of liquid steel. The outside surface of the ceramic inner portion 6 is enveloped in a protective can 5. The protective can 5 can be formed of metallic sheet material, such as steel, that may be spaced apart from the outside surface of the ceramic inner portion 6 in order to define one or more annular, gas conducting spaces. The argon gas is injected into the upper tundish nozzle 4 via a gas injection port 7.
While such upper tundish nozzles 4 have generally shown themselves to be effective in retarding the accumulation of bore-obstructing alumina deposits, the inventors have observed a number of shortcomings associated with such nozzles. One specific issue relates to leakage of argon gas, i.e. the loss of argon from the system in areas that are not the gas injection holes 8″ of the inner bore surface of the upper tundish nozzle 4. Such leaks can occur when cracks 9 in the inner ceramic portion 6 intersect with the argon pressure/distribution manifold 8 and/or the individual gas injection channels 8′. Such leaks can jeopardize the proper function of the gas in pathways to the interior bore of the upper tundish nozzle 4. If the gas leaks are serious enough it could interfere with forming a protective fluid film over the surface of the nozzle bore. The pressure of the inert gas must be maintained at a level high enough to overcome the considerable backpressure that the molten steel applies to the surface of the bore. Ideally, the gas pressure should be just enough to form the desired film. If it is too high, the gas can stir the steel excessively, thus creating additional defects. Thus, the control of the gas pressure and flow is critical and must be maintained within a narrow range. Any significant leak can jeopardize the desired delicate pressure balance. Further such argon loss is an added expense to production and therefore should be minimized if possible.
Clearly, there is a need for an improved upper tundish nozzle 6 design that minimizes or eliminates the leakage mechanisms inherent in the prior art designs.
The present invention relates to a leak-proof gas injected upper tundish nozzle. The gas injected upper tundish nozzle 4 may include a protective can 5, and a ceramic inner portion 6 disposed within the protective can 5, as shown in
The gas flow passages may include a gas pressure/distribution manifold 8 and individual gas injection channels 8′. The sacrificial mold 6* may include a proto-manifold 8* and proto-injection channels 8** formed of sacrificial material.
The gas flow seal 11 may be formed by depositing nickel or nickel alloy onto the proto-manifold 8* and proto-injection channels 8** by a method selected from the group consisting of electroless plating, nickel foil strips, sputtering, physical vapor deposition, chemical vapor deposition, plasma deposition, and metal printing. Additional nickel or nickel alloy may be deposited into the gas pressure/distribution manifold 8 and individual gas injection channels 8′ after the sacrificial mold 6* has been removed from the ceramic inner portion 6.
The protective can 5 may be formed of a metal material such as, for instance, a steel material. The ceramic inner portion 6 may be formed from a refractory material consisting of a ceramic oxide of one or more of aluminum, silicon, magnesium, chromium, or zirconium, or mixtures thereof. The gas distribution channels 8′ may have gas outlets 8″ to release the gas into the steel flowing within the upper tundish nozzle 4.
The gas flow seal 11 may be formed by depositing nickel or nickel alloy into the gas pressure/distribution manifold 8 and individual gas injection channels 8′ after the sacrificial mold 6* has been removed from the ceramic inner portion 6 without deposition of nickel/nickel alloy onto the sacrificial mold 6*.
The present invention is an improved argon injected upper tundish nozzle 4 which minimizes/eliminates unwanted leakage of inert gas (such as argon) therefrom.
The upper tundish nozzle 4 of the present invention is the type that contains preformed argon pressure/distribution manifold 8 and individual gas injection channels 8′ as shown in
The ceramic inner portion 6 of the upper tundish nozzle 4 is generally formed by hydrostatic pressing of powdered ceramic materials. For this type of upper tundish nozzle 4, the preformed argon pressure/distribution manifold 8 and individual gas injection channels 8′ are formed by isostatic pressing of the powdered ceramic material around a sacrificial mold. After the isostatic pressing, the mold is then removed leaving the argon pressure/distribution manifold 8 and individual gas injection channels 8′.
The inventors electroplated nickel onto a sacrificial mold 6* and used it to isostatically press to form an upper tundish nozzle 4. While the inventors have used electroplating to deposit the nickel seal 11. Other viable techniques include electroless plating, nickel foil strips, sputtering, physical vapor deposition, chemical vapor deposition, plasma deposition, metal printing and the like. What is important is not how the nickel got into position, but rather forming the nickel seal 11 onto the inner surface of the argon pressure/distribution manifold 8 and individual gas injection channels 8′ of the ceramic inner portion 6.
Further, while the nickel sealant layer 11 may be formed onto the sacrificial mold 6*, it may alternatively be formed by gaseous or liquid deposition onto the inner surface of the argon pressure/distribution manifold 8 and individual gas injection channels 8′ after the ceramic inner portion 6 has already been formed. Additionally, both pre-production deposition of the nickel/alloy sealant 11 onto the sacrificial mold 6* and post-production of deposition of additional nickel/alloy sealant 11 may be combined to form the final product.
Filing Document | Filing Date | Country | Kind |
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PCT/IB2021/058718 | 9/24/2021 | WO |