This is a U.S. national stage of application No. PCT/DE2009/000629, filed on Apr. 28, 2009.
This application claims the priority of German application no. 10 2008 021 675.5 filed Apr. 30, 2008 and 10 2008 035 900.9 filed Jul. 31, 2008, the entire content of both of which are hereby incorporated by reference.
The present invention is related to a light-emitting diode chip with a semiconductor layer sequence, which comprises an active zone for generating electromagnetic radiation.
The light yield of light-emitting diode chips is influenced by various factors. By means of suitable electrical contacting of the light-emitting diode chip it is possible to achieve good internal quantum efficiency. At the same time, however, contacting constitutes a possible absorption source for the generated radiation, so limiting outcoupling efficiency and thus the light yield of the light-emitting diode chip.
One object of the invention is to increase the light yield of light-emitting diode chips.
A light-emitting diode chip with a semiconductor layer sequence is provided, which comprises an active zone for generating electromagnetic radiation. To generate radiation, the semiconductor layer sequence is contacted electrically.
Applied to the semiconductor layer sequence is a current spreading layer, which is contacted electrically by means of contacts. For example, the contacts cover 1%-8% of the current spreading layer, and particularly preferably they cover 2%-4% of the current spreading layer.
When contacting the semiconductor layer sequence by way of a current spreading layer, it is possible to achieve particularly uniform current distribution. The absorption of radiation at the contacts is minimised by the small contact surface. A degree of coverage of 1%-8% and in particular of 2%-4% represents a good compromise between sufficient power supply and tenable absorption.
In this case, surface coverage of the semiconductor layer sequence relates to the sum of the cross-sectional areas of the contacts at the interface with the current spreading layer.
The charge carriers are injected via the contacts into the current spreading layer and distributed uniformly laterally in the current spreading layer. From the current spreading layer they enter the semiconductor layer. A p-doped semiconductor layer generally comprises only low transverse conductivity and may therefore only bring about insufficient lateral distribution of the charge carriers. It is therefore particularly advantageous here for the charge carriers to be distributed uniformly laterally by means of a current spreading layer before they are injected into the semiconductor layer.
The contacts are preferably distributed uniformly over the surface of the current spreading layer.
This results in a particularly uniform lateral distribution of the charge carriers in the current spreading layer.
In an advantageous embodiment the contacts take the form of separate contact points. A contact is designated a contact point if it covers the current spreading layer only in point-like manner.
The contact points are preferably distributed uniformly over the surface of the current spreading layer.
In a preferred embodiment neighbouring contact points are arranged with a spacing of less than 30 μm, in particular of less than or equal to 12 μm.
The contacts are for example arranged at nodes of a regular grid. The grid constant of the grid is preferably less than 30 μm. It is particularly advantageous if the grid constant is less than or equal to 12 μm.
The grid constant then corresponds to the spacing between neighbouring contact points. The cross-sectional area of the individual contact points preferably decreases as the grid constant likewise decreases. This ensures that the contacts cover a total of only 1%-8% and particularly preferably only 2%-4% of the surface of the current spreading layer even with a relatively small grid constant. The area of a contact point results directly from the contact spacing and the average surface coverage.
In one advantageous configuration a free region is formed at the interface between the current spreading layer and the contacts, in which region the current spreading layer is not covered by contacts. The surface coverage of the free region is for example similar in magnitude to the surface coverage of the contacts. If the contacts are arranged at the nodes of a regular grid, the nodes of the grid located in the free region are free of contacts. In this case, for example, the free region is as large as the region of the current spreading layer in which the nodes of the grid are free of contacts. In one embodiment the free region takes the form of a frame and surrounds the contacts. For example, the width of a frame portion lies in the range from at least 1 μm to at most 10 μm.
The free region is preferably provided in a region in which a particularly large proportion of the generated radiation arises, since in this way absorption of the radiation may be reduced particularly effectively. The majority of the radiation is generated in a central region of the active zone of the semiconductor layer sequence. For this reason, a particularly large amount of radiation also impinges on a region of the current spreading layer which is located perpendicularly below this central region. The provision of a free region there is therefore particularly favourable. The area of the free region is preferably selected such that maximally uniform current distribution is ensured.
In one embodiment the contacts are configured such that their thermal conductivity increases as the spacing from the semiconductor layer sequence increases.
It may in this way be ensured that the contacts provide good dissipation of the heat generated in the active zone, without their leading to elevated absorption of the radiation. In the vicinity of the semiconductor layer sequence the contacts exhibit low absorbency for generated radiation. This is usually accompanied by low thermal conductivity. For example, the contacts are reflected at the boundary to the current spreading layer. With increasing distance from the semiconductor layer sequence, a smaller proportion of the radiation impinges on the contacts or further constituents of the light-emitting diode chips due to reflection and absorption of the radiation. For this reason, when configuring the contacts less consideration has here to be paid to absorption of the radiation and the contacts may be optimised in terms of their thermal conductivity.
An increase in thermal conductivity with increasing distance from the semiconductor layer sequence may be achieved for example by an increase in the cross-sectional areas of the contacts. The contacts are for example conical in form.
Preferably, a dielectric layer adjoins the side of the current spreading layer which is remote from the semiconductor layer sequence. Since the dielectric layer exhibits only slight electrical conductivity, the contacts are passed therethrough and are in electrical contact with the current spreading layer.
The dielectric layer serves to reflect back the impinging radiation into the semiconductor layer sequence with as little loss as possible. The reflected radiation may then leave the light-emitting diode chip for example through a top outcoupling region. The dielectric layer thus increases the outcoupling efficiency of the light-emitting diode chip. This is particularly advantageous for thin-film light-emitting diode chips or in the case of a flip chip structure.
The dielectric layer takes the form, for example, of a Bragg mirror, in which dielectric sublayers with high and low refractive indices are alternately arranged.
In one advantageous embodiment the dielectric layer comprises a particularly low refractive index. In this way, the largest possible proportion of the radiation is reflected. For example, the dielectric layer contains a low-k- or an ultra low-k material. The dielectric layer may also be an air layer. This means that the contacts may be surrounded at least in places by an air layer.
In one embodiment of the light-emitting diode chip, a metallic layer is located on the side of the dielectric layer which is remote from the semiconductor layer sequence. The contacts preferably adjoin the metallic layer.
The metallic layer makes it possible for the part of the radiation which has not been reflected by the dielectric layer to be reflected back into the semiconductor layer sequence.
In one embodiment the light-emitting diode chip comprises an electrically conductive carrier. In this case the semiconductor layer sequence may be electrically connected by means of a bottom contact which is located on the outside of the carrier. The charge carriers may then be injected via the bottom contact, the carrier, the metallic layer, the contacts and the current spreading layer into the semiconductor layer sequence.
In one advantageous embodiment of the light-emitting diode chip, the current spreading layer is configured such that it absorbs the smallest possible proportion of generated radiation. However, uniform current distribution has to be ensured in this case.
The inventors have established that a current spreading layer with a thickness in the range from 10 nm to 60 nm represents a good compromise between minimising absorption and maximising transverse conductivity.
In this case, the optimum thickness of the current spreading layer also depends on the material used. For example, the current spreading layer contains a transparent conductive oxide (TCO) such as indium-tin oxide (ITO), indium-zinc oxide (IZO) or zinc oxide (ZnO).
Preferably, an ITO layer has a thickness of at least 15 nm, an IZO layer a thickness of at least 30 nm and a ZnO layer a thickness of at least 40 nm.
In a particularly advantageous embodiment of the light-emitting diode chip, the arrangement of the contacts, the form of the contacts, the thickness of the current spreading layer and the material of the current spreading layer are all matched to one another and optimised. For example, when the contacts are spaced by a relatively small amount, the thickness of the current spreading layer may be reduced.
The stated semiconductor chip and its advantageous configurations are explained below with reference to schematic figures, which are not to scale and in which:
The semiconductor layers 21, 22, 23 may be grown epitaxially and preferably exhibit a total thickness of less than 20 μm, in particular of less than 10 μm. In particular, the light-emitting diode chip 1 may be a thin-film light-emitting diode chip.
A top contact 61 and a bottom contact 62 are provided for electrical contacting of the light-emitting diode chip. For example, the top contact 61 takes the form of a bond pad and is connected with a bonding wire (not shown). The bottom contact 62 is connected for example to a conductive track structure of a printed circuit board (not shown).
The bottom contact 62 is arranged on the outside of a carrier 6 of the light-emitting diode chip 1. The carrier 6 is electrically conductive and comprises for example semiconductor materials, such as silicon, silicon carbide, gallium arsenide, gallium nitride or germanium.
In an alternative embodiment the carrier 6 may also consist of a non-conductive material. The contacts 5 are then preferably passed through the carrier 6.
By means of contacts 5, an electrical connection is produced between the carrier 6 and the semiconductor layer sequence 2. The contacts 5 adjoin a current spreading layer 3, which in turn adjoins the p-doped semiconductor layer 23. In other embodiments the contacts 5 may also project into the current spreading layer 3.
The contacts 5 are uniformly distributed over the surface of the semiconductor layer sequence 2. The spacing a of two neighbouring contacts 5 is preferably less than 24 μm, particularly preferably less than 12 μm.
The current spreading layer 3 preferably exhibits a thickness b in the range from 10 nm to 60 nm. It contains a transparent conductive oxide (TCO) for example indium-tin oxide (ITO), indium-zinc oxide (IZO) or zinc oxide (ZnO). The current spreading layer 3 is sputtered onto the semiconductor layer 23, for example.
Between the current spreading layer 3 and the carrier 6 there is located a dielectric layer 4, through which the contacts 5 are passed. The dielectric layer 4 serves to reflect impinging radiation back into the semiconductor layer sequence 2, such that this may leave the light-emitting diode chip 1 through a top outcoupling region 8. The dielectric layer 4 contains silicon dioxide, for example. In further embodiments the dielectric layer 4 may contain a material which has a particularly low refractive index. The dielectric layer 4 may in particular also be an air layer.
To produce the contacts 5, recesses may be introduced into the dielectric layer 4 in a photolithographic process and filled with a conductive material, for example a metal.
In addition, in a central region the dielectric layer 4 passes through the current spreading layer 3 and directly adjoins the p-doped semiconductor layer 23. This leads to absorption of the radiation in the current spreading layer 3 being reduced precisely in this central region.
The dielectric layer 4 is closed off in the direction of the carrier 6 by a metallic layer 63. The metallic layer 63 is suitable for reflecting radiation which was not reflected by the dielectric layer 4 back into the semiconductor layer sequence 2. The metallic layer 63 is applied to the dielectric layer 4 for example by sputtering, vapour deposition or by electrodeposition. The contacts 5 are in electrical contact with the metallic layer 63. The metallic layer 63 is enclosed by a further metallic layer 64.
In addition, in this exemplary embodiment the top outcoupling region 8 is roughened. This improves outcoupling efficiency. The dielectric layer 4 is also arranged laterally on the semiconductor layer sequence 2. This assists in electrical insulation of the light-emitting diode chip 1.
In
It is clear from
For the calculation it was assumed that the contacts are arranged at the nodes of a regular grid with a grid constant of 12.5 μm. The radiation generated in the active zone 21 has a wavelength of 460 nm.
In
Contacts of the contact materials 54, 55, 56 according to
The calculations are based on a power supply of 2 A/mm2 and a specific contact resistivity ρK of an arrangement of TCO layer and contacts of 5×10−10 Ωm2. The contact resistivity of the arrangement results from the quotient of the specific contact resistivity and the base area of the arrangement. By pretreatment of the TCO layer this contact resistivity may be further reduced.
Where contact spacings a are small, the specific contact resistivities ρK of the arrangements approach a value of around 4×10−8 Ωm2. This value corresponds to the specific contact resistivity ρK between the semiconductor layer and the TCO layer, and between the TCO layer and the contacts. For larger contact spacings the specific contact resistivity ρK increases due to current spreading in the TCO layer.
In this respect, the specific contact resistivity ρK should not become too great, since otherwise the efficiency of the light-emitting diode chip is impaired. The inventors have established that ρK should rise by 50% at most due to current spreading. This corresponds to a maximum specific contact resistivity ρK of around 6×10−8 Ωm2, which is shown in
In
In the arrangement according to
In
For contact spacings a <6 μm a plateau is in each case reached in the thermal resistivity RT, which substantially reflects the surface coverage and thermal conductivity of the contacts. Where contact resistivities are relatively large, the thermal resistivity RT increases due to thermal expansion in the semiconductor layer. With the contact spacing a derived from
For arrangements 91-97 shown, the emitted light outputs P were measured. In this case, a series of components were measured for each arrangement and a mean calculated. The measurement results are in each case plotted in scale units above the arrangements 91-97 shown. Under the arrangements the median, the mean and the number of components measured are stated in each case. It is clear from
In the arrangements measured, the contact structures are not connected with a current spreading layer, but rather directly with a semiconductor layer.
In
The description made with reference to exemplary embodiments does not restrict the invention to these embodiments, but rather encompasses any novel feature and any combination of features. These include in particular any combination of features in the claims, even if this feature or this combination is not itself explicitly indicated in the claims or exemplary embodiments.
Number | Date | Country | Kind |
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10 2008 021 675 | Apr 2008 | DE | national |
10 2008 035 900 | Jul 2008 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/DE2009/000629 | 4/28/2009 | WO | 00 | 1/4/2011 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2009/132641 | 11/5/2009 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
5917202 | Haitz et al. | Jun 1999 | A |
6784462 | Schubert | Aug 2004 | B2 |
7012279 | Wierer, Jr. et al. | Mar 2006 | B2 |
7119372 | Stokes et al. | Oct 2006 | B2 |
7135709 | Wirth et al. | Nov 2006 | B1 |
7642183 | Zhao et al. | Jan 2010 | B2 |
7683380 | Lee et al. | Mar 2010 | B2 |
20030111667 | Schubert | Jun 2003 | A1 |
20040119085 | Bader et al. | Jun 2004 | A1 |
20050087884 | Stokes et al. | Apr 2005 | A1 |
20050199888 | Seong et al. | Sep 2005 | A1 |
20060273335 | Asahara et al. | Dec 2006 | A1 |
20070278508 | Baur et al. | Dec 2007 | A1 |
20080093612 | Konno et al. | Apr 2008 | A1 |
20100171135 | Engl et al. | Jul 2010 | A1 |
20100208763 | Engl et al. | Aug 2010 | A1 |
20100213485 | McKenzie et al. | Aug 2010 | A1 |
Number | Date | Country |
---|---|---|
199 47 030 | Apr 2001 | DE |
10 2005 003 460 | Oct 2005 | DE |
10 2004 061 865 | Mar 2006 | DE |
10 2005 025 416 | Dec 2006 | DE |
102 44 986 | Feb 2008 | DE |
10 2007 022 947 | Oct 2008 | DE |
10 2007 029 370 | Nov 2008 | DE |
10 2008 005 332 | Jun 2009 | DE |
WO 2004112157 | Dec 2004 | WO |
WO 2005013382 | Feb 2005 | WO |
WO 2009068015 | Jun 2009 | WO |
Number | Date | Country | |
---|---|---|---|
20110114988 A1 | May 2011 | US |